#------------------------------------------------------------------------------
#$Date: 2015-11-25 18:35:01 +0200 (Wed, 25 Nov 2015) $
#$Revision: 170533 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/11/80/7118072.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7118072
loop_
_publ_author_name
'Savi\'c, Nada D'
'Gli\<si\'c, Biljana \/D'
'Wadepohl, Hubert'
'Pavic, Aleksandar'
'Lidija, Senerovic'
'Nikodinovic-Runic, Jasmina'
'Djuran, Milos I.'
_publ_section_title
;
 Silver(I) complexes with quinazoline and phthalazine: synthesis,
 structural characterization and evaluation of biological activities
;
_journal_name_full               'Med. Chem. Commun.'
_journal_paper_doi               10.1039/C5MD00494B
_journal_year                    2015
_chemical_formula_moiety         'C20 H18 Ag2 N6, 2(B F4)'
_chemical_formula_sum            'C20 H18 Ag2 B2 F8 N6'
_chemical_formula_weight         731.76
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   difmap
_audit_block_code                co_bg18
_audit_creation_date             2015-01-24
_audit_creation_method
;
Olex2 1.2
(compiled 2015.01.19 svn.r3143 for OlexSys, GUI svn.r4992)
;
_audit_update_record
;
2015-09-18 deposited with the CCDC.
2015-11-24 downloaded from the CCDC.
;
_cell_angle_alpha                110.495(12)
_cell_angle_beta                 99.220(9)
_cell_angle_gamma                98.036(11)
_cell_formula_units_Z            1
_cell_length_a                   7.544(3)
_cell_length_b                   8.109(4)
_cell_length_c                   11.175(5)
_cell_measurement_reflns_used    8144
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      32.38
_cell_measurement_theta_min      2.71
_cell_volume                     617.7(5)
_computing_cell_refinement
;
SAINT (see _computing_data_reduction). Includes estimated systematic errors
 of the unit cell constants from Monte Carlo simulations.
;
_computing_data_collection       'SMART-5.631 (Bruker AXS, 2003)'
_computing_data_reduction
'SAINT V8.34A (Bruker AXS, 1997-2013),SADABS-2014_4 (Sheldrick and Bruker AXS, 1997-2014)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material
'encif (Wadepohl, 2009-14); encifer 1.5 (CCDC, 2014)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2008)'
_computing_structure_solution    'SUPERFLIP (Palatinus, 2007-2009)'
_diffrn_ambient_environment      'perfluoro polyether oil / N~2~'
_diffrn_ambient_temperature      100(1)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 8.19
_diffrn_detector_type            CCD-PXL-KAF2
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.933
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker AXS Smart 1000'
_diffrn_measurement_method       '\f- and \w-scans'
_diffrn_measurement_specimen_support 'polyimid foil'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0225
_diffrn_reflns_av_unetI/netI     0.0203
_diffrn_reflns_laue_measured_fraction_full 1.000
_diffrn_reflns_laue_measured_fraction_max 0.933
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15499
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.933
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         32.386
_diffrn_reflns_theta_min         1.997
_diffrn_source                   'sealed X-Ray tube (Mo)'
_diffrn_source_type              'fine focus tube'
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.668
_exptl_absorpt_correction_T_max  0.7464
_exptl_absorpt_correction_T_min  0.6421
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
multi-scan from symmetry-related measurements (Blessing 1995)
SADABS (see _computing_data_reduction)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.967
_exptl_crystal_description       plate
_exptl_crystal_F_000             356
_exptl_crystal_size_max          0.330
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.120
_refine_diff_density_max         0.640
_refine_diff_density_min         -0.294
_refine_diff_density_rms         0.085
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     192
_refine_ls_number_reflns         4134
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.0222
_refine_ls_R_factor_gt           0.0196
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[\s^2^(Fo^2^)+(0.0209P)^2^+0.3500P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0460
_refine_ls_wR_factor_ref         0.0471
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3860
_reflns_number_total             4134
_reflns_threshold_expression     'I > 2\s(I)'
_iucr_refine_instructions_details
;
    co_bg18.res created by SHELXL-2014/7

TITL co_bg18 - #2331 - in P-1 - superflip - smart
CELL 0.71073 7.5443 8.1087 11.1747 110.4953 99.2196 98.0356
ZERR 1 0.0032 0.0035 0.0047 0.0115 0.0092 0.0111
LATT 1
SFAC C H Ag B F N
UNIT 20 18 2 2 8 6

L.S. 10
PLAN  25
SIZE 0.12 0.15 0.33
TEMP -173
BOND $H
CONF
HTAB
MORE -1
fmap 2
acta
REM <olex2.extras>
REM <HklSrc "%./co_bg18.hkl">
REM </olex2.extras>

WGHT    0.020900    0.350000
FVAR       0.15480
AG    3    1.015120    0.837950    0.859196    11.00000    0.02128    0.00883 =
         0.01625    0.00268    0.00529    0.00031
N1    6    0.871535    0.751487    1.002739    11.00000    0.01454    0.00991 =
         0.01221    0.00152    0.00225    0.00096
N2    6    0.846023    0.885429    1.111751    11.00000    0.01685    0.00964 =
         0.01364    0.00157    0.00271    0.00109
N3    6    0.949609    0.565763    0.695561    11.00000    0.02445    0.01413 =
         0.01858    0.00348    0.00481    0.00262
C1    1    0.765997    0.841914    1.195181    11.00000    0.01633    0.01205 =
         0.01525    0.00236    0.00337    0.00156
H1    2    0.748416    0.943894    1.269964    11.00000   -1.20000
C2    1    0.703677    0.662068    1.183103    11.00000    0.01225    0.01264 =
         0.01463    0.00404    0.00221    0.00142
C3    1    0.618199    0.617334    1.274411    11.00000    0.01793    0.01962 =
         0.01983    0.00757    0.00768    0.00375
H3    2    0.600321    0.717028    1.352116    11.00000   -1.20000
C4    1    0.561142    0.438468    1.252276    11.00000    0.01780    0.02130 =
         0.02390    0.01168    0.00799    0.00216
H4    2    0.506503    0.405278    1.312590    11.00000   -1.20000
C5    1    0.586931    0.301369    1.140913    11.00000    0.01615    0.01493 =
         0.02454    0.00992    0.00451    0.00089
H5    2    0.545030    0.183252    1.130518    11.00000   -1.20000
C6    1    0.669478    0.342944    1.050750    11.00000    0.01371    0.01218 =
         0.01996    0.00616    0.00289    0.00137
H6    2    0.688097    0.246284    0.973411    11.00000   -1.20000
C7    1    0.728827    0.525671    1.071769    11.00000    0.01057    0.01055 =
         0.01447    0.00391    0.00082    0.00071
C8    1    0.813757    0.582362    0.984316    11.00000    0.01219    0.01059 =
         0.01303    0.00308    0.00211    0.00176
H8    2    0.831453    0.493805    0.905885    11.00000   -1.20000
C9    1    0.926669    0.424612    0.618245    11.00000    0.01923    0.01508 =
         0.01601    0.00518    0.00534    0.00203
C10   1    0.898325    0.245515    0.517224    11.00000    0.03171    0.01477 =
         0.02103   -0.00161    0.01127   -0.00012
AFIX 138
H10A  2    0.786560    0.218559    0.462442    11.00000   -1.50000
H10B  2    0.903635    0.163605    0.555246    11.00000   -1.50000
H10C  2    0.987108    0.242719    0.471001    11.00000   -1.50000
AFIX   0

F1    5    0.285125    0.030110    0.177173    11.00000    0.02730    0.02286 =
         0.03068    0.01630    0.01272    0.00722
F2    5    0.253536   -0.190395    0.256532    11.00000    0.07063    0.01410 =
         0.02885    0.00984    0.02543    0.01066
F3    5    0.205708    0.084480    0.373025    11.00000    0.03586    0.02318 =
         0.03226    0.00810    0.01951    0.01428
F4    5    0.493968    0.049087    0.352814    11.00000    0.02066    0.07031 =
         0.04228    0.01057   -0.00131    0.01045
B     4    0.310206   -0.006618    0.291302    11.00000    0.01867    0.01465 =
         0.02212    0.00529    0.00718    0.00546
HKLF 4

REM  co_bg18 - #2331 - in P-1 - superflip - smart
REM R1 =  0.0196 for    3860 Fo > 4sig(Fo)  and  0.0222 for all    4134 data
REM    192 parameters refined using      0 restraints

END

WGHT      0.0210      0.3494

REM Instructions for potential hydrogen bonds
EQIV $1 x, y+1, z+1
HTAB C1 F4_$1
EQIV $2 -x+1, -y, -z+1
HTAB C8 F2_$2
HTAB C10 F4
HTAB C10 F2_$2
HTAB C10 F3_$2
EQIV $3 x+1, y, z
HTAB C10 F3_$3

REM Highest difference peak  0.640,  deepest hole -0.294,  1-sigma level  0.085
Q1    1   1.0455  0.5207  0.5778  11.00000  0.05    0.64
Q2    1   1.1242  0.8171  0.8501  11.00000  0.05    0.62
Q3    1   0.9233  0.8533  0.8652  11.00000  0.05    0.62
Q4    1   1.0152  0.8344  0.7942  11.00000  0.05    0.62
Q5    1   0.6649  0.6354  1.2255  11.00000  0.05    0.58
Q6    1   1.0645  0.8563  0.9377  11.00000  0.05    0.57
Q7    1   0.7473  0.5522  1.0142  11.00000  0.05    0.53
Q8    1   0.7966  0.8549  1.1478  11.00000  0.05    0.52
Q9    1   0.6964  0.4389  1.0675  11.00000  0.05    0.52
Q10   1   0.7134  0.5941  1.1317  11.00000  0.05    0.51
Q11   1   0.7233  0.7546  1.1903  11.00000  0.05    0.48
Q12   1   0.6210  0.3368  1.0961  11.00000  0.05    0.47
Q13   1   0.5799  0.3804  1.1958  11.00000  0.05    0.47
Q14   1   0.9168  0.7848  0.9685  11.00000  0.05    0.43
Q15   1   0.4862  0.0120  0.3914  11.00000  0.05    0.42
Q16   1   0.6036  0.5268  1.2503  11.00000  0.05    0.40
Q17   1   0.6487  0.2952  0.9973  11.00000  0.05    0.38
Q18   1   0.8404  0.8246  1.0594  11.00000  0.05    0.37
Q19   1   0.2590  0.0452  0.3318  11.00000  0.05    0.37
Q20   1   0.8155  0.6627  0.9863  11.00000  0.05    0.37
Q21   1   0.2741  0.1022  0.4294  11.00000  0.05    0.37
Q22   1   0.9748  0.5146  0.6458  11.00000  0.05    0.35
Q23   1   0.3415 -0.1282  0.2944  11.00000  0.05    0.34
Q24   1   0.8806  0.9767  1.1264  11.00000  0.05    0.33
Q25   1   0.3978  0.0735  0.3773  11.00000  0.05    0.33
;
_cod_data_source_file            c5md00494b2.cif
_cod_data_source_block           co_bg18
_cod_database_code               7118072
_audit_block_refno               2331
_audit_block_usercomment         BG79
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.825
_shelx_estimated_absorpt_t_min   0.609
_shelxl_version_number           2014/7
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Idealised Me refined as rotating group with stretchable bonds:
 C10(H10A,H10B,H10C)
;
_shelx_res_checksum              88404
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Ag Ag 1.01512(2) 0.83795(2) 0.85920(2) 0.01622(4) Uani 1 1 d .
N1 N 0.87154(16) 0.75149(15) 1.00274(11) 0.0132(2) Uani 1 1 d .
N2 N 0.84602(16) 0.88543(15) 1.11175(12) 0.0144(2) Uani 1 1 d .
N3 N 0.94961(19) 0.56576(17) 0.69556(13) 0.0200(2) Uani 1 1 d .
C1 C 0.76600(19) 0.84191(18) 1.19518(14) 0.0155(2) Uani 1 1 d .
H1 H 0.748(3) 0.944(3) 1.270(2) 0.019 Uiso 1 1 d R
C2 C 0.70368(18) 0.66207(18) 1.18310(13) 0.0137(2) Uani 1 1 d .
C3 C 0.6182(2) 0.6173(2) 1.27441(15) 0.0187(3) Uani 1 1 d .
H3 H 0.600(3) 0.717(3) 1.352(2) 0.022 Uiso 1 1 d R
C4 C 0.5611(2) 0.4385(2) 1.25228(16) 0.0200(3) Uani 1 1 d .
H4 H 0.507(3) 0.405(3) 1.313(2) 0.024 Uiso 1 1 d R
C5 C 0.5869(2) 0.3014(2) 1.14091(15) 0.0181(3) Uani 1 1 d .
H5 H 0.545(3) 0.183(3) 1.131(2) 0.022 Uiso 1 1 d R
C6 C 0.66948(19) 0.34294(18) 1.05075(15) 0.0155(2) Uani 1 1 d .
H6 H 0.688(3) 0.246(3) 0.973(2) 0.019 Uiso 1 1 d R
C7 C 0.72883(17) 0.52567(17) 1.07177(13) 0.0125(2) Uani 1 1 d .
C8 C 0.81376(18) 0.58236(17) 0.98432(13) 0.0125(2) Uani 1 1 d .
H8 H 0.831(3) 0.494(3) 0.9059(19) 0.015 Uiso 1 1 d R
C9 C 0.9267(2) 0.42461(19) 0.61825(14) 0.0170(3) Uani 1 1 d .
C10 C 0.8983(2) 0.2455(2) 0.51722(16) 0.0247(3) Uani 1 1 d .
H10A H 0.7866(18) 0.2186(9) 0.4624(12) 0.037 Uiso 1 1 calc GR
H10B H 0.9036(19) 0.1636(12) 0.5552(6) 0.037 Uiso 1 1 calc GR
H10C H 0.9871(17) 0.2427(6) 0.4710(11) 0.037 Uiso 1 1 calc GR
F1 F 0.28512(14) 0.03011(13) 0.17717(10) 0.02429(19) Uani 1 1 d .
F2 F 0.25354(19) -0.19039(13) 0.25653(11) 0.0355(3) Uani 1 1 d .
F3 F 0.20571(15) 0.08448(14) 0.37302(11) 0.0288(2) Uani 1 1 d .
F4 F 0.49397(16) 0.0491(2) 0.35281(13) 0.0484(3) Uani 1 1 d .
B B 0.3102(2) -0.0066(2) 0.29130(17) 0.0184(3) Uani 1 1 d .
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_23
_atom_site_aniso_U_13
_atom_site_aniso_U_12
Ag 0.02128(6) 0.00883(5) 0.01625(6) 0.00268(4) 0.00529(4) 0.00031(4)
N1 0.0145(5) 0.0099(5) 0.0122(5) 0.0015(4) 0.0023(4) 0.0010(4)
N2 0.0169(5) 0.0096(5) 0.0136(5) 0.0016(4) 0.0027(4) 0.0011(4)
N3 0.0245(6) 0.0141(5) 0.0186(6) 0.0035(5) 0.0048(5) 0.0026(5)
C1 0.0163(6) 0.0121(6) 0.0152(6) 0.0024(5) 0.0034(5) 0.0016(5)
C2 0.0123(5) 0.0126(5) 0.0146(6) 0.0040(5) 0.0022(4) 0.0014(4)
C3 0.0179(6) 0.0196(7) 0.0198(7) 0.0076(5) 0.0077(5) 0.0038(5)
C4 0.0178(6) 0.0213(7) 0.0239(7) 0.0117(6) 0.0080(5) 0.0022(5)
C5 0.0161(6) 0.0149(6) 0.0245(7) 0.0099(5) 0.0045(5) 0.0009(5)
C6 0.0137(6) 0.0122(6) 0.0200(7) 0.0062(5) 0.0029(5) 0.0014(4)
C7 0.0106(5) 0.0105(5) 0.0145(6) 0.0039(5) 0.0008(4) 0.0007(4)
C8 0.0122(5) 0.0106(5) 0.0130(6) 0.0031(5) 0.0021(4) 0.0018(4)
C9 0.0192(6) 0.0151(6) 0.0160(6) 0.0052(5) 0.0053(5) 0.0020(5)
C10 0.0317(8) 0.0148(6) 0.0210(7) -0.0016(6) 0.0113(6) -0.0001(6)
F1 0.0273(5) 0.0229(4) 0.0307(5) 0.0163(4) 0.0127(4) 0.0072(4)
F2 0.0706(8) 0.0141(4) 0.0289(5) 0.0098(4) 0.0254(5) 0.0107(5)
F3 0.0359(5) 0.0232(5) 0.0323(5) 0.0081(4) 0.0195(4) 0.0143(4)
F4 0.0207(5) 0.0703(9) 0.0423(7) 0.0106(7) -0.0013(5) 0.0104(6)
B 0.0187(7) 0.0147(7) 0.0221(8) 0.0053(6) 0.0072(6) 0.0055(5)
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag N1 127.44(4) 2_777 .
N2 Ag N3 135.49(5) 2_777 .
N3 Ag N1 96.99(5) . .
N2 N1 Ag 117.88(8) . .
C8 N1 Ag 122.87(9) . .
C8 N1 N2 119.26(12) . .
N1 N2 Ag 114.12(9) . 2_777
C1 N2 Ag 125.67(9) . 2_777
C1 N2 N1 119.65(12) . .
C9 N3 Ag 174.77(13) . .
N2 C1 H1 115.8(12) . .
N2 C1 C2 124.18(13) . .
C2 C1 H1 120.0(12) . .
C3 C2 C1 123.48(13) . .
C7 C2 C1 116.16(12) . .
C7 C2 C3 120.35(13) . .
C2 C3 H3 118.7(12) . .
C4 C3 C2 118.64(14) . .
C4 C3 H3 122.6(12) . .
C3 C4 H4 120.3(13) . .
C3 C4 C5 121.11(14) . .
C5 C4 H4 118.6(13) . .
C4 C5 H5 117.5(13) . .
C6 C5 C4 120.90(13) . .
C6 C5 H5 121.6(13) . .
C5 C6 H6 120.5(12) . .
C5 C6 C7 118.80(13) . .
C7 C6 H6 120.7(12) . .
C2 C7 C6 120.20(13) . .
C2 C7 C8 116.68(12) . .
C6 C7 C8 123.12(13) . .
N1 C8 C7 124.05(12) . .
N1 C8 H8 116.3(11) . .
C7 C8 H8 119.6(11) . .
N3 C9 C10 178.76(16) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10B 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
F2 B F1 108.46(13) . .
F2 B F3 109.73(13) . .
F3 B F1 109.34(13) . .
F4 B F1 108.64(13) . .
F4 B F2 110.34(15) . .
F4 B F3 110.30(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag N1 2.3173(13) .
Ag N2 2.2267(15) 2_777
Ag N3 2.2447(15) .
N1 N2 1.3812(16) .
N1 C8 1.3113(18) .
N2 Ag 2.2267(14) 2_777
N2 C1 1.3074(19) .
N3 C9 1.1361(19) .
C1 H1 0.99(2) .
C1 C2 1.420(2) .
C2 C3 1.412(2) .
C2 C7 1.4064(19) .
C3 H3 1.00(2) .
C3 C4 1.375(2) .
C4 H4 0.94(2) .
C4 C5 1.411(2) .
C5 H5 0.93(2) .
C5 C6 1.377(2) .
C6 H6 0.99(2) .
C6 C7 1.4100(19) .
C7 C8 1.4177(19) .
C8 H8 0.96(2) .
C9 C10 1.455(2) .
C10 H10A 0.907(13) .
C10 H10B 0.907(13) .
C10 H10C 0.907(13) .
F1 B 1.398(2) .
F2 B 1.385(2) .
F3 B 1.3865(19) .
F4 B 1.379(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Ag N1 N2 Ag -7.93(12) . 2_777
Ag N1 N2 C1 -179.81(10) . .
Ag N1 C8 C7 178.70(10) . .
Ag N2 C1 C2 -169.88(10) 2_777 .
N1 N2 C1 C2 1.0(2) . .
N2 N1 C8 C7 -1.6(2) . .
N2 C1 C2 C3 179.71(14) . .
N2 C1 C2 C7 -1.3(2) . .
C1 C2 C3 C4 179.23(14) . .
C1 C2 C7 C6 -179.34(13) . .
C1 C2 C7 C8 0.17(18) . .
C2 C3 C4 C5 0.0(2) . .
C2 C7 C8 N1 1.2(2) . .
C3 C2 C7 C6 -0.3(2) . .
C3 C2 C7 C8 179.24(13) . .
C3 C4 C5 C6 -0.3(2) . .
C4 C5 C6 C7 0.2(2) . .
C5 C6 C7 C2 0.0(2) . .
C5 C6 C7 C8 -179.45(13) . .
C6 C7 C8 N1 -179.29(13) . .
C7 C2 C3 C4 0.2(2) . .
C8 N1 N2 Ag 172.31(10) . 2_777
C8 N1 N2 C1 0.44(19) . .