#------------------------------------------------------------------------------
#$Date: 2016-03-24 00:01:46 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179521 $
#$URL: svn://www.crystallography.net/cod/cif/4/34/18/4341881.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4341881
loop_
_publ_author_name
'Zhang, Xiao-Peng'
'Chang, Victoria Y.'
'Liu, Jian'
'Yang, Xiao-Liang'
'Huang, Wei'
'Li, Yizhi'
'Li, Cheng-Hui'
'Muller, Gilles'
'You, Xiao-Zeng'
_publ_section_title
;
 Potential Switchable Circularly Polarized Luminescence from Chiral
 Cyclometalated Platinum(II) Complexes.
;
_journal_issue                   1
_journal_name_full               'Inorganic chemistry'
_journal_page_first              143
_journal_page_last               152
_journal_paper_doi               10.1021/ic5019136
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'C40 H40 F3 N3 O3 Pt S'
_chemical_formula_sum            'C40 H40 F3 N3 O3 Pt S'
_chemical_formula_weight         894.90
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.869(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.598(6)
_cell_length_b                   18.956(6)
_cell_length_c                   10.500(3)
_cell_measurement_reflns_used    8641
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.251
_cell_measurement_theta_min      2.2275
_cell_volume                     3509.9(18)
_computing_cell_refinement       SMART
_computing_data_collection       SMART,(Bruker,2000)
_computing_data_reduction        SAINT(Bruker,2000)
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL(Bruker,2000) '
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker Smart Aepex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0586
_diffrn_reflns_av_sigmaI/netI    0.0542
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            11475
_diffrn_reflns_theta_full        24.99
_diffrn_reflns_theta_max         24.99
_diffrn_reflns_theta_min         1.58
_exptl_absorpt_coefficient_mu    4.117
_exptl_absorpt_correction_T_max  0.6836
_exptl_absorpt_correction_T_min  0.4931
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS,Bruker,2000
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.694
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rod
_exptl_crystal_F_000             1784
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.427
_refine_diff_density_min         -1.524
_refine_diff_density_rms         0.206
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     264
_refine_ls_number_reflns         3075
_refine_ls_number_restraints     52
_refine_ls_restrained_S_all      1.057
_refine_ls_R_factor_all          0.0470
_refine_ls_R_factor_gt           0.0450
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1120P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1366
_refine_ls_wR_factor_ref         0.1379
_reflns_number_gt                2867
_reflns_number_total             3075
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic5019136_si_005.cif
_cod_data_source_block           mo_20121221g_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/saulius/struct/COD-crude-data--automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 

 Adding full bibliography for 4341879--4341883.cif.
;
_cod_original_cell_volume        3509.9(19)
_cod_original_sg_symbol_H-M      'C2/c  '
_cod_database_code               4341881
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.0000 0.077140(14) 0.7500 0.03233(19) Uani 1 2 d S
C1 C 0.0000 -0.0263(5) 0.7500 0.0342(19) Uani 1 2 d S
C2 C 0.0000 0.1845(5) 0.7500 0.041(2) Uani 1 2 d S
C3 C 0.0000 -0.1683(5) 0.7500 0.042(2) Uani 1 2 d S
H3 H 0.0000 -0.2173 0.7500 0.050 Uiso 1 2 calc SR
C4 C 0.0430(4) -0.1338(3) 0.6956(7) 0.0411(15) Uani 1 1 d .
H4 H 0.0709 -0.1591 0.6587 0.049 Uiso 1 1 calc R
C5 C 0.0443(4) -0.0602(4) 0.6964(7) 0.0362(14) Uani 1 1 d .
C6 C 0.0890(3) -0.0115(3) 0.6546(6) 0.0346(12) Uani 1 1 d .
C7 C 0.1441(3) -0.0304(3) 0.6100(6) 0.0378(13) Uani 1 1 d .
H7 H 0.1506 -0.0775 0.5936 0.045 Uiso 1 1 calc R
C8 C 0.1890(4) 0.0205(4) 0.5902(7) 0.0401(14) Uani 1 1 d .
C9 C 0.1782(5) 0.0908(4) 0.6149(9) 0.0425(16) Uani 1 1 d .
C10 C 0.1227(3) 0.1071(3) 0.6551(7) 0.0364(13) Uani 1 1 d .
H10 H 0.1153 0.1543 0.6700 0.044 Uiso 1 1 calc R
C11 C 0.2536(5) 0.0030(5) 0.5521(9) 0.0543(19) Uani 1 1 d .
H11A H 0.2884 -0.0294 0.6216 0.065 Uiso 1 1 calc R
H11B H 0.2334 -0.0200 0.4604 0.065 Uiso 1 1 calc R
C12 C 0.2958(6) 0.0689(4) 0.5476(10) 0.050(2) Uani 1 1 d .
H12 H 0.3380 0.0612 0.5230 0.060 Uiso 1 1 calc R
C13 C 0.2379(5) 0.1256(5) 0.4578(9) 0.059(2) Uani 1 1 d .
H13A H 0.1921 0.1067 0.3824 0.070 Uiso 1 1 calc R
H13B H 0.2594 0.1631 0.4238 0.070 Uiso 1 1 calc R
C14 C 0.2303(4) 0.1441(4) 0.5974(8) 0.0449(16) Uani 1 1 d .
H14 H 0.2212 0.1937 0.6114 0.054 Uiso 1 1 calc R
C15 C 0.3149(4) 0.1163(4) 0.6815(7) 0.0428(15) Uani 1 1 d .
C16 C 0.3713(4) 0.1756(4) 0.6973(10) 0.061(2) Uani 1 1 d .
H16A H 0.3694 0.2105 0.7620 0.091 Uiso 1 1 calc R
H16B H 0.3581 0.1970 0.6067 0.091 Uiso 1 1 calc R
H16C H 0.4216 0.1565 0.7330 0.091 Uiso 1 1 calc R
C17 C 0.3378(6) 0.0813(4) 0.8246(10) 0.054(2) Uani 1 1 d .
H17A H 0.3898 0.0665 0.8619 0.081 Uiso 1 1 calc R
H17B H 0.3061 0.0410 0.8138 0.081 Uiso 1 1 calc R
H17C H 0.3321 0.1143 0.8886 0.081 Uiso 1 1 calc R
C18 C 0.0000 0.3169(5) 0.7500 0.045(2) Uani 1 2 d S
C19 C 0.0264(5) 0.3528(4) 0.6638(8) 0.0522(17) Uani 1 1 d .
C20 C 0.0249(9) 0.4265(5) 0.6663(15) 0.082(4) Uani 1 1 d .
H20 H 0.0414 0.4517 0.6089 0.098 Uiso 1 1 calc R
C21 C 0.0000 0.4628(6) 0.7500 0.080(4) Uani 1 2 d S
H21 H 0.0000 0.5119 0.7500 0.096 Uiso 1 2 calc SR
C22 C 0.0520(7) 0.3129(6) 0.5723(12) 0.094(3) Uani 1 1 d .
H22A H 0.0996 0.2904 0.6295 0.141 Uiso 1 1 calc R
H22B H 0.0583 0.3445 0.5068 0.141 Uiso 1 1 calc R
H22C H 0.0150 0.2777 0.5208 0.141 Uiso 1 1 calc R
C23 C 0.2710(4) 0.7210(3) 0.4616(5) 0.0940(15) Uani 0.50 1 d PDU
F1 F 0.280(2) 0.6562(17) 0.540(4) 0.154(6) Uani 0.50 1 d PU
O2 O 0.3375(6) 0.7442(10) 0.481(2) 0.136(6) Uani 0.50 1 d PDU
F3 F 0.2216(14) 0.7013(14) 0.3388(15) 0.172(6) Uani 0.50 1 d PDU
N1 N 0.0780(3) 0.0582(3) 0.6743(5) 0.0336(11) Uani 1 1 d .
N2 N 0.0000 0.2445(4) 0.7500 0.0425(17) Uani 1 2 d S
O1 O 0.1993(18) 0.6693(14) 0.436(3) 0.165(5) Uani 0.50 1 d PU
F2 F 0.2499(17) 0.7336(14) 0.3296(9) 0.171(5) Uani 0.50 1 d PDU
O3 O 0.307(2) 0.6722(19) 0.563(5) 0.154(6) Uani 0.50 1 d PU
S1 S 0.2710(4) 0.7210(3) 0.4616(5) 0.0940(15) Uani 0.50 1 d PDU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Pt1 C2 180.000(1) . .
C1 Pt1 N1 79.84(16) . 2_556
C2 Pt1 N1 100.16(16) . 2_556
C1 Pt1 N1 79.84(16) . .
C2 Pt1 N1 100.16(16) . .
N1 Pt1 N1 159.7(3) 2_556 .
C5 C1 C5 124.6(9) . 2_556
C5 C1 Pt1 117.7(5) . .
C5 C1 Pt1 117.7(5) 2_556 .
N2 C2 Pt1 180.000(1) . .
C4 C3 C4 123.1(9) . 2_556
C4 C3 H3 118.4 . .
C4 C3 H3 118.4 2_556 .
C3 C4 C5 119.1(6) . .
C3 C4 H4 120.4 . .
C5 C4 H4 120.4 . .
C1 C5 C4 117.0(7) . .
C1 C5 C6 113.2(6) . .
C4 C5 C6 129.8(6) . .
N1 C6 C7 119.5(6) . .
N1 C6 C5 114.1(5) . .
C7 C6 C5 126.2(6) . .
C8 C7 C6 120.5(6) . .
C8 C7 H7 119.7 . .
C6 C7 H7 119.7 . .
C7 C8 C9 118.8(6) . .
C7 C8 C11 123.1(6) . .
C9 C8 C11 117.9(6) . .
C10 C9 C8 118.8(7) . .
C10 C9 C14 124.2(7) . .
C8 C9 C14 117.0(6) . .
N1 C10 C9 123.2(6) . .
N1 C10 H10 118.4 . .
C9 C10 H10 118.4 . .
C12 C11 C8 111.0(7) . .
C12 C11 H11A 109.4 . .
C8 C11 H11A 109.4 . .
C12 C11 H11B 109.4 . .
C8 C11 H11B 109.4 . .
H11A C11 H11B 108.0 . .
C11 C12 C13 109.1(8) . .
C11 C12 C15 111.4(6) . .
C13 C12 C15 88.5(6) . .
C11 C12 H12 115.0 . .
C13 C12 H12 115.0 . .
C15 C12 H12 115.0 . .
C12 C13 C14 85.9(6) . .
C12 C13 H13A 114.3 . .
C14 C13 H13A 114.3 . .
C12 C13 H13B 114.3 . .
C14 C13 H13B 114.3 . .
H13A C13 H13B 111.5 . .
C9 C14 C13 108.0(6) . .
C9 C14 C15 108.0(6) . .
C13 C14 C15 86.8(5) . .
C9 C14 H14 116.7 . .
C13 C14 H14 116.7 . .
C15 C14 H14 116.7 . .
C17 C15 C16 109.0(7) . .
C17 C15 C12 119.2(6) . .
C16 C15 C12 113.3(6) . .
C17 C15 C14 118.6(6) . .
C16 C15 C14 110.2(6) . .
C12 C15 C14 84.8(6) . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C15 C17 H17A 109.5 . .
C15 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C15 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
N2 C18 C19 119.1(5) . .
N2 C18 C19 119.1(5) . 2_556
C19 C18 C19 121.9(10) . 2_556
C18 C19 C20 117.1(9) . .
C18 C19 C22 120.0(8) . .
C20 C19 C22 122.8(9) . .
C21 C20 C19 122.2(11) . .
C21 C20 H20 118.9 . .
C19 C20 H20 118.9 . .
C20 C21 C20 119.4(11) . 2_556
C20 C21 H21 120.3 . .
C20 C21 H21 120.3 2_556 .
C19 C22 H22A 109.5 . .
C19 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C19 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
F2 C23 F3 39.1(12) . .
F2 C23 O2 86.3(15) . .
F3 C23 O2 121.2(17) . .
F2 C23 O3 142(3) . .
F3 C23 O3 120(2) . .
O2 C23 O3 88(2) . .
F2 C23 F1 132.2(19) . .
F3 C23 F1 100.1(17) . .
O2 C23 F1 109.2(17) . .
O3 C23 F1 23(2) . .
F2 C23 O1 94.7(15) . .
F3 C23 O1 56.0(14) . .
O2 C23 O1 162.7(15) . .
O3 C23 O1 80.4(19) . .
F1 C23 O1 58.0(16) . .
F2 C23 S1 112.5(15) . 7_566
F3 C23 S1 110.0(16) . 7_566
O2 C23 S1 110.7(10) . 7_566
O3 C23 S1 105(2) . 7_566
F1 C23 S1 103.8(19) . 7_566
O1 C23 S1 84.9(12) . 7_566
F2 C23 C23 112.5(15) . 7_566
F3 C23 C23 110.0(16) . 7_566
O2 C23 C23 110.7(10) . 7_566
O3 C23 C23 105(2) . 7_566
F1 C23 C23 103.8(19) . 7_566
O1 C23 C23 84.9(12) . 7_566
S1 C23 C23 0.0(3) 7_566 7_566
O3 F1 C23 69(6) . .
O3 F1 O1 136(8) . .
C23 F1 O1 67.4(19) . .
C23 O2 F2 46.4(8) . .
F2 F3 C23 70.4(8) . .
F2 F3 O1 144(2) . .
C23 F3 O1 74.7(15) . .
C10 N1 C6 119.0(6) . .
C10 N1 Pt1 125.6(5) . .
C6 N1 Pt1 115.1(4) . .
C2 N2 C18 180.000(3) . .
F3 O1 F1 92(3) . .
F3 O1 C23 49.3(9) . .
F1 O1 C23 54.6(15) . .
F3 F2 C23 70.5(8) . .
F3 F2 O2 113.6(16) . .
C23 F2 O2 47.4(8) . .
F1 O3 C23 88(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C1 1.960(10) .
Pt1 C2 2.035(10) .
Pt1 N1 2.039(5) 2_556
Pt1 N1 2.039(5) .
C1 C5 1.383(8) .
C1 C5 1.383(8) 2_556
C2 N2 1.138(13) .
C3 C4 1.373(8) .
C3 C4 1.373(8) 2_556
C3 H3 0.9300 .
C4 C5 1.395(9) .
C4 H4 0.9300 .
C5 C6 1.465(9) .
C6 N1 1.369(8) .
C6 C7 1.398(8) .
C7 C8 1.379(9) .
C7 H7 0.9300 .
C8 C9 1.392(9) .
C8 C11 1.521(9) .
C9 C10 1.361(10) .
C9 C14 1.503(10) .
C10 N1 1.351(9) .
C10 H10 0.9300 .
C11 C12 1.510(12) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 C13 1.549(13) .
C12 C15 1.569(10) .
C12 H12 0.9800 .
C13 C14 1.577(11) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 C15 1.591(10) .
C14 H14 0.9800 .
C15 C17 1.521(11) .
C15 C16 1.533(9) .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 N2 1.372(13) .
C18 C19 1.399(9) .
C18 C19 1.399(9) 2_556
C19 C20 1.399(11) .
C19 C22 1.473(13) .
C20 C21 1.363(16) .
C20 H20 0.9300 .
C21 C20 1.363(16) 2_556
C21 H21 0.9300 .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 F2 1.284(5) .
C23 F3 1.285(5) .
C23 O2 1.304(5) .
C23 O3 1.35(4) .
C23 F1 1.44(3) .
C23 O1 1.64(3) .
C23 S1 1.765(11) 7_566
C23 C23 1.765(11) 7_566
F1 O3 0.56(5) .
F1 O1 1.50(5) .
O2 F2 1.77(3) .
F3 F2 0.86(3) .
F3 O1 1.41(3) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C2 Pt1 C1 C5 156(100) . .
N1 Pt1 C1 C5 176.4(3) 2_556 .
N1 Pt1 C1 C5 -3.6(3) . .
C2 Pt1 C1 C5 -24(100) . 2_556
N1 Pt1 C1 C5 -3.6(3) 2_556 2_556
N1 Pt1 C1 C5 176.4(3) . 2_556
C1 Pt1 C2 N2 0(100) . .
N1 Pt1 C2 N2 159(100) 2_556 .
N1 Pt1 C2 N2 -21(100) . .
C4 C3 C4 C5 0.8(4) 2_556 .
C5 C1 C5 C4 0.7(4) 2_556 .
Pt1 C1 C5 C4 -179.3(4) . .
C5 C1 C5 C6 -176.5(6) 2_556 .
Pt1 C1 C5 C6 3.5(6) . .
C3 C4 C5 C1 -1.5(9) . .
C3 C4 C5 C6 175.2(6) . .
C1 C5 C6 N1 -0.8(7) . .
C4 C5 C6 N1 -177.6(6) . .
C1 C5 C6 C7 173.4(5) . .
C4 C5 C6 C7 -3.4(11) . .
N1 C6 C7 C8 2.1(9) . .
C5 C6 C7 C8 -171.9(6) . .
C6 C7 C8 C9 -0.3(10) . .
C6 C7 C8 C11 175.5(7) . .
C7 C8 C9 C10 -1.2(11) . .
C11 C8 C9 C10 -177.2(7) . .
C7 C8 C9 C14 177.7(7) . .
C11 C8 C9 C14 1.7(11) . .
C8 C9 C10 N1 0.9(12) . .
C14 C9 C10 N1 -177.9(7) . .
C7 C8 C11 C12 -176.0(7) . .
C9 C8 C11 C12 -0.2(11) . .
C8 C11 C12 C13 -48.8(8) . .
C8 C11 C12 C15 47.3(10) . .
C11 C12 C13 C14 84.0(6) . .
C15 C12 C13 C14 -28.1(6) . .
C10 C9 C14 C13 -137.2(8) . .
C8 C9 C14 C13 44.0(9) . .
C10 C9 C14 C15 130.3(8) . .
C8 C9 C14 C15 -48.5(9) . .
C12 C13 C14 C9 -80.2(7) . .
C12 C13 C14 C15 27.8(6) . .
C11 C12 C15 C17 38.0(11) . .
C13 C12 C15 C17 147.9(7) . .
C11 C12 C15 C16 168.3(7) . .
C13 C12 C15 C16 -81.8(7) . .
C11 C12 C15 C14 -82.0(8) . .
C13 C12 C15 C14 27.9(5) . .
C9 C14 C15 C17 -40.1(9) . .
C13 C14 C15 C17 -148.0(7) . .
C9 C14 C15 C16 -166.6(6) . .
C13 C14 C15 C16 85.5(6) . .
C9 C14 C15 C12 80.5(6) . .
C13 C14 C15 C12 -27.4(6) . .
N2 C18 C19 C20 179.5(8) . .
C19 C18 C19 C20 -0.5(8) 2_556 .
N2 C18 C19 C22 1.4(10) . .
C19 C18 C19 C22 -178.6(9) 2_556 .
C18 C19 C20 C21 1.0(16) . .
C22 C19 C20 C21 179.0(10) . .
C19 C20 C21 C20 -0.5(8) . 2_556
F2 C23 F1 O3 126(10) . .
F3 C23 F1 O3 152(10) . .
O2 C23 F1 O3 23(11) . .
O1 C23 F1 O3 -170(11) . .
S1 C23 F1 O3 -95(10) 7_566 .
C23 C23 F1 O3 -95(10) 7_566 .
F2 C23 F1 O1 -64(3) . .
F3 C23 F1 O1 -39(3) . .
O2 C23 F1 O1 -167.0(18) . .
O3 C23 F1 O1 170(11) . .
S1 C23 F1 O1 74.9(19) 7_566 .
C23 C23 F1 O1 74.9(19) 7_566 .
F3 C23 O2 F2 18(3) . .
O3 C23 O2 F2 142(3) . .
F1 C23 O2 F2 134(2) . .
O1 C23 O2 F2 94(5) . .
S1 C23 O2 F2 -112.6(14) 7_566 .
C23 C23 O2 F2 -112.6(14) 7_566 .
O2 C23 F3 F2 -30(4) . .
O3 C23 F3 F2 -138(4) . .
F1 C23 F3 F2 -150(4) . .
O1 C23 F3 F2 170(5) . .
S1 C23 F3 F2 101(4) 7_566 .
C23 C23 F3 F2 101(4) 7_566 .
F2 C23 F3 O1 -170(5) . .
O2 C23 F3 O1 159.7(19) . .
O3 C23 F3 O1 52(3) . .
F1 C23 F3 O1 40(3) . .
S1 C23 F3 O1 -69.0(19) 7_566 .
C23 C23 F3 O1 -69.0(19) 7_566 .
C9 C10 N1 C6 0.9(10) . .
C9 C10 N1 Pt1 174.6(6) . .
C7 C6 N1 C10 -2.4(9) . .
C5 C6 N1 C10 172.3(5) . .
C7 C6 N1 Pt1 -176.7(4) . .
C5 C6 N1 Pt1 -2.0(7) . .
C1 Pt1 N1 C10 -170.9(5) . .
C2 Pt1 N1 C10 9.1(5) . .
N1 Pt1 N1 C10 -170.9(5) 2_556 .
C1 Pt1 N1 C6 3.0(4) . .
C2 Pt1 N1 C6 -177.0(4) . .
N1 Pt1 N1 C6 3.0(4) 2_556 .
Pt1 C2 N2 C18 0(100) . .
C19 C18 N2 C2 -138(100) . .
C19 C18 N2 C2 42(100) 2_556 .
F2 F3 O1 F1 -53(9) . .
C23 F3 O1 F1 -37(2) . .
F2 F3 O1 C23 -15(7) . .
O3 F1 O1 F3 48(16) . .
C23 F1 O1 F3 34.3(19) . .
O3 F1 O1 C23 14(15) . .
F2 C23 O1 F3 6(3) . .
O2 C23 O1 F3 -86(5) . .
O3 C23 O1 F3 -136(3) . .
F1 C23 O1 F3 -132(3) . .
S1 C23 O1 F3 118(2) 7_566 .
C23 C23 O1 F3 118(2) 7_566 .
F2 C23 O1 F1 138(2) . .
F3 C23 O1 F1 132(3) . .
O2 C23 O1 F1 46(5) . .
O3 C23 O1 F1 -4(4) . .
S1 C23 O1 F1 -110(2) 7_566 .
C23 C23 O1 F1 -110(2) 7_566 .
O1 F3 F2 C23 16(7) . .
C23 F3 F2 O2 20(3) . .
O1 F3 F2 O2 36(10) . .
O2 C23 F2 F3 155(4) . .
O3 C23 F2 F3 72(5) . .
F1 C23 F2 F3 42(5) . .
O1 C23 F2 F3 -8(4) . .
S1 C23 F2 F3 -94(4) 7_566 .
C23 C23 F2 F3 -94(4) 7_566 .
F3 C23 F2 O2 -155(4) . .
O3 C23 F2 O2 -82(3) . .
F1 C23 F2 O2 -113(3) . .
O1 C23 F2 O2 -162.7(16) . .
S1 C23 F2 O2 110.9(12) 7_566 .
C23 C23 F2 O2 110.9(12) 7_566 .
C23 O2 F2 F3 -26(4) . .
O1 F1 O3 C23 -14(15) . .
F2 C23 O3 F1 -77(12) . .
F3 C23 O3 F1 -33(11) . .
O2 C23 O3 F1 -158(10) . .
O1 C23 O3 F1 9(10) . .
S1 C23 O3 F1 91(10) 7_566 .
C23 C23 O3 F1 91(10) 7_566 .
