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#$Date: 2025-08-21 02:27:06 +0300 (Thu, 21 Aug 2025) $
#$Revision: 301840 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/36/4343691.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4343691
loop_
_publ_author_name
'Schroeder, D. R.'
'Jacobson, R. A.'
_publ_section_title
;
 Crystal structure of hexaamminecobalt nonafluoroantimonate (III)
;
_journal_name_full               'Inorganic Chemistry'
_journal_page_first              515
_journal_page_last               518
_journal_volume                  12
_journal_year                    1973
_chemical_formula_sum            'Co F9 H18 N6 Sb2'
_chemical_name_systematic        'Co (N H3)6 Sb2 F9'
_space_group_IT_number           14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 93.15
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   7.223
_cell_length_b                   7.298
_cell_length_c                   12.432
_cell_volume                     654.344
_citation_journal_id_ASTM        INOCAJ
_cod_data_source_file            Schroeder_INOCAJ_1973_622.cif
_cod_data_source_block           H18Co1F9N6Sb2
_cod_original_cell_volume        654.3435
_cod_original_formula_sum        'H18 Co1 F9 N6 Sb2'
_cod_database_code               4343691
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,y+1/2,-z+1/2
-x,-y,-z
x,-y-1/2,z-1/2
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
_atom_site_attached_hydrogens
F5 F-1 0.0988 0.5315 0.0175 0.5 0.0 0
N1 N-3 0.7595 0.0857 0.0137 1 0.0 3
F1 F-1 0.3163 0.0077 0.3721 1 0.0 0
Co1 Co+3 0.5 0 0 1 0.0 0
F4 F-1 0.0832 0.2674 0.3771 1 0.0 0
F3 F-1 0.7878 0.1425 0.2688 1 0.0 0
N3 N-3 0.4771 0.3991 0.3496 1 0.0 3
N2 N-3 0.4171 0.2361 0.0576 1 0.0 3
F2 F-1 0.1314 0.1066 0.1864 1 0.0 0
Sb1 Sb+3 0.03496 0.01997 0.32524 1 0.0 0
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 PubChem 139143331
