Crystallography Open Database

Information card for entry 4000594

Preview

Coordinates	4000594.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	Co5 Mo5 N5 O14
Calculated formula	Co5 Mo10 N9 O54
SMILES	O=[Mo]1(O[Mo]2(=O)(O[Mo]3(=[O][Co]([OH2])([OH2])([OH2])([OH2])[OH2])(O[Mo](O[Mo](O[Co]456(O[Co]7(O[Mo](=O)(=O)O[Mo](=O)(O[Mo](=O)(O[Mo](O[Mo](O7)(=[O][Co]([OH2])([OH2])([OH2])([OH2])[OH2])=O)(=O)=O)(=O)O4)(O5)=O)(O2)(O6)O3)O1)(=O)=O)(=O)=O)=O)=O)=O.[Co]([OH2])([OH2])([OH2])([OH2])([OH2])[OH2].O.O.O.O.O.O.O.O.O
Title of publication	Evidence and characterization of a new decamolybdocobaltate cobalt salt, an efficient precursor for hydrotreating catalyst preparation
Journal of publication	Chemistry of Materials
Year of publication	2005
a	15.7 ± 0.005 Å
b	13.05 ± 0.005 Å
c	26.98 ± 0.005 Å
α	90 ± 0.005°
β	105.713 ± 0.005°
γ	90 ± 0.005°
Cell volume	5321 ± 3 Å³
Cell temperature	293 ± 2 K
Ambient diffraction temperature	293 ± 2 K
Number of distinct elements	4
Space group number	9
Hermann-Mauguin space group symbol	C 1 c 1
Hall space group symbol	C -2yc
Has coordinates	Yes
Has disorder	No
Has F_obs	No

Version history

Revision	Date	Message	Files
270074 (current)	2021-10-24	cif/4 Fixing Z values and formulae	4000594.cif
178377	2016-03-21	cif/4/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/00.	4000594.cif
120677	2014-07-23	cod/ (saulius@koala.ibt.lt) Adding 4906 DOIs identified by CodBot.	4000594.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4000594.cif
966	2010-01-30	cif/ Adding _cod_database_code tags to all COD entries. Adding tag description to the cif_cod.dic dictionary so that COD entries can be validated.	4000594.cif
853	2009-11-16	cif/ Reconstructing spacegroup designators from the symmetry operators were possible. The comands used can be found in the log file reformat-spacegroups-2009.11.14.log committed with the current revision. Only lines that contained spacegroup designators were changed, and all files pass vcif test after the conversion.	4000594.cif
19	2008-01-26	Changing all end-of-line codes from DOS style to UNIX style in all COD CIF files, for more convenient processing: In the cod/cif/ directory: ff \*.cif \| xargs perl -i -pe 's/\r\n/\n/'	4000594.cif
14	2008-01-14	Appending a header with SVN keywords, COD URL and copying policy to all COD CIF files.	4000594.cif
13	2008-01-13	Setting the svn:keywords property to "Author Date Revision URL Id" for all CIF files in the cod/cif directory.	4000594.cif
1	2007-11-30	Adding all .cif files from the COD, downloaded in a Cod.zip file on 2007.02.07 (and the same Cod.zip is downloadable today, on 2007.11.29)	4000594.cif