#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/12/2201281.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2201281_Fobs loop_ _publ_author_name 'Barnett, Sarah A.' 'Blake, Alexander J.' 'Champness, Neil R.' 'Wilson, Claire' _publ_section_title ; trans-Bis(acetonitrile)tetraaquacobalt(II) dinitrate at 150K ; _journal_issue 8 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m444 _journal_page_last m446 _journal_volume 58 _journal_year 2002 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 119.744 _cell_angle_gamma 90.000 _cell_length_a 7.7375 _cell_length_b 13.0290 _cell_length_c 7.7605 _exptl_crystal_F_000 346.00 _reflns_d_resolution_high 0.7559 _[local]_cod_data_source_file bt6169Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' MHATCO in P2(1)/c for SAB\NRC' _shelx_refln_list_code 4 _shelx_f_calc_maximum 109.39 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 2738.19 2830.53 70.64 o 2 0 0 466.39 482.39 13.98 o 3 0 0 2613.47 2752.25 70.53 o 4 0 0 60.28 58.51 4.97 o 5 0 0 73.71 75.97 5.89 o 6 0 0 452.39 428.58 16.15 o 7 0 0 456.58 430.73 17.20 o 8 0 0 38.48 29.56 5.65 o 1 1 0 1307.22 1493.84 21.50 o 2 1 0 12.55 19.77 1.39 o 3 1 0 636.91 664.67 13.69 o 4 1 0 32.27 32.81 2.93 o 5 1 0 96.09 96.36 4.69 o 6 1 0 0.63 2.55 2.27 o 7 1 0 12.55 14.71 3.19 o 8 1 0 8.24 14.52 3.36 o 0 2 0 3298.01 3441.20 84.32 o 1 2 0 1425.68 1448.74 20.99 o 2 2 0 1814.59 1912.56 27.82 o 3 2 0 1326.78 1398.77 23.28 o 4 2 0 1502.39 1508.97 25.46 o 5 2 0 590.59 565.25 13.30 o 6 2 0 10.14 14.86 2.81 o 7 2 0 333.62 304.71 9.85 o 8 2 0 255.71 244.69 9.06 o 1 3 0 26.70 34.18 1.43 o 2 3 0 1899.99 2087.62 30.43 o 3 3 0 268.31 284.66 5.59 o 4 3 0 38.01 45.70 2.61 o 5 3 0 35.36 35.08 3.28 o 6 3 0 0.37 2.31 2.16 o 7 3 0 0.02 -0.53 2.34 o 8 3 0 11.13 11.22 3.04 o 0 4 0 1333.89 1356.95 34.67 o 1 4 0 943.78 933.88 14.14 o 2 4 0 1385.25 1320.58 19.81 o 3 4 0 1060.59 1128.16 17.45 o 4 4 0 2392.99 2446.58 44.70 o 5 4 0 715.13 695.36 15.78 o 6 4 0 102.47 99.81 5.40 o 7 4 0 269.83 254.61 9.04 o 8 4 0 283.47 259.81 9.64 o 1 5 0 1406.38 1392.24 22.81 o 2 5 0 414.59 446.25 8.23 o 3 5 0 68.90 81.86 2.89 o 4 5 0 489.69 470.28 9.90 o 5 5 0 63.60 76.74 4.50 o 6 5 0 56.15 64.02 4.54 o 7 5 0 2.76 -0.71 2.53 o 8 5 0 0.02 7.67 3.28 o 0 6 0 6568.95 6366.67 156.71 o 1 6 0 1263.38 1236.13 20.65 o 2 6 0 5.77 12.55 1.52 o 3 6 0 2634.62 2638.54 38.98 o 4 6 0 986.80 980.75 17.84 o 5 6 0 40.38 41.06 3.68 o 6 6 0 749.65 764.22 17.97 o 7 6 0 147.19 158.53 8.48 o 8 6 0 30.47 48.58 8.91 o 1 7 0 233.73 240.50 5.87 o 2 7 0 276.73 276.18 5.78 o 3 7 0 1.39 1.26 1.63 o 4 7 0 125.24 123.34 5.21 o 5 7 0 181.79 171.04 7.80 o 6 7 0 27.80 34.10 4.54 o 7 7 0 5.09 8.46 3.10 o 0 8 0 1158.09 1205.87 32.90 o 1 8 0 1326.68 1268.49 22.25 o 2 8 0 277.23 237.33 6.79 o 3 8 0 936.82 891.72 16.41 o 4 8 0 1316.40 1274.76 25.62 o 5 8 0 117.31 123.04 6.90 o 6 8 0 84.92 89.10 6.49 o 7 8 0 53.62 56.05 5.80 o 1 9 0 0.75 -0.73 1.59 o 2 9 0 80.47 80.04 4.03 o 3 9 0 47.37 45.32 3.10 o 4 9 0 361.69 367.89 10.15 o 5 9 0 28.06 25.83 4.03 o 6 9 0 62.86 66.86 5.76 o 7 9 0 1.43 4.22 3.26 o 0 10 0 295.57 256.88 10.56 o 1 10 0 755.52 692.08 15.08 o 2 10 0 397.49 396.26 10.07 o 3 10 0 13.09 18.36 2.55 o 4 10 0 456.80 456.13 13.62 o 5 10 0 422.70 412.41 16.79 o 6 10 0 58.70 58.86 5.70 o 7 10 0 137.00 155.32 17.93 o 1 11 0 155.31 141.80 5.55 o 2 11 0 66.70 75.56 4.30 o 3 11 0 1.50 1.37 1.99 o 4 11 0 3.59 11.12 3.00 o 5 11 0 6.30 9.96 4.13 o 6 11 0 38.07 42.88 5.98 o 0 12 0 1056.74 1026.69 30.54 o 1 12 0 133.84 134.91 5.78 o 2 12 0 249.61 246.43 7.86 o 3 12 0 403.54 393.05 10.64 o 4 12 0 47.73 47.20 4.58 o 5 12 0 55.29 65.77 6.92 o 1 13 0 60.47 66.09 4.43 o 2 13 0 0.30 0.51 2.31 o 3 13 0 0.01 1.35 2.16 o 4 13 0 128.38 122.06 7.11 o 5 13 0 15.97 26.49 5.14 o 0 14 0 454.54 447.18 17.03 o 1 14 0 173.31 175.35 7.00 o 2 14 0 262.79 255.64 8.57 o 3 14 0 344.46 314.73 9.74 o 4 14 0 92.13 87.53 6.25 o 1 15 0 0.02 1.07 2.31 o 2 15 0 55.30 60.91 4.61 o 3 15 0 1.54 7.71 3.30 o 4 15 0 0.47 12.17 4.22 o 0 16 0 193.39 207.21 11.35 o 1 16 0 194.02 199.80 7.88 o 2 16 0 52.38 60.31 5.52 o -9 1 1 94.75 109.01 7.65 o -8 1 1 196.10 185.82 7.69 o -7 1 1 95.24 100.28 5.44 o -6 1 1 155.48 162.60 6.34 o -5 1 1 152.40 147.93 5.70 o -4 1 1 2023.02 2157.16 31.85 o -3 1 1 5081.26 5330.89 76.05 o -2 1 1 11966.71 13530.72 190.96 o -1 1 1 1992.23 2170.06 31.06 o 0 1 1 1996.95 2058.75 29.64 o 1 1 1 4069.63 4342.96 61.75 o 2 1 1 549.05 636.20 12.89 o 3 1 1 1701.32 1768.01 33.17 o 4 1 1 1516.54 1499.91 29.21 o 5 1 1 110.59 109.68 5.29 o 6 1 1 140.60 141.38 6.38 o 7 1 1 291.24 272.19 9.34 o -9 2 1 2.08 11.69 5.05 o -8 2 1 93.87 82.09 5.35 o -7 2 1 20.26 22.04 3.25 o -6 2 1 111.49 125.19 5.57 o -5 2 1 14.64 22.72 2.81 o -4 2 1 2.06 1.31 1.18 o -3 2 1 24.27 16.26 1.41 o -2 2 1 276.29 270.76 4.93 o -1 2 1 298.57 300.89 5.01 o 0 2 1 2361.46 2631.60 41.16 o 1 2 1 1364.22 1460.82 22.02 o 2 2 1 411.48 381.10 7.39 o 3 2 1 57.34 61.62 2.66 o 4 2 1 486.96 521.73 12.27 o 5 2 1 4.48 2.10 2.25 o 6 2 1 1.44 3.06 2.40 o 7 2 1 1.23 0.26 2.25 o 8 2 1 38.52 33.33 11.22 o -9 3 1 17.78 28.93 10.34 o -8 3 1 73.54 77.42 5.16 o -7 3 1 1043.29 1015.64 22.36 o -6 3 1 288.85 297.27 9.00 o -5 3 1 104.85 104.47 4.82 o -4 3 1 3924.16 4022.04 58.21 o -3 3 1 77.92 70.94 2.46 o -2 3 1 3546.34 3896.79 61.08 o -1 3 1 6053.25 6448.85 99.95 o 0 3 1 10464.60 11141.46 157.40 o 1 3 1 136.97 142.51 3.25 o 2 3 1 1122.46 1071.62 17.03 o 3 3 1 1244.16 1237.88 21.14 o 4 3 1 578.79 553.73 12.87 o 5 3 1 740.82 696.64 16.04 o 6 3 1 575.60 523.89 13.64 o 7 3 1 157.70 165.28 7.50 o 8 3 1 50.80 62.30 11.97 o -9 4 1 2.49 11.57 9.29 o -8 4 1 7.66 11.26 3.02 o -7 4 1 54.86 50.27 4.35 o -6 4 1 131.11 141.59 6.08 o -5 4 1 79.07 83.64 3.73 o -4 4 1 588.92 596.82 10.34 o -3 4 1 435.64 445.87 7.92 o -2 4 1 3095.38 3395.20 48.92 o -1 4 1 0.71 0.99 1.01 o 0 4 1 807.79 833.05 12.72 o 1 4 1 182.90 195.01 4.11 o 2 4 1 369.22 404.87 7.22 o 3 4 1 18.11 19.83 1.93 o 4 4 1 20.00 20.22 2.72 o 5 4 1 39.57 40.12 3.79 o 6 4 1 39.92 44.21 4.18 o 7 4 1 2.36 7.05 3.13 o 8 4 1 0.42 -14.63 7.32 o -8 5 1 245.00 239.47 10.26 o -7 5 1 207.41 203.77 7.82 o -6 5 1 120.86 130.90 5.87 o -5 5 1 1033.99 1029.71 18.81 o -4 5 1 1103.49 1100.00 17.50 o -3 5 1 1856.16 1860.75 27.80 o -2 5 1 10.23 18.40 1.78 o -1 5 1 11.45 6.55 1.29 o 0 5 1 3721.34 3718.77 58.49 o 1 5 1 1303.70 1362.28 20.47 o 2 5 1 1896.33 1925.13 28.59 o 3 5 1 1581.13 1546.42 26.21 o 4 5 1 1379.67 1339.45 26.71 o 5 5 1 179.06 181.75 6.96 o 6 5 1 35.30 42.02 4.16 o 7 5 1 115.21 113.85 6.57 o -8 6 1 9.27 19.27 4.01 o -7 6 1 1.80 3.30 2.59 o -6 6 1 152.16 151.23 7.43 o -5 6 1 0.98 0.84 1.78 o -4 6 1 0.33 -0.19 1.44 o -3 6 1 56.79 61.30 2.64 o -2 6 1 0.35 0.71 1.39 o -1 6 1 132.94 140.13 4.01 o 0 6 1 6.79 8.12 1.33 o 1 6 1 1044.56 1093.87 16.90 o 2 6 1 745.13 760.85 12.49 o 3 6 1 14.02 16.38 2.04 o 4 6 1 153.85 167.55 6.40 o 5 6 1 2.48 1.39 2.51 o 6 6 1 1.62 0.45 2.61 o 7 6 1 0.08 -0.39 3.28 o -8 7 1 224.42 228.22 10.37 o -7 7 1 113.27 123.30 7.43 o -6 7 1 287.35 280.12 10.47 o -5 7 1 945.94 893.04 19.02 o -4 7 1 57.68 53.44 3.06 o -3 7 1 1764.30 1718.45 28.76 o -2 7 1 1604.31 1559.92 26.09 o -1 7 1 398.75 400.89 8.10 o 0 7 1 3039.33 3021.36 48.88 o 1 7 1 1763.67 1653.04 24.95 o 2 7 1 555.18 522.67 10.13 o 3 7 1 298.38 316.72 7.71 o 4 7 1 903.48 885.65 19.17 o 5 7 1 66.98 68.19 5.48 o 6 7 1 1.19 1.16 3.11 o 7 7 1 208.77 201.09 10.20 o -8 8 1 18.07 20.78 5.06 o -7 8 1 3.27 5.29 3.23 o -6 8 1 72.54 85.86 5.89 o -5 8 1 5.52 5.21 2.23 o -4 8 1 41.24 44.53 3.08 o -3 8 1 510.83 478.17 9.96 o -2 8 1 545.36 546.70 10.79 o -1 8 1 167.25 158.10 4.60 o 0 8 1 101.54 105.91 3.56 o 1 8 1 73.13 83.42 3.41 o 2 8 1 2.69 2.57 1.63 o 3 8 1 7.56 5.10 2.12 o 4 8 1 0.17 3.86 2.10 o 5 8 1 2.00 1.95 2.85 o 6 8 1 19.20 28.25 4.50 o 7 8 1 8.08 14.26 10.43 o -7 9 1 417.02 433.19 18.61 o -6 9 1 174.68 190.62 8.69 o -5 9 1 23.69 28.85 3.49 o -4 9 1 498.04 472.38 10.30 o -3 9 1 500.77 470.95 10.00 o -2 9 1 123.14 119.34 4.26 o -1 9 1 2018.82 1987.90 40.07 o 0 9 1 1363.19 1266.73 25.34 o 1 9 1 124.20 114.16 4.97 o 2 9 1 698.69 643.17 14.13 o 3 9 1 389.55 389.78 10.28 o 4 9 1 183.86 175.45 6.57 o 5 9 1 175.93 195.24 9.02 o 6 9 1 86.49 96.98 7.15 o -7 10 1 3.52 10.30 4.07 o -6 10 1 76.62 81.26 6.30 o -5 10 1 5.50 6.40 2.59 o -4 10 1 14.27 18.10 2.40 o -3 10 1 141.73 129.17 5.27 o -2 10 1 29.30 27.14 2.89 o -1 10 1 3.89 3.41 1.91 o 0 10 1 209.26 202.10 6.51 o 1 10 1 36.74 42.47 3.25 o 2 10 1 408.26 383.07 9.87 o 3 10 1 11.13 15.64 2.91 o 4 10 1 557.51 522.03 15.31 o 5 10 1 8.66 2.42 3.45 o 6 10 1 0.11 3.23 3.71 o -7 11 1 56.86 59.09 8.80 o -6 11 1 32.45 44.50 5.53 o -5 11 1 66.92 76.38 5.46 o -4 11 1 745.18 708.83 16.11 o -3 11 1 432.97 407.23 10.58 o -2 11 1 143.98 141.85 5.68 o -1 11 1 231.39 219.34 7.11 o 0 11 1 223.20 211.62 7.18 o 1 11 1 173.11 170.06 6.17 o 2 11 1 174.14 170.82 6.25 o 3 11 1 753.07 719.88 19.21 o 4 11 1 306.34 297.32 10.65 o 5 11 1 166.12 170.44 10.54 o -6 12 1 1.45 10.04 3.94 o -5 12 1 0.43 1.95 2.74 o -4 12 1 0.03 4.13 2.61 o -3 12 1 54.90 57.74 3.98 o -2 12 1 5.86 9.57 2.36 o -1 12 1 2.38 3.49 2.10 o 0 12 1 4.94 5.46 2.29 o 1 12 1 136.30 134.52 5.85 o 2 12 1 93.69 103.17 5.23 o 3 12 1 16.29 15.27 3.26 o 4 12 1 2.03 2.98 2.74 o 5 12 1 6.79 9.17 4.33 o -6 13 1 83.49 82.89 10.88 o -5 13 1 207.72 214.26 9.40 o -4 13 1 265.68 260.41 10.07 o -3 13 1 156.82 165.75 6.66 o -2 13 1 380.85 365.12 10.35 o -1 13 1 214.92 204.45 7.33 o 0 13 1 465.44 441.18 11.67 o 1 13 1 590.80 588.29 14.37 o 2 13 1 2.29 1.74 2.21 o 3 13 1 64.80 65.75 5.27 o 4 13 1 179.70 192.33 8.82 o -5 14 1 59.42 79.07 7.15 o -4 14 1 8.84 16.92 3.56 o -3 14 1 1.42 3.17 2.40 o -2 14 1 1.77 4.18 2.49 o -1 14 1 0.25 6.81 2.55 o 0 14 1 22.88 20.30 3.10 o 1 14 1 11.96 9.60 2.72 o 2 14 1 58.69 56.80 4.41 o 3 14 1 2.28 6.88 3.10 o 4 14 1 57.15 60.35 5.63 o -4 15 1 153.10 169.31 9.90 o -3 15 1 139.32 145.17 6.75 o -2 15 1 229.60 247.18 8.67 o -1 15 1 326.47 331.58 11.69 o 0 15 1 185.95 186.07 7.45 o 1 15 1 162.73 178.17 7.39 o 2 15 1 85.70 88.90 5.36 o 3 15 1 44.75 45.00 4.90 o -3 16 1 27.75 39.66 5.44 o -2 16 1 17.10 25.47 3.85 o -1 16 1 64.87 71.96 5.06 o 0 16 1 13.15 15.23 3.15 o 1 16 1 6.12 6.58 2.95 o 2 16 1 57.74 74.13 7.65 o -1 17 1 50.10 73.23 10.45 o -9 0 2 11.92 16.98 4.78 o -8 0 2 454.98 424.13 17.00 o -7 0 2 362.24 361.57 14.54 o -6 0 2 110.98 106.81 6.96 o -5 0 2 2818.53 2891.63 60.29 o -4 0 2 5233.23 5478.13 111.14 o -3 0 2 2213.48 2368.45 48.79 o -2 0 2 62.22 73.72 3.02 o -1 0 2 7480.38 7530.82 183.81 o 0 0 2 2207.27 2355.73 48.04 o 1 0 2 318.19 328.31 8.14 o 2 0 2 280.57 240.69 9.23 o 3 0 2 7.62 9.38 3.02 o 4 0 2 975.69 957.10 28.59 o 5 0 2 460.72 455.76 17.01 o 6 0 2 516.12 452.98 17.82 o 7 0 2 125.67 121.65 9.77 o -9 1 2 24.50 28.42 3.70 o -8 1 2 33.78 39.73 3.98 o -7 1 2 20.29 27.71 3.19 o -6 1 2 31.44 35.92 3.19 o -5 1 2 190.52 181.21 4.71 o -4 1 2 214.66 232.70 5.12 o -3 1 2 1326.03 1504.53 22.40 o -2 1 2 474.67 511.26 8.16 o -1 1 2 1190.26 1165.51 18.83 o 0 1 2 527.28 504.94 8.01 o 1 1 2 459.62 542.46 9.30 o 2 1 2 930.83 1009.25 17.39 o 3 1 2 146.66 147.48 5.46 o 4 1 2 103.33 113.85 5.25 o 5 1 2 0.65 0.13 2.33 o 6 1 2 58.25 62.07 4.80 o 7 1 2 0.02 -1.33 3.11 o -9 2 2 72.30 78.65 5.44 o -8 2 2 192.57 170.14 7.17 o -7 2 2 182.86 176.18 6.81 o -6 2 2 399.65 376.65 10.04 o -5 2 2 350.86 345.03 7.03 o -4 2 2 2420.96 2571.42 37.76 o -3 2 2 6058.58 6461.25 92.10 o -2 2 2 10.11 14.44 1.13 o -1 2 2 435.24 435.44 7.80 o 0 2 2 2364.57 2241.04 32.47 o 1 2 2 838.33 831.45 13.11 o 2 2 2 1288.60 1276.80 21.59 o 3 2 2 1386.72 1373.35 30.95 o 4 2 2 1574.11 1537.73 30.43 o 5 2 2 190.19 189.65 7.30 o 6 2 2 52.42 54.64 4.90 o 7 2 2 154.37 160.25 7.84 o -9 3 2 3.00 6.96 2.85 o -8 3 2 0.86 2.70 2.55 o -7 3 2 63.98 70.19 4.63 o -6 3 2 0.59 3.96 1.86 o -5 3 2 79.15 95.24 3.34 o -4 3 2 190.02 197.26 4.65 o -3 3 2 142.64 182.76 4.20 o -2 3 2 133.02 133.60 3.15 o -1 3 2 44.85 44.31 1.65 o 0 3 2 2282.00 2512.24 36.43 o 1 3 2 171.66 171.55 3.94 o 2 3 2 85.81 85.07 2.81 o 3 3 2 28.29 30.03 2.89 o 4 3 2 1.36 -0.96 2.03 o 5 3 2 0.93 -3.94 2.33 o 6 3 2 71.82 55.79 4.86 o 7 3 2 5.02 1.82 3.23 o -9 4 2 122.01 119.55 8.63 o -8 4 2 112.51 108.61 5.93 o -7 4 2 481.94 471.76 12.44 o -6 4 2 637.99 624.30 14.52 o -5 4 2 2.13 4.07 1.52 o -4 4 2 321.26 309.52 6.27 o -3 4 2 1373.10 1366.99 20.78 o -2 4 2 463.10 446.64 7.60 o -1 4 2 793.72 835.82 12.91 o 0 4 2 6245.49 6350.25 98.91 o 1 4 2 1643.39 1609.99 24.09 o 2 4 2 393.28 382.79 7.13 o 3 4 2 2125.09 2173.91 40.14 o 4 4 2 1042.55 1080.17 22.55 o 5 4 2 96.44 86.10 5.14 o 6 4 2 12.00 12.34 3.43 o 7 4 2 205.53 233.30 9.25 o -9 5 2 19.46 15.74 4.09 o -8 5 2 74.54 69.89 5.67 o -7 5 2 0.10 -1.18 2.31 o -6 5 2 22.30 22.81 3.00 o -5 5 2 109.18 103.75 3.66 o -4 5 2 510.53 518.90 9.30 o -3 5 2 100.73 123.32 3.60 o -2 5 2 4.71 1.50 1.31 o -1 5 2 1654.37 1817.93 29.49 o 0 5 2 3.59 7.00 1.20 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