#------------------------------------------------------------------------------
#$Date: 2024-11-17 20:31:36 +0200 (Sun, 17 Nov 2024) $
#$Revision: 295967 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/00/16/4001656.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4001656
loop_
_publ_author_name
'Chan, Julia Y.'
'Wang, Mary E.'
'Rehr, Anette'
'Kauzlarich, Susan M.'
'Webb, David J.'
_publ_section_title
;
 Synthesis, Structure, and Magnetic Properties of the Rare-Earth Zintl
 Compounds Eu14MnPn11and Eu14InPn11(Pn = Sb, Bi)
;
_journal_issue                   10
_journal_name_full               'Chemistry of Materials'
_journal_page_first              2131
_journal_paper_doi               10.1021/cm970219l
_journal_volume                  9
_journal_year                    1997
_chemical_formula_sum            'Bi11 Eu14 Mn'
_chemical_formula_weight         4481.16
_space_group_IT_number           142
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-I 4bd 2c'
_symmetry_space_group_name_H-M   'I 41/a c d :2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   17.632(4)
_cell_length_b                   17.632(4)
_cell_length_c                   23.047(6)
_cell_measurement_reflns_used    44
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      13.4
_cell_measurement_theta_min      3.2
_cell_volume                     7165(3)
_computing_cell_refinement       'Siemens P3'
_computing_data_collection       'Siemens P3'
_computing_data_reduction        'Siemens xdisk'
_computing_molecular_graphics    CrystalMaker
_computing_publication_material  xcif
_computing_structure_refinement  'SHELXTL 5 (Sheldrick, 1994)'
_computing_structure_solution    'SHELXTL 5 (Sheldrick, 1994)'
_diffrn_ambient_temperature      130(2)
_diffrn_measurement_device       'Siemens R3m/V'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'normal-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0791
_diffrn_reflns_av_sigmaI/netI    0.1006
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            5175
_diffrn_reflns_theta_max         30.03
_diffrn_reflns_theta_min         2.31
_diffrn_standards_decay_%        <0.1
_diffrn_standards_interval_count 198
_diffrn_standards_number         2
_exptl_absorpt_coefficient_mu    78.204
_exptl_absorpt_correction_T_max  0.130
_exptl_absorpt_correction_T_min  0.097
_exptl_absorpt_correction_type   'psi scans'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    8.308
_exptl_crystal_description       needle
_exptl_crystal_F_000             14560
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.02
_exptl_crystal_size_min          0.02
_refine_diff_density_max         3.051
_refine_diff_density_min         -2.766
_refine_diff_density_rms         0.719
_refine_ls_extinction_coef       0.000112(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_all   0.987
_refine_ls_goodness_of_fit_obs   1.045
_refine_ls_matrix_type           full
_refine_ls_number_parameters     62
_refine_ls_number_reflns         2628
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.987
_refine_ls_restrained_S_obs      1.045
_refine_ls_R_factor_all          0.0803
_refine_ls_R_factor_obs          0.0453
_refine_ls_shift/esd_max         0.001
_refine_ls_shift/esd_mean        0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0105P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_all         0.0896
_refine_ls_wR_factor_obs         0.0782
_reflns_number_observed          1802
_reflns_number_total             2628
_reflns_observed_criterion       >2sigma(I)
_cod_data_source_file            cm970219l.cif
_cod_data_source_block           jc39
_cod_depositor_comments
;
The following automatic conversions were performed:

'_refine_ls_weighting_scheme' value 'calc
w=1/[\s^2^(Fo^2^)+(0.0105P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3' was
changed to 'calc'. New tag '_refine_ls_weighting_details' was
created. The value of the new tag was set to
'w=1/[\s^2^(Fo^2^)+(0.0105P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'.

Automatic conversion script
Id: cif_fix_values 3143 2015-03-26 13:38:13Z robertas 
;
_cod_original_cell_volume        7165.0(30)
_cod_original_sg_symbol_H-M      I4(1)/acd
_cod_database_code               4001656
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-y+1/4, x+3/4, z+1/4'
'y+1/4, -x+1/4, z+3/4'
'-x+1/2, y, -z'
'x, -y, -z+1/2'
'y+1/4, x+3/4, -z+3/4'
'-y+1/4, -x+1/4, -z+1/4'
'x+1/2, y+1/2, z+1/2'
'-x+1, -y+1/2, z+1'
'-y+3/4, x+5/4, z+3/4'
'y+3/4, -x+3/4, z+5/4'
'-x+1, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1'
'y+3/4, x+5/4, -z+5/4'
'-y+3/4, -x+3/4, -z+3/4'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'y-1/4, -x-3/4, -z-1/4'
'-y-1/4, x-1/4, -z-3/4'
'x-1/2, -y, z'
'-x, y, z-1/2'
'-y-1/4, -x-3/4, z-3/4'
'y-1/4, x-1/4, z-1/4'
'-x+1/2, -y+1/2, -z+1/2'
'x, y+1/2, -z'
'y+1/4, -x-1/4, -z+1/4'
'-y+1/4, x+1/4, -z-1/4'
'x, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z'
'-y+1/4, -x-1/4, z-1/4'
'y+1/4, x+1/4, z+1/4'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_thermal_displace_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags
Bi1 Bi 0.13621(4) 0.38621(4) 0.1250 0.0097(2) Uani 1 d S
Bi2 Bi 0.00509(4) 0.10987(4) 0.81249(3) 0.0111(2) Uani 1 d .
Bi3 Bi 0.86877(5) 0.97309(4) 0.95304(3) 0.0107(2) Uani 1 d .
Bi4 Bi 0.0000 0.2500 0.1250 0.0110(3) Uani 1 d S
Eu1 Eu -0.04184(6) -0.07362(6) 0.82786(4) 0.0107(2) Uani 1 d .
Eu2 Eu -0.02203(6) 0.12378(6) 0.00044(5) 0.0129(2) Uani 1 d .
Eu3 Eu 0.35530(8) 0.0000 0.2500 0.0107(3) Uani 1 d S
Eu4 Eu 0.17903(6) 0.40960(6) 0.84277(4) 0.0126(2) Uani 1 d .
Mn1 Mn 0.0000 0.2500 0.8750 0.0084(11) Uani 1 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Eu4 Bi1 Eu4 79.14(4) 12_453 5_556
Eu4 Bi1 Bi4 140.43(2) 12_453 .
Eu4 Bi1 Bi4 140.43(2) 5_556 .
Eu4 Bi1 Eu1 88.97(3) 12_453 26_556
Eu4 Bi1 Eu1 142.96(3) 5_556 26_556
Bi4 Bi1 Eu1 59.59(2) . 26_556
Eu4 Bi1 Eu1 142.96(3) 12_453 32_554
Eu4 Bi1 Eu1 88.97(3) 5_556 32_554
Bi4 Bi1 Eu1 59.59(2) . 32_554
Eu1 Bi1 Eu1 119.19(5) 26_556 32_554
Eu4 Bi1 Eu2 137.86(3) 12_453 8
Eu4 Bi1 Eu2 86.47(3) 5_556 8
Bi4 Bi1 Eu2 63.83(2) . 8
Eu1 Bi1 Eu2 79.14(3) 26_556 8
Eu1 Bi1 Eu2 75.05(3) 32_554 8
Eu4 Bi1 Eu2 86.47(3) 12_453 10_454
Eu4 Bi1 Eu2 137.86(3) 5_556 10_454
Bi4 Bi1 Eu2 63.83(2) . 10_454
Eu1 Bi1 Eu2 75.05(3) 26_556 10_454
Eu1 Bi1 Eu2 79.14(3) 32_554 10_454
Eu2 Bi1 Eu2 127.66(5) 8 10_454
Eu4 Bi1 Eu3 67.86(3) 12_453 25
Eu4 Bi1 Eu3 73.02(3) 5_556 25
Bi4 Bi1 Eu3 115.71(3) . 25
Eu1 Bi1 Eu3 70.01(3) 26_556 25
Eu1 Bi1 Eu3 141.36(2) 32_554 25
Eu2 Bi1 Eu3 70.07(3) 8 25
Eu2 Bi1 Eu3 136.34(3) 10_454 25
Eu4 Bi1 Eu3 73.02(3) 12_453 27_565
Eu4 Bi1 Eu3 67.86(3) 5_556 27_565
Bi4 Bi1 Eu3 115.71(3) . 27_565
Eu1 Bi1 Eu3 141.36(2) 26_556 27_565
Eu1 Bi1 Eu3 70.01(3) 32_554 27_565
Eu2 Bi1 Eu3 136.34(3) 8 27_565
Eu2 Bi1 Eu3 70.07(3) 10_454 27_565
Eu3 Bi1 Eu3 128.58(5) 25 27_565
Mn1 Bi2 Eu2 72.44(3) . 28_556
Mn1 Bi2 Eu4 87.31(3) . 10_454
Eu2 Bi2 Eu4 141.46(4) 28_556 10_454
Mn1 Bi2 Eu1 140.44(3) . .
Eu2 Bi2 Eu1 144.06(4) 28_556 .
Eu4 Bi2 Eu1 68.85(3) 10_454 .
Mn1 Bi2 Eu1 129.33(3) . 6_556
Eu2 Bi2 Eu1 81.88(3) 28_556 6_556
Eu4 Bi2 Eu1 86.73(3) 10_454 6_556
Eu1 Bi2 Eu1 81.91(3) . 6_556
Mn1 Bi2 Eu3 135.88(3) . 2
Eu2 Bi2 Eu3 73.17(3) 28_556 2
Eu4 Bi2 Eu3 136.37(3) 10_454 2
Eu1 Bi2 Eu3 71.25(3) . 2
Eu1 Bi2 Eu3 70.77(3) 6_556 2
Mn1 Bi2 Eu4 83.19(3) . 19_567
Eu2 Bi2 Eu4 84.05(3) 28_556 19_567
Eu4 Bi2 Eu4 126.62(3) 10_454 19_567
Eu1 Bi2 Eu4 86.46(3) . 19_567
Eu1 Bi2 Eu4 137.23(3) 6_556 19_567
Eu3 Bi2 Eu4 66.51(3) 2 19_567
Mn1 Bi2 Eu2 62.75(2) . 19_566
Eu2 Bi2 Eu2 76.27(3) 28_556 19_566
Eu4 Bi2 Eu2 65.27(3) 10_454 19_566
Eu1 Bi2 Eu2 126.23(3) . 19_566
Eu1 Bi2 Eu2 69.17(3) 6_556 19_566
Eu3 Bi2 Eu2 132.15(3) 2 19_566
Eu4 Bi2 Eu2 144.36(3) 19_567 19_566
Eu3 Bi3 Eu4 75.81(3) 20_667 3_655
Eu3 Bi3 Eu1 125.92(3) 20_667 16_556
Eu4 Bi3 Eu1 87.01(3) 3_655 16_556
Eu3 Bi3 Eu2 139.34(3) 20_667 17_666
Eu4 Bi3 Eu2 72.33(3) 3_655 17_666
Eu1 Bi3 Eu2 77.06(3) 16_556 17_666
Eu3 Bi3 Eu4 70.00(3) 20_667 10_564
Eu4 Bi3 Eu4 145.75(4) 3_655 10_564
Eu1 Bi3 Eu4 111.24(3) 16_556 10_564
Eu2 Bi3 Eu4 138.43(4) 17_666 10_564
Eu3 Bi3 Eu1 137.95(3) 20_667 1_665
Eu4 Bi3 Eu1 146.23(4) 3_655 1_665
Eu1 Bi3 Eu1 72.51(4) 16_556 1_665
Eu2 Bi3 Eu1 76.99(3) 17_666 1_665
Eu4 Bi3 Eu1 67.98(3) 10_564 1_665
Eu3 Bi3 Eu2 73.04(3) 20_667 1_666
Eu4 Bi3 Eu2 87.57(3) 3_655 1_666
Eu1 Bi3 Eu2 157.96(4) 16_556 1_666
Eu2 Bi3 Eu2 80.94(3) 17_666 1_666
Eu4 Bi3 Eu2 84.63(3) 10_564 1_666
Eu1 Bi3 Eu2 101.35(3) 1_665 1_666
Eu3 Bi3 Eu4 68.44(2) 20_667 7_556
Eu4 Bi3 Eu4 94.16(3) 3_655 7_556
Eu1 Bi3 Eu4 62.10(3) 16_556 7_556
Eu2 Bi3 Eu4 137.76(3) 17_666 7_556
Eu4 Bi3 Eu4 71.58(3) 10_564 7_556
Eu1 Bi3 Eu4 99.23(3) 1_665 7_556
Eu2 Bi3 Eu4 139.67(3) 1_666 7_556
Eu1 Bi4 Eu1 120.41(4) 26_556 32_554
Eu1 Bi4 Eu1 142.45(4) 26_556 17_556
Eu1 Bi4 Eu1 72.60(4) 32_554 17_556
Eu1 Bi4 Eu1 72.60(4) 26_556 23_565
Eu1 Bi4 Eu1 142.45(4) 32_554 23_565
Eu1 Bi4 Eu1 120.41(4) 17_556 23_565
Eu1 Bi4 Bi1 119.79(2) 26_556 10_454
Eu1 Bi4 Bi1 119.79(2) 32_554 10_454
Eu1 Bi4 Bi1 60.21(2) 17_556 10_454
Eu1 Bi4 Bi1 60.21(2) 23_565 10_454
Eu1 Bi4 Bi1 60.21(2) 26_556 .
Eu1 Bi4 Bi1 60.21(2) 32_554 .
Eu1 Bi4 Bi1 119.79(2) 17_556 .
Eu1 Bi4 Bi1 119.79(2) 23_565 .
Bi1 Bi4 Bi1 180.0 10_454 .
Eu1 Bi4 Eu2 77.43(2) 26_556 8
Eu1 Bi4 Eu2 73.43(3) 32_554 8
Eu1 Bi4 Eu2 73.26(2) 17_556 8
Eu1 Bi4 Eu2 142.27(2) 23_565 8
Bi1 Bi4 Eu2 120.40(2) 10_454 8
Bi1 Bi4 Eu2 59.60(2) . 8
Eu1 Bi4 Eu2 142.27(2) 26_556 .
Eu1 Bi4 Eu2 73.26(2) 32_554 .
Eu1 Bi4 Eu2 73.43(3) 17_556 .
Eu1 Bi4 Eu2 77.43(2) 23_565 .
Bi1 Bi4 Eu2 59.60(2) 10_454 .
Bi1 Bi4 Eu2 120.40(2) . .
Eu2 Bi4 Eu2 138.34(3) 8 .
Eu1 Bi4 Eu2 73.26(2) 26_556 15_444
Eu1 Bi4 Eu2 142.27(2) 32_554 15_444
Eu1 Bi4 Eu2 77.43(2) 17_556 15_444
Eu1 Bi4 Eu2 73.43(3) 23_565 15_444
Bi1 Bi4 Eu2 59.60(2) 10_454 15_444
Bi1 Bi4 Eu2 120.40(2) . 15_444
Eu2 Bi4 Eu2 76.40(4) 8 15_444
Eu2 Bi4 Eu2 119.21(4) . 15_444
Eu1 Bi4 Eu2 73.43(3) 26_556 10_454
Eu1 Bi4 Eu2 77.43(2) 32_554 10_454
Eu1 Bi4 Eu2 142.27(2) 17_556 10_454
Eu1 Bi4 Eu2 73.26(2) 23_565 10_454
Bi1 Bi4 Eu2 120.40(2) 10_454 10_454
Bi1 Bi4 Eu2 59.60(2) . 10_454
Eu2 Bi4 Eu2 119.21(4) 8 10_454
Eu2 Bi4 Eu2 76.40(4) . 10_454
Eu2 Bi4 Eu2 138.34(3) 15_444 10_454
Bi2 Eu1 Bi3 116.04(4) . 16_556
Bi2 Eu1 Bi4 150.19(4) . 17_556
Bi3 Eu1 Bi4 93.30(3) 16_556 17_556
Bi2 Eu1 Bi3 88.30(3) . 1_445
Bi3 Eu1 Bi3 78.24(3) 16_556 1_445
Bi4 Eu1 Bi3 92.96(3) 17_556 1_445
Bi2 Eu1 Bi1 90.39(3) . 26_546
Bi3 Eu1 Bi1 153.50(4) 16_556 26_546
Bi4 Eu1 Bi1 60.20(2) 17_556 26_546
Bi3 Eu1 Bi1 102.02(3) 1_445 26_546
Bi2 Eu1 Bi2 91.19(3) . 6_556
Bi3 Eu1 Bi2 89.16(3) 16_556 6_556
Bi4 Eu1 Bi2 94.58(3) 17_556 6_556
Bi3 Eu1 Bi2 165.67(4) 1_445 6_556
Bi1 Eu1 Bi2 92.30(3) 26_546 6_556
Bi2 Eu1 Eu4 55.32(3) . 10_454
Bi3 Eu1 Eu4 66.03(3) 16_556 10_454
Bi4 Eu1 Eu4 144.50(4) 17_556 10_454
Bi3 Eu1 Eu4 55.94(3) 1_445 10_454
Bi1 Eu1 Eu4 136.12(4) 26_546 10_454
Bi2 Eu1 Eu4 112.68(3) 6_556 10_454
Bi2 Eu1 Eu3 55.42(2) . 2
Bi3 Eu1 Eu3 140.21(4) 16_556 2
Bi4 Eu1 Eu3 105.42(3) 17_556 2
Bi3 Eu1 Eu3 133.74(3) 1_445 2
Bi1 Eu1 Eu3 56.38(3) 26_546 2
Bi2 Eu1 Eu3 55.18(2) 6_556 2
Eu4 Eu1 Eu3 108.72(3) 10_454 2
Bi2 Eu1 Eu1 140.84(3) . 16_446
Bi3 Eu1 Eu1 53.97(3) 16_556 16_446
Bi4 Eu1 Eu1 53.70(2) 17_556 16_446
Bi3 Eu1 Eu1 53.52(3) 1_445 16_446
Bi1 Eu1 Eu1 104.53(3) 26_546 16_446
Bi2 Eu1 Eu1 123.38(4) 6_556 16_446
Eu4 Eu1 Eu1 91.42(2) 10_454 16_446
Eu3 Eu1 Eu1 158.84(2) 2 16_446
Bi2 Eu1 Eu2 147.67(4) . 24_556
Bi3 Eu1 Eu2 51.49(2) 16_556 24_556
Bi4 Eu1 Eu2 56.41(2) 17_556 24_556
Bi3 Eu1 Eu2 113.54(3) 1_445 24_556
Bi1 Eu1 Eu2 106.84(3) 26_546 24_556
Bi2 Eu1 Eu2 61.66(3) 6_556 24_556
Eu4 Eu1 Eu2 116.65(3) 10_454 24_556
Eu3 Eu1 Eu2 111.98(3) 2 24_556
Eu1 Eu1 Eu2 61.73(3) 16_446 24_556
Bi2 Eu1 Eu2 103.64(3) . 17_556
Bi3 Eu1 Eu2 113.76(3) 16_556 17_556
Bi4 Eu1 Eu2 56.31(2) 17_556 17_556
Bi3 Eu1 Eu2 51.32(3) 1_445 17_556
Bi1 Eu1 Eu2 53.71(2) 26_546 17_556
Bi2 Eu1 Eu2 142.19(4) 6_556 17_556
Eu4 Eu1 Eu2 104.25(3) 10_454 17_556
Eu3 Eu1 Eu2 105.81(3) 2 17_556
Eu1 Eu1 Eu2 61.50(3) 16_446 17_556
Eu2 Eu1 Eu2 108.62(3) 24_556 17_556
Bi2 Eu1 Eu2 112.77(3) . 31_556
Bi3 Eu1 Eu2 114.00(3) 16_556 31_556
Bi4 Eu1 Eu2 54.10(2) 17_556 31_556
Bi3 Eu1 Eu2 143.95(3) 1_445 31_556
Bi1 Eu1 Eu2 51.57(2) 26_546 31_556
Bi2 Eu1 Eu2 48.25(2) 6_556 31_556
Eu4 Eu1 Eu2 159.94(3) 10_454 31_556
Eu3 Eu1 Eu2 57.35(2) 2 31_556
Eu1 Eu1 Eu2 104.65(2) 16_446 31_556
Eu2 Eu1 Eu2 63.33(3) 24_556 31_556
Eu2 Eu1 Eu2 94.08(3) 17_556 31_556
Bi2 Eu2 Bi3 165.55(4) 19_566 17_666
Bi2 Eu2 Bi3 90.40(3) 19_566 1_444
Bi3 Eu2 Bi3 99.06(3) 17_666 1_444
Bi2 Eu2 Bi1 91.71(3) 19_566 10_454
Bi3 Eu2 Bi1 100.03(3) 17_666 10_454
Bi3 Eu2 Bi1 84.29(3) 1_444 10_454
Bi2 Eu2 Bi4 91.03(3) 19_566 .
Bi3 Eu2 Bi4 88.48(3) 17_666 .
Bi3 Eu2 Bi4 140.85(3) 1_444 .
Bi1 Eu2 Bi4 56.56(3) 10_454 .
Bi2 Eu2 Mn1 48.04(2) 19_566 1_554
Bi3 Eu2 Mn1 118.23(3) 17_666 1_554
Bi3 Eu2 Mn1 106.02(3) 1_444 1_554
Bi1 Eu2 Mn1 137.34(3) 10_454 1_554
Bi4 Eu2 Mn1 103.79(3) . 1_554
Bi2 Eu2 Bi2 85.21(3) 19_566 28_556
Bi3 Eu2 Bi2 80.43(3) 17_666 28_556
Bi3 Eu2 Bi2 137.43(4) 1_444 28_556
Bi1 Eu2 Bi2 138.06(4) 10_454 28_556
Bi4 Eu2 Bi2 81.64(3) . 28_556
Mn1 Eu2 Bi2 43.89(2) 1_554 28_556
Bi2 Eu2 Eu4 114.91(4) 19_566 19_566
Bi3 Eu2 Eu4 53.58(3) 17_666 19_566
Bi3 Eu2 Eu4 95.63(3) 1_444 19_566
Bi1 Eu2 Eu4 153.38(3) 10_454 19_566
Bi4 Eu2 Eu4 118.86(3) . 19_566
Mn1 Eu2 Eu4 68.30(3) 1_554 19_566
Bi2 Eu2 Eu4 49.85(2) 28_556 19_566
Bi2 Eu2 Eu3 54.91(3) 19_566 20_556
Bi3 Eu2 Eu3 139.35(4) 17_666 20_556
Bi3 Eu2 Eu3 51.84(3) 1_444 20_556
Bi1 Eu2 Eu3 55.00(2) 10_454 20_556
Bi4 Eu2 Eu3 99.04(3) . 20_556
Mn1 Eu2 Eu3 98.77(3) 1_554 20_556
Bi2 Eu2 Eu3 140.08(3) 28_556 20_556
Eu4 Eu2 Eu3 141.66(4) 19_566 20_556
Bi2 Eu2 Eu1 118.73(3) 19_566 32_554
Bi3 Eu2 Eu1 51.45(2) 17_666 32_554
Bi3 Eu2 Eu1 150.48(4) 1_444 32_554
Bi1 Eu2 Eu1 98.52(4) 10_454 32_554
Bi4 Eu2 Eu1 50.34(2) . 32_554
Mn1 Eu2 Eu1 91.82(3) 1_554 32_554
Bi2 Eu2 Eu1 49.17(3) 28_556 32_554
Eu4 Eu2 Eu1 68.95(3) 19_566 32_554
Eu3 Eu2 Eu1 149.32(3) 20_556 32_554
Bi2 Eu2 Eu1 135.60(4) 19_566 17_556
Bi3 Eu2 Eu1 51.69(2) 17_666 17_556
Bi3 Eu2 Eu1 106.54(3) 1_444 17_556
Bi1 Eu2 Eu1 51.25(3) 10_454 17_556
Bi4 Eu2 Eu1 50.26(2) . 17_556
Mn1 Eu2 Eu1 147.15(3) 1_554 17_556
Bi2 Eu2 Eu1 105.93(3) 28_556 17_556
Eu4 Eu2 Eu1 104.11(3) 19_566 17_556
Eu3 Eu2 Eu1 104.60(3) 20_556 17_556
Eu1 Eu2 Eu1 56.77(3) 32_554 17_556
Bi2 Eu2 Eu1 49.87(3) 19_566 23_565
Bi3 Eu2 Eu1 135.05(4) 17_666 23_565
Bi3 Eu2 Eu1 107.52(3) 1_444 23_565
Bi1 Eu2 Eu1 49.28(2) 10_454 23_565
Bi4 Eu2 Eu1 48.47(2) . 23_565
Mn1 Eu2 Eu1 88.65(3) 1_554 23_565
Bi2 Eu2 Eu1 101.63(3) 28_556 23_565
Eu4 Eu2 Eu1 151.25(3) 19_566 23_565
Eu3 Eu2 Eu1 55.88(3) 20_556 23_565
Eu1 Eu2 Eu1 95.99(3) 32_554 23_565
Eu1 Eu2 Eu1 85.74(3) 17_556 23_565
Bi3 Eu3 Bi3 90.64(5) 27_466 32_444
Bi3 Eu3 Bi2 173.39(2) 27_466 5_556
Bi3 Eu3 Bi2 90.61(2) 32_444 5_556
Bi3 Eu3 Bi2 90.61(2) 27_466 2_554
Bi3 Eu3 Bi2 173.39(2) 32_444 2_554
Bi2 Eu3 Bi2 88.88(4) 5_556 2_554
Bi3 Eu3 Bi1 97.06(3) 27_466 25
Bi3 Eu3 Bi1 86.38(2) 32_444 25
Bi2 Eu3 Bi1 89.50(3) 5_556 25
Bi2 Eu3 Bi1 87.02(2) 2_554 25
Bi3 Eu3 Bi1 86.38(2) 27_466 20_656
Bi3 Eu3 Bi1 97.06(3) 32_444 20_656
Bi2 Eu3 Bi1 87.02(2) 5_556 20_656
Bi2 Eu3 Bi1 89.50(3) 2_554 20_656
Bi1 Eu3 Bi1 175.12(5) 25 20_656
Bi3 Eu3 Eu4 55.83(2) 27_466 20_657
Bi3 Eu3 Eu4 117.74(4) 32_444 20_657
Bi2 Eu3 Eu4 128.74(4) 5_556 20_657
Bi2 Eu3 Eu4 58.13(2) 2_554 20_657
Bi1 Eu3 Eu4 54.25(2) 25 20_657
Bi1 Eu3 Eu4 126.16(2) 20_656 20_657
Bi3 Eu3 Eu4 117.74(4) 27_466 23_665
Bi3 Eu3 Eu4 55.83(2) 32_444 23_665
Bi2 Eu3 Eu4 58.13(2) 5_556 23_665
Bi2 Eu3 Eu4 128.74(4) 2_554 23_665
Bi1 Eu3 Eu4 126.17(2) 25 23_665
Bi1 Eu3 Eu4 54.25(2) 20_656 23_665
Eu4 Eu3 Eu4 172.15(5) 20_657 23_665
Bi3 Eu3 Eu1 129.96(2) 27_466 2_554
Bi3 Eu3 Eu1 121.61(2) 32_444 2_554
Bi2 Eu3 Eu1 54.05(3) 5_556 2_554
Bi2 Eu3 Eu1 53.32(3) 2_554 2_554
Bi1 Eu3 Eu1 53.61(2) 25 2_554
Bi1 Eu3 Eu1 121.51(4) 20_656 2_554
Eu4 Eu3 Eu1 74.73(3) 20_657 2_554
Eu4 Eu3 Eu1 112.14(3) 23_665 2_554
Bi3 Eu3 Eu1 121.61(2) 27_466 5_556
Bi3 Eu3 Eu1 129.96(2) 32_444 5_556
Bi2 Eu3 Eu1 53.32(3) 5_556 5_556
Bi2 Eu3 Eu1 54.05(3) 2_554 5_556
Bi1 Eu3 Eu1 121.51(4) 25 5_556
Bi1 Eu3 Eu1 53.61(2) 20_656 5_556
Eu4 Eu3 Eu1 112.14(3) 20_657 5_556
Eu4 Eu3 Eu1 74.73(3) 23_665 5_556
Eu1 Eu3 Eu1 67.91(4) 2_554 5_556
Bi3 Eu3 Eu2 133.28(4) 27_466 32
Bi3 Eu3 Eu2 55.11(2) 32_444 32
Bi2 Eu3 Eu2 51.92(2) 5_556 32
Bi2 Eu3 Eu2 120.09(4) 2_554 32
Bi1 Eu3 Eu2 54.93(2) 25 32
Bi1 Eu3 Eu2 124.59(2) 20_656 32
Eu4 Eu3 Eu2 109.13(2) 20_657 32
Eu4 Eu3 Eu2 71.54(2) 23_665 32
Eu1 Eu3 Eu2 66.77(3) 2_554 32
Eu1 Eu3 Eu2 105.10(3) 5_556 32
Bi3 Eu3 Eu2 55.11(2) 27_466 27
Bi3 Eu3 Eu2 133.28(4) 32_444 27
Bi2 Eu3 Eu2 120.09(4) 5_556 27
Bi2 Eu3 Eu2 51.92(2) 2_554 27
Bi1 Eu3 Eu2 124.59(2) 25 27
Bi1 Eu3 Eu2 54.93(2) 20_656 27
Eu4 Eu3 Eu2 71.54(2) 20_657 27
Eu4 Eu3 Eu2 109.13(2) 23_665 27
Eu1 Eu3 Eu2 105.10(3) 2_554 27
Eu1 Eu3 Eu2 66.77(3) 5_556 27
Eu2 Eu3 Eu2 170.73(5) 32 27
Bi2 Eu4 Bi3 90.53(3) 10_454 4_464
Bi2 Eu4 Bi1 167.04(4) 10_454 11_545
Bi3 Eu4 Bi1 88.25(3) 4_464 11_545
Bi2 Eu4 Bi3 88.72(3) 10_454 10_564
Bi3 Eu4 Bi3 150.58(4) 4_464 10_564
Bi1 Eu4 Bi3 98.64(3) 11_545 10_564
Bi2 Eu4 Bi2 82.07(4) 10_454 28_557
Bi3 Eu4 Bi2 121.35(4) 4_464 28_557
Bi1 Eu4 Bi2 87.55(3) 11_545 28_557
Bi3 Eu4 Bi2 87.66(3) 10_564 28_557
Bi2 Eu4 Eu1 55.82(3) 10_454 10_454
Bi3 Eu4 Eu1 100.08(3) 4_464 10_454
Bi1 Eu4 Eu1 137.04(4) 11_545 10_454
Bi3 Eu4 Eu1 56.08(3) 10_564 10_454
Bi2 Eu4 Eu1 121.16(3) 28_557 10_454
Bi2 Eu4 Eu3 120.45(3) 10_454 27_566
Bi3 Eu4 Eu3 145.15(4) 4_464 27_566
Bi1 Eu4 Eu3 57.89(2) 11_545 27_566
Bi3 Eu4 Eu3 54.17(3) 10_564 27_566
Bi2 Eu4 Eu3 55.37(3) 28_557 27_566
Eu1 Eu4 Eu3 110.24(3) 10_454 27_566
Bi2 Eu4 Bi3 103.51(3) 10_454 7_446
Bi3 Eu4 Bi3 80.53(3) 4_464 7_446
Bi1 Eu4 Bi3 89.02(3) 11_545 7_446
Bi3 Eu4 Bi3 71.10(3) 10_564 7_446
Bi2 Eu4 Bi3 157.71(3) 28_557 7_446
Eu1 Eu4 Bi3 51.87(2) 10_454 7_446
Eu3 Eu4 Bi3 104.72(3) 27_566 7_446
Bi2 Eu4 Eu2 64.88(3) 10_454 28_556
Bi3 Eu4 Eu2 54.08(3) 4_464 28_556
Bi1 Eu4 Eu2 104.34(3) 11_545 28_556
Bi3 Eu4 Eu2 147.33(4) 10_564 28_556
Bi2 Eu4 Eu2 70.67(3) 28_557 28_556
Eu1 Eu4 Eu2 114.68(3) 10_454 28_556
Eu3 Eu4 Eu2 122.13(4) 27_566 28_556
Bi3 Eu4 Eu2 131.39(3) 7_446 28_556
Bi2 Eu4 Eu3 131.98(4) 10_454 26_556
Bi3 Eu4 Eu3 51.71(2) 4_464 26_556
Bi1 Eu4 Eu3 55.14(2) 11_545 26_556
Bi3 Eu4 Eu3 110.08(3) 10_564 26_556
Bi2 Eu4 Eu3 139.88(3) 28_557 26_556
Eu1 Eu4 Eu3 98.06(3) 10_454 26_556
Eu3 Eu4 Eu3 105.77(3) 27_566 26_556
Bi3 Eu4 Eu3 48.84(2) 7_446 26_556
Eu2 Eu4 Eu3 102.10(3) 28_556 26_556
Bi2 Eu4 Eu4 141.79(2) 10_454 16_556
Bi3 Eu4 Eu4 106.15(4) 4_464 16_556
Bi1 Eu4 Eu4 50.43(2) 11_545 16_556
Bi3 Eu4 Eu4 59.97(3) 10_564 16_556
Bi2 Eu4 Eu4 115.04(4) 28_557 16_556
Eu1 Eu4 Eu4 87.05(2) 10_454 16_556
Eu3 Eu4 Eu4 60.18(3) 27_566 16_556
Bi3 Eu4 Eu4 48.45(2) 7_446 16_556
Eu2 Eu4 Eu4 151.49(3) 28_556 16_556
Eu3 Eu4 Eu4 54.50(3) 26_556 16_556
Bi2 Mn1 Bi2 104.69(2) 28_557 .
Bi2 Mn1 Bi2 104.69(2) 28_557 10_454
Bi2 Mn1 Bi2 119.54(3) . 10_454
Bi2 Mn1 Bi2 119.54(3) 28_557 19_567
Bi2 Mn1 Bi2 104.69(2) . 19_567
Bi2 Mn1 Bi2 104.69(2) 10_454 19_567
Bi2 Mn1 Eu2 59.53(2) 28_557 10_455
Bi2 Mn1 Eu2 156.51(2) . 10_455
Bi2 Mn1 Eu2 82.90(3) 10_454 10_455
Bi2 Mn1 Eu2 73.36(2) 19_567 10_455
Bi2 Mn1 Eu2 73.36(2) 28_557 1_556
Bi2 Mn1 Eu2 82.90(3) . 1_556
Bi2 Mn1 Eu2 156.51(2) 10_454 1_556
Bi2 Mn1 Eu2 59.53(2) 19_567 1_556
Eu2 Mn1 Eu2 76.01(4) 10_455 1_556
Bi2 Mn1 Eu2 156.51(2) 28_557 19_566
Bi2 Mn1 Eu2 73.36(2) . 19_566
Bi2 Mn1 Eu2 59.53(2) 10_454 19_566
Bi2 Mn1 Eu2 82.90(3) 19_567 19_566
Eu2 Mn1 Eu2 128.38(2) 10_455 19_566
Eu2 Mn1 Eu2 128.38(2) 1_556 19_566
Bi2 Mn1 Eu2 82.90(3) 28_557 28_556
Bi2 Mn1 Eu2 59.53(2) . 28_556
Bi2 Mn1 Eu2 73.36(2) 10_454 28_556
Bi2 Mn1 Eu2 156.51(2) 19_567 28_556
Eu2 Mn1 Eu2 128.38(2) 10_455 28_556
Eu2 Mn1 Eu2 128.38(2) 1_556 28_556
Eu2 Mn1 Eu2 76.01(4) 19_566 28_556
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Bi1 Eu4 3.367(2) 12_453
Bi1 Eu4 3.367(2) 5_556
Bi1 Bi4 3.3965(13) .
Bi1 Eu1 3.3967(13) 26_556
Bi1 Eu1 3.3968(13) 32_554
Bi1 Eu2 3.5108(13) 8
Bi1 Eu2 3.5108(14) 10_454
Bi1 Eu3 3.5138(8) 25
Bi1 Eu3 3.5138(8) 27_565
Bi2 Mn1 2.8615(9) .
Bi2 Eu2 3.3168(14) 28_556
Bi2 Eu4 3.338(2) 10_454
Bi2 Eu1 3.358(2) .
Bi2 Eu1 3.3994(15) 6_556
Bi2 Eu3 3.4476(15) 2
Bi2 Eu4 3.5582(14) 19_567
Bi2 Eu2 3.954(2) 19_566
Bi3 Eu3 3.3153(15) 20_667
Bi3 Eu4 3.3504(15) 3_655
Bi3 Eu1 3.3696(15) 16_556
Bi3 Eu2 3.3718(15) 17_666
Bi3 Eu4 3.3832(14) 10_564
Bi3 Eu1 3.3890(14) 1_665
Bi3 Eu2 3.4584(15) 1_666
Bi3 Eu4 3.914(2) 7_556
Bi4 Eu1 3.3758(13) 26_556
Bi4 Eu1 3.3758(13) 32_554
Bi4 Eu1 3.3758(13) 17_556
Bi4 Eu1 3.3758(13) 23_565
Bi4 Bi1 3.3965(13) 10_454
Bi4 Eu2 3.6530(13) 8
Bi4 Eu2 3.6530(13) .
Bi4 Eu2 3.6530(13) 15_444
Bi4 Eu2 3.6530(13) 10_454
Eu1 Bi3 3.3696(15) 16_556
Eu1 Bi4 3.3758(13) 17_556
Eu1 Bi3 3.3890(14) 1_445
Eu1 Bi1 3.3967(13) 26_546
Eu1 Bi2 3.3994(15) 6_556
Eu1 Eu4 3.786(2) 10_454
Eu1 Eu3 3.965(2) 2
Eu1 Eu1 3.997(2) 16_446
Eu1 Eu2 4.199(2) 24_556
Eu1 Eu2 4.208(2) 17_556
Eu1 Eu2 4.401(2) 31_556
Eu2 Bi2 3.3168(14) 19_566
Eu2 Bi3 3.3718(15) 17_666
Eu2 Bi3 3.4584(15) 1_444
Eu2 Bi1 3.5108(13) 10_454
Eu2 Mn1 3.6691(13) 1_554
Eu2 Bi2 3.954(2) 28_556
Eu2 Eu4 3.967(2) 19_566
Eu2 Eu3 4.0328(14) 20_556
Eu2 Eu1 4.199(2) 32_554
Eu2 Eu1 4.208(2) 17_556
Eu2 Eu1 4.401(2) 23_565
Eu3 Bi3 3.3153(15) 27_466
Eu3 Bi3 3.3153(15) 32_444
Eu3 Bi2 3.4476(15) 5_556
Eu3 Bi2 3.4476(15) 2_554
Eu3 Bi1 3.5138(8) 25
Eu3 Bi1 3.5138(8) 20_656
Eu3 Eu4 3.8427(13) 20_657
Eu3 Eu4 3.8427(13) 23_665
Eu3 Eu1 3.965(2) 2_554
Eu3 Eu1 3.965(2) 5_556
Eu3 Eu2 4.0328(14) 32
Eu3 Eu2 4.0328(14) 27
Eu4 Bi2 3.338(2) 10_454
Eu4 Bi3 3.3504(15) 4_464
Eu4 Bi1 3.367(2) 11_545
Eu4 Bi3 3.3832(14) 10_564
Eu4 Bi2 3.5582(14) 28_557
Eu4 Eu1 3.786(2) 10_454
Eu4 Eu3 3.8427(13) 27_566
Eu4 Bi3 3.914(2) 7_446
Eu4 Eu2 3.967(2) 28_556
Eu4 Eu3 4.095(2) 26_556
Eu4 Eu4 4.289(2) 16_556
Mn1 Bi2 2.8615(9) 28_557
Mn1 Bi2 2.8615(9) 10_454
Mn1 Bi2 2.8615(9) 19_567
Mn1 Eu2 3.6691(13) 10_455
Mn1 Eu2 3.6691(13) 1_556
Mn1 Eu2 3.6691(13) 19_566
Mn1 Eu2 3.6691(13) 28_556
