#------------------------------------------------------------------------------ #$Date: 2011-05-17 10:53:27 +0300 (Tue, 17 May 2011) $ #$Revision: 19531 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/2018034.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2018034_Fobs loop_ _publ_author_name 'Thomas, Tegan' 'Pugh, David' 'Parkin, Ivan P.' 'Carmalt, Claire J.' _publ_section_title ; Novel ion pairs obtained from the reaction of titanium(IV) halides with simple arsane ligands ; _journal_coeditor_code GG3254 _journal_issue 4 _journal_name_full 'Acta Crystallographica Section C' _journal_page_first m96 _journal_page_last m99 _journal_volume 67 _journal_year 2011 _space_group_IT_number 57 _symmetry_space_group_name_Hall '-P 2c 2b' _symmetry_space_group_name_H-M 'P b c m' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 9.7061 _cell_length_b 17.8553 _cell_length_c 10.4555 _exptl_crystal_F_000 1064.00 _reflns_d_resolution_high 0.7500 _[local]_cod_data_source_file gg3254IIsup2.hkl _[local]_cod_data_source_block II #BEGIN Tags that were not found in dictionaries: _shelx_title ' str0746a in Pbcm' _shelx_refln_list_code 4 _shelx_f_calc_maximum 441.21 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, z+1/2' '-x, y+1/2, -z+1/2' 'x, -y+1/2, -z' '-x, -y, -z' 'x, y, -z-1/2' 'x, -y-1/2, z-1/2' '-x, y-1/2, z' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 37508.41 39102.63 812.34 o 3 0 0 44545.69 46483.86 970.56 o 4 0 0 7165.71 7223.83 183.67 o 5 0 0 1787.29 1738.15 85.72 o 6 0 0 116.53 128.98 53.13 o 7 0 0 1676.98 1761.85 105.06 o 8 0 0 5063.96 4587.54 171.28 o 9 0 0 2283.69 1739.58 179.44 o 10 0 0 52.35 86.49 108.80 o 11 0 0 48.89 190.88 162.37 o 12 0 0 2207.57 2419.79 333.66 o 2 1 0 251.97 292.00 22.16 o 3 1 0 6811.31 7441.28 137.23 o 4 1 0 4902.60 4701.79 93.08 o 5 1 0 5120.21 5152.50 129.36 o 6 1 0 45876.03 44627.54 678.80 o 7 1 0 5514.31 5085.50 118.05 o 8 1 0 7409.62 6950.18 151.58 o 9 1 0 2467.83 2438.57 126.51 o 10 1 0 923.41 886.01 116.59 o 11 1 0 221.26 464.45 139.54 o 12 1 0 13.15 497.03 196.22 o 1 2 0 415.95 469.75 19.35 o 2 2 0 2660.34 2725.42 52.99 o 3 2 0 6163.22 6519.37 122.96 o 4 2 0 455.88 480.58 35.93 o 5 2 0 12130.35 12347.18 227.50 o 6 2 0 99.58 114.06 34.48 o 7 2 0 3673.27 3581.55 96.62 o 8 2 0 1640.56 1597.32 77.80 o 9 2 0 432.32 461.43 79.32 o 10 2 0 1608.17 1624.71 139.45 o 11 2 0 701.49 670.22 155.87 o 12 2 0 1199.97 1714.46 313.10 o 1 3 0 32316.66 33719.21 609.92 o 2 3 0 2487.84 2282.81 47.80 o 3 3 0 409.74 456.43 27.37 o 4 3 0 22622.41 22622.61 351.31 o 5 3 0 9786.97 9585.88 184.72 o 6 3 0 324.92 197.76 57.75 o 7 3 0 1342.22 1319.88 71.22 o 8 3 0 896.74 1036.33 71.80 o 9 3 0 652.57 673.18 102.10 o 10 3 0 135.10 179.21 93.08 o 11 3 0 59.42 319.15 237.83 o 12 3 0 10.31 91.17 236.47 o 0 4 0 38373.77 37581.59 781.39 o 1 4 0 2078.13 2094.38 60.50 o 2 4 0 1404.54 1404.69 45.97 o 3 4 0 988.73 1297.25 40.87 o 4 4 0 19.88 29.23 23.33 o 5 4 0 180.24 162.75 29.97 o 6 4 0 652.55 736.20 48.90 o 7 4 0 125.67 83.70 37.93 o 8 4 0 146.00 225.56 57.35 o 9 4 0 785.85 785.74 103.70 o 10 4 0 54.11 149.68 123.87 o 11 4 0 200.70 263.08 154.75 o 12 4 0 852.10 986.23 284.97 o 1 5 0 764.02 845.14 31.14 o 2 5 0 2003.68 2259.75 63.70 o 3 5 0 13536.21 13986.65 223.85 o 4 5 0 66.23 117.14 26.40 o 5 5 0 5130.93 5012.71 106.00 o 6 5 0 30744.15 29893.08 470.38 o 7 5 0 577.35 654.98 52.45 o 8 5 0 16598.19 16290.17 319.74 o 9 5 0 2226.90 2378.28 410.28 o 10 5 0 358.04 61.52 110.38 o 11 5 0 49.84 29.81 135.02 o 12 5 0 63.79 182.27 173.34 o 0 6 0 161398.34 163526.77 4327.84 o 1 6 0 5129.86 5684.97 191.02 o 2 6 0 9127.68 9663.29 173.05 o 3 6 0 55.01 80.10 23.03 o 4 6 0 2234.58 2422.17 82.20 o 5 6 0 175.92 233.88 34.65 o 6 6 0 1759.73 1823.37 68.75 o 7 6 0 1883.24 2207.03 91.44 o 8 6 0 1301.12 1265.38 97.97 o 9 6 0 71.03 141.51 106.23 o 10 6 0 142.27 176.44 129.82 o 11 6 0 78.29 69.62 132.14 o 12 6 0 4003.31 3544.53 457.03 o 1 7 0 27183.90 26526.86 470.50 o 2 7 0 4871.93 4609.69 130.06 o 3 7 0 1825.09 1961.81 58.57 o 4 7 0 1724.82 1706.54 56.64 o 5 7 0 11572.60 11223.58 197.22 o 6 7 0 11863.42 11932.70 214.52 o 7 7 0 781.25 753.88 76.74 o 8 7 0 2215.83 2159.03 118.93 o 9 7 0 405.53 395.20 124.45 o 10 7 0 0.31 -28.97 118.35 o 11 7 0 697.26 727.77 183.21 o 12 7 0 73.31 292.53 287.88 o 0 8 0 2760.71 2610.25 133.09 o 1 8 0 21153.30 20897.04 358.33 o 2 8 0 11915.89 11908.61 196.76 o 3 8 0 320.69 328.77 30.57 o 4 8 0 10166.98 9826.44 203.72 o 5 8 0 35577.45 34867.00 590.92 o 6 8 0 936.84 1004.48 77.88 o 7 8 0 13594.95 13692.77 308.33 o 8 8 0 1177.22 1363.48 119.04 o 9 8 0 3592.74 3578.33 244.95 o 10 8 0 5043.83 4933.83 497.38 o 11 8 0 791.29 990.40 195.94 o 12 8 0 589.72 754.61 302.81 o 1 9 0 13272.28 13015.97 214.75 o 2 9 0 70.15 81.78 25.08 o 3 9 0 1281.15 1427.15 62.74 o 4 9 0 9695.20 9630.50 173.28 o 5 9 0 1846.70 2007.41 114.79 o 6 9 0 1044.26 1165.52 83.49 o 7 9 0 226.31 310.89 66.95 o 8 9 0 1931.29 2169.96 153.44 o 9 9 0 708.12 675.11 148.55 o 10 9 0 2879.12 2696.39 239.50 o 11 9 0 2723.88 2890.74 365.57 o 0 10 0 1280.99 1369.22 74.40 o 1 10 0 2242.06 2192.17 62.46 o 2 10 0 153.18 118.57 27.59 o 3 10 0 8159.24 7941.24 158.33 o 4 10 0 2137.69 2280.58 99.93 o 5 10 0 664.31 670.26 65.18 o 6 10 0 1889.18 1854.64 102.51 o 7 10 0 2818.75 2860.47 131.91 o 8 10 0 719.18 840.39 95.43 o 9 10 0 3.29 71.20 173.04 o 10 10 0 305.83 484.86 159.69 o 11 10 0 1333.21 1675.98 242.65 o 1 11 0 6.12 -5.18 28.09 o 2 11 0 8187.18 7917.92 201.00 o 3 11 0 6076.85 6026.99 137.58 o 4 11 0 478.58 470.54 49.02 o 5 11 0 1333.12 1384.79 86.78 o 6 11 0 701.00 815.94 92.82 o 7 11 0 892.28 870.58 89.85 o 8 11 0 110.06 257.86 93.43 o 9 11 0 939.40 1103.23 171.43 o 10 11 0 2.10 94.40 140.47 o 11 11 0 731.07 694.47 309.60 o 0 12 0 12081.43 11597.72 288.23 o 1 12 0 2260.24 2323.82 74.08 o 2 12 0 2781.82 2713.65 97.37 o 3 12 0 114.33 108.54 37.42 o 4 12 0 1164.16 1188.75 91.63 o 5 12 0 254.54 282.51 57.93 o 6 12 0 450.44 632.82 78.30 o 7 12 0 1639.85 1751.01 116.30 o 8 12 0 966.13 914.12 107.17 o 9 12 0 3636.06 3412.45 484.39 o 10 12 0 770.96 562.37 177.23 o 1 13 0 7329.43 7144.09 158.52 o 2 13 0 1117.71 967.27 70.44 o 3 13 0 9085.22 8441.28 183.22 o 4 13 0 5015.70 4868.46 168.42 o 5 13 0 3332.27 3400.00 134.57 o 6 13 0 240.42 157.87 67.15 o 7 13 0 52.12 143.96 94.69 o 8 13 0 14.85 77.87 88.36 o 9 13 0 162.95 239.22 156.16 o 10 13 0 63.16 29.20 154.98 o 0 14 0 690.09 752.96 101.84 o 1 14 0 2441.31 2685.56 102.02 o 2 14 0 11657.10 11352.62 230.62 o 3 14 0 5156.77 4771.15 145.88 o 4 14 0 1247.26 1501.38 113.15 o 5 14 0 16193.37 15195.75 342.40 o 6 14 0 5242.39 4770.20 169.10 o 7 14 0 2968.59 2879.58 146.06 o 8 14 0 222.96 295.57 103.48 o 9 14 0 1300.63 1093.78 193.41 o 1 15 0 9372.61 9315.45 278.48 o 2 15 0 4962.41 4692.54 130.08 o 3 15 0 31.20 72.78 70.03 o 4 15 0 4104.03 3821.12 145.13 o 5 15 0 3729.34 3715.38 169.27 o 6 15 0 211.67 174.88 78.33 o 7 15 0 4.18 62.87 83.89 o 8 15 0 42.03 -31.80 92.31 o 9 15 0 664.88 595.16 240.45 o 0 16 0 4437.21 4352.78 208.12 o 1 16 0 3034.06 3193.84 131.42 o 2 16 0 701.62 747.06 92.34 o 3 16 0 5501.44 5094.41 188.88 o 4 16 0 1242.80 1310.40 101.99 o 5 16 0 897.62 905.65 96.43 o 6 16 0 433.71 458.68 94.09 o 7 16 0 279.28 329.87 99.19 o 8 16 0 18.61 56.47 105.78 o 9 16 0 260.57 262.85 218.62 o 1 17 0 6582.80 6253.53 211.23 o 2 17 0 20.02 121.09 111.80 o 3 17 0 2696.35 2943.43 197.42 o 4 17 0 183.58 415.20 84.09 o 5 17 0 254.26 289.14 87.53 o 6 17 0 1223.37 1122.38 118.64 o 7 17 0 159.53 236.74 105.13 o 8 17 0 619.27 805.69 139.37 o 0 18 0 335.36 337.27 120.11 o 1 18 0 16.27 69.82 79.56 o 2 18 0 568.35 609.71 107.26 o 3 18 0 3800.86 3509.18 281.18 o 4 18 0 2185.57 2042.88 151.42 o 5 18 0 1857.29 1817.05 135.46 o 6 18 0 2389.43 2125.78 166.47 o 7 18 0 12.44 127.24 105.19 o 8 18 0 574.03 638.71 151.13 o 1 19 0 482.45 606.76 114.85 o 2 19 0 2191.72 2322.25 222.27 o 3 19 0 4034.41 3986.39 249.54 o 4 19 0 1720.02 2013.23 159.18 o 5 19 0 649.31 578.70 130.69 o 6 19 0 15.54 58.37 120.42 o 7 19 0 110.14 211.72 120.63 o 0 20 0 182.58 196.12 173.42 o 1 20 0 387.38 558.52 118.83 o 2 20 0 238.55 228.19 103.91 o 3 20 0 82.81 166.38 108.81 o 4 20 0 24.61 37.01 108.62 o 5 20 0 189.57 219.17 123.07 o 6 20 0 15.73 128.29 209.57 o 7 20 0 545.66 381.46 208.25 o 1 21 0 934.50 968.50 157.66 o 2 21 0 595.15 696.84 174.95 o 3 21 0 33.02 174.87 119.09 o 4 21 0 15.13 -30.27 119.72 o 5 21 0 0.21 49.80 131.93 o 0 22 0 7071.79 6989.93 471.19 o 1 22 0 2261.38 1976.32 209.37 o 2 22 0 430.66 381.15 155.42 o 3 22 0 2142.22 2093.11 191.05 o 4 22 0 332.12 368.87 152.90 o 1 1 1 265.79 246.86 14.67 o 2 1 1 902.60 1013.78 27.33 o 3 1 1 88.99 125.51 14.32 o 4 1 1 142.72 139.73 18.41 o 5 1 1 5182.77 4888.27 75.71 o 6 1 1 581.49 642.05 32.80 o 7 1 1 1022.08 1163.79 44.86 o 8 1 1 612.28 615.41 45.53 o 9 1 1 2454.52 2456.09 120.82 o 10 1 1 164.61 169.34 64.54 o 11 1 1 957.83 1021.55 106.65 o 12 1 1 4.66 159.85 159.48 o 0 2 1 12021.78 12690.02 191.27 o 1 2 1 10341.95 10399.06 123.52 o 2 2 1 339.31 316.68 13.73 o 3 2 1 11380.44 12115.84 142.64 o 4 2 1 9832.17 9438.19 113.90 o 5 2 1 14480.39 14289.39 174.69 o 6 2 1 320.28 402.58 31.04 o 7 2 1 2113.63 2128.66 55.33 o 8 2 1 580.24 656.56 46.35 o 9 2 1 5956.79 5581.04 125.45 o 10 2 1 5172.45 5106.04 149.10 o 11 2 1 335.62 503.26 102.64 o 12 2 1 837.51 1084.74 157.99 o 1 3 1 25694.70 26342.96 287.88 o 2 3 1 2645.66 2625.50 39.95 o 3 3 1 46461.25 49619.05 518.12 o 4 3 1 34110.31 35178.13 391.89 o 5 3 1 71.00 71.52 19.38 o 6 3 1 68.48 108.35 24.35 o 7 3 1 2560.24 2865.44 66.50 o 8 3 1 204.12 223.16 42.04 o 9 3 1 1039.44 1021.31 65.79 o 10 3 1 498.41 498.25 83.68 o 11 3 1 3015.18 2938.48 166.04 o 12 3 1 3.86 25.75 133.56 o 0 4 1 31.07 37.54 12.79 o 1 4 1 1964.95 2084.47 33.40 o 2 4 1 244.71 289.77 23.97 o 3 4 1 16242.74 16678.87 184.30 o 4 4 1 310.46 385.77 22.51 o 5 4 1 1456.66 1662.90 46.61 o 6 4 1 506.70 652.67 34.97 o 7 4 1 437.99 533.64 37.03 o 8 4 1 80.22 109.83 41.64 o 9 4 1 1089.43 1092.06 82.52 o 10 4 1 511.08 404.83 123.13 o 11 4 1 209.82 232.80 103.28 o 12 4 1 242.48 116.61 138.26 o 1 5 1 221.74 278.39 16.67 o 2 5 1 1975.68 2191.69 39.44 o 3 5 1 149.11 126.34 15.76 o 4 5 1 113.56 118.76 18.41 o 5 5 1 4431.63 4383.40 67.85 o 6 5 1 6151.85 5720.28 86.52 o 7 5 1 4.83 25.26 29.12 o 8 5 1 3439.85 3493.47 95.71 o 9 5 1 1781.58 1722.12 131.26 o 10 5 1 288.52 354.46 92.34 o 11 5 1 1125.66 848.08 395.33 o 12 5 1 10.76 -3.58 127.12 o 0 6 1 17020.71 16283.19 278.84 o 1 6 1 9475.26 9474.57 120.21 o 2 6 1 1325.75 1435.17 33.98 o 3 6 1 9689.37 9163.33 114.56 o 4 6 1 1441.85 1490.75 36.42 o 5 6 1 1416.31 1496.18 40.26 o 6 6 1 591.22 692.94 37.30 o 7 6 1 3064.71 3049.21 78.99 o 8 6 1 3711.32 4040.26 151.16 o 9 6 1 13.11 -12.66 57.34 o 10 6 1 1655.00 1624.30 140.95 o 11 6 1 5.44 77.31 100.35 o 12 6 1 5.77 50.83 171.30 o 1 7 1 9182.77 8656.85 103.39 o 2 7 1 7677.82 7057.52 97.60 o 3 7 1 3563.53 3555.01 56.36 o 4 7 1 10308.34 9698.61 120.08 o 5 7 1 158.07 187.51 24.32 o 6 7 1 556.55 603.73 39.10 o 7 7 1 1428.16 1625.09 59.83 o 8 7 1 830.32 1052.64 79.93 o 9 7 1 583.90 626.57 82.32 o 10 7 1 118.05 142.53 93.06 o 11 7 1 443.51 447.80 112.78 o 12 7 1 82.47 225.57 206.32 o 0 8 1 2096.35 2048.26 100.81 o 1 8 1 936.86 1159.52 30.32 o 2 8 1 1394.49 1448.53 38.68 o 3 8 1 12033.47 11612.89 151.87 o 4 8 1 1419.70 1602.23 41.35 o 5 8 1 9629.16 9234.77 133.79 o 6 8 1 2320.04 2314.83 64.03 o 7 8 1 8.50 136.32 41.02 o 8 8 1 800.98 831.90 75.12 o 9 8 1 425.96 536.84 79.54 o 10 8 1 243.98 290.98 97.52 o 11 8 1 16.47 -27.53 107.07 o 12 8 1 46.03 1.73 190.19 o 1 9 1 5700.00 5330.13 74.02 o 2 9 1 1109.86 1132.23 36.88 o 3 9 1 1553.98 1807.58 47.06 o 4 9 1 179.53 263.62 29.18 o 5 9 1 93.57 82.56 28.89 o 6 9 1 2649.53 2628.13 74.55 o 7 9 1 115.38 118.05 44.04 o 8 9 1 18.32 41.38 59.49 o 9 9 1 31.45 43.32 67.79 o 10 9 1 16.51 140.95 129.90 o 11 9 1 206.29 298.69 120.38 o 0 10 1 36650.19 35977.25 547.13 o 1 10 1 6300.68 6026.45 86.70 o 2 10 1 3679.13 3525.00 61.72 o 3 10 1 8812.36 8427.55 121.37 o 4 10 1 115.22 111.87 26.16 o 5 10 1 932.51 988.86 50.11 o 6 10 1 740.22 821.12 53.82 o 7 10 1 704.48 787.22 59.70 o 8 10 1 1884.39 2137.63 108.81 o 9 10 1 1861.70 1934.68 114.09 o 10 10 1 2.74 42.54 103.71 o 11 10 1 233.61 289.00 197.90 o 1 11 1 11214.23 10714.14 139.09 o 2 11 1 18957.31 18121.94 219.17 o 3 11 1 76.51 58.38 22.63 o 4 11 1 3877.74 3836.66 85.11 o 5 11 1 3346.02 3414.44 81.96 o 6 11 1 6012.19 6001.84 123.29 o 7 11 1 1580.00 1641.25 77.60 o 8 11 1 2392.77 2385.38 115.43 o 9 11 1 6672.00 6531.44 183.87 o 10 11 1 147.28 245.30 112.25 o 11 11 1 168.41 587.46 206.57 o 0 12 1 1619.80 1756.11 82.62 o 1 12 1 1929.94 2101.87 87.96 o 2 12 1 1292.80 1412.81 45.36 o 3 12 1 4015.23 3806.49 90.12 o 4 12 1 2904.95 2868.38 80.60 o 5 12 1 1164.43 1291.91 63.00 o 6 12 1 3.63 8.95 41.50 o 7 12 1 781.48 861.64 65.92 o 8 12 1 1364.95 1376.44 97.76 o 9 12 1 132.47 181.38 82.58 o 10 12 1 159.91 223.51 112.53 o 1 13 1 2331.81 2404.95 61.32 o 2 13 1 1722.88 1792.49 56.77 o 3 13 1 1297.30 1390.54 59.96 o 4 13 1 981.01 970.52 52.61 o 5 13 1 1374.05 1384.53 72.62 o 6 13 1 697.24 827.12 62.99 o 7 13 1 209.56 179.99 56.53 o 8 13 1 173.74 172.92 73.12 o 9 13 1 9.89 70.41 81.21 o 10 13 1 502.98 907.07 285.17 o 0 14 1 5909.57 5655.33 164.93 o 1 14 1 637.78 650.91 44.18 o 2 14 1 3121.04 3220.40 79.57 o 3 14 1 1397.49 1442.18 64.19 o 4 14 1 57.85 59.02 36.65 o 5 14 1 448.94 488.95 52.89 o 6 14 1 697.24 775.69 75.02 o 7 14 1 382.88 361.44 62.94 o 8 14 1 79.34 177.27 76.61 o 9 14 1 250.02 317.71 94.61 o 1 15 1 977.46 1061.81 55.24 o 2 15 1 159.88 94.10 42.51 o 3 15 1 624.09 633.89 52.66 o 4 15 1 344.75 286.94 67.40 o 5 15 1 1774.86 1752.43 79.59 o 6 15 1 3336.14 3060.18 153.78 o 7 15 1 603.80 711.21 71.68 o 8 15 1 723.90 711.38 92.02 o 9 15 1 829.96 962.05 114.39 o 0 16 1 7836.17 7972.44 207.94 o 1 16 1 4656.84 4265.75 109.20 o 2 16 1 87.85 97.82 41.19 o 3 16 1 991.70 1060.93 68.71 o 4 16 1 379.80 350.97 51.45 o 5 16 1 589.59 516.45 63.39 o 6 16 1 1513.40 1395.08 87.64 o 7 16 1 593.97 600.90 83.54 o 8 16 1 814.00 765.54 100.88 o 9 16 1 130.46 55.10 110.04 o 1 17 1 52.24 128.92 50.50 o 2 17 1 22.40 43.37 47.06 o 3 17 1 604.41 776.80 90.23 o 4 17 1 13.41 7.69 53.14 o 5 17 1 4628.19 4498.12 132.88 o 6 17 1 2831.11 2827.92 109.58 o 7 17 1 279.71 174.35 71.54 o 8 17 1 1430.26 1408.64 124.61 o 9 17 1 1894.65 1645.01 439.19 o 0 18 1 642.71 692.05 106.03 o 1 18 1 323.77 396.53 65.55 o 2 18 1 10.58 -1.06 55.35 o 3 18 1 765.69 731.46 79.57 o 4 18 1 129.50 253.63 70.49 o 5 18 1 0.41 63.59 65.58 o 6 18 1 237.56 219.58 70.48 o 7 18 1 615.08 523.96 82.46 o 8 18 1 97.83 145.45 108.69 o 1 19 1 126.26 139.71 71.66 o 2 19 1 130.38 377.33 131.03 o 3 19 1 1231.89 1348.34 97.19 o 4 19 1 2324.59 2320.49 132.07 o 5 19 1 0.43 -15.49 76.36 o 6 19 1 628.82 875.75 120.16 o 7 19 1 92.25 50.17 92.65 o 0 20 1 140.22 150.26 115.51 o 1 20 1 0.70 22.22 75.04 o 2 20 1 1155.01 1167.23 131.04 o 3 20 1 148.83 163.01 86.69 o 4 20 1 2200.33 2118.99 122.64 o 5 20 1 386.28 272.30 90.14 o 6 20 1 100.26 137.48 101.85 o 1 21 1 76.72 37.90 79.22 o 2 21 1 1947.82 1943.77 181.86 o 3 21 1 54.40 106.95 85.15 o 4 21 1 54.20 109.15 89.85 o 5 21 1 297.10 462.05 111.60 o 6 21 1 297.11 343.53 189.94 o 0 22 1 2397.32 2260.79 281.18 o 1 22 1 1250.63 1275.90 134.41 o 2 22 1 51.07 229.06 195.36 o 3 22 1 693.57 793.01 118.25 o 4 22 1 115.73 330.03 132.43 o 3 23 1 33.11 300.10 364.31 o 0 0 2 133200.31 139460.78 3447.53 o 1 0 2 9684.70 9576.20 453.61 o 2 0 2 2951.68 2925.82 66.10 o 3 0 2 37932.99 37135.44 601.46 o 4 0 2 38524.11 37551.70 614.80 o 5 0 2 3999.07 3784.41 85.09 o 6 0 2 5468.57 5257.10 114.29 o 7 0 2 29.87 101.74 41.54 o 8 0 2 720.47 861.73 78.07 o 9 0 2 428.74 369.07 82.77 o 10 0 2 52.80 59.21 75.22 o 11 0 2 137.46 321.55 158.00 o 12 0 2 88.47 643.45 242.48 o 1 1 2 7463.69 7154.78 137.95 o 2 1 2 17804.80 17929.29 212.17 o 3 1 2 18595.31 18593.28 291.51 o 4 1 2 4496.06 4366.82 62.61 o 5 1 2 572.88 674.20 30.08 o 6 1 2 10254.69 9835.36 132.29 o 7 1 2 1219.97 1357.75 53.17 o 8 1 2 956.91 988.51 56.61 o 9 1 2 2223.22 2124.61 84.20 o 10 1 2 1245.13 1297.52 76.44 o 11 1 2 687.03 844.08 104.20 o 12 1 2 1469.31 1731.41 175.41 o 0 2 2 339.58 452.06 22.57 o 1 2 2 285.44 314.22 14.16 o 2 2 2 5385.64 5335.03 69.87 o 3 2 2 6596.10 6682.62 89.49 o 4 2 2 576.80 647.20 25.36 o 5 2 2 1522.04 1610.29 41.57 o 6 2 2 2583.62 2769.17 65.94 o 7 2 2 113.47 88.57 28.88 o 8 2 2 1525.75 1533.99 67.20 o 9 2 2 1366.56 1451.86 70.49 o 10 2 2 17.31 37.06 61.53 o 11 2 2 804.03 708.38 143.49 o 12 2 2 1348.39 1348.93 146.77 o 1 3 2 24459.50 25568.81 283.63 o 2 3 2 3647.66 3529.09 56.39 o 3 3 2 53.06 54.67 12.86 o 4 3 2 13438.50 13120.74 158.46 o 5 3 2 8027.36 7900.92 103.30 o 6 3 2 373.96 413.41 31.23 o 7 3 2 1338.12 1278.83 55.67 o 8 3 2 1105.24 1182.31 59.96 o 9 3 2 368.52 444.04 51.29 o 10 3 2 22.11 47.98 54.35 o 11 3 2 5.31 -46.07 86.93 o 12 3 2 29.22 18.10 135.83 o 0 4 2 27518.91 28545.75 427.17 o 1 4 2 30.48 16.32 10.28 o 2 4 2 18076.76 18476.35 210.57 o 3 4 2 9946.84 9880.26 127.74 o 4 4 2 125.61 167.90 18.59 o 5 4 2 19352.00 19046.31 225.75 o 6 4 2 4577.58 4513.02 76.47 o 7 4 2 5281.48 4863.80 97.65 o 8 4 2 413.25 508.38 49.92 o 9 4 2 374.70 495.65 58.84 o 10 4 2 553.20 498.26 73.11 o 11 4 2 84.60 63.12 96.71 o 12 4 2 714.31 397.89 151.23 o 1 5 2 11626.58 11838.67 147.77 o 2 5 2 2147.02 2011.05 41.15 o 3 5 2 4468.74 4614.80 73.33 o 4 5 2 96.21 137.85 18.35 o 5 5 2 2116.30 2262.39 48.79 o 6 5 2 7591.64 7197.23 105.97 o 7 5 2 147.48 92.82 33.06 o 8 5 2 7032.58 6703.03 145.87 o 9 5 2 2650.77 2590.80 95.71 o 10 5 2 533.21 464.85 73.78 o 11 5 2 1817.14 1756.24 243.95 o 12 5 2 1221.46 853.95 165.41 o 0 6 2 397.63 485.13 43.49 o 1 6 2 701.07 810.15 27.44 o 2 6 2 297.34 297.82 21.17 o 3 6 2 269.44 296.98 26.21 o 4 6 2 2845.38 2664.48 51.20 o 5 6 2 60.11 81.88 22.41 o 6 6 2 138.07 178.81 30.19 o 7 6 2 86.24 132.49 38.94 o 8 6 2 2374.20 2411.70 85.73 o 9 6 2 2788.54 2656.91 145.04 o 10 6 2 3.84 -62.61 72.33 o 11 6 2 587.04 774.86 127.47 o 12 6 2 822.15 720.75 220.17 o 1 7 2 13190.63 12875.70 171.40 o 2 7 2 28544.32 26904.02 304.76 o 3 7 2 9752.00 9794.92 133.23 o 4 7 2 418.94 429.11 29.20 o 5 7 2 3365.89 3266.39 72.14 o 6 7 2 11.68 66.92 36.55 o 7 7 2 0.78 -26.77 36.53 o 8 7 2 8.20 32.19 46.58 o 9 7 2 157.23 163.33 66.04 o 10 7 2 52.20 58.96 70.88 o 11 7 2 101.25 175.63 104.43 o 12 7 2 718.80 557.32 288.65 o 0 8 2 1977.99 1900.33 55.05 o 1 8 2 9347.93 9401.05 132.14 o 2 8 2 408.89 511.83 28.23 o 3 8 2 10554.17 10271.59 132.21 o 4 8 2 8885.84 8663.64 138.77 o 5 8 2 4372.48 4311.44 80.09 o 6 8 2 913.52 1008.56 47.14 o 7 8 2 7805.69 7657.38 146.37 o 8 8 2 1498.84 1504.71 92.08 o 9 8 2 12.04 -55.31 64.05 o 10 8 2 1281.48 1235.29 107.61 o 11 8 2 670.55 822.76 136.01 o 12 8 2 283.37 422.12 342.00 o 1 9 2 11755.37 11370.54 141.47 o 2 9 2 326.50 304.54 24.69 o 3 9 2 12.34 11.66 21.34 o 4 9 2 2263.41 2375.70 105.01 o 5 9 2 1127.73 1215.76 47.81 o 6 9 2 1179.85 1268.79 53.55 o 7 9 2 96.06 186.86 50.39 o 8 9 2 978.22 1167.70 87.13 o 9 9 2 189.02 214.62 72.84 o 10 9 2 1264.05 1223.43 107.93 o 11 9 2 1428.11 1465.97 158.93 o 0 10 2 3211.60 3044.73 81.50 o 1 10 2 15.66 41.73 19.35 o 2 10 2 1023.95 1075.25 41.86 o 3 10 2 10.03 -0.32 22.71 o 4 10 2 1104.66 1251.25 49.78 o 5 10 2 3723.78 3710.28 78.20 o 6 10 2 399.13 530.26 48.70 o 7 10 2 12057.57 11255.29 229.98 o 8 10 2 1827.58 1785.83 103.13 o 9 10 2 780.56 881.13 95.22 o 10 10 2 1354.16 1337.20 120.35 o 11 10 2 1060.65 880.81 163.75 o 1 11 2 4828.96 4537.51 118.86 o 2 11 2 1651.71 1758.74 52.73 o 3 11 2 588.84 623.44 39.54 o 4 11 2 380.11 317.20 32.84 o 5 11 2 1256.58 1383.33 61.54 o 6 11 2 603.49 754.46 56.78 o 7 11 2 14.72 22.69 54.29 o 8 11 2 101.35 70.49 65.26 o 9 11 2 413.33 459.46 87.05 o 10 11 2 16.88 27.47 88.53 o 11 11 2 0.04 135.21 282.64 o 0 12 2 9403.50 9082.29 212.22 o 1 12 2 382.26 382.20 30.86 o 2 12 2 442.68 463.59 34.30 o 3 12 2 370.41 344.80 39.04 o 4 12 2 788.56 817.64 47.03 o 5 12 2 39.13 46.43 35.83 o 6 12 2 2617.91 2644.26 97.54 o 7 12 2 3778.31 4093.85 147.27 o 8 12 2 841.23 1003.91 92.56 o 9 12 2 163.46 184.91 85.95 o 10 12 2 1389.20 1514.62 164.28 o 1 13 2 5138.17 4960.75 89.54 o 2 13 2 1463.69 1539.01 54.06 o 3 13 2 179.85 155.14 33.61 o 4 13 2 2505.06 2433.99 79.75 o 5 13 2 448.12 472.19 53.62 o 6 13 2 4023.85 3671.19 170.84 o 7 13 2 559.87 514.54 75.60 o 8 13 2 970.42 954.02 92.87 o 9 13 2 21.70 14.55 78.08 o 10 13 2 242.64 252.78 96.96 o 0 14 2 1592.36 1722.79 101.73 o 1 14 2 163.19 215.65 35.51 o 2 14 2 2236.88 2088.33 72.80 o 3 14 2 45.60 83.42 33.20 o 4 14 2 945.29 885.39 54.25 o 5 14 2 2359.06 2296.44 90.49 o 6 14 2 512.34 592.18 92.90 o 7 14 2 2089.47 2075.11 112.05 o 8 14 2 489.58 496.59 95.77 o 9 14 2 54.93 73.22 87.43 o 10 14 2 17.78 70.81 348.98 o 1 15 2 9104.48 8497.79 151.01 o 2 15 2 7857.38 7519.13 141.40 o 3 15 2 1867.32 1935.33 76.20 o 4 15 2 284.80 255.25 48.71 o 5 15 2 2295.15 2294.79 93.20 o 6 15 2 133.12 101.40 56.72 o 7 15 2 33.07 -13.08 68.99 o 8 15 2 25.98 99.60 79.35 o 9 15 2 178.82 335.01 96.99 o 0 16 2 1295.08 1378.78 111.56 o 1 16 2 472.69 482.85 65.75 o 2 16 2 184.81 284.50 49.00 o 3 16 2 553.99 613.20 58.24 o 4 16 2 687.09 673.29 86.05 o 5 16 2 321.08 214.91 53.42 o 6 16 2 181.48 445.82 127.58 o 7 16 2 902.76 810.43 94.20 o 8 16 2 561.75 537.51 97.95 o 9 16 2 7.36 -86.39 128.91 o 1 17 2 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4 21 2 1347.61 1449.13 189.45 o 5 21 2 116.93 157.39 129.71 o 0 22 2 3332.52 3320.16 251.49 o 1 22 2 553.30 700.02 145.89 o 2 22 2 432.46 511.62 103.25 o 3 22 2 454.36 589.44 110.35 o 4 22 2 157.37 118.99 150.11 o 2 23 2 656.60 817.46 359.65 o 1 1 3 9468.76 9678.74 114.70 o 2 1 3 21550.93 21853.75 317.34 o 3 1 3 290.57 346.11 28.27 o 4 1 3 3595.11 3669.50 79.81 o 5 1 3 6242.76 5901.95 105.08 o 6 1 3 14861.41 14413.23 208.13 o 7 1 3 66.00 65.97 28.94 o 8 1 3 5929.02 5617.00 119.05 o 9 1 3 6387.02 5617.93 126.33 o 10 1 3 426.92 425.66 73.68 o 11 1 3 514.39 551.32 81.94 o 12 1 3 115.23 154.80 133.79 o 0 2 3 13346.59 14290.42 222.64 o 1 2 3 3221.00 3453.69 49.66 o 2 2 3 7563.26 7840.88 101.40 o 3 2 3 2143.17 2042.24 68.63 o 4 2 3 21299.73 20569.01 227.84 o 5 2 3 172.53 183.91 22.16 o 6 2 3 6764.67 6247.93 103.81 o 7 2 3 2148.69 2236.50 69.35 o 8 2 3 5073.15 4874.60 103.97 o 9 2 3 77.10 106.26 45.93 o 10 2 3 4414.07 4350.58 145.07 o 11 2 3 199.01 311.38 78.43 o 12 2 3 1944.63 1904.25 165.24 o 1 3 3 9169.92 9372.51 112.96 o 2 3 3 18895.83 18329.72 288.78 o 3 3 3 6175.43 5948.99 81.97 o 4 3 3 433.63 465.25 23.12 o 5 3 3 117.79 159.50 21.45 o 6 3 3 5389.97 5250.02 97.72 o 7 3 3 1410.63 1501.40 60.32 o 8 3 3 21.98 58.58 37.34 o 9 3 3 17.59 37.81 47.63 o 10 3 3 548.91 523.70 70.66 o 11 3 3 554.05 424.65 92.86 o 12 3 3 2126.88 2225.16 209.58 o 0 4 3 52447.07 53948.97 795.77 o 1 4 3 25723.10 25897.44 277.72 o 2 4 3 1479.50 1515.29 37.94 o 3 4 3 35.64 56.57 17.08 o 4 4 3 732.70 810.37 31.23 o 5 4 3 4286.14 4402.35 86.13 o 6 4 3 1973.63 2120.59 63.94 o 7 4 3 509.12 581.29 45.43 o 8 4 3 4358.63 4355.09 140.38 o 9 4 3 3195.42 3198.36 105.84 o 10 4 3 177.91 236.81 68.07 o 11 4 3 435.69 384.42 90.55 o 12 4 3 3.88 151.78 139.87 o 1 5 3 8284.07 7858.65 95.89 o 2 5 3 16302.88 15675.98 184.60 o 3 5 3 3241.68 3095.67 63.69 o 4 5 3 1637.65 1674.77 42.09 o 5 5 3 600.52 603.42 42.28 o 6 5 3 3258.54 3320.10 82.59 o 7 5 3 2302.10 2260.79 78.76 o 8 5 3 3.92 26.94 42.63 o 9 5 3 6.09 19.42 49.54 o 10 5 3 365.91 334.10 73.30 o 11 5 3 1783.81 1941.56 126.73 o 12 5 3 486.52 998.46 443.55 o 0 6 3 3001.61 2935.60 67.45 o 1 6 3 4356.29 4139.91 66.31 o 2 6 3 3844.44 3645.91 70.16 o 3 6 3 5941.18 5773.79 111.32 o 4 6 3 580.47 633.41 31.34 o 5 6 3 1552.14 1668.63 65.61 o 6 6 3 1.26 -30.04 30.04 o 7 6 3 628.31 574.21 60.64 o 8 6 3 1748.52 1790.21 89.87 o 9 6 3 15.91 1.71 52.11 o 10 6 3 2018.22 2005.33 107.52 o 11 6 3 14.90 80.67 95.75 o 12 6 3 5.32 180.13 196.69 o 1 7 3 18775.94 18427.66 206.59 o 2 7 3 34383.96 33561.98 396.34 o 3 7 3 4119.11 3962.97 70.11 o 4 7 3 30322.27 28835.69 365.93 o 5 7 3 426.84 491.17 36.25 o 6 7 3 8864.32 8403.71 151.29 o 7 7 3 3877.78 3692.22 135.10 o 8 7 3 219.10 356.75 54.59 o 9 7 3 2019.10 2253.38 112.73 o 10 7 3 712.68 536.39 108.38 o 11 7 3 407.22 448.67 107.86 o 0 8 3 13712.85 13249.17 239.37 o 1 8 3 1761.71 1818.77 41.69 o 2 8 3 8831.96 8458.09 120.41 o 3 8 3 379.37 392.42 30.10 o 4 8 3 7373.05 7069.35 109.09 o 5 8 3 784.53 810.06 44.26 o 6 8 3 5.92 23.16 34.51 o 7 8 3 27.71 28.37 41.67 o 8 8 3 3529.73 3243.25 113.89 o 9 8 3 1389.68 1398.20 99.22 o 10 8 3 297.08 341.24 88.46 o 11 8 3 26.09 131.71 99.52 o 1 9 3 5754.14 5898.07 91.95 o 2 9 3 6708.20 6203.17 91.66 o 3 9 3 22702.79 21964.86 274.17 o 4 9 3 6256.91 6264.03 102.26 o 5 9 3 146.48 138.86 28.44 o 6 9 3 41.23 65.48 38.15 o 7 9 3 135.72 144.49 48.47 o 8 9 3 326.71 336.31 68.43 o 9 9 3 429.34 332.22 78.82 o 10 9 3 42.39 -75.69 75.69 o 11 9 3 2012.95 2107.03 144.48 o 0 10 3 274.49 249.64 34.39 o 1 10 3 32.82 40.86 20.02 o 2 10 3 5323.51 5067.38 86.34 o 3 10 3 24660.75 23303.21 306.71 o 4 10 3 1405.70 1449.82 51.39 o 5 10 3 11461.73 11260.56 180.93 o 6 10 3 5700.44 5439.04 118.00 o 7 10 3 706.06 729.12 65.47 o 8 10 3 157.78 253.66 67.82 o 9 10 3 1092.94 1208.91 100.08 o 10 10 3 142.05 161.49 84.45 o 11 10 3 520.18 639.89 229.77 o 1 11 3 582.10 608.26 37.55 o 2 11 3 408.02 417.33 35.33 o 3 11 3 3190.24 3066.56 68.21 o 4 11 3 1297.85 1397.10 56.80 o 5 11 3 61.26 101.74 34.88 o 6 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538.96 592.64 73.82 o 3 18 3 713.61 719.26 74.27 o 4 18 3 320.67 386.18 76.74 o 5 18 3 11.15 1.24 68.98 o 6 18 3 1957.52 1951.23 134.60 o 7 18 3 3486.45 3484.67 311.53 o 1 19 3 18.63 82.77 63.37 o 2 19 3 64.40 67.61 64.26 o 3 19 3 137.83 197.08 79.13 o 4 19 3 123.30 86.93 68.21 o 5 19 3 302.98 338.11 82.78 o 6 19 3 137.63 209.69 102.35 o 7 19 3 15.87 85.55 201.55 o 0 20 3 1124.47 1402.57 187.20 o 1 20 3 0.65 72.33 76.49 o 2 20 3 16.23 216.76 90.98 o 3 20 3 733.55 612.51 98.12 o 4 20 3 211.55 275.85 87.24 o 5 20 3 791.56 876.06 138.45 o 6 20 3 0.05 396.27 445.98 o 1 21 3 2795.89 2796.52 146.82 o 2 21 3 1155.70 1244.45 113.86 o 3 21 3 2075.17 1980.94 136.72 o 4 21 3 1003.03 1017.43 120.37 o 5 21 3 30.46 13.44 161.52 o 0 22 3 16.91 121.30 128.98 o 1 22 3 105.58 211.41 101.67 o 2 22 3 532.75 637.12 110.94 o 3 22 3 2355.25 2116.03 194.25 o 4 22 3 248.90 326.86 193.02 o 1 23 3 1585.70 1652.38 407.95 o 0 0 4 21794.81 19852.26 575.01 o 1 0 4 5556.86 5294.49 98.33 o 2 0 4 5467.07 5137.59 104.05 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831.53 795.75 112.84 o 2 11 10 2.28 3.41 77.42 o 3 11 10 572.89 600.03 91.51 o 4 11 10 125.41 173.19 79.88 o 5 11 10 433.21 469.39 92.17 o 6 11 10 755.34 649.92 142.21 o 0 12 10 4420.99 4562.06 439.87 o 1 12 10 560.75 774.98 132.64 o 2 12 10 58.38 115.64 80.71 o 3 12 10 402.19 274.69 83.64 o 4 12 10 506.29 485.72 94.84 o 5 12 10 28.96 64.03 105.82 o 6 12 10 1091.34 1578.73 279.22 o 1 13 10 725.30 809.32 118.91 o 2 13 10 1195.90 1306.47 110.03 o 3 13 10 376.77 400.29 92.05 o 4 13 10 18.36 -32.36 82.91 o 5 13 10 80.87 44.04 123.02 o 0 14 10 556.44 547.26 177.70 o 1 14 10 85.84 158.98 104.16 o 2 14 10 10.92 42.79 87.20 o 3 14 10 232.47 228.19 89.28 o 4 14 10 152.84 128.97 110.13 o 1 15 10 2551.30 2760.85 185.50 o 2 15 10 2900.03 3026.53 162.25 o 3 15 10 763.55 911.79 163.26 o 1 16 10 4.52 -87.29 200.58 o 2 16 10 26.76 21.50 176.38 o 1 1 11 102.84 194.77 66.23 o 2 1 11 263.56 204.84 77.37 o 3 1 11 82.24 66.69 64.31 o 4 1 11 127.67 161.06 70.90 o 5 1 11 822.05 848.68 99.09 o 6 1 11 221.63 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