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Information card for entry 7015473
Preview
| Coordinates | 7015473.cif |
|---|---|
| Original paper (by DOI) | HTML |
| External links | ChemSpider |
| Common name | Hdapp |
|---|---|
| Formula | C15 H20 N2 O3 |
| Calculated formula | C15 H20 N2 O3 |
| SMILES | Cc1c(c(=O)ccn1c1ccc(cc1)N(C)C)O.CO |
| Title of publication | One-step synthesis of Mo(0) and W(0) bis(dinitrogen) complexes with the linear tetraphosphine ligand prP4: stereoselective formation of cis-[M(N2)2(rac-prP4)] and trans-[M(N2)2(meso-prP4)]; M = Mo, W. |
| Authors of publication | Römer, René; Gradert, Christian; Bannwarth, Alexander; Peters, Gerhard; Näther, Christian; Tuczek, Felix |
| Journal of publication | Dalton transactions (Cambridge, England : 2003) |
| Year of publication | 2011 |
| Journal volume | 40 |
| Journal issue | 13 |
| Pages of publication | 3229 - 3236 |
| a | 7.5438 ± 0.0008 Å |
| b | 9.0878 ± 0.0009 Å |
| c | 11.3719 ± 0.0012 Å |
| α | 85.485 ± 0.006° |
| β | 78.375 ± 0.006° |
| γ | 69.76 ± 0.005° |
| Cell volume | 716.44 ± 0.13 Å3 |
| Cell temperature | 173 ± 2 K |
| Ambient diffraction temperature | 173 ± 2 K |
| Number of distinct elements | 4 |
| Space group number | 2 |
| Hermann-Mauguin space group symbol | P -1 |
| Hall space group symbol | -P 1 |
| Residual factor for all reflections | 0.0676 |
| Residual factor for significantly intense reflections | 0.0459 |
| Weighted residual factors for significantly intense reflections | 0.1173 |
| Weighted residual factors for all reflections included in the refinement | 0.1281 |
| Goodness-of-fit parameter for all reflections included in the refinement | 1.067 |
| Diffraction radiation wavelength | 0.71069 Å |
| Diffraction radiation type | MoKα |
| Has coordinates | Yes |
| Has disorder | No |
| Has Fobs | No |
| Revision | Date | Message | Files |
|---|---|---|---|
| 202017 (current) | 2017-10-14 | cif/ Marking COD entries in range 7 that are known to be related to ChemSpider entries using the _cod_related_entry data loop. |
7015473.cif |
| 179858 | 2016-03-25 | cif/7/01/ (antanas@kurmis) Replacing _[local]_cod_* tags with their equivalents from the COD CIF dictionary in multiple entries in subrange 7/01/54. |
7015473.cif |
| 120112 | 2014-07-12 | Adding DOIs to range 7 structures. | 7015473.cif |
| 35909 | 2012-02-26 | cif/7/: reorganising range 7 into a prefix-directory tree. | 7015473.cif |
| 21162 | 2011-06-21 | ../uploads/cif-deposit/cod/cif Adding structures of 7015472, 7015473, 7015474, 7015475 via cif-deposit CGI script. |
7015473.cif |
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