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Information card for entry 4102723
Preview
| Coordinates | 4102723.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | (Ar[CH2tBu]N)2(C(H)tBuNAr)TaOC(H)NtBu |
|---|---|
| Formula | C44 H69 N4 O Ta |
| Calculated formula | C44 H69 N4 O Ta |
| Title of publication | Carbon Dioxide Reduction by Terminal Tantalum Hydrides: Formation and Isolation of Bridging Methylene Diolate Complexes |
| Authors of publication | Matthew A. Rankin; Christopher C. Cummins |
| Journal of publication | Journal of the American Chemical Society |
| Year of publication | 2010 |
| Journal volume | 132 |
| Pages of publication | 10021 - 10023 |
| a | 10.7775 ± 0.0012 Å |
| b | 13.8137 ± 0.0015 Å |
| c | 15.7172 ± 0.0017 Å |
| α | 86.206 ± 0.002° |
| β | 72.564 ± 0.002° |
| γ | 77.292 ± 0.002° |
| Cell volume | 2177.7 ± 0.4 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 5 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0284 |
| Residual factor for significantly intense reflections | 0.024 |
| Weighted residual factors for significantly intense reflections | 0.0549 |
| Weighted residual factors for all reflections included in the refinement | 0.0574 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.053 |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 178773 (current) | 2016-03-21 | cif/4/10/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/10/27. |
4102723.cif |
| 120076 | 2014-07-11 | Adding DOIs to range 4/10 structures. | 4102723.cif |
| 34330 | 2012-02-24 | cif/4/ Reorganising CIF range 4 into a prefix tree. |
4102723.cif |
| 25625 | 2011-09-12 | ../uploads/cif-deposit/cod/cif Adding structures of 4102723 via cif-deposit CGI script. |
4102723.cif |
All data in the COD and the database itself are dedicated to the
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Users of the data should acknowledge the original authors of the
structural data.