#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/23/2202350.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2202350_Fobs loop_ _publ_author_name 'Lee, Clare' 'Harrison, William T. A.' _publ_section_title ; Propane-1,2-diammonium hydrogenarsenate monohydrate ; _journal_issue 9 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m739 _journal_page_last m741 _journal_volume 59 _journal_year 2003 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2yn' _symmetry_space_group_name_H-M 'P 1 21/n 1' _cell_angle_alpha 90.000 _cell_angle_beta 92.315 _cell_angle_gamma 90.000 _cell_length_a 10.9115 _cell_length_b 6.1530 _cell_length_c 13.3653 _exptl_crystal_F_000 480.00 _reflns_d_resolution_high 0.6617 _[local]_cod_data_source_file bt6320Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' cl05 in P2(1)/n' _shelx_refln_list_code 4 _shelx_f_calc_maximum 172.86 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x-1/2, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 6538.60 7421.00 61.65 o 4 0 0 6586.46 6888.06 48.39 o 6 0 0 16094.87 15592.52 157.66 o 8 0 0 12945.76 12902.26 260.15 o 10 0 0 2207.87 2221.63 39.91 o 12 0 0 1106.15 1153.80 42.57 o 14 0 0 1506.42 1425.57 57.11 o 16 0 0 442.18 420.88 36.16 o 1 1 0 5180.58 5328.59 23.34 o 2 1 0 290.82 284.50 6.43 o 3 1 0 2387.69 2147.21 22.05 o 4 1 0 135.04 150.35 6.76 o 5 1 0 874.18 799.11 14.05 o 6 1 0 291.06 296.15 10.28 o 7 1 0 1911.78 1950.24 41.32 o 8 1 0 239.65 234.93 11.36 o 9 1 0 2196.08 2178.71 31.44 o 10 1 0 64.50 64.64 7.75 o 11 1 0 305.20 294.71 12.22 o 12 1 0 2.35 -0.60 7.00 o 13 1 0 277.06 275.73 15.49 o 14 1 0 17.36 26.37 13.29 o 15 1 0 173.23 158.00 25.75 o 16 1 0 8.04 12.28 19.22 o 0 2 0 862.61 734.33 27.49 o 1 2 0 58.35 73.61 5.06 o 2 2 0 2458.45 2675.63 17.54 o 3 2 0 826.75 842.17 9.10 o 4 2 0 3066.49 3265.35 50.73 o 5 2 0 850.01 847.86 11.25 o 6 2 0 1540.03 1648.15 26.23 o 7 2 0 1.27 6.92 6.62 o 8 2 0 28.95 36.84 8.26 o 9 2 0 71.18 63.95 9.02 o 10 2 0 108.14 110.84 10.15 o 11 2 0 47.38 44.27 9.77 o 12 2 0 416.77 394.53 17.33 o 13 2 0 23.79 13.79 11.16 o 14 2 0 35.23 32.16 19.62 o 15 2 0 1.27 16.01 19.22 o 16 2 0 0.44 -12.01 18.82 o 1 3 0 219.07 190.07 6.82 o 2 3 0 228.37 246.33 11.51 o 3 3 0 9336.11 9438.42 75.75 o 4 3 0 2.11 0.25 4.08 o 5 3 0 3501.64 3328.28 24.64 o 6 3 0 236.62 237.95 9.03 o 7 3 0 466.10 490.61 12.66 o 8 3 0 232.89 224.23 10.13 o 9 3 0 870.02 901.54 21.54 o 10 3 0 0.59 -4.66 7.52 o 11 3 0 1377.49 1358.13 38.74 o 12 3 0 1.07 9.34 17.48 o 13 3 0 522.93 491.79 25.41 o 14 3 0 8.02 7.21 18.95 o 15 3 0 91.50 97.68 24.82 o 0 4 0 4908.59 4934.51 50.50 o 1 4 0 0.80 -3.69 5.47 o 2 4 0 2471.77 2377.02 24.34 o 3 4 0 161.63 159.02 8.20 o 4 4 0 6489.34 6550.91 42.13 o 5 4 0 80.57 75.94 7.93 o 6 4 0 2211.91 2268.44 53.21 o 7 4 0 11.83 14.41 6.75 o 8 4 0 1398.96 1400.23 35.81 o 9 4 0 4.03 1.90 11.42 o 10 4 0 1127.49 1157.15 44.02 o 11 4 0 0.52 5.78 12.86 o 12 4 0 795.73 855.48 73.33 o 13 4 0 1.97 -2.14 18.55 o 14 4 0 438.17 413.81 38.16 o 1 5 0 300.35 311.58 11.92 o 2 5 0 245.98 242.17 11.21 o 3 5 0 2031.68 2070.13 26.03 o 4 5 0 33.46 22.73 7.11 o 5 5 0 1050.37 1008.74 22.81 o 6 5 0 0.10 1.97 10.24 o 7 5 0 130.45 136.11 16.25 o 8 5 0 91.76 109.89 14.81 o 9 5 0 173.65 157.25 17.28 o 10 5 0 46.75 42.88 16.08 o 11 5 0 301.46 321.64 24.11 o 12 5 0 9.70 -0.14 13.92 o 13 5 0 157.47 144.12 27.89 o 0 6 0 1195.44 1181.96 31.30 o 1 6 0 12.61 4.89 7.73 o 2 6 0 846.36 859.79 19.27 o 3 6 0 69.95 73.28 10.43 o 4 6 0 148.14 149.01 15.89 o 5 6 0 166.18 180.20 17.49 o 6 6 0 484.86 477.38 25.36 o 7 6 0 0.56 7.16 13.26 o 8 6 0 675.70 637.14 29.96 o 9 6 0 0.43 4.23 13.77 o 10 6 0 112.92 120.68 19.15 o 11 6 0 22.24 20.69 15.68 o 12 6 0 66.58 52.75 17.35 o 1 7 0 1626.52 1728.50 34.49 o 2 7 0 27.04 22.33 11.06 o 3 7 0 1529.92 1558.96 42.44 o 4 7 0 11.36 14.88 13.11 o 5 7 0 896.10 916.89 35.02 o 6 7 0 6.23 8.03 14.06 o 7 7 0 958.90 1008.79 39.06 o 8 7 0 0.78 0.83 14.96 o 9 7 0 657.83 646.22 33.65 o 10 7 0 1.83 22.86 16.35 o 0 8 0 1066.63 1062.34 54.04 o 1 8 0 0.00 2.66 19.75 o 2 8 0 295.11 303.05 35.23 o 3 8 0 1.60 -1.94 15.21 o 4 8 0 183.49 188.89 21.42 o 5 8 0 18.17 13.98 15.20 o 6 8 0 401.99 404.90 28.12 o 7 8 0 3.90 8.37 15.90 o 8 8 0 351.80 354.05 28.26 o 1 9 0 6.01 -3.20 22.55 o 2 9 0 6.19 -2.80 23.09 o 3 9 0 1.04 -6.54 23.35 o 4 9 0 0.64 13.08 24.69 o -15 0 1 263.68 268.89 31.63 o -13 0 1 81.51 98.75 21.22 o -11 0 1 678.60 631.85 23.42 o -9 0 1 270.23 271.41 15.01 o -7 0 1 1949.00 2041.32 30.91 o -5 0 1 2217.64 2493.30 28.82 o -3 0 1 137.30 181.20 7.01 o -1 0 1 2958.81 3427.20 34.16 o 1 0 1 2625.41 2882.22 30.16 o 3 0 1 3772.84 4023.62 37.36 o 5 0 1 20.48 23.06 5.77 o 7 0 1 523.07 531.29 17.07 o 9 0 1 457.74 450.88 18.58 o 11 0 1 99.88 79.89 12.60 o 13 0 1 1.37 -7.26 10.26 o 15 0 1 63.34 56.71 22.02 o -16 1 1 68.16 67.79 23.09 o -15 1 1 147.55 126.92 25.35 o -14 1 1 27.05 19.38 12.73 o -13 1 1 580.73 612.64 27.25 o -12 1 1 3.18 1.17 8.19 o -11 1 1 1828.34 1805.32 52.27 o -10 1 1 113.30 101.22 8.34 o -9 1 1 1909.63 1914.46 24.67 o -8 1 1 581.13 575.74 15.64 o -7 1 1 2556.25 2682.40 29.70 o -6 1 1 39.22 37.82 4.62 o -5 1 1 11316.13 11623.70 50.72 o -3 1 1 14991.20 15738.17 155.08 o -2 1 1 4688.13 4881.29 32.37 o -1 1 1 8214.47 8451.84 35.05 o 0 1 1 618.01 541.80 15.48 o 1 1 1 13096.01 12707.97 66.90 o 2 1 1 1326.27 1250.37 10.61 o 3 1 1 29879.04 28518.92 161.95 o 4 1 1 310.28 377.38 8.99 o 5 1 1 4645.00 4846.59 99.76 o 6 1 1 939.51 1021.56 17.23 o 7 1 1 4743.62 4803.00 52.40 o 8 1 1 1.24 0.29 7.11 o 9 1 1 3104.49 3096.63 37.50 o 10 1 1 24.32 25.40 7.20 o 11 1 1 1398.51 1413.66 24.33 o 12 1 1 39.75 44.50 8.46 o 13 1 1 735.38 690.28 19.27 o 14 1 1 0.17 8.67 17.08 o 15 1 1 403.49 387.38 34.70 o 16 1 1 12.94 30.16 19.75 o -16 2 1 161.54 146.79 27.76 o -15 2 1 0.09 -4.40 18.68 o -14 2 1 806.88 776.90 47.37 o -13 2 1 30.08 15.11 12.22 o -12 2 1 751.97 778.81 23.18 o -11 2 1 27.44 24.98 10.98 o -10 2 1 1082.35 1119.66 24.30 o -9 2 1 24.96 29.67 8.28 o -8 2 1 3748.05 3770.38 60.10 o -7 2 1 20.04 17.92 5.06 o -6 2 1 3522.21 3648.94 26.92 o -5 2 1 372.32 381.57 10.34 o -4 2 1 5086.88 5207.85 24.66 o -3 2 1 315.40 335.92 7.22 o -2 2 1 2690.75 2536.65 19.03 o -1 2 1 43.35 46.80 4.65 o 0 2 1 15759.21 14997.85 78.47 o 1 2 1 62.47 87.69 6.11 o 2 2 1 2452.45 2332.22 31.26 o 3 2 1 257.26 263.34 4.78 o 4 2 1 3761.70 3794.59 50.98 o 5 2 1 102.84 119.46 7.49 o 6 2 1 6033.19 6110.44 46.17 o 7 2 1 53.28 45.14 7.29 o 8 2 1 2050.85 2081.88 31.68 o 9 2 1 25.32 27.24 7.05 o 10 2 1 1680.68 1765.03 37.79 o 11 2 1 3.09 3.03 7.25 o 12 2 1 881.79 909.94 25.15 o 13 2 1 0.26 0.37 11.00 o 14 2 1 602.16 612.93 28.30 o 15 2 1 0.02 -6.00 17.61 o 16 2 1 261.85 247.80 31.76 o -15 3 1 45.39 39.10 21.75 o -14 3 1 30.75 23.89 20.15 o -13 3 1 171.57 186.95 28.02 o -12 3 1 46.37 46.84 19.88 o -11 3 1 234.49 225.49 17.19 o -10 3 1 223.63 246.43 13.58 o -9 3 1 266.22 261.37 12.95 o -8 3 1 85.28 84.72 8.07 o -7 3 1 544.75 540.58 13.52 o -6 3 1 13.78 13.53 4.88 o -5 3 1 479.29 430.36 9.83 o -4 3 1 314.28 316.44 8.53 o -3 3 1 1717.71 1786.68 17.89 o -2 3 1 1322.64 1346.04 17.96 o -1 3 1 766.36 716.31 13.40 o 0 3 1 259.44 301.56 9.45 o 1 3 1 113.42 96.82 5.60 o 2 3 1 155.09 159.53 6.59 o 3 3 1 1568.14 1495.52 16.11 o 4 3 1 263.22 275.65 6.28 o 5 3 1 1201.08 1119.50 11.70 o 6 3 1 403.25 383.24 9.42 o 7 3 1 341.69 341.54 9.88 o 8 3 1 9.32 7.47 6.61 o 9 3 1 189.57 180.74 10.29 o 10 3 1 74.87 78.71 10.71 o 11 3 1 388.68 381.43 17.44 o 12 3 1 47.72 45.92 16.68 o 13 3 1 197.12 181.91 18.08 o 14 3 1 1.93 -5.20 12.18 o 15 3 1 38.45 41.63 21.48 o -14 4 1 37.63 33.49 22.15 o -13 4 1 153.69 172.54 28.02 o -12 4 1 6.85 18.42 14.04 o -11 4 1 441.02 442.64 39.57 o -10 4 1 135.81 129.04 22.42 o -9 4 1 14.86 12.28 16.28 o -8 4 1 147.09 158.96 11.19 o -7 4 1 441.74 405.29 14.28 o -6 4 1 194.30 211.83 11.37 o -5 4 1 1842.82 1914.54 21.84 o -4 4 1 27.64 19.20 7.25 o -3 4 1 177.13 166.19 9.69 o -2 4 1 560.70 572.58 14.58 o -1 4 1 505.24 503.05 13.74 o 0 4 1 232.93 209.09 8.75 o 1 4 1 879.29 884.48 15.22 o 2 4 1 26.44 25.88 6.29 o 3 4 1 845.70 828.68 14.59 o 4 4 1 179.06 176.32 8.38 o 5 4 1 133.39 124.07 7.76 o 6 4 1 53.76 59.13 12.04 o 7 4 1 235.40 219.82 16.25 o 8 4 1 236.24 224.68 13.94 o 9 4 1 114.11 119.74 11.93 o 10 4 1 28.86 30.23 10.57 o 11 4 1 31.20 35.34 10.78 o 12 4 1 78.90 88.65 16.32 o 14 4 1 3.47 -6.00 20.68 o -13 5 1 236.66 262.59 24.09 o -12 5 1 44.40 46.27 24.69 o -11 5 1 615.99 630.10 31.13 o -10 5 1 10.23 16.63 13.82 o -9 5 1 1185.47 1168.64 65.25 o -8 5 1 80.43 58.73 13.44 o -7 5 1 1093.47 1095.59 44.64 o -6 5 1 45.37 41.15 9.34 o -5 5 1 2163.80 2131.27 26.66 o -4 5 1 36.83 25.02 7.31 o -3 5 1 2077.70 2095.10 26.45 o -2 5 1 332.60 333.76 12.64 o -1 5 1 4239.26 4177.37 40.64 o 0 5 1 1.00 8.21 7.38 o 1 5 1 1862.94 1906.58 24.94 o 2 5 1 179.92 177.82 10.08 o 3 5 1 3941.26 3922.30 35.39 o 4 5 1 3.55 5.39 8.24 o 5 5 1 1409.38 1427.97 35.83 o 6 5 1 149.68 152.90 26.62 o 7 5 1 1903.62 1850.75 43.59 o 8 5 1 1.30 -0.17 12.26 o 9 5 1 1065.80 1026.77 35.05 o 10 5 1 0.26 5.90 12.54 o 11 5 1 756.74 740.35 32.59 o 12 5 1 17.60 10.53 14.09 o 13 5 1 312.65 309.99 35.63 o -12 6 1 142.80 136.55 20.36 o -11 6 1 8.93 -4.50 14.41 o -10 6 1 610.67 680.98 33.57 o -9 6 1 79.62 84.72 17.08 o -8 6 1 1066.88 1001.98 35.95 o -7 6 1 229.34 236.75 20.36 o -6 6 1 1190.09 1208.03 36.95 o -5 6 1 174.41 165.57 30.76 o -4 6 1 1235.49 1219.37 22.81 o -3 6 1 13.48 19.38 7.91 o -2 6 1 1654.48 1631.61 26.08 o -1 6 1 299.12 295.07 12.74 o 0 6 1 3364.75 3395.02 36.84 o 1 6 1 384.99 364.51 13.75 o 2 6 1 1593.29 1574.11 29.90 o 3 6 1 2.59 0.10 8.89 o 4 6 1 1226.82 1261.27 36.14 o 5 6 1 36.99 44.43 14.05 o 6 6 1 1345.73 1258.25 37.86 o 7 6 1 141.26 135.87 17.14 o 8 6 1 1111.58 1119.55 38.48 o 9 6 1 7.61 16.97 13.77 o 10 6 1 519.04 513.94 52.51 o 11 6 1 0.10 3.36 15.51 o 12 6 1 283.71 306.11 31.76 o -10 7 1 91.47 112.36 28.02 o -9 7 1 22.78 31.39 16.37 o -8 7 1 131.78 129.35 29.62 o -7 7 1 27.01 28.25 15.74 o -6 7 1 44.36 29.25 15.47 o -5 7 1 0.71 -8.01 12.58 o -4 7 1 42.09 53.30 27.29 o -3 7 1 40.64 42.63 10.54 o -2 7 1 217.71 221.63 15.54 o -1 7 1 84.53 80.19 10.56 o 0 7 1 76.80 62.72 11.96 o 1 7 1 7.60 3.55 9.93 o 2 7 1 47.27 49.39 16.58 o 3 7 1 65.69 64.91 15.40 o 4 7 1 34.19 39.78 14.63 o 5 7 1 0.64 -2.26 13.17 o 6 7 1 57.62 59.09 16.13 o 7 7 1 34.24 33.09 16.18 o 8 7 1 11.58 12.63 15.60 o 9 7 1 29.57 36.30 16.24 o 10 7 1 12.99 23.35 16.65 o -8 8 1 144.79 148.51 21.56 o -7 8 1 3.66 2.69 15.70 o -6 8 1 278.54 279.69 28.89 o -5 8 1 50.63 52.21 27.69 o -4 8 1 235.77 265.40 23.23 o -3 8 1 2.81 -14.28 20.28 o -2 8 1 460.51 454.77 26.77 o -1 8 1 37.25 41.82 15.81 o 0 8 1 269.29 263.50 22.43 o 1 8 1 10.04 12.04 11.82 o 2 8 1 240.66 292.92 23.49 o 3 8 1 39.83 59.55 17.31 o 4 8 1 439.11 457.19 49.71 o 5 8 1 11.40 13.27 15.07 o 6 8 1 228.09 235.31 24.17 o 7 8 1 0.64 9.47 16.98 o 8 8 1 143.96 137.89 22.20 o -4 9 1 0.41 -0.93 24.15 o -3 9 1 353.30 326.53 39.23 o -2 9 1 2.22 -1.47 24.29 o 0 9 1 17.72 18.23 15.62 o 1 9 1 272.46 263.82 34.70 o 2 9 1 2.30 18.82 24.55 o 3 9 1 697.00 768.23 55.11 o 4 9 1 1.72 20.02 25.09 o -16 0 2 271.61 241.26 30.83 o -14 0 2 512.18 547.38 38.30 o -12 0 2 307.05 342.41 28.82 o -10 0 2 1661.36 1694.33 65.39 o -8 0 2 4905.68 5130.58 53.05 o -6 0 2 3763.94 4055.91 49.44 o -4 0 2 3684.95 3518.42 25.24 o -2 0 2 20638.35 21208.71 118.43 o 0 0 2 10328.67 10702.08 72.34 o 2 0 2 24275.46 21873.13 187.57 o 4 0 2 1861.53 1615.56 19.27 o 6 0 2 9024.14 9072.89 50.56 o 8 0 2 4432.55 4353.60 50.59 o 10 0 2 3174.45 3118.64 107.15 o 12 0 2 600.21 607.41 24.85 o 14 0 2 521.36 519.94 25.91 o -16 1 2 125.40 103.38 23.75 o -15 1 2 225.25 229.58 20.52 o -14 1 2 198.44 180.20 18.44 o -13 1 2 51.87 38.91 12.51 o -12 1 2 346.88 341.71 27.09 o -11 1 2 598.98 594.97 36.03 o -10 1 2 523.73 521.82 14.17 o -9 1 2 939.22 925.44 17.06 o -8 1 2 1358.76 1344.09 22.81 o -7 1 2 2997.58 2994.05 25.58 o -6 1 2 1546.07 1602.93 17.42 o -5 1 2 352.85 318.55 9.73 o -4 1 2 675.05 693.89 13.16 o -3 1 2 1093.76 1130.37 12.73 o -2 1 2 7034.14 7801.58 73.22 o -1 1 2 12922.66 12849.71 127.38 o 0 1 2 1229.37 1382.49 10.67 o 1 1 2 3122.03 3348.43 28.21 o 2 1 2 2928.43 2856.26 38.26 o 3 1 2 1775.08 1601.06 28.97 o 4 1 2 1090.98 1111.61 12.55 o 5 1 2 423.09 393.71 8.81 o 6 1 2 1571.30 1637.26 18.42 o 7 1 2 3915.53 3868.51 80.09 o 8 1 2 648.75 627.49 12.38 o 9 1 2 918.02 918.54 15.57 o 10 1 2 227.47 234.93 11.02 o 11 1 2 353.62 337.62 13.28 o 12 1 2 270.11 253.77 12.71 o 13 1 2 211.97 185.68 14.15 o 14 1 2 89.85 81.76 11.98 o 15 1 2 278.72 274.49 30.56 o -16 2 2 0.37 5.47 21.48 o -15 2 2 255.23 241.00 30.69 o -14 2 2 14.77 14.74 12.88 o -13 2 2 214.62 196.36 18.72 o -12 2 2 32.13 25.07 11.59 o -11 2 2 693.73 676.70 25.82 o -10 2 2 135.89 134.73 14.00 o -9 2 2 548.50 566.91 17.09 o -8 2 2 0.99 6.82 7.19 o -7 2 2 880.22 868.91 14.29 o -6 2 2 50.16 48.07 5.47 o -5 2 2 2382.74 2503.94 32.24 o -4 2 2 2120.78 2368.10 27.90 o -3 2 2 1846.29 1685.18 15.89 o -2 2 2 1449.80 1457.03 16.35 o -1 2 2 1864.35 1676.00 16.92 o 0 2 2 766.94 837.86 13.91 o 1 2 2 1706.31 1569.77 15.74 o 2 2 2 388.46 385.11 7.14 o 3 2 2 1293.71 1242.30 14.03 o 4 2 2 4772.71 5182.22 39.87 o 5 2 2 1887.35 1880.54 34.19 o 6 2 2 23.33 27.05 5.61 o 7 2 2 249.23 250.69 9.61 o 8 2 2 15.89 11.47 6.43 o 9 2 2 585.69 599.84 14.86 o 10 2 2 285.97 283.99 11.75 o 11 2 2 274.57 259.31 14.60 o 12 2 2 180.94 161.88 13.46 o 13 2 2 149.58 151.52 13.50 o 14 2 2 3.29 -3.82 11.97 o 15 2 2 49.58 54.94 14.76 o -15 3 2 115.56 126.50 27.09 o -14 3 2 50.26 48.71 21.88 o -13 3 2 370.56 389.92 35.36 o -12 3 2 142.95 119.41 15.35 o -11 3 2 1087.41 1161.16 40.37 o -10 3 2 237.66 234.39 20.22 o -9 3 2 570.62 600.85 20.56 o -8 3 2 265.22 256.77 10.75 o -7 3 2 1031.00 1044.67 21.03 o -6 3 2 779.02 796.29 14.06 o -5 3 2 4308.45 4270.58 31.13 o -4 3 2 448.32 437.46 11.17 o -3 3 2 4055.07 4080.68 33.15 o -2 3 2 1994.45 2094.90 23.03 o -1 3 2 2832.02 2903.58 32.77 o 0 3 2 184.66 178.25 7.91 o 1 3 2 1060.57 1031.33 17.34 o 2 3 2 1760.05 1828.46 30.02 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