#------------------------------------------------------------------------------
#$Date: 2016-02-14 16:26:36 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176435 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/57/1515705.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1515705
loop_
_publ_author_name
'Patil, Siddappa'
'Deally, Anthony'
'Gleeson, Brendan'
'Müller-Bunz, Helge'
'Paradisi, Francesca'
'Tacke, Matthias'
_publ_section_title
;
 Novel benzyl-substituted N-heterocyclic carbene-silver acetate complexes:
 synthesis, cytotoxicity and antibacterial studies.
;
_journal_issue                   1
_journal_name_full               'Metallomics : integrated biometal science'
_journal_page_first              74
_journal_page_last               88
_journal_paper_doi               10.1039/c0mt00034e
_journal_volume                  3
_journal_year                    2011
_chemical_formula_moiety         'C62 H54 Ag2 N4 O4 '
_chemical_formula_sum            'C62 H54 Ag2 N4 O4'
_chemical_formula_weight         1134.83
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 119.297(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.9368(7)
_cell_length_b                   9.5997(2)
_cell_length_c                   25.2845(7)
_cell_measurement_reflns_used    15516
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      76.6904
_cell_measurement_theta_min      3.6907
_cell_volume                     5066.9(3)
_computing_cell_refinement
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan 5 2010,16:28:46)
;
_computing_data_collection
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan 5 2010,16:28:46)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan 5 2010,16:28:46)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.3196
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Cu) X-ray Source'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0327
_diffrn_reflns_av_sigmaI/netI    0.0213
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            24441
_diffrn_reflns_theta_full        75.00
_diffrn_reflns_theta_max         76.89
_diffrn_reflns_theta_min         4.01
_exptl_absorpt_coefficient_mu    6.625
_exptl_absorpt_correction_T_max  0.905
_exptl_absorpt_correction_T_min  0.608
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan 5 2010,16:28:46)
Analytical numeric absorption correction using a multifaceted crystal
model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.488
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2320
_exptl_crystal_size_max          0.1491
_exptl_crystal_size_mid          0.0309
_exptl_crystal_size_min          0.0169
_refine_diff_density_max         0.348
_refine_diff_density_min         -0.581
_refine_diff_density_rms         0.061
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.069
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     326
_refine_ls_number_reflns         5254
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.069
_refine_ls_R_factor_all          0.0273
_refine_ls_R_factor_gt           0.0233
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0293P)²+4.4420P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0551
_refine_ls_wR_factor_ref         0.0564
_reflns_number_gt                4726
_reflns_number_total             5254
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c0mt00034e.txt
_cod_data_source_block           tac116(4f)
_cod_original_cell_volume        5066.9(2)
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C62 H54 Ag2 N4 O4 '
_cod_database_code               1515705
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag Ag 0.463396(6) 0.097235(13) 0.015242(5) 0.01829(5) Uani 1 1 d .
C1 C 0.70493(9) 0.2643(2) 0.22045(8) 0.0223(4) Uani 1 1 d .
H1 H 0.7379 0.2047 0.2231 0.027 Uiso 1 1 calc R
C2 C 0.71608(9) 0.3484(2) 0.26950(9) 0.0262(4) Uani 1 1 d .
H2 H 0.7563 0.3449 0.3057 0.031 Uiso 1 1 calc R
C3 C 0.66867(10) 0.4371(2) 0.26561(9) 0.0250(4) Uani 1 1 d .
H3 H 0.6765 0.4964 0.2986 0.030 Uiso 1 1 calc R
C4 C 0.60950(10) 0.4389(2) 0.21308(9) 0.0242(4) Uani 1 1 d .
H4 H 0.5767 0.4990 0.2104 0.029 Uiso 1 1 calc R
C5 C 0.59799(9) 0.3538(2) 0.16460(8) 0.0212(4) Uani 1 1 d .
H5 H 0.5572 0.3550 0.1291 0.025 Uiso 1 1 calc R
C6 C 0.64585(9) 0.26656(18) 0.16755(8) 0.0172(3) Uani 1 1 d .
C7 C 0.63310(8) 0.17070(18) 0.11513(8) 0.0178(3) Uani 1 1 d .
H7A H 0.6744 0.1353 0.1205 0.021 Uiso 1 1 calc R
H7B H 0.6077 0.0898 0.1156 0.021 Uiso 1 1 calc R
N1 N 0.52400(7) 0.30180(16) -0.03158(6) 0.0157(3) Uani 1 1 d .
C8 C 0.53637(8) 0.21780(18) 0.01581(8) 0.0159(3) Uani 1 1 d .
C9 C 0.62531(8) 0.34012(18) 0.03487(8) 0.0165(3) Uani 1 1 d .
C11 C 0.69378(8) 0.37820(19) 0.06644(8) 0.0174(3) Uani 1 1 d .
C12 C 0.71514(9) 0.50644(19) 0.09595(8) 0.0209(4) Uani 1 1 d .
H12 H 0.6857 0.5694 0.0982 0.025 Uiso 1 1 calc R
C13 C 0.77967(10) 0.5412(2) 0.12195(9) 0.0260(4) Uani 1 1 d .
H13 H 0.7942 0.6283 0.1419 0.031 Uiso 1 1 calc R
C14 C 0.82271(9) 0.4508(2) 0.11915(9) 0.0289(4) Uani 1 1 d .
H14 H 0.8666 0.4758 0.1368 0.035 Uiso 1 1 calc R
C15 C 0.80194(11) 0.3232(3) 0.09052(11) 0.0361(5) Uani 1 1 d .
H15 H 0.8317 0.2600 0.0890 0.043 Uiso 1 1 calc R
C16 C 0.73749(10) 0.2879(2) 0.06401(10) 0.0290(4) Uani 1 1 d .
H16 H 0.7233 0.2007 0.0440 0.035 Uiso 1 1 calc R
C10 C 0.57795(8) 0.37819(18) -0.02123(8) 0.0160(3) Uani 1 1 d .
C17 C 0.58007(8) 0.47296(19) -0.06617(8) 0.0169(3) Uani 1 1 d .
C18 C 0.60024(8) 0.61073(19) -0.05083(8) 0.0182(3) Uani 1 1 d .
H18 H 0.6119 0.6443 -0.0114 0.022 Uiso 1 1 calc R
C19 C 0.60346(9) 0.6993(2) -0.09284(9) 0.0222(4) Uani 1 1 d .
H19 H 0.6172 0.7929 -0.0821 0.027 Uiso 1 1 calc R
C20 C 0.58664(9) 0.6510(2) -0.15046(9) 0.0240(4) Uani 1 1 d .
H20 H 0.5889 0.7114 -0.1791 0.029 Uiso 1 1 calc R
C21 C 0.56653(9) 0.5145(2) -0.16616(8) 0.0243(4) Uani 1 1 d .
H21 H 0.5549 0.4815 -0.2056 0.029 Uiso 1 1 calc R
C22 C 0.56334(9) 0.4261(2) -0.12447(8) 0.0210(4) Uani 1 1 d .
H22 H 0.5496 0.3326 -0.1356 0.025 Uiso 1 1 calc R
N2 N 0.59847(7) 0.24094(15) 0.05630(6) 0.0157(3) Uani 1 1 d .
C23 C 0.46122(8) 0.30821(19) -0.08600(8) 0.0176(3) Uani 1 1 d .
H23A H 0.4569 0.3993 -0.1060 0.021 Uiso 1 1 calc R
H23B H 0.4278 0.3032 -0.0738 0.021 Uiso 1 1 calc R
C24 C 0.44929(8) 0.19354(18) -0.13151(8) 0.0170(3) Uani 1 1 d .
C25 C 0.49591(9) 0.09840(19) -0.12550(8) 0.0194(3) Uani 1 1 d .
H25 H 0.5380 0.1041 -0.0918 0.023 Uiso 1 1 calc R
C26 C 0.48060(10) -0.0053(2) -0.16909(9) 0.0236(4) Uani 1 1 d .
H26 H 0.5124 -0.0705 -0.1648 0.028 Uiso 1 1 calc R
C27 C 0.41956(10) -0.0145(2) -0.21848(9) 0.0260(4) Uani 1 1 d .
H27 H 0.4096 -0.0853 -0.2480 0.031 Uiso 1 1 calc R
C28 C 0.37289(10) 0.0807(2) -0.22463(9) 0.0260(4) Uani 1 1 d .
H28 H 0.3310 0.0753 -0.2585 0.031 Uiso 1 1 calc R
C29 C 0.38776(9) 0.1838(2) -0.18110(8) 0.0214(4) Uani 1 1 d .
H29 H 0.3557 0.2482 -0.1852 0.026 Uiso 1 1 calc R
O1 O 0.37297(6) 0.02848(14) 0.00549(6) 0.0219(3) Uani 1 1 d .
O2 O 0.33797(7) 0.16291(15) -0.07663(6) 0.0254(3) Uani 1 1 d .
C30 C 0.32874(9) 0.09429(19) -0.03998(8) 0.0198(3) Uani 1 1 d .
C31 C 0.26218(10) 0.0893(2) -0.04707(10) 0.0281(4) Uani 1 1 d .
H31A H 0.2475 0.1843 -0.0464 0.042 Uiso 1 1 calc R
H31B H 0.2632 0.0355 -0.0137 0.042 Uiso 1 1 calc R
H31C H 0.2327 0.0449 -0.0858 0.042 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C8 Ag O1 163.40(6) .
C8 Ag Ag 75.37(5) 5_655
O1 Ag Ag 118.27(4) 5_655
C6 C1 C2 120.56(18) .
C6 C1 H1 119.7 .
C2 C1 H1 119.7 .
C3 C2 C1 120.06(18) .
C3 C2 H2 120.0 .
C1 C2 H2 120.0 .
C2 C3 C4 119.52(18) .
C2 C3 H3 120.2 .
C4 C3 H3 120.2 .
C5 C4 C3 120.51(18) .
C5 C4 H4 119.7 .
C3 C4 H4 119.7 .
C4 C5 C6 120.40(17) .
C4 C5 H5 119.8 .
C6 C5 H5 119.8 .
C5 C6 C1 118.92(16) .
C5 C6 C7 120.67(16) .
C1 C6 C7 120.36(16) .
N2 C7 C6 112.32(14) .
N2 C7 H7A 109.1 .
C6 C7 H7A 109.1 .
N2 C7 H7B 109.1 .
C6 C7 H7B 109.1 .
H7A C7 H7B 107.9 .
C8 N1 C10 111.51(14) .
C8 N1 C23 122.59(15) .
C10 N1 C23 125.90(14) .
N2 C8 N1 104.88(14) .
N2 C8 Ag 134.73(13) .
N1 C8 Ag 120.31(12) .
C10 C9 N2 106.27(15) .
C10 C9 C11 129.41(16) .
N2 C9 C11 123.96(15) .
C16 C11 C12 119.21(17) .
C16 C11 C9 119.00(17) .
C12 C11 C9 121.70(16) .
C13 C12 C11 119.61(18) .
C13 C12 H12 120.2 .
C11 C12 H12 120.2 .
C14 C13 C12 120.72(19) .
C14 C13 H13 119.6 .
C12 C13 H13 119.6 .
C13 C14 C15 119.91(19) .
C13 C14 H14 120.0 .
C15 C14 H14 120.0 .
C14 C15 C16 119.8(2) .
C14 C15 H15 120.1 .
C16 C15 H15 120.1 .
C11 C16 C15 120.7(2) .
C11 C16 H16 119.6 .
C15 C16 H16 119.6 .
C9 C10 N1 106.06(15) .
C9 C10 C17 129.96(16) .
N1 C10 C17 123.89(15) .
C18 C17 C22 118.62(16) .
C18 C17 C10 120.50(16) .
C22 C17 C10 120.87(16) .
C19 C18 C17 120.49(17) .
C19 C18 H18 119.8 .
C17 C18 H18 119.8 .
C20 C19 C18 120.06(18) .
C20 C19 H19 120.0 .
C18 C19 H19 120.0 .
C21 C20 C19 119.92(17) .
C21 C20 H20 120.0 .
C19 C20 H20 120.0 .
C22 C21 C20 120.16(17) .
C22 C21 H21 119.9 .
C20 C21 H21 119.9 .
C21 C22 C17 120.75(18) .
C21 C22 H22 119.6 .
C17 C22 H22 119.6 .
C8 N2 C9 111.28(14) .
C8 N2 C7 124.12(15) .
C9 N2 C7 124.60(15) .
N1 C23 C24 114.18(15) .
N1 C23 H23A 108.7 .
C24 C23 H23A 108.7 .
N1 C23 H23B 108.7 .
C24 C23 H23B 108.7 .
H23A C23 H23B 107.6 .
C25 C24 C29 119.49(17) .
C25 C24 C23 123.43(16) .
C29 C24 C23 117.07(16) .
C24 C25 C26 119.72(17) .
C24 C25 H25 120.1 .
C26 C25 H25 120.1 .
C27 C26 C25 120.74(18) .
C27 C26 H26 119.6 .
C25 C26 H26 119.6 .
C26 C27 C28 119.64(18) .
C26 C27 H27 120.2 .
C28 C27 H27 120.2 .
C29 C28 C27 119.89(18) .
C29 C28 H28 120.1 .
C27 C28 H28 120.1 .
C28 C29 C24 120.52(18) .
C28 C29 H29 119.7 .
C24 C29 H29 119.7 .
C30 O1 Ag 107.04(11) .
O2 C30 O1 124.00(17) .
O2 C30 C31 119.30(17) .
O1 C30 C31 116.68(17) .
C30 C31 H31A 109.5 .
C30 C31 H31B 109.5 .
H31A C31 H31B 109.5 .
C30 C31 H31C 109.5 .
H31A C31 H31C 109.5 .
H31B C31 H31C 109.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag C8 2.0896(17) .
Ag O1 2.1585(12) .
Ag Ag 2.9107(3) 5_655
C1 C6 1.392(3) .
C1 C2 1.392(3) .
C1 H1 0.9500 .
C2 C3 1.383(3) .
C2 H2 0.9500 .
C3 C4 1.389(3) .
C3 H3 0.9500 .
C4 C5 1.384(3) .
C4 H4 0.9500 .
C5 C6 1.392(3) .
C5 H5 0.9500 .
C6 C7 1.517(2) .
C7 N2 1.465(2) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
N1 C8 1.351(2) .
N1 C10 1.394(2) .
N1 C23 1.460(2) .
C8 N2 1.348(2) .
C9 C10 1.363(2) .
C9 N2 1.398(2) .
C9 C11 1.475(2) .
C11 C16 1.383(3) .
C11 C12 1.400(3) .
C12 C13 1.391(3) .
C12 H12 0.9500 .
C13 C14 1.375(3) .
C13 H13 0.9500 .
C14 C15 1.385(3) .
C14 H14 0.9500 .
C15 C16 1.390(3) .
C15 H15 0.9500 .
C16 H16 0.9500 .
C10 C17 1.476(2) .
C17 C18 1.396(3) .
C17 C22 1.399(2) .
C18 C19 1.392(3) .
C18 H18 0.9500 .
C19 C20 1.388(3) .
C19 H19 0.9500 .
C20 C21 1.385(3) .
C20 H20 0.9500 .
C21 C22 1.384(3) .
C21 H21 0.9500 .
C22 H22 0.9500 .
C23 C24 1.515(2) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 C25 1.392(3) .
C24 C29 1.394(3) .
C25 C26 1.395(3) .
C25 H25 0.9500 .
C26 C27 1.384(3) .
C26 H26 0.9500 .
C27 C28 1.392(3) .
C27 H27 0.9500 .
C28 C29 1.391(3) .
C28 H28 0.9500 .
C29 H29 0.9500 .
O1 C30 1.285(2) .
O2 C30 1.242(2) .
C30 C31 1.514(3) .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C6 C1 C2 C3 -1.1(3) .
C1 C2 C3 C4 1.6(3) .
C2 C3 C4 C5 -0.7(3) .
C3 C4 C5 C6 -0.8(3) .
C4 C5 C6 C1 1.3(3) .
C4 C5 C6 C7 178.64(17) .
C2 C1 C6 C5 -0.3(3) .
C2 C1 C6 C7 -177.68(17) .
C5 C6 C7 N2 44.5(2) .
C1 C6 C7 N2 -138.17(17) .
C10 N1 C8 N2 -0.11(19) .
C23 N1 C8 N2 179.81(15) .
C10 N1 C8 Ag 177.09(11) .
C23 N1 C8 Ag -3.0(2) .
O1 Ag C8 N2 131.3(2) .
Ag Ag C8 N2 -81.77(17) 5_655
O1 Ag C8 N1 -44.9(3) .
Ag Ag C8 N1 102.05(13) 5_655
C10 C9 C11 C16 -96.5(2) .
N2 C9 C11 C16 75.7(2) .
C10 C9 C11 C12 80.0(2) .
N2 C9 C11 C12 -107.8(2) .
C16 C11 C12 C13 0.4(3) .
C9 C11 C12 C13 -176.12(17) .
C11 C12 C13 C14 -0.2(3) .
C12 C13 C14 C15 -0.4(3) .
C13 C14 C15 C16 0.9(3) .
C12 C11 C16 C15 0.1(3) .
C9 C11 C16 C15 176.7(2) .
C14 C15 C16 C11 -0.7(4) .
N2 C9 C10 N1 0.52(18) .
C11 C9 C10 N1 173.74(17) .
N2 C9 C10 C17 -176.04(17) .
C11 C9 C10 C17 -2.8(3) .
C8 N1 C10 C9 -0.3(2) .
C23 N1 C10 C9 179.82(16) .
C8 N1 C10 C17 176.55(16) .
C23 N1 C10 C17 -3.4(3) .
C9 C10 C17 C18 -57.0(3) .
N1 C10 C17 C18 126.97(18) .
C9 C10 C17 C22 121.5(2) .
N1 C10 C17 C22 -54.5(2) .
C22 C17 C18 C19 0.1(3) .
C10 C17 C18 C19 178.71(16) .
C17 C18 C19 C20 -0.1(3) .
C18 C19 C20 C21 0.1(3) .
C19 C20 C21 C22 -0.2(3) .
C20 C21 C22 C17 0.2(3) .
C18 C17 C22 C21 -0.2(3) .
C10 C17 C22 C21 -178.77(17) .
N1 C8 N2 C9 0.44(19) .
Ag C8 N2 C9 -176.15(13) .
N1 C8 N2 C7 -179.51(15) .
Ag C8 N2 C7 3.9(3) .
C10 C9 N2 C8 -0.62(19) .
C11 C9 N2 C8 -174.31(16) .
C10 C9 N2 C7 179.33(15) .
C11 C9 N2 C7 5.6(3) .
C6 C7 N2 C8 -107.18(19) .
C6 C7 N2 C9 72.9(2) .
C8 N1 C23 C24 -82.3(2) .
C10 N1 C23 C24 97.6(2) .
N1 C23 C24 C25 -6.3(2) .
N1 C23 C24 C29 172.73(15) .
C29 C24 C25 C26 0.0(3) .
C23 C24 C25 C26 179.05(16) .
C24 C25 C26 C27 0.3(3) .
C25 C26 C27 C28 -0.2(3) .
C26 C27 C28 C29 -0.2(3) .
C27 C28 C29 C24 0.6(3) .
C25 C24 C29 C28 -0.5(3) .
C23 C24 C29 C28 -179.53(17) .
C8 Ag O1 C30 33.8(3) .
Ag Ag O1 C30 -109.34(11) 5_655
Ag O1 C30 O2 12.0(2) .
Ag O1 C30 C31 -166.21(13) .
