#------------------------------------------------------------------------------ #$Date: 2016-04-02 22:15:59 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180840 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/01/71/2017121.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2017121_Fobs loop_ _publ_author_name 'Chen, Hong-Feng' 'Fang, Qi' 'Yu, Wen-Tao' 'Batsanov, Andrei S.' 'Howard, Judith A. K.' _publ_section_title ; 5-(4,5-Ethylenedithio-1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalen-2-one (EDTO--TTP) and 5-[4,5-(ethene-1,2-diyldithio)-1,3-dithiol-2-ylidene]-1,3,4,6-tetrathiapentalen-2-one (VDTO--TTP) ; _journal_coeditor_code SK3310 _journal_issue 5 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first o198 _journal_page_last o201 _journal_volume 65 _journal_year 2009 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 99.548 _cell_angle_gamma 90.000 _cell_length_a 6.4948 _cell_length_b 28.7194 _cell_length_c 7.1503 _exptl_crystal_F_000 776.00 _reflns_d_resolution_high 0.7776 _cod_data_source_file sk3310Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' s220 in P2(1)/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 461.38 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 0.29 -2.07 4.70 o 4 0 0 1771.43 1751.72 33.02 o 6 0 0 32.66 27.94 12.49 o 1 1 0 8577.60 9117.26 82.24 o 2 1 0 15666.91 16398.04 138.80 o 3 1 0 419.33 484.64 9.30 o 4 1 0 2259.91 2325.56 31.33 o 5 1 0 5.16 -0.27 5.33 o 6 1 0 268.72 266.05 14.10 o 7 1 0 96.82 136.12 19.47 o 8 1 0 245.61 232.49 47.68 o 1 2 0 8363.06 8598.63 123.42 o 2 2 0 9563.54 10013.91 90.12 o 3 2 0 2338.78 2348.79 27.67 o 4 2 0 1.05 -3.58 3.58 o 5 2 0 14.30 12.41 5.97 o 6 2 0 12.57 5.71 8.16 o 7 2 0 11.69 -5.00 11.58 o 8 2 0 12.78 30.08 35.41 o 1 3 0 15.49 24.39 2.05 o 2 3 0 13820.08 14277.73 123.09 o 3 3 0 34.32 50.97 3.57 o 4 3 0 2546.75 2625.07 34.45 o 5 3 0 814.95 797.67 18.51 o 6 3 0 573.14 575.97 20.31 o 7 3 0 904.49 964.57 31.30 o 8 3 0 26.50 16.58 33.77 o 0 4 0 5668.91 5655.46 88.72 o 1 4 0 234.80 209.38 5.30 o 2 4 0 9828.48 10206.18 91.85 o 3 4 0 1385.74 1265.12 19.02 o 4 4 0 3070.30 2967.37 37.86 o 5 4 0 506.60 507.82 22.20 o 6 4 0 34.42 31.43 8.81 o 7 4 0 268.40 279.42 19.09 o 1 5 0 185.14 180.23 5.13 o 2 5 0 18.61 9.53 2.32 o 3 5 0 131.29 157.16 5.75 o 4 5 0 7024.00 6757.98 72.76 o 5 5 0 56.94 78.51 8.40 o 6 5 0 21.53 34.29 11.55 o 7 5 0 198.89 188.23 16.56 o 0 6 0 556.78 541.12 13.40 o 1 6 0 224.60 219.99 5.85 o 2 6 0 1769.77 1872.62 22.38 o 3 6 0 134.05 119.38 6.24 o 4 6 0 13769.58 13099.56 126.42 o 5 6 0 2.04 -3.71 6.86 o 6 6 0 576.29 644.43 20.63 o 7 6 0 85.28 94.07 13.85 o 1 7 0 17.27 21.64 4.43 o 2 7 0 1264.19 1271.38 16.80 o 3 7 0 773.17 729.18 12.76 o 4 7 0 769.79 780.93 19.12 o 5 7 0 6.30 3.85 6.68 o 6 7 0 4796.86 4727.61 71.85 o 7 7 0 18.98 15.42 11.83 o 0 8 0 0.39 1.27 3.79 o 1 8 0 1385.44 1435.53 20.88 o 2 8 0 209.85 211.26 6.79 o 3 8 0 344.32 350.38 10.81 o 4 8 0 275.32 260.36 10.50 o 5 8 0 1146.51 1234.26 27.56 o 6 8 0 2770.58 2699.48 57.56 o 7 8 0 276.22 313.60 19.46 o 1 9 0 576.48 579.44 11.29 o 2 9 0 1624.02 1823.09 26.19 o 3 9 0 2581.14 2591.56 30.53 o 4 9 0 140.58 137.37 8.60 o 5 9 0 662.69 668.92 23.01 o 6 9 0 209.26 257.44 31.28 o 7 9 0 1371.17 1439.05 45.34 o 0 10 0 1821.03 1719.73 34.31 o 1 10 0 384.61 374.96 9.76 o 2 10 0 42.21 32.90 3.56 o 3 10 0 0.06 -1.55 2.81 o 4 10 0 324.22 335.76 14.49 o 5 10 0 6.23 1.04 8.82 o 6 10 0 1245.49 1269.28 34.45 o 7 10 0 3625.83 3751.72 80.99 o 1 11 0 1612.93 1656.24 36.86 o 2 11 0 5882.68 6044.65 69.50 o 3 11 0 13.85 18.40 4.06 o 4 11 0 215.46 225.16 10.15 o 5 11 0 1481.00 1485.38 40.20 o 6 11 0 14.10 6.76 10.22 o 7 11 0 1158.09 1165.21 35.14 o 0 12 0 89.41 113.12 7.49 o 1 12 0 2247.32 2637.64 38.56 o 2 12 0 3.13 2.10 4.71 o 3 12 0 72.60 81.30 5.63 o 4 12 0 1164.66 1110.17 34.72 o 5 12 0 1545.43 1588.66 37.07 o 6 12 0 761.88 800.65 27.36 o 7 12 0 853.88 915.96 30.95 o 1 13 0 159.98 142.68 7.33 o 2 13 0 257.60 280.17 8.47 o 3 13 0 666.77 681.68 17.03 o 4 13 0 0.03 -5.55 5.67 o 5 13 0 1872.13 1933.69 42.33 o 6 13 0 720.36 668.03 25.91 o 7 13 0 10.45 2.59 12.59 o 0 14 0 2072.75 2424.73 46.77 o 1 14 0 188.08 186.13 8.30 o 2 14 0 70.68 83.39 7.91 o 3 14 0 8.84 3.96 4.83 o 4 14 0 3036.60 2694.09 44.91 o 5 14 0 1923.84 1935.45 42.65 o 6 14 0 120.58 140.13 13.77 o 7 14 0 1050.56 1086.76 35.11 o 1 15 0 5164.59 5425.45 70.56 o 2 15 0 4.41 5.26 5.60 o 3 15 0 18197.11 17555.37 210.10 o 4 15 0 10.99 -0.91 6.91 o 5 15 0 263.20 296.73 16.66 o 6 15 0 73.23 51.00 11.86 o 7 15 0 0.78 5.73 30.29 o 0 16 0 5.78 -1.36 5.10 o 1 16 0 2186.45 2356.77 37.01 o 2 16 0 489.36 501.76 16.82 o 3 16 0 11791.47 12114.46 160.00 o 4 16 0 1159.14 1146.88 26.35 o 5 16 0 1288.58 1291.01 35.62 o 6 16 0 335.91 353.44 19.91 o 7 16 0 241.27 272.81 45.43 o 1 17 0 10588.93 10947.22 127.75 o 2 17 0 396.65 415.71 15.83 o 3 17 0 7.21 -2.62 6.88 o 4 17 0 5.18 0.08 9.70 o 5 17 0 6.22 5.21 9.28 o 6 17 0 1596.38 1686.20 42.66 o 0 18 0 14.01 7.71 5.99 o 1 18 0 12922.19 13233.47 150.66 o 2 18 0 23.16 16.97 6.80 o 3 18 0 89.15 125.43 10.79 o 4 18 0 203.58 217.07 14.31 o 5 18 0 60.32 62.55 11.89 o 6 18 0 1.16 -11.28 11.28 o 1 19 0 241.64 274.10 30.36 o 2 19 0 552.83 530.08 18.53 o 3 19 0 536.02 590.97 20.31 o 4 19 0 190.28 155.82 13.02 o 5 19 0 2.66 -8.59 8.66 o 6 19 0 380.28 393.70 21.92 o 0 20 0 2631.60 2614.30 65.58 o 1 20 0 8954.66 8652.21 120.03 o 2 20 0 558.80 549.18 18.99 o 3 20 0 313.06 306.52 17.93 o 4 20 0 12.87 20.92 9.27 o 5 20 0 373.82 404.86 20.10 o 6 20 0 1632.26 1566.76 41.71 o 1 21 0 13381.98 12944.83 168.02 o 2 21 0 122.81 183.79 12.17 o 3 21 0 37.74 59.35 10.14 o 4 21 0 1040.88 1091.07 30.90 o 5 21 0 3.51 -2.77 10.96 o 6 21 0 314.83 349.21 21.05 o 0 22 0 198.51 193.58 16.67 o 1 22 0 582.77 658.05 37.69 o 2 22 0 0.79 6.64 7.30 o 3 22 0 3505.62 3657.73 96.59 o 4 22 0 3.27 -0.06 9.42 o 5 22 0 47.35 35.52 11.39 o 6 22 0 228.03 175.18 35.20 o 1 23 0 4.00 14.98 11.05 o 2 23 0 53.14 43.69 10.93 o 3 23 0 1480.72 1524.36 49.57 o 4 23 0 234.16 266.02 20.22 o 5 23 0 42.37 45.79 13.04 o 6 23 0 605.02 650.60 56.89 o 0 24 0 7.42 14.94 15.76 o 1 24 0 456.11 418.61 21.20 o 2 24 0 2.27 -8.84 8.84 o 3 24 0 730.36 780.73 25.54 o 4 24 0 2545.20 2544.11 53.36 o 5 24 0 2204.79 2108.05 49.35 o 1 25 0 244.24 265.76 17.72 o 2 25 0 713.17 679.67 27.00 o 3 25 0 9.19 3.92 10.96 o 4 25 0 94.03 68.09 13.15 o 5 25 0 902.24 959.38 40.43 o 0 26 0 698.50 705.45 47.48 o 1 26 0 165.87 148.77 24.11 o 2 26 0 1804.48 1675.81 44.97 o 3 26 0 931.28 989.17 41.90 o 4 26 0 1.54 -5.98 12.20 o 5 26 0 695.02 690.52 28.79 o 1 27 0 369.45 421.15 58.74 o 2 27 0 712.64 717.91 28.32 o 3 27 0 871.76 832.63 32.29 o 4 27 0 55.91 26.77 19.29 o 0 28 0 1412.23 1386.33 71.42 o 1 28 0 1268.17 1287.47 48.11 o 2 28 0 354.52 357.79 21.99 o 3 28 0 672.66 705.93 29.73 o 4 28 0 717.79 759.04 39.89 o 1 29 0 214.50 258.05 24.06 o 2 29 0 120.45 155.53 27.40 o 3 29 0 133.91 107.71 15.23 o 4 29 0 1010.41 1034.79 57.80 o 0 30 0 6561.23 6357.20 202.61 o 1 30 0 461.86 471.97 48.50 o 2 30 0 0.43 5.45 12.86 o 3 30 0 4.41 -1.72 13.36 o 4 30 0 157.17 160.25 35.00 o 1 31 0 40.79 43.77 19.65 o 2 31 0 2859.81 2786.57 82.85 o 3 31 0 1081.00 1215.73 42.26 o 0 32 0 3009.75 3128.97 124.43 o 1 32 0 112.97 123.10 34.79 o 2 32 0 1595.91 1536.42 70.30 o 3 32 0 1864.46 2111.22 99.87 o 1 33 0 0.13 -18.11 18.11 o 2 33 0 446.39 483.88 36.82 o 3 33 0 376.75 380.45 44.41 o 0 34 0 1063.76 1059.50 69.38 o 1 34 0 21.63 -4.31 17.36 o -7 0 1 8240.20 8296.54 178.75 o -5 0 1 49.12 40.07 9.52 o -3 0 1 1583.41 1745.12 37.17 o -1 0 1 2.81 14.86 2.48 o 1 0 1 744.57 730.18 14.52 o 3 0 1 44.61 14.60 4.82 o 5 0 1 931.49 901.39 29.07 o 7 0 1 3855.01 4248.31 110.95 o -8 1 1 21.36 2.66 27.22 o -7 1 1 71.06 73.28 12.78 o -6 1 1 7.05 -6.87 6.87 o -5 1 1 2350.67 2277.08 35.99 o -4 1 1 222.94 242.46 9.22 o -3 1 1 161.53 150.62 8.76 o -2 1 1 13.15 9.65 4.70 o -1 1 1 41.29 48.92 2.62 o 0 1 1 36.21 34.23 2.49 o 1 1 1 0.21 -1.44 1.81 o 2 1 1 323.87 368.98 7.53 o 3 1 1 240.66 237.01 8.59 o 4 1 1 974.82 963.24 16.11 o 5 1 1 2537.95 2377.90 37.46 o 6 1 1 1706.90 1744.75 40.86 o 7 1 1 210.99 215.88 20.44 o -8 2 1 1.10 -24.76 24.76 o -7 2 1 2305.69 2310.63 50.95 o -6 2 1 12.87 12.99 7.99 o -5 2 1 151.70 151.30 9.44 o -4 2 1 32.32 39.66 6.87 o -3 2 1 142.59 137.53 7.05 o -2 2 1 1766.15 1798.63 31.20 o -1 2 1 317.43 389.49 7.88 o 0 2 1 818.77 918.71 11.52 o 1 2 1 119.29 109.62 3.80 o 2 2 1 834.75 878.33 12.95 o 3 2 1 515.34 541.24 10.47 o 4 2 1 293.67 296.60 8.79 o 5 2 1 4.63 17.17 7.35 o 6 2 1 2074.37 2125.46 46.56 o 7 2 1 1897.63 2029.11 48.10 o -8 3 1 251.90 274.85 43.80 o -7 3 1 768.50 808.20 31.19 o -6 3 1 999.39 963.81 24.96 o -5 3 1 8734.51 8528.97 98.29 o -4 3 1 105.94 119.98 7.02 o -3 3 1 4.01 1.56 3.83 o -2 3 1 1944.91 2013.56 33.37 o -1 3 1 546.98 548.95 10.15 o 0 3 1 476.98 502.79 7.41 o 1 3 1 43.47 58.23 3.43 o 2 3 1 1.74 -1.94 2.56 o 3 3 1 232.79 283.27 7.57 o 4 3 1 2464.97 2335.39 35.77 o 5 3 1 6445.47 6146.39 94.76 o 6 3 1 764.84 791.26 23.21 o 7 3 1 270.70 292.14 20.44 o -8 4 1 0.93 0.61 31.72 o -7 4 1 260.15 279.23 16.25 o -6 4 1 166.00 195.33 12.59 o -5 4 1 12776.23 12716.91 152.53 o -4 4 1 320.45 333.80 10.94 o -3 4 1 2038.85 2179.40 33.85 o -2 4 1 4881.68 4915.80 62.56 o -1 4 1 100.27 105.17 4.87 o 0 4 1 4151.41 4448.67 55.22 o 1 4 1 458.24 421.49 7.21 o 2 4 1 2786.87 2769.70 30.88 o 3 4 1 1024.89 1113.11 16.43 o 4 4 1 5010.35 4987.38 53.16 o 5 4 1 3644.22 3555.59 62.76 o 6 4 1 4.52 -3.38 8.18 o 7 4 1 169.01 220.51 22.98 o -8 5 1 296.02 421.79 53.62 o -7 5 1 13.66 6.61 9.84 o -6 5 1 318.08 278.56 14.22 o -5 5 1 631.56 639.80 16.41 o -4 5 1 5495.15 5452.80 66.62 o -3 5 1 9389.15 9305.31 109.88 o -2 5 1 963.37 1000.76 18.06 o -1 5 1 1298.80 1270.29 19.77 o 0 5 1 224.67 254.49 6.22 o 1 5 1 585.68 602.51 10.05 o 2 5 1 1408.23 1461.70 19.27 o 3 5 1 5868.95 5853.87 58.81 o 4 5 1 11160.91 10943.85 101.38 o 5 5 1 2.46 11.40 6.84 o 6 5 1 52.57 47.13 9.72 o 7 5 1 2.88 -10.04 12.97 o -7 6 1 6.53 1.30 9.24 o -6 6 1 0.64 3.90 7.65 o -5 6 1 9.87 2.51 6.63 o -4 6 1 271.56 283.93 13.42 o -3 6 1 14791.54 14635.42 162.10 o -2 6 1 11598.50 12383.13 138.39 o -1 6 1 659.78 670.58 10.77 o 0 6 1 2358.08 2415.09 30.71 o 1 6 1 4808.90 4753.91 47.45 o 2 6 1 22249.68 23433.19 191.46 o 3 6 1 3548.90 3487.31 38.65 o 4 6 1 733.01 728.77 22.53 o 5 6 1 41.39 31.68 8.45 o 6 6 1 169.52 181.28 13.12 o 7 6 1 149.27 187.54 19.50 o -7 7 1 361.92 352.16 18.19 o -6 7 1 534.02 548.22 19.64 o -5 7 1 55.95 67.00 9.26 o -4 7 1 249.12 257.37 9.81 o -3 7 1 10596.01 11198.37 116.79 o -2 7 1 5692.28 6198.36 86.41 o -1 7 1 6175.37 6359.49 65.03 o 0 7 1 79.62 90.59 5.76 o 1 7 1 1434.03 1421.93 17.75 o 2 7 1 17034.41 17346.49 228.98 o 3 7 1 1573.74 1653.30 24.18 o 4 7 1 793.91 738.20 16.78 o 5 7 1 13.70 -0.41 8.08 o 6 7 1 434.55 426.75 20.10 o 7 7 1 317.46 345.12 25.40 o -7 8 1 252.59 269.92 18.15 o -6 8 1 18.59 -4.55 7.73 o -5 8 1 1092.35 1067.31 24.73 o -4 8 1 666.40 662.11 16.76 o -3 8 1 916.17 831.20 15.21 o -2 8 1 1768.48 2129.07 32.31 o -1 8 1 5302.49 5484.41 57.59 o 0 8 1 11983.17 12055.07 113.66 o 1 8 1 0.98 5.91 2.82 o 2 8 1 8587.40 9101.31 90.61 o 3 8 1 259.39 237.11 6.88 o 4 8 1 1249.89 1237.86 23.23 o 5 8 1 1851.35 1806.02 35.19 o 6 8 1 0.73 14.26 9.62 o 7 8 1 376.22 403.62 23.37 o -8 9 1 43.37 27.83 34.38 o -7 9 1 146.47 142.84 15.23 o -6 9 1 328.13 349.83 16.39 o -5 9 1 376.18 410.03 26.35 o -4 9 1 151.08 165.63 8.48 o -3 9 1 128.17 153.62 7.59 o -2 9 1 290.06 284.21 8.96 o -1 9 1 6168.61 6315.73 70.63 o 0 9 1 4972.64 5181.59 55.03 o 1 9 1 1982.63 1952.47 27.13 o 2 9 1 71.73 108.50 8.19 o 3 9 1 34.18 44.51 7.08 o 4 9 1 419.76 384.94 12.29 o 5 9 1 148.51 176.42 14.09 o 6 9 1 100.85 139.20 25.15 o 7 9 1 513.08 513.51 24.12 o -7 10 1 23.38 34.76 13.11 o -6 10 1 48.07 45.33 10.77 o -5 10 1 2429.31 2245.29 40.28 o -4 10 1 0.20 6.32 6.51 o -3 10 1 4382.48 4416.18 60.10 o -2 10 1 549.85 557.18 13.09 o -1 10 1 30621.09 32100.74 275.43 o 0 10 1 9806.86 9601.89 93.84 o 1 10 1 22216.39 23482.77 242.97 o 2 10 1 556.55 567.27 11.46 o 3 10 1 2868.03 2863.51 36.52 o 4 10 1 19.11 3.01 6.81 o 5 10 1 1748.78 1689.97 38.09 o 6 10 1 175.93 199.81 15.61 o 7 10 1 1.73 3.46 12.80 o -7 11 1 11.95 10.51 12.93 o -6 11 1 1241.41 1210.08 35.36 o -5 11 1 277.86 256.85 13.22 o -4 11 1 737.67 724.59 21.30 o -3 11 1 5.95 5.42 4.22 o -2 11 1 12804.28 13225.33 225.05 o -1 11 1 8629.99 9234.50 98.75 o 0 11 1 949.15 996.51 19.09 o 1 11 1 26100.91 26528.93 329.15 o 2 11 1 3494.57 3720.44 43.75 o 3 11 1 45.55 56.38 6.63 o 4 11 1 426.06 421.70 14.40 o 5 11 1 219.37 235.54 14.65 o 6 11 1 150.05 186.19 15.37 o 7 11 1 133.88 137.10 16.14 o -7 12 1 958.25 988.20 39.52 o -6 12 1 4.73 -8.57 8.57 o -5 12 1 125.48 149.11 16.60 o -4 12 1 2.32 -2.17 6.36 o -3 12 1 1876.75 1794.22 30.61 o -2 12 1 11981.25 12072.92 177.34 o -1 12 1 125.89 162.93 6.54 o 0 12 1 766.83 843.12 13.86 o 1 12 1 7116.66 7651.65 111.98 o 2 12 1 3024.36 3032.13 37.47 o 3 12 1 1853.65 1793.50 28.72 o 4 12 1 3.53 6.15 7.06 o 5 12 1 187.75 215.48 14.44 o 6 12 1 27.19 18.99 11.00 o 7 12 1 264.08 304.87 20.04 o -7 13 1 42.98 23.40 12.74 o -6 13 1 2.05 -1.16 9.45 o -5 13 1 521.96 517.36 19.97 o -4 13 1 6930.41 6753.24 99.74 o -3 13 1 3041.26 2957.77 44.55 o -2 13 1 4998.61 5183.51 67.83 o -1 13 1 142.45 127.31 7.28 o 0 13 1 809.25 786.55 13.48 o 1 13 1 853.36 846.09 16.03 o 2 13 1 975.93 979.63 18.78 o 3 13 1 5895.92 5870.88 70.77 o 4 13 1 2951.32 2823.31 46.32 o 5 13 1 592.42 610.07 19.38 o 6 13 1 254.90 276.45 17.99 o 7 13 1 61.98 77.27 19.90 o -7 14 1 236.81 246.30 28.54 o -6 14 1 637.42 636.52 28.09 o -5 14 1 570.17 615.63 21.73 o -4 14 1 2513.94 2470.17 47.43 o -3 14 1 3242.55 3136.75 53.91 o -2 14 1 41.62 25.04 6.62 o -1 14 1 377.49 414.88 10.46 o 0 14 1 442.44 424.61 9.58 o 1 14 1 118.22 136.75 6.67 o 2 14 1 75.62 84.10 7.34 o 3 14 1 13399.88 12872.35 135.32 o 4 14 1 803.24 839.78 22.31 o 5 14 1 565.06 589.89 19.64 o 6 14 1 856.23 876.95 38.52 o 7 14 1 57.85 76.75 27.01 o -7 15 1 1.87 -2.63 12.82 o -6 15 1 345.64 325.28 19.08 o -5 15 1 12.53 3.51 8.68 o -4 15 1 6071.76 5790.83 89.35 o -3 15 1 333.53 343.67 14.57 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