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Information card for entry 4333326
Preview
| Coordinates | 4333326.cif |
|---|---|
| Original paper (by DOI) | HTML |
| Common name | [Ru(η^5^-C~5~Me~5~){P^i^Pr~2~NHCH~2~CH~2~NHP^i^Pr~2~-κ^2^-P,P'}(η^2^-O~2~)] [B{C~8~H~3~F~6~}~4~] |
|---|---|
| Chemical name | pentahapto-pentamethylcyclopentadienyl-{bis((diisopropylphosphino)amino) ethane-κ^2^-P,P'}-dihapto-dioxygen-ruthenium (II) tetrakis{3,5-bis(trifluoromethyl)phenyl}borate |
| Formula | C56 H61 B F24 N2 O2 P2 Ru |
| Calculated formula | C56 H61 B F24 N2 O2 P2 Ru |
| Title of publication | Coordinatively Unsaturated Semisandwich Complexes of Ruthenium with Phosphinoamine Ligands and Related Species: A Complex Containing (R,R)-1,2-Bis((diisopropylphosphino)amino)cyclohexane in a New Coordination Form κ3P,P‘,N-η2-P,N |
| Authors of publication | Palacios, M. Dolores; Puerta, M. Carmen; Valerga, Pedro; Lledós, Agustí; Veilly, Edouard |
| Journal of publication | Inorganic Chemistry |
| Year of publication | 2007 |
| Journal volume | 46 |
| Journal issue | 17 |
| Pages of publication | 6958 - 6967 |
| a | 14.176 ± 0.003 Å |
| b | 14.483 ± 0.003 Å |
| c | 15.648 ± 0.003 Å |
| α | 98.52 ± 0.03° |
| β | 102.84 ± 0.03° |
| γ | 100.43 ± 0.03° |
| Cell volume | 3020.6 ± 1.3 Å3 |
| Cell temperature | 100 ± 2 K |
| Ambient diffraction temperature | 100 ± 2 K |
| Number of distinct elements | 8 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0693 |
| Residual factor for significantly intense reflections | 0.0594 |
| Weighted residual factors for significantly intense reflections | 0.112 |
| Weighted residual factors for all reflections included in the refinement | 0.1172 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.076 |
| Diffraction radiation probe | x-ray |
| Diffraction radiation wavelength | 0.71073 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | Yes |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 194597 (current) | 2017-03-29 | cif/4/ (antanas@echidna.ibt.lt) Replacing the "\K" substring with the "\k" substring in the values of the _chemical_name_common and _chemical_name_systematic data items in entries 4063887, 4063888, 4063889, 4063890, 4063891, 4063892, 4063893, 4064692, 4064693, 4064694, 4065699, 4304592, 4307205, 4317613, 4333324, 4333326. |
4333326.cif |
| 179436 | 2016-03-23 | cif/4/33/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 4/33/33. |
4333326.cif |
| 98932 | 2014-01-30 | cif/ Adding structures of 4333324, 4333325, 4333326, 4333327 via cif-deposit CGI script. |
4333326.cif |
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Users of the data should acknowledge the original authors of the
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