#------------------------------------------------------------------------------ #$Date: 2010-11-09 07:06:26 +0000 (Tue, 09 Nov 2010) $ #$Revision: 2225 $ #$URL: svn://cod.ibt.lt/cod/cif/4/4310736.hkl $ #------------------------------------------------------------------------------ # # This file is available in the Crystallography Open Database (COD), # http://www.crystallography.net/ # # All data on this site have been placed in the public domain by the # contributors. # data_4310736 loop_ _publ_author_name 'C. Soulard' 'X. Rocquefelte' 'P.-E. Petit' 'M. Evain' 'S. Jobic' 'J.-P. Iti\'e' 'P. Munsch' 'H.-J. Koo' 'M.-H. Whangbo' _publ_section_title ; Experimental and Theoretical Investigation on the Relative Stability of the PdS2- and Pyrite-Type Structures of PdSe2 ; _journal_name_full 'Inorganic Chemistry' _journal_page_first 1943 _journal_page_last 1949 _journal_volume 43 _journal_year 2004 _chemical_formula_sum 'Pd Se2' _chemical_formula_weight 264.3 _chemical_name_systematic ' ?' _space_group_IT_number 61 _symmetry_cell_setting orthorhombic _symmetry_space_group_name_Hall '-P 2ac 2ab' _symmetry_space_group_name_H-M 'P b c a' _audit_creation_method 'Jana2000 Version : 28/01/2002' _cell_angle_alpha 90 _cell_angle_beta 90 _cell_angle_gamma 90 _cell_formula_units_Z 4 _cell_length_a 5.7457 _cell_length_b 5.8679 _cell_length_c 7.6946 _cell_volume 259.425 _computing_data_reduction Jana2000 _computing_publication_material Jana2000 _computing_structure_refinement Jana2000 _diffrn_measurement_device_type CAD4 _diffrn_measurement_method \q/2\q _diffrn_radiation_type 'Mo K\a' _diffrn_radiation_wavelength 0.71069 _exptl_absorpt_correction_T_max 1.000 _exptl_absorpt_correction_T_min 1.000 _exptl_absorpt_correction_type none _exptl_crystal_density_diffrn 6.765 _exptl_crystal_F_000 456 _reflns_number_total 801 _[local]_cod_data_source_file ic0352396si20040127_123902.hkl _[local]_cod_data_source_block (I) _[local]_cod_chemical_formula_sum_orig 'Pd1 Se2' _cod_original_cell_volume 259.4249 _cod_database_code 4310736 loop_ _symmetry_equiv_pos_site_id _symmetry_equiv_pos_as_xyz 1 x,y,z 2 1/2+x,y,1/2-z 3 1/2-x,1/2+y,z 4 -x,1/2+y,1/2-z 5 -x,-y,-z 6 1/2-x,-y,1/2+z 7 1/2+x,1/2-y,-z 8 x,1/2-y,1/2+z #======================================================================= # 11. STRUCTURE-FACTOR LIST loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_meas _refln_F_calc _refln_F_sigma 2 0 0 58.6 57.8 1.2 4 0 0 14.5 14.9 0.3 6 0 0 6.3 6.4 0.2 8 0 0 35.7 35.8 0.7 10 0 0 23.6 24.2 0.5 2 1 0 44.8 44.6 0.9 4 1 0 11.5 11.5 0.2 6 1 0 20.7 20.9 0.4 8 1 0 10.0 10.0 0.2 10 1 0 6.7 6.7 0.2 0 2 0 52.6 52.8 1.1 2 2 0 41.7 42.5 0.8 4 2 0 26.9 27.3 0.5 6 2 0 21.2 21.2 0.4 8 2 0 18.4 18.4 0.4 10 2 0 12.8 13.4 0.3 2 3 0 39.3 40.4 0.8 4 3 0 11.8 12.1 0.2 6 3 0 21.7 21.6 0.4 8 3 0 11.2 10.9 0.3 0 4 0 17.2 17.6 0.4 2 4 0 23.5 23.4 0.5 4 4 0 60.4 60.9 1.2 6 4 0 33.7 33.9 0.7 8 4 0 1.5 2.0 1.1 2 5 0 21.6 22.0 0.4 4 5 0 5.6 5.8 0.2 6 5 0 12.0 12.2 0.3 8 5 0 5.6 5.9 0.2 0 6 0 14.9 14.9 0.3 2 6 0 21.5 21.6 0.4 4 6 0 26.7 27.0 0.6 6 6 0 19.9 19.9 0.4 8 6 0 9.5 10.1 0.3 2 7 0 25.0 25.6 0.5 4 7 0 7.6 7.5 0.2 6 7 0 14.6 14.7 0.3 0 8 0 41.9 41.9 0.9 2 8 0 21.4 21.3 0.4 4 8 0 3.1 3.3 0.4 6 8 0 6.1 5.9 0.3 2 9 0 7.4 7.4 0.2 4 9 0 0.0 2.0 1.3 0 10 0 20.1 20.4 0.4 2 10 0 13.9 14.2 0.3 1 1 1 15.2 15.6 0.3 2 1 1 26.8 27.1 0.5 3 1 1 54.6 55.1 1.1 4 1 1 7.0 7.0 0.1 5 1 1 50.9 51.2 1.0 6 1 1 12.4 12.5 0.3 7 1 1 17.1 17.1 0.3 8 1 1 5.9 6.1 0.2 9 1 1 3.6 3.7 0.2 10 1 1 3.9 4.0 0.2 0 2 1 37.8 38.2 0.8 1 2 1 34.1 34.9 0.7 2 2 1 5.8 5.8 0.1 3 2 1 37.7 38.5 0.8 4 2 1 24.2 24.7 0.5 5 2 1 11.4 11.6 0.2 6 2 1 9.0 9.2 0.2 7 2 1 22.4 22.5 0.5 8 2 1 9.7 9.6 0.2 9 2 1 0.0 0.1 1.0 10 2 1 6.1 6.1 0.2 1 3 1 59.1 59.9 1.2 2 3 1 17.6 18.2 0.4 3 3 1 18.9 19.5 0.4 4 3 1 4.8 4.8 0.1 5 3 1 7.3 7.2 0.2 6 3 1 9.4 9.4 0.2 7 3 1 21.0 21.1 0.4 8 3 1 4.5 4.5 0.2 9 3 1 22.0 22.3 0.4 0 4 1 5.1 5.1 0.1 1 4 1 4.6 4.7 0.1 2 4 1 1.1 0.9 0.6 3 4 1 5.5 5.6 0.1 4 4 1 3.6 3.5 0.1 5 4 1 1.4 1.5 0.3 6 4 1 0.8 1.6 0.9 7 4 1 3.6 3.6 0.2 8 4 1 1.0 1.3 1.0 9 4 1 0.0 0.4 1.1 1 5 1 50.1 50.9 1.0 2 5 1 18.6 19.1 0.4 3 5 1 11.8 11.7 0.2 4 5 1 5.5 5.5 0.1 5 5 1 1.9 2.2 0.3 6 5 1 10.1 10.3 0.2 7 5 1 18.4 18.5 0.4 8 5 1 4.9 5.4 0.2 9 5 1 21.5 22.1 0.4 0 6 1 19.9 20.1 0.4 1 6 1 18.5 18.9 0.4 2 6 1 3.3 3.2 0.1 3 6 1 22.1 22.4 0.4 4 6 1 14.9 14.7 0.3 5 6 1 7.1 7.0 0.2 6 6 1 5.6 5.8 0.2 7 6 1 14.5 14.5 0.3 8 6 1 6.5 6.5 0.2 1 7 1 11.8 12.0 0.2 2 7 1 7.1 7.4 0.2 3 7 1 24.3 24.3 0.5 4 7 1 2.2 1.9 0.4 5 7 1 24.2 23.7 0.5 6 7 1 4.1 4.3 0.2 7 7 1 11.3 11.7 0.3 0 8 1 4.8 4.9 0.2 1 8 1 4.7 4.5 0.2 2 8 1 0.0 0.9 0.9 3 8 1 5.7 5.8 0.2 4 8 1 3.9 3.6 0.2 5 8 1 1.8 1.3 1.3 6 8 1 1.9 1.7 1.1 1 9 1 3.4 3.9 0.3 2 9 1 9.7 9.9 0.2 3 9 1 20.9 21.2 0.4 4 9 1 3.1 3.0 0.3 5 9 1 22.5 23.3 0.5 0 10 1 8.2 8.3 0.2 1 10 1 7.9 7.9 0.2 2 10 1 1.3 1.3 1.1 3 10 1 9.3 9.6 0.2 0 0 2 55.9 54.7 1.1 1 0 2 41.9 41.1 0.8 2 0 2 45.8 46.2 0.9 3 0 2 44.4 44.4 0.9 4 0 2 14.5 14.4 0.3 5 0 2 13.5 13.4 0.3 6 0 2 16.5 16.4 0.3 7 0 2 26.2 25.8 0.5 8 0 2 23.6 23.4 0.5 9 0 2 0.0 0.1 1.2 10 0 2 16.0 16.4 0.3 1 1 2 32.7 32.0 0.7 2 1 2 15.6 15.8 0.3 3 1 2 17.4 17.5 0.4 4 1 2 4.2 4.2 0.1 5 1 2 23.5 23.8 0.5 6 1 2 7.5 7.5 0.2 7 1 2 3.1 3.2 0.2 8 1 2 3.1 3.7 0.3 9 1 2 11.4 11.4 0.2 10 1 2 2.5 2.4 0.4 0 2 2 43.6 44.6 0.9 1 2 2 3.1 3.2 0.1 2 2 2 37.5 38.0 0.8 3 2 2 3.5 3.7 0.1 4 2 2 27.7 27.8 0.6 5 2 2 1.3 1.0 0.7 6 2 2 21.1 21.2 0.4 7 2 2 2.0 2.3 0.3 8 2 2 16.9 16.8 0.3 9 2 2 0.0 0.3 1.0 10 2 2 12.0 12.2 0.3 1 3 2 30.8 31.3 0.6 2 3 2 15.5 15.4 0.3 3 3 2 17.4 17.4 0.4 4 3 2 4.4 4.4 0.1 5 3 2 24.8 24.9 0.5 6 3 2 7.8 7.7 0.2 7 3 2 3.3 3.2 0.2 8 3 2 4.2 3.9 0.2 9 3 2 12.2 12.2 0.3 0 4 2 13.8 13.7 0.3 1 4 2 28.3 28.6 0.6 2 4 2 26.2 26.5 0.5 3 4 2 33.3 32.8 0.7 4 4 2 37.0 37.2 0.7 5 4 2 10.2 10.3 0.2 6 4 2 24.4 24.2 0.5 7 4 2 20.7 20.5 0.4 8 4 2 9.3 9.4 0.2 9 4 2 0.0 0.3 1.0 1 5 2 15.7 15.8 0.3 2 5 2 7.7 7.9 0.2 3 5 2 9.7 9.4 0.2 4 5 2 1.5 2.0 0.8 5 5 2 13.2 13.2 0.3 6 5 2 4.6 4.5 0.2 7 5 2 1.8 2.2 0.9 8 5 2 1.8 2.2 1.0 9 5 2 6.8 7.0 0.2 0 6 2 19.8 19.9 0.4 1 6 2 5.5 5.4 0.1 2 6 2 21.6 21.6 0.4 3 6 2 6.7 6.8 0.2 4 6 2 22.1 21.9 0.4 5 6 2 1.1 1.6 0.9 6 6 2 17.3 17.1 0.4 7 6 2 4.0 4.3 0.2 8 6 2 11.2 11.4 0.2 1 7 2 18.4 18.5 0.4 2 7 2 9.2 9.2 0.2 3 7 2 10.6 10.7 0.2 4 7 2 2.4 2.7 0.4 5 7 2 17.2 16.3 0.4 6 7 2 5.5 5.4 0.2 7 7 2 2.1 2.1 1.1 0 8 2 26.2 26.0 0.5 1 8 2 13.6 13.5 0.3 2 8 2 18.1 18.2 0.4 3 8 2 16.1 16.2 0.3 4 8 2 8.6 8.5 0.2 5 8 2 5.9 5.5 0.2 6 8 2 9.9 9.9 0.2 1 9 2 5.4 5.2 0.2 2 9 2 2.4 2.7 0.4 3 9 2 3.1 3.3 0.3 4 9 2 0.0 0.8 1.1 5 9 2 4.4 4.7 0.3 0 10 2 15.1 15.4 0.3 1 10 2 3.6 4.0 0.3 2 10 2 12.5 12.9 0.3 3 10 2 4.7 5.1 0.2 1 1 3 43.3 44.1 0.9 2 1 3 40.6 40.1 0.8 3 1 3 28.9 28.8 0.6 4 1 3 11.3 11.2 0.2 5 1 3 19.3 19.2 0.4 6 1 3 20.0 19.9 0.4 7 1 3 19.4 19.1 0.4 8 1 3 9.9 9.8 0.2 9 1 3 16.3 16.1 0.3 10 1 3 6.2 6.6 0.2 0 2 3 54.2 54.5 1.1 1 2 3 7.6 7.6 0.2 2 2 3 9.2 9.0 0.2 3 2 3 8.6 8.6 0.2 4 2 3 38.7 38.8 0.8 5 2 3 3.0 2.7 0.1 6 2 3 14.9 14.9 0.3 7 2 3 5.2 5.0 0.2 8 2 3 15.8 15.5 0.3 9 2 3 0.0 0.2 1.1 1 3 3 28.1 28.0 0.6 2 3 3 28.3 28.2 0.6 3 3 3 31.2 30.8 0.6 4 3 3 7.7 7.6 0.2 5 3 3 26.4 26.0 0.5 6 3 3 15.1 15.1 0.3 7 3 3 16.6 16.4 0.3 8 3 3 7.4 7.4 0.2 9 3 3 10.8 10.7 0.2 0 4 3 8.1 8.0 0.2 1 4 3 0.7 1.1 0.7 2 4 3 0.5 1.5 0.8 3 4 3 1.3 1.3 0.8 4 4 3 5.5 5.6 0.1 5 4 3 0.7 0.2 0.8 6 4 3 2.3 2.6 0.3 7 4 3 0.9 0.7 0.9 8 4 3 1.9 2.1 1.0 9 4 3 0.4 0.1 1.1 1 5 3 19.9 19.8 0.4 2 5 3 30.1 30.3 0.6 3 5 3 25.9 25.2 0.5 4 5 3 9.3 8.8 0.2 5 5 3 23.4 22.9 0.5 6 5 3 16.9 16.7 0.3 7 5 3 14.2 14.1 0.3 8 5 3 8.8 8.9 0.2 0 6 3 32.1 32.0 0.7 1 6 3 4.0 4.2 0.1 2 6 3 5.3 5.2 0.1 3 6 3 4.9 4.9 0.2 4 6 3 24.3 23.6 0.5 5 6 3 1.4 1.8 1.0 6 6 3 9.8 9.4 0.2 7 6 3 3.6 3.5 0.3 8 6 3 10.4 10.7 0.2 1 7 3 21.1 20.8 0.4 2 7 3 12.1 11.9 0.3 3 7 3 16.4 16.1 0.3 4 7 3 3.3 3.2 0.3 5 7 3 13.5 13.2 0.3 6 7 3 7.0 6.9 0.2 7 7 3 12.1 12.4 0.3 0 8 3 8.2 7.9 0.2 1 8 3 1.4 1.0 0.9 2 8 3 0.0 1.5 0.9 3 8 3 1.8 1.2 0.9 4 8 3 6.2 5.8 0.2 5 8 3 0.0 0.5 1.2 6 8 3 3.3 2.8 0.5 1 9 3 17.0 16.8 0.4 2 9 3 16.2 16.1 0.3 3 9 3 11.8 11.5 0.3 4 9 3 5.0 5.0 0.2 0 10 3 13.5 13.6 0.3 1 10 3 0.0 1.9 1.1 2 10 3 1.9 2.1 1.1 0 0 4 5.4 5.1 0.2 1 0 4 25.5 24.7 0.5 2 0 4 26.5 26.6 0.5 3 0 4 28.0 28.4 0.6 4 0 4 53.0 53.2 1.1 5 0 4 8.9 8.8 0.2 6 0 4 30.4 30.2 0.6 7 0 4 17.5 17.3 0.4 8 0 4 3.4 3.9 0.4 9 0 4 0.0 0.2 1.2 1 1 4 20.0 19.8 0.4 2 1 4 24.6 24.4 0.5 3 1 4 11.1 11.0 0.2 4 1 4 6.6 6.6 0.1 5 1 4 15.7 15.6 0.3 6 1 4 12.6 12.6 0.3 7 1 4 1.7 2.1 0.9 8 1 4 6.0 6.1 0.2 9 1 4 7.8 7.7 0.2 0 2 4 29.3 29.5 0.6 1 2 4 1.9 2.0 0.2 2 2 4 28.8 29.2 0.6 3 2 4 2.2 2.3 0.2 4 2 4 26.8 26.6 0.5 5 2 4 0.9 0.8 0.7 6 2 4 20.0 19.9 0.4 7 2 4 1.4 1.7 0.9 8 2 4 13.6 13.4 0.3 9 2 4 0.7 0.3 1.0 1 3 4 19.4 20.0 0.4 2 3 4 25.0 24.8 0.5 3 3 4 11.7 11.2 0.2 4 3 4 7.0 7.0 0.2 5 3 4 16.5 16.3 0.3 6 3 4 13.2 13.2 0.3 7 3 4 0.0 2.0 0.9 8 3 4 6.7 6.7 0.2 9 3 4 8.2 8.3 0.2 0 4 4 54.2 54.7 1.1 1 4 4 18.5 18.5 0.4 2 4 4 29.8 29.0 0.6 3 4 4 22.2 21.7 0.5 4 4 4 1.9 2.0 0.3 5 4 4 6.6 6.6 0.2 6 4 4 8.8 8.5 0.2 7 4 4 13.7 13.6 0.3 8 4 4 22.2 22.1 0.5 9 4 4 0.0 0.2 1.1 1 5 4 10.3 10.3 0.2 2 5 4 13.3 13.1 0.3 3 5 4 6.1 6.2 0.2 4 5 4 3.5 3.6 0.2 5 5 4 8.9 8.8 0.2 6 5 4 7.5 7.2 0.2 7 5 4 1.1 1.4 1.0 8 5 4 3.4 3.4 0.3 0 6 4 26.0 25.9 0.5 1 6 4 3.6 3.6 0.2 2 6 4 20.5 20.3 0.4 3 6 4 4.8 4.5 0.2 4 6 4 13.0 12.7 0.3 5 6 4 0.0 1.0 1.2 6 6 4 12.4 12.0 0.3 7 6 4 2.8 2.8 0.4 8 6 4 12.9 12.7 0.3 1 7 4 12.2 12.2 0.3 2 7 4 15.7 15.5 0.3 3 7 4 7.2 7.1 0.2 4 7 4 5.2 4.7 0.2 5 7 4 11.3 11.0 0.3 6 7 4 9.3 8.9 0.3 7 7 4 0.0 1.3 1.1 0 8 4 0.0 2.0 1.1 1 8 4 9.3 9.0 0.2 2 8 4 12.8 12.5 0.3 3 8 4 11.1 10.8 0.2 4 8 4 24.7 24.2 0.5 5 8 4 3.5 3.7 0.3 6 8 4 15.4 15.6 0.3 1 9 4 3.8 3.6 0.2 2 9 4 4.8 4.5 0.2 3 9 4 2.2 2.2 0.5 4 9 4 1.3 1.0 1.2 0 10 4 6.7 7.0 0.3 1 10 4 2.6 2.7 0.4 1 1 5 52.4 52.5 1.1 2 1 5 6.2 6.0 0.2 3 1 5 10.3 10.2 0.2 4 1 5 2.3 2.0 0.2 5 1 5 2.1 2.5 0.2 6 1 5 2.3 2.8 0.3 7 1 5 18.5 18.2 0.4 8 1 5 1.6 1.4 1.0 9 1 5 22.4 22.2 0.5 0 2 5 8.4 8.3 0.2 1 2 5 28.7 28.5 0.6 2 2 5 0.3 1.4 0.8 3 2 5 33.6 33.0 0.7 4 2 5 5.9 5.9 0.1 5 2 5 10.5 10.3 0.2 6 2 5 1.7 2.5 0.9 7 2 5 21.0 20.7 0.4 8 2 5 2.1 2.3 0.4 9 2 5 0.8 0.2 1.0 1 3 5 6.4 6.4 0.2 2 3 5 4.2 4.2 0.1 3 3 5 33.0 32.9 0.7 4 3 5 1.2 1.1 0.8 5 3 5 34.3 33.8 0.7 6 3 5 2.2 2.5 0.3 7 3 5 12.2 11.9 0.3 8 3 5 1.1 1.4 1.1 9 3 5 2.9 2.9 0.4 0 4 5 1.0 1.2 0.9 1 4 5 4.0 4.1 0.1 2 4 5 0.0 0.2 0.8 3 4 5 5.2 5.1 0.1 4 4 5 0.0 0.9 1.0 5 4 5 1.1 1.2 0.9 6 4 5 0.0 0.5 1.0 7 4 5 3.0 3.1 0.3 8 4 5 0.0 0.3 1.1 1 5 5 2.1 1.9 0.3 2 5 5 4.5 4.6 0.2 3 5 5 30.3 30.1 0.6 4 5 5 1.5 1.3 1.1 5 5 5 34.5 33.0 0.7 6 5 5 2.7 2.7 0.3 7 5 5 10.2 10.1 0.2 8 5 5 1.5 1.7 1.1 0 6 5 5.1 5.0 0.2 1 6 5 17.1 17.0 0.3 2 6 5 2.0 0.9 0.4 3 6 5 20.7 20.2 0.4 4 6 5 3.9 3.6 0.2 5 6 5 6.9 6.8 0.2 6 6 5 0.0 1.5 1.2 7 6 5 14.0 14.0 0.3 1 7 5 23.9 23.7 0.5 2 7 5 1.8 1.9 0.9 3 7 5 10.1 9.6 0.2 4 7 5 0.0 0.6 1.1 5 7 5 5.8 5.6 0.2 6 7 5 0.0 0.9 1.2 0 8 5 1.3 1.3 1.2 1 8 5 3.7 4.2 0.2 2 8 5 0.0 0.3 1.0 3 8 5 5.5 5.2 0.2 4 8 5 0.8 0.9 1.2 5 8 5 0.0 1.5 1.1 1 9 5 23.2 23.1 0.5 2 9 5 1.8 2.6 1.1 3 9 5 4.9 4.7 0.2 0 0 6 14.4 14.4 0.3 1 0 6 11.0 11.1 0.2 2 0 6 18.1 17.1 0.4 3 0 6 13.0 12.9 0.3 4 0 6 47.0 47.1 0.9 5 0 6 3.9 3.9 0.2 6 0 6 26.9 26.5 0.6 7 0 6 7.7 7.7 0.2 8 0 6 2.0 1.6 1.2 9 0 6 0.0 0.4 1.3 1 1 6 8.6 8.6 0.2 2 1 6 24.6 23.8 0.5 3 1 6 5.0 5.1 0.1 4 1 6 6.7 6.8 0.2 5 1 6 7.0 7.1 0.2 6 1 6 12.9 12.9 0.3 7 1 6 0.0 1.1 1.0 8 1 6 6.5 6.5 0.2 9 1 6 3.6 3.7 0.3 0 2 6 17.9 20.2 0.4 1 2 6 1.2 0.9 0.7 2 2 6 21.7 21.4 0.4 3 2 6 0.9 1.2 0.9 4 2 6 21.3 21.0 0.4 5 2 6 0.0 0.1 0.9 6 2 6 16.3 16.1 0.3 7 2 6 0.0 0.4 1.0 8 2 6 10.8 10.7 0.2 9 2 6 0.0 0.2 1.1 1 3 6 9.2 8.9 0.2 2 3 6 24.8 24.8 0.5 3 3 6 5.2 5.2 0.1 4 3 6 7.2 7.2 0.2 5 3 6 7.5 7.5 0.2 6 3 6 13.7 13.6 0.3 7 3 6 0.0 1.1 1.0 8 3 6 7.2 7.2 0.2 0 4 6 47.4 48.2 1.0 1 4 6 8.8 8.3 0.2 2 4 6 23.7 23.6 0.5 3 4 6 9.8 9.7 0.2 4 4 6 6.3 6.0 0.2 5 4 6 3.7 3.5 0.3 6 4 6 4.7 4.8 0.2 7 4 6 6.6 6.7 0.2 8 4 6 19.9 20.1 0.4 1 5 6 4.8 4.8 0.2 2 5 6 13.3 13.4 0.3 3 5 6 2.2 2.8 0.4 4 5 6 4.1 3.7 0.2 5 5 6 3.6 4.0 0.3 6 5 6 7.8 7.6 0.2 7 5 6 1.0 0.8 1.1 0 6 6 22.3 21.9 0.5 1 6 6 2.0 1.6 0.4 2 6 6 16.8 16.4 0.3 3 6 6 2.2 1.9 0.5 4 6 6 9.4 9.2 0.2 5 6 6 1.4 0.7 1.1 6 6 6 9.5 9.2 0.2 7 6 6 1.7 1.6 1.2 1 7 6 5.6 5.8 0.2 2 7 6 16.2 16.2 0.3 3 7 6 3.3 3.3 0.4 4 7 6 5.1 5.0 0.2 5 7 6 5.3 5.1 0.2 6 7 6 8.9 9.5 0.2 0 8 6 3.3 3.4 0.4 1 8 6 3.9 4.3 0.3 2 8 6 9.6 9.5 0.2 3 8 6 5.5 5.2 0.2 4 8 6 22.0 22.4 0.5 5 8 6 1.3 1.7 1.1 1 9 6 1.7 1.6 1.1 2 9 6 4.5 4.8 0.3 3 9 6 0.0 1.2 1.3 1 1 7 30.3 30.5 0.6 2 1 7 20.6 20.4 0.4 3 1 7 11.7 11.9 0.3 4 1 7 5.7 5.7 0.2 5 1 7 6.0 6.0 0.2 6 1 7 11.9 11.5 0.3 7 1 7 13.1 12.9 0.3 8 1 7 5.9 6.0 0.2 0 2 7 28.6 28.7 0.6 1 2 7 11.9 11.6 0.3 2 2 7 4.6 4.6 0.2 3 2 7 13.7 13.8 0.3 4 2 7 21.0 21.0 0.4 5 2 7 4.1 4.2 0.2 6 2 7 8.6 8.3 0.2 7 2 7 9.3 8.9 0.2 8 2 7 9.3 9.3 0.2 1 3 7 10.3 10.3 0.2 2 3 7 15.4 15.2 0.3 3 3 7 20.9 20.8 0.4 4 3 7 4.5 4.4 0.2 5 3 7 20.8 20.4 0.4 6 3 7 8.5 8.3 0.2 7 3 7 10.1 10.1 0.2 8 3 7 3.8 4.0 0.3 0 4 7 4.1 4.3 0.4 1 4 7 0.9 1.7 1.0 2 4 7 0.0 0.8 0.9 3 4 7 1.8 2.2 0.9 4 4 7 2.9 3.1 0.3 5 4 7 1.2 0.4 1.1 6 4 7 1.8 1.4 1.4 7 4 7 0.7 1.3 1.2 8 4 7 0.0 1.3 1.3 1 5 7 6.7 6.5 0.2 2 5 7 17.0 16.9 0.4 3 5 7 18.9 18.8 0.4 4 5 7 5.1 5.1 0.2 5 5 7 20.0 19.6 0.4 6 5 7 9.6 9.5 0.2 7 5 7 9.5 8.8 0.3 0 6 7 17.7 17.8 0.4 1 6 7 7.3 7.2 0.2 2 6 7 2.9 2.8 0.5 3 6 7 8.5 8.7 0.2 4 6 7 13.8 13.7 0.3 5 6 7 2.4 2.9 0.5 6 6 7 6.0 5.6 0.3 1 7 7 15.6 15.5 0.3 2 7 7 7.0 6.7 0.2 3 7 7 9.2 9.2 0.2 4 7 7 1.1 1.7 1.2 5 7 7 6.6 6.7 0.2 0 8 7 4.4 4.5 0.4 1 8 7 2.1 1.8 1.2 2 8 7 0.0 0.8 1.4 3 8 7 2.5 2.3 1.3 4 8 7 3.2 3.6 0.4 1 9 7 13.8 14.2 0.3 0 0 8 17.4 17.7 0.4 1 0 8 19.4 19.4 0.4 2 0 8 16.2 16.0 0.4 3 0 8 23.5 22.9 0.5 4 0 8 14.2 13.3 0.3 5 0 8 7.1 7.1 0.3 6 0 8 11.2 11.4 0.3 7 0 8 14.9 14.9 0.4 8 0 8 9.4 9.3 0.3 1 1 8 15.3 15.3 0.3 2 1 8 0.0 0.5 1.1 3 1 8 9.0 8.9 0.2 4 1 8 0.0 0.0 1.3 5 1 8 13.6 13.2 0.3 6 1 8 1.4 0.3 1.1 7 1 8 0.0 1.9 1.4 8 1 8 1.8 0.0 1.2 0 2 8 16.0 16.1 0.3 1 2 8 0.6 1.6 0.9 2 2 8 14.9 15.3 0.3 3 2 8 1.4 2.1 1.1 4 2 8 13.7 13.3 0.3 5 2 8 0.0 0.3 1.3 6 2 8 11.3 11.0 0.3 7 2 8 1.6 1.1 1.3 8 2 8 8.4 8.7 0.3 1 3 8 15.8 16.0 0.3 2 3 8 0.0 0.5 1.1 3 3 8 9.3 9.3 0.2 4 3 8 1.4 0.1 1.2 5 3 8 14.1 14.1 0.3 6 3 8 0.0 0.3 1.5 7 3 8 2.1 1.9 1.5 0 4 8 13.0 13.4 0.3 1 4 8 15.0 15.1 0.3 2 4 8 13.6 13.5 0.3 3 4 8 17.8 18.1 0.4 4 4 8 12.6 12.5 0.3 5 4 8 6.2 6.1 0.2 6 4 8 9.8 10.0 0.3 7 4 8 12.6 12.7 0.3 1 5 8 8.7 8.8 0.2 2 5 8 0.0 0.3 1.1 3 5 8 5.0 5.2 0.2 4 5 8 0.0 0.0 1.2 5 5 8 7.7 7.7 0.2 6 5 8 2.0 0.3 1.5 0 6 8 11.9 11.5 0.4 1 6 8 3.6 3.0 0.4 2 6 8 11.3 11.2 0.3 3 6 8 4.2 3.8 0.3 4 6 8 10.2 10.2 0.3 5 6 8 1.6 1.2 1.3 6 6 8 8.7 8.5 0.3 1 7 8 11.2 10.9 0.3 2 7 8 0.0 0.3 1.4 3 7 8 6.4 6.3 0.3 4 7 8 0.0 0.0 1.4 0 8 8 9.5 9.5 0.4 1 8 8 8.0 8.2 0.3 2 8 8 9.3 8.9 0.3 3 8 8 10.1 10.1 0.3 1 1 9 5.3 5.4 0.2 2 1 9 13.5 13.8 0.3 3 1 9 17.0 16.9 0.4 4 1 9 4.6 3.9 0.3 5 1 9 18.1 17.3 0.4 6 1 9 8.5 8.1 0.3 7 1 9 7.3 7.4 0.3 0 2 9 19.3 19.4 0.4 1 2 9 8.6 8.8 0.2 2 2 9 2.7 3.2 0.4 3 2 9 10.0 10.4 0.3 4 2 9 14.8 14.4 0.3 5 2 9 3.6 3.5 0.4 6 2 9 6.0 6.0 0.3 7 2 9 7.5 7.2 0.3 1 3 9 18.0 18.1 0.4 2 3 9 10.2 10.4 0.3 3 3 9 7.9 7.8 0.2 4 3 9 3.6 3.1 0.3 5 3 9 5.0 4.6 0.3 6 3 9 5.6 5.8 0.4 7 3 9 8.8 8.8 0.3 0 4 9 3.1 3.0 0.4 1 4 9 0.0 1.3 1.3 2 4 9 0.0 0.6 1.4 3 4 9 0.0 1.6 1.2 4 4 9 2.3 2.1 1.3 5 4 9 0.0 0.5 1.3 6 4 9 0.0 1.0 1.5 1 5 9 17.4 17.2 0.4 2 5 9 11.5 11.7 0.3 3 5 9 6.1 5.9 0.2 4 5 9 3.3 3.7 0.4 5 5 9 2.4 2.6 1.3 6 5 9 7.0 6.8 0.3 0 6 9 12.8 12.4 0.4 1 6 9 5.7 5.7 0.3 2 6 9 2.0 2.0 1.3 3 6 9 7.2 6.9 0.3 4 6 9 9.7 9.8 0.3 5 6 9 2.2 2.4 1.3 1 7 9 6.2 5.9 0.3 2 7 9 5.1 4.8 0.3 3 7 9 9.4 9.8 0.3 0 8 9 2.2 3.3 2.0 0 0 10 29.6 30.0 0.7 1 0 10 4.5 4.6 0.3 2 0 10 13.5 13.6 0.3 3 0 10 5.2 5.7 0.3 4 0 10 5.5 5.4 0.3 5 0 10 2.4 1.5 1.7 6 0 10 0.0 2.1 2.2 7 0 10 2.7 3.7 2.0 1 1 10 3.7 3.6 0.2 2 1 10 11.8 11.9 0.3 3 1 10 2.6 2.1 0.4 4 1 10 2.6 3.4 0.6 5 1 10 2.7 3.3 1.4 6 1 10 7.6 7.0 0.3 7 1 10 2.2 0.4 1.8 0 2 10 11.9 12.1 0.3 1 2 10 1.0 0.4 1.1 2 2 10 10.2 10.4 0.2 3 2 10 0.0 0.6 1.2 4 2 10 8.0 7.8 0.3 5 2 10 0.0 0.1 1.7 6 2 10 7.3 7.0 0.3 1 3 10 3.7 3.9 0.3 2 3 10 12.6 12.7 0.3 3 3 10 2.9 2.2 0.5 4 3 10 2.8 3.8 1.5 5 3 10 4.4 3.6 0.4 6 3 10 7.4 7.5 0.3 0 4 10 6.0 6.2 0.3 1 4 10 4.0 3.6 0.3 2 4 10 7.0 6.6 0.2 3 4 10 3.5 4.4 0.6 4 4 10 20.0 19.9 0.4 5 4 10 0.0 1.5 1.4 6 4 10 11.4 11.7 0.3 1 5 10 0.0 2.2 1.3 2 5 10 7.1 7.1 0.3 3 5 10 2.4 1.2 1.6 4 5 10 0.0 1.9 1.5 5 5 10 2.1 1.9 1.4 0 6 10 4.6 4.7 0.4 1 6 10 1.1 0.7 1.4 2 6 10 7.1 7.1 0.3 3 6 10 2.4 0.9 1.6 4 6 10 8.8 9.4 0.3 1 7 10 2.5 2.8 1.5 2 7 10 8.9 9.1 0.3 1 1 11 0.0 1.1 1.2 2 1 11 3.1 2.7 0.4 3 1 11 13.1 13.1 0.3 4 1 11 0.0 0.8 1.3 5 1 11 14.9 14.8 0.3 6 1 11 1.1 1.4 1.4 0 2 11 3.4 3.6 0.4 1 2 11 9.5 9.7 0.2 2 2 11 1.5 0.5 1.2 3 2 11 11.7 11.7 0.3 4 2 11 3.2 2.8 0.4 5 2 11 3.6 3.9 0.4 6 2 11 0.0 1.0 1.6 1 3 11 14.4 14.5 0.3 2 3 11 1.5 1.9 1.1 3 3 11 3.3 3.5 0.4 4 3 11 1.1 0.4 1.3 5 3 11 1.8 1.0 1.4 0 4 11 2.3 0.5 1.4 1 4 11 0.0 1.5 1.2 2 4 11 1.5 0.1 1.3 3 4 11 1.3 1.8 1.2 4 4 11 0.0 0.5 1.4 1 5 11 14.7 14.6 0.3 2 5 11 2.5 2.2 1.3 3 5 11 2.1 2.1 1.4 4 5 11 1.7 0.5 1.6 0 6 11 2.5 2.5 1.6 1 6 11 6.3 6.6 0.3 2 6 11 0.0 0.4 1.4 0 0 12 14.9 15.6 0.4 1 0 12 6.2 6.1 0.3 2 0 12 7.9 8.0 0.3 3 0 12 7.3 7.4 0.3 4 0 12 1.3 1.4 1.4 5 0 12 2.0 2.7 1.5 1 1 12 4.5 4.9 0.3 2 1 12 5.4 5.6 0.2 3 1 12 2.6 2.9 0.6 4 1 12 1.3 1.7 1.2 5 1 12 4.0 4.5 0.4 0 2 12 6.9 7.3 0.3 1 2 12 1.8 0.5 1.2 2 2 12 6.1 6.4 0.3 3 2 12 0.0 0.5 1.3 4 2 12 4.9 5.1 0.3 1 3 12 5.6 5.3 0.3 2 3 12 5.9 6.0 0.3 3 3 12 3.2 3.1 0.4 4 3 12 0.0 1.9 1.4 0 4 12 1.4 1.7 1.4 1 4 12 4.8 5.1 0.3 2 4 12 4.3 4.5 0.3 3 4 12 6.3 6.3 0.3 1 5 12 3.3 2.9 0.5 1 1 13 4.3 4.2 0.3 2 1 13 7.0 7.1 0.2 3 1 13 4.8 5.2 0.3 0 2 13 9.6 9.8 0.3 1 2 13 0.0 0.9 1.2 2 2 13 2.0 1.6 1.2 3 2 13 0.0 1.2 1.3 1 3 13 5.2 5.4 0.3 2 3 13 4.5 5.3 0.4 #===END