#------------------------------------------------------------------------------ #$Date: 2016-04-03 00:05:03 +0300 (Sun, 03 Apr 2016) $ #$Revision: 180956 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/36/2203612.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2203612_Fobs loop_ _publ_author_name 'Zhang, Zhu-Yan' 'Gao, Shan' 'Huo, Li-Hua' 'Zhao, Hui' 'Zhao, Jing-Gui' 'Ng, Seik Weng' _publ_section_title ; Hexaaquanickel(II) bis[(4-oxo-4H-pyridin-1-yl)acetate] dihydrate ; _journal_issue 5 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m544 _journal_page_last m545 _journal_volume 60 _journal_year 2004 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 98.425 _cell_angle_gamma 90.000 _cell_length_a 12.3872 _cell_length_b 12.8165 _cell_length_c 6.7661 _exptl_crystal_F_000 532.00 _reflns_d_resolution_high 0.7701 _cod_data_source_file hg6034Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' z in P2(1)/c' _shelx_refln_list_code 4 _shelx_f_calc_maximum 127.35 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 2612.32 2276.24 23.29 o 3 0 0 2076.81 1925.79 5.67 o 4 0 0 12850.13 9344.34 115.66 o 5 0 0 12882.36 9712.57 13.46 o 6 0 0 11.13 32.80 1.18 o 7 0 0 5526.36 5125.69 34.60 o 8 0 0 1869.36 1748.66 3.58 o 9 0 0 997.02 979.29 24.82 o 10 0 0 734.17 728.96 24.20 o 11 0 0 2482.75 2328.64 52.53 o 12 0 0 102.13 119.83 2.60 o 13 0 0 264.19 260.66 3.75 o 14 0 0 32.10 40.02 4.31 o 15 0 0 70.31 66.23 3.17 o 2 1 0 354.28 377.22 5.06 o 3 1 0 10.13 12.77 0.73 o 4 1 0 11.04 5.81 0.71 o 5 1 0 45.27 49.34 0.90 o 6 1 0 208.41 188.17 1.02 o 7 1 0 1612.56 1673.17 11.73 o 8 1 0 145.00 168.28 1.51 o 9 1 0 34.77 25.05 1.18 o 10 1 0 77.40 68.35 1.56 o 11 1 0 184.73 179.82 2.53 o 12 1 0 66.85 60.18 1.75 o 13 1 0 39.94 41.16 3.08 o 14 1 0 52.18 55.84 2.01 o 15 1 0 69.64 68.17 2.21 o 0 2 0 1273.61 1278.56 10.07 o 1 2 0 1997.64 2007.24 22.11 o 2 2 0 7077.25 5872.05 77.46 o 3 2 0 2893.24 2732.07 5.94 o 4 2 0 634.47 620.75 5.03 o 5 2 0 3156.15 2980.60 43.26 o 6 2 0 5419.77 4932.96 48.57 o 7 2 0 3046.00 2834.19 15.46 o 8 2 0 284.85 275.32 3.20 o 9 2 0 21.88 18.00 1.12 o 10 2 0 96.20 100.68 3.22 o 11 2 0 330.43 339.13 3.88 o 12 2 0 427.57 427.18 4.98 o 13 2 0 475.80 455.50 7.99 o 14 2 0 174.07 163.09 2.47 o 15 2 0 31.38 33.47 3.48 o 1 3 0 818.63 907.32 10.19 o 2 3 0 565.32 546.60 2.67 o 3 3 0 8.00 7.64 0.44 o 4 3 0 1197.73 1252.72 22.88 o 5 3 0 1011.13 1087.08 9.93 o 6 3 0 0.03 1.57 0.69 o 7 3 0 48.41 53.83 0.88 o 8 3 0 16.86 13.63 0.95 o 9 3 0 19.68 17.60 1.08 o 10 3 0 66.80 70.86 1.42 o 11 3 0 352.69 336.03 6.89 o 12 3 0 96.02 90.56 1.88 o 13 3 0 13.91 12.21 1.72 o 14 3 0 3.02 5.70 1.83 o 15 3 0 21.44 24.07 2.18 o 0 4 0 7460.10 6591.87 116.53 o 1 4 0 15669.97 12540.15 171.67 o 2 4 0 226.92 208.49 0.97 o 3 4 0 103.08 128.10 3.29 o 4 4 0 185.01 158.61 2.77 o 5 4 0 110.38 91.14 1.00 o 6 4 0 3904.70 3890.61 31.50 o 7 4 0 3.44 5.96 0.84 o 8 4 0 475.82 476.43 4.54 o 9 4 0 358.82 353.16 3.95 o 10 4 0 337.31 330.83 7.14 o 11 4 0 60.70 63.30 1.44 o 12 4 0 1150.82 1096.93 22.36 o 13 4 0 78.26 83.09 2.41 o 14 4 0 94.26 91.90 1.93 o 15 4 0 63.85 70.02 2.32 o 1 5 0 1994.66 2106.14 23.70 o 2 5 0 108.28 112.71 1.27 o 3 5 0 998.86 973.40 6.65 o 4 5 0 366.62 383.14 13.99 o 5 5 0 59.27 57.90 0.82 o 6 5 0 14.94 19.20 0.70 o 7 5 0 8.43 10.91 1.01 o 8 5 0 19.39 16.12 0.77 o 9 5 0 8.61 9.48 0.95 o 10 5 0 47.24 46.24 1.13 o 11 5 0 12.00 13.91 1.48 o 12 5 0 6.15 5.63 1.46 o 13 5 0 0.26 1.24 1.55 o 14 5 0 7.80 13.02 1.65 o 15 5 0 4.42 4.19 1.86 o 0 6 0 1858.63 1930.05 20.89 o 1 6 0 4158.18 4081.78 25.56 o 2 6 0 611.73 570.84 3.91 o 3 6 0 73.52 53.41 0.79 o 4 6 0 877.07 854.73 9.30 o 5 6 0 1673.18 1680.30 26.03 o 6 6 0 2040.79 1970.38 23.29 o 7 6 0 376.92 371.24 5.65 o 8 6 0 453.10 471.06 5.16 o 9 6 0 834.06 874.39 12.78 o 10 6 0 682.68 690.43 5.34 o 11 6 0 290.15 287.47 2.94 o 12 6 0 501.01 483.69 7.74 o 13 6 0 325.67 334.22 6.21 o 14 6 0 177.94 177.47 4.17 o 1 7 0 53.23 52.74 1.01 o 2 7 0 216.07 233.00 3.66 o 3 7 0 42.32 45.22 1.06 o 4 7 0 67.79 53.80 1.61 o 5 7 0 125.45 128.50 1.86 o 6 7 0 374.21 410.23 19.42 o 7 7 0 3.87 6.10 0.96 o 8 7 0 23.20 24.21 0.90 o 9 7 0 55.30 52.55 2.43 o 10 7 0 59.84 55.89 2.55 o 11 7 0 0.06 -0.25 1.14 o 12 7 0 0.90 1.89 1.08 o 13 7 0 7.67 9.13 1.23 o 14 7 0 7.04 8.58 1.97 o 0 8 0 4255.65 4233.35 70.36 o 1 8 0 189.96 219.83 2.92 o 2 8 0 1812.61 1816.92 20.56 o 3 8 0 1305.70 1303.05 17.15 o 4 8 0 428.17 411.79 4.14 o 5 8 0 1541.58 1495.62 31.73 o 6 8 0 638.52 581.61 7.83 o 7 8 0 2278.01 2251.99 20.49 o 8 8 0 343.13 329.09 7.68 o 9 8 0 29.67 35.88 1.99 o 10 8 0 164.94 155.76 5.05 o 11 8 0 617.12 578.10 26.39 o 12 8 0 114.16 104.13 6.44 o 13 8 0 505.02 497.54 12.65 o 1 9 0 394.84 369.18 4.05 o 2 9 0 1.08 1.95 0.89 o 3 9 0 41.89 40.18 1.20 o 4 9 0 111.37 106.82 3.06 o 5 9 0 387.48 361.00 3.06 o 6 9 0 24.14 22.26 1.69 o 7 9 0 149.87 140.23 2.30 o 8 9 0 106.77 102.36 2.22 o 9 9 0 35.69 36.19 2.31 o 10 9 0 4.22 4.39 1.13 o 11 9 0 130.76 146.27 8.97 o 12 9 0 60.03 64.08 6.01 o 13 9 0 10.07 13.22 5.05 o 0 10 0 2952.97 2900.31 6.19 o 1 10 0 220.61 199.92 3.88 o 2 10 0 10.83 12.44 0.93 o 3 10 0 144.95 138.93 3.10 o 4 10 0 169.38 158.02 3.75 o 5 10 0 137.57 135.28 2.93 o 6 10 0 5.48 8.08 1.58 o 7 10 0 386.22 405.44 5.35 o 8 10 0 357.27 353.14 9.59 o 9 10 0 77.72 78.57 2.86 o 10 10 0 208.28 216.55 4.73 o 11 10 0 576.19 610.70 12.27 o 12 10 0 142.71 151.83 6.43 o 1 11 0 773.50 747.12 9.72 o 2 11 0 304.52 293.52 7.50 o 3 11 0 4.29 3.51 1.23 o 4 11 0 41.46 40.13 1.59 o 5 11 0 69.49 63.34 2.66 o 6 11 0 83.86 75.21 1.99 o 7 11 0 4.01 5.97 2.08 o 8 11 0 0.39 3.22 2.18 o 9 11 0 56.14 54.06 2.50 o 10 11 0 0.25 1.63 2.68 o 11 11 0 0.00 -0.09 3.61 o 0 12 0 97.44 95.95 4.96 o 1 12 0 932.54 932.41 13.98 o 2 12 0 431.26 426.39 7.32 o 3 12 0 229.02 218.47 5.33 o 4 12 0 361.93 365.46 5.53 o 5 12 0 293.93 289.86 5.58 o 6 12 0 866.08 853.73 15.70 o 7 12 0 95.04 89.97 2.06 o 8 12 0 67.76 76.92 2.20 o 9 12 0 251.32 257.27 2.69 o 10 12 0 51.63 51.07 2.96 o 11 12 0 14.54 12.95 3.08 o 1 13 0 10.78 12.77 1.29 o 2 13 0 3.54 5.61 1.32 o 3 13 0 59.70 56.22 1.70 o 4 13 0 10.64 15.70 1.37 o 5 13 0 15.26 13.65 2.31 o 6 13 0 5.00 4.93 1.94 o 7 13 0 100.03 94.95 3.27 o 8 13 0 103.91 99.00 3.02 o 9 13 0 93.45 96.79 2.58 o 0 14 0 380.28 359.32 14.60 o 1 14 0 852.35 806.70 21.36 o 2 14 0 394.99 392.96 8.01 o 3 14 0 257.64 255.79 4.53 o 4 14 0 616.77 607.94 8.22 o 5 14 0 324.70 321.66 7.93 o 6 14 0 357.60 351.53 4.38 o 7 14 0 151.11 145.37 2.28 o 8 14 0 155.23 159.04 2.96 o 1 15 0 72.71 74.25 4.90 o 2 15 0 9.71 11.14 1.13 o 3 15 0 41.77 43.56 2.25 o 4 15 0 29.18 29.13 1.78 o 5 15 0 5.79 7.54 1.73 o 6 15 0 1.78 3.07 1.96 o 0 16 0 248.89 259.75 6.84 o 1 16 0 77.77 94.17 10.16 o 2 16 0 371.01 371.99 28.47 o 3 16 0 266.08 295.57 8.13 o 4 16 0 23.05 24.55 1.55 o -15 1 1 119.23 110.08 2.51 o -14 1 1 234.94 224.22 3.56 o -13 1 1 316.69 297.85 4.71 o -12 1 1 861.04 833.18 2.69 o -11 1 1 237.55 251.99 3.61 o -10 1 1 32.82 32.09 1.47 o -9 1 1 223.75 208.44 1.46 o -8 1 1 1286.73 1302.44 7.57 o -7 1 1 2022.13 2123.94 9.66 o -6 1 1 2498.95 2561.96 31.37 o -5 1 1 1117.55 1160.27 5.42 o -4 1 1 1657.75 1809.51 26.65 o -3 1 1 427.08 459.35 3.59 o -2 1 1 2151.85 2451.80 50.27 o -1 1 1 8257.62 8108.75 84.13 o 0 1 1 546.50 581.89 8.83 o 1 1 1 8283.95 7383.33 298.86 o 2 1 1 4167.87 3613.07 44.19 o 3 1 1 1167.73 1078.28 9.00 o 4 1 1 2087.77 1797.50 18.84 o 5 1 1 5181.57 4393.41 42.85 o 6 1 1 7684.85 6587.58 77.63 o 7 1 1 1706.42 1521.17 11.22 o 8 1 1 91.51 90.90 1.63 o 9 1 1 1122.13 1083.71 5.87 o 10 1 1 495.43 507.41 5.18 o 11 1 1 580.37 563.44 11.57 o 12 1 1 866.11 827.91 8.36 o 13 1 1 382.01 366.82 6.04 o 14 1 1 156.77 156.57 4.50 o 15 1 1 22.99 22.92 2.22 o -15 2 1 3.26 0.64 2.01 o -14 2 1 0.02 0.54 1.84 o -13 2 1 1.95 1.29 2.00 o -12 2 1 343.51 304.80 2.69 o -11 2 1 306.15 269.86 2.96 o -10 2 1 15.45 15.70 1.31 o -9 2 1 11.24 14.88 1.16 o -8 2 1 24.15 27.93 1.22 o -7 2 1 2052.67 2228.75 22.51 o -6 2 1 665.32 838.64 3.79 o -5 2 1 1.03 1.50 0.79 o -4 2 1 318.87 350.72 4.04 o -3 2 1 6.95 13.70 0.48 o -2 2 1 176.50 174.38 2.56 o -1 2 1 3506.27 3807.30 43.33 o 0 2 1 5352.23 5397.03 29.56 o 1 2 1 2763.58 2689.83 61.38 o 2 2 1 350.47 376.38 5.72 o 3 2 1 4049.91 3607.65 17.37 o 4 2 1 4.16 2.33 0.58 o 5 2 1 28.63 30.49 0.70 o 6 2 1 0.41 1.70 0.81 o 7 2 1 188.42 175.75 1.75 o 8 2 1 78.19 66.41 1.13 o 9 2 1 266.89 248.27 1.49 o 10 2 1 380.61 373.84 6.14 o 11 2 1 326.16 305.49 3.03 o 12 2 1 11.29 13.52 2.33 o 13 2 1 55.05 50.98 1.89 o 14 2 1 5.75 5.61 1.97 o 15 2 1 24.94 31.78 2.23 o -15 3 1 33.62 33.81 1.99 o -14 3 1 111.44 116.91 2.46 o -13 3 1 200.68 193.69 2.46 o -12 3 1 31.79 35.86 2.23 o -11 3 1 639.57 610.41 4.99 o -10 3 1 900.62 872.60 7.32 o -9 3 1 167.61 171.46 2.29 o -8 3 1 144.84 133.85 2.76 o -7 3 1 642.11 686.93 5.13 o -6 3 1 1579.65 1597.12 21.68 o -5 3 1 693.98 639.74 7.33 o -4 3 1 1294.10 1557.99 36.92 o -3 3 1 354.75 364.95 5.26 o -2 3 1 3357.95 3694.55 77.28 o -1 3 1 2711.98 2946.62 40.88 o 0 3 1 16217.80 13606.51 145.72 o 1 3 1 149.95 158.93 2.85 o 2 3 1 4.42 6.91 0.92 o 3 3 1 12.85 9.29 0.61 o 4 3 1 1605.68 1486.57 11.02 o 5 3 1 2894.63 2610.95 21.62 o 6 3 1 369.37 318.25 2.17 o 7 3 1 696.89 700.32 3.65 o 8 3 1 1289.47 1231.96 22.90 o 9 3 1 944.94 899.59 10.32 o 10 3 1 1001.19 948.13 4.65 o 11 3 1 822.55 801.20 6.00 o 12 3 1 341.66 337.59 4.30 o 13 3 1 354.57 343.18 5.48 o 14 3 1 127.90 125.50 2.28 o 15 3 1 82.61 84.70 2.24 o -15 4 1 52.50 52.77 1.91 o -14 4 1 38.90 40.03 1.78 o -13 4 1 21.94 23.89 1.62 o -12 4 1 25.35 26.03 1.51 o -11 4 1 130.64 127.38 2.18 o -10 4 1 14.76 15.89 1.98 o -9 4 1 215.52 208.97 2.16 o -8 4 1 27.73 31.13 1.16 o -7 4 1 10.48 10.29 0.79 o -6 4 1 1014.84 1081.99 15.68 o -5 4 1 666.53 717.41 7.50 o -4 4 1 42.28 51.76 0.59 o -3 4 1 148.24 182.85 3.37 o -2 4 1 243.20 243.34 2.47 o -1 4 1 3128.93 3363.68 45.25 o 0 4 1 104.19 110.32 1.67 o 1 4 1 3039.34 3055.56 21.88 o 2 4 1 6579.82 5952.54 127.50 o 3 4 1 3085.43 3147.58 25.50 o 4 4 1 19.65 13.43 0.61 o 5 4 1 212.77 216.71 4.30 o 6 4 1 670.52 672.83 2.91 o 7 4 1 135.58 136.44 1.48 o 8 4 1 45.27 39.23 1.03 o 9 4 1 202.15 190.95 1.37 o 10 4 1 122.70 119.85 1.80 o 11 4 1 43.39 49.54 1.71 o 12 4 1 20.32 21.76 1.56 o 13 4 1 1.87 2.51 1.82 o 14 4 1 2.83 2.69 2.18 o 15 4 1 0.18 3.21 2.03 o -15 5 1 53.96 54.61 1.84 o -14 5 1 92.54 88.11 1.85 o -13 5 1 700.75 687.42 8.17 o -12 5 1 586.29 591.92 2.17 o -11 5 1 110.95 105.25 1.37 o -10 5 1 5.52 4.83 1.07 o -9 5 1 130.90 138.92 1.40 o -8 5 1 2270.39 2295.80 26.34 o -7 5 1 2139.30 2254.83 44.98 o -6 5 1 1000.85 1003.57 17.11 o -5 5 1 2056.34 2199.36 59.51 o -4 5 1 2850.18 3171.90 110.78 o -3 5 1 3244.13 3108.63 34.00 o -2 5 1 77.87 58.48 1.01 o -1 5 1 285.40 226.84 6.90 o 0 5 1 4603.85 4555.81 45.65 o 1 5 1 350.18 287.10 4.30 o 2 5 1 113.79 95.89 2.00 o 3 5 1 2592.97 2559.77 32.59 o 4 5 1 2247.18 2176.14 23.26 o 5 5 1 1208.92 1139.46 11.33 o 6 5 1 849.14 771.88 2.87 o 7 5 1 2165.67 2121.47 15.22 o 8 5 1 914.53 874.14 11.78 o 9 5 1 654.43 627.11 9.55 o 10 5 1 98.40 105.46 2.47 o 11 5 1 902.32 906.17 11.86 o 12 5 1 485.06 499.62 6.78 o 13 5 1 90.82 89.59 2.51 o 14 5 1 51.65 48.43 2.51 o -14 6 1 20.68 16.17 1.82 o -13 6 1 3.35 7.15 1.32 o -12 6 1 26.87 22.91 1.27 o -11 6 1 812.07 781.28 6.44 o -10 6 1 27.88 28.32 1.58 o -9 6 1 739.86 743.05 14.07 o -8 6 1 183.28 186.61 3.73 o -7 6 1 730.51 786.34 12.60 o -6 6 1 184.12 211.82 3.71 o -5 6 1 72.51 82.81 1.71 o -4 6 1 611.16 610.76 4.73 o -3 6 1 1668.29 1692.63 23.67 o -2 6 1 382.25 372.07 4.75 o -1 6 1 277.32 319.19 4.72 o 0 6 1 5028.14 5230.77 55.13 o 1 6 1 8.02 8.68 0.54 o 2 6 1 119.14 126.49 1.87 o 3 6 1 432.80 413.56 4.06 o 4 6 1 156.73 147.66 3.10 o 5 6 1 321.60 337.86 4.78 o 6 6 1 11.54 7.82 1.25 o 7 6 1 448.37 462.92 7.54 o 8 6 1 1394.14 1297.34 27.45 o 9 6 1 6.32 6.82 1.19 o 10 6 1 3.88 3.95 1.39 o 11 6 1 77.02 81.96 3.82 o 12 6 1 1.32 -1.56 1.64 o 13 6 1 63.51 74.78 4.20 o 14 6 1 5.55 6.09 2.02 o -14 7 1 268.75 280.68 14.15 o -13 7 1 192.48 187.98 3.37 o -12 7 1 681.89 691.28 7.19 o -11 7 1 817.92 835.41 11.46 o -10 7 1 1355.63 1436.00 12.16 o -9 7 1 716.29 742.98 9.85 o -8 7 1 1362.21 1432.76 7.18 o -7 7 1 1134.18 1186.81 16.26 o -6 7 1 3351.14 3382.88 52.02 o -5 7 1 1311.31 1310.81 24.75 o -4 7 1 921.34 869.10 12.88 o -3 7 1 2046.84 2022.73 28.27 o -2 7 1 2080.12 2113.22 11.25 o -1 7 1 7886.90 7636.91 77.75 o 0 7 1 1144.13 1105.03 7.20 o 1 7 1 5031.22 4958.25 65.71 o 2 7 1 831.47 835.05 7.41 o 3 7 1 102.07 85.25 1.09 o 4 7 1 117.66 104.65 1.22 o 5 7 1 872.66 851.10 11.20 o 6 7 1 1495.55 1467.24 7.87 o 7 7 1 16.90 17.10 1.06 o 8 7 1 53.23 52.17 1.37 o 9 7 1 469.66 472.64 6.67 o 10 7 1 665.95 679.44 12.70 o 11 7 1 48.73 48.37 3.86 o 12 7 1 70.14 66.72 2.79 o 13 7 1 80.37 83.85 2.55 o -14 8 1 2.19 8.06 3.86 o -13 8 1 15.82 15.71 3.75 o -12 8 1 35.18 30.85 3.69 o -11 8 1 0.01 1.23 1.03 o -10 8 1 21.42 18.00 1.19 o -9 8 1 46.52 43.49 1.24 o -8 8 1 1.50 2.44 1.14 o -7 8 1 27.89 25.25 1.95 o -6 8 1 120.87 107.24 1.85 o -5 8 1 227.93 224.13 3.75 o -4 8 1 28.35 24.13 1.10 o -3 8 1 628.88 659.17 8.80 o -2 8 1 725.63 747.66 10.38 o -1 8 1 1228.95 1229.14 5.68 o 0 8 1 570.73 567.89 3.51 o 1 8 1 50.22 49.36 1.07 o 2 8 1 0.08 1.03 0.52 o 3 8 1 156.72 152.82 1.78 o 4 8 1 450.74 476.94 9.96 o 5 8 1 45.95 49.30 0.85 o 6 8 1 60.08 65.74 1.82 o 7 8 1 0.15 1.71 0.43 o 8 8 1 250.15 246.60 2.86 o 9 8 1 21.32 20.28 0.88 o 10 8 1 45.91 49.20 1.39 o 11 8 1 28.19 26.24 1.89 o 12 8 1 45.62 41.59 4.21 o 13 8 1 0.08 0.60 3.23 o -13 9 1 157.16 170.45 7.95 o -12 9 1 386.72 363.34 3.71 o -11 9 1 212.19 201.06 16.22 o -10 9 1 101.54 103.14 6.11 o -9 9 1 473.92 513.87 9.97 o -8 9 1 444.71 454.01 8.90 o -7 9 1 690.46 645.94 13.68 o 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