#------------------------------------------------------------------------------ #$Date: 2015-03-10 02:02:58 +0200 (Tue, 10 Mar 2015) $ #$Revision: 133720 $ #$URL: file:///home/coder/svn-repositories/cod/cif/4/12/34/4123497.cif $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_4123497 loop_ _publ_author_name 'Wang, Timothy C.' 'Bury, Wojciech' 'Gomez-Gualdron, Diego A' 'Vermeulen, Nicolaas A.' 'Mondloch, Joseph E.' 'Deria, Pravas' 'Zhang, Kainan' 'Moghadam, Peyman Z.' 'Sarjeant, Amy A.' 'Snurr, Randall Q.' 'Stoddart, J. Fraser' 'Hupp, Joseph T.' 'Farha, Omar K.' _publ_section_title ; Ultrahigh Surface Area Zirconium MOFs and Insights into the Applicability of the BET Theory. ; _journal_name_full 'Journal of the American Chemical Society' _journal_page_first 150309080817005 _journal_paper_doi 10.1021/ja512973b _journal_year 2015 _chemical_formula_moiety 'C228 H114 O32 Zr6' _chemical_formula_sum 'C228 H114 O32 Zr6' _chemical_formula_weight 3912.51 _chemical_name_systematic ; ? ; _space_group_crystal_system cubic _space_group_IT_number 221 _space_group_name_Hall '-P 4 2 3' _space_group_name_H-M_alt 'P m -3 m' _symmetry_space_group_name_Hall '-P 4 2 3' _symmetry_space_group_name_H-M 'P m -3 m' _atom_sites_solution_hydrogens mixed _atom_sites_solution_primary direct _audit_creation_date 2013-10-23 _audit_creation_method ; Olex2 1.2 (compiled 2013.09.17 svn.r2790 for OlexSys, GUI svn.r4601) ; _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 1 _cell_length_a 27.9293(5) _cell_length_b 27.9293(5) _cell_length_c 27.9293(5) _cell_measurement_reflns_used 9113 _cell_measurement_temperature 225(2) _cell_measurement_theta_max 67.606 _cell_measurement_theta_min 2.740 _cell_volume 21786.1(7) _computing_cell_refinement 'SAINT V7.23A (Bruker, 2005)' _computing_data_collection 'APEX2 V2.1-4 (Bruker, 2007)' _computing_data_reduction 'Bruker SAINT' _computing_molecular_graphics ; O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann, OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Cryst. (2009). 42, 339-341. ; _computing_publication_material ; O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann, OLEX2: a complete structure solution, refinement and analysis program. J. Appl. Cryst. (2009). 42, 339-341. ; _computing_structure_refinement ; SHELX, G.M. Sheldrick, Acta Cryst. (2008). A64, 112-122 ; _computing_structure_solution ; SHELX, G.M. Sheldrick, Acta Cryst. (2008). A64, 112-122 ; _diffrn_ambient_temperature 225.0 _diffrn_detector_area_resol_mean 8 _diffrn_measured_fraction_theta_full 0.999 _diffrn_measured_fraction_theta_max 0.994 _diffrn_measurement_device_type 'Bruker Kappa APEX CCD area detector' _diffrn_measurement_method '\w and \f scans' _diffrn_radiation_monochromator 'MX optics' _diffrn_radiation_type CuK\a _diffrn_radiation_wavelength 1.54178 _diffrn_reflns_av_R_equivalents 0.0614 _diffrn_reflns_av_unetI/netI 0.0172 _diffrn_reflns_laue_measured_fraction_full 0.999 _diffrn_reflns_laue_measured_fraction_max 0.994 _diffrn_reflns_limit_h_max 33 _diffrn_reflns_limit_h_min -33 _diffrn_reflns_limit_k_max 32 _diffrn_reflns_limit_k_min -32 _diffrn_reflns_limit_l_max 26 _diffrn_reflns_limit_l_min -31 _diffrn_reflns_number 103147 _diffrn_reflns_point_group_measured_fraction_full 0.999 _diffrn_reflns_point_group_measured_fraction_max 0.994 _diffrn_reflns_theta_full 67.679 _diffrn_reflns_theta_max 68.29 _diffrn_reflns_theta_min 1.58 _diffrn_source microsource _exptl_absorpt_coefficient_mu 0.698 _exptl_absorpt_correction_T_max 0.7530 _exptl_absorpt_correction_T_min 0.6922 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_process_details ; SADABS-2012/1 (Bruker,2012) was used for absorption correction. wR2(int) was 0.0810 before and 0.0624 after correction. The Ratio of minimum to maximum transmission is 0.9193. The \l/2 correction factor is 0.0015. ; _exptl_crystal_colour yellow _exptl_crystal_colour_primary yellow _exptl_crystal_density_diffrn 0.298 _exptl_crystal_description cube _exptl_crystal_F_000 1978 _exptl_crystal_size_max 0.099 _exptl_crystal_size_mid 0.098 _exptl_crystal_size_min 0.084 _refine_diff_density_max 2.467 _refine_diff_density_min -1.185 _refine_diff_density_rms 0.119 _refine_ls_extinction_method none _refine_ls_goodness_of_fit_ref 1.653 _refine_ls_hydrogen_treatment mixed _refine_ls_matrix_type full _refine_ls_number_parameters 201 _refine_ls_number_reflns 3871 _refine_ls_number_restraints 3763 _refine_ls_restrained_S_all 1.544 _refine_ls_R_factor_all 0.1143 _refine_ls_R_factor_gt 0.1071 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 _refine_ls_structure_factor_coef Fsqd _refine_ls_weighting_details 'w=1/[\s^2^(Fo^2^)+(0.2000P)^2^] where P=(Fo^2^+2Fc^2^)/3' _refine_ls_weighting_scheme calc _refine_ls_wR_factor_gt 0.3332 _refine_ls_wR_factor_ref 0.3502 _reflns_Friedel_coverage 0.000 _reflns_number_gt 3266 _reflns_number_total 3871 _reflns_threshold_expression 'I > 2\s(I)' _[local]_cod_data_source_file ja512973b_si_004.cif _[local]_cod_data_source_block n3147b_a _cod_original_cell_volume 21786.1(12) _cod_database_code 4123497 _shelxl_version_number 2013-4 _shelx_space_group_comment ; The symmetry employed for this shelxl refinement is uniquely defined by the following loop, which should always be used as a source of symmetry information in preference to the above space-group names. They are only intended as comments. ; _shelx_estimated_absorpt_t_max 0.944 _shelx_estimated_absorpt_t_min 0.934 _olex2_refinement_description ; 1. Fixed Uiso At 1.2 times of: All C(H) groups 2. Restrained distances C18-H18 = C49-H49 0.94 with sigma of 0.001 C1-C2 \\sim C16-C17 \\sim C31-C32 \\sim C46-C47 \\sim C8-C5 \\sim C23-C20 \\sim C38-C35 \\sim C53-C50 - C10-C9 \\sim C25-C24 \\sim C40-C39 \\sim C54-C55 \\sim C13-C61 \\sim C28-C66 \\sim C43-C68 \\sim C58-C73 with sigma of 0.02 C9-C8 \\sim C24-C23 \\sim C39-C38 \\sim C54-C53 with sigma of 0.02 C61-C74 \\sim C61-C62 \\sim C63-C62 \\sim C64-C63 \\sim C65-C64 \\sim C65-C66 \\sim C67-C66 \\sim C68-C67 \\sim C69-C68 \\sim C70-C69 \\sim C71-C70 \\sim C72-C71 \\sim C72-C73 \\sim C74-C73 \\sim C62-C75 \\sim C65- C76 \\sim C76-C69 \\sim C76-C75 \\sim C72-C75 with sigma of 0.02 C61-C73 \\sim C74-C72 \\sim C71-C69 \\sim C70-C76 \\sim C68-C66 \\sim C67-C65 \\sim C64-C62 \\sim C63-C75 with sigma of 0.02 C61-C72 \\sim C62-C73 \\sim C75-C74 \\sim C76-C67 \\sim C66-C69 \\sim C68-C65 \\sim C65-C62 \\sim C63-C76 \\sim C64-C75 \\sim C69-C72 \\sim C70-C75 \\sim C71-C76 with sigma of 0.02 C58-C74 \\sim C13-C62 \\sim C28-C67 \\sim C43-C69 \\sim C58-C72 \\sim C13-C74 \\sim C28-C65 \\sim C43-C67 with sigma of 0.02 C57-C73 \\sim C12-C61 \\sim C27-C66 \\sim C42-C68 \\sim C49-C53 \\sim C4-C8 \\sim C19-C23 \\sim C34-C38 - C59-C73 \\sim C14-C61 \\sim C29-C66 \\sim C44-C68 \\sim C51-C53 \\sim C6-C8 \\sim C21-C23 \\sim C36-C38 with sigma of 0.02 C45-C39 \\sim C60-C54 \\sim C15-C9 \\sim C30-C24 \\sim C41-C39 \\sim C56-C54 \\sim C11-C9 \\sim C26-C24 with sigma of 0.02 C39-C34 \\sim C38-C41 \\sim C54-C49 \\sim C53-C56 \\sim C9-C4 \\sim C8-C11 \\sim C24-C19 \\sim C23-C26 - C39-C36 \\sim C38-C45 \\sim C54-C51 \\sim C53-C60 \\sim C9-C6 \\sim C8-C15 \\sim C24-C21 \\sim C23-C30 with sigma of 0.02 C15-C10 \\sim C11-C10 \\sim C12-C11 \\sim C13-C12 \\sim C14-C13 \\sim C15-C14 \\sim C7-C2 \\sim C7-C6 - C6-C5 \\sim C5-C4 \\sim C4-C3 \\sim C3-C2 \\sim C33-C32 \\sim C34-C33 \\sim C35-C34 \\sim C36-C35 \\sim C37- C36 \\sim C37-C32 \\sim C56-C55 \\sim C57-C56 \\sim C58-C57 \\sim C59-C58 \\sim C60-C59 \\sim C60-C55 - C41-C40 \\sim C42-C41 \\sim C43-C42 \\sim C44-C43 \\sim C45-C44 \\sim C45-C40 \\sim C30-C25 \\sim C30-C29 \\sim C29-C28 \\sim C28-C27 \\sim C27-C26 \\sim C26-C25 \\sim C48-C47 \\sim C49-C48 \\sim C50-C49 \\sim C51- C50 \\sim C52-C51 \\sim C52-C47 \\sim C18-C17 \\sim C19-C18 \\sim C20-C19 \\sim C21-C20 \\sim C22-C21 - C22-C17 with sigma of 0.02 C10-C13 \\sim C11-C14 \\sim C12-C15 \\sim C25-C28 \\sim C26-C29 \\sim C27-C30 \\sim C40-C43 \\sim C41-C44 \\sim C42-C45 \\sim C55-C58 \\sim C56-C59 \\sim C57-C60 \\sim C32-C35 \\sim C33-C36 \\sim C34-C37 \\sim C17- C20 \\sim C18-C21 \\sim C19-C22 \\sim C47-C50 \\sim C48-C51 \\sim C49-C52 \\sim C2-C5 \\sim C7-C4 \\sim C6-C3 with sigma of 0.02 C10-C12 \\sim C11-C13 \\sim C12-C14 \\sim C13-C15 \\sim C14-C10 \\sim C15-C11 \\sim C25-C27 \\sim C26-C28 \\sim C27-C29 \\sim C28-C30 \\sim C29-C25 \\sim C30-C26 \\sim C40-C42 \\sim C41-C43 \\sim C42-C44 \\sim C43- C45 \\sim C44-C40 \\sim C45-C41 \\sim C55-C57 \\sim C56-C58 \\sim C57-C59 \\sim C58-C60 \\sim C59-C55 - C60-C56 \\sim C47-C49 \\sim C48-C50 \\sim C49-C51 \\sim C50-C52 \\sim C51-C47 \\sim C52-C48 \\sim C32-C34 \\sim C33-C35 \\sim C34-C36 \\sim C35-C37 \\sim C36-C32 \\sim C37-C33 \\sim C17-C19 \\sim C18-C20 \\sim C19- C21 \\sim C20-C22 \\sim C21-C17 \\sim C22-C18 \\sim C2-C6 \\sim C7-C5 \\sim C6-C4 \\sim C5-C3 \\sim C4-C2 \\sim C3- C7 with sigma of 0.02 C31-C33 \\sim C31-C37 with sigma of 0.02 O1-C1 \\sim O1_$1-C1 \\sim C31-O1_$2 \\sim C31-O1_$3 \\sim O1_$4-C46 \\sim O1_$5-C46 \\sim O1_$6-C16 \\sim C16-O1_$7 with sigma of 0.02 C1-C3 \\sim C1-C7 with sigma of 0.02 C16-C18 \\sim C16-C22 with sigma of 0.02 C46-C48 \\sim C46-C52 with sigma of 0.02 C15-H14 \\sim C13-H14 with sigma of 0.02 C10-C5 \\sim C55-C50 \\sim C40-C35 \\sim C25-C20 with sigma of 0.01 C17-H18 \\sim C19-H18 with sigma of 0.02 3. Restrained planarity C17, C18, C19, C20, C21, C22 with sigma of 0.1 C66, C67, C68, C69, C76, C65, C70, C71, C72, C75, C62, C63, C64, C73, C74, C61 with sigma of 0.1 C10, C11, C12, C13, C14, C15 with sigma of 0.1 C25, C26, C27, C28, C29, C30, C24, C66 with sigma of 0.1 C40, C41, C42, C43, C44, C45, C39, C68, H44 with sigma of 0.01 C55, C56, C57, C58, C59, C60, C54, C73 with sigma of 0.1 C47, C48, C49, C50, C51, C52, H49 with sigma of 0.1 C32, C33, C34, C35, C36, C37, C31 with sigma of 0.1 C2, C7, C6, C5, C4, C3 with sigma of 0.1 4. Uiso/Uaniso restraints and constraints Uanis(C66) \\sim Ueq, Uanis(C67) \\sim Ueq, Uanis(C68) \\sim Ueq, Uanis(C69) \\sim Ueq, Uanis(C76) \\sim Ueq, Uanis(C65) \\sim Ueq, Uanis(C70) \\sim Ueq, Uanis(C71) \\sim Ueq, Uanis(C72) \\sim Ueq, Uanis(C75) \\sim Ueq, Uanis(C62) \\sim Ueq, Uanis(C63) \\sim Ueq, Uanis(C64) \\sim Ueq, Uanis(C73) \\sim Ueq, Uanis(C74) \\sim Ueq, Uanis(C61) \\sim Ueq, Uanis(C17) \\sim Ueq, Uanis(C18) \\sim Ueq, Uanis(C19) \\sim Ueq, Uanis(C20) \\sim Ueq, Uanis(C21) \\sim Ueq, Uanis(C22) \\sim Ueq, Uanis(C32) \\sim Ueq, Uanis(C33) \\sim Ueq, Uanis(C34) \\sim Ueq, Uanis(C35) \\sim Ueq, Uanis(C36) \\sim Ueq, Uanis(C37) \\sim Ueq, Uanis(C47) \\sim Ueq, Uanis(C48) \\sim Ueq, Uanis(C49) \\sim Ueq, Uanis(C50) \\sim Ueq, Uanis(C51) \\sim Ueq, Uanis(C52) \\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C3) \\sim Ueq, Uanis(C4) \\sim Ueq, Uanis(C5) \\sim Ueq, Uanis(C6) \\sim Ueq, Uanis(C7) \\sim Ueq, Uanis(C38) \\sim Ueq, Uanis(C39) \\sim Ueq, Uanis(C8) \\sim Ueq, Uanis(C9) \\sim Ueq, Uanis(C23) \\sim Ueq, Uanis(C24) \\sim Ueq, Uanis(C16) \\sim Ueq, Uanis(C53) \\sim Ueq, Uanis(C46) \\sim Ueq, Uanis(C31) \\sim Ueq, Uanis(C1) \\sim Ueq, Uanis(C55) \\sim Ueq, Uanis(C56) \\sim Ueq, Uanis(C57) \\sim Ueq, Uanis(C58) \\sim Ueq, Uanis(C59) \\sim Ueq, Uanis(C60) \\sim Ueq, Uanis(C25) \\sim Ueq, Uanis(C26) \\sim Ueq, Uanis(C27) \\sim Ueq, Uanis(C28) \\sim Ueq, Uanis(C29) \\sim Ueq, Uanis(C30) \\sim Ueq, Uanis(C40) \\sim Ueq, Uanis(C41) \\sim Ueq, Uanis(C42) \\sim Ueq, Uanis(C43) \\sim Ueq, Uanis(C44) \\sim Ueq, Uanis(C45) \\sim Ueq, Uanis(C54) \\sim Ueq, Uanis(C10) \\sim Ueq, Uanis(C11) \\sim Ueq, Uanis(C12) \\sim Ueq, Uanis(C13) \\sim Ueq, Uanis(C14) \\sim Ueq, Uanis(C15) \\sim Ueq: with sigma of 0.1 and sigma for terminal atoms of 0.2 Uanis(C66) = Uanis(C67) = Uanis(C68) = Uanis(C69) = Uanis(C76) = Uanis(C65) = Uanis(C70) = Uanis(C71) = Uanis(C72) = Uanis(C75) = Uanis(C62) = Uanis(C63) = Uanis(C64) = Uanis(C73) = Uanis(C74) = Uanis(C61) = Uanis(C17) = Uanis(C18) = Uanis(C19) = Uanis(C20) = Uanis(C21) = Uanis(C22) = Uanis(C32) = Uanis(C33) = Uanis(C34) = Uanis(C35) = Uanis(C36) = Uanis(C37) = Uanis(C47) = Uanis(C48) = Uanis(C49) = Uanis(C50) = Uanis(C51) = Uanis(C52) = Uanis(C2) = Uanis(C3) = Uanis(C4) = Uanis(C5) = Uanis(C6) = Uanis(C7) = Uanis(C38) = Uanis(C39) = Uanis(C8) = Uanis(C9) = Uanis(C23) = Uanis(C24) = Uanis(C16) = Uanis(C53) = Uanis(C46) = Uanis(C31) = Uanis(C1) = Uanis(C55) = Uanis(C56) = Uanis(C57) = Uanis(C58) = Uanis(C59) = Uanis(C60) = Uanis(C25) = Uanis(C26) = Uanis(C27) = Uanis(C28) = Uanis(C29) = Uanis(C30) = Uanis(C40) = Uanis(C41) = Uanis(C42) = Uanis(C43) = Uanis(C44) = Uanis(C45) = Uanis(C54) = Uanis(C10) = Uanis(C11) = Uanis(C12) = Uanis(C13) = Uanis(C14) = Uanis(C15) 5. Others Fixed Sof: C1(0.0625) C2(0.0625) C3(0.0625) H3(0.0625) C4(0.0625) H4(0.0625) C5(0.0625) C6(0.0625) H6(0.0625) C7(0.0625) H7(0.0625) C8(0.0625) C9(0.0625) C10(0.0625) C11(0.0625) H11(0.0625) C12(0.0625) H12(0.0625) C13(0.0625) C14(0.0625) H14(0.0625) C15(0.0625) H15(0.0625) C16(0.0625) C17(0.0625) C18(0.0625) H18(0.0625) C19(0.0625) H19(0.0625) C20(0.0625) C21(0.0625) H21(0.0625) C22(0.0625) H22(0.0625) C23(0.0625) C24(0.0625) C25(0.0625) C26(0.0625) H26(0.0625) C27(0.0625) H27(0.0625) C28(0.0625) C29(0.0625) H29(0.0625) C30(0.0625) H30(0.0625) C31(0.0625) C32(0.0625) C33(0.0625) H33(0.0625) C34(0.0625) H34(0.0625) C35(0.0625) C36(0.0625) H36(0.0625) C37(0.0625) H37(0.0625) C38(0.0625) C39(0.0625) C40(0.0625) C41(0.0625) H41(0.0625) C42(0.0625) H42(0.0625) C43(0.0625) C44(0.0625) H44(0.0625) C45(0.0625) H45(0.0625) C46(0.0625) C47(0.0625) C48(0.0625) H48(0.0625) C49(0.0625) H49(0.0625) C50(0.0625) C51(0.0625) H51(0.0625) C52(0.0625) H52(0.0625) C53(0.0625) C54(0.0625) C55(0.0625) C56(0.0625) H56(0.0625) C57(0.0625) H57(0.0625) C58(0.0625) C59(0.0625) H59(0.0625) C60(0.0625) H60(0.0625) C61(0.0625) C62(0.0625) C63(0.0625) H63(0.0625) C64(0.0625) H64(0.0625) C65(0.0625) C66(0.0625) C67(0.0625) H67(0.0625) C68(0.0625) C69(0.0625) C70(0.0625) H70(0.0625) C71(0.0625) H71(0.0625) C72(0.0625) C73(0.0625) C74(0.0625) H74(0.0625) C75(0.0625) C76(0.0625) Fixed X: C1(0.5) C2(0.5) C5(0.5) C8(0.5) C9(0.5) C10(0.5) C13(0.5) C16(0.5) C17(0.5) C18(0.5) H18(0.5) C19(0.5) C20(0.5) C21(0.5) C22(0.5) C23(0.5) C24(0.5) C25(0.5) C28(0.5) C31(0.5) C32(0.5) C35(0.5) C38(0.5) C39(0.5) C40(0.5) C43(0.5) C46(0.5) C47(0.5) C50(0.5) C53(0.5) C54(0.5) C55(0.5) C58(0.5) C61(0.5) C62(0.5) C63(0.5) C64(0.5) C65(0.5) C66(0.5) C67(0.5) C68(0.5) C69(0.5) C70(0.5) C71(0.5) C72(0.5) C73(0.5) C74(0.5) C75(0.5) C76(0.5) 6.a Aromatic/amide H refined with riding coordinates: C3(H3), C4(H4), C6(H6), C7(H7), C11(H11), C12(H12), C14(H14), C15(H15), C19(H19), C21(H21), C22(H22), C26(H26), C27(H27), C29(H29), C30(H30), C33(H33), C34(H34), C36(H36), C37(H37), C41(H41), C42(H42), C44(H44), C45(H45), C48(H48), C49(H49), C51(H51), C52(H52), C56(H56), C57(H57), C59(H59), C60(H60), C63(H63), C64(H64), C67(H67), C70(H70), C71(H71), C74(H74) ; _smtbx_masks_special_details ; The solvent masking procedure as implemented in Olex2 was used to remove the electronic contribution of solvent molecules from the refinement. As the exact solvent content is not known, only the atoms used in the refinement model are reported in the formula here. Total solvent accessible volume / cell = 16316.2 Ang^3^ [74.9%] Total electron count / cell = 3879.2 ; _shelx_res_file ; TITL n3147b_a in Pm-3m #221 CELL 1.54178 27.9293 27.9293 27.9293 90 90 90 ZERR 1 0.0005 0.0005 0.0005 0 0 0 LATT 1 SYMM -Y,+X,+Z SYMM -X,-Y,+Z SYMM +Y,-X,+Z SYMM +X,-Z,+Y SYMM +X,-Y,-Z SYMM +X,+Z,-Y SYMM +Z,+Y,-X SYMM -X,+Y,-Z SYMM -Z,+Y,+X SYMM +Z,+X,+Y SYMM +Y,+Z,+X SYMM -Y,-Z,+X SYMM +Z,-X,-Y SYMM -Y,+Z,-X SYMM -Z,-X,+Y SYMM -Z,+X,-Y SYMM +Y,-Z,-X SYMM +Y,+X,-Z SYMM -Y,-X,-Z SYMM -X,+Z,+Y SYMM -X,-Z,-Y SYMM +Z,-Y,+X SYMM -Z,-Y,-X SFAC C H O Zr UNIT 228 114 32.00016 6 EQIV $1 1-X,1-Z,1-Y EQIV $2 1-X,-1+Z,1+Y EQIV $3 +X,-Y,2-Z EQIV $4 +X,1-Z,1+Y EQIV $5 1-X,+Y,2-Z EQIV $6 +X,-1+Z,1-Y EQIV $7 1-X,-Y,+Z DFIX 0.94 0.001 C18 H18 C49 H49 SADI C1 C2 C16 C17 C31 C32 C46 C47 C8 C5 C23 C20 C38 C35 C53 C50 C10 C9 C25 = C24 C40 C39 C54 C55 C13 C61 C28 C66 C43 C68 C58 C73 SADI C9 C8 C24 C23 C39 C38 C54 C53 SADI C61 C74 C61 C62 C63 C62 C64 C63 C65 C64 C65 C66 C67 C66 C68 C67 C69 C68 = C70 C69 C71 C70 C72 C71 C72 C73 C74 C73 C62 C75 C65 C76 C76 C69 C76 C75 C72 C75 SADI C61 C73 C74 C72 C71 C69 C70 C76 C68 C66 C67 C65 C64 C62 C63 C75 SADI C61 C72 C62 C73 C75 C74 C76 C67 C66 C69 C68 C65 C65 C62 C63 C76 C64 C75 = C69 C72 C70 C75 C71 C76 SADI C58 C74 C13 C62 C28 C67 C43 C69 C58 C72 C13 C74 C28 C65 C43 C67 SADI C57 C73 C12 C61 C27 C66 C42 C68 C49 C53 C4 C8 C19 C23 C34 C38 C59 C73 = C14 C61 C29 C66 C44 C68 C51 C53 C6 C8 C21 C23 C36 C38 SADI C45 C39 C60 C54 C15 C9 C30 C24 C41 C39 C56 C54 C11 C9 C26 C24 SADI C39 C34 C38 C41 C54 C49 C53 C56 C9 C4 C8 C11 C24 C19 C23 C26 C39 C36 = C38 C45 C54 C51 C53 C60 C9 C6 C8 C15 C24 C21 C23 C30 SADI C15 C10 C11 C10 C12 C11 C13 C12 C14 C13 C15 C14 C7 C2 C7 C6 C6 C5 C5 C4 = C4 C3 C3 C2 C33 C32 C34 C33 C35 C34 C36 C35 C37 C36 C37 C32 C56 C55 C57 C56 = C58 C57 C59 C58 C60 C59 C60 C55 C41 C40 C42 C41 C43 C42 C44 C43 C45 C44 C45 = C40 C30 C25 C30 C29 C29 C28 C28 C27 C27 C26 C26 C25 C48 C47 C49 C48 C50 C49 = C51 C50 C52 C51 C52 C47 C18 C17 C19 C18 C20 C19 C21 C20 C22 C21 C22 C17 SADI C10 C13 C11 C14 C12 C15 C25 C28 C26 C29 C27 C30 C40 C43 C41 C44 C42 C45 = C55 C58 C56 C59 C57 C60 C32 C35 C33 C36 C34 C37 C17 C20 C18 C21 C19 C22 C47 = C50 C48 C51 C49 C52 C2 C5 C7 C4 C6 C3 SADI C10 C12 C11 C13 C12 C14 C13 C15 C14 C10 C15 C11 C25 C27 C26 C28 C27 C29 = C28 C30 C29 C25 C30 C26 C40 C42 C41 C43 C42 C44 C43 C45 C44 C40 C45 C41 C55 = C57 C56 C58 C57 C59 C58 C60 C59 C55 C60 C56 C47 C49 C48 C50 C49 C51 C50 C52 = C51 C47 C52 C48 C32 C34 C33 C35 C34 C36 C35 C37 C36 C32 C37 C33 C17 C19 C18 = C20 C19 C21 C20 C22 C21 C17 C22 C18 C2 C6 C7 C5 C6 C4 C5 C3 C4 C2 C3 C7 SADI C31 C33 C31 C37 SADI O1 C1 O1_$1 C1 C31 O1_$2 C31 O1_$3 O1_$4 C46 O1_$5 C46 O1_$6 C16 C16 O1_$7 SADI C1 C3 C1 C7 SADI C16 C18 C16 C22 SADI C46 C48 C46 C52 SADI C15 H14 C13 H14 SADI 0.01 C10 C5 C55 C50 C40 C35 C25 C20 SADI C17 H18 C19 H18 FLAT C17 C18 C19 C20 C21 C22 FLAT C66 C67 C68 C69 C76 C65 C70 C71 C72 C75 C62 C63 C64 C73 C74 C61 FLAT C10 C11 C12 C13 C14 C15 FLAT C25 C26 C27 C28 C29 C30 C24 C66 FLAT 0.01 C40 C41 C42 C43 C44 C45 C39 C68 H44 FLAT C55 C56 C57 C58 C59 C60 C54 C73 FLAT C47 C48 C49 C50 C51 C52 H49 FLAT C32 C33 C34 C35 C36 C37 C31 FLAT C2 C7 C6 C5 C4 C3 ISOR C66 C67 C68 C69 C76 C65 C70 C71 C72 C75 C62 C63 C64 C73 C74 C61 C17 C18 = C19 C20 C21 C22 C32 C33 C34 C35 C36 C37 C47 C48 C49 C50 C51 C52 C2 C3 C4 C5 = C6 C7 C38 C39 C8 C9 C23 C24 C16 C53 C46 C31 C1 C55 C56 C57 C58 C59 C60 C25 = C26 C27 C28 C29 C30 C40 C41 C42 C43 C44 C45 C54 C10 C11 C12 C13 C14 C15 EADP C66 C67 C68 C69 C76 C65 C70 C71 C72 C75 C62 C63 C64 C73 C74 C61 C17 C18 = C19 C20 C21 C22 C32 C33 C34 C35 C36 C37 C47 C48 C49 C50 C51 C52 C2 C3 C4 C5 = C6 C7 C38 C39 C8 C9 C23 C24 C16 C53 C46 C31 C1 C55 C56 C57 C58 C59 C60 C25 = C26 C27 C28 C29 C30 C40 C41 C42 C43 C44 C45 C54 C10 C11 C12 C13 C14 C15 L.S. 10 PLAN 20 SIZE 0.084 0.098 0.099 TEMP -48.15 REM SADI C1 C61 C16 C66 C31 C68 C46 C73 REM reset to Pm-3m #221 BOND $H WPDB -2 CONF fmap 2 acta REM Y:/Amy/n3147b/n3147b_a-mask.hkl WGHT 0.200000 FVAR 0.18401 ZR1 4 0.500000 0.500000 0.588401 10.12500 0.03340 0.03340 = 0.02527 0.00000 0.00000 0.00000 O1 3 0.500000 0.430709 0.627210 10.50000 0.06598 0.04683 = 0.03721 0.01014 0.00000 0.00000 O2 3 0.456731 0.456731 0.543269 10.16667 0.07231 0.07231 = 0.07231 -0.04356 -0.04356 0.04356 PART -1 C1 1 10.500000 0.385107 0.615369 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C2 1 10.500000 0.350776 0.657449 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C3 1 0.514357 0.303449 0.651476 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H3 2 0.521266 0.291792 0.620668 10.06250 -1.20000 AFIX 0 C4 1 0.518510 0.273459 0.690719 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H4 2 0.534025 0.243762 0.687532 10.06250 -1.20000 AFIX 0 C5 1 10.500000 0.286931 0.734459 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C6 1 0.485126 0.333717 0.740634 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H6 2 0.475261 0.344219 0.771050 10.06250 -1.20000 AFIX 0 C7 1 0.484638 0.365171 0.702479 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H7 2 0.473777 0.396696 0.707053 10.06250 -1.20000 AFIX 0 C8 1 10.500000 0.253929 0.774770 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C9 1 10.500000 0.225178 0.808122 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C10 1 10.500000 0.191307 0.847847 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C11 1 0.459428 0.165177 0.858575 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H11 2 0.431606 0.169135 0.840054 10.06250 -1.20000 AFIX 0 C12 1 0.459466 0.132912 0.896762 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H12 2 0.431526 0.115662 0.904148 10.06250 -1.20000 AFIX 0 C13 1 10.500000 0.126291 0.923488 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C14 1 0.541182 0.151456 0.911836 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H14 2 0.570122 0.144607 0.927596 10.06250 -1.20000 AFIX 0 C15 1 0.539654 0.186776 0.876878 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H15 2 0.565754 0.207669 0.872998 10.06250 -1.20000 AFIX 0 C16 1 10.500000 -0.388042 0.611746 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C17 1 10.500000 -0.351557 0.647770 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C18 1 10.500000 -0.364842 0.695513 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 H18 2 10.500000 -0.397543 0.703476 10.06250 -1.20000 C19 1 10.500000 -0.330508 0.730293 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H19 2 0.500000 -0.339402 0.762753 10.06250 -1.20000 AFIX 0 C20 1 10.500000 -0.282645 0.717717 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C21 1 10.500000 -0.269212 0.670233 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H21 2 0.500000 -0.236606 0.661889 10.06250 -1.20000 AFIX 0 C22 1 10.500000 -0.303651 0.635189 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H22 2 0.500000 -0.294718 0.602740 10.06250 -1.20000 AFIX 0 C23 1 10.500000 -0.245807 0.754174 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C24 1 10.500000 -0.217239 0.787690 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C25 1 10.500000 -0.187658 0.830486 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C26 1 0.514088 -0.206024 0.874112 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H26 2 0.523558 -0.238227 0.876562 10.06250 -1.20000 AFIX 0 C27 1 0.514266 -0.177399 0.913724 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H27 2 0.523856 -0.189693 0.943551 10.06250 -1.20000 AFIX 0 C28 1 10.500000 -0.129488 0.909447 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C29 1 0.487135 -0.111322 0.866666 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H29 2 0.477736 -0.079094 0.864266 10.06250 -1.20000 AFIX 0 C30 1 0.487713 -0.139976 0.826210 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H30 2 0.479817 -0.127088 0.796138 10.06250 -1.20000 AFIX 0 C31 1 10.500000 -0.388326 1.388475 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C32 1 10.500000 -0.362367 1.344529 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C33 1 0.541111 -0.359516 1.317512 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H33 2 0.569468 -0.374174 1.328180 10.06250 -1.20000 AFIX 0 C34 1 0.540370 -0.334783 1.274316 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H34 2 0.567305 -0.334860 1.254135 10.06250 -1.20000 AFIX 0 C35 1 10.500000 -0.310408 1.261646 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C36 1 0.456612 -0.320043 1.284885 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H36 2 0.427399 -0.310214 1.271367 10.06250 -1.20000 AFIX 0 C37 1 0.457492 -0.343970 1.327534 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H37 2 0.429149 -0.347878 1.345258 10.06250 -1.20000 AFIX 0 C38 1 10.500000 -0.275452 1.223550 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C39 1 10.500000 -0.242724 1.194073 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C40 1 10.500000 -0.208757 1.154711 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C41 1 0.542031 -0.199270 1.130382 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H41 2 0.570571 -0.214726 1.139290 10.06250 -1.20000 AFIX 0 C42 1 0.541926 -0.167152 1.093119 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H42 2 0.570351 -0.160757 1.076271 10.06250 -1.20000 AFIX 0 C43 1 10.500000 -0.144324 1.080506 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C44 1 0.458048 -0.154057 1.104608 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H44 2 0.429488 -0.138720 1.095560 10.06250 -1.20000 AFIX 0 C45 1 0.457987 -0.186282 1.141974 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H45 2 0.429499 -0.192873 1.158639 10.06250 -1.20000 AFIX 0 C46 1 10.500000 0.386855 1.386861 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C47 1 10.500000 0.348108 1.351572 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C48 1 0.486158 0.356855 1.304820 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H48 2 0.476935 0.387863 1.295536 10.06250 -1.20000 AFIX 0 C49 1 0.485883 0.320170 1.271873 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H49 2 0.476016 0.326132 1.240253 10.06250 -1.20000 AFIX 0 C50 1 10.500000 0.274769 1.285034 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C51 1 0.515559 0.266387 1.331351 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H51 2 0.529416 0.236796 1.339420 10.06250 -1.20000 AFIX 0 C52 1 0.510671 0.301464 1.365454 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H52 2 0.514518 0.293996 1.398045 10.06250 -1.20000 AFIX 0 C53 1 10.500000 0.236203 1.250383 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C54 1 10.500000 0.203119 1.221198 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C55 1 10.500000 0.169105 1.181554 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C56 1 0.457335 0.157535 1.159338 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H56 2 0.428235 0.168612 1.172115 10.06250 -1.20000 AFIX 0 C57 1 0.457290 0.129881 1.118612 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H57 2 0.428247 0.122527 1.103277 10.06250 -1.20000 AFIX 0 C58 1 10.500000 0.112899 1.100236 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C59 1 0.542471 0.123414 1.122912 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H59 2 0.571452 0.111214 1.110912 10.06250 -1.20000 AFIX 0 C60 1 0.542448 0.151998 1.163437 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H60 2 0.571501 0.159711 1.178576 10.06250 -1.20000 AFIX 0 C61 1 10.500000 0.096535 0.966779 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C62 1 10.500000 0.046396 0.963619 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C63 1 10.500000 0.022850 0.919272 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H63 2 0.500000 0.041291 0.891118 10.06250 -1.20000 AFIX 0 C64 1 10.500000 -0.026486 0.915464 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H64 2 0.500000 -0.041294 0.885240 10.06250 -1.20000 AFIX 0 C65 1 10.500000 -0.054049 0.957295 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C66 1 10.500000 -0.103091 0.953961 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C67 1 10.500000 -0.132296 0.995210 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H67 2 0.500000 -0.165819 0.992218 10.06250 -1.20000 AFIX 0 C68 1 10.500000 -0.110959 1.040762 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C69 1 10.500000 -0.061605 1.045472 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C70 1 10.500000 -0.038463 1.089693 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H70 2 0.500000 -0.056794 1.117919 10.06250 -1.20000 AFIX 0 C71 1 10.500000 0.011491 1.092858 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H71 2 0.500000 0.026511 1.122977 10.06250 -1.20000 AFIX 0 C72 1 10.500000 0.039341 1.050563 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C73 1 10.500000 0.089126 1.054105 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C74 1 10.500000 0.117556 1.012024 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 AFIX 43 H74 2 0.500000 0.151106 1.014700 10.06250 -1.20000 AFIX 0 C75 1 10.500000 0.017314 1.005703 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 C76 1 10.500000 -0.033097 1.003084 10.06250 0.31827 0.00993 = 0.06766 -0.00620 0.00961 -0.02860 HKLF 4 REM n3147b_a in Pm-3m #221 REM R1 = 0.1071 for 3266 Fo > 4sig(Fo) and 0.1143 for all 3871 data REM 201 parameters refined using 3763 restraints END WGHT 0.2000 0.0000 REM Highest difference peak 2.467, deepest hole -1.185, 1-sigma level 0.119 Q1 1 0.3926 -0.3926 1.3925 10.16667 0.05 2.37 Q2 1 0.5480 -0.0473 0.9527 10.50000 0.05 1.10 Q3 1 0.4460 0.0966 0.9626 11.00000 0.05 0.78 Q4 1 0.5494 -0.0285 1.0000 10.50000 0.05 0.68 Q5 1 0.5500 -0.1229 1.0000 10.50000 0.05 0.68 Q6 1 0.6137 -0.3863 1.3514 10.50000 0.05 0.60 Q7 1 0.6139 -0.3861 1.3363 10.50000 0.05 0.56 Q8 1 0.5487 -0.2150 0.7850 10.50000 0.05 0.50 Q9 1 0.5000 -0.2949 0.6197 10.50000 0.05 0.48 Q10 1 0.4507 0.1804 1.1804 10.50000 0.05 0.46 Q11 1 0.4471 0.1272 0.9116 11.00000 0.05 0.43 Q12 1 0.5000 -0.1565 0.8435 10.25000 0.05 0.41 Q13 1 0.5352 0.2803 0.7197 10.50000 0.05 0.40 Q14 1 0.5435 -0.2447 0.7553 10.50000 0.05 0.37 Q15 1 0.5776 -0.1714 1.0876 11.00000 0.05 0.37 Q16 1 0.5901 -0.1741 1.0815 11.00000 0.05 0.36 Q17 1 0.5000 -0.1282 0.8718 10.25000 0.05 0.33 Q18 1 0.6083 -0.3917 1.2804 10.50000 0.05 0.31 Q19 1 0.5956 -0.2189 1.1320 11.00000 0.05 0.31 Q20 1 0.4007 -0.3516 1.3308 11.00000 0.05 0.29 ; _shelx_res_checksum 30190 _shelx_hkl_file ; 0 1 015182.53 0.06 0 1 1 4175.29 49.16 0 2 012509.77 100.08 0 2 1 72.53 13.10 0 2 2 1459.47 24.59 0 3 0 7019.23 10.06 0 3 1 106.61 4.25 0 3 2 12.84 1.84 0 3 3 455.22 6.91 0 4 0 791.38 8.56 0 4 1 105.30 0.74 0 4 2 151.10 0.39 0 4 3 441.32 0.59 0 4 4 63.68 4.01 0 5 0 2427.45 31.97 0 5 1 120.13 5.90 0 5 2 1.46 0.49 0 5 3 520.12 3.84 0 5 4 147.48 1.03 0 5 5 81.71 1.07 0 6 0 2283.89 95.90 0 6 1 511.30 15.84 0 6 2 32.28 1.36 0 6 3 107.92 1.01 0 6 4 249.26 3.28 0 6 5 208.36 1.11 0 6 6 243.73 2.43 0 7 0 1039.89 51.38 0 7 1 811.98 7.39 0 7 2 72.84 0.74 0 7 3 110.67 2.02 0 7 4 31.41 0.60 0 7 5 295.03 1.48 0 7 6 229.34 1.32 0 7 7 116.79 1.11 0 8 0 2134.04 46.68 0 8 1 1726.56 12.49 0 8 2 312.47 2.99 0 8 3 0.53 0.62 0 8 4 1.60 0.68 0 8 5 6.70 0.60 0 8 6 41.20 0.70 0 8 7 4.72 0.58 0 8 8 61.85 2.31 0 9 0 1753.10 22.77 0 9 1 1904.14 10.14 0 9 2 338.77 2.98 0 9 3 1.60 0.55 0 9 4 5.44 1.02 0 9 5 1.66 0.61 0 9 6 4.57 0.56 0 9 7 33.62 0.92 0 9 8 76.97 1.44 0 9 9 832.54 11.27 0 10 0 996.01 17.45 0 10 1 1220.86 6.89 0 10 2 282.45 3.60 0 10 3 36.05 1.10 0 10 4 2.93 0.82 0 10 5 17.59 0.83 0 10 6 27.68 0.81 0 10 7 68.30 1.00 0 10 8 662.39 5.89 0 10 9 875.08 7.58 0 10 10 805.00 10.06 0 11 0 683.69 12.20 0 11 1 704.40 4.60 0 11 2 215.40 3.09 0 11 3 70.28 1.37 0 11 4 2.59 0.78 0 11 5 1.29 0.78 0 11 6 1.12 0.97 0 11 7 392.87 4.40 0 11 8 606.36 6.00 0 11 9 654.35 6.38 0 11 10 729.39 7.04 0 11 11 470.87 7.93 0 12 0 538.91 8.60 0 12 1 647.65 4.53 0 12 2 91.24 1.88 0 12 3 81.50 1.32 0 12 4 4.54 0.90 0 12 5 0.87 0.84 0 12 6 138.14 2.16 0 12 7 176.16 2.38 0 12 8 420.89 4.88 0 12 9 616.65 6.35 0 12 10 388.55 4.21 0 12 11 513.67 5.82 0 12 12 701.53 10.57 0 13 0 1162.88 21.32 0 13 1 732.04 6.03 0 13 2 320.03 4.47 0 13 3 66.34 1.25 0 13 4 11.84 0.98 0 13 5 89.74 2.03 0 13 6 67.96 1.77 0 13 7 171.34 2.52 0 13 8 208.48 2.98 0 13 9 272.57 3.67 0 13 10 386.96 4.44 0 13 11 493.78 5.77 0 13 12 371.94 5.09 0 13 13 334.95 4.78 0 14 0 687.98 14.20 0 14 1 695.32 6.81 0 14 2 163.47 2.48 0 14 3 35.09 1.23 0 14 4 0.49 1.01 0 14 5 0.67 1.02 0 14 6 23.98 1.56 0 14 7 63.00 1.79 0 14 8 118.13 2.55 0 14 9 206.57 2.77 0 14 10 401.02 4.30 0 14 11 297.14 4.04 0 14 12 234.90 2.59 0 14 13 261.85 2.48 0 14 14 252.19 3.56 0 15 0 740.18 16.69 0 15 1 512.73 5.32 0 15 2 287.58 3.17 0 15 3 27.47 1.00 0 15 4 11.36 1.11 0 15 5 38.98 1.40 0 15 6 7.14 1.02 0 15 7 12.72 1.15 0 15 8 38.08 1.42 0 15 9 147.14 2.75 0 15 10 111.39 2.15 0 15 11 132.36 1.78 0 15 12 145.15 2.24 0 15 13 147.43 1.57 0 15 14 131.18 1.76 0 15 15 112.71 3.02 0 16 0 411.86 7.48 0 16 1 307.39 3.73 0 16 2 148.77 1.84 0 16 3 0.62 0.88 0 16 4 63.33 1.71 0 16 5 113.32 2.01 0 16 6 101.80 1.96 0 16 7 6.73 1.07 0 16 8 19.87 1.21 0 16 9 23.41 0.92 0 16 10 65.34 1.21 0 16 11 88.15 1.37 0 16 12 74.68 1.14 0 16 13 76.89 1.13 0 16 14 43.75 0.98 0 16 15 32.38 0.87 0 16 16 14.42 1.11 0 17 0 341.34 7.42 0 17 1 191.12 2.86 0 17 2 68.61 1.40 0 17 3 1.68 0.93 0 17 4 46.06 1.67 0 17 5 160.40 2.49 0 17 6 100.15 1.65 0 17 7 35.07 1.05 0 17 8 0.02 0.63 0 17 9 17.62 0.79 0 17 10 41.86 0.91 0 17 11 45.68 1.17 0 17 12 36.45 0.97 0 17 13 14.21 0.69 0 17 14 11.22 0.73 0 17 15 2.10 0.64 0 17 16 2.35 0.67 0 17 17 0.12 0.93 0 18 0 269.10 5.42 0 18 1 122.46 2.03 0 18 2 44.02 1.01 0 18 3 9.36 0.68 0 18 4 39.45 0.94 0 18 5 113.96 1.37 0 18 6 112.54 1.41 0 18 7 27.11 0.69 0 18 8 0.00 0.46 0 18 9 30.24 0.82 0 18 10 32.98 0.82 0 18 11 41.00 0.96 0 18 12 8.85 0.68 0 18 13 28.65 0.91 0 18 14 0.03 0.60 0 18 15 5.74 0.69 0 18 16 9.47 0.73 0 18 17 0.08 0.64 0 18 18 0.40 0.88 0 19 0 267.23 4.20 0 19 1 122.03 1.53 0 19 2 50.46 0.79 0 19 3 0.11 0.51 0 19 4 30.53 0.82 0 19 5 65.45 1.14 0 19 6 49.90 0.81 0 19 7 4.62 0.51 0 19 8 18.38 0.58 0 19 9 19.34 0.75 0 19 10 45.41 1.02 0 19 11 16.15 0.72 0 19 12 58.14 1.22 0 19 13 11.81 0.74 0 19 14 2.95 0.82 0 19 15 2.00 0.69 0 19 16 0.01 0.61 0 19 17 0.45 0.78 0 19 18 3.37 0.82 0 19 19 3.19 1.14 0 20 0 356.54 3.62 0 20 1 181.40 1.57 0 20 2 120.95 1.18 0 20 3 11.93 0.53 0 20 4 0.10 0.50 0 20 5 14.35 0.62 0 20 6 0.06 0.51 0 20 7 6.85 0.54 0 20 8 22.64 0.67 0 20 9 41.62 0.99 0 20 10 13.63 0.68 0 20 11 114.86 1.78 0 20 12 50.09 1.07 0 20 13 38.37 1.07 0 20 14 6.85 0.69 0 20 15 18.71 0.89 0 20 16 0.03 0.75 0 20 17 1.01 0.83 0 20 18 0.23 0.81 0 20 19 4.94 0.85 0 20 20 34.72 2.22 0 21 0 383.69 4.33 0 21 1 285.90 2.24 0 21 2 147.17 1.37 0 21 3 60.26 1.06 0 21 4 11.56 0.62 0 21 5 10.06 0.61 0 21 6 15.12 0.68 0 21 7 19.20 0.69 0 21 8 22.45 0.81 0 21 9 21.78 0.70 0 21 10 140.95 1.92 0 21 11 127.79 1.70 0 21 12 138.43 1.86 0 21 13 62.49 1.14 0 21 14 74.45 1.39 0 21 15 12.32 0.78 0 21 16 3.18 0.79 0 21 17 1.96 0.77 0 21 18 1.92 0.90 0 21 19 25.86 1.34 0 21 20 50.15 1.45 0 21 21 67.40 2.02 0 22 0 625.31 8.04 0 22 1 355.94 2.57 0 22 2 309.71 2.35 0 22 3 162.22 1.55 0 22 4 103.02 1.32 0 22 5 63.63 1.03 0 22 6 25.65 0.72 0 22 7 6.73 0.66 0 22 8 8.52 0.65 0 22 9 77.28 1.21 0 22 10 143.44 1.88 0 22 11 185.65 2.19 0 22 12 146.88 1.97 0 22 13 167.09 2.22 0 22 14 55.66 1.18 0 22 15 38.16 1.09 0 22 16 14.39 0.97 0 22 17 7.63 0.94 0 22 18 17.59 0.95 0 22 19 37.19 1.27 0 22 20 52.24 1.46 0 22 21 81.01 1.77 0 22 22 90.85 2.50 0 23 0 210.72 3.22 0 23 1 318.08 2.31 0 23 2 157.07 1.59 0 23 3 146.26 1.54 0 23 4 99.54 1.29 0 23 5 25.78 0.75 0 23 6 1.79 0.61 0 23 7 0.37 0.58 0 23 8 22.08 0.79 0 23 9 111.31 1.67 0 23 10 135.82 1.85 0 23 11 178.22 2.07 0 23 12 226.71 2.53 0 23 13 117.37 1.72 0 23 14 98.51 1.77 0 23 15 46.35 1.28 0 23 16 24.97 1.08 0 23 17 15.16 0.91 0 23 18 18.60 1.07 0 23 19 22.50 1.22 0 23 20 46.86 1.31 0 23 21 62.33 2.02 0 23 22 82.78 2.22 0 23 23 86.43 3.94 0 24 0 444.54 6.67 0 24 1 308.12 2.26 0 24 2 296.03 2.61 0 24 3 206.98 1.83 0 24 4 64.07 0.98 0 24 5 13.09 0.85 0 24 6 0.07 0.60 0 24 7 3.48 0.65 0 24 8 41.96 1.01 0 24 9 52.66 1.13 0 24 10 120.31 1.93 0 24 11 144.95 2.10 0 24 12 115.52 1.80 0 24 13 119.93 2.00 0 24 14 67.01 1.36 0 24 15 34.38 1.10 0 24 16 22.30 0.95 0 24 17 10.81 1.17 0 24 18 7.93 1.07 0 24 19 15.09 1.11 0 24 20 24.39 1.09 0 24 21 50.05 1.33 0 24 22 65.36 1.91 0 24 23 70.61 2.16 0 25 0 119.33 3.67 0 25 1 238.36 1.99 0 25 2 113.12 1.49 0 25 3 35.53 0.85 0 25 4 2.95 0.71 0 25 5 1.00 0.62 0 25 6 0.03 0.68 0 25 7 18.49 0.84 0 25 8 14.85 0.75 0 25 9 58.94 1.17 0 25 10 76.63 1.41 0 25 11 72.97 1.32 0 25 12 94.44 1.65 0 25 13 56.01 1.26 0 25 14 30.80 1.01 0 25 15 14.33 0.88 0 25 16 4.31 0.90 0 25 17 1.87 0.94 0 25 18 1.39 0.97 0 25 19 1.98 1.04 0 25 20 12.51 0.99 0 25 21 25.08 1.13 0 25 22 43.33 1.82 0 26 0 120.82 3.71 0 26 1 169.23 1.67 0 26 2 57.91 1.06 0 26 3 7.00 0.68 0 26 4 3.65 0.63 0 26 5 2.29 0.68 0 26 6 0.43 0.67 0 26 7 1.13 0.65 0 26 8 14.81 0.87 0 26 9 28.50 0.91 0 26 10 32.45 0.90 0 26 11 42.13 1.26 0 26 12 26.03 0.99 0 26 13 16.51 0.89 0 26 14 4.50 0.77 0 26 15 0.11 0.89 0 26 16 0.00 0.90 0 26 17 2.09 0.87 0 26 18 0.09 1.06 0 26 19 0.02 0.91 0 26 20 2.83 0.94 0 26 21 11.07 1.37 0 27 0 97.84 3.06 0 27 1 77.50 1.05 0 27 2 19.26 0.82 0 27 3 0.06 0.59 0 27 4 8.56 0.70 0 27 5 6.98 0.72 0 27 6 9.39 0.71 0 27 7 0.22 0.69 0 27 8 3.52 0.71 0 27 9 9.99 0.84 0 27 10 24.40 0.89 0 27 11 12.65 0.82 0 27 12 8.05 0.73 0 27 13 1.05 0.66 0 27 14 0.10 0.75 0 27 15 1.74 0.78 0 27 16 5.73 0.86 0 27 17 6.03 0.93 0 27 18 4.26 0.90 0 27 19 0.43 1.11 0 27 20 0.00 4.00 0 28 0 6.26 1.29 0 28 1 21.90 0.71 0 28 2 0.23 0.62 0 28 3 7.79 0.73 0 28 4 16.88 0.78 0 28 5 27.36 0.82 0 28 6 22.88 0.81 0 28 7 2.51 0.74 0 28 8 0.01 0.71 0 28 9 8.05 0.75 0 28 10 6.73 0.75 0 28 11 3.91 0.68 0 28 12 0.48 0.71 0 28 13 0.03 0.71 0 28 14 0.47 0.74 0 28 15 3.66 0.81 0 28 16 8.81 0.89 0 28 17 9.33 1.48 0 28 18 3.49 1.65 0 29 0 35.10 2.06 0 29 1 18.39 0.91 0 29 2 3.06 0.64 0 29 3 0.64 0.62 0 29 4 12.76 0.67 0 29 5 14.39 0.82 0 29 6 6.31 0.75 0 29 7 4.62 0.70 0 29 8 0.27 0.67 0 29 9 3.51 0.66 0 29 10 4.81 0.68 0 29 11 3.76 0.70 0 29 12 0.55 0.69 0 29 13 0.14 0.72 0 29 14 0.06 0.74 0 29 15 2.67 0.84 0 29 16 4.04 1.36 0 30 0 52.65 1.81 0 30 1 31.76 0.95 0 30 2 9.28 0.70 0 30 3 0.01 0.61 0 30 4 3.30 0.66 0 30 5 2.45 0.76 0 30 6 3.31 0.68 0 30 7 0.16 0.64 0 30 8 0.45 0.66 0 30 9 3.03 0.70 0 30 10 13.56 0.71 0 30 11 10.12 0.68 0 30 12 11.05 0.81 0 30 13 3.80 0.90 0 30 14 1.68 1.26 0 30 15 0.17 1.68 0 31 0 77.61 2.33 0 31 1 46.14 1.19 0 31 2 25.90 0.81 0 31 3 5.26 0.69 0 31 4 0.88 0.65 0 31 5 0.05 0.63 0 31 6 0.05 0.73 0 31 7 0.57 0.76 0 31 8 1.78 0.79 0 31 9 13.58 0.96 0 31 10 21.02 1.01 0 31 11 36.24 1.38 0 31 12 27.76 4.00 0 32 0 97.46 6.35 0 32 1 51.43 1.39 0 32 2 49.70 1.95 0 32 3 24.55 1.11 0 32 4 10.20 0.76 0 32 5 0.98 0.71 0 32 6 1.36 0.77 0 32 7 2.10 0.80 0 32 8 14.26 1.44 0 32 9 20.33 1.83 0 33 0 74.07 4.80 0 33 1 48.13 2.87 0 33 2 55.06 5.33 0 33 3 23.75 2.11 0 33 4 11.41 2.60 0 33 5 3.74 2.70 1 1 130115.71 84.84 1 2 1 2973.78 14.11 1 2 2 967.84 9.37 1 3 1 257.17 7.66 1 3 2 77.18 1.18 1 3 3 178.95 3.10 1 4 1 994.80 0.59 1 4 2 21.55 0.28 1 4 3 122.04 0.54 1 4 4 8.13 3.41 1 5 1 455.01 1.73 1 5 2 40.77 1.18 1 5 3 347.30 4.81 1 5 4 225.43 1.71 1 5 5 124.75 1.58 1 6 1 353.81 5.05 1 6 2 12.74 1.15 1 6 3 29.00 0.72 1 6 4 433.84 2.59 1 6 5 231.16 1.31 1 6 6 219.88 2.44 1 7 1 644.97 5.47 1 7 2 63.63 0.75 1 7 3 0.05 0.52 1 7 4 71.11 0.36 1 7 5 263.01 1.42 1 7 6 212.36 1.34 1 7 7 119.58 1.28 1 8 1 726.32 5.32 1 8 2 163.49 1.17 1 8 3 6.47 0.47 1 8 4 33.54 0.52 1 8 5 29.63 0.58 1 8 6 84.51 0.77 1 8 7 24.99 0.51 1 8 8 18.55 0.91 1 9 1 1016.23 8.39 1 9 2 408.16 2.25 1 9 3 38.95 0.46 1 9 4 8.51 0.54 1 9 5 0.08 0.45 1 9 6 4.24 0.44 1 9 7 27.28 0.57 1 9 8 55.60 0.78 1 9 9 710.75 6.15 1 10 1 647.47 5.52 1 10 2 442.82 2.44 1 10 3 72.78 0.96 1 10 4 0.63 0.45 1 10 5 9.99 0.55 1 10 6 18.94 0.54 1 10 7 59.76 0.69 1 10 8 618.68 3.63 1 10 9 772.52 4.39 1 10 10 753.30 6.24 1 11 1 305.37 3.60 1 11 2 319.54 1.80 1 11 3 53.43 0.89 1 11 4 6.74 0.54 1 11 5 0.39 0.54 1 11 6 2.13 0.63 1 11 7 383.14 2.76 1 11 8 626.67 3.76 1 11 9 616.84 4.25 1 11 10 711.68 4.66 1 11 11 479.36 5.25 1 12 1 460.82 5.05 1 12 2 210.00 1.48 1 12 3 64.18 1.14 1 12 4 17.86 0.68 1 12 5 1.16 0.60 1 12 6 109.49 1.34 1 12 7 144.64 1.52 1 12 8 400.05 3.11 1 12 9 514.47 4.02 1 12 10 333.41 2.84 1 12 11 466.06 3.92 1 12 12 602.06 6.82 1 13 1 293.84 3.23 1 13 2 189.45 1.60 1 13 3 0.12 0.66 1 13 4 0.02 0.62 1 13 5 27.71 1.04 1 13 6 26.84 0.89 1 13 7 115.82 1.63 1 13 8 192.13 2.03 1 13 9 244.36 2.37 1 13 10 368.56 2.94 1 13 11 467.15 3.80 1 13 12 330.33 3.18 1 13 13 282.05 2.90 1 14 1 647.77 7.12 1 14 2 194.88 1.75 1 14 3 22.44 0.85 1 14 4 0.05 0.72 1 14 5 2.31 0.75 1 14 6 16.68 0.88 1 14 7 32.70 0.97 1 14 8 76.40 1.40 1 14 9 134.20 1.75 1 14 10 287.85 2.74 1 14 11 205.31 2.38 1 14 12 164.13 1.55 1 14 13 183.98 1.48 1 14 14 188.43 2.13 1 15 1 352.65 3.64 1 15 2 154.58 1.64 1 15 3 2.93 0.63 1 15 4 37.10 0.94 1 15 5 74.87 1.17 1 15 6 15.26 0.81 1 15 7 2.29 0.73 1 15 8 22.05 0.88 1 15 9 122.31 1.67 1 15 10 93.46 1.31 1 15 11 105.90 1.24 1 15 12 121.57 1.13 1 15 13 103.77 0.94 1 15 14 94.84 0.94 1 15 15 68.87 1.33 1 16 1 286.89 3.24 1 16 2 82.23 1.19 1 16 3 0.66 0.62 1 16 4 81.03 1.29 1 16 5 119.93 1.53 1 16 6 94.65 1.67 1 16 7 15.17 0.86 1 16 8 7.63 0.76 1 16 9 14.68 0.56 1 16 10 45.71 0.77 1 16 11 55.92 0.82 1 16 12 53.33 0.67 1 16 13 41.70 0.73 1 16 14 25.91 0.55 1 16 15 13.31 0.52 1 16 16 6.41 0.67 1 17 1 163.74 2.34 1 17 2 14.48 0.82 1 17 3 2.24 0.71 1 17 4 85.31 1.25 1 17 5 187.11 1.77 1 17 6 119.36 1.27 1 17 7 61.20 0.82 1 17 8 5.55 0.46 1 17 9 10.65 0.43 1 17 10 35.33 0.74 1 17 11 34.47 0.72 1 17 12 34.46 0.63 1 17 13 7.22 0.45 1 17 14 6.51 0.45 1 17 15 0.30 0.42 1 17 16 8.94 0.50 1 17 17 5.11 0.66 1 18 1 117.81 1.57 1 18 2 7.96 0.55 1 18 3 5.23 0.51 1 18 4 60.80 0.82 1 18 5 111.52 1.06 1 18 6 118.17 1.07 1 18 7 40.09 0.56 1 18 8 3.66 0.36 1 18 9 20.17 0.46 1 18 10 24.85 0.51 1 18 11 25.37 0.64 1 18 12 5.68 0.47 1 18 13 18.21 0.55 1 18 14 0.17 0.44 1 18 15 12.28 0.51 1 18 16 10.40 0.52 1 18 17 0.96 0.47 1 18 18 0.09 0.71 1 19 1 138.73 1.48 1 19 2 21.52 0.49 1 19 3 0.98 0.34 1 19 4 36.57 0.52 1 19 5 49.24 0.63 1 19 6 47.46 0.61 1 19 7 5.53 0.41 1 19 8 9.92 0.41 1 19 9 14.94 0.44 1 19 10 39.42 0.70 1 19 11 8.04 0.49 1 19 12 45.52 0.79 1 19 13 5.45 0.49 1 19 14 0.54 0.51 1 19 15 8.28 0.52 1 19 16 0.88 0.48 1 19 17 6.03 0.58 1 19 18 4.60 0.52 1 19 19 0.66 0.89 1 20 1 192.37 1.33 1 20 2 77.14 0.73 1 20 3 10.56 0.39 1 20 4 2.08 0.35 1 20 5 13.95 0.54 1 20 6 0.71 0.35 1 20 7 4.57 0.38 1 20 8 15.21 0.46 1 20 9 37.99 0.66 1 20 10 16.20 0.50 1 20 11 106.92 1.17 1 20 12 47.58 0.73 1 20 13 34.26 0.73 1 20 14 4.20 0.50 1 20 15 9.89 0.54 1 20 16 0.54 0.52 1 20 17 5.51 0.51 1 20 18 0.06 0.58 1 20 19 2.52 0.67 1 20 20 32.02 1.23 1 21 1 354.99 2.36 1 21 2 155.61 1.07 1 21 3 75.09 0.78 1 21 4 14.33 0.43 1 21 5 17.01 0.44 1 21 6 12.84 0.44 1 21 7 17.05 0.45 1 21 8 14.74 0.50 1 21 9 13.53 0.47 1 21 10 120.88 1.21 1 21 11 103.86 1.17 1 21 12 115.53 1.29 1 21 13 54.06 0.77 1 21 14 64.44 0.90 1 21 15 8.45 0.53 1 21 16 2.44 0.57 1 21 17 0.73 0.53 1 21 18 2.10 0.65 1 21 19 21.65 0.72 1 21 20 47.97 0.95 1 21 21 64.20 1.39 1 22 1 237.44 1.75 1 22 2 196.72 1.24 1 22 3 87.26 0.82 1 22 4 57.67 0.67 1 22 5 42.20 0.60 1 22 6 13.13 0.47 1 22 7 3.91 0.41 1 22 8 6.39 0.47 1 22 9 70.25 0.92 1 22 10 140.97 1.31 1 22 11 182.64 1.54 1 22 12 139.78 1.31 1 22 13 164.11 1.51 1 22 14 52.10 0.83 1 22 15 32.87 0.74 1 22 16 11.10 0.58 1 22 17 5.56 0.59 1 22 18 14.85 0.73 1 22 19 29.79 0.84 1 22 20 46.79 0.93 1 22 21 74.06 1.10 1 22 22 82.96 1.65 1 23 1 425.31 3.08 1 23 2 248.74 1.43 1 23 3 191.50 1.31 1 23 4 133.87 1.05 1 23 5 39.01 0.61 1 23 6 3.64 0.40 1 23 7 0.19 0.42 1 23 8 21.75 0.55 1 23 9 97.17 1.07 1 23 10 120.95 1.25 1 23 11 161.82 1.42 1 23 12 196.59 1.69 1 23 13 102.03 1.27 1 23 14 81.92 1.09 1 23 15 36.63 0.74 1 23 16 17.38 0.71 1 23 17 13.41 0.73 1 23 18 16.40 0.74 1 23 19 21.66 0.81 1 23 20 46.81 0.87 1 23 21 62.72 0.97 1 23 22 80.78 1.44 1 23 23 82.33 1.71 1 24 1 133.75 1.55 1 24 2 179.64 1.22 1 24 3 105.08 1.01 1 24 4 29.74 0.57 1 24 5 3.21 0.44 1 24 6 0.23 0.42 1 24 7 2.55 0.46 1 24 8 45.24 0.70 1 24 9 53.75 0.83 1 24 10 120.56 1.29 1 24 11 151.24 1.38 1 24 12 110.39 1.34 1 24 13 114.05 1.34 1 24 14 58.50 0.85 1 24 15 28.44 0.75 1 24 16 13.65 0.74 1 24 17 7.99 0.66 1 24 18 4.26 0.72 1 24 19 11.99 0.71 1 24 20 20.47 0.71 1 24 21 45.55 0.90 1 24 22 61.35 1.22 1 24 23 64.29 1.46 1 25 1 233.19 2.25 1 25 2 164.67 1.16 1 25 3 48.68 0.68 1 25 4 8.87 0.45 1 25 5 0.28 0.42 1 25 6 0.41 0.45 1 25 7 17.27 0.55 1 25 8 13.59 0.53 1 25 9 46.25 0.80 1 25 10 59.68 0.87 1 25 11 62.90 0.94 1 25 12 76.42 1.11 1 25 13 45.16 0.80 1 25 14 21.79 0.70 1 25 15 10.23 0.65 1 25 16 1.01 0.60 1 25 17 0.83 0.62 1 25 18 0.14 0.67 1 25 19 1.31 0.60 1 25 20 9.33 0.68 1 25 21 21.51 0.76 1 25 22 39.54 1.23 1 26 1 98.21 1.57 1 26 2 54.36 0.67 1 26 3 2.64 0.45 1 26 4 5.20 0.46 1 26 5 6.61 0.50 1 26 6 0.07 0.47 1 26 7 0.05 0.46 1 26 8 10.11 0.56 1 26 9 18.52 0.66 1 26 10 22.52 0.64 1 26 11 36.01 0.70 1 26 12 20.68 0.63 1 26 13 12.94 0.59 1 26 14 2.01 0.58 1 26 15 0.01 0.55 1 26 16 0.71 0.60 1 26 17 3.30 0.67 1 26 18 1.03 0.62 1 26 19 0.05 0.60 1 26 20 1.62 0.68 1 26 21 8.41 1.28 1 27 1 12.38 0.78 1 27 2 4.24 0.48 1 27 3 5.53 0.43 1 27 4 18.12 0.55 1 27 5 18.96 0.54 1 27 6 14.54 0.51 1 27 7 2.18 0.50 1 27 8 1.38 0.53 1 27 9 4.49 0.53 1 27 10 14.18 0.59 1 27 11 7.56 0.54 1 27 12 3.77 0.52 1 27 13 0.03 0.50 1 27 14 0.84 0.53 1 27 15 3.64 0.57 1 27 16 11.44 0.66 1 27 17 9.16 0.79 1 27 18 7.50 0.63 1 27 19 0.48 0.89 1 27 20 0.05 2.05 1 28 1 15.43 0.79 1 28 2 0.43 0.44 1 28 3 6.09 0.47 1 28 4 11.89 0.53 1 28 5 31.29 0.59 1 28 6 25.21 0.60 1 28 7 4.94 0.52 1 28 8 0.30 0.50 1 28 9 4.32 0.52 1 28 10 3.44 0.51 1 28 11 2.25 0.51 1 28 12 0.05 0.48 1 28 13 0.33 0.51 1 28 14 3.44 0.53 1 28 15 6.99 0.61 1 28 16 17.45 0.68 1 28 17 16.44 0.79 1 28 18 8.73 1.13 1 29 1 3.68 0.65 1 29 2 0.16 0.46 1 29 3 5.76 0.48 1 29 4 20.32 0.55 1 29 5 27.59 0.67 1 29 6 13.93 0.56 1 29 7 9.96 0.50 1 29 8 0.04 0.46 1 29 9 1.44 0.49 1 29 10 2.46 0.48 1 29 11 2.30 0.45 1 29 12 0.31 0.47 1 29 13 0.01 0.51 1 29 14 0.83 0.59 1 29 15 3.58 0.71 1 29 16 6.90 1.01 1 30 1 27.19 0.84 1 30 2 6.00 0.47 1 30 3 0.18 0.43 1 30 4 4.08 0.46 1 30 5 4.53 0.47 1 30 6 5.61 0.48 1 30 7 0.86 0.49 1 30 8 0.14 0.48 1 30 9 1.58 0.49 1 30 10 8.61 0.50 1 30 11 6.40 0.51 1 30 12 8.60 0.55 1 30 13 2.61 0.63 1 30 14 0.71 0.94 1 30 15 0.05 1.21 1 31 1 54.27 1.47 1 31 2 19.06 0.52 1 31 3 5.33 0.47 1 31 4 0.50 0.43 1 31 5 0.16 0.46 1 31 6 0.20 0.46 1 31 7 0.28 0.47 1 31 8 1.48 0.55 1 31 9 11.33 0.54 1 31 10 14.52 0.68 1 31 11 26.40 1.05 1 31 12 21.00 1.85 1 32 1 59.34 1.31 1 32 2 29.25 0.70 1 32 3 21.78 0.65 1 32 4 4.44 0.52 1 32 5 0.18 0.51 1 32 6 0.48 0.54 1 32 7 0.86 0.60 1 32 8 11.80 0.96 1 32 9 18.65 1.46 1 32 10 36.75 2.80 1 33 1 71.94 2.16 1 33 2 40.36 2.04 1 33 3 32.85 1.25 1 33 4 8.68 1.38 1 33 5 5.50 1.46 1 33 6 2.57 2.00 2 2 2 6507.00 21.81 2 3 2 688.52 2.43 2 3 3 747.93 4.92 2 4 2 139.16 0.71 2 4 3 52.32 0.56 2 4 4 43.29 0.60 2 5 2 34.22 2.41 2 5 3 290.83 2.57 2 5 4 287.81 2.72 2 5 5 158.74 2.73 2 6 2 5.85 0.95 2 6 3 53.46 0.43 2 6 4 503.54 2.13 2 6 5 308.33 2.25 2 6 6 320.00 3.78 2 7 2 98.11 1.19 2 7 3 2.66 0.33 2 7 4 68.01 0.49 2 7 5 294.93 2.12 2 7 6 291.06 2.19 2 7 7 163.15 2.00 2 8 2 110.79 1.21 2 8 3 2.40 0.35 2 8 4 38.88 0.48 2 8 5 63.85 0.83 2 8 6 155.39 1.15 2 8 7 89.69 0.92 2 8 8 7.81 0.66 2 9 2 224.69 1.87 2 9 3 31.63 0.53 2 9 4 9.06 0.44 2 9 5 6.95 0.51 2 9 6 1.93 0.50 2 9 7 1.04 0.46 2 9 8 4.40 0.52 2 9 9 440.88 4.06 2 10 2 350.59 3.14 2 10 3 159.48 1.21 2 10 4 7.00 0.46 2 10 5 7.36 0.47 2 10 6 14.68 0.53 2 10 7 44.80 0.65 2 10 8 429.48 2.66 2 10 9 587.85 3.36 2 10 10 636.61 5.20 2 11 2 290.67 2.69 2 11 3 165.09 1.17 2 11 4 36.38 0.69 2 11 5 0.10 0.54 2 11 6 0.56 0.60 2 11 7 321.30 2.30 2 11 8 468.91 3.05 2 11 9 501.03 3.49 2 11 10 584.44 3.79 2 11 11 392.61 4.36 2 12 2 37.82 1.07 2 12 3 34.14 0.75 2 12 4 1.04 0.63 2 12 5 5.04 0.64 2 12 6 50.05 0.99 2 12 7 83.95 1.22 2 12 8 296.52 2.46 2 12 9 398.49 3.12 2 12 10 273.36 2.43 2 12 11 389.72 3.42 2 12 12 471.10 5.40 2 13 2 67.67 1.57 2 13 3 0.34 0.64 2 13 4 7.23 0.69 2 13 5 4.20 0.72 2 13 6 3.02 0.67 2 13 7 44.04 0.95 2 13 8 93.53 1.30 2 13 9 131.97 1.77 2 13 10 224.44 2.42 2 13 11 292.46 3.04 2 13 12 193.35 2.47 2 13 13 129.92 2.02 2 14 2 6.57 1.03 2 14 3 14.51 0.80 2 14 4 58.81 1.12 2 14 5 50.37 1.14 2 14 6 3.24 0.77 2 14 7 0.12 0.76 2 14 8 19.08 0.90 2 14 9 53.70 1.22 2 14 10 156.59 2.10 2 14 11 108.87 1.74 2 14 12 72.80 1.05 2 14 13 69.29 0.84 2 14 14 70.79 1.06 2 15 2 45.35 1.40 2 15 3 12.17 0.71 2 15 4 107.28 1.30 2 15 5 129.19 1.74 2 15 6 68.31 1.31 2 15 7 12.31 0.88 2 15 8 0.09 0.78 2 15 9 34.70 1.02 2 15 10 27.31 0.85 2 15 11 38.06 0.70 2 15 12 39.65 0.65 2 15 13 27.68 0.54 2 15 14 20.03 0.56 2 15 15 10.18 0.68 2 16 2 16.87 0.98 2 16 3 23.66 0.76 2 16 4 156.05 1.74 2 16 5 169.78 1.97 2 16 6 177.81 2.02 2 16 7 71.22 1.56 2 16 8 2.07 0.61 2 16 9 0.03 0.47 2 16 10 10.18 0.60 2 16 11 20.29 0.54 2 16 12 16.44 0.48 2 16 13 7.12 0.49 2 16 14 0.53 0.42 2 16 15 0.47 0.43 2 16 16 4.36 0.63 2 17 2 0.08 0.92 2 17 3 39.46 0.94 2 17 4 119.44 1.53 2 17 5 191.15 2.01 2 17 6 171.66 1.56 2 17 7 116.11 1.15 2 17 8 28.70 0.60 2 17 9 0.05 0.38 2 17 10 8.47 0.43 2 17 11 10.15 0.44 2 17 12 7.65 0.46 2 17 13 0.40 0.42 2 17 14 1.75 0.44 2 17 15 16.17 0.51 2 17 16 45.66 0.70 2 17 17 26.36 0.93 2 18 2 0.47 0.62 2 18 3 34.52 0.59 2 18 4 73.57 0.86 2 18 5 122.00 1.20 2 18 6 157.36 1.19 2 18 7 82.74 0.92 2 18 8 22.31 0.51 2 18 9 3.24 0.42 2 18 10 8.21 0.44 2 18 11 10.56 0.49 2 18 12 0.30 0.43 2 18 13 3.17 0.44 2 18 14 11.04 0.51 2 18 15 41.22 0.69 2 18 16 47.35 0.76 2 18 17 16.31 0.61 2 18 18 12.80 0.83 2 19 2 11.53 0.50 2 19 3 2.95 0.34 2 19 4 37.71 0.56 2 19 5 56.31 0.67 2 19 6 65.29 0.71 2 19 7 21.33 0.45 2 19 8 0.15 0.37 2 19 9 3.26 0.37 2 19 10 19.02 0.53 2 19 11 2.01 0.43 2 19 12 27.05 0.64 2 19 13 0.46 0.47 2 19 14 1.82 0.48 2 19 15 21.53 0.63 2 19 16 14.01 0.59 2 19 17 20.84 0.64 2 19 18 18.19 0.66 2 19 19 0.47 0.80 2 20 2 75.07 0.79 2 20 3 4.98 0.34 2 20 4 0.42 0.36 2 20 5 12.89 0.42 2 20 6 1.38 0.36 2 20 7 0.76 0.35 2 20 8 3.44 0.41 2 20 9 19.07 0.48 2 20 10 6.37 0.47 2 20 11 66.89 1.03 2 20 12 26.71 0.65 2 20 13 14.52 0.60 2 20 14 0.02 0.50 2 20 15 1.44 0.51 2 20 16 9.25 0.61 2 20 17 15.16 0.64 2 20 18 2.35 0.55 2 20 19 0.39 0.62 2 20 20 22.05 1.05 2 21 2 90.39 1.13 2 21 3 30.38 0.51 2 21 4 4.21 0.36 2 21 5 2.86 0.36 2 21 6 4.67 0.41 2 21 7 5.59 0.43 2 21 8 4.16 0.45 2 21 9 8.52 0.45 2 21 10 96.84 1.11 2 21 11 83.38 1.27 2 21 12 96.35 1.10 2 21 13 38.10 0.70 2 21 14 41.55 0.79 2 21 15 2.15 0.53 2 21 16 0.05 0.55 2 21 17 0.29 0.51 2 21 18 0.03 0.55 2 21 19 13.86 0.68 2 21 20 36.42 0.81 2 21 21 53.50 1.32 2 22 2 185.33 1.77 2 22 3 82.57 0.80 2 22 4 57.93 0.66 2 22 5 31.03 0.61 2 22 6 11.82 0.43 2 22 7 1.73 0.39 2 22 8 1.92 0.45 2 22 9 54.42 0.79 2 22 10 109.85 1.25 2 22 11 142.43 1.45 2 22 12 112.24 1.24 2 22 13 122.79 1.38 2 22 14 33.77 0.69 2 22 15 16.85 0.64 2 22 16 3.96 0.59 2 22 17 2.02 0.56 2 22 18 8.10 0.65 2 22 19 22.26 0.74 2 22 20 38.30 1.01 2 22 21 65.02 0.99 2 22 22 74.38 1.55 2 23 2 118.41 1.45 2 23 3 104.92 1.02 2 23 4 72.34 0.77 2 23 5 14.49 0.50 2 23 6 0.91 0.42 2 23 7 0.02 0.42 2 23 8 16.99 0.55 2 23 9 90.07 1.01 2 23 10 115.08 1.24 2 23 11 145.87 1.39 2 23 12 178.77 1.61 2 23 13 84.39 1.03 2 23 14 62.23 0.92 2 23 15 19.40 0.63 2 23 16 8.39 0.58 2 23 17 5.73 0.67 2 23 18 7.70 0.70 2 23 19 13.79 0.68 2 23 20 34.23 0.84 2 23 21 52.11 0.87 2 23 22 69.08 1.09 2 23 23 71.19 1.63 2 24 2 167.27 1.81 2 24 3 119.03 1.05 2 24 4 34.24 0.58 2 24 5 4.30 0.44 2 24 6 0.12 0.42 2 24 7 2.90 0.46 2 24 8 37.57 0.66 2 24 9 44.15 0.72 2 24 10 93.96 1.14 2 24 11 114.35 1.29 2 24 12 80.30 1.14 2 24 13 75.12 1.07 2 24 14 33.69 0.75 2 24 15 8.66 0.66 2 24 16 4.11 0.66 2 24 17 1.45 0.63 2 24 18 0.73 0.60 2 24 19 6.32 0.66 2 24 20 14.83 0.65 2 24 21 36.51 0.79 2 24 22 47.58 0.94 2 24 23 52.16 2.00 2 25 2 66.89 1.48 2 25 3 21.35 0.52 2 25 4 0.23 0.42 2 25 5 4.22 0.46 2 25 6 0.36 0.45 2 25 7 6.71 0.47 2 25 8 5.03 0.46 2 25 9 25.05 0.69 2 25 10 36.08 0.76 2 25 11 40.29 0.77 2 25 12 49.89 0.82 2 25 13 25.38 0.67 2 25 14 10.60 0.64 2 25 15 1.02 0.62 2 25 16 0.19 0.59 2 25 17 0.47 0.59 2 25 18 0.77 0.65 2 25 19 0.04 0.59 2 25 20 5.31 0.62 2 25 21 15.20 0.73 2 25 22 25.90 1.23 2 26 2 7.45 0.66 2 26 3 0.34 0.41 2 26 4 21.39 0.53 2 26 5 17.12 0.51 2 26 6 2.60 0.46 2 26 7 2.70 0.48 2 26 8 1.20 0.53 2 26 9 3.55 0.57 2 26 10 6.88 0.57 2 26 11 15.27 0.58 2 26 12 7.27 0.54 2 26 13 2.30 0.57 2 26 14 0.15 0.57 2 26 15 5.89 0.61 2 26 16 7.47 0.64 2 26 17 14.19 0.71 2 26 18 7.15 0.64 2 26 19 2.27 0.63 2 26 20 0.15 0.81 2 26 21 4.18 1.40 2 27 2 1.47 0.66 2 27 3 13.25 0.50 2 27 4 35.98 0.63 2 27 5 33.56 0.62 2 27 6 32.30 0.63 2 27 7 13.34 0.55 2 27 8 1.39 0.52 2 27 9 0.14 0.50 2 27 10 1.92 0.49 2 27 11 0.73 0.49 2 27 12 0.02 0.51 2 27 13 3.58 0.54 2 27 14 7.74 0.58 2 27 15 20.08 0.69 2 27 16 28.53 0.74 2 27 17 26.65 0.75 2 27 18 19.63 0.79 2 27 19 5.06 0.93 2 28 2 10.81 0.66 2 28 3 21.29 0.60 2 28 4 36.52 0.65 2 28 5 57.51 0.72 2 28 6 53.86 0.74 2 28 7 20.49 0.61 2 28 8 6.74 0.53 2 28 9 0.02 0.46 2 28 10 0.01 0.50 2 28 11 0.02 0.49 2 28 12 1.12 0.49 2 28 13 4.71 0.52 2 28 14 11.34 0.60 2 28 15 22.05 0.68 2 28 16 33.56 0.84 2 28 17 32.92 0.92 2 28 18 19.10 1.19 2 29 2 1.08 0.60 2 29 3 8.92 0.51 2 29 4 30.09 0.64 2 29 5 38.57 0.67 2 29 6 27.44 0.62 2 29 7 20.14 0.55 2 29 8 2.53 0.51 2 29 9 0.07 0.47 2 29 10 0.03 0.48 2 29 11 0.08 0.45 2 29 12 0.34 0.46 2 29 13 2.19 0.54 2 29 14 5.65 0.66 2 29 15 13.25 0.77 2 29 16 16.98 1.01 2 30 2 0.76 0.64 2 30 3 3.42 0.45 2 30 4 13.03 0.50 2 30 5 14.18 0.54 2 30 6 16.26 0.60 2 30 7 6.05 0.57 2 30 8 1.12 0.51 2 30 9 0.01 0.51 2 30 10 1.94 0.45 2 30 11 1.64 0.52 2 30 12 2.90 0.53 2 30 13 0.08 0.83 2 30 14 0.29 1.47 2 30 15 1.75 1.05 2 31 2 11.02 0.71 2 31 3 0.42 0.43 2 31 4 0.59 0.45 2 31 5 3.46 0.48 2 31 6 3.39 0.49 2 31 7 0.45 0.48 2 31 8 0.01 0.46 2 31 9 4.87 0.55 2 31 10 5.57 0.63 2 31 11 14.44 0.88 2 31 12 12.08 1.96 2 32 2 30.49 0.98 2 32 3 12.02 0.57 2 32 4 2.49 0.53 2 32 5 0.00 0.51 2 32 6 0.08 0.63 2 32 7 0.37 0.65 2 32 8 8.07 0.91 2 32 9 12.72 1.41 2 33 2 43.52 3.05 2 33 3 17.81 1.44 2 33 4 5.62 1.40 2 33 5 3.50 2.30 2 33 6 1.46 2.20 3 3 3 3327.14 34.86 3 4 3 34.31 1.18 3 4 4 23.88 0.68 3 5 3 300.64 2.97 3 5 4 477.68 2.71 3 5 5 579.83 3.60 3 6 3 10.78 3.24 3 6 4 312.38 1.09 3 6 5 431.53 2.58 3 6 6 272.24 4.24 3 7 3 13.37 0.66 3 7 4 52.60 0.51 3 7 5 459.18 2.01 3 7 6 386.31 2.68 3 7 7 331.42 2.75 3 8 3 0.02 0.56 3 8 4 26.57 0.57 3 8 5 101.70 0.95 3 8 6 184.31 1.51 3 8 7 224.76 1.42 3 8 8 82.56 1.24 3 9 3 1.75 0.55 3 9 4 22.91 0.45 3 9 5 41.87 0.59 3 9 6 40.00 0.74 3 9 7 47.85 0.78 3 9 8 23.93 0.61 3 9 9 132.57 2.19 3 10 3 107.80 1.24 3 10 4 3.99 0.44 3 10 5 13.19 0.49 3 10 6 0.39 0.50 3 10 7 3.74 0.54 3 10 8 187.21 1.55 3 10 9 301.29 2.01 3 10 10 418.51 3.58 3 11 3 128.60 1.58 3 11 4 26.52 0.73 3 11 5 0.02 0.55 3 11 6 5.36 0.58 3 11 7 176.54 1.68 3 11 8 245.47 2.25 3 11 9 318.99 2.48 3 11 10 393.23 2.77 3 11 11 270.87 3.65 3 12 3 43.72 1.19 3 12 4 2.62 0.67 3 12 5 0.98 0.63 3 12 6 21.71 0.79 3 12 7 38.09 0.90 3 12 8 154.63 1.76 3 12 9 230.99 2.17 3 12 10 165.80 1.91 3 12 11 255.30 2.75 3 12 12 274.46 4.21 3 13 3 45.65 1.31 3 13 4 60.34 0.96 3 13 5 7.30 0.73 3 13 6 11.04 0.79 3 13 7 3.51 0.71 3 13 8 15.64 0.86 3 13 9 55.95 1.20 3 13 10 118.22 1.83 3 13 11 155.26 2.34 3 13 12 91.74 1.69 3 13 13 49.76 1.21 3 14 3 93.24 1.77 3 14 4 152.58 1.76 3 14 5 146.43 1.81 3 14 6 64.40 1.29 3 14 7 27.50 1.05 3 14 8 4.15 0.84 3 14 9 6.45 0.90 3 14 10 49.18 1.28 3 14 11 30.38 0.94 3 14 12 11.77 0.71 3 14 13 8.60 0.43 3 14 14 3.54 0.68 3 15 3 139.04 2.08 3 15 4 260.72 2.12 3 15 5 316.84 2.60 3 15 6 221.63 2.18 3 15 7 97.45 1.56 3 15 8 43.28 1.18 3 15 9 0.16 0.79 3 15 10 0.20 0.57 3 15 11 1.06 0.50 3 15 12 0.87 0.42 3 15 13 0.12 0.44 3 15 14 2.62 0.41 3 15 15 6.45 0.71 3 16 3 125.34 2.47 3 16 4 257.32 2.55 3 16 5 327.25 2.84 3 16 6 313.98 2.91 3 16 7 180.56 2.16 3 16 8 50.99 1.05 3 16 9 24.11 0.70 3 16 10 3.42 0.41 3 16 11 0.09 0.48 3 16 12 0.28 0.41 3 16 13 4.61 0.42 3 16 14 25.26 0.57 3 16 15 36.43 0.66 3 16 16 55.16 1.12 3 17 3 95.32 2.06 3 17 4 155.19 1.91 3 17 5 284.95 2.24 3 17 6 268.47 2.03 3 17 7 216.39 1.58 3 17 8 94.00 1.01 3 17 9 23.31 0.47 3 17 10 2.13 0.46 3 17 11 0.13 0.50 3 17 12 1.59 0.40 3 17 13 20.03 0.58 3 17 14 37.89 0.66 3 17 15 76.41 0.94 3 17 16 127.34 1.26 3 17 17 89.17 1.44 3 18 3 64.59 1.34 3 18 4 85.43 1.00 3 18 5 174.11 1.29 3 18 6 198.91 1.32 3 18 7 148.20 1.02 3 18 8 63.61 0.68 3 18 9 5.32 0.44 3 18 10 0.79 0.45 3 18 11 0.37 0.44 3 18 12 6.46 0.49 3 18 13 2.42 0.46 3 18 14 45.06 0.77 3 18 15 103.55 1.17 3 18 16 113.31 1.18 3 18 17 65.33 0.90 3 18 18 54.65 1.34 3 19 3 7.60 0.52 3 19 4 41.42 0.60 3 19 5 79.36 0.75 3 19 6 86.12 0.86 3 19 7 52.97 0.60 3 19 8 5.61 0.39 3 19 9 1.99 0.40 3 19 10 1.93 0.45 3 19 11 0.06 0.47 3 19 12 6.06 0.49 3 19 13 2.85 0.46 3 19 14 15.05 0.60 3 19 15 56.61 0.89 3 19 16 52.33 0.85 3 19 17 64.57 0.99 3 19 18 51.62 0.95 3 19 19 10.80 0.92 3 20 3 0.04 0.52 3 20 4 8.60 0.39 3 20 5 33.03 0.50 3 20 6 13.79 0.43 3 20 7 4.70 0.38 3 20 8 0.46 0.37 3 20 9 1.22 0.40 3 20 10 0.51 0.43 3 20 11 43.43 0.70 3 20 12 10.57 0.56 3 20 13 3.82 0.57 3 20 14 1.77 0.60 3 20 15 1.92 0.54 3 20 16 32.67 0.73 3 20 17 42.13 0.85 3 20 18 15.88 0.66 3 20 19 1.58 0.55 3 20 20 9.42 0.95 3 21 3 20.30 0.63 3 21 4 0.81 0.38 3 21 5 0.44 0.39 3 21 6 0.61 0.40 3 21 7 0.16 0.41 3 21 8 0.27 0.40 3 21 9 0.81 0.45 3 21 10 59.35 0.82 3 21 11 61.08 0.86 3 21 12 57.21 0.93 3 21 13 17.96 0.68 3 21 14 18.56 0.78 3 21 15 0.39 0.52 3 21 16 5.27 0.60 3 21 17 6.20 0.60 3 21 18 1.45 0.54 3 21 19 5.95 0.63 3 21 20 25.35 0.73 3 21 21 44.59 1.14 3 22 3 41.56 0.80 3 22 4 25.33 0.55 3 22 5 14.64 0.49 3 22 6 1.97 0.41 3 22 7 0.00 0.42 3 22 8 0.47 0.44 3 22 9 38.17 0.68 3 22 10 94.69 1.10 3 22 11 131.85 1.41 3 22 12 91.25 1.16 3 22 13 89.50 1.13 3 22 14 18.42 0.63 3 22 15 4.76 0.58 3 22 16 0.03 0.54 3 22 17 0.20 0.57 3 22 18 1.84 0.55 3 22 19 9.26 0.62 3 22 20 25.03 0.77 3 22 21 49.88 0.91 3 22 22 58.02 1.94 3 23 3 93.62 1.34 3 23 4 63.64 0.75 3 23 5 17.54 0.49 3 23 6 0.09 0.42 3 23 7 0.03 0.42 3 23 8 12.82 0.51 3 23 9 66.77 0.88 3 23 10 95.40 1.20 3 23 11 114.05 1.37 3 23 12 127.38 1.44 3 23 13 51.60 0.85 3 23 14 28.12 0.71 3 23 15 4.76 0.54 3 23 16 0.24 0.55 3 23 17 0.13 0.53 3 23 18 1.72 0.58 3 23 19 4.86 0.62 3 23 20 20.63 0.75 3 23 21 36.55 0.86 3 23 22 51.55 0.86 3 23 23 49.26 1.33 3 24 3 61.58 1.09 3 24 4 15.12 0.50 3 24 5 0.43 0.41 3 24 6 3.96 0.43 3 24 7 0.01 0.44 3 24 8 13.75 0.58 3 24 9 22.45 0.67 3 24 10 58.38 0.91 3 24 11 73.65 1.00 3 24 12 49.31 0.83 3 24 13 44.00 0.77 3 24 14 12.17 0.60 3 24 15 1.43 0.53 3 24 16 0.02 0.51 3 24 17 0.39 0.61 3 24 18 0.13 0.61 3 24 19 0.98 0.63 3 24 20 7.64 0.60 3 24 21 21.05 0.67 3 24 22 31.20 0.94 3 24 23 32.59 2.93 3 25 3 0.02 0.59 3 25 4 6.93 0.44 3 25 5 17.95 0.54 3 25 6 12.67 0.50 3 25 7 0.01 0.47 3 25 8 0.28 0.47 3 25 9 5.81 0.53 3 25 10 12.09 0.57 3 25 11 13.72 0.63 3 25 12 17.76 0.66 3 25 13 6.38 0.55 3 25 14 0.06 0.52 3 25 15 2.20 0.62 3 25 16 10.18 0.67 3 25 17 9.00 0.69 3 25 18 6.35 0.61 3 25 19 2.11 0.58 3 25 20 1.21 0.52 3 25 21 6.39 0.81 3 25 22 14.38 2.68 3 26 3 26.05 0.73 3 26 4 57.43 0.72 3 26 5 46.88 0.72 3 26 6 27.11 0.58 3 26 7 19.78 0.57 3 26 8 6.64 0.50 3 26 9 1.34 0.51 3 26 10 0.02 0.49 3 26 11 1.06 0.54 3 26 12 0.09 0.52 3 26 13 0.57 0.55 3 26 14 10.09 0.63 3 26 15 21.89 0.71 3 26 16 30.33 0.75 3 26 17 36.57 0.81 3 26 18 21.70 0.80 3 26 19 10.79 0.95 3 26 20 0.88 0.88 3 26 21 0.35 4.00 3 27 3 50.41 0.97 3 27 4 67.53 0.79 3 27 5 67.10 0.81 3 27 6 69.37 0.85 3 27 7 38.94 0.68 3 27 8 20.13 0.61 3 27 9 7.78 0.54 3 27 10 0.80 0.52 3 27 11 1.23 0.51 3 27 12 2.70 0.50 3 27 13 11.92 0.61 3 27 14 26.03 0.68 3 27 15 43.46 0.80 3 27 16 59.92 0.99 3 27 17 54.88 1.12 3 27 18 41.36 0.97 3 27 19 17.92 1.12 3 28 3 39.11 0.97 3 28 4 51.14 0.75 3 28 5 75.22 1.00 3 28 6 75.93 0.90 3 28 7 40.87 0.70 3 28 8 26.95 0.63 3 28 9 6.62 0.52 3 28 10 4.00 0.50 3 28 11 4.03 0.52 3 28 12 10.13 0.62 3 28 13 17.12 0.61 3 28 14 34.16 0.73 3 28 15 46.37 0.89 3 28 16 60.50 1.07 3 28 17 53.44 1.44 3 28 18 34.30 1.50 3 29 3 22.86 0.95 3 29 4 49.12 0.73 3 29 5 63.69 0.80 3 29 6 51.74 0.81 3 29 7 42.65 0.73 3 29 8 18.28 0.58 3 29 9 6.41 0.54 3 29 10 2.10 0.52 3 29 11 1.97 0.51 3 29 12 4.77 0.53 3 29 13 9.64 0.63 3 29 14 19.35 0.75 3 29 15 30.37 0.84 3 29 16 35.78 1.46 3 30 3 13.46 0.75 3 30 4 30.50 0.63 3 30 5 34.92 0.67 3 30 6 33.39 0.72 3 30 7 20.18 0.66 3 30 8 10.08 0.58 3 30 9 3.64 0.54 3 30 10 0.00 0.55 3 30 11 0.02 0.45 3 30 12 0.01 0.55 3 30 13 1.48 0.65 3 30 14 5.40 0.89 3 31 3 0.60 0.58 3 31 4 5.81 0.47 3 31 5 13.63 0.54 3 31 6 11.11 0.53 3 31 7 4.93 0.53 3 31 8 2.28 0.55 3 31 9 0.14 0.53 3 31 10 1.51 0.68 3 31 11 5.67 0.96 3 31 12 3.83 1.48 3 32 3 6.99 0.84 3 32 4 0.34 0.53 3 32 5 1.79 0.56 3 32 6 0.72 0.54 3 32 7 0.32 0.61 3 32 8 1.83 1.09 3 32 9 3.08 1.93 3 33 3 10.02 1.56 3 33 4 1.92 1.48 3 33 5 0.34 1.62 4 4 4 1.04 2.90 4 5 4 271.09 2.07 4 5 5 369.29 2.91 4 6 4 521.76 2.40 4 6 5 623.77 3.10 4 6 6 659.35 4.64 4 7 4 33.92 1.16 4 7 5 350.16 2.01 4 7 6 519.96 2.87 4 7 7 338.75 3.77 4 8 4 64.69 0.99 4 8 5 164.46 1.11 4 8 6 378.52 1.96 4 8 7 418.72 2.24 4 8 8 301.32 2.49 4 9 4 50.94 0.85 4 9 5 85.33 0.85 4 9 6 141.62 1.16 4 9 7 181.86 1.46 4 9 8 124.41 1.13 4 9 9 8.49 0.93 4 10 4 3.49 0.65 4 10 5 57.85 0.65 4 10 6 35.52 0.78 4 10 7 36.10 0.73 4 10 8 20.37 0.71 4 10 9 67.10 1.02 4 10 10 135.04 2.17 4 11 4 11.79 0.86 4 11 5 4.52 0.59 4 11 6 20.27 0.70 4 11 7 34.48 0.84 4 11 8 86.59 1.30 4 11 9 140.60 1.59 4 11 10 168.24 1.86 4 11 11 140.34 2.94 4 12 4 0.18 0.93 4 12 5 5.82 0.67 4 12 6 2.33 0.68 4 12 7 0.23 0.75 4 12 8 64.83 1.17 4 12 9 92.48 1.51 4 12 10 74.35 1.43 4 12 11 151.51 2.29 4 12 12 165.29 3.37 4 13 4 56.28 1.48 4 13 5 21.09 0.85 4 13 6 25.21 0.92 4 13 7 9.12 0.80 4 13 8 0.07 0.78 4 13 9 12.16 0.94 4 13 10 53.36 1.36 4 13 11 70.54 1.66 4 13 12 46.68 1.06 4 13 13 14.91 0.82 4 14 4 212.82 3.16 4 14 5 222.78 2.18 4 14 6 132.31 1.81 4 14 7 108.20 1.58 4 14 8 44.31 1.17 4 14 9 5.08 0.88 4 14 10 6.51 0.87 4 14 11 2.34 0.66 4 14 12 0.28 0.51 4 14 13 0.26 0.38 4 14 14 1.66 0.53 4 15 4 433.99 4.36 4 15 5 496.12 3.51 4 15 6 382.04 3.14 4 15 7 225.87 2.51 4 15 8 133.58 1.79 4 15 9 35.36 1.01 4 15 10 16.28 0.67 4 15 11 10.47 0.51 4 15 12 8.37 0.54 4 15 13 15.33 0.53 4 15 14 34.15 0.66 4 15 15 65.42 1.29 4 16 4 476.32 5.01 4 16 5 546.96 4.10 4 16 6 527.09 3.71 4 16 7 345.46 2.90 4 16 8 173.77 1.54 4 16 9 105.56 1.16 4 16 10 38.11 0.78 4 16 11 21.38 0.51 4 16 12 18.31 0.51 4 16 13 45.11 0.69 4 16 14 83.61 1.11 4 16 15 119.15 1.17 4 16 16 143.50 1.96 4 17 4 277.66 3.40 4 17 5 392.72 2.47 4 17 6 434.45 2.51 4 17 7 327.32 2.13 4 17 8 207.95 1.40 4 17 9 92.93 0.83 4 17 10 25.65 0.56 4 17 11 16.64 0.52 4 17 12 19.04 0.56 4 17 13 61.39 0.89 4 17 14 93.36 1.17 4 17 15 165.72 1.50 4 17 16 226.07 1.86 4 17 17 179.89 2.33 4 18 4 136.79 1.66 4 18 5 212.51 1.47 4 18 6 284.92 1.59 4 18 7 211.96 1.45 4 18 8 142.73 1.08 4 18 9 43.38 0.56 4 18 10 18.81 0.51 4 18 11 8.93 0.48 4 18 12 24.47 0.63 4 18 13 21.33 0.65 4 18 14 87.80 1.20 4 18 15 177.29 1.66 4 18 16 184.78 1.70 4 18 17 138.16 1.48 4 18 18 113.34 2.09 4 19 4 94.38 1.19 4 19 5 112.31 0.95 4 19 6 150.12 1.06 4 19 7 92.79 0.93 4 19 8 37.64 0.56 4 19 9 21.53 0.48 4 19 10 2.74 0.49 4 19 11 6.35 0.50 4 19 12 0.09 0.51 4 19 13 13.16 0.59 4 19 14 39.09 0.79 4 19 15 98.51 1.24 4 19 16 106.29 1.27 4 19 17 131.74 1.50 4 19 18 96.90 1.41 4 19 19 33.45 1.06 4 20 4 24.74 0.71 4 20 5 38.03 0.61 4 20 6 36.38 0.55 4 20 7 15.55 0.48 4 20 8 10.37 0.45 4 20 9 1.76 0.44 4 20 10 0.50 0.47 4 20 11 20.53 0.60 4 20 12 4.68 0.57 4 20 13 0.35 0.54 4 20 14 8.15 0.59 4 20 15 13.64 0.67 4 20 16 64.37 0.98 4 20 17 80.05 1.08 4 20 18 38.29 0.80 4 20 19 7.33 0.60 4 20 20 3.70 0.81 4 21 4 2.18 0.56 4 21 5 0.77 0.40 4 21 6 2.37 0.39 4 21 7 3.86 0.42 4 21 8 2.70 0.42 4 21 9 0.13 0.44 4 21 10 36.84 0.69 4 21 11 49.41 0.83 4 21 12 47.67 0.89 4 21 13 12.96 0.63 4 21 14 6.13 0.61 4 21 15 5.63 0.61 4 21 16 20.14 0.70 4 21 17 26.15 0.73 4 21 18 11.58 0.61 4 21 19 0.34 0.50 4 21 20 12.15 0.65 4 21 21 25.65 1.00 4 22 4 19.79 0.73 4 22 5 10.95 0.46 4 22 6 0.19 0.42 4 22 7 2.17 0.45 4 22 8 0.32 0.44 4 22 9 22.12 0.61 4 22 10 64.94 0.95 4 22 11 100.06 1.29 4 22 12 67.60 1.00 4 22 13 53.64 0.88 4 22 14 4.82 0.59 4 22 15 0.02 0.56 4 22 16 5.53 0.58 4 22 17 5.43 0.57 4 22 18 0.14 0.56 4 22 19 3.22 0.58 4 22 20 14.98 0.64 4 22 21 32.68 0.71 4 22 22 39.15 1.07 4 23 4 41.04 0.91 4 23 5 5.84 0.44 4 23 6 2.25 0.43 4 23 7 6.13 0.44 4 23 8 1.95 0.50 4 23 9 33.73 0.70 4 23 10 61.69 0.92 4 23 11 78.30 1.02 4 23 12 87.66 1.37 4 23 13 28.30 0.72 4 23 14 9.32 0.60 4 23 15 0.00 0.53 4 23 16 2.56 0.53 4 23 17 2.41 0.57 4 23 18 0.27 0.59 4 23 19 1.07 0.55 4 23 20 8.03 0.61 4 23 21 19.83 0.69 4 23 22 29.15 0.79 4 23 23 23.76 1.65 4 24 4 0.60 0.60 4 24 5 8.36 0.47 4 24 6 17.97 0.57 4 24 7 10.68 0.51 4 24 8 0.77 0.50 4 24 9 6.04 0.54 4 24 10 25.33 0.69 4 24 11 37.80 0.77 4 24 12 23.03 0.69 4 24 13 14.53 0.61 4 24 14 0.83 0.53 4 24 15 2.20 0.54 4 24 16 7.41 0.58 4 24 17 8.72 0.61 4 24 18 5.28 0.60 4 24 19 0.14 0.56 4 24 20 1.37 0.54 4 24 21 9.40 0.67 4 24 22 15.47 1.16 4 24 23 14.88 2.75 4 25 4 33.96 0.85 4 25 5 68.04 0.78 4 25 6 44.31 0.67 4 25 7 19.43 0.58 4 25 8 13.98 0.54 4 25 9 0.78 0.51 4 25 10 0.41 0.49 4 25 11 2.29 0.53 4 25 12 4.00 0.53 4 25 13 0.19 0.57 4 25 14 2.21 0.55 4 25 15 12.99 0.60 4 25 16 27.92 0.75 4 25 17 25.98 0.77 4 25 18 19.93 0.65 4 25 19 7.49 0.67 4 25 20 0.52 0.58 4 25 21 1.28 1.53 4 25 22 4.79 5.25 4 26 4 102.75 1.49 4 26 5 106.65 1.01 4 26 6 62.08 0.80 4 26 7 57.72 0.77 4 26 8 26.71 0.62 4 26 9 14.47 0.57 4 26 10 5.04 0.54 4 26 11 1.06 0.54 4 26 12 1.67 0.51 4 26 13 6.87 0.58 4 26 14 21.16 0.66 4 26 15 41.31 0.88 4 26 16 54.92 0.95 4 26 17 61.59 1.01 4 26 18 41.57 0.91 4 26 19 19.48 0.74 4 26 20 6.16 1.11 4 27 4 84.97 1.33 4 27 5 101.04 0.99 4 27 6 86.60 1.01 4 27 7 68.01 0.83 4 27 8 38.23 0.73 4 27 9 22.77 0.64 4 27 10 10.26 0.59 4 27 11 8.26 0.62 4 27 12 11.66 0.56 4 27 13 29.27 0.63 4 27 14 44.67 0.85 4 27 15 70.90 0.99 4 27 16 86.08 1.11 4 27 17 80.10 1.27 4 27 18 57.42 1.18 4 27 19 25.62 1.82 4 28 4 67.27 1.20 4 28 5 101.30 1.06 4 28 6 99.01 1.15 4 28 7 74.02 1.00 4 28 8 46.82 0.81 4 28 9 21.76 0.64 4 28 10 14.09 0.60 4 28 11 10.01 0.56 4 28 12 18.01 0.66 4 28 13 29.96 0.72 4 28 14 50.18 0.90 4 28 15 70.83 1.41 4 28 16 87.40 1.42 4 28 17 81.49 2.22 4 28 18 54.67 3.32 4 29 4 72.41 1.86 4 29 5 88.64 1.06 4 29 6 80.65 1.16 4 29 7 74.21 1.24 4 29 8 39.48 0.86 4 29 9 21.73 0.60 4 29 10 11.65 0.56 4 29 11 8.14 0.59 4 29 12 11.86 0.63 4 29 13 21.62 0.66 4 29 14 32.46 0.86 4 29 15 47.24 1.02 4 29 16 53.67 1.66 4 30 4 47.42 1.01 4 30 5 51.52 0.83 4 30 6 56.47 0.82 4 30 7 44.11 0.74 4 30 8 25.75 0.72 4 30 9 13.57 0.64 4 30 10 3.27 0.53 4 30 11 1.50 0.55 4 30 12 1.66 0.57 4 30 13 6.59 0.76 4 30 14 12.84 0.96 4 31 4 14.00 0.74 4 31 5 21.66 0.63 4 31 6 26.30 0.67 4 31 7 16.51 0.71 4 31 8 11.00 0.67 4 31 9 2.00 0.62 4 31 10 0.24 0.63 4 31 11 0.90 1.08 4 31 12 0.15 1.14 4 32 4 1.53 0.81 4 32 5 6.12 0.62 4 32 6 7.67 0.66 4 32 7 3.99 0.64 4 32 8 0.12 1.06 4 32 9 0.33 1.70 4 33 4 0.34 2.00 4 33 5 0.67 2.20 5 5 5 186.13 4.35 5 6 5 491.22 5.03 5 6 6 715.95 6.21 5 7 5 610.69 4.50 5 7 6 972.91 4.36 5 7 7 868.81 5.81 5 8 5 195.20 2.56 5 8 6 520.52 2.92 5 8 7 711.52 3.67 5 8 8 532.51 4.46 5 9 5 106.03 1.79 5 9 6 260.27 1.81 5 9 7 355.68 2.66 5 9 8 258.25 1.93 5 9 9 21.86 1.11 5 10 5 139.35 1.58 5 10 6 159.67 1.49 5 10 7 126.01 1.33 5 10 8 11.09 0.73 5 10 9 0.86 0.63 5 10 10 34.52 1.24 5 11 5 46.80 1.41 5 11 6 95.06 1.15 5 11 7 0.33 0.70 5 11 8 1.00 0.76 5 11 9 23.18 1.01 5 11 10 48.94 1.27 5 11 11 61.56 2.04 5 12 5 15.83 1.22 5 12 6 4.88 0.79 5 12 7 2.52 0.77 5 12 8 12.15 0.86 5 12 9 23.61 1.05 5 12 10 34.01 1.25 5 12 11 101.49 1.90 5 12 12 111.77 2.61 5 13 5 11.90 1.31 5 13 6 27.10 0.98 5 13 7 15.17 0.94 5 13 8 7.07 0.89 5 13 9 0.37 0.85 5 13 10 23.02 1.08 5 13 11 44.47 1.32 5 13 12 33.20 0.87 5 13 13 8.94 0.75 5 14 5 227.46 3.15 5 14 6 168.44 2.08 5 14 7 143.52 1.84 5 14 8 82.23 1.47 5 14 9 20.10 1.07 5 14 10 0.01 0.80 5 14 11 1.01 0.61 5 14 12 0.04 0.49 5 14 13 1.97 0.45 5 14 14 6.91 0.76 5 15 5 561.09 5.81 5 15 6 472.92 3.64 5 15 7 330.30 3.02 5 15 8 214.27 2.08 5 15 9 89.15 1.31 5 15 10 46.42 0.84 5 15 11 19.88 0.61 5 15 12 20.03 0.63 5 15 13 26.88 0.60 5 15 14 55.99 0.78 5 15 15 100.39 1.65 5 16 5 664.92 6.01 5 16 6 638.64 4.20 5 16 7 511.60 3.38 5 16 8 292.42 2.14 5 16 9 184.33 1.46 5 16 10 95.58 0.94 5 16 11 44.98 0.69 5 16 12 38.49 0.67 5 16 13 74.85 0.99 5 16 14 126.93 1.39 5 16 15 167.28 1.54 5 16 16 212.47 2.64 5 17 5 529.71 4.07 5 17 6 552.63 3.08 5 17 7 477.23 2.60 5 17 8 310.00 1.88 5 17 9 164.87 1.19 5 17 10 73.14 0.82 5 17 11 42.31 0.80 5 17 12 44.15 0.82 5 17 13 93.36 1.23 5 17 14 146.68 1.54 5 17 15 222.49 2.04 5 17 16 292.77 2.31 5 17 17 236.65 2.97 5 18 5 334.59 2.72 5 18 6 357.23 2.03 5 18 7 326.20 1.77 5 18 8 212.70 1.33 5 18 9 79.86 0.94 5 18 10 43.91 0.70 5 18 11 20.35 0.65 5 18 12 32.37 0.73 5 18 13 34.78 0.78 5 18 14 119.24 1.46 5 18 15 225.67 2.00 5 18 16 244.88 2.11 5 18 17 198.00 1.87 5 18 18 172.18 2.37 5 19 5 166.97 1.80 5 19 6 167.65 1.25 5 19 7 144.15 1.17 5 19 8 75.11 0.82 5 19 9 40.46 0.66 5 19 10 13.57 0.58 5 19 11 12.08 0.58 5 19 12 0.23 0.53 5 19 13 13.55 0.62 5 19 14 50.10 0.95 5 19 15 111.91 1.41 5 19 16 140.92 1.55 5 19 17 166.18 1.65 5 19 18 124.14 1.41 5 19 19 46.45 1.24 5 20 5 67.65 1.02 5 20 6 45.98 0.65 5 20 7 33.60 0.57 5 20 8 27.53 0.53 5 20 9 8.58 0.52 5 20 10 2.19 0.52 5 20 11 9.25 0.59 5 20 12 4.30 0.56 5 20 13 0.22 0.57 5 20 14 10.68 0.64 5 20 15 25.50 0.76 5 20 16 86.71 1.13 5 20 17 102.17 1.29 5 20 18 59.30 0.90 5 20 19 12.79 0.62 5 20 20 0.60 0.76 5 21 5 3.46 0.58 5 21 6 1.99 0.43 5 21 7 9.12 0.44 5 21 8 8.88 0.47 5 21 9 0.74 0.48 5 21 10 24.00 0.62 5 21 11 39.70 0.79 5 21 12 41.51 0.75 5 21 13 10.77 0.63 5 21 14 0.68 0.59 5 21 15 15.79 0.66 5 21 16 37.16 0.77 5 21 17 46.01 0.86 5 21 18 22.70 0.67 5 21 19 0.26 0.51 5 21 20 5.43 0.51 5 21 21 15.09 0.92 5 22 5 1.15 0.59 5 22 6 1.47 0.45 5 22 7 12.28 0.52 5 22 8 8.09 0.48 5 22 9 6.30 0.53 5 22 10 38.76 0.76 5 22 11 71.82 0.93 5 22 12 53.91 0.89 5 22 13 35.09 0.77 5 22 14 0.46 0.59 5 22 15 4.94 0.57 5 22 16 17.78 0.68 5 22 17 17.82 0.66 5 22 18 5.58 0.54 5 22 19 0.01 0.52 5 22 20 5.28 0.60 5 22 21 15.06 0.59 5 22 22 15.88 1.09 5 23 5 1.82 0.65 5 23 6 24.81 0.63 5 23 7 31.45 0.62 5 23 8 4.78 0.52 5 23 9 5.23 0.53 5 23 10 27.07 0.68 5 23 11 41.15 0.83 5 23 12 50.57 0.86 5 23 13 13.21 0.67 5 23 14 0.73 0.57 5 23 15 4.41 0.56 5 23 16 10.85 0.62 5 23 17 10.97 0.58 5 23 18 4.75 0.54 5 23 19 0.05 0.53 5 23 20 2.44 0.50 5 23 21 8.75 0.72 5 23 22 11.71 0.81 5 23 23 9.65 1.68 5 24 5 39.70 0.91 5 24 6 65.77 0.82 5 24 7 45.15 0.69 5 24 8 8.37 0.52 5 24 9 0.23 0.49 5 24 10 6.33 0.68 5 24 11 17.53 0.65 5 24 12 11.79 0.63 5 24 13 6.06 0.58 5 24 14 0.23 0.52 5 24 15 8.91 0.58 5 24 16 16.71 0.74 5 24 17 20.48 0.64 5 24 18 13.76 0.60 5 24 19 3.23 0.59 5 24 20 0.01 0.73 5 24 21 2.10 0.74 5 24 22 3.98 1.20 5 25 5 90.98 1.49 5 25 6 82.45 0.88 5 25 7 40.40 0.72 5 25 8 27.40 0.63 5 25 9 6.79 0.58 5 25 10 0.35 0.53 5 25 11 0.38 0.52 5 25 12 0.65 0.59 5 25 13 0.11 0.51 5 25 14 6.06 0.59 5 25 15 23.28 0.67 5 25 16 40.58 0.77 5 25 17 39.72 0.85 5 25 18 30.15 0.77 5 25 19 13.73 0.65 5 25 20 2.03 0.76 5 25 21 0.02 1.25 5 26 5 96.83 1.46 5 26 6 85.62 1.08 5 26 7 61.96 0.86 5 26 8 33.94 0.72 5 26 9 21.87 0.63 5 26 10 7.73 0.64 5 26 11 3.36 0.49 5 26 12 3.96 0.52 5 26 13 10.30 0.58 5 26 14 28.40 0.68 5 26 15 52.05 0.93 5 26 16 70.50 1.08 5 26 17 74.32 1.17 5 26 18 51.13 0.98 5 26 19 25.98 0.89 5 26 20 7.95 1.75 5 27 5 107.98 1.47 5 27 6 120.42 1.16 5 27 7 83.70 1.07 5 27 8 53.49 0.85 5 27 9 32.85 0.72 5 27 10 16.17 0.63 5 27 11 11.39 0.58 5 27 12 13.97 0.65 5 27 13 28.29 0.72 5 27 14 45.71 0.91 5 27 15 74.44 1.18 5 27 16 95.45 1.41 5 27 17 89.54 1.62 5 27 18 63.48 1.95 5 27 19 34.62 2.07 5 28 5 119.35 1.78 5 28 6 135.51 1.38 5 28 7 94.87 1.15 5 28 8 64.98 0.92 5 28 9 36.19 0.74 5 28 10 22.22 0.65 5 28 11 16.95 0.62 5 28 12 23.48 0.68 5 28 13 32.05 0.75 5 28 14 54.22 0.94 5 28 15 74.02 1.27 5 28 16 95.99 1.64 5 28 17 85.70 1.93 5 29 5 100.97 1.56 5 29 6 106.00 1.39 5 29 7 89.48 1.19 5 29 8 57.36 0.85 5 29 9 32.56 0.72 5 29 10 18.23 0.60 5 29 11 14.37 0.66 5 29 12 15.72 0.63 5 29 13 25.92 0.70 5 29 14 39.64 0.91 5 29 15 54.71 1.31 5 29 16 68.92 3.16 5 30 5 62.66 1.51 5 30 6 68.63 1.01 5 30 7 61.12 1.07 5 30 8 42.35 0.83 5 30 9 23.00 0.73 5 30 10 9.07 0.66 5 30 11 5.19 0.57 5 30 12 4.49 0.62 5 30 13 10.17 0.76 5 30 14 18.69 1.63 5 31 5 36.99 1.36 5 31 6 37.49 0.86 5 31 7 31.95 0.76 5 31 8 22.52 0.69 5 31 9 6.42 0.68 5 31 10 2.13 0.86 5 31 11 0.02 1.40 5 32 5 18.95 1.01 5 32 6 16.25 0.78 5 32 7 15.92 0.95 5 32 8 5.20 1.04 5 32 9 0.95 1.27 6 6 6 790.90 12.49 6 7 6 1232.44 8.20 6 7 7 1298.63 8.89 6 8 6 774.15 6.63 6 8 7 1061.71 5.73 6 8 8 841.50 7.23 6 9 6 420.73 4.10 6 9 7 566.60 3.88 6 9 8 401.94 2.81 6 9 9 101.95 1.97 6 10 6 199.63 3.27 6 10 7 170.42 1.84 6 10 8 52.34 1.19 6 10 9 8.11 0.74 6 10 10 9.81 1.16 6 11 6 118.24 2.13 6 11 7 8.32 0.90 6 11 8 2.41 0.76 6 11 9 8.55 0.85 6 11 10 31.57 1.06 6 11 11 75.68 2.15 6 12 6 7.36 1.23 6 12 7 3.43 0.84 6 12 8 1.38 0.79 6 12 9 6.14 0.90 6 12 10 24.74 1.17 6 12 11 101.46 1.90 6 12 12 103.83 2.54 6 13 6 40.23 1.49 6 13 7 22.85 1.09 6 13 8 16.35 0.99 6 13 9 0.15 0.89 6 13 10 19.57 1.08 6 13 11 49.22 1.09 6 13 12 44.09 0.87 6 13 13 19.12 0.85 6 14 6 153.51 2.97 6 14 7 139.53 1.98 6 14 8 97.18 1.73 6 14 9 26.29 1.21 6 14 10 0.66 0.67 6 14 11 2.24 0.61 6 14 12 0.44 0.47 6 14 13 0.07 0.47 6 14 14 4.64 0.99 6 15 6 448.75 4.98 6 15 7 342.92 2.85 6 15 8 239.17 2.26 6 15 9 111.11 1.55 6 15 10 47.27 0.91 6 15 11 16.83 0.57 6 15 12 14.28 0.59 6 15 13 15.20 0.63 6 15 14 43.82 0.78 6 15 15 87.57 1.74 6 16 6 634.11 5.49 6 16 7 537.31 3.10 6 16 8 321.99 2.22 6 16 9 195.80 1.45 6 16 10 98.88 1.01 6 16 11 47.14 0.72 6 16 12 36.31 0.68 6 16 13 65.84 0.90 6 16 14 117.65 1.39 6 16 15 158.41 1.58 6 16 16 215.50 3.16 6 17 6 628.92 4.92 6 17 7 548.97 2.73 6 17 8 346.01 1.95 6 17 9 183.28 1.33 6 17 10 72.25 0.95 6 17 11 39.46 0.74 6 17 12 37.45 0.75 6 17 13 73.40 1.15 6 17 14 136.03 1.66 6 17 15 218.97 2.16 6 17 16 288.61 2.32 6 17 17 246.95 3.01 6 18 6 400.18 3.02 6 18 7 364.09 1.97 6 18 8 219.10 1.47 6 18 9 90.27 1.05 6 18 10 42.87 0.73 6 18 11 20.49 0.64 6 18 12 25.57 0.64 6 18 13 31.00 0.80 6 18 14 102.89 1.39 6 18 15 217.39 1.96 6 18 16 231.80 2.03 6 18 17 198.38 1.91 6 18 18 158.80 2.22 6 19 6 192.72 1.96 6 19 7 156.15 1.26 6 19 8 76.32 0.89 6 19 9 39.37 0.63 6 19 10 10.83 0.55 6 19 11 6.85 0.53 6 19 12 0.00 0.54 6 19 13 7.10 0.62 6 19 14 38.53 0.91 6 19 15 102.91 1.37 6 19 16 139.87 1.63 6 19 17 160.57 1.66 6 19 18 107.78 1.29 6 19 19 45.58 1.23 6 20 6 53.41 0.96 6 20 7 34.76 0.59 6 20 8 23.58 0.53 6 20 9 7.79 0.47 6 20 10 0.09 0.48 6 20 11 11.93 0.58 6 20 12 10.30 0.64 6 20 13 1.34 0.58 6 20 14 5.17 0.63 6 20 15 32.53 0.79 6 20 16 92.95 1.18 6 20 17 102.29 1.29 6 20 18 59.09 0.92 6 20 19 14.59 0.62 6 20 20 0.05 0.75 6 21 6 6.31 0.66 6 21 7 13.41 0.50 6 21 8 11.66 0.52 6 21 9 1.77 0.48 6 21 10 15.74 0.58 6 21 11 35.17 0.79 6 21 12 37.83 0.76 6 21 13 10.47 0.67 6 21 14 0.38 0.59 6 21 15 18.73 0.68 6 21 16 41.95 0.84 6 21 17 48.67 0.88 6 21 18 22.09 0.66 6 21 19 1.44 0.53 6 21 20 2.11 0.50 6 21 21 6.68 0.81 6 22 6 19.48 0.76 6 22 7 34.69 0.66 6 22 8 24.24 0.58 6 22 9 0.00 0.49 6 22 10 17.64 0.67 6 22 11 48.68 0.83 6 22 12 41.36 0.82 6 22 13 20.92 0.74 6 22 14 0.11 0.58 6 22 15 10.07 0.63 6 22 16 26.64 0.70 6 22 17 23.71 0.69 6 22 18 9.20 0.60 6 22 19 1.21 0.49 6 22 20 1.77 0.48 6 22 21 5.69 0.83 6 22 22 6.29 0.90 6 23 6 78.06 1.17 6 23 7 76.59 0.87 6 23 8 27.95 0.64 6 23 9 0.25 0.54 6 23 10 10.41 0.62 6 23 11 26.56 0.71 6 23 12 36.21 0.77 6 23 13 8.78 0.67 6 23 14 0.10 0.57 6 23 15 7.81 0.60 6 23 16 17.78 0.64 6 23 17 17.90 0.60 6 23 18 9.33 0.52 6 23 19 1.71 0.52 6 23 20 0.30 0.55 6 23 21 2.57 0.70 6 23 22 4.35 0.77 6 23 23 3.52 2.04 6 24 6 92.61 1.67 6 24 7 68.70 0.83 6 24 8 24.02 0.63 6 24 9 2.45 0.52 6 24 10 1.49 0.56 6 24 11 11.76 0.64 6 24 12 9.71 0.61 6 24 13 3.59 0.58 6 24 14 0.42 0.56 6 24 15 9.97 0.59 6 24 16 20.16 0.64 6 24 17 24.55 0.69 6 24 18 15.98 0.68 6 24 19 5.70 0.57 6 24 20 0.17 0.72 6 24 21 0.24 0.76 6 24 22 1.15 1.60 6 25 6 68.32 1.15 6 25 7 40.86 0.74 6 25 8 26.09 0.64 6 25 9 4.64 0.57 6 25 10 0.11 0.51 6 25 11 1.44 0.53 6 25 12 1.00 0.54 6 25 13 0.01 0.53 6 25 14 5.65 0.60 6 25 15 23.18 0.70 6 25 16 40.80 0.90 6 25 17 41.23 0.77 6 25 18 29.82 0.76 6 25 19 13.92 0.74 6 25 20 2.33 0.82 6 25 21 0.10 3.16 6 26 6 67.53 1.31 6 26 7 54.21 0.83 6 26 8 30.80 0.71 6 26 9 13.03 0.63 6 26 10 3.38 0.60 6 26 11 0.66 0.51 6 26 12 0.79 0.53 6 26 13 4.90 0.62 6 26 14 19.78 0.71 6 26 15 39.77 0.86 6 26 16 57.54 1.02 6 26 17 62.50 1.04 6 26 18 43.17 0.96 6 26 19 20.80 1.00 6 26 20 6.31 2.12 6 27 6 106.61 1.64 6 27 7 82.64 1.01 6 27 8 53.07 0.83 6 27 9 23.81 0.69 6 27 10 12.50 0.64 6 27 11 7.06 0.58 6 27 12 9.36 0.61 6 27 13 20.44 0.69 6 27 14 37.04 0.77 6 27 15 63.09 1.06 6 27 16 78.52 1.15 6 27 17 77.27 1.38 6 27 18 54.32 1.52 6 27 19 29.73 4.30 6 28 6 131.14 1.82 6 28 7 102.35 1.19 6 28 8 67.12 1.03 6 28 9 32.91 0.72 6 28 10 18.19 0.67 6 28 11 13.26 0.65 6 28 12 17.75 0.64 6 28 13 23.96 0.69 6 28 14 45.54 0.85 6 28 15 65.15 1.39 6 28 16 80.65 1.30 6 28 17 75.33 3.22 6 29 6 109.04 1.90 6 29 7 95.00 1.21 6 29 8 63.20 0.94 6 29 9 33.38 0.73 6 29 10 16.36 0.61 6 29 11 12.56 0.57 6 29 12 11.52 0.61 6 29 13 20.14 0.64 6 29 14 33.45 0.83 6 29 15 49.66 1.61 6 30 6 74.65 2.03 6 30 7 65.39 0.96 6 30 8 46.30 0.91 6 30 9 25.98 0.70 6 30 10 9.03 0.67 6 30 11 5.25 0.63 6 30 12 3.85 0.71 6 30 13 8.93 1.12 6 31 6 45.65 1.17 6 31 7 36.26 0.81 6 31 8 26.25 0.75 6 31 9 10.73 0.79 6 31 10 2.68 0.91 6 31 11 0.04 1.12 6 32 6 22.55 1.26 6 32 7 17.36 1.18 6 32 8 8.18 1.52 7 7 7 1242.99 19.79 7 8 7 1208.54 10.10 7 8 8 1001.16 8.18 7 9 7 705.89 6.36 7 9 8 416.76 2.88 7 9 9 115.02 2.02 7 10 7 180.29 2.22 7 10 8 34.50 1.00 7 10 9 0.86 0.72 7 10 10 40.42 1.54 7 11 7 1.42 1.23 7 11 8 4.40 0.81 7 11 9 31.41 1.04 7 11 10 73.09 1.46 7 11 11 119.98 2.95 7 12 7 6.49 1.16 7 12 8 6.97 0.87 7 12 9 19.91 1.08 7 12 10 73.92 1.60 7 12 11 143.11 2.16 7 12 12 162.99 2.36 7 13 7 33.11 1.69 7 13 8 11.69 1.02 7 13 9 0.01 0.95 7 13 10 33.39 1.13 7 13 11 52.26 1.18 7 13 12 67.97 1.26 7 13 13 30.56 1.15 7 14 7 144.73 2.82 7 14 8 92.58 1.58 7 14 9 22.30 0.88 7 14 10 0.21 0.69 7 14 11 5.09 0.63 7 14 12 7.29 0.56 7 14 13 3.12 0.51 7 14 14 0.12 0.80 7 15 7 258.31 3.87 7 15 8 188.95 1.76 7 15 9 80.23 1.14 7 15 10 18.40 0.70 7 15 11 6.47 0.54 7 15 12 3.56 0.53 7 15 13 4.55 0.61 7 15 14 18.57 0.70 7 15 15 61.83 1.30 7 16 7 410.47 3.72 7 16 8 267.06 1.68 7 16 9 131.32 1.08 7 16 10 45.55 0.66 7 16 11 17.11 0.61 7 16 12 11.51 0.59 7 16 13 29.10 0.76 7 16 14 60.03 1.04 7 16 15 109.05 1.35 7 16 16 164.98 2.45 7 17 7 407.26 3.30 7 17 8 275.47 1.58 7 17 9 119.16 1.13 7 17 10 36.07 0.68 7 17 11 15.15 0.61 7 17 12 18.44 0.61 7 17 13 38.39 0.79 7 17 14 86.28 1.22 7 17 15 159.10 1.66 7 17 16 216.31 1.97 7 17 17 177.97 2.45 7 18 7 282.66 2.56 7 18 8 173.08 1.24 7 18 9 51.83 0.73 7 18 10 18.20 0.56 7 18 11 3.06 0.55 7 18 12 7.10 0.58 7 18 13 11.98 0.71 7 18 14 59.15 1.17 7 18 15 151.23 1.79 7 18 16 172.89 1.79 7 18 17 144.18 1.58 7 18 18 114.16 2.09 7 19 7 101.61 1.48 7 19 8 45.66 0.66 7 19 9 9.97 0.48 7 19 10 0.98 0.51 7 19 11 0.44 0.56 7 19 12 2.38 0.57 7 19 13 0.57 0.62 7 19 14 25.76 0.78 7 19 15 72.73 1.12 7 19 16 117.67 1.48 7 19 17 121.59 1.46 7 19 18 75.44 1.05 7 19 19 30.05 1.08 7 20 7 18.87 0.73 7 20 8 10.33 0.49 7 20 9 0.42 0.47 7 20 10 2.05 0.54 7 20 11 22.11 0.68 7 20 12 17.21 0.72 7 20 13 4.67 0.65 7 20 14 2.07 0.59 7 20 15 21.90 0.75 7 20 16 68.21 1.03 7 20 17 67.04 1.01 7 20 18 39.20 0.76 7 20 19 7.03 0.57 7 20 20 0.17 0.78 7 21 7 22.50 0.74 7 21 8 14.05 0.52 7 21 9 0.31 0.52 7 21 10 14.67 0.64 7 21 11 45.69 0.85 7 21 12 43.83 0.82 7 21 13 19.47 0.73 7 21 14 0.41 0.60 7 21 15 10.54 0.66 7 21 16 34.68 0.78 7 21 17 40.88 0.78 7 21 18 18.90 0.62 7 21 19 1.11 0.51 7 21 20 0.83 0.47 7 21 21 3.43 1.05 7 22 7 53.77 1.04 7 22 8 30.28 0.67 7 22 9 0.22 0.54 7 22 10 14.00 0.66 7 22 11 45.44 0.84 7 22 12 44.27 0.87 7 22 13 25.17 0.71 7 22 14 0.69 0.61 7 22 15 4.34 0.71 7 22 16 18.60 0.67 7 22 17 16.51 0.62 7 22 18 6.85 0.57 7 22 19 0.34 0.50 7 22 20 1.20 0.57 7 22 21 4.04 0.67 7 22 22 5.36 1.17 7 23 7 80.59 1.31 7 23 8 28.47 0.67 7 23 9 0.52 0.54 7 23 10 11.64 0.63 7 23 11 26.65 0.77 7 23 12 39.00 0.80 7 23 13 16.71 0.74 7 23 14 0.97 0.58 7 23 15 2.45 0.59 7 23 16 11.08 0.59 7 23 17 12.97 0.62 7 23 18 8.07 0.55 7 23 19 0.89 0.53 7 23 20 0.04 0.59 7 23 21 1.66 0.62 7 23 22 3.71 0.80 7 23 23 3.86 2.40 7 24 7 54.14 1.03 7 24 8 16.12 0.59 7 24 9 0.38 0.54 7 24 10 6.62 0.57 7 24 11 17.63 0.70 7 24 12 19.64 0.67 7 24 13 8.98 0.66 7 24 14 0.09 0.61 7 24 15 4.90 0.62 7 24 16 14.36 0.63 7 24 17 17.88 0.61 7 24 18 12.14 0.61 7 24 19 2.91 0.64 7 24 20 0.07 0.65 7 24 21 0.47 0.83 7 24 22 1.76 2.06 7 25 7 27.49 0.98 7 25 8 12.48 0.61 7 25 9 1.46 0.56 7 25 10 2.29 0.56 7 25 11 6.39 0.61 7 25 12 6.37 0.65 7 25 13 2.09 0.64 7 25 14 0.86 0.59 7 25 15 12.26 0.62 7 25 16 25.36 0.77 7 25 17 24.81 0.75 7 25 18 18.93 0.78 7 25 19 6.95 0.77 7 25 20 1.03 0.87 7 25 21 0.02 2.09 7 26 7 40.31 0.99 7 26 8 17.16 0.63 7 26 9 6.73 0.56 7 26 10 0.02 0.55 7 26 11 0.20 0.56 7 26 12 0.29 0.57 7 26 13 0.42 0.54 7 26 14 9.55 0.62 7 26 15 25.95 0.68 7 26 16 38.75 0.74 7 26 17 38.69 0.92 7 26 18 28.25 0.88 7 26 19 12.17 1.28 7 26 20 3.55 3.30 7 27 7 62.58 1.20 7 27 8 30.74 0.72 7 27 9 11.67 0.64 7 27 10 2.59 0.56 7 27 11 0.54 0.51 7 27 12 1.49 0.57 7 27 13 9.04 0.56 7 27 14 17.81 0.63 7 27 15 39.83 0.79 7 27 16 49.60 1.33 7 27 17 46.12 0.97 7 27 18 32.76 2.43 7 28 7 83.04 1.52 7 28 8 41.89 0.79 7 28 9 19.59 0.67 7 28 10 7.08 0.57 7 28 11 3.37 0.60 7 28 12 6.69 0.60 7 28 13 12.82 0.57 7 28 14 26.58 0.81 7 28 15 45.09 0.91 7 28 16 56.72 1.63 7 28 17 51.81 4.90 7 29 7 82.48 2.03 7 29 8 44.47 0.84 7 29 9 21.51 0.73 7 29 10 9.45 0.56 7 29 11 4.46 0.54 7 29 12 5.30 0.58 7 29 13 12.58 0.70 7 29 14 21.90 0.88 7 29 15 35.09 1.46 7 30 7 59.43 1.26 7 30 8 35.52 0.74 7 30 9 16.56 0.66 7 30 10 5.03 0.57 7 30 11 0.78 0.69 7 30 12 0.97 0.86 7 30 13 4.08 1.46 7 31 7 32.39 1.09 7 31 8 21.76 0.79 7 31 9 7.66 0.93 7 31 10 2.26 1.29 7 31 11 0.27 2.00 7 32 7 12.47 2.45 8 8 8 882.46 10.56 8 9 8 226.74 2.54 8 9 9 6.85 1.11 8 10 8 2.02 1.03 8 10 9 46.40 1.11 8 10 10 161.65 2.69 8 11 8 19.02 1.68 8 11 9 121.26 1.77 8 11 10 181.49 2.28 8 11 11 267.55 3.85 8 12 8 22.10 1.49 8 12 9 70.90 1.44 8 12 10 118.91 2.02 8 12 11 194.83 2.35 8 12 12 158.69 2.66 8 13 8 1.58 1.33 8 13 9 12.20 0.97 8 13 10 56.56 1.17 8 13 11 100.79 1.49 8 13 12 87.25 1.25 8 13 13 51.19 1.17 8 14 8 46.24 1.50 8 14 9 2.14 0.66 8 14 10 3.18 0.72 8 14 11 22.54 0.66 8 14 12 19.18 0.67 8 14 13 11.92 0.62 8 14 14 1.62 0.85 8 15 8 100.01 2.15 8 15 9 28.11 0.82 8 15 10 3.23 0.51 8 15 11 0.60 0.48 8 15 12 1.78 0.63 8 15 13 0.36 0.58 8 15 14 2.97 0.65 8 15 15 18.63 1.08 8 16 8 124.55 1.61 8 16 9 48.14 0.67 8 16 10 9.86 0.55 8 16 11 0.56 0.51 8 16 12 0.02 0.55 8 16 13 7.25 0.60 8 16 14 26.08 0.80 8 16 15 50.71 0.97 8 16 16 95.25 1.87 8 17 8 126.42 1.70 8 17 9 42.57 0.81 8 17 10 3.32 0.47 8 17 11 0.12 0.56 8 17 12 0.26 0.54 8 17 13 8.93 0.62 8 17 14 40.68 0.84 8 17 15 83.65 1.36 8 17 16 123.73 1.51 8 17 17 104.80 1.91 8 18 8 58.79 1.07 8 18 9 10.26 0.49 8 18 10 0.31 0.44 8 18 11 3.05 0.54 8 18 12 1.27 0.58 8 18 13 1.60 0.64 8 18 14 26.17 0.86 8 18 15 87.27 1.29 8 18 16 100.52 1.44 8 18 17 86.72 1.27 8 18 18 62.93 1.41 8 19 8 5.94 0.70 8 19 9 0.02 0.45 8 19 10 9.85 0.56 8 19 11 13.85 0.70 8 19 12 14.66 0.66 8 19 13 1.15 0.61 8 19 14 9.74 0.72 8 19 15 39.44 0.89 8 19 16 67.58 1.06 8 19 17 70.37 0.96 8 19 18 36.99 0.81 8 19 19 13.58 0.85 8 20 8 0.49 0.65 8 20 9 0.98 0.48 8 20 10 23.16 0.66 8 20 11 42.48 0.84 8 20 12 36.81 0.86 8 20 13 10.59 0.72 8 20 14 0.09 0.62 8 20 15 12.82 0.71 8 20 16 36.74 0.81 8 20 17 37.10 0.77 8 20 18 19.00 0.63 8 20 19 2.19 0.49 8 20 20 1.06 0.70 8 21 8 3.65 0.72 8 21 9 0.43 0.53 8 21 10 30.65 0.84 8 21 11 66.23 1.06 8 21 12 56.89 0.98 8 21 13 28.42 0.85 8 21 14 3.75 0.64 8 21 15 2.46 0.61 8 21 16 13.01 0.67 8 21 17 17.66 0.64 8 21 18 4.30 0.53 8 21 19 0.14 0.53 8 21 20 3.95 0.60 8 21 21 9.43 0.86 8 22 8 8.70 0.76 8 22 9 1.65 0.55 8 22 10 36.45 0.80 8 22 11 80.87 1.06 8 22 12 76.66 1.16 8 22 13 43.00 0.90 8 22 14 10.09 0.65 8 22 15 0.05 0.58 8 22 16 5.75 0.62 8 22 17 7.39 0.60 8 22 18 1.90 0.53 8 22 19 0.01 0.55 8 22 20 2.87 0.57 8 22 21 8.03 0.70 8 22 22 10.18 1.01 8 23 8 3.97 0.85 8 23 9 4.66 0.59 8 23 10 34.96 0.80 8 23 11 65.21 1.04 8 23 12 71.72 1.10 8 23 13 40.31 0.95 8 23 14 10.53 0.71 8 23 15 0.27 0.64 8 23 16 1.98 0.57 8 23 17 4.68 0.56 8 23 18 1.71 0.62 8 23 19 0.01 0.53 8 23 20 1.33 0.64 8 23 21 5.96 0.68 8 23 22 10.09 0.98 8 23 23 10.99 4.50 8 24 8 2.02 0.76 8 24 9 4.70 0.59 8 24 10 19.57 0.78 8 24 11 45.61 0.94 8 24 12 48.82 0.97 8 24 13 27.74 0.82 8 24 14 6.77 0.68 8 24 15 0.04 0.55 8 24 16 2.53 0.56 8 24 17 5.56 0.59 8 24 18 2.60 0.58 8 24 19 0.23 0.57 8 24 20 0.64 0.84 8 24 21 2.99 0.83 8 24 22 7.07 3.50 8 25 8 3.55 0.85 8 25 9 0.98 0.63 8 25 10 8.16 0.66 8 25 11 21.41 0.74 8 25 12 20.24 0.76 8 25 13 11.47 0.70 8 25 14 0.37 0.60 8 25 15 2.08 0.54 8 25 16 8.78 0.61 8 25 17 9.36 0.64 8 25 18 5.43 0.68 8 25 19 1.41 0.96 8 25 20 0.00 0.94 8 26 8 6.84 0.88 8 26 9 0.05 0.58 8 26 10 1.82 0.60 8 26 11 5.86 0.62 8 26 12 6.10 0.63 8 26 13 0.68 0.55 8 26 14 2.80 0.50 8 26 15 9.07 0.63 8 26 16 17.42 0.65 8 26 17 17.46 0.75 8 26 18 10.13 0.87 8 26 19 3.26 1.24 8 27 8 16.35 0.88 8 27 9 1.47 0.58 8 27 10 0.01 0.56 8 27 11 0.75 0.56 8 27 12 0.15 0.52 8 27 13 1.41 0.50 8 27 14 8.87 0.57 8 27 15 19.44 0.69 8 27 16 27.79 0.79 8 27 17 26.53 0.93 8 27 18 16.57 3.65 8 28 8 20.53 0.89 8 28 9 4.00 0.54 8 28 10 0.42 0.55 8 28 11 0.07 0.51 8 28 12 0.84 0.55 8 28 13 2.57 0.66 8 28 14 12.90 0.63 8 28 15 21.66 0.98 8 28 16 31.23 1.21 8 29 8 23.11 0.91 8 29 9 6.12 0.59 8 29 10 1.11 0.56 8 29 11 0.47 0.51 8 29 12 0.66 0.75 8 29 13 3.06 0.76 8 29 14 10.38 1.24 8 29 15 17.85 1.52 8 30 8 20.44 0.93 8 30 9 7.22 0.63 8 30 10 0.61 0.66 8 30 11 0.02 0.88 8 30 12 0.00 1.36 8 30 13 0.83 2.30 8 31 8 9.98 0.99 8 31 9 2.23 1.23 8 31 10 0.01 1.78 9 9 9 40.49 2.28 9 10 9 181.08 2.86 9 10 10 332.53 3.82 9 11 9 224.28 3.90 9 11 10 289.07 3.11 9 11 11 305.06 4.60 9 12 9 131.76 2.95 9 12 10 209.99 2.52 9 12 11 223.44 2.53 9 12 12 208.33 2.76 9 13 9 37.92 1.83 9 13 10 99.43 1.46 9 13 11 115.19 1.62 9 13 12 106.61 1.35 9 13 13 60.98 1.90 9 14 9 5.05 0.87 9 14 10 27.59 0.63 9 14 11 46.29 0.71 9 14 12 40.79 0.87 9 14 13 26.47 0.80 9 14 14 7.99 0.91 9 15 9 2.25 0.60 9 15 10 2.97 0.58 9 15 11 12.29 0.52 9 15 12 11.55 0.66 9 15 13 5.31 0.53 9 15 14 0.05 0.70 9 15 15 5.77 0.93 9 16 9 7.10 0.72 9 16 10 0.35 0.47 9 16 11 6.48 0.57 9 16 12 4.84 0.62 9 16 13 0.03 0.60 9 16 14 4.87 0.66 9 16 15 19.20 0.78 9 16 16 42.04 1.21 9 17 9 0.99 0.61 9 17 10 5.48 0.48 9 17 11 13.85 0.61 9 17 12 6.33 0.64 9 17 13 0.01 0.68 9 17 14 11.63 0.71 9 17 15 38.12 0.88 9 17 16 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9 22 15 5.10 0.64 9 22 16 0.05 0.57 9 22 17 0.01 0.57 9 22 18 0.61 0.58 9 22 19 3.82 0.61 9 22 20 14.57 0.65 9 22 21 23.62 0.68 9 22 22 29.23 1.23 9 23 9 37.96 1.26 9 23 10 96.78 1.81 9 23 11 137.35 1.76 9 23 12 130.67 1.74 9 23 13 86.22 1.33 9 23 14 38.17 0.88 9 23 15 7.82 0.82 9 23 16 1.03 0.63 9 23 17 0.03 0.58 9 23 18 0.30 0.56 9 23 19 2.64 0.55 9 23 20 9.19 0.73 9 23 21 18.28 0.81 9 23 22 25.77 1.31 9 24 9 26.48 1.43 9 24 10 63.71 1.17 9 24 11 97.60 1.61 9 24 12 93.78 1.50 9 24 13 58.96 1.08 9 24 14 27.13 0.74 9 24 15 4.39 0.60 9 24 16 0.49 0.59 9 24 17 0.01 0.55 9 24 18 0.03 0.51 9 24 19 0.97 0.56 9 24 20 5.76 0.75 9 24 21 11.50 1.31 9 25 9 7.02 1.02 9 25 10 30.70 1.01 9 25 11 49.69 0.90 9 25 12 44.23 0.99 9 25 13 31.05 0.80 9 25 14 9.62 0.67 9 25 15 0.38 0.59 9 25 16 0.12 0.56 9 25 17 0.30 0.57 9 25 18 0.09 0.57 9 25 19 0.24 0.80 9 25 20 3.27 2.47 9 26 9 1.16 0.90 9 26 10 12.11 0.74 9 26 11 18.51 0.71 9 26 12 16.17 0.68 9 26 13 5.66 0.61 9 26 14 0.15 0.54 9 26 15 2.00 0.53 9 26 16 4.36 0.58 9 26 17 4.96 0.63 9 26 18 2.72 1.01 9 26 19 0.47 2.66 9 27 9 0.10 0.77 9 27 10 3.45 0.56 9 27 11 4.54 0.58 9 27 12 2.10 0.56 9 27 13 0.03 0.55 9 27 14 1.98 0.54 9 27 15 9.09 0.56 9 27 16 12.29 0.75 9 27 17 11.91 1.17 9 28 9 0.22 0.69 9 28 10 0.74 0.50 9 28 11 0.38 0.59 9 28 12 0.03 0.51 9 28 13 0.38 0.57 9 28 14 4.04 0.60 9 28 15 10.31 1.10 9 28 16 16.30 1.55 9 29 9 0.41 0.82 9 29 10 0.08 0.62 9 29 11 0.04 0.60 9 29 12 0.16 0.57 9 29 13 0.24 0.67 9 29 14 2.53 0.96 9 30 9 0.73 0.86 9 30 10 0.13 0.69 9 30 11 0.29 1.16 9 30 12 1.02 2.26 9 31 9 0.30 3.50 10 10 10 417.09 7.72 10 11 10 317.24 4.94 10 11 11 313.35 5.01 10 12 10 248.51 4.14 10 12 11 230.03 2.77 10 12 12 210.78 3.22 10 13 10 142.96 2.23 10 13 11 147.36 1.53 10 13 12 117.60 1.40 10 13 13 68.66 1.86 10 14 10 53.18 1.36 10 14 11 67.50 0.94 10 14 12 55.87 0.97 10 14 13 37.28 0.86 10 14 14 14.81 0.92 10 15 10 17.35 0.80 10 15 11 28.32 0.74 10 15 12 20.33 0.75 10 15 13 8.91 0.68 10 15 14 2.20 0.61 10 15 15 0.60 0.81 10 16 10 13.74 0.87 10 16 11 24.14 0.76 10 16 12 13.30 0.69 10 16 13 1.97 0.65 10 16 14 0.12 0.64 10 16 15 5.91 0.64 10 16 16 20.15 1.07 10 17 10 26.87 0.97 10 17 11 32.16 0.86 10 17 12 12.97 0.77 10 17 13 1.77 0.65 10 17 14 3.86 0.67 10 17 15 17.04 0.70 10 17 16 30.15 0.77 10 17 17 28.17 1.12 10 18 10 46.08 1.12 10 18 11 49.40 0.91 10 18 12 26.36 0.81 10 18 13 4.80 0.66 10 18 14 1.29 0.72 10 18 15 14.20 0.73 10 18 16 23.38 0.74 10 18 17 21.13 0.78 10 18 18 11.92 1.23 10 19 10 62.28 1.33 10 19 11 69.97 1.20 10 19 12 41.00 0.97 10 19 13 16.83 0.75 10 19 14 0.08 0.72 10 19 15 3.76 0.80 10 19 16 13.90 0.75 10 19 17 11.42 0.90 10 19 18 3.59 0.70 10 19 19 0.02 0.92 10 20 10 106.97 2.07 10 20 11 114.88 1.73 10 20 12 98.27 1.60 10 20 13 46.09 1.16 10 20 14 12.60 0.88 10 20 15 0.07 0.67 10 20 16 2.09 0.79 10 20 17 1.54 0.67 10 20 18 0.38 0.69 10 20 19 2.58 0.68 10 20 20 12.02 1.00 10 21 10 138.13 2.57 10 21 11 179.01 2.10 10 21 12 147.20 2.01 10 21 13 96.98 1.82 10 21 14 28.11 0.97 10 21 15 8.62 0.74 10 21 16 0.14 0.82 10 21 17 0.02 0.67 10 21 18 1.42 0.66 10 21 19 11.47 0.67 10 21 20 25.26 0.78 10 21 21 44.47 1.29 10 22 10 186.03 2.89 10 22 11 222.36 2.30 10 22 12 213.62 2.27 10 22 13 135.14 1.83 10 22 14 64.17 1.09 10 22 15 24.52 0.84 10 22 16 5.39 0.67 10 22 17 3.47 0.65 10 22 18 5.85 0.66 10 22 19 16.55 0.67 10 22 20 29.78 0.77 10 22 21 48.89 0.87 10 22 22 52.27 1.61 10 23 10 177.47 3.20 10 23 11 209.32 2.27 10 23 12 197.93 2.13 10 23 13 141.50 1.82 10 23 14 68.96 1.08 10 23 15 31.73 0.82 10 23 16 11.23 0.67 10 23 17 6.44 0.65 10 23 18 6.83 0.62 10 23 19 15.32 0.65 10 23 20 24.95 0.74 10 23 21 40.65 1.11 10 23 22 46.31 2.90 10 24 10 115.62 2.23 10 24 11 146.79 1.75 10 24 12 146.87 1.83 10 24 13 94.72 1.41 10 24 14 50.08 1.02 10 24 15 20.50 0.73 10 24 16 7.23 0.62 10 24 17 4.22 0.56 10 24 18 3.88 0.56 10 24 19 8.49 0.64 10 24 20 17.29 0.97 10 24 21 27.62 3.28 10 25 10 64.18 1.54 10 25 11 82.90 1.27 10 25 12 74.32 1.07 10 25 13 47.44 1.05 10 25 14 18.84 0.73 10 25 15 4.80 0.60 10 25 16 0.61 0.57 10 25 17 0.34 0.53 10 25 18 0.32 0.59 10 25 19 1.91 0.83 10 25 20 8.05 2.54 10 26 10 25.06 1.04 10 26 11 33.96 0.82 10 26 12 25.90 0.84 10 26 13 10.34 0.63 10 26 14 2.82 0.57 10 26 15 0.02 0.50 10 26 16 0.58 0.55 10 26 17 0.70 0.62 10 26 18 0.27 1.53 10 27 10 7.06 0.88 10 27 11 10.20 0.61 10 27 12 4.39 0.55 10 27 13 0.40 0.51 10 27 14 0.01 0.58 10 27 15 2.44 0.57 10 27 16 5.28 0.73 10 27 17 5.44 1.78 10 28 10 1.29 0.77 10 28 11 1.47 0.50 10 28 12 0.06 0.51 10 28 13 0.10 0.51 10 28 14 0.98 0.66 10 28 15 4.82 1.17 10 29 10 0.14 0.85 10 29 11 0.47 0.58 10 29 12 0.09 0.99 10 29 13 0.00 1.05 10 30 10 1.89 1.56 10 30 11 3.18 1.07 11 11 11 344.90 6.12 11 12 11 218.15 2.79 11 12 12 180.18 2.51 11 13 11 156.97 2.18 11 13 12 119.99 1.58 11 13 13 84.61 2.03 11 14 11 63.98 2.40 11 14 12 56.95 1.06 11 14 13 40.55 0.94 11 14 14 9.71 1.07 11 15 11 30.35 1.03 11 15 12 29.31 0.86 11 15 13 14.58 0.68 11 15 14 3.23 0.67 11 15 15 0.11 0.89 11 16 11 21.06 1.03 11 16 12 16.38 0.73 11 16 13 3.53 0.63 11 16 14 0.01 0.58 11 16 15 2.98 0.63 11 16 16 12.15 0.98 11 17 11 24.79 1.35 11 17 12 15.58 0.85 11 17 13 2.62 0.81 11 17 14 1.29 0.77 11 17 15 10.85 0.77 11 17 16 17.65 0.78 11 17 17 19.65 1.33 11 18 11 37.55 1.46 11 18 12 25.67 0.93 11 18 13 3.42 0.84 11 18 14 0.53 0.96 11 18 15 10.10 0.76 11 18 16 15.45 0.85 11 18 17 15.94 0.88 11 18 18 7.06 1.20 11 19 11 75.74 2.22 11 19 12 50.09 1.09 11 19 13 22.63 0.86 11 19 14 1.78 0.84 11 19 15 1.32 0.80 11 19 16 6.29 0.94 11 19 17 7.64 0.81 11 19 18 2.00 0.81 11 19 19 0.05 0.99 11 20 11 120.52 2.58 11 20 12 105.46 1.81 11 20 13 52.08 1.23 11 20 14 23.73 1.01 11 20 15 0.55 0.85 11 20 16 0.03 0.72 11 20 17 0.33 0.88 11 20 18 0.28 0.68 11 20 19 4.36 0.70 11 20 20 23.68 1.07 11 21 11 234.22 3.16 11 21 12 189.23 2.33 11 21 13 130.83 1.85 11 21 14 56.67 1.23 11 21 15 18.45 0.94 11 21 16 3.49 0.74 11 21 17 1.01 0.68 11 21 18 5.08 0.70 11 21 19 15.19 0.75 11 21 20 40.95 0.90 11 21 21 57.26 1.73 11 22 11 269.68 3.77 11 22 12 247.50 2.71 11 22 13 162.31 2.21 11 22 14 94.66 2.19 11 22 15 38.70 1.02 11 22 16 14.58 0.76 11 22 17 6.99 0.70 11 22 18 14.55 0.71 11 22 19 27.86 0.78 11 22 20 52.15 0.94 11 22 21 67.86 1.55 11 22 22 72.72 5.56 11 23 11 264.40 3.66 11 23 12 234.19 2.51 11 23 13 179.08 2.10 11 23 14 100.82 1.55 11 23 15 50.89 0.94 11 23 16 24.03 0.77 11 23 17 12.01 0.69 11 23 18 15.88 0.69 11 23 19 26.50 0.73 11 23 20 42.82 1.33 11 23 21 54.29 1.95 11 24 11 183.55 2.90 11 24 12 171.17 1.95 11 24 13 118.12 1.73 11 24 14 65.26 1.12 11 24 15 32.32 0.80 11 24 16 14.66 0.68 11 24 17 7.51 0.79 11 24 18 8.48 0.67 11 24 19 15.55 0.96 11 24 20 26.77 1.14 11 25 11 96.09 1.96 11 25 12 83.22 1.64 11 25 13 56.79 0.98 11 25 14 22.17 0.77 11 25 15 9.47 0.63 11 25 16 2.54 0.57 11 25 17 1.13 0.55 11 25 18 1.33 0.82 11 25 19 5.23 1.34 11 26 11 38.10 1.11 11 26 12 28.23 0.75 11 26 13 15.04 0.65 11 26 14 3.25 0.57 11 26 15 0.48 0.55 11 26 16 0.32 0.62 11 26 17 0.90 0.77 11 26 18 0.45 1.85 11 27 11 8.58 0.82 11 27 12 3.92 0.54 11 27 13 1.29 0.51 11 27 14 0.00 0.64 11 27 15 0.75 0.65 11 27 16 3.38 1.14 11 28 11 0.56 0.72 11 28 12 0.01 0.52 11 28 13 0.01 0.59 11 28 14 0.58 0.98 11 28 15 2.34 1.80 11 29 11 0.48 1.12 11 29 12 0.18 1.50 12 12 12 172.94 4.61 12 13 12 98.72 2.12 12 13 13 65.77 1.78 12 14 12 54.78 1.41 12 14 13 42.60 0.99 12 14 14 18.54 1.26 12 15 12 20.32 1.12 12 15 13 11.39 0.75 12 15 14 4.55 0.83 12 15 15 0.06 1.08 12 16 12 5.92 1.11 12 16 13 1.48 0.68 12 16 14 0.00 0.76 12 16 15 4.48 0.83 12 16 16 15.28 1.38 12 17 12 5.19 1.07 12 17 13 0.71 0.68 12 17 14 1.61 0.81 12 17 15 11.83 0.88 12 17 16 20.27 0.97 12 17 17 24.62 1.36 12 18 12 14.94 1.00 12 18 13 2.24 0.83 12 18 14 0.87 0.87 12 18 15 8.33 0.83 12 18 16 19.76 0.94 12 18 17 24.02 0.97 12 18 18 18.73 1.30 12 19 12 30.36 1.22 12 19 13 15.47 0.89 12 19 14 0.79 0.81 12 19 15 1.16 0.78 12 19 16 7.09 0.87 12 19 17 8.19 0.85 12 19 18 5.16 0.83 12 19 19 0.00 1.69 12 20 12 97.87 3.08 12 20 13 55.60 1.30 12 20 14 23.28 1.01 12 20 15 0.88 0.97 12 20 16 0.24 0.91 12 20 17 1.15 0.96 12 20 18 0.40 0.77 12 20 19 3.41 0.87 12 20 20 18.70 1.48 12 21 12 167.84 3.37 12 21 13 126.52 2.03 12 21 14 58.64 1.29 12 21 15 21.46 1.05 12 21 16 3.59 0.79 12 21 17 1.76 0.78 12 21 18 3.51 0.74 12 21 19 19.44 0.82 12 21 20 45.05 0.93 12 21 21 67.95 3.30 12 22 12 246.59 3.92 12 22 13 173.84 2.19 12 22 14 106.92 1.74 12 22 15 44.85 1.18 12 22 16 15.28 0.82 12 22 17 6.94 0.77 12 22 18 11.07 0.77 12 22 19 28.09 0.80 12 22 20 49.45 0.99 12 22 21 68.92 1.68 12 22 22 67.33 4.20 12 23 12 208.92 3.50 12 23 13 164.71 2.00 12 23 14 99.12 1.54 12 23 15 45.88 1.00 12 23 16 21.96 0.76 12 23 17 12.11 0.74 12 23 18 15.36 0.80 12 23 19 28.43 0.75 12 23 20 45.09 1.02 12 23 21 55.66 2.60 12 24 12 158.72 2.62 12 24 13 110.90 1.53 12 24 14 67.04 1.12 12 24 15 27.94 0.81 12 24 16 13.45 0.66 12 24 17 6.96 0.66 12 24 18 8.19 0.65 12 24 19 14.39 0.97 12 24 20 26.00 2.02 12 25 12 75.99 2.03 12 25 13 49.74 0.97 12 25 14 25.00 0.73 12 25 15 7.59 0.62 12 25 16 2.31 0.61 12 25 17 0.56 0.65 12 25 18 0.93 0.85 12 25 19 3.54 2.00 12 26 12 22.03 0.99 12 26 13 9.92 0.60 12 26 14 3.30 0.57 12 26 15 0.07 0.61 12 26 16 0.41 0.62 12 26 17 1.83 1.24 12 27 12 2.91 0.77 12 27 13 0.27 0.53 12 27 14 0.03 0.58 12 27 15 1.92 0.87 12 27 16 4.14 1.70 12 28 12 0.16 1.00 12 28 13 0.12 0.79 12 28 14 0.65 1.27 12 29 12 0.86 2.10 13 13 13 51.26 5.16 13 14 13 35.35 1.50 13 14 14 15.77 1.30 13 15 13 6.91 1.18 13 15 14 2.16 0.79 13 15 15 0.00 1.17 13 16 13 0.21 1.06 13 16 14 0.49 0.81 13 16 15 6.44 0.92 13 16 16 20.89 1.46 13 17 13 0.24 1.09 13 17 14 5.78 0.87 13 17 15 17.79 0.99 13 17 16 32.56 1.24 13 17 17 46.95 1.65 13 18 13 0.17 1.09 13 18 14 6.47 0.82 13 18 15 12.71 0.94 13 18 16 31.50 1.35 13 18 17 42.67 1.11 13 18 18 32.42 1.40 13 19 13 5.78 1.11 13 19 14 0.17 0.76 13 19 15 4.54 0.78 13 19 16 18.90 0.98 13 19 17 25.51 1.02 13 19 18 18.20 0.90 13 19 19 6.07 1.19 13 20 13 33.83 1.58 13 20 14 12.52 0.95 13 20 15 0.20 0.84 13 20 16 1.49 0.93 13 20 17 4.07 1.25 13 20 18 1.64 0.94 13 20 19 0.29 0.75 13 20 20 12.54 1.28 13 21 13 94.91 3.08 13 21 14 43.08 1.15 13 21 15 13.50 0.93 13 21 16 0.32 0.85 13 21 17 0.00 0.82 13 21 18 0.22 0.76 13 21 19 7.13 0.75 13 21 20 28.57 0.91 13 21 21 45.07 1.45 13 22 13 122.08 2.83 13 22 14 72.31 1.50 13 22 15 29.76 0.95 13 22 16 6.88 0.85 13 22 17 2.77 0.71 13 22 18 6.05 0.73 13 22 19 18.07 0.76 13 22 20 35.47 0.94 13 22 21 51.77 1.30 13 23 13 127.24 2.64 13 23 14 71.67 1.31 13 23 15 31.02 0.95 13 23 16 11.02 0.82 13 23 17 5.85 0.70 13 23 18 7.41 0.72 13 23 19 16.30 0.83 13 23 20 26.70 1.21 13 24 13 78.44 1.95 13 24 14 43.01 0.93 13 24 15 17.55 0.73 13 24 16 6.38 0.62 13 24 17 3.80 0.67 13 24 18 4.06 0.79 13 24 19 8.24 1.72 13 25 13 32.26 1.15 13 25 14 13.59 0.65 13 25 15 3.40 0.61 13 25 16 0.23 0.66 13 25 17 0.02 0.79 13 25 18 0.01 1.40 13 26 13 5.82 0.79 13 26 14 0.84 0.58 13 26 15 0.07 0.63 13 26 16 1.84 0.95 13 27 13 0.03 0.82 13 27 14 1.07 0.70 13 27 15 4.13 1.10 13 28 13 0.35 1.35 14 14 14 4.95 2.35 14 15 14 0.01 1.18 14 15 15 2.82 1.27 14 16 14 2.27 1.24 14 16 15 16.01 1.03 14 16 16 32.34 2.00 14 17 14 10.06 1.45 14 17 15 32.35 1.20 14 17 16 45.70 1.37 14 17 17 62.84 2.25 14 18 14 16.01 1.35 14 18 15 32.67 1.09 14 18 16 54.74 1.25 14 18 17 68.41 1.41 14 18 18 60.24 1.78 14 19 14 4.25 1.07 14 19 15 17.83 0.87 14 19 16 35.52 1.05 14 19 17 45.63 1.21 14 19 18 35.88 1.08 14 19 19 18.35 1.32 14 20 14 1.94 1.22 14 20 15 3.60 1.09 14 20 16 11.83 1.05 14 20 17 21.13 1.09 14 20 18 12.77 1.14 14 20 19 4.16 0.75 14 20 20 0.24 1.08 14 21 14 17.06 1.84 14 21 15 2.37 0.90 14 21 16 0.75 1.01 14 21 17 2.15 0.83 14 21 18 0.54 0.77 14 21 19 0.91 0.70 14 21 20 9.25 0.80 14 21 21 21.31 1.22 14 22 14 34.35 1.50 14 22 15 11.37 0.85 14 22 16 0.94 0.79 14 22 17 0.01 0.77 14 22 18 1.00 0.72 14 22 19 4.79 0.74 14 22 20 14.09 0.82 14 22 21 25.06 1.75 14 23 14 31.50 1.34 14 23 15 11.72 0.79 14 23 16 2.74 0.73 14 23 17 0.55 0.70 14 23 18 1.64 0.69 14 23 19 4.43 0.88 14 23 20 10.78 1.48 14 24 14 16.94 1.12 14 24 15 5.51 0.62 14 24 16 1.00 0.68 14 24 17 0.19 0.75 14 24 18 0.39 1.27 14 25 14 4.66 1.01 14 25 15 0.52 0.62 14 25 16 0.12 0.78 14 25 17 0.43 1.51 14 26 14 0.19 1.03 14 26 15 2.40 0.91 14 26 16 6.86 1.90 14 27 14 3.63 1.33 15 15 15 6.84 2.52 15 16 15 29.34 1.70 15 16 16 54.57 1.99 15 17 15 53.13 2.09 15 17 16 72.30 1.79 15 17 17 91.25 2.73 15 18 15 47.11 1.81 15 18 16 73.33 1.53 15 18 17 90.99 1.77 15 18 18 92.88 2.44 15 19 15 37.32 1.45 15 19 16 57.78 1.23 15 19 17 65.87 1.41 15 19 18 60.74 1.22 15 19 19 33.32 1.34 15 20 15 20.62 1.47 15 20 16 30.18 1.18 15 20 17 36.19 1.17 15 20 18 29.45 1.13 15 20 19 11.77 0.80 15 20 20 0.80 1.12 15 21 15 1.95 1.28 15 21 16 9.94 0.94 15 21 17 11.00 0.94 15 21 18 10.85 0.81 15 21 19 1.69 0.72 15 21 20 0.66 0.76 15 21 21 4.94 2.50 15 22 15 0.87 1.19 15 22 16 0.53 0.80 15 22 17 1.73 0.82 15 22 18 0.94 0.70 15 22 19 0.04 0.75 15 22 20 2.74 1.73 15 23 15 1.67 1.17 15 23 16 0.05 0.69 15 23 17 0.18 0.71 15 23 18 0.06 0.87 15 23 19 0.34 3.75 15 24 15 0.39 0.97 15 24 16 0.09 0.68 15 24 17 0.85 1.02 15 24 18 0.50 2.10 15 25 15 1.05 1.02 15 25 16 3.52 2.45 15 26 15 6.82 2.10 16 16 16 80.92 5.95 16 17 16 93.52 2.88 16 17 17 109.37 2.82 16 18 16 97.06 2.34 16 18 17 106.57 1.73 16 18 18 98.31 2.06 16 19 16 82.97 2.13 16 19 17 88.85 1.61 16 19 18 68.33 1.44 16 19 19 42.12 1.50 16 20 16 45.14 2.09 16 20 17 52.57 1.29 16 20 18 36.08 1.05 16 20 19 17.76 0.91 16 20 20 3.99 1.14 16 21 16 20.38 1.45 16 21 17 21.37 1.11 16 21 18 15.32 0.79 16 21 19 4.14 0.79 16 21 20 0.16 1.08 16 22 16 4.85 1.12 16 22 17 7.27 0.74 16 22 18 4.63 0.85 16 22 19 0.89 1.54 16 23 16 0.71 0.95 16 23 17 2.60 0.83 16 23 18 2.07 2.50 16 24 16 2.25 1.67 17 17 17 121.15 5.90 17 18 17 106.24 2.46 17 18 18 89.88 2.11 17 19 17 86.00 2.16 17 19 18 58.41 1.13 17 19 19 35.00 1.43 17 20 17 51.30 1.57 17 20 18 30.52 0.95 17 20 19 13.86 1.07 17 20 20 2.40 1.78 17 21 17 20.03 1.16 17 21 18 12.40 0.87 17 21 19 3.77 1.28 17 22 17 6.93 1.19 17 22 18 4.14 1.90 18 18 18 76.98 3.51 18 19 18 38.08 1.54 18 19 19 16.69 2.06 18 20 18 17.17 1.53 18 20 19 5.25 1.29 18 21 18 4.86 1.80 19 19 19 4.90 3.10 0 0 0 0.00 0.00 ; _shelx_hkl_checksum 97765 loop_ _space_group_symop_operation_xyz 'x, y, z' '-y, x, z' '-x, -y, z' 'y, -x, z' 'x, -z, y' 'x, -y, -z' 'x, z, -y' 'z, y, -x' '-x, y, -z' '-z, y, x' 'z, x, y' 'y, z, x' '-y, -z, x' 'z, -x, -y' '-y, z, -x' '-z, -x, y' '-z, x, -y' 'y, -z, -x' 'y, x, -z' '-y, -x, -z' '-x, z, y' '-x, -z, -y' 'z, -y, x' '-z, -y, -x' '-x, -y, -z' 'y, -x, -z' 'x, y, -z' '-y, x, -z' '-x, z, -y' '-x, y, z' '-x, -z, y' '-z, -y, x' 'x, -y, z' 'z, -y, -x' '-z, -x, -y' '-y, -z, -x' 'y, z, -x' '-z, x, y' 'y, -z, x' 'z, x, -y' 'z, -x, y' '-y, z, x' '-y, -x, z' 'y, x, z' 'x, -z, -y' 'x, z, y' '-z, y, -x' 'z, y, x' loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_site_symmetry_order _atom_site_calc_flag _atom_site_refinement_flags_posn _atom_site_refinement_flags_adp _atom_site_refinement_flags_occupancy _atom_site_disorder_assembly _atom_site_disorder_group Zr1 Zr 0.5000 0.5000 0.58840(2) 0.0307(4) Uani 1 8 d S T P . . O1 O 0.5000 0.43071(12) 0.62721(11) 0.0500(8) Uani 1 2 d DS T P . . O2 O 0.45673(18) 0.45673(18) 0.54327(18) 0.072(3) Uani 1 6 d S T P . . C1 C 0.5000 0.3851(5) 0.6154(5) 0.132(3) Uani 0.0625 1 d DS U P . -1 C2 C 0.5000 0.3508(6) 0.6574(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 C3 C 0.514(3) 0.3034(9) 0.6515(9) 0.132(3) Uani 0.0625 1 d D U P . -1 H3 H 0.5213 0.2918 0.6207 0.158 Uiso 0.0625 1 calc R U P . -1 C4 C 0.519(2) 0.2735(10) 0.6907(10) 0.132(3) Uani 0.0625 1 d D U P . -1 H4 H 0.5340 0.2438 0.6875 0.158 Uiso 0.0625 1 calc R U P . -1 C5 C 0.5000 0.2869(7) 0.7345(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 C6 C 0.485(2) 0.3337(9) 0.7406(9) 0.132(3) Uani 0.0625 1 d D U P . -1 H6 H 0.4753 0.3442 0.7710 0.158 Uiso 0.0625 1 calc R U P . -1 C7 C 0.485(2) 0.3652(9) 0.7025(8) 0.132(3) Uani 0.0625 1 d D U P . -1 H7 H 0.4738 0.3967 0.7071 0.158 Uiso 0.0625 1 calc R U P . -1 C8 C 0.5000 0.2539(9) 0.7748(9) 0.132(3) Uani 0.0625 1 d DS U P . -1 C9 C 0.5000 0.2252(10) 0.8081(10) 0.132(3) Uani 0.0625 1 d DS U P . -1 C10 C 0.5000 0.1913(8) 0.8478(9) 0.132(3) Uani 0.0625 1 d DS U P . -1 C11 C 0.4594(5) 0.1652(11) 0.8586(10) 0.132(3) Uani 0.0625 1 d D U P . -1 H11 H 0.4316 0.1691 0.8401 0.158 Uiso 0.0625 1 calc R U P . -1 C12 C 0.4595(6) 0.1329(13) 0.8968(11) 0.132(3) Uani 0.0625 1 d D U P . -1 H12 H 0.4315 0.1157 0.9041 0.158 Uiso 0.0625 1 calc R U P . -1 C13 C 0.5000 0.1263(7) 0.9235(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 C14 C 0.5412(6) 0.1515(14) 0.9118(13) 0.132(3) Uani 0.0625 1 d D U P . -1 H14 H 0.5701 0.1446 0.9276 0.158 Uiso 0.0625 1 calc DR U P . -1 C15 C 0.5397(7) 0.1868(12) 0.8769(12) 0.132(3) Uani 0.0625 1 d D U P . -1 H15 H 0.5658 0.2077 0.8730 0.158 Uiso 0.0625 1 calc R U P . -1 C16 C 0.5000 -0.3880(5) 0.6117(5) 0.132(3) Uani 0.0625 1 d DS U P . -1 C17 C 0.5000 -0.3516(6) 0.6478(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 C18 C 0.5000 -0.3648(6) 0.6955(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 H18 H 0.5000 -0.3975(6) 0.7035(10) 0.158 Uiso 0.0625 1 d DS U P A -1 C19 C 0.5000 -0.3305(7) 0.7303(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 H19 H 0.5000 -0.3394 0.7628 0.158 Uiso 0.0625 1 calc R U P . -1 C20 C 0.5000 -0.2826(7) 0.7177(8) 0.132(3) Uani 0.0625 1 d DS U P . -1 C21 C 0.5000 -0.2692(6) 0.6702(9) 0.132(3) Uani 0.0625 1 d DS U P . -1 H21 H 0.5000 -0.2366 0.6619 0.158 Uiso 0.0625 1 calc R U P . -1 C22 C 0.5000 -0.3037(6) 0.6352(8) 0.132(3) Uani 0.0625 1 d DS U P . -1 H22 H 0.5000 -0.2947 0.6027 0.158 Uiso 0.0625 1 calc R U P . -1 C23 C 0.5000 -0.2458(10) 0.7542(11) 0.132(3) Uani 0.0625 1 d DS U P . -1 C24 C 0.5000 -0.2172(10) 0.7877(10) 0.132(3) Uani 0.0625 1 d DS U P . -1 C25 C 0.5000 -0.1877(7) 0.8305(8) 0.132(3) Uani 0.0625 1 d DS U P . -1 C26 C 0.5141(18) -0.2060(7) 0.8741(9) 0.132(3) Uani 0.0625 1 d D U P . -1 H26 H 0.5236 -0.2382 0.8766 0.158 Uiso 0.0625 1 calc R U P . -1 C27 C 0.5143(19) -0.1774(7) 0.9137(8) 0.132(3) Uani 0.0625 1 d D U P . -1 H27 H 0.5239 -0.1897 0.9436 0.158 Uiso 0.0625 1 calc R U P . -1 C28 C 0.5000 -0.1295(6) 0.9094(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C29 C 0.487(2) -0.1113(8) 0.8667(7) 0.132(3) Uani 0.0625 1 d D U P . -1 H29 H 0.4777 -0.0791 0.8643 0.158 Uiso 0.0625 1 calc R U P . -1 C30 C 0.488(2) -0.1400(8) 0.8262(8) 0.132(3) Uani 0.0625 1 d D U P . -1 H30 H 0.4798 -0.1271 0.7961 0.158 Uiso 0.0625 1 calc R U P . -1 C31 C 0.5000 -0.3883(5) 1.3885(5) 0.132(3) Uani 0.0625 1 d DS U P . -1 C32 C 0.5000 -0.3624(8) 1.3445(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 C33 C 0.5411(5) -0.3595(9) 1.3175(8) 0.132(3) Uani 0.0625 1 d D U P . -1 H33 H 0.5695 -0.3742 1.3282 0.158 Uiso 0.0625 1 calc R U P . -1 C34 C 0.5404(6) -0.3348(12) 1.2743(10) 0.132(3) Uani 0.0625 1 d D U P . -1 H34 H 0.5673 -0.3349 1.2541 0.158 Uiso 0.0625 1 calc R U P . -1 C35 C 0.5000 -0.3104(11) 1.2616(9) 0.132(3) Uani 0.0625 1 d DS U P . -1 C36 C 0.4566(4) -0.3200(13) 1.2849(11) 0.132(3) Uani 0.0625 1 d D U P . -1 H36 H 0.4274 -0.3102 1.2714 0.158 Uiso 0.0625 1 calc R U P . -1 C37 C 0.4575(5) -0.3440(12) 1.3275(9) 0.132(3) Uani 0.0625 1 d D U P . -1 H37 H 0.4291 -0.3479 1.3453 0.158 Uiso 0.0625 1 calc R U P . -1 C38 C 0.5000 -0.2755(11) 1.2235(11) 0.132(3) Uani 0.0625 1 d DS U P . -1 C39 C 0.5000 -0.2427(8) 1.1941(8) 0.132(3) Uani 0.0625 1 d DS U P . -1 C40 C 0.5000 -0.2088(6) 1.1547(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C41 C 0.5420(4) -0.1993(6) 1.1304(6) 0.132(3) Uani 0.0625 1 d D U P . -1 H41 H 0.5706 -0.2147 1.1393 0.158 Uiso 0.0625 1 calc R U P . -1 C42 C 0.5419(4) -0.1672(6) 1.0931(6) 0.132(3) Uani 0.0625 1 d D U P . -1 H42 H 0.5704 -0.1608 1.0763 0.158 Uiso 0.0625 1 calc R U P . -1 C43 C 0.5000 -0.1443(5) 1.0805(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C44 C 0.4580(4) -0.1541(7) 1.1046(7) 0.132(3) Uani 0.0625 1 d D U P . -1 H44 H 0.4295 -0.1387 1.0956 0.158 Uiso 0.0625 1 calc R U P . -1 C45 C 0.4580(4) -0.1863(7) 1.1420(7) 0.132(3) Uani 0.0625 1 d D U P . -1 H45 H 0.4295 -0.1929 1.1586 0.158 Uiso 0.0625 1 calc R U P . -1 C46 C 0.5000 0.3869(5) 1.3869(5) 0.132(3) Uani 0.0625 1 d DS U P . -1 C47 C 0.5000 0.3481(6) 1.3516(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 C48 C 0.4862(18) 0.3569(7) 1.3048(8) 0.132(3) Uani 0.0625 1 d D U P . -1 H48 H 0.4769 0.3879 1.2955 0.158 Uiso 0.0625 1 calc R U P . -1 C49 C 0.486(2) 0.3202(8) 1.2719(9) 0.132(3) Uani 0.0625 1 d D U P . -1 H49 H 0.4760 0.3261 1.2403 0.158 Uiso 0.0625 1 calc DR U P . -1 C50 C 0.5000 0.2748(7) 1.2850(8) 0.132(3) Uani 0.0625 1 d DS U P . -1 C51 C 0.516(3) 0.2664(9) 1.3314(11) 0.132(3) Uani 0.0625 1 d D U P . -1 H51 H 0.5294 0.2368 1.3394 0.158 Uiso 0.0625 1 calc R U P . -1 C52 C 0.511(3) 0.3015(8) 1.3655(9) 0.132(3) Uani 0.0625 1 d D U P . -1 H52 H 0.5145 0.2940 1.3980 0.158 Uiso 0.0625 1 calc R U P . -1 C53 C 0.5000 0.2362(8) 1.2504(10) 0.132(3) Uani 0.0625 1 d DS U P . -1 C54 C 0.5000 0.2031(9) 1.2212(10) 0.132(3) Uani 0.0625 1 d DS U P . -1 C55 C 0.5000 0.1691(8) 1.1816(9) 0.132(3) Uani 0.0625 1 d DS U P . -1 C56 C 0.4573(4) 0.1575(14) 1.1593(11) 0.132(3) Uani 0.0625 1 d D U P . -1 H56 H 0.4282 0.1686 1.1721 0.158 Uiso 0.0625 1 calc R U P . -1 C57 C 0.4573(4) 0.1299(14) 1.1186(11) 0.132(3) Uani 0.0625 1 d D U P . -1 H57 H 0.4282 0.1225 1.1033 0.158 Uiso 0.0625 1 calc R U P . -1 C58 C 0.5000 0.1129(7) 1.1002(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 C59 C 0.5425(4) 0.1234(19) 1.1229(14) 0.132(3) Uani 0.0625 1 d D U P . -1 H59 H 0.5715 0.1112 1.1109 0.158 Uiso 0.0625 1 calc R U P . -1 C60 C 0.5424(4) 0.1520(14) 1.1634(12) 0.132(3) Uani 0.0625 1 d D U P . -1 H60 H 0.5715 0.1597 1.1786 0.158 Uiso 0.0625 1 calc R U P . -1 C61 C 0.5000 0.0965(6) 0.9668(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C62 C 0.5000 0.0464(5) 0.9636(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 C63 C 0.5000 0.0229(8) 0.9193(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 H63 H 0.5000 0.0413 0.8911 0.158 Uiso 0.0625 1 calc R U P . -1 C64 C 0.5000 -0.0265(7) 0.9155(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 H64 H 0.5000 -0.0413 0.8852 0.158 Uiso 0.0625 1 calc R U P . -1 C65 C 0.5000 -0.0540(5) 0.9573(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C66 C 0.5000 -0.1031(6) 0.9540(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C67 C 0.5000 -0.1323(6) 0.9952(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 H67 H 0.5000 -0.1658 0.9922 0.158 Uiso 0.0625 1 calc R U P . -1 C68 C 0.5000 -0.1110(6) 1.0408(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C69 C 0.5000 -0.0616(4) 1.0455(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C70 C 0.5000 -0.0385(6) 1.0897(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 H70 H 0.5000 -0.0568 1.1179 0.158 Uiso 0.0625 1 calc R U P . -1 C71 C 0.5000 0.0115(6) 1.0929(7) 0.132(3) Uani 0.0625 1 d DS U P . -1 H71 H 0.5000 0.0265 1.1230 0.158 Uiso 0.0625 1 calc R U P . -1 C72 C 0.5000 0.0393(4) 1.0506(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C73 C 0.5000 0.0891(6) 1.0541(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C74 C 0.5000 0.1176(6) 1.0120(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 H74 H 0.5000 0.1511 1.0147 0.158 Uiso 0.0625 1 calc R U P . -1 C75 C 0.5000 0.0173(4) 1.0057(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 C76 C 0.5000 -0.0331(4) 1.0031(6) 0.132(3) Uani 0.0625 1 d DS U P . -1 loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 Zr1 0.0334(4) 0.0334(4) 0.0253(5) 0.000 0.000 0.000 O1 0.066(2) 0.0468(18) 0.0372(16) 0.0101(14) 0.000 0.000 O2 0.072(3) 0.072(3) 0.072(3) -0.044(3) -0.044(3) 0.044(3) C1 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C2 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C3 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C4 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C5 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C6 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C7 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C8 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C9 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C10 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C11 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C12 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C13 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C14 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C15 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C16 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C17 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C18 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C19 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C20 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C21 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C22 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C23 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C24 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C25 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C26 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C27 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C28 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C29 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C30 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C31 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C32 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C33 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C34 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C35 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C36 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C37 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C38 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C39 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C40 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C41 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C42 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C43 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C44 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C45 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C46 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C47 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C48 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C49 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C50 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C51 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C52 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C53 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C54 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C55 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C56 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C57 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C58 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C59 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C60 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C61 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C62 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C63 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C64 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C65 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C66 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C67 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C68 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C69 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C70 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C71 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C72 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C73 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C74 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C75 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) C76 0.318(7) 0.010(3) 0.068(4) -0.006(3) 0.010(9) -0.029(6) loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' Zr Zr -0.1862 2.2449 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 Zr1 Zr1 Zr1 60.0 8_556 29_656 Zr1 Zr1 Zr1 60.0 32_665 29_656 Zr1 Zr1 Zr1 90.0 5_565 29_656 Zr1 Zr1 Zr1 60.001(1) 5_565 32_665 Zr1 Zr1 Zr1 60.0 5_565 8_556 Zr1 Zr1 Zr1 90.0 32_665 8_556 O1 Zr1 Zr1 110.22(6) 2_655 29_656 O1 Zr1 Zr1 110.22(6) 4_565 29_656 O1 Zr1 Zr1 74.25(9) 3_665 29_656 O1 Zr1 Zr1 164.25(9) . 29_656 O1 Zr1 Zr1 164.25(9) 4_565 8_556 O1 Zr1 Zr1 74.25(9) 2_655 8_556 O1 Zr1 Zr1 110.22(6) 3_665 8_556 O1 Zr1 Zr1 110.21(6) . 8_556 O1 Zr1 Zr1 110.21(6) . 32_665 O1 Zr1 Zr1 74.25(9) 4_565 32_665 O1 Zr1 Zr1 164.25(9) 2_655 32_665 O1 Zr1 Zr1 110.22(6) 3_665 32_665 O1 Zr1 Zr1 110.22(6) 4_565 5_565 O1 Zr1 Zr1 110.22(6) 2_655 5_565 O1 Zr1 Zr1 74.25(9) . 5_565 O1 Zr1 Zr1 164.25(9) 3_665 5_565 O1 Zr1 O1 76.18(8) 3_665 2_655 O1 Zr1 O1 121.49(17) . 3_665 O1 Zr1 O1 76.18(8) . 4_565 O1 Zr1 O1 76.18(8) 3_665 4_565 O1 Zr1 O1 121.49(17) 2_655 4_565 O1 Zr1 O1 76.18(8) . 2_655 O2 Zr1 Zr1 34.70(11) . 5_565 O2 Zr1 Zr1 34.71(11) 2_655 5_565 O2 Zr1 Zr1 89.0(2) . 29_656 O2 Zr1 Zr1 34.71(11) 2_655 8_556 O2 Zr1 Zr1 34.71(11) 4_565 32_665 O2 Zr1 Zr1 34.70(11) . 32_665 O2 Zr1 Zr1 89.0(2) 4_565 5_565 O2 Zr1 Zr1 89.0(2) 3_665 5_565 O2 Zr1 Zr1 89.0(2) 4_565 8_556 O2 Zr1 Zr1 89.0(2) 2_655 32_665 O2 Zr1 Zr1 89.0(2) 3_665 32_665 O2 Zr1 Zr1 89.0(2) . 8_556 O2 Zr1 Zr1 34.71(11) 3_665 8_556 O2 Zr1 Zr1 89.0(2) 2_655 29_656 O2 Zr1 Zr1 34.71(11) 4_565 29_656 O2 Zr1 Zr1 34.71(11) 3_665 29_656 O2 Zr1 O1 141.86(4) 4_565 2_655 O2 Zr1 O1 78.08(19) 3_665 2_655 O2 Zr1 O1 141.86(3) . 2_655 O2 Zr1 O1 78.08(19) 2_655 2_655 O2 Zr1 O1 78.09(19) . 4_565 O2 Zr1 O1 141.86(4) 2_655 3_665 O2 Zr1 O1 78.08(19) 3_665 3_665 O2 Zr1 O1 78.08(19) 4_565 3_665 O2 Zr1 O1 141.86(4) 3_665 4_565 O2 Zr1 O1 78.09(19) . . O2 Zr1 O1 78.08(19) 2_655 . O2 Zr1 O1 141.86(4) 3_665 . O2 Zr1 O1 141.86(4) . 3_665 O2 Zr1 O1 141.86(4) 4_565 . O2 Zr1 O1 141.86(4) 2_655 4_565 O2 Zr1 O1 78.08(19) 4_565 4_565 O2 Zr1 O2 69.4(2) 3_665 2_655 O2 Zr1 O2 107.2(5) 4_565 2_655 O2 Zr1 O2 69.4(2) . 2_655 O2 Zr1 O2 69.4(2) 4_565 3_665 O2 Zr1 O2 107.2(5) . 3_665 O2 Zr1 O2 69.4(2) . 4_565 C1 O1 Zr1 136.2(7) . . Zr1 O2 Zr1 110.6(2) . 32_665 Zr1 O2 Zr1 110.6(2) . 5_565 Zr1 O2 Zr1 110.6(2) 32_665 5_565 O1 C1 O1 119.5(12) . 22_666 O1 C1 C2 114.7(10) . . O1 C1 C2 125.8(11) 22_666 . C3 C2 C1 120.5(10) . . C7 C2 C1 121.3(10) . . C7 C2 C3 118.2(7) . . C2 C3 H3 119.9 . . C4 C3 C2 120.3(8) . . C4 C3 H3 119.9 . . C3 C4 H4 119.8 . . C5 C4 C3 120.3(9) . . C5 C4 H4 119.8 . . C4 C5 C6 118.8(7) . . C4 C5 C8 120.8(10) . . C6 C5 C8 120.2(10) . . C5 C6 H6 119.7 . . C7 C6 C5 120.5(8) . . C7 C6 H6 119.7 . . C2 C7 H7 119.6 . . C6 C7 C2 120.8(8) . . C6 C7 H7 119.6 . . C9 C8 C5 179(2) . . C8 C9 C10 180(3) . . C11 C10 C9 120.5(7) . . C15 C10 C9 120.5(8) . . C15 C10 C11 118.9(7) . . C10 C11 H11 119.8 . . C10 C11 C12 120.4(8) . . C12 C11 H11 119.8 . . C11 C12 H12 119.9 . . C13 C12 C11 120.3(8) . . C13 C12 H12 119.9 . . C12 C13 C14 119.3(7) . . C12 C13 C61 121.7(6) . . C14 C13 C61 118.7(6) . . C13 C14 H14 120.0 . . C13 C14 C15 120.0(8) . . C15 C14 H14 120.0 . . C10 C15 C14 120.2(8) . . C10 C15 H15 119.9 . . C14 C15 H15 119.9 . . O1 C16 O1 129.7(13) 7_546 3_655 O1 C16 C17 114.9(11) 7_546 . O1 C16 C17 115.4(11) 3_655 . C18 C17 C16 119.1(11) . . C22 C17 C16 120.6(11) . . C22 C17 C18 120.3(7) . . C17 C18 H18 119.2(14) . . C19 C18 C17 119.8(7) . . C19 C18 H18 120.9(14) . . C18 C19 H19 120.0 . . C18 C19 C20 119.9(8) . . C20 C19 H19 120.0 . . C19 C20 C23 120.6(10) . . C21 C20 C19 120.5(7) . . C21 C20 C23 118.9(10) . . C20 C21 H21 120.1 . . C22 C21 C20 119.7(7) . . C22 C21 H21 120.1 . . C17 C22 H22 120.1 . . C21 C22 C17 119.8(8) . . C21 C22 H22 120.1 . . C24 C23 C20 175.1(18) . . C23 C24 C25 174.2(18) . . C26 C25 C24 121.0(10) . . C26 C25 C30 120.4(7) . . C30 C25 C24 118.5(10) . . C25 C26 H26 120.0 . . C27 C26 C25 119.9(8) . . C27 C26 H26 120.0 . . C26 C27 H27 120.4 . . C26 C27 C28 119.3(8) . . C28 C27 H27 120.4 . . C27 C28 C66 114.4(9) . . C29 C28 C27 120.7(7) . . C29 C28 C66 124.8(9) . . C28 C29 H29 119.9 . . C28 C29 C30 120.2(8) . . C30 C29 H29 119.9 . . C25 C30 C29 119.3(8) . . C25 C30 H30 120.3 . . C29 C30 H30 120.3 . . O1 C31 O1 130.5(14) 21_646 6_557 O1 C31 C32 129.2(14) 21_646 . O1 C31 C32 100.3(12) 6_557 . C33 C32 C31 120.1(6) . . C33 C32 C37 120.6(8) . . C37 C32 C31 119.1(5) . . C32 C33 H33 120.3 . . C32 C33 C34 119.5(8) . . C34 C33 H33 120.3 . . C33 C34 H34 120.5 . . C35 C34 C33 119.0(8) . . C35 C34 H34 120.5 . . C34 C35 C36 119.9(7) . . C34 C35 C38 121.9(7) . . C36 C35 C38 118.1(7) . . C35 C36 H36 120.6 . . C37 C36 C35 118.8(8) . . C37 C36 H36 120.6 . . C32 C37 H37 120.1 . . C36 C37 C32 119.9(8) . . C36 C37 H37 120.1 . . C39 C38 C35 175(4) . . C38 C39 C40 173(2) . . C41 C40 C39 119.8(4) . . C45 C40 C39 119.6(4) . . C45 C40 C41 120.6(7) . . C40 C41 H41 120.1 . . C42 C41 C40 119.7(7) . . C42 C41 H41 120.1 . . C41 C42 H42 120.1 . . C41 C42 C43 119.8(8) . . C43 C42 H42 120.1 . . C42 C43 C68 119.5(5) . . C44 C43 C42 120.4(7) . . C44 C43 C68 120.1(5) . . C43 C44 H44 120.0 . . C45 C44 C43 120.0(8) . . C45 C44 H44 120.0 . . C40 C45 C44 119.5(8) . . C40 C45 H45 120.3 . . C44 C45 H45 120.3 . . O1 C46 O1 125.6(13) 9_657 5_566 O1 C46 C47 119.9(11) 9_657 . O1 C46 C47 114.5(11) 5_566 . C48 C47 C46 120.3(11) . . C48 C47 C52 119.2(8) . . C52 C47 C46 120.3(11) . . C47 C48 H48 120.0 . . C49 C48 C47 120.1(8) . . C49 C48 H48 120.0 . . C48 C49 H49 119.8 . . C48 C49 C50 120.3(8) . . C50 C49 H49 119.8 . . C49 C50 C51 119.6(7) . . C49 C50 C53 120.4(10) . . C51 C50 C53 119.9(10) . . C50 C51 H51 120.1 . . C52 C51 C50 119.8(9) . . C52 C51 H51 120.1 . . C47 C52 H52 120.1 . . C51 C52 C47 119.7(9) . . C51 C52 H52 120.1 . . C54 C53 C50 179(2) . . C53 C54 C55 172(2) . . C56 C55 C54 119.5(5) . . C60 C55 C54 120.4(5) . . C60 C55 C56 119.8(7) . . C55 C56 H56 119.9 . . C57 C56 C55 120.2(8) . . C57 C56 H56 119.9 . . C56 C57 H57 120.0 . . C56 C57 C58 119.9(8) . . C58 C57 H57 120.0 . . C57 C58 C73 119.2(6) . . C59 C58 C57 120.0(7) . . C59 C58 C73 120.4(6) . . C58 C59 H59 120.0 . . C58 C59 C60 119.9(8) . . C60 C59 H59 120.0 . . C55 C60 C59 120.1(8) . . C55 C60 H60 120.0 . . C59 C60 H60 120.0 . . C62 C61 C13 120.9(10) . . C74 C61 C13 120.6(11) . . C74 C61 C62 118.5(9) . . C61 C62 C75 121.0(10) . . C63 C62 C61 121.6(13) . . C63 C62 C75 117.4(9) . . C62 C63 H63 118.8 . . C64 C63 C62 122.4(10) . . C64 C63 H63 118.8 . . C63 C64 H64 120.5 . . C63 C64 C65 119.0(10) . . C65 C64 H64 120.5 . . C64 C65 C76 122.0(10) . . C66 C65 C64 119.5(12) . . C66 C65 C76 118.5(9) . . C65 C66 C28 124.6(9) . . C65 C66 C67 121.4(8) . . C67 C66 C28 114.0(9) . . C66 C67 H67 120.2 . . C68 C67 C66 119.6(9) . . C68 C67 H67 120.2 . . C67 C68 C43 114.9(8) . . C69 C68 C43 124.6(9) . . C69 C68 C67 120.6(9) . . C68 C69 C70 123.1(12) . . C68 C69 C76 118.5(9) . . C70 C69 C76 118.5(9) . . C69 C70 H70 119.4 . . C69 C70 C71 121.2(10) . . C71 C70 H70 119.4 . . C70 C71 H71 120.1 . . C70 C71 C72 119.7(10) . . C72 C71 H71 120.1 . . C73 C72 C71 119.3(11) . . C73 C72 C75 120.2(9) . . C75 C72 C71 120.5(10) . . C72 C73 C58 121.3(10) . . C72 C73 C74 120.0(9) . . C74 C73 C58 118.7(11) . . C61 C74 C73 121.0(9) . . C61 C74 H74 119.5 . . C73 C74 H74 119.5 . . C72 C75 C62 119.2(9) . . C72 C75 C76 119.1(9) . . C76 C75 C62 121.7(8) . . C65 C76 C69 121.5(9) . . C65 C76 C75 117.6(9) . . C75 C76 C69 120.9(8) . . loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 Zr1 Zr1 3.4917(8) 29_656 Zr1 Zr1 3.4917(8) 8_556 Zr1 Zr1 3.4917(8) 5_565 Zr1 Zr1 3.4917(8) 32_665 Zr1 O1 2.218(3) . Zr1 O1 2.218(3) 3_665 Zr1 O1 2.218(3) 4_565 Zr1 O1 2.218(3) 2_655 Zr1 O2 2.124(3) 2_655 Zr1 O2 2.124(3) 3_665 Zr1 O2 2.124(3) 4_565 Zr1 O2 2.124(3) . O1 C1 1.316(13) . O2 Zr1 2.124(3) 32_665 O2 Zr1 2.124(3) 5_565 C1 O1 1.332(13) 22_666 C1 C2 1.517(14) . C2 C3 1.391(12) . C2 C7 1.388(12) . C3 H3 0.9400 . C3 C4 1.384(12) . C4 H4 0.9400 . C4 C5 1.379(12) . C5 C6 1.382(12) . C5 C8 1.455(11) . C6 H6 0.9400 . C6 C7 1.381(12) . C7 H7 0.9400 . C8 C9 1.230(19) . C9 C10 1.458(11) . C10 C11 1.381(11) . C10 C15 1.378(11) . C11 H11 0.9400 . C11 C12 1.396(11) . C12 H12 0.9400 . C12 C13 1.369(11) . C13 C14 1.387(10) . C13 C61 1.467(12) . C14 H14 0.9400 . C14 C15 1.389(11) . C15 H15 0.9400 . C16 O1 1.260(13) 7_546 C16 O1 1.268(12) 3_655 C16 C17 1.432(14) . C17 C18 1.384(12) . C17 C22 1.383(12) . C18 H18 0.9400(10) . C18 C19 1.365(12) . C19 H19 0.9400 . C19 C20 1.382(12) . C20 C21 1.378(12) . C20 C23 1.448(11) . C21 H21 0.9400 . C21 C22 1.372(12) . C22 H22 0.9400 . C23 C24 1.230(19) . C24 C25 1.453(12) . C25 C26 1.379(12) . C25 C30 1.380(12) . C26 H26 0.9400 . C26 C27 1.365(12) . C27 H27 0.9400 . C27 C28 1.401(12) . C28 C29 1.347(12) . C28 C66 1.445(12) . C29 H29 0.9400 . C29 C30 1.385(12) . C30 H30 0.9400 . C31 O1 1.257(13) 21_646 C31 O1 1.262(13) 6_557 C31 C32 1.426(14) . C32 C33 1.376(11) . C32 C37 1.378(11) . C33 H33 0.9400 . C33 C34 1.390(12) . C34 H34 0.9400 . C34 C35 1.364(11) . C35 C36 1.401(11) . C35 C38 1.444(12) . C36 H36 0.9400 . C36 C37 1.366(12) . C37 H37 0.9400 . C38 C39 1.23(2) . C39 C40 1.452(12) . C40 C41 1.382(10) . C40 C45 1.377(10) . C41 H41 0.9400 . C41 C42 1.374(11) . C42 H42 0.9400 . C42 C43 1.379(11) . C43 C44 1.378(11) . C43 C68 1.449(12) . C44 H44 0.9400 . C44 C45 1.378(11) . C45 H45 0.9400 . C46 O1 1.286(13) 9_657 C46 O1 1.286(13) 5_566 C46 C47 1.464(14) . C47 C48 1.384(12) . C47 C52 1.392(12) . C48 H48 0.9400 . C48 C49 1.377(12) . C49 H49 0.9400 . C49 C50 1.378(12) . C50 C51 1.385(12) . C50 C53 1.448(11) . C51 H51 0.9400 . C51 C52 1.373(13) . C52 H52 0.9400 . C53 C54 1.232(19) . C54 C55 1.459(11) . C55 C56 1.382(11) . C55 C60 1.375(10) . C56 H56 0.9400 . C56 C57 1.375(11) . C57 H57 0.9400 . C57 C58 1.382(11) . C58 C59 1.376(11) . C58 C73 1.449(12) . C59 H59 0.9400 . C59 C60 1.385(11) . C60 H60 0.9400 . C61 C62 1.403(12) . C61 C74 1.393(13) . C62 C63 1.402(13) . C62 C75 1.429(12) . C63 H63 0.9400 . C63 C64 1.382(13) . C64 H64 0.9400 . C64 C65 1.399(14) . C65 C66 1.373(12) . C65 C76 1.406(12) . C66 C67 1.412(12) . C67 H67 0.9400 . C67 C68 1.405(12) . C68 C69 1.385(12) . C69 C70 1.394(13) . C69 C76 1.427(12) . C70 H70 0.9400 . C70 C71 1.398(13) . C71 H71 0.9400 . C71 C72 1.414(14) . C72 C73 1.394(12) . C72 C75 1.396(12) . C73 C74 1.418(12) . C74 H74 0.9400 . C75 C76 1.410(12) . loop_ _geom_torsion_atom_site_label_1 _geom_torsion_atom_site_label_2 _geom_torsion_atom_site_label_3 _geom_torsion_atom_site_label_4 _geom_torsion _geom_torsion_site_symmetry_1 _geom_torsion_site_symmetry_4 Zr1 O1 C1 O1 0.000(4) . 22_666 Zr1 O1 C1 C2 180.000(4) . . O1 C1 C2 C3 -160(4) . . O1 C1 C2 C3 20(4) 22_666 . O1 C1 C2 C7 -159(3) 22_666 . O1 C1 C2 C7 21(3) . . O1 C16 C17 C18 0.000(1) 3_655 . O1 C16 C17 C18 180.000(1) 7_546 . O1 C16 C17 C22 180.000(1) 3_655 . O1 C16 C17 C22 0.000(2) 7_546 . O1 C31 C32 C33 -74.6(17) 6_557 . O1 C31 C32 C33 105.4(17) 21_646 . O1 C31 C32 C37 -80(2) 21_646 . O1 C31 C32 C37 100(2) 6_557 . O1 C46 C47 C48 -19(3) 9_657 . O1 C46 C47 C48 161(3) 5_566 . O1 C46 C47 C52 166(4) 9_657 . O1 C46 C47 C52 -14(4) 5_566 . C1 C2 C3 C4 174(3) . . C1 C2 C7 C6 -179.5(14) . . C2 C3 C4 C5 12(7) . . C3 C2 C7 C6 2(3) . . C3 C4 C5 C6 -11(6) . . C3 C4 C5 C8 174(3) . . C4 C5 C6 C7 6(5) . . C5 C6 C7 C2 -1(3) . . C7 C2 C3 C4 -8(5) . . C8 C5 C6 C7 -179.5(13) . . C9 C10 C11 C12 -180(3) . . C9 C10 C15 C14 -174(3) . . C10 C11 C12 C13 -1(2) . . C11 C10 C15 C14 9(4) . . C11 C12 C13 C14 -1(5) . . C11 C12 C13 C61 173.6(18) . . C12 C13 C14 C15 7(6) . . C12 C13 C61 C62 77(3) . . C12 C13 C61 C74 -103(3) . . C13 C14 C15 C10 -11(6) . . C13 C61 C62 C63 0.000(7) . . C13 C61 C62 C75 180.000(5) . . C13 C61 C74 C73 180.000(4) . . C14 C13 C61 C62 -109(3) . . C14 C13 C61 C74 71(3) . . C15 C10 C11 C12 -3(2) . . C16 C17 C18 C19 180.000(2) . . C16 C17 C22 C21 180.000(2) . . C17 C18 C19 C20 0.000(1) . . C18 C17 C22 C21 0.000(4) . . C18 C19 C20 C21 0.000(1) . . C18 C19 C20 C23 180.000(4) . . C19 C20 C21 C22 0.000(2) . . C20 C21 C22 C17 0.000(2) . . C22 C17 C18 C19 0.000(3) . . C23 C20 C21 C22 180.000(1) . . C24 C25 C26 C27 179.3(9) . . C24 C25 C30 C29 179(4) . . C25 C26 C27 C28 0.1(15) . . C26 C25 C30 C29 -4(6) . . C26 C27 C28 C29 -1(4) . . C26 C27 C28 C66 177.9(9) . . C27 C28 C29 C30 0(6) . . C27 C28 C66 C65 162(3) . . C27 C28 C66 C67 -18(3) . . C28 C29 C30 C25 2(7) . . C28 C66 C67 C68 180.000(3) . . C29 C28 C66 C65 -19(4) . . C29 C28 C66 C67 161(4) . . C30 C25 C26 C27 2(3) . . C31 C32 C33 C34 178.9(19) . . C31 C32 C37 C36 -178(3) . . C32 C33 C34 C35 6(2) . . C33 C32 C37 C36 -4(4) . . C33 C34 C35 C36 -16(4) . . C33 C34 C35 C38 166(3) . . C34 C35 C36 C37 17(5) . . C35 C36 C37 C32 -7(5) . . C37 C32 C33 C34 5(2) . . C38 C35 C36 C37 -165(4) . . C39 C40 C41 C42 179.9(3) . . C39 C40 C45 C44 180.0(5) . . C40 C41 C42 C43 0.5(3) . . C41 C40 C45 C44 0.0(7) . . C41 C42 C43 C44 -0.9(6) . . C41 C42 C43 C68 -179.2(4) . . C42 C43 C44 C45 0.9(9) . . C42 C43 C68 C67 77.4(7) . . C42 C43 C68 C69 -102.6(7) . . C43 C44 C45 C40 -0.4(9) . . C43 C68 C69 C70 0.000(5) . . C43 C68 C69 C76 180.000(4) . . C44 C43 C68 C67 -100.9(9) . . C44 C43 C68 C69 79.1(9) . . C45 C40 C41 C42 0.0(3) . . C46 C47 C48 C49 -179.5(14) . . C46 C47 C52 C51 -173(4) . . C47 C48 C49 C50 -1(3) . . C48 C47 C52 C51 11(6) . . C48 C49 C50 C51 -1(6) . . C48 C49 C50 C53 -179.6(14) . . C49 C50 C51 C52 9(7) . . C50 C51 C52 C47 -14(7) . . C52 C47 C48 C49 -4(3) . . C53 C50 C51 C52 -173(4) . . C54 C55 C56 C57 173(2) . . C54 C55 C60 C59 -174(4) . . C55 C56 C57 C58 1.1(16) . . C56 C55 C60 C59 0(5) . . C56 C57 C58 C59 0(4) . . C56 C57 C58 C73 -172.1(14) . . C57 C58 C59 C60 -2(6) . . C57 C58 C73 C72 -99(3) . . C57 C58 C73 C74 81(3) . . C58 C59 C60 C55 1(7) . . C58 C73 C74 C61 180.000(4) . . C59 C58 C73 C72 89(3) . . C59 C58 C73 C74 -91(3) . . C60 C55 C56 C57 -1(2) . . C61 C13 C14 C15 -168(3) . . C61 C62 C63 C64 180.000(3) . . C61 C62 C75 C72 0.000(8) . . C61 C62 C75 C76 180.000(4) . . C62 C61 C74 C73 0.000(11) . . C62 C63 C64 C65 0.000(5) . . C62 C75 C76 C65 0.000(4) . . C62 C75 C76 C69 180.000(4) . . C63 C62 C75 C72 180.000(4) . . C63 C62 C75 C76 0.000(3) . . C63 C64 C65 C66 180.000(4) . . C63 C64 C65 C76 0.000(4) . . C64 C65 C66 C28 0.000(4) . . C64 C65 C66 C67 180.000(3) . . C64 C65 C76 C69 180.000(5) . . C64 C65 C76 C75 0.000(4) . . C65 C66 C67 C68 0.000(4) . . C66 C28 C29 C30 -179(3) . . C66 C65 C76 C69 0.000(4) . . C66 C65 C76 C75 180.000(4) . . C66 C67 C68 C43 180.000(4) . . C66 C67 C68 C69 0.000(4) . . C67 C68 C69 C70 180.000(5) . . C67 C68 C69 C76 0.000(4) . . C68 C43 C44 C45 179.1(6) . . C68 C69 C70 C71 180.000(5) . . C68 C69 C76 C65 0.000(4) . . C68 C69 C76 C75 180.000(4) . . C69 C70 C71 C72 0.000(5) . . C70 C69 C76 C65 180.000(3) . . C70 C69 C76 C75 0.000(4) . . C70 C71 C72 C73 180.000(5) . . C70 C71 C72 C75 0.000(5) . . C71 C72 C73 C58 0.000(5) . . C71 C72 C73 C74 180.000(5) . . C71 C72 C75 C62 180.000(4) . . C71 C72 C75 C76 0.000(4) . . C72 C73 C74 C61 0.000(6) . . C72 C75 C76 C65 180.000(4) . . C72 C75 C76 C69 0.000(4) . . C73 C58 C59 C60 171(3) . . C73 C72 C75 C62 0.000(5) . . C73 C72 C75 C76 180.000(6) . . C74 C61 C62 C63 180.000(5) . . C74 C61 C62 C75 0.000(5) . . C75 C62 C63 C64 0.000(3) . . C75 C72 C73 C58 180.000(7) . . C75 C72 C73 C74 0.000(5) . . C76 C65 C66 C28 180.000(3) . . C76 C65 C66 C67 0.000(4) . . C76 C69 C70 C71 0.000(4) . . loop_ _smtbx_masks_void_nr _smtbx_masks_void_average_x _smtbx_masks_void_average_y _smtbx_masks_void_average_z _smtbx_masks_void_volume _smtbx_masks_void_count_electrons 1 0.445 -0.993 -0.414 16316.2 3879.1