#------------------------------------------------------------------------------ #$Date: 2011-09-28 17:24:46 +0300 (Wed, 28 Sep 2011) $ #$Revision: 26848 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/20/87/2208770.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2208770_Fobs loop_ _publ_author_name 'Harrison, William T. A.' 'Gaonkar, S. L.' 'Anilkumar, H. G.' 'Yathirajan, H. S.' _publ_section_title ; 5-Bromo-1-(4-fluorophenyl)-1,3-dihydroisobenzofuran ; _journal_coeditor_code XU2018 _journal_issue 4 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first o1534 _journal_page_last o1535 _journal_volume 62 _journal_year 2006 _space_group_IT_number 14 _symmetry_space_group_name_Hall '-P 2ybc' _symmetry_space_group_name_H-M 'P 1 21/c 1' _cell_angle_alpha 90.000 _cell_angle_beta 92.542 _cell_angle_gamma 90.000 _cell_length_a 6.0560 _cell_length_b 7.8659 _cell_length_c 24.2289 _exptl_crystal_F_000 584.00 _reflns_d_resolution_high 0.7683 _[local]_cod_data_source_file xu2018Isup2.hkl _[local]_cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' HSY13 SOTON DATA' _shelx_refln_list_code 4 _shelx_f_calc_maximum 197.23 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y-1/2, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 1 0 0 71.47 7.16 8.95 o 2 0 0 2257.04 2181.34 45.30 o 3 0 0 563.44 679.51 150.53 o 4 0 0 1069.10 1041.84 34.95 o 5 0 0 2214.53 2277.96 80.86 o 6 0 0 484.92 451.28 56.52 o 7 0 0 63.75 153.43 93.44 o 1 1 0 24112.72 23596.72 294.92 o 2 1 0 5187.71 5040.83 66.42 o 3 1 0 291.59 356.57 10.60 o 4 1 0 1711.12 1731.12 34.58 o 5 1 0 1302.76 1322.96 48.51 o 6 1 0 283.48 291.22 30.19 o 7 1 0 269.46 258.07 53.11 o 0 2 0 7704.17 7278.02 208.34 o 1 2 0 2361.16 2371.81 413.28 o 2 2 0 1895.01 1918.28 87.12 o 3 2 0 2924.22 3002.53 43.01 o 4 2 0 550.40 559.82 20.48 o 5 2 0 663.53 635.48 25.88 o 6 2 0 210.98 209.35 29.62 o 7 2 0 3.08 -17.51 40.25 o 1 3 0 10.13 6.60 4.50 o 3 3 0 202.89 189.80 10.76 o 4 3 0 5.61 6.71 12.52 o 5 3 0 37.34 11.16 18.50 o 6 3 0 20.27 62.17 30.31 o 7 3 0 13.93 28.07 46.06 o 0 4 0 4404.17 4514.83 136.06 o 1 4 0 976.15 998.74 22.42 o 2 4 0 325.52 317.28 13.41 o 3 4 0 309.41 305.39 14.52 o 4 4 0 9.13 24.03 20.42 o 5 4 0 155.62 156.66 24.26 o 6 4 0 179.88 140.22 41.28 o 7 4 0 3.28 -19.13 71.79 o 1 5 0 4793.39 4818.63 99.12 o 2 5 0 901.94 943.26 27.48 o 3 5 0 10.19 -1.05 10.70 o 4 5 0 2080.19 2094.32 83.90 o 5 5 0 179.40 175.88 32.76 o 6 5 0 78.99 48.86 56.40 o 0 6 0 4035.88 4014.45 194.85 o 1 6 0 11.75 35.91 18.63 o 2 6 0 4164.08 4245.07 109.62 o 3 6 0 1854.02 2085.10 87.91 o 4 6 0 156.89 169.96 32.81 o 5 6 0 413.20 373.51 45.91 o 6 6 0 553.62 829.50 153.77 o 1 7 0 4519.02 4431.14 139.34 o 2 7 0 26.68 93.52 49.99 o 3 7 0 1.72 29.49 32.33 o 4 7 0 1085.00 1161.24 59.08 o 5 7 0 246.68 232.94 45.19 o 0 8 0 1499.25 1367.32 173.12 o 1 8 0 212.13 164.72 51.97 o 2 8 0 59.89 95.19 33.07 o 3 8 0 220.46 321.12 62.73 o 4 8 0 178.94 194.12 37.52 o 1 9 0 63.27 -19.81 112.07 o 2 9 0 53.63 -59.27 77.48 o 3 9 0 13.17 198.53 90.24 o 0 10 0 2.96 64.84 113.22 o 1 10 0 0.07 6.64 77.89 o -7 1 1 12.45 -40.57 44.18 o -6 1 1 278.74 261.33 33.66 o -5 1 1 169.06 191.20 27.34 o -4 1 1 9.98 30.81 13.59 o -3 1 1 2596.36 2922.26 47.31 o -2 1 1 45.14 59.70 6.58 o -1 1 1 11167.83 10589.50 418.19 o 1 1 1 721.86 701.56 12.80 o 2 1 1 15.13 18.34 7.26 o 3 1 1 2052.78 2023.58 30.63 o 4 1 1 284.28 267.08 12.04 o 5 1 1 616.01 601.41 24.66 o 6 1 1 110.31 110.05 30.53 o 7 1 1 7.30 1.79 37.67 o -7 2 1 719.97 682.21 56.69 o -6 2 1 1.86 -35.44 35.44 o -5 2 1 365.15 427.97 25.21 o -4 2 1 3025.89 3187.40 62.48 o -3 2 1 51.68 58.17 8.44 o -2 2 1 3552.47 3497.04 44.46 o -1 2 1 961.56 896.11 43.49 o 0 2 1 10228.24 10059.52 139.93 o 1 2 1 20898.89 20913.08 300.22 o 2 2 1 6235.07 6074.92 73.58 o 3 2 1 365.49 424.48 12.28 o 4 2 1 1844.80 1914.41 38.75 o 5 2 1 183.59 178.76 15.52 o 6 2 1 8.26 -1.85 30.08 o 7 2 1 331.24 276.22 57.63 o -7 3 1 82.83 78.33 42.24 o -6 3 1 475.99 461.23 58.76 o -5 3 1 817.62 803.12 32.66 o -4 3 1 207.53 195.07 14.55 o -3 3 1 8303.98 8796.17 139.03 o -2 3 1 1520.77 1524.36 26.80 o -1 3 1 5685.21 5886.61 93.90 o 0 3 1 11741.96 11280.83 146.75 o 1 3 1 391.27 431.37 8.98 o 2 3 1 2814.80 2782.15 42.62 o 3 3 1 2492.98 2441.71 43.12 o 4 3 1 1017.56 1049.10 26.73 o 5 3 1 1111.05 1082.30 50.07 o 6 3 1 613.42 747.30 51.01 o 7 3 1 25.53 48.59 39.33 o -7 4 1 408.77 433.82 80.56 o -6 4 1 20.88 -22.01 29.85 o -5 4 1 378.30 386.25 30.81 o -4 4 1 3134.71 3139.54 73.68 o -3 4 1 4.02 13.38 9.25 o -2 4 1 9038.24 9259.38 128.99 o -1 4 1 5158.14 4879.24 94.12 o 0 4 1 995.14 998.45 20.39 o 1 4 1 1519.80 1472.78 39.91 o 2 4 1 71.29 66.05 15.08 o 3 4 1 318.73 312.39 14.12 o 4 4 1 1985.36 1997.51 48.54 o 5 4 1 1124.17 1197.13 58.24 o 6 4 1 88.10 100.57 52.02 o 7 4 1 282.19 419.03 74.04 o -6 5 1 443.08 486.62 154.38 o -5 5 1 411.51 353.92 34.60 o -4 5 1 485.46 513.61 36.23 o -3 5 1 1404.68 1413.59 43.69 o -2 5 1 560.07 512.78 23.04 o -1 5 1 198.19 216.37 99.69 o 0 5 1 1524.99 1528.83 184.66 o 1 5 1 13.11 7.39 15.16 o 2 5 1 9.21 25.58 7.95 o 3 5 1 1155.81 1143.01 34.11 o 4 5 1 85.11 87.18 21.38 o 5 5 1 422.77 468.95 44.18 o 6 5 1 90.87 149.46 52.20 o -6 6 1 18.75 49.57 56.15 o -5 6 1 0.91 8.96 34.69 o -4 6 1 97.23 134.83 25.26 o -3 6 1 33.25 53.42 21.39 o -2 6 1 676.47 696.94 37.56 o -1 6 1 108.14 118.99 18.19 o 0 6 1 6.54 39.49 30.56 o 1 6 1 59.43 44.43 17.68 o 2 6 1 343.21 313.52 35.54 o 3 6 1 87.11 52.10 41.89 o 4 6 1 79.69 24.19 29.25 o 5 6 1 38.25 31.52 29.03 o 6 6 1 5.28 18.35 62.75 o -5 7 1 119.59 82.74 47.79 o -4 7 1 0.09 -28.22 36.08 o -3 7 1 585.45 569.38 44.23 o -2 7 1 1.96 105.79 41.26 o -1 7 1 3.50 692.74 211.57 o 0 7 1 118.83 152.79 66.41 o 1 7 1 4.06 14.37 19.27 o 2 7 1 174.10 209.35 72.63 o 3 7 1 111.06 78.25 31.61 o 4 7 1 1.11 33.51 26.46 o 5 7 1 174.93 201.35 55.09 o -4 8 1 328.34 433.25 62.06 o -3 8 1 39.96 27.69 52.91 o -2 8 1 1177.27 1136.65 89.95 o -1 8 1 743.84 684.67 78.49 o 0 8 1 7.64 72.93 51.94 o 1 8 1 154.12 213.18 64.64 o 2 8 1 130.09 117.96 29.24 o 3 8 1 143.28 143.77 41.51 o 4 8 1 416.05 382.86 59.58 o -3 9 1 1002.98 791.24 108.76 o -2 9 1 165.68 144.18 95.04 o -1 9 1 146.81 122.69 72.79 o 0 9 1 1344.46 1397.10 106.90 o 1 9 1 89.54 83.45 76.81 o 2 9 1 193.52 233.85 82.85 o 3 9 1 275.02 86.12 77.97 o -1 10 1 259.48 462.35 138.62 o 0 10 1 80.73 54.23 75.53 o 1 10 1 542.77 565.11 90.51 o -7 0 2 156.47 179.50 83.97 o -6 0 2 881.64 844.81 120.86 o -5 0 2 789.24 806.16 54.46 o -4 0 2 139.07 95.88 20.08 o -3 0 2 5195.49 5182.69 88.89 o -2 0 2 1963.34 1910.78 40.95 o -1 0 2 1301.89 1212.83 58.70 o 1 0 2 200.12 191.03 10.88 o 2 0 2 11468.04 11766.88 192.24 o 3 0 2 11065.11 10997.46 212.93 o 4 0 2 2027.34 2081.92 105.16 o 5 0 2 1350.59 1380.61 68.08 o 6 0 2 593.88 607.42 51.63 o 7 0 2 85.14 54.80 91.36 o -7 1 2 451.98 472.46 65.07 o -6 1 2 3.25 8.44 30.41 o -5 1 2 211.48 241.77 27.92 o -4 1 2 2056.96 2108.78 45.22 o -3 1 2 397.79 438.60 11.98 o -2 1 2 8717.61 8555.41 91.10 o -1 1 2 142.67 137.94 60.21 o 1 1 2 6931.99 6701.89 98.03 o 2 1 2 9355.69 9325.86 115.73 o 3 1 2 225.90 227.68 9.10 o 4 1 2 2059.39 2087.17 42.18 o 5 1 2 2276.91 2422.12 72.11 o 6 1 2 517.25 478.93 39.59 o 7 1 2 320.69 355.99 81.81 o -7 2 2 0.55 -51.58 63.58 o -6 2 2 636.90 661.62 76.37 o -5 2 2 3.31 24.56 16.83 o -4 2 2 198.05 246.12 22.02 o -3 2 2 1949.77 1927.71 44.40 o -2 2 2 124.97 133.89 7.45 o -1 2 2 1074.43 1094.30 19.10 o 0 2 2 4453.35 4162.73 125.43 o 1 2 2 4086.32 3987.35 53.45 o 2 2 2 202.19 274.29 8.63 o 3 2 2 1894.43 1873.34 24.87 o 4 2 2 178.75 170.41 12.21 o 5 2 2 1624.80 1567.16 57.26 o 6 2 2 26.59 14.65 25.88 o 7 2 2 18.85 -35.05 35.05 o -7 3 2 3.28 -0.75 52.64 o -6 3 2 44.48 64.68 39.97 o -5 3 2 425.29 494.53 37.29 o -4 3 2 2.06 34.57 14.70 o -3 3 2 102.47 104.94 9.23 o -2 3 2 51.90 66.74 9.07 o -1 3 2 1726.75 1884.21 150.29 o 0 3 2 717.70 672.93 13.82 o 1 3 2 840.63 879.92 17.16 o 2 3 2 407.99 431.07 28.96 o 3 3 2 224.50 223.66 10.64 o 4 3 2 65.77 56.57 12.75 o 5 3 2 16.92 -2.14 16.92 o 6 3 2 14.27 15.93 36.52 o 7 3 2 5.20 -26.96 39.67 o -7 4 2 28.05 21.44 52.44 o -6 4 2 89.40 113.67 35.99 o -5 4 2 230.13 226.93 25.69 o -4 4 2 158.27 166.33 34.94 o -3 4 2 146.12 146.58 12.68 o -2 4 2 129.62 140.46 13.07 o -1 4 2 3.90 530.33 176.57 o 0 4 2 16.77 20.97 4.64 o 1 4 2 60.40 43.43 6.95 o 2 4 2 779.47 768.13 21.00 o 3 4 2 1843.35 1833.49 41.78 o 4 4 2 5.89 17.17 13.48 o 5 4 2 137.71 143.30 23.24 o 6 4 2 89.92 128.61 47.78 o 7 4 2 14.45 -14.00 84.35 o -6 5 2 2.54 46.18 53.39 o -5 5 2 197.90 207.31 38.36 o -4 5 2 676.08 669.90 32.06 o -3 5 2 78.20 49.03 14.92 o -2 5 2 2739.47 2909.73 82.65 o -1 5 2 1872.12 1923.85 75.83 o 0 5 2 53.08 43.63 7.59 o 1 5 2 794.64 860.78 40.23 o 2 5 2 431.51 453.58 16.75 o 3 5 2 3.67 21.82 12.32 o 4 5 2 2649.34 2829.22 105.53 o 5 5 2 382.52 430.60 42.98 o 6 5 2 182.17 202.38 45.78 o -6 6 2 264.68 306.47 79.58 o -5 6 2 66.46 116.73 47.47 o -4 6 2 22.11 5.74 24.98 o -3 6 2 2292.13 2298.25 109.77 o -2 6 2 597.32 672.56 136.60 o -1 6 2 1509.28 1522.58 83.65 o 0 6 2 4149.82 4053.30 207.15 o 1 6 2 2387.26 2460.62 79.68 o 2 6 2 543.20 528.76 25.95 o 3 6 2 602.89 629.17 43.10 o 4 6 2 153.38 152.96 33.27 o 5 6 2 559.01 517.78 51.24 o 6 6 2 597.88 578.67 84.69 o -5 7 2 347.01 172.91 46.05 o -4 7 2 833.36 827.84 67.62 o -3 7 2 6.04 -17.18 26.04 o -2 7 2 879.49 923.76 57.15 o -1 7 2 1293.72 1160.57 58.93 o 0 7 2 156.15 145.55 55.46 o 1 7 2 2792.96 3170.69 139.82 o 2 7 2 1241.54 1298.69 80.43 o 3 7 2 6.76 12.83 29.72 o 4 7 2 652.96 691.14 58.74 o 5 7 2 173.32 176.64 52.07 o -4 8 2 81.95 94.06 48.96 o -3 8 2 517.33 460.30 47.90 o -2 8 2 99.20 98.91 28.93 o -1 8 2 120.38 218.02 58.05 o 0 8 2 346.40 318.75 51.42 o 1 8 2 262.47 262.65 75.62 o 2 8 2 280.68 226.11 49.84 o 3 8 2 668.80 548.00 83.75 o 4 8 2 165.17 216.79 67.27 o -3 9 2 7.26 27.83 71.30 o -2 9 2 44.93 -42.38 69.65 o -1 9 2 2.63 -1.89 66.27 o 0 9 2 21.49 28.77 52.00 o 1 9 2 175.94 54.82 81.18 o 2 9 2 134.13 -23.14 90.80 o 3 9 2 0.66 -17.61 122.04 o -1 10 2 1.60 15.16 79.64 o 0 10 2 25.49 83.56 87.44 o 1 10 2 89.40 152.13 82.95 o -7 1 3 4.50 -41.85 41.85 o -6 1 3 718.07 715.32 50.10 o -5 1 3 648.34 668.35 39.74 o -4 1 3 25.39 44.42 16.15 o -3 1 3 1525.75 1570.83 26.33 o -2 1 3 585.91 563.33 12.26 o -1 1 3 11.73 21.76 3.75 o 0 1 3 325.82 154.13 22.44 o 1 1 3 152.72 172.74 5.37 o 2 1 3 4926.92 4937.94 61.47 o 3 1 3 2808.24 2738.33 39.05 o 4 1 3 181.59 157.93 29.39 o 5 1 3 564.34 562.54 29.02 o 6 1 3 127.69 124.13 27.48 o 7 1 3 6.76 -1.46 41.76 o -7 2 3 186.43 161.14 60.99 o -6 2 3 399.95 350.78 33.78 o -5 2 3 811.03 832.95 31.93 o -4 2 3 3734.53 3832.62 81.31 o -3 2 3 138.15 131.85 8.57 o -2 2 3 4204.56 4105.68 54.38 o -1 2 3 3400.32 3164.20 64.85 o 0 2 3 4665.16 4667.70 83.13 o 1 2 3 5128.01 4953.81 66.65 o 2 2 3 5646.46 5726.40 70.63 o 3 2 3 4310.47 4745.99 56.68 o 4 2 3 3291.06 3377.63 76.02 o 5 2 3 438.83 495.27 37.59 o 6 2 3 89.25 64.79 31.41 o 7 2 3 344.25 426.41 44.59 o -7 3 3 24.42 17.65 54.98 o -6 3 3 246.53 248.70 29.62 o -5 3 3 1153.61 1219.43 42.54 o -4 3 3 19.44 25.38 12.18 o -3 3 3 8868.98 9414.57 185.25 o -2 3 3 1855.93 1900.80 30.17 o -1 3 3 4826.37 4916.28 77.59 o 0 3 3 10063.64 10074.70 180.96 o 1 3 3 6082.92 6184.21 84.28 o 2 3 3 8076.28 8414.26 94.15 o 3 3 3 2489.16 2489.71 42.67 o 4 3 3 9.94 23.16 12.13 o 5 3 3 487.59 515.76 36.94 o 6 3 3 1702.15 1750.21 108.36 o 7 3 3 1.01 75.80 49.29 o -7 4 3 120.15 125.44 65.06 o -6 4 3 9.83 -20.80 52.29 o -5 4 3 19.29 49.33 23.69 o -4 4 3 3088.46 3147.60 91.20 o -3 4 3 6.07 -6.62 11.68 o -2 4 3 7672.34 7985.14 160.33 o -1 4 3 692.37 632.28 12.82 o 0 4 3 1308.76 1434.34 23.51 o 1 4 3 14552.67 14971.91 198.45 o 2 4 3 4995.86 4937.13 81.10 o 3 4 3 1017.77 912.32 26.22 o 4 4 3 307.84 300.86 18.87 o 5 4 3 888.57 819.91 47.10 o 6 4 3 88.44 23.29 42.59 o 7 4 3 405.92 275.90 86.08 o -6 5 3 63.67 -26.88 50.58 o -5 5 3 86.69 61.77 29.38 o -4 5 3 903.67 968.63 55.26 o -3 5 3 1089.97 1033.08 35.10 o -2 5 3 368.54 406.09 32.94 o -1 5 3 1109.46 1194.66 49.91 o 0 5 3 1937.24 1943.88 41.90 o 1 5 3 1826.20 2021.77 51.50 o 2 5 3 768.69 787.20 21.09 o 3 5 3 2128.01 2111.16 59.16 o 4 5 3 72.58 62.48 26.99 o 5 5 3 13.84 58.57 32.16 o 6 5 3 143.90 172.37 42.54 o -6 6 3 138.54 129.65 56.24 o -5 6 3 4.82 -0.11 34.65 o -4 6 3 63.24 64.31 25.30 o -3 6 3 0.21 9.86 20.55 o -2 6 3 245.10 243.80 23.67 o -1 6 3 19.68 49.78 28.27 o 0 6 3 0.75 615.94 210.97 o 1 6 3 871.03 879.26 39.88 o 2 6 3 6.43 -15.35 19.05 o 3 6 3 57.46 48.11 29.56 o 4 6 3 11.35 2.11 28.69 o 5 6 3 137.98 75.23 42.18 o 6 6 3 2.88 94.89 59.11 o -5 7 3 28.22 31.80 39.23 o -4 7 3 1.74 35.28 42.72 o -3 7 3 383.19 337.48 44.53 o -2 7 3 1.61 29.79 38.63 o -1 7 3 7.69 77.75 45.64 o 0 7 3 390.27 390.53 39.20 o 1 7 3 637.30 597.31 45.40 o 2 7 3 74.41 82.18 25.50 o 3 7 3 58.26 -2.16 29.85 o 4 7 3 5.63 23.12 44.52 o 5 7 3 290.04 142.56 55.68 o -4 8 3 264.76 239.78 54.52 o -3 8 3 57.61 25.95 36.92 o -2 8 3 566.92 551.91 63.02 o -1 8 3 493.15 489.31 75.37 o 0 8 3 18.71 26.66 47.77 o 1 8 3 931.11 913.30 124.48 o 2 8 3 1309.21 1340.19 108.54 o 3 8 3 30.77 -48.09 48.09 o 4 8 3 406.68 366.28 58.41 o -3 9 3 900.22 904.29 154.99 o -2 9 3 165.04 245.62 69.85 o -1 9 3 146.78 83.39 111.24 o 0 9 3 872.89 861.04 80.03 o 1 9 3 230.53 56.30 81.50 o 2 9 3 1058.64 1092.64 152.50 o 3 9 3 778.99 567.11 134.14 o -1 10 3 508.58 662.61 90.82 o 0 10 3 10.20 -77.46 80.79 o 1 10 3 355.60 421.54 115.55 o -7 0 4 55.29 165.82 118.63 o -6 0 4 3483.05 3585.22 204.56 o -5 0 4 452.81 431.61 49.00 o -4 0 4 1151.78 1049.35 45.85 o -3 0 4 9236.00 9122.45 185.36 o -2 0 4 6023.62 5646.21 107.00 o -1 0 4 20054.98 19058.79 521.67 o 1 0 4 3045.96 3046.11 54.89 o 2 0 4 3563.08 3443.57 54.10 o 3 0 4 4891.79 4926.13 100.32 o 4 0 4 19.63 62.29 28.79 o 5 0 4 935.17 911.92 54.33 o 6 0 4 1176.58 1070.57 65.73 o 7 0 4 18.95 -27.92 63.74 o -7 1 4 496.44 406.60 72.19 o -6 1 4 7.75 23.90 29.20 o -5 1 4 2980.63 3023.86 98.74 o -4 1 4 3138.37 3150.38 76.73 o -3 1 4 24.66 35.73 7.88 o -2 1 4 3374.35 3122.35 41.12 o -1 1 4 13035.75 12561.31 204.65 o 0 1 4 1657.43 1715.82 31.97 o 1 1 4 9361.03 8903.12 131.93 o 2 1 4 953.69 842.93 14.48 o 3 1 4 744.55 776.84 18.23 o 4 1 4 1895.45 1838.60 36.36 o 5 1 4 1184.98 1182.58 42.39 o 6 1 4 365.18 324.75 33.07 o 7 1 4 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