Crystallography Open Database

Information card for entry 4322715

Preview

Coordinates	4322715.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C28.5 H64 O5 P4 W2
Calculated formula	C28.9 O5 P4 W2
Title of publication	Preparation and Characterization of (iPrO)4WW(η2-dmpe)2(CO), (η1-O2CH)(iPrO)4WW(η2-dmpe)2(H), [H(η2-dmpe)WWO2]2(μ-O), and W2(O)4(μ-O)[W(η2-dmpe)2CO]2 (dmpe = Bisdimethylphosphinomethane), Compounds with W-W Bonds between Metal Atoms in Greatly Differing Oxidation States
Authors of publication	Malcolm H. Chisholm; Kirsten Folting; Keith S. Kramer; William E. Streib
Journal of publication	Inorganic Chemistry
Year of publication	1998
Journal volume	37
Pages of publication	1549 - 1554
a	19.546 ± 0.003 Å
b	21.745 ± 0.004 Å
c	18.114 ± 0.003 Å
α	90°
β	90°
γ	90°
Cell volume	7699 ± 2 Å³
Cell temperature	102 K
Ambient diffraction temperature	102 K
Number of distinct elements	5
Space group number	61
Hermann-Mauguin space group symbol	P c a b
Hall space group symbol	-P 2bc 2ac
Residual factor for significantly intense reflections	0.0511
Weighted residual factors for all reflections included in the refinement	0.0463
Goodness-of-fit parameter for all reflections included in the refinement	1.1371
Diffraction radiation wavelength	0.71069 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
179330 (current)	2016-03-23	cif/4/32/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/32/27.	4322715.cif
120105	2014-07-12	Adding DOIs to range 4/32 structures.	4322715.cif
34330	2012-02-24	cif/4/ Reorganising CIF range 4 into a prefix tree.	4322715.cif
21602	2011-06-24	../uploads/cif-deposit/cod/cif Adding structures of 4322715 via cif-deposit CGI script.	4322715.cif