#------------------------------------------------------------------------------ #$Date: 2016-04-03 01:41:20 +0300 (Sun, 03 Apr 2016) $ #$Revision: 181080 $ #$URL: file:///home/coder/svn-repositories/cod/hkl/2/21/60/2216091.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/. The original data for this entry # were provided by IUCr Journals, http://journals.iucr.org/. # # The file may be used within the scientific community so long as # proper attribution is given to the journal article from which the # data were obtained. # data_2216091_Fobs loop_ _publ_author_name 'Butcher, Ray J.' 'Pourian, Mohamad' 'Jasinski, Jerry P.' _publ_section_title ; [2,2'-(2,6,9,13-Tetraazatetradeca-1,13-diene-1,14-diyl)diphenolato]iron(III) chloride ; _journal_coeditor_code PR2016 _journal_issue 11 _journal_name_full 'Acta Crystallographica Section E' _journal_page_first m2742 _journal_page_last m2743 _journal_volume 63 _journal_year 2007 _space_group_IT_number 56 _symmetry_space_group_name_Hall '-P 2ab 2ac' _symmetry_space_group_name_H-M 'P c c n' _cell_angle_alpha 90.000 _cell_angle_beta 90.000 _cell_angle_gamma 90.000 _cell_length_a 7.5156 _cell_length_b 16.1607 _cell_length_c 17.6539 _exptl_crystal_F_000 988.00 _reflns_d_resolution_high 0.8418 _cod_data_source_file pr2016Isup2.hkl _cod_data_source_block I #BEGIN Tags that were not found in dictionaries: _shelx_title ' Fe-3 in Pccn' _shelx_refln_list_code 4 _shelx_f_calc_maximum 232.03 _shelx_f_squared_multiplier 1.000 #END Tags that were not found in dictionaries loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x+1/2, -y+1/2, z' '-x, y+1/2, -z+1/2' 'x+1/2, -y, -z+1/2' '-x, -y, -z' 'x-1/2, y-1/2, -z' 'x, -y-1/2, z-1/2' '-x-1/2, y, z-1/2' loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 22456.65 23989.29 723.93 o 4 0 0 10790.82 11426.90 352.36 o 6 0 0 4595.54 4759.06 161.34 o 8 0 0 2015.94 2222.25 97.62 o 1 1 0 21886.52 20687.78 622.88 o 3 1 0 416.32 463.72 28.74 o 5 1 0 922.80 957.75 47.95 o 7 1 0 355.62 358.45 32.17 o 0 2 0 44793.18 48210.82 1448.18 o 2 2 0 27545.11 27702.66 835.76 o 4 2 0 8999.00 9303.20 288.95 o 6 2 0 2816.57 2824.51 105.27 o 8 2 0 1958.39 2064.81 93.87 o 1 3 0 8626.75 8751.86 266.46 o 3 3 0 52.86 47.95 13.28 o 5 3 0 2400.21 2457.47 90.28 o 7 3 0 270.35 256.77 26.08 o 0 4 0 7641.73 8310.31 253.65 o 2 4 0 18877.28 20216.24 612.41 o 4 4 0 9902.95 9136.40 285.20 o 6 4 0 6313.23 6270.96 207.11 o 8 4 0 364.03 364.08 30.93 o 1 5 0 928.92 974.46 39.52 o 3 5 0 703.06 737.99 37.64 o 5 5 0 1073.13 1075.51 53.73 o 7 5 0 1309.47 1223.11 68.57 o 0 6 0 8781.53 9090.16 279.42 o 2 6 0 10225.56 10710.15 329.56 o 4 6 0 7167.32 6871.98 219.44 o 6 6 0 4667.31 4492.60 156.50 o 8 6 0 730.07 848.10 63.10 o 1 7 0 258.17 268.02 26.55 o 3 7 0 2184.26 2255.05 82.00 o 5 7 0 722.95 678.79 47.64 o 7 7 0 73.19 44.98 25.15 o 0 8 0 53840.18 58742.60 1770.86 o 2 8 0 56.93 4.37 26.86 o 4 8 0 7639.27 7885.64 252.09 o 6 8 0 1028.77 1062.24 61.54 o 8 8 0 2378.83 2452.31 109.49 o 1 9 0 726.35 720.50 39.98 o 3 9 0 1677.50 1841.15 73.10 o 5 9 0 97.03 93.40 21.87 o 7 9 0 40.47 11.09 30.93 o 0 10 0 2521.18 2247.71 82.62 o 2 10 0 7279.94 7248.39 231.63 o 4 10 0 6484.86 6602.08 216.95 o 6 10 0 15.21 15.93 29.68 o 1 11 0 276.31 255.06 24.83 o 3 11 0 1317.23 1348.37 63.57 o 5 11 0 76.77 80.44 24.05 o 7 11 0 38.51 44.20 28.58 o 0 12 0 106.12 92.31 19.05 o 2 12 0 6522.73 6772.33 221.01 o 4 12 0 2473.82 2479.80 99.34 o 6 12 0 1211.24 1321.35 75.60 o 1 13 0 34.17 55.13 20.77 o 3 13 0 1181.99 1174.07 63.72 o 5 13 0 59.10 35.61 26.24 o 0 14 0 246.67 245.68 24.52 o 2 14 0 2534.86 2566.64 102.46 o 4 14 0 2020.27 2065.28 93.71 o 6 14 0 1381.04 1470.51 82.78 o 1 15 0 23.35 34.36 40.77 o 3 15 0 1773.31 1805.38 85.75 o 5 15 0 305.65 315.66 31.86 o 0 16 0 564.48 659.74 54.35 o 2 16 0 1636.13 1742.13 82.78 o 4 16 0 1410.91 1459.27 82.47 o 1 17 0 131.98 167.12 27.33 o 3 17 0 654.17 708.47 62.16 o 0 18 0 1661.30 1733.85 86.06 o 2 18 0 505.98 507.14 42.48 o 1 19 0 458.15 457.16 42.17 o 1 1 1 387.97 469.81 19.68 o 2 1 1 204.53 257.24 22.18 o 3 1 1 88.55 72.78 13.12 o 4 1 1 91.69 83.72 15.31 o 5 1 1 103.30 127.45 18.12 o 6 1 1 37.91 48.89 20.62 o 7 1 1 15.31 22.02 38.58 o 8 1 1 4.81 -32.02 44.67 o 1 2 1 4323.00 4486.98 138.23 o 2 2 1 4426.06 4397.33 137.91 o 3 2 1 24.14 -22.33 22.33 o 4 2 1 11.59 -25.61 25.61 o 5 2 1 10.34 -9.68 29.99 o 6 2 1 425.98 509.49 43.26 o 7 2 1 33.39 19.37 28.11 o 8 2 1 7.87 32.49 26.24 o 1 3 1 13305.13 13217.91 400.47 o 2 3 1 791.47 806.87 35.45 o 3 3 1 1412.49 1391.95 53.42 o 4 3 1 33.52 6.25 26.08 o 5 3 1 61.27 119.02 18.43 o 6 3 1 38.00 -15.62 36.39 o 7 3 1 247.86 339.40 33.11 o 8 3 1 16.02 27.65 43.73 o 1 4 1 0.37 -3.12 19.37 o 2 4 1 1950.52 2086.52 71.22 o 3 4 1 0.56 24.21 13.43 o 4 4 1 489.36 481.84 35.14 o 5 4 1 624.26 682.23 44.36 o 6 4 1 53.16 80.59 22.49 o 7 4 1 420.99 380.16 35.30 o 8 4 1 457.67 423.58 38.42 o 1 5 1 92.56 113.71 12.81 o 2 5 1 0.19 -5.94 21.87 o 3 5 1 1330.97 1516.43 58.41 o 4 5 1 313.78 358.14 33.11 o 5 5 1 452.01 490.28 40.92 o 6 5 1 31.23 37.17 22.18 o 7 5 1 550.30 511.20 51.23 o 8 5 1 0.23 -44.67 44.67 o 1 6 1 468.40 527.76 30.30 o 2 6 1 11898.08 13296.47 407.03 o 3 6 1 141.12 135.42 16.40 o 4 6 1 395.20 435.14 36.39 o 5 6 1 15.78 -4.69 34.67 o 6 6 1 4.23 11.71 39.20 o 7 6 1 29.79 48.11 24.68 o 8 6 1 128.60 137.91 27.96 o 1 7 1 2782.03 3056.92 101.68 o 2 7 1 189.10 212.10 20.46 o 3 7 1 2023.33 2404.21 85.90 o 4 7 1 533.27 607.42 41.86 o 5 7 1 738.95 668.95 48.11 o 6 7 1 2.59 -38.42 38.42 o 7 7 1 207.68 193.21 26.86 o 8 7 1 58.14 76.69 27.80 o 1 8 1 131.19 22.33 28.58 o 2 8 1 3915.60 4535.55 147.91 o 3 8 1 130.39 136.98 17.96 o 4 8 1 11.23 20.62 19.05 o 5 8 1 158.36 201.48 23.12 o 6 8 1 2.30 -39.52 39.52 o 7 8 1 54.78 73.10 25.30 o 8 8 1 25.62 83.72 29.99 o 1 9 1 1365.82 1397.57 57.95 o 2 9 1 3.41 -27.96 27.96 o 3 9 1 6.31 2.19 31.08 o 4 9 1 347.92 344.24 29.21 o 5 9 1 29.77 12.65 38.42 o 6 9 1 40.34 38.42 23.90 o 7 9 1 14.20 63.57 25.46 o 1 10 1 5.27 -30.93 30.93 o 2 10 1 53.72 16.56 29.99 o 3 10 1 4.42 -9.37 33.11 o 4 10 1 20.03 72.94 21.87 o 5 10 1 4.50 -20.15 38.73 o 6 10 1 200.15 200.55 27.02 o 7 10 1 0.34 29.68 46.23 o 1 11 1 577.75 620.85 42.33 o 2 11 1 117.18 119.95 20.30 o 3 11 1 261.11 273.02 23.74 o 4 11 1 1.94 17.65 38.89 o 5 11 1 125.37 100.27 24.52 o 6 11 1 168.49 181.96 27.80 o 7 11 1 93.37 0.31 51.07 o 1 12 1 32.96 -28.74 34.99 o 2 12 1 2.26 33.58 36.55 o 3 12 1 98.29 114.33 23.12 o 4 12 1 205.13 231.16 25.93 o 5 12 1 416.02 500.90 51.85 o 6 12 1 43.41 27.96 46.54 o 1 13 1 615.77 713.94 49.36 o 2 13 1 22.29 18.74 38.42 o 3 13 1 4.90 5.47 39.83 o 4 13 1 137.43 140.57 25.93 o 5 13 1 10.64 26.24 45.76 o 6 13 1 0.93 -22.49 48.57 o 1 14 1 329.62 263.49 27.18 o 2 14 1 8.15 -14.21 41.39 o 3 14 1 137.87 176.34 26.24 o 4 14 1 40.16 80.44 26.24 o 5 14 1 21.45 -47.48 47.48 o 6 14 1 2.44 -34.05 49.36 o 1 15 1 876.81 674.73 55.92 o 2 15 1 1.97 30.30 42.01 o 3 15 1 194.17 176.02 29.36 o 4 15 1 0.00 17.65 33.58 o 5 15 1 0.82 -19.99 47.64 o 1 16 1 2.70 -45.14 45.14 o 2 16 1 0.06 -44.98 44.98 o 3 16 1 80.55 98.24 29.36 o 4 16 1 115.14 84.19 29.21 o 1 17 1 95.80 107.93 26.86 o 2 17 1 2.61 -45.61 45.61 o 3 17 1 0.97 28.43 48.73 o 4 17 1 2.10 7.34 51.23 o 1 18 1 1.62 -47.64 47.64 o 2 18 1 77.53 115.58 29.36 o 3 18 1 19.89 65.91 28.89 o 1 19 1 0.06 3.90 49.98 o 0 0 2 26576.42 26211.22 788.13 o 1 0 2 12409.29 13644.30 412.02 o 2 0 2 11078.76 11867.04 360.95 o 3 0 2 25.43 5.94 21.87 o 4 0 2 460.69 515.42 33.58 o 5 0 2 4999.82 5441.92 177.43 o 6 0 2 1563.65 1520.65 69.50 o 7 0 2 1163.63 1195.47 64.82 o 8 0 2 841.86 826.39 61.85 o 0 1 2 16015.71 15541.37 468.25 o 1 1 2 24426.51 23981.01 722.22 o 2 1 2 15149.93 15807.36 479.19 o 3 1 2 480.84 439.05 28.74 o 4 1 2 92.43 81.69 15.31 o 5 1 2 2831.24 2811.08 100.27 o 6 1 2 1.00 34.52 35.45 o 7 1 2 1090.91 1110.34 63.88 o 8 1 2 154.46 198.05 27.49 o 0 2 2 22217.92 23174.29 697.85 o 1 2 2 3024.21 3283.55 102.77 o 2 2 2 1108.49 1084.26 42.17 o 3 2 2 6158.03 5938.75 186.33 o 4 2 2 1280.69 1353.37 55.60 o 5 2 2 2669.92 2712.84 97.77 o 6 2 2 1650.56 1728.22 74.03 o 7 2 2 939.11 1019.29 60.60 o 8 2 2 154.77 172.59 27.33 o 0 3 2 6218.89 7008.33 213.98 o 1 3 2 7897.30 8160.69 249.28 o 2 3 2 709.21 694.88 32.49 o 3 3 2 5912.41 5636.68 177.74 o 4 3 2 892.45 891.05 44.05 o 5 3 2 1670.24 1647.01 68.10 o 6 3 2 84.36 54.51 21.40 o 7 3 2 1883.91 1876.76 84.50 o 8 3 2 59.23 93.71 26.08 o 0 4 2 1655.13 1868.17 62.79 o 1 4 2 6377.01 6743.90 207.89 o 2 4 2 7334.85 7189.66 222.57 o 3 4 2 2906.87 2712.99 92.15 o 4 4 2 2010.95 1902.53 72.16 o 5 4 2 3532.87 3437.71 120.42 o 6 4 2 2180.51 2071.06 85.75 o 7 4 2 1230.67 1284.65 69.04 o 8 4 2 25.67 -42.64 44.51 o 0 5 2 3073.82 3431.77 109.64 o 1 5 2 5191.70 5382.09 168.06 o 2 5 2 159.39 177.90 17.49 o 3 5 2 2258.23 2098.23 75.28 o 4 5 2 33.00 73.25 16.71 o 5 5 2 4932.91 4715.64 158.53 o 6 5 2 562.28 543.85 47.33 o 7 5 2 910.17 895.12 60.91 o 8 5 2 96.44 121.98 26.55 o 0 6 2 1230.14 1281.53 49.36 o 1 6 2 4837.21 4946.95 156.34 o 2 6 2 1643.98 1662.16 61.54 o 3 6 2 4348.03 4170.23 136.82 o 4 6 2 2667.59 2533.22 91.68 o 5 6 2 2244.63 2191.95 86.68 o 6 6 2 943.74 943.53 57.01 o 7 6 2 1027.28 982.58 63.41 o 8 6 2 236.62 205.39 29.21 o 0 7 2 4581.20 5070.19 160.87 o 1 7 2 4027.22 4179.44 135.26 o 2 7 2 1112.24 1178.44 49.82 o 3 7 2 3940.99 3937.82 131.04 o 4 7 2 197.35 200.86 19.84 o 5 7 2 1976.03 1929.39 80.12 o 6 7 2 2.97 -39.52 39.52 o 7 7 2 408.32 411.24 36.86 o 8 7 2 47.61 -9.68 48.26 o 0 8 2 3569.87 3652.15 121.05 o 1 8 2 6911.48 7221.68 226.94 o 2 8 2 2313.35 2355.32 84.19 o 3 8 2 2026.95 1958.29 75.28 o 4 8 2 556.62 563.06 42.01 o 5 8 2 1322.89 1321.35 64.66 o 6 8 2 332.43 331.12 27.33 o 7 8 2 600.42 636.78 55.76 o 8 8 2 599.75 609.13 60.60 o 0 9 2 3229.31 3418.81 116.99 o 1 9 2 3890.16 3754.61 126.82 o 2 9 2 72.40 106.68 17.49 o 3 9 2 3001.85 3139.07 110.89 o 4 9 2 17.77 16.24 34.67 o 5 9 2 615.59 652.87 49.20 o 6 9 2 64.26 55.60 24.52 o 7 9 2 337.32 352.20 31.24 o 0 10 2 2118.87 2013.58 79.50 o 1 10 2 3385.31 3074.57 108.86 o 2 10 2 2036.01 1990.62 77.63 o 3 10 2 2777.70 2776.72 102.93 o 4 10 2 669.70 657.08 49.36 o 5 10 2 634.71 590.70 50.61 o 6 10 2 151.51 144.79 26.40 o 7 10 2 134.12 173.68 28.89 o 0 11 2 38.91 29.83 33.42 o 1 11 2 1743.31 1474.89 68.25 o 2 11 2 118.68 88.87 21.09 o 3 11 2 2957.98 3015.53 111.52 o 4 11 2 518.26 609.29 47.64 o 5 11 2 126.66 167.28 24.83 o 6 11 2 606.64 581.18 55.29 o 7 11 2 706.99 694.73 62.63 o 0 12 2 69.39 53.57 19.21 o 1 12 2 2247.86 2151.03 86.84 o 2 12 2 2891.00 2954.15 109.18 o 3 12 2 1447.28 1577.19 72.63 o 4 12 2 694.64 751.11 54.51 o 5 12 2 296.09 281.61 28.89 o 6 12 2 236.77 280.51 30.14 o 0 13 2 3.18 -10.31 34.52 o 1 13 2 1140.20 1051.93 62.63 o 2 13 2 320.28 217.88 28.11 o 3 13 2 607.49 636.78 51.70 o 4 13 2 81.20 30.61 31.24 o 5 13 2 1555.78 1629.04 83.40 o 6 13 2 426.62 427.64 40.61 o 0 14 2 88.98 85.90 22.33 o 1 14 2 1032.75 981.64 61.23 o 2 14 2 529.83 514.64 50.76 o 3 14 2 930.76 955.40 61.85 o 4 14 2 1114.90 1144.39 69.35 o 5 14 2 599.21 616.01 60.13 o 6 14 2 306.02 300.66 32.96 o 0 15 2 73.48 29.52 23.90 o 1 15 2 182.97 174.31 27.18 o 2 15 2 286.03 277.39 28.11 o 3 15 2 2017.56 2000.46 93.24 o 4 15 2 43.84 28.11 48.57 o 5 15 2 540.27 587.11 59.82 o 0 16 2 1060.36 1044.43 64.19 o 1 16 2 279.58 243.34 28.89 o 2 16 2 88.11 33.11 46.23 o 3 16 2 1623.81 1636.23 86.68 o 4 16 2 764.47 735.96 63.26 o 0 17 2 61.32 25.46 49.20 o 1 17 2 531.91 508.86 40.61 o 2 17 2 54.92 -29.68 46.86 o 3 17 2 557.61 617.72 46.70 o 4 17 2 44.13 12.18 36.70 o 0 18 2 389.43 392.03 38.73 o 1 18 2 381.86 310.35 33.42 o 2 18 2 440.86 425.61 34.21 o 0 19 2 1.52 -51.23 51.23 o 1 1 3 14999.94 14696.08 444.51 o 2 1 3 17256.47 17749.25 537.76 o 3 1 3 4164.24 4456.05 142.29 o 4 1 3 2294.16 2404.21 85.12 o 5 1 3 116.68 120.73 18.74 o 6 1 3 43.66 34.83 21.09 o 7 1 3 8.62 -24.21 41.08 o 8 1 3 23.85 40.14 45.61 o 1 2 3 44.58 62.48 10.62 o 2 2 3 2216.44 2312.84 77.16 o 3 2 3 1341.13 1371.80 53.42 o 4 2 3 251.53 230.22 21.24 o 5 2 3 62.63 89.50 18.59 o 6 2 3 107.09 117.45 21.71 o 7 2 3 0.76 5.94 40.61 o 8 2 3 2.63 -45.29 45.76 o 1 3 3 63.80 67.47 11.40 o 2 3 3 658.31 633.03 31.71 o 3 3 3 488.26 627.10 34.21 o 4 3 3 953.98 912.76 45.29 o 5 3 3 9.17 20.93 31.86 o 6 3 3 123.87 129.95 22.18 o 7 3 3 0.52 47.95 24.37 o 8 3 3 0.57 13.74 44.05 o 1 4 3 338.55 345.64 24.52 o 2 4 3 62.27 76.22 12.96 o 3 4 3 279.44 272.55 28.11 o 4 4 3 546.70 551.66 37.49 o 5 4 3 75.02 55.45 19.68 o 6 4 3 34.26 59.04 21.55 o 7 4 3 24.42 26.40 42.80 o 8 4 3 30.50 -18.74 44.51 o 1 5 3 15.32 -10.15 20.46 o 2 5 3 8.01 -22.18 22.18 o 3 5 3 159.69 152.44 16.24 o 4 5 3 407.05 427.33 35.77 o 5 5 3 107.17 104.65 20.62 o 6 5 3 12.26 -3.28 38.89 o 7 5 3 62.16 99.49 25.30 o 8 5 3 2.68 7.03 44.98 o 1 6 3 60.29 64.97 13.12 o 2 6 3 201.67 204.29 19.21 o 3 6 3 24.53 12.03 27.02 o 4 6 3 37.91 48.89 17.81 o 5 6 3 1.35 24.37 35.45 o 6 6 3 902.92 811.09 54.35 o 7 6 3 0.10 -19.05 42.48 o 8 6 3 46.36 39.67 27.18 o 1 7 3 122.64 184.30 18.74 o 2 7 3 1411.62 1523.93 59.66 o 3 7 3 810.97 972.43 47.17 o 4 7 3 582.22 639.59 42.64 o 5 7 3 36.00 24.05 36.70 o 6 7 3 39.54 68.72 23.58 o 7 7 3 42.99 109.18 25.77 o 8 7 3 42.12 42.33 48.42 o 1 8 3 103.28 125.11 16.09 o 2 8 3 81.88 68.57 16.24 o 3 8 3 4.20 -3.90 29.52 o 4 8 3 7.75 9.37 31.86 o 5 8 3 80.61 91.06 22.18 o 6 8 3 330.78 329.87 33.27 o 7 8 3 0.92 47.48 25.61 o 8 8 3 9.35 -33.42 47.17 o 1 9 3 1236.42 1394.14 58.73 o 2 9 3 1134.80 1192.19 54.35 o 3 9 3 71.09 74.35 19.05 o 4 9 3 272.66 292.54 28.11 o 5 9 3 1.83 31.71 38.27 o 6 9 3 33.14 81.84 25.15 o 7 9 3 7.98 35.14 44.83 o 1 10 3 17.60 -24.05 30.93 o 2 10 3 235.95 238.81 21.09 o 3 10 3 110.62 144.32 21.09 o 4 10 3 2.18 11.87 36.39 o 5 10 3 0.54 15.46 27.33 o 6 10 3 16.78 -19.84 44.36 o 7 10 3 5.55 -7.97 47.33 o 1 11 3 11.57 5.00 33.58 o 2 11 3 7.01 -3.59 34.21 o 3 11 3 337.81 364.86 30.77 o 4 11 3 576.51 615.23 49.67 o 5 11 3 338.42 408.12 35.61 o 6 11 3 73.14 70.28 26.86 o 7 11 3 71.55 -34.05 50.92 o 1 12 3 35.46 68.10 20.93 o 2 12 3 191.96 138.23 22.96 o 3 12 3 28.14 21.55 27.80 o 4 12 3 126.18 111.21 24.99 o 5 12 3 56.20 89.18 26.40 o 6 12 3 73.40 -3.75 48.11 o 1 13 3 42.89 30.30 37.64 o 2 13 3 28.69 -38.58 38.58 o 3 13 3 89.78 144.79 24.99 o 4 13 3 143.73 137.76 26.55 o 5 13 3 338.94 347.21 31.71 o 6 13 3 3.05 -23.58 51.07 o 1 14 3 3.69 -39.36 39.36 o 2 14 3 15.72 -12.18 40.30 o 3 14 3 11.10 17.02 43.26 o 4 14 3 17.19 -9.84 45.29 o 5 14 3 103.82 131.51 28.89 o 1 15 3 67.88 71.38 24.68 o 2 15 3 15.81 22.02 24.52 o 3 15 3 4.50 29.05 26.40 o 4 15 3 47.89 89.65 27.65 o 5 15 3 191.20 177.12 31.39 o 1 16 3 10.76 10.15 45.14 o 2 16 3 0.66 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