Crystallography Open Database

Information card for entry 7015467

Preview

Coordinates	7015467.cif
Original paper (by DOI)	HTML

Structure parameters

Formula	C54 H108 O13 P Rh Si8
Calculated formula	C54 H108 O13 P Rh Si8
Title of publication	Silsesquioxyl rhodium(I) complexes‒synthesis, structure and catalytic activity.
Authors of publication	Marciniec, Bogdan; Kownacki, Ireneusz; Franczyk, Adrian; Kubicki, Maciej
Journal of publication	Dalton transactions (Cambridge, England : 2003)
Year of publication	2011
Journal volume	40
Journal issue	18
Pages of publication	5073 - 5077
a	10.9023 ± 0.0012 Å
b	14.8954 ± 0.0018 Å
c	21.769 ± 0.003 Å
α	99.731 ± 0.012°
β	98.469 ± 0.009°
γ	104.467 ± 0.01°
Cell volume	3306.6 ± 0.8 Å³
Cell temperature	100 ± 1 K
Ambient diffraction temperature	100 ± 1 K
Number of distinct elements	6
Space group number	2
Hermann-Mauguin space group symbol	P -1
Hall space group symbol	-P 1
Residual factor for all reflections	0.0958
Residual factor for significantly intense reflections	0.0563
Weighted residual factors for significantly intense reflections	0.1313
Weighted residual factors for all reflections included in the refinement	0.1368
Goodness-of-fit parameter for all reflections included in the refinement	0.96
Diffraction radiation wavelength	0.71073 Å
Diffraction radiation type	MoKα
Has coordinates	Yes
Has disorder	Yes
Has F_obs	No

Version history

Revision	Date	Message	Files
179858 (current)	2016-03-25	cif/7/01/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/01/54.	7015467.cif
120112	2014-07-12	Adding DOIs to range 7 structures.	7015467.cif
35909	2012-02-26	cif/7/: reorganising range 7 into a prefix-directory tree.	7015467.cif
21159	2011-06-21	../uploads/cif-deposit/cod/cif Adding structures of 7015466, 7015467 via cif-deposit CGI script.	7015467.cif