#------------------------------------------------------------------------------ #$Date: 2016-04-02 23:59:31 +0300 (Sat, 02 Apr 2016) $ #$Revision: 180937 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/17/2201774.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2201774_Fobs loop_ _publ_author_name 'Sundar, T. V.' 'Parthasarathi, V.' 'Thamotharan, S.' 'Sekar, K. G.' _publ_section_title ; Quinolinium dichromate, [C~9~H~7~NH^+^]~2~·Cr~2~O~7~^2{-^} ; _journal_issue 6 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m327 _journal_page_last m329 _journal_volume 59 _journal_year 2003 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 97.670 _cell_angle_gamma 90.000 _cell_length_a 12.2860 _cell_length_b 9.9650 _cell_length_c 15.3860 _exptl_crystal_F_000 968.00 _reflns_d_resolution_high 0.8418 _cod_data_source_file br6097Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' vp1\QDC\Monoclinic\P21/c\2(C9 H7 N H), Cr2 O7\C18 H16 N2 O7 Cr2' _shelx_refln_list_code 4 _shelx_f_calc_maximum 409.11 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 55625.07 53536.23 422.49 o 3 0 0 58728.95 54115.29 520.40 o 4 0 0 4707.99 4497.51 41.43 o 5 0 0 2852.73 2045.74 31.98 o 6 0 0 6054.96 5689.27 57.14 o 7 0 0 1965.11 1758.08 37.98 o 8 0 0 7573.33 7423.28 78.32 o 9 0 0 28.60 -23.11 23.11 o 10 0 0 4952.12 5237.66 78.11 o 11 0 0 5320.32 5765.45 87.73 o 12 0 0 1054.33 910.79 30.84 o 13 0 0 691.13 741.33 27.77 o 14 0 0 325.64 380.81 23.78 o 1 1 0 4669.16 4851.26 27.06 o 2 1 0 26727.66 23370.16 73.45 o 3 1 0 15529.40 13662.69 76.68 o 4 1 0 12609.57 10627.59 63.78 o 5 1 0 8943.14 8018.63 60.80 o 6 1 0 8362.38 7197.47 63.95 o 7 1 0 7353.95 6744.35 68.28 o 8 1 0 21.04 9.29 15.71 o 9 1 0 4774.63 4580.83 67.06 o 10 1 0 195.91 175.51 17.10 o 11 1 0 89.45 119.37 15.29 o 12 1 0 28.16 47.06 23.15 o 13 1 0 12.96 36.18 22.14 o 14 1 0 255.52 310.05 21.22 o 0 2 0 94923.38 113278.60 683.22 o 1 2 0 2259.13 2131.92 23.53 o 2 2 0 16447.04 15091.06 67.44 o 3 2 0 18448.70 16082.19 78.24 o 4 2 0 2092.51 2070.41 32.14 o 5 2 0 1760.09 1238.99 29.50 o 6 2 0 1842.08 1369.37 38.49 o 7 2 0 342.71 231.56 14.75 o 8 2 0 6142.86 5582.88 70.25 o 9 2 0 25.71 46.43 17.86 o 10 2 0 2145.71 2142.30 52.31 o 11 2 0 1270.21 1246.93 38.24 o 12 2 0 157.30 134.25 16.98 o 13 2 0 289.23 344.17 19.45 o 14 2 0 131.26 173.83 17.69 o 1 3 0 29620.50 28831.02 100.47 o 2 3 0 1284.38 916.29 20.88 o 3 3 0 9573.56 8920.26 64.54 o 4 3 0 24347.21 21400.31 106.05 o 5 3 0 2994.02 2739.76 43.24 o 6 3 0 18374.81 17525.05 114.04 o 7 3 0 8269.50 7763.25 84.67 o 8 3 0 47.18 84.29 15.63 o 9 3 0 2819.34 2983.80 71.35 o 10 3 0 690.05 759.82 29.03 o 11 3 0 334.89 343.33 20.93 o 12 3 0 768.89 798.60 27.02 o 13 3 0 10.92 -22.23 22.77 o 0 4 0 867.28 1407.99 26.85 o 1 4 0 2.29 16.60 9.66 o 2 4 0 3541.92 2954.85 39.96 o 3 4 0 2600.95 2068.81 34.96 o 4 4 0 3589.01 3483.35 47.56 o 5 4 0 6999.59 5954.28 65.72 o 6 4 0 1302.79 1168.32 33.61 o 7 4 0 1496.22 1453.37 40.25 o 8 4 0 2760.65 2776.94 57.82 o 9 4 0 44.85 50.51 14.50 o 10 4 0 560.33 597.42 23.78 o 11 4 0 129.88 187.86 19.41 o 12 4 0 2.95 -2.10 31.35 o 13 4 0 161.73 202.36 29.03 o 1 5 0 4326.41 4348.17 51.60 o 2 5 0 1198.34 1013.44 27.65 o 3 5 0 1330.62 1337.65 31.98 o 4 5 0 5201.98 4733.69 59.04 o 5 5 0 5.76 17.19 14.71 o 6 5 0 2233.88 2214.02 46.85 o 7 5 0 894.56 858.05 26.30 o 8 5 0 20.80 34.45 20.42 o 9 5 0 1004.64 1057.30 32.77 o 10 5 0 288.71 333.20 20.04 o 11 5 0 189.70 215.85 18.78 o 12 5 0 567.53 641.20 28.24 o 13 5 0 1.58 0.00 27.19 o 0 6 0 1807.39 2018.77 39.79 o 1 6 0 537.47 543.93 16.81 o 2 6 0 659.47 636.11 19.96 o 3 6 0 2907.08 2726.27 48.78 o 4 6 0 0.12 16.43 14.66 o 5 6 0 2122.52 2075.95 46.77 o 6 6 0 689.59 673.97 20.71 o 7 6 0 1112.00 1048.23 29.66 o 8 6 0 683.67 718.72 23.74 o 9 6 0 2.73 -18.45 22.56 o 10 6 0 321.48 310.14 20.71 o 11 6 0 234.97 244.59 20.38 o 12 6 0 21.27 -28.61 28.61 o 1 7 0 1305.09 1422.78 37.73 o 2 7 0 1433.95 1422.82 38.82 o 3 7 0 1.51 9.08 16.30 o 4 7 0 484.59 501.57 17.98 o 5 7 0 26.24 39.88 19.62 o 6 7 0 333.00 316.86 17.48 o 7 7 0 2.94 28.57 18.91 o 8 7 0 21.08 14.37 21.22 o 9 7 0 312.20 295.81 19.58 o 10 7 0 42.56 36.60 23.32 o 11 7 0 58.88 34.96 25.97 o 0 8 0 1322.32 1534.46 42.86 o 1 8 0 339.05 306.69 16.09 o 2 8 0 60.59 80.68 12.90 o 3 8 0 1059.67 1052.01 30.04 o 4 8 0 50.20 22.06 20.25 o 5 8 0 38.03 56.01 21.98 o 6 8 0 96.20 108.49 15.38 o 7 8 0 10.44 15.97 21.14 o 8 8 0 125.04 113.79 16.01 o 9 8 0 0.72 31.22 21.43 o 10 8 0 60.42 69.29 25.21 o 1 9 0 157.28 196.18 15.63 o 2 9 0 182.83 189.46 15.25 o 3 9 0 43.28 55.55 21.05 o 4 9 0 127.03 120.51 15.34 o 5 9 0 71.47 58.28 22.56 o 6 9 0 129.08 69.92 24.79 o 7 9 0 81.05 83.57 15.13 o 8 9 0 4.45 -1.60 23.07 o 9 9 0 51.65 60.13 26.56 o 0 10 0 104.07 118.79 15.71 o 1 10 0 6.95 2.77 21.09 o 2 10 0 25.22 22.27 18.87 o 3 10 0 32.92 43.91 21.43 o 4 10 0 2.10 17.23 20.50 o 5 10 0 94.84 83.53 15.46 o 6 10 0 37.45 17.27 25.51 o 7 10 0 0.20 -19.79 22.14 o 1 11 0 20.36 -7.94 21.77 o 2 11 0 0.03 1.60 21.60 o 3 11 0 12.67 35.88 19.45 o 4 11 0 0.85 -21.30 24.41 o 5 11 0 3.37 18.70 23.45 o -14 1 1 0.43 -8.53 25.13 o -13 1 1 2.16 23.24 21.64 o -12 1 1 8.81 30.38 21.01 o -11 1 1 14.59 -8.74 23.19 o -10 1 1 1.14 -9.03 22.98 o -9 1 1 110.29 138.95 14.54 o -8 1 1 36.32 17.23 18.03 o -7 1 1 2.38 -11.93 15.71 o -6 1 1 20.31 10.42 14.66 o -5 1 1 124.54 108.03 9.29 o -4 1 1 176.99 160.85 9.83 o -3 1 1 0.12 5.25 12.27 o -2 1 1 80.67 84.25 6.18 o -1 1 1 4.17 -1.47 6.26 o 0 1 1 244.23 177.14 12.25 o 1 1 1 390.07 304.09 8.61 o 2 1 1 195.29 146.56 7.31 o 3 1 1 13.66 14.12 13.28 o 4 1 1 1178.13 1059.83 28.53 o 5 1 1 18.58 15.08 13.53 o 6 1 1 125.61 102.02 10.42 o 7 1 1 55.19 54.62 11.13 o 8 1 1 8.10 -15.63 17.86 o 9 1 1 181.05 186.77 14.24 o 10 1 1 168.34 134.37 16.05 o 11 1 1 0.48 16.09 20.38 o 12 1 1 41.59 59.12 21.05 o 13 1 1 21.13 30.59 24.58 o 14 1 1 2.70 14.54 23.24 o -14 2 1 5.82 1.76 26.72 o -13 2 1 9.72 14.62 24.33 o -12 2 1 2.92 -1.43 22.35 o -11 2 1 1.37 37.23 24.50 o -10 2 1 231.61 252.32 17.90 o -9 2 1 209.98 233.24 17.86 o -8 2 1 187.94 168.07 16.77 o -7 2 1 6.89 21.05 19.83 o -6 2 1 41.55 68.57 11.51 o -5 2 1 1960.79 1947.42 38.49 o -4 2 1 0.12 4.87 10.13 o -3 2 1 23.65 4.83 9.33 o -2 2 1 224.91 259.59 7.61 o -1 2 1 64.60 37.48 4.20 o 0 2 1 9949.27 11393.69 752.84 o 1 2 1 143.76 214.92 6.93 o 2 2 1 52.04 27.02 10.21 o 3 2 1 9.61 18.99 11.01 o 4 2 1 7.74 -1.22 12.35 o 5 2 1 1748.98 1733.29 39.92 o 6 2 1 34.70 59.71 19.20 o 7 2 1 108.68 79.50 23.87 o 8 2 1 323.50 376.11 20.88 o 9 2 1 119.30 70.93 25.84 o 10 2 1 429.18 498.13 22.98 o 11 2 1 405.30 476.07 23.40 o 12 2 1 120.68 107.06 17.06 o 13 2 1 56.72 74.88 27.02 o 14 2 1 32.77 3.36 27.98 o -14 3 1 0.61 43.03 28.19 o -13 3 1 2.01 -24.58 24.92 o -12 3 1 86.09 91.31 18.19 o -11 3 1 203.99 220.34 20.50 o -10 3 1 94.39 115.63 19.33 o -9 3 1 552.33 549.89 25.25 o -8 3 1 90.20 79.75 14.96 o -7 3 1 325.40 260.34 13.53 o -6 3 1 1305.31 1283.99 31.51 o -5 3 1 241.62 252.57 9.50 o -4 3 1 93.82 81.05 6.85 o -3 3 1 430.05 345.14 10.38 o -2 3 1 112.92 133.79 6.43 o -1 3 1 6103.08 5700.32 44.04 o 0 3 1 46.88 39.71 7.96 o 1 3 1 3726.14 3869.96 39.96 o 2 3 1 90.38 120.51 7.14 o 3 3 1 26.30 28.49 11.30 o 4 3 1 17.70 -10.92 13.11 o 5 3 1 482.15 460.06 14.12 o 6 3 1 1517.82 1657.49 41.89 o 7 3 1 304.49 263.24 18.19 o 8 3 1 85.31 116.60 17.73 o 9 3 1 663.31 760.15 29.50 o 10 3 1 2.98 3.61 32.19 o 11 3 1 111.56 139.67 22.48 o 12 3 1 10.78 39.46 29.29 o 13 3 1 0.11 -23.11 29.87 o -13 4 1 2.65 59.12 30.17 o -12 4 1 6.78 42.19 27.19 o -11 4 1 22.61 37.86 22.35 o -10 4 1 63.97 63.70 21.22 o -9 4 1 3.79 15.34 18.11 o -8 4 1 505.20 430.01 17.31 o -7 4 1 52.80 50.30 16.77 o -6 4 1 73.08 49.12 9.33 o -5 4 1 165.18 130.93 9.41 o -4 4 1 1025.58 988.73 25.21 o -3 4 1 43.85 46.85 6.18 o -2 4 1 797.07 633.80 16.68 o -1 4 1 18.03 5.76 8.53 o 0 4 1 1301.44 1830.14 90.49 o 1 4 1 26.85 15.17 9.20 o 2 4 1 510.30 436.95 13.24 o 3 4 1 26.61 46.30 7.27 o 4 4 1 423.16 466.78 13.82 o 5 4 1 6.35 34.88 14.16 o 6 4 1 221.06 192.23 13.87 o 7 4 1 0.73 -20.80 20.80 o 8 4 1 767.80 761.37 24.58 o 9 4 1 14.89 8.45 23.40 o 10 4 1 106.58 125.26 19.66 o 11 4 1 0.43 -32.94 32.94 o 12 4 1 12.83 18.66 32.40 o 13 4 1 30.06 23.66 38.40 o -13 5 1 11.04 -8.11 21.81 o -12 5 1 69.63 82.65 15.71 o -11 5 1 173.28 178.07 16.51 o -10 5 1 69.11 55.30 22.31 o -9 5 1 301.51 263.33 16.39 o -8 5 1 0.23 -17.86 17.86 o -7 5 1 476.18 413.33 16.56 o -6 5 1 91.28 125.51 11.09 o -5 5 1 174.03 185.59 11.68 o -4 5 1 795.97 763.93 21.60 o -3 5 1 1067.34 1165.67 28.78 o -2 5 1 4.81 19.62 9.29 o -1 5 1 4330.60 4626.50 52.65 o 0 5 1 103.72 111.27 15.48 o 1 5 1 3507.50 4018.62 51.39 o 2 5 1 19.25 20.71 12.06 o 3 5 1 483.46 378.67 12.52 o 4 5 1 1868.36 1707.83 38.45 o 5 5 1 190.76 196.06 12.77 o 6 5 1 616.31 644.60 20.00 o 7 5 1 1649.04 1599.68 46.35 o 8 5 1 7.03 14.87 20.38 o 9 5 1 446.93 441.07 21.98 o 10 5 1 239.76 255.93 20.34 o 11 5 1 219.56 169.04 22.06 o 12 5 1 176.53 206.65 23.74 o -12 6 1 14.02 50.46 21.98 o -11 6 1 4.16 14.12 20.67 o -10 6 1 111.19 131.98 15.04 o -9 6 1 51.75 25.59 21.01 o -8 6 1 402.82 376.65 17.61 o -7 6 1 883.03 921.33 29.96 o -6 6 1 858.07 765.24 22.82 o -5 6 1 3372.35 3330.79 56.05 o -4 6 1 176.19 152.11 11.85 o -3 6 1 516.14 510.86 15.46 o -2 6 1 2077.21 1951.07 39.16 o -1 6 1 44.76 59.25 9.37 o 0 6 1 158.05 117.58 16.68 o 1 6 1 158.79 203.07 11.64 o 2 6 1 1407.40 1283.11 35.04 o 3 6 1 1204.14 1235.67 35.17 o 4 6 1 95.21 92.69 12.10 o 5 6 1 4663.71 4285.27 67.61 o 6 6 1 1343.17 1320.42 35.67 o 7 6 1 508.38 510.31 21.39 o 8 6 1 601.11 536.40 23.45 o 9 6 1 67.71 79.54 24.33 o 10 6 1 75.06 21.98 25.88 o 11 6 1 4.12 38.32 24.75 o 12 6 1 4.95 15.97 28.57 o -11 7 1 105.05 129.04 17.35 o -10 7 1 0.13 25.84 17.56 o -9 7 1 142.96 170.01 15.17 o -8 7 1 6.19 5.00 20.88 o -7 7 1 16.46 43.45 18.61 o -6 7 1 70.37 34.92 19.50 o -5 7 1 248.27 262.78 15.84 o -4 7 1 725.43 742.21 21.85 o -3 7 1 285.88 311.15 14.92 o -2 7 1 896.88 924.07 27.65 o -1 7 1 2053.19 2178.86 45.72 o 0 7 1 0.23 17.71 9.98 o 1 7 1 1608.61 1765.90 42.82 o 2 7 1 1488.64 1535.14 40.76 o 3 7 1 84.40 69.62 12.65 o 4 7 1 741.29 687.84 21.18 o 5 7 1 124.30 112.57 14.62 o 6 7 1 29.10 7.02 21.01 o 7 7 1 814.99 697.25 24.45 o 8 7 1 10.97 26.81 21.85 o 9 7 1 232.70 211.02 18.82 o 10 7 1 81.12 66.64 18.24 o 11 7 1 95.61 34.41 31.43 o -10 8 1 202.54 218.70 18.53 o -9 8 1 0.55 6.01 20.71 o -8 8 1 208.03 215.18 17.48 o -7 8 1 426.38 374.38 19.45 o -6 8 1 310.29 292.95 17.90 o -5 8 1 832.97 903.94 27.06 o -4 8 1 0.81 20.50 18.15 o -3 8 1 1081.53 1113.11 33.61 o -2 8 1 1072.41 1193.19 34.92 o -1 8 1 338.64 351.31 16.39 o 0 8 1 2236.30 2429.04 58.55 o 1 8 1 692.53 818.22 25.63 o 2 8 1 564.20 591.99 20.34 o 3 8 1 2314.65 2341.84 53.95 o 4 8 1 281.65 271.52 17.19 o 5 8 1 2323.77 2261.55 57.94 o 6 8 1 474.01 407.32 21.35 o 7 8 1 303.67 326.57 20.80 o 8 8 1 421.00 408.80 21.56 o 9 8 1 17.79 46.51 25.63 o 10 8 1 173.77 182.28 19.16 o -9 9 1 218.91 231.48 19.92 o -8 9 1 68.55 96.98 15.71 o -7 9 1 116.56 138.87 15.55 o -6 9 1 249.12 262.91 18.03 o -5 9 1 3.27 -6.51 20.04 o -4 9 1 797.61 732.76 23.87 o -3 9 1 195.73 171.01 17.14 o -2 9 1 726.72 723.97 22.19 o -1 9 1 1838.60 1918.89 52.10 o 0 9 1 8.11 30.48 13.50 o 1 9 1 1153.53 1208.49 33.66 o 2 9 1 1065.36 1108.86 32.35 o 3 9 1 11.00 16.51 19.45 o 4 9 1 558.44 584.60 22.06 o 5 9 1 127.07 158.83 16.85 o 6 9 1 173.16 152.36 17.82 o 7 9 1 224.70 194.59 18.49 o 8 9 1 37.73 11.81 24.83 o 9 9 1 247.97 265.18 20.80 o -7 10 1 97.04 65.21 28.95 o -6 10 1 26.18 45.30 23.53 o -5 10 1 412.51 421.48 21.68 o -4 10 1 19.51 17.31 21.47 o -3 10 1 486.36 456.15 22.06 o -2 10 1 305.67 327.78 19.96 o -1 10 1 18.56 29.08 21.30 o 0 10 1 862.51 958.33 28.38 o 1 10 1 345.99 384.26 19.58 o 2 10 1 336.25 386.06 20.50 o 3 10 1 599.63 600.78 23.19 o 4 10 1 3.05 11.77 20.84 o 5 10 1 379.33 402.28 21.60 o 6 10 1 177.56 157.44 17.90 o 7 10 1 121.86 139.96 17.94 o -5 11 1 18.57 27.31 24.62 o -4 11 1 257.59 272.87 20.80 o -3 11 1 255.52 220.43 20.67 o -2 11 1 122.14 67.82 28.24 o -1 11 1 440.13 436.95 22.48 o 0 11 1 0.45 -0.44 14.99 o 1 11 1 197.39 202.61 19.92 o 2 11 1 200.26 179.21 18.95 o 3 11 1 70.01 112.57 17.14 o 4 11 1 427.95 384.17 23.61 o 5 11 1 0.16 -22.48 26.77 o -14 0 2 25.89 14.24 24.79 o -13 0 2 23.73 48.49 24.41 o -12 0 2 32.66 -15.80 25.93 o -11 0 2 0.94 -11.68 24.92 o -10 0 2 489.64 568.84 23.24 o -9 0 2 13.54 -20.29 20.29 o -8 0 2 6.92 1.89 17.56 o -7 0 2 353.80 360.64 14.24 o -6 0 2 27.46 40.38 13.19 o -5 0 2 383.78 379.17 11.51 o -4 0 2 101.38 82.48 7.90 o -3 0 2 656.40 657.63 18.95 o -2 0 2 513.28 501.24 13.32 o -1 0 2 111.00 121.98 5.92 o 0 0 2 1610.11 2257.06 16.91 o 1 0 2 113.30 107.27 6.22 o 2 0 2 2180.65 2170.16 29.50 o 3 0 2 2382.70 2235.96 33.32 o 4 0 2 308.74 318.54 10.25 o 5 0 2 2926.98 2764.09 43.19 o 6 0 2 565.24 539.51 16.39 o 7 0 2 964.40 997.93 27.40 o 8 0 2 753.63 665.53 19.58 o 9 0 2 0.28 17.06 18.03 o 10 0 2 524.76 548.80 20.29 o 11 0 2 126.96 121.64 17.56 o 12 0 2 310.87 366.82 20.17 o 13 0 2 88.11 70.55 17.35 o 14 0 2 0.41 -13.49 25.04 o -14 1 2 5.50 -7.31 23.45 o -13 1 2 7.39 -16.72 25.34 o -12 1 2 61.14 31.43 28.03 o -11 1 2 56.56 83.07 25.88 o -10 1 2 93.48 129.79 17.14 o -9 1 2 7.18 -21.60 21.60 o -8 1 2 44.19 57.44 19.96 o -7 1 2 32.79 39.03 16.64 o -6 1 2 275.82 252.40 12.31 o -5 1 2 152.83 150.13 10.00 o -4 1 2 721.23 624.81 19.54 o -3 1 2 129.55 125.47 9.33 o -2 1 2 526.23 489.55 14.50 o -1 1 2 1785.83 1782.58 23.66 o 0 1 2 47.09 45.96 3.50 o 1 1 2 2517.88 2532.31 29.20 o 2 1 2 1135.59 1029.36 23.11 o 3 1 2 604.39 548.46 16.77 o 4 1 2 2477.15 2127.80 40.59 o 5 1 2 17.46 19.12 13.91 o 6 1 2 1910.84 1719.85 41.98 o 7 1 2 632.07 563.30 18.53 o 8 1 2 137.96 145.09 14.96 o 9 1 2 633.48 597.42 22.19 o 10 1 2 36.19 44.67 23.53 o 11 1 2 6.68 26.51 20.13 o 12 1 2 128.32 125.05 18.32 o 13 1 2 2.44 8.03 25.08 o 14 1 2 49.71 78.41 28.15 o -14 2 2 1.67 15.46 27.31 o -13 2 2 6.09 19.75 24.83 o -12 2 2 5.25 42.27 24.29 o -11 2 2 7.62 6.01 24.50 o -10 2 2 4.27 28.32 22.82 o -9 2 2 22.24 28.78 23.03 o -8 2 2 40.09 6.13 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