#------------------------------------------------------------------------------
#$Date: 2016-03-23 16:38:40 +0200 (Wed, 23 Mar 2016) $
#$Revision: 179387 $
#$URL: svn://www.crystallography.net/cod/cif/4/32/84/4328429.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4328429
loop_
_publ_author_name
'Stanislav S. Stoyko'
'Mansura Khatun'
'Arthur Mar'
_publ_contact_author_address
; Department of Chemistry
  University of Alberta
  Edmonton, AB
  Canada  T6G 2G2
;
_publ_contact_author_email       arthur.mar@ualberta.ca
_publ_contact_author_fax         '(780) 492-8231'
_publ_contact_author_name        'Dr. Arthur Mar'
_publ_contact_author_phone       '(780) 492-5592'
_publ_section_title
;
 Ternary Arsenides A2Zn2As3 (A = Sr, Eu) and Their Stuffed Derivatives
 A2Ag2ZnAs3
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              2621
_journal_page_last               2628
_journal_paper_doi               10.1021/ic202580m
_journal_volume                  51
_journal_year                    2012
_chemical_formula_structural     'Eu2 Zn2 As3'
_chemical_formula_sum            'As3 Eu2 Zn2'
_chemical_formula_weight         659.42
_chemical_name_common            'europium zinc arsenide (2/2/3)'
_chemical_name_systematic        'europium zinc arsenide (2/2/3)'
_space_group_IT_number           12
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 126.525(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.032(4)
_cell_length_b                   4.2550(12)
_cell_length_c                   11.871(3)
_cell_measurement_reflns_used    2713
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      32.60
_cell_measurement_theta_min      2.55
_cell_volume                     650.7(3)
_computing_cell_refinement       'Bruker SAINT 7.68A (Bruker, 2009)'
_computing_data_collection       'Bruker SMART 5.054 (Bruker, 1999)'
_computing_data_reduction        'Bruker SAINT 7.68A'
_computing_molecular_graphics    'ATOMS 5.1 (Dowty, 1999)'
_computing_publication_material  'Bruker SHELXTL 6.12'
_computing_structure_refinement  'Bruker SHELXTL 6.12'
_computing_structure_solution    'Bruker SHELXTL 6.12'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.968
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type  'Bruker D8/SMART APEX II CCD'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0298
_diffrn_reflns_av_sigmaI/netI    0.0266
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            4487
_diffrn_reflns_theta_full        33.06
_diffrn_reflns_theta_max         33.06
_diffrn_reflns_theta_min         2.13
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    41.294
_exptl_absorpt_correction_T_max  0.5374
_exptl_absorpt_correction_T_min  0.0424
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker SHELXTL 6.12 (Sheldrick, 2001)'
_exptl_crystal_colour            grey
_exptl_crystal_density_diffrn    6.731
_exptl_crystal_description       needle
_exptl_crystal_F_000             1140
_exptl_crystal_size_max          0.51
_exptl_crystal_size_mid          0.03
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.534
_refine_diff_density_min         -1.321
_refine_diff_density_rms         0.300
_refine_ls_extinction_coef       0.00114(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_matrix_type           full
_refine_ls_number_parameters     44
_refine_ls_number_reflns         1333
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.005
_refine_ls_R_factor_all          0.0246
_refine_ls_R_factor_gt           0.0191
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0152P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0353
_refine_ls_wR_factor_ref         0.0369
_reflns_number_gt                1172
_reflns_number_total             1333
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ic202580m_si_002_3.cif
_cod_data_source_block           Eu2Zn2As3
_cod_original_cell_volume        650.8(3)
_cod_database_code               4328429
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.266741(19) 0.0000 0.66429(3) 0.00734(6) Uani 1 2 d S
Eu2 Eu 0.39395(2) 0.0000 0.05022(3) 0.00797(6) Uani 1 2 d S
Zn1 Zn 0.04012(5) 0.0000 0.31430(6) 0.00911(11) Uani 1 2 d S
Zn2 Zn 0.41019(5) 0.0000 0.34714(6) 0.00950(12) Uani 1 2 d S
As1 As 0.07743(4) 0.0000 0.12487(5) 0.00736(10) Uani 1 2 d S
As2 As 0.15341(4) 0.0000 0.80033(5) 0.00727(10) Uani 1 2 d S
As3 As 0.38709(4) 0.0000 0.54008(5) 0.00704(10) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
As3 Eu1 As3 93.44(2) . 7_546
As3 Eu1 As3 93.44(2) . 7_556
As3 Eu1 As3 88.05(2) 7_546 7_556
As3 Eu1 As2 177.846(16) . .
As3 Eu1 As2 88.11(2) 7_546 .
As3 Eu1 As2 88.11(2) 7_556 .
As3 Eu1 As1 87.28(2) . 7_556
As3 Eu1 As1 179.020(14) 7_546 7_556
As3 Eu1 As1 92.58(2) 7_556 7_556
As2 Eu1 As1 91.15(2) . 7_556
As3 Eu1 As1 87.28(2) . 7_546
As3 Eu1 As1 92.58(2) 7_546 7_546
As3 Eu1 As1 179.020(14) 7_556 7_546
As2 Eu1 As1 91.15(2) . 7_546
As1 Eu1 As1 86.79(2) 7_556 7_546
As3 Eu1 Zn2 135.787(14) . 7_546
As3 Eu1 Zn2 44.881(19) 7_546 7_546
As3 Eu1 Zn2 98.07(2) 7_556 7_546
As2 Eu1 Zn2 45.284(14) . 7_546
As1 Eu1 Zn2 134.24(2) 7_556 7_546
As1 Eu1 Zn2 81.86(2) 7_546 7_546
As3 Eu1 Zn2 135.787(14) . 7_556
As3 Eu1 Zn2 98.07(2) 7_546 7_556
As3 Eu1 Zn2 44.882(19) 7_556 7_556
As2 Eu1 Zn2 45.284(14) . 7_556
As1 Eu1 Zn2 81.86(2) 7_556 7_556
As1 Eu1 Zn2 134.24(2) 7_546 7_556
Zn2 Eu1 Zn2 75.29(3) 7_546 7_556
As3 Eu1 Zn1 86.28(3) . .
As3 Eu1 Zn1 44.671(12) 7_546 .
As3 Eu1 Zn1 44.671(12) 7_556 .
As2 Eu1 Zn1 95.87(3) . .
As1 Eu1 Zn1 136.093(12) 7_556 .
As1 Eu1 Zn1 136.093(12) 7_546 .
Zn2 Eu1 Zn1 73.18(2) 7_546 .
Zn2 Eu1 Zn1 73.18(2) 7_556 .
As3 Eu1 Zn1 43.631(14) . 7_556
As3 Eu1 Zn1 135.42(2) 7_546 7_556
As3 Eu1 Zn1 84.24(2) 7_556 7_556
As2 Eu1 Zn1 135.196(15) . 7_556
As1 Eu1 Zn1 45.435(19) 7_556 7_556
As1 Eu1 Zn1 95.83(2) 7_546 7_556
Zn2 Eu1 Zn1 177.687(12) 7_546 7_556
Zn2 Eu1 Zn1 106.56(2) 7_556 7_556
Zn1 Eu1 Zn1 108.59(2) . 7_556
As3 Eu1 Zn1 43.631(14) . 7_546
As3 Eu1 Zn1 84.24(2) 7_546 7_546
As3 Eu1 Zn1 135.42(2) 7_556 7_546
As2 Eu1 Zn1 135.196(15) . 7_546
As1 Eu1 Zn1 95.83(2) 7_556 7_546
As1 Eu1 Zn1 45.435(18) 7_546 7_546
Zn2 Eu1 Zn1 106.56(2) 7_546 7_546
Zn2 Eu1 Zn1 177.687(12) 7_556 7_546
Zn1 Eu1 Zn1 108.59(2) . 7_546
Zn1 Eu1 Zn1 71.56(2) 7_556 7_546
As3 Eu1 Eu2 123.46(2) . 1_556
As3 Eu1 Eu2 124.384(13) 7_546 1_556
As3 Eu1 Eu2 124.384(13) 7_556 1_556
As2 Eu1 Eu2 54.39(2) . 1_556
As1 Eu1 Eu2 54.637(13) 7_556 1_556
As1 Eu1 Eu2 54.637(13) 7_546 1_556
Zn2 Eu1 Eu2 83.429(14) 7_546 1_556
Zn2 Eu1 Eu2 83.429(14) 7_556 1_556
Zn1 Eu1 Eu2 150.258(16) . 1_556
Zn1 Eu1 Eu2 95.356(14) 7_556 1_556
Zn1 Eu1 Eu2 95.356(14) 7_546 1_556
As2 Eu2 As2 85.34(2) 7_556 7_546
As2 Eu2 As2 87.71(2) 7_556 1_554
As2 Eu2 As2 87.71(2) 7_546 1_554
As2 Eu2 As1 175.168(15) 7_556 7_545
As2 Eu2 As1 95.34(2) 7_546 7_545
As2 Eu2 As1 87.53(2) 1_554 7_545
As2 Eu2 As1 95.34(2) 7_556 7
As2 Eu2 As1 175.168(15) 7_546 7
As2 Eu2 As1 87.53(2) 1_554 7
As1 Eu2 As1 83.58(2) 7_545 7
As2 Eu2 As1 83.57(2) 7_556 3
As2 Eu2 As1 139.728(18) 7_546 3
As2 Eu2 As1 130.201(17) 1_554 3
As1 Eu2 As1 98.865(18) 7_545 3
As1 Eu2 As1 45.067(19) 7 3
As2 Eu2 As1 139.728(18) 7_556 3_545
As2 Eu2 As1 83.57(2) 7_546 3_545
As2 Eu2 As1 130.201(17) 1_554 3_545
As1 Eu2 As1 45.067(19) 7_545 3_545
As1 Eu2 As1 98.865(18) 7 3_545
As1 Eu2 As1 80.41(3) 3 3_545
As2 Eu2 Zn1 46.11(2) 7_556 3
As2 Eu2 Zn1 99.92(3) 7_546 3
As2 Eu2 Zn1 131.526(13) 1_554 3
As1 Eu2 Zn1 138.16(2) 7_545 3
As1 Eu2 Zn1 83.91(3) 7 3
As1 Eu2 Zn1 47.111(17) 3 3
As1 Eu2 Zn1 98.27(2) 3_545 3
As2 Eu2 Zn1 99.92(3) 7_556 3_545
As2 Eu2 Zn1 46.11(2) 7_546 3_545
As2 Eu2 Zn1 131.526(13) 1_554 3_545
As1 Eu2 Zn1 83.91(3) 7_545 3_545
As1 Eu2 Zn1 138.16(2) 7 3_545
As1 Eu2 Zn1 98.27(2) 3 3_545
As1 Eu2 Zn1 47.111(17) 3_545 3_545
Zn1 Eu2 Zn1 79.37(3) 3 3_545
As2 Eu2 Zn2 45.916(13) 7_556 .
As2 Eu2 Zn2 45.916(13) 7_546 .
As2 Eu2 Zn2 105.77(2) 1_554 .
As1 Eu2 Zn2 136.719(13) 7_545 .
As1 Eu2 Zn2 136.719(13) 7 .
As1 Eu2 Zn2 102.558(15) 3 .
As1 Eu2 Zn2 102.558(14) 3_545 .
Zn1 Eu2 Zn2 56.200(19) 3 .
Zn1 Eu2 Zn2 56.200(19) 3_545 .
As2 Eu2 Eu1 123.543(16) 7_556 1_554
As2 Eu2 Eu1 123.543(16) 7_546 1_554
As2 Eu2 Eu1 51.829(14) 1_554 1_554
As1 Eu2 Eu1 52.282(16) 7_545 1_554
As1 Eu2 Eu1 52.282(16) 7 1_554
As1 Eu2 Eu1 94.471(11) 3 1_554
As1 Eu2 Eu1 94.471(11) 3_545 1_554
Zn1 Eu2 Eu1 135.804(14) 3 1_554
Zn1 Eu2 Eu1 135.804(14) 3_545 1_554
Zn2 Eu2 Eu1 157.601(17) . 1_554
As2 Eu2 Eu2 131.779(12) 7_556 5_655
As2 Eu2 Eu2 131.779(12) 7_546 5_655
As2 Eu2 Eu2 118.13(3) 1_554 5_655
As1 Eu2 Eu2 50.499(12) 7_545 5_655
As1 Eu2 Eu2 50.499(12) 7 5_655
As1 Eu2 Eu2 48.366(15) 3 5_655
As1 Eu2 Eu2 48.366(15) 3_545 5_655
Zn1 Eu2 Eu2 91.84(2) 3 5_655
Zn1 Eu2 Eu2 91.84(2) 3_545 5_655
Zn2 Eu2 Eu2 136.095(16) . 5_655
Eu1 Eu2 Eu2 66.303(18) 1_554 5_655
As2 Zn1 As3 106.50(2) 5_556 7_556
As2 Zn1 As3 106.50(2) 5_556 7_546
As3 Zn1 As3 113.46(4) 7_556 7_546
As2 Zn1 As1 111.48(3) 5_556 .
As3 Zn1 As1 109.43(2) 7_556 .
As3 Zn1 As1 109.43(2) 7_546 .
As2 Zn1 Zn2 51.784(19) 5_556 3_445
As3 Zn1 Zn2 123.27(3) 7_556 3_445
As3 Zn1 Zn2 54.74(2) 7_546 3_445
As1 Zn1 Zn2 127.107(19) . 3_445
As2 Zn1 Zn2 51.784(19) 5_556 3_455
As3 Zn1 Zn2 54.74(2) 7_556 3_455
As3 Zn1 Zn2 123.27(3) 7_546 3_455
As1 Zn1 Zn2 127.107(19) . 3_455
Zn2 Zn1 Zn2 84.65(3) 3_445 3_455
As2 Zn1 Eu2 62.941(15) 5_556 3_445
As3 Zn1 Eu2 162.64(2) 7_556 3_445
As3 Zn1 Eu2 83.49(2) 7_546 3_445
As1 Zn1 Eu2 65.73(2) . 3_445
Zn2 Zn1 Eu2 62.61(2) 3_445 3_445
Zn2 Zn1 Eu2 113.57(3) 3_455 3_445
As2 Zn1 Eu2 62.941(15) 5_556 3_455
As3 Zn1 Eu2 83.49(2) 7_556 3_455
As3 Zn1 Eu2 162.64(2) 7_546 3_455
As1 Zn1 Eu2 65.73(2) . 3_455
Zn2 Zn1 Eu2 113.57(3) 3_445 3_455
Zn2 Zn1 Eu2 62.61(2) 3_455 3_455
Eu2 Zn1 Eu2 79.37(3) 3_445 3_455
As2 Zn1 Eu1 134.67(3) 5_556 .
As3 Zn1 Eu1 57.760(18) 7_556 .
As3 Zn1 Eu1 57.760(18) 7_546 .
As1 Zn1 Eu1 113.85(3) . .
Zn2 Zn1 Eu1 98.45(3) 3_445 .
Zn2 Zn1 Eu1 98.45(3) 3_455 .
Eu2 Zn1 Eu1 139.575(13) 3_445 .
Eu2 Zn1 Eu1 139.575(13) 3_455 .
As2 Zn1 Eu1 138.997(18) 5_556 7_556
As3 Zn1 Eu1 55.706(18) 7_556 7_556
As3 Zn1 Eu1 114.47(3) 7_546 7_556
As1 Zn1 Eu1 56.396(15) . 7_556
Zn2 Zn1 Eu1 168.83(2) 3_445 7_556
Zn2 Zn1 Eu1 101.17(2) 3_455 7_556
Eu2 Zn1 Eu1 122.13(2) 3_445 7_556
Eu2 Zn1 Eu1 77.59(2) 3_455 7_556
Eu1 Zn1 Eu1 71.41(2) . 7_556
As2 Zn1 Eu1 138.997(18) 5_556 7_546
As3 Zn1 Eu1 114.47(3) 7_556 7_546
As3 Zn1 Eu1 55.706(18) 7_546 7_546
As1 Zn1 Eu1 56.396(15) . 7_546
Zn2 Zn1 Eu1 101.17(2) 3_445 7_546
Zn2 Zn1 Eu1 168.83(2) 3_455 7_546
Eu2 Zn1 Eu1 77.59(2) 3_445 7_546
Eu2 Zn1 Eu1 122.13(2) 3_455 7_546
Eu1 Zn1 Eu1 71.41(2) . 7_546
Eu1 Zn1 Eu1 71.56(2) 7_556 7_546
As3 Zn2 As2 114.05(2) . 7_546
As3 Zn2 As2 114.05(2) . 7_556
As2 Zn2 As2 113.04(4) 7_546 7_556
As3 Zn2 As3 109.61(3) . 5_656
As2 Zn2 As3 102.33(2) 7_546 5_656
As2 Zn2 As3 102.33(2) 7_556 5_656
As3 Zn2 Zn2 57.15(3) . 5_656
As2 Zn2 Zn2 122.234(19) 7_546 5_656
As2 Zn2 Zn2 122.234(19) 7_556 5_656
As3 Zn2 Zn2 52.46(2) 5_656 5_656
As3 Zn2 Zn1 125.07(2) . 3
As2 Zn2 Zn1 120.03(3) 7_546 3
As2 Zn2 Zn1 51.49(2) 7_556 3
As3 Zn2 Zn1 50.862(19) 5_656 3
Zn2 Zn2 Zn1 85.45(3) 5_656 3
As3 Zn2 Zn1 125.07(2) . 3_545
As2 Zn2 Zn1 51.49(2) 7_546 3_545
As2 Zn2 Zn1 120.03(3) 7_556 3_545
As3 Zn2 Zn1 50.862(19) 5_656 3_545
Zn2 Zn2 Zn1 85.45(3) 5_656 3_545
Zn1 Zn2 Zn1 84.65(3) 3 3_545
As3 Zn2 Eu2 169.69(3) . .
As2 Zn2 Eu2 62.129(19) 7_546 .
As2 Zn2 Eu2 62.129(19) 7_556 .
As3 Zn2 Eu2 80.71(2) 5_656 .
Zn2 Zn2 Eu2 133.17(4) 5_656 .
Zn1 Zn2 Eu2 61.189(15) 3 .
Zn1 Zn2 Eu2 61.189(15) 3_545 .
As3 Zn2 Eu1 58.689(15) . 7_546
As2 Zn2 Eu1 58.683(18) 7_546 7_546
As2 Zn2 Eu1 119.94(3) 7_556 7_546
As3 Zn2 Eu1 137.489(17) 5_656 7_546
Zn2 Zn2 Eu1 102.70(3) 5_656 7_546
Zn1 Zn2 Eu1 171.05(2) 3 7_546
Zn1 Zn2 Eu1 99.52(2) 3_545 7_546
Eu2 Zn2 Eu1 113.850(15) . 7_546
As3 Zn2 Eu1 58.689(15) . 7_556
As2 Zn2 Eu1 119.94(3) 7_546 7_556
As2 Zn2 Eu1 58.683(18) 7_556 7_556
As3 Zn2 Eu1 137.489(17) 5_656 7_556
Zn2 Zn2 Eu1 102.70(3) 5_656 7_556
Zn1 Zn2 Eu1 99.52(2) 3 7_556
Zn1 Zn2 Eu1 171.05(2) 3_545 7_556
Eu2 Zn2 Eu1 113.850(15) . 7_556
Eu1 Zn2 Eu1 75.29(3) 7_546 7_556
As1 As1 Zn1 116.23(4) 5 .
As1 As1 Eu1 135.719(13) 5 7_556
Zn1 As1 Eu1 78.17(2) . 7_556
As1 As1 Eu1 135.719(13) 5 7_546
Zn1 As1 Eu1 78.17(2) . 7_546
Eu1 As1 Eu1 86.79(2) 7_556 7_546
As1 As1 Eu2 69.67(3) 5 7_545
Zn1 As1 Eu2 138.186(12) . 7_545
Eu1 As1 Eu2 128.66(2) 7_556 7_545
Eu1 As1 Eu2 73.08(2) 7_546 7_545
As1 As1 Eu2 69.67(3) 5 7
Zn1 As1 Eu2 138.186(12) . 7
Eu1 As1 Eu2 73.08(2) 7_556 7
Eu1 As1 Eu2 128.66(2) 7_546 7
Eu2 As1 Eu2 83.58(2) 7_545 7
As1 As1 Eu2 65.27(2) 5 3_445
Zn1 As1 Eu2 67.158(18) . 3_445
Eu1 As1 Eu2 145.33(2) 7_556 3_445
Eu1 As1 Eu2 86.30(2) 7_546 3_445
Eu2 As1 Eu2 81.135(19) 7_545 3_445
Eu2 As1 Eu2 134.932(19) 7 3_445
As1 As1 Eu2 65.27(2) 5 3_455
Zn1 As1 Eu2 67.158(18) . 3_455
Eu1 As1 Eu2 86.30(2) 7_556 3_455
Eu1 As1 Eu2 145.33(2) 7_546 3_455
Eu2 As1 Eu2 134.932(19) 7_545 3_455
Eu2 As1 Eu2 81.135(18) 7 3_455
Eu2 As1 Eu2 80.41(3) 3_445 3_455
Zn1 As2 Zn2 76.73(2) 5_556 7_546
Zn1 As2 Zn2 76.729(19) 5_556 7_556
Zn2 As2 Zn2 113.05(4) 7_546 7_556
Zn1 As2 Eu1 129.46(3) 5_556 .
Zn2 As2 Eu1 76.03(2) 7_546 .
Zn2 As2 Eu1 76.03(2) 7_556 .
Zn1 As2 Eu2 70.949(18) 5_556 7_556
Zn2 As2 Eu2 145.17(3) 7_546 7_556
Zn2 As2 Eu2 71.95(2) 7_556 7_556
Eu1 As2 Eu2 135.735(13) . 7_556
Zn1 As2 Eu2 70.949(18) 5_556 7_546
Zn2 As2 Eu2 71.95(2) 7_546 7_546
Zn2 As2 Eu2 145.17(3) 7_556 7_546
Eu1 As2 Eu2 135.735(12) . 7_546
Eu2 As2 Eu2 85.34(2) 7_556 7_546
Zn1 As2 Eu2 156.75(3) 5_556 1_556
Zn2 As2 Eu2 114.135(19) 7_546 1_556
Zn2 As2 Eu2 114.135(19) 7_556 1_556
Eu1 As2 Eu2 73.78(3) . 1_556
Eu2 As2 Eu2 92.29(2) 7_556 1_556
Eu2 As2 Eu2 92.29(2) 7_546 1_556
Zn2 As3 Zn1 111.11(2) . 7_556
Zn2 As3 Zn1 111.11(2) . 7_546
Zn1 As3 Zn1 113.46(4) 7_556 7_546
Zn2 As3 Zn2 70.39(3) . 5_656
Zn1 As3 Zn2 74.397(19) 7_556 5_656
Zn1 As3 Zn2 74.397(19) 7_546 5_656
Zn2 As3 Eu1 156.17(3) . .
Zn1 As3 Eu1 80.66(2) 7_556 .
Zn1 As3 Eu1 80.66(2) 7_546 .
Zn2 As3 Eu1 133.43(3) 5_656 .
Zn2 As3 Eu1 76.43(2) . 7_546
Zn1 As3 Eu1 161.23(2) 7_556 7_546
Zn1 As3 Eu1 77.57(2) 7_546 7_546
Zn2 As3 Eu1 124.165(17) 5_656 7_546
Eu1 As3 Eu1 86.56(2) . 7_546
Zn2 As3 Eu1 76.43(2) . 7_556
Zn1 As3 Eu1 77.57(2) 7_556 7_556
Zn1 As3 Eu1 161.23(2) 7_546 7_556
Zn2 As3 Eu1 124.165(17) 5_656 7_556
Eu1 As3 Eu1 86.56(2) . 7_556
Eu1 As3 Eu1 88.05(2) 7_546 7_556
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 As3 3.0468(8) .
Eu1 As3 3.0614(7) 7_546
Eu1 As3 3.0614(7) 7_556
Eu1 As2 3.0664(8) .
Eu1 As1 3.0966(7) 7_556
Eu1 As1 3.0966(7) 7_546
Eu1 Zn2 3.4833(9) 7_546
Eu1 Zn2 3.4833(9) 7_556
Eu1 Zn1 3.5346(10) .
Eu1 Zn1 3.6389(9) 7_556
Eu1 Zn1 3.6389(9) 7_546
Eu1 Eu2 3.7452(12) 1_556
Eu2 As2 3.1390(7) 7_556
Eu2 As2 3.1390(7) 7_546
Eu2 As2 3.1709(9) 1_554
Eu2 As1 3.1924(7) 7_545
Eu2 As1 3.1924(7) 7
Eu2 As1 3.2958(8) 3
Eu2 As1 3.2958(8) 3_545
Eu2 Zn1 3.3318(8) 3
Eu2 Zn1 3.3318(8) 3_545
Eu2 Zn2 3.3762(11) .
Eu2 Eu1 3.7452(12) 1_554
Eu2 Eu2 4.2203(11) 5_655
Zn1 As2 2.5402(11) 5_556
Zn1 As3 2.5446(7) 7_556
Zn1 As3 2.5446(7) 7_546
Zn1 As1 2.6488(10) .
Zn1 Zn2 3.1597(8) 3_445
Zn1 Zn2 3.1597(8) 3_455
Zn1 Eu2 3.3317(8) 3_445
Zn1 Eu2 3.3317(8) 3_455
Zn1 Eu1 3.6390(9) 7_556
Zn1 Eu1 3.6390(9) 7_546
Zn2 As3 2.5284(10) .
Zn2 As2 2.5507(7) 7_546
Zn2 As2 2.5507(7) 7_556
Zn2 As3 2.6788(11) 5_656
Zn2 Zn2 3.0039(14) 5_656
Zn2 Zn1 3.1598(8) 3
Zn2 Zn1 3.1598(8) 3_545
Zn2 Eu1 3.4832(9) 7_546
Zn2 Eu1 3.4832(9) 7_556
As1 As1 2.4883(11) 5
As1 Eu1 3.0966(7) 7_556
As1 Eu1 3.0966(7) 7_546
As1 Eu2 3.1925(7) 7_545
As1 Eu2 3.1925(7) 7
As1 Eu2 3.2958(8) 3_445
As1 Eu2 3.2958(8) 3_455
As2 Zn1 2.5402(11) 5_556
As2 Zn2 2.5506(7) 7_546
As2 Zn2 2.5506(7) 7_556
As2 Eu2 3.1390(7) 7_556
As2 Eu2 3.1390(7) 7_546
As2 Eu2 3.1709(9) 1_556
As3 Zn1 2.5446(7) 7_556
As3 Zn1 2.5446(7) 7_546
As3 Zn2 2.6788(11) 5_656
As3 Eu1 3.0614(7) 7_546
As3 Eu1 3.0614(7) 7_556
