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Information card for entry 4075220
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| Coordinates | 4075220.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | 16 |
|---|---|
| Chemical name | Bis[N-(triphenylphosphinimino)phenylacetimidato-N',O]methylsiliconium chloride |
| Formula | C58.5 H55.5 Cl11.5 N4 O2.5 P2 Si |
| Calculated formula | C58.5 H55.5 Cl11.5 N4 O2.5 P2 Si |
| Title of publication | Donor-Stabilized Silyl Cations. 10. Pentacoordinate Siliconium-Ion Salts with a Triphenylphosphinimino-NLigand Group: Two-Bond P−N−Si Coupling as a Measure for Coordination Strength1 |
| Authors of publication | Sivaramakrishna, Akella; Kalikhman, Inna; Kertsnus, Evgenia; Korlyukov, Alexander A.; Kost, Daniel |
| Journal of publication | Organometallics |
| Year of publication | 2006 |
| Journal volume | 25 |
| Journal issue | 15 |
| Pages of publication | 3665 |
| a | 14.167 ± 0.004 Å |
| b | 16.592 ± 0.003 Å |
| c | 17.193 ± 0.004 Å |
| α | 61.488 ± 0.004° |
| β | 68.668 ± 0.004° |
| γ | 83.82 ± 0.006° |
| Cell volume | 3297.1 ± 1.4 Å3 |
| Cell temperature | 120 ± 2 K |
| Ambient diffraction temperature | 120 ± 2 K |
| Number of distinct elements | 7 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.1245 |
| Residual factor for significantly intense reflections | 0.0637 |
| Weighted residual factors for significantly intense reflections | 0.1238 |
| Weighted residual factors for all reflections included in the refinement | 0.1369 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.023 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 176467 (current) | 2016-02-16 | cif/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in range 4. |
4075220.cif |
| 171438 | 2015-12-11 | cod/ (antanas@echidna.ibt.lt) Replacing '’' sequences with a quotation mark ("'") in _chemical_name_systematic tag values in multiple entries. |
4075220.cif |
| 120075 | 2014-07-11 | Adding DOIs to range 4/07 structures. | 4075220.cif |
| 49122 | 2012-03-27 | ../uploads/cif-deposit/cod/cif Adding structures of 4075220 via cif-deposit CGI script. |
4075220.cif |
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Users of the data should acknowledge the original authors of the
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