#------------------------------------------------------------------------------
#$Date: 2016-02-18 17:37:37 +0200 (Thu, 18 Feb 2016) $
#$Revision: 176729 $
#$URL: svn://www.crystallography.net/cod/cif/1/51/85/1518521.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1518521
loop_
_publ_author_name
'Yoshida, Takuya'
'Yasuda, Yuta'
'Nagashima, Eri'
'Arai, Hidekazu'
'Matsunaga, Satoshi'
'Nomiya, Kenji'
_publ_section_title
;
 Various Oxygen-Centered Phosphanegold(I) Cluster Cations Formed by
 Polyoxometalate (POM)-Mediated Clusterization: Effects of POMs and
 Phosphanes
;
_journal_issue                   4
_journal_name_full               Inorganics
_journal_page_first              660
_journal_paper_doi               10.3390/inorganics2040660
_journal_volume                  2
_journal_year                    2014
_chemical_formula_sum            'C168 H168 Au8 Mo12 O46 P8 Si'
_chemical_formula_weight         5925.89
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           148
_symmetry_cell_setting           rhombohedral
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            3
_cell_length_a                   20.3813(7)
_cell_length_b                   20.3813(7)
_cell_length_c                   36.679(2)
_cell_measurement_reflns_used    9493
_cell_measurement_temperature    100
_cell_measurement_theta_max      28.30
_cell_measurement_theta_min      2.37
_cell_volume                     13195.1(10)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100
_diffrn_detector_area_resol_mean 8.366
_diffrn_measured_fraction_theta_full 0.961
_diffrn_measured_fraction_theta_max 0.961
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0332
_diffrn_reflns_av_sigmaI/netI    0.0246
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       48
_diffrn_reflns_limit_l_min       -48
_diffrn_reflns_number            38116
_diffrn_reflns_theta_full        28.30
_diffrn_reflns_theta_max         28.30
_diffrn_reflns_theta_min         1.60
_exptl_absorpt_coefficient_mu    7.619
_exptl_absorpt_correction_T_max  0.3945
_exptl_absorpt_correction_T_min  0.2011
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS; Sheldrick, 1996'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.237
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             8442
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.15
_refine_diff_density_max         2.851
_refine_diff_density_min         -3.609
_refine_diff_density_rms         0.201
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     370
_refine_ls_number_reflns         7015
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.074
_refine_ls_R_factor_all          0.0390
_refine_ls_R_factor_gt           0.0376
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0211P)²+599.8458P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0855
_refine_ls_wR_factor_ref         0.0862
_reflns_number_gt                6730
_reflns_number_total             7015
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            4.cif
_cod_data_source_block           ty039sr-3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Rhombohedral' changed to
'rhombohedral' according to
/usr/data/users/saulius/crontab/automatic-downloads/current/MDPI/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2935 2014-11-11 08:27:57Z andrius 
;
_cod_original_cell_volume        13195.2(11)
_cod_original_sg_symbol_H-M      R-3
_cod_database_code               1518521
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Au1 Au 0.6667 0.3333 0.059533(9) 0.01224(8) Uani 1 3 d S
Au2 Au 0.736337(11) 0.451102(11) 0.002786(5) 0.01053(6) Uani 1 1 d .
C1 C 0.7491(3) 0.3352(3) 0.13930(15) 0.0149(11) Uani 1 1 d .
C2 C 0.7440(4) 0.2944(3) 0.17071(16) 0.0172(11) Uani 1 1 d .
H2 H 0.6959 0.2632 0.1816 0.021 Uiso 1 1 calc R
C3 C 0.8087(4) 0.2989(4) 0.18641(17) 0.0223(13) Uani 1 1 d .
C4 C 0.8785(4) 0.3461(4) 0.17021(18) 0.0221(13) Uani 1 1 d .
H4 H 0.9231 0.3505 0.1808 0.027 Uiso 1 1 calc R
C5 C 0.8842(4) 0.3866(4) 0.13896(18) 0.0253(14) Uani 1 1 d .
H5 H 0.9325 0.4185 0.1284 0.030 Uiso 1 1 calc R
C6 C 0.8196(4) 0.3811(4) 0.12286(17) 0.0227(13) Uani 1 1 d .
H6 H 0.8235 0.4081 0.1011 0.027 Uiso 1 1 calc R
C7 C 0.8023(5) 0.2526(5) 0.2194(2) 0.0359(18) Uani 1 1 d .
H7A H 0.8028 0.2067 0.2118 0.054 Uiso 1 1 calc R
H7B H 0.7548 0.2384 0.2322 0.054 Uiso 1 1 calc R
H7C H 0.8452 0.2824 0.2357 0.054 Uiso 1 1 calc R
C8 C 0.8771(3) 0.6052(3) 0.04405(15) 0.0138(10) Uani 1 1 d .
C9 C 0.8635(3) 0.5840(3) 0.08089(16) 0.0171(11) Uani 1 1 d .
H9 H 0.8129 0.5556 0.0895 0.021 Uiso 1 1 calc R
C10 C 0.9234(4) 0.6040(3) 0.10495(17) 0.0199(12) Uani 1 1 d .
C11 C 0.9969(4) 0.6442(4) 0.09179(17) 0.0216(12) Uani 1 1 d .
H11 H 1.0380 0.6580 0.1081 0.026 Uiso 1 1 calc R
C12 C 1.0115(4) 0.6646(4) 0.05535(17) 0.0224(13) Uani 1 1 d .
H12 H 1.0623 0.6919 0.0469 0.027 Uiso 1 1 calc R
C13 C 0.9514(4) 0.6448(4) 0.03108(17) 0.0201(12) Uani 1 1 d .
H13 H 0.9611 0.6581 0.0060 0.024 Uiso 1 1 calc R
C14 C 0.9086(4) 0.5843(4) 0.14487(17) 0.0288(15) Uani 1 1 d .
H14A H 0.9485 0.5758 0.1547 0.043 Uiso 1 1 calc R
H14B H 0.8593 0.5382 0.1478 0.043 Uiso 1 1 calc R
H14C H 0.9085 0.6261 0.1580 0.043 Uiso 1 1 calc R
C15 C 0.7323(3) 0.5965(3) 0.03715(15) 0.0151(11) Uani 1 1 d .
C16 C 0.6544(4) 0.5480(4) 0.03363(16) 0.0181(11) Uani 1 1 d .
H16 H 0.6363 0.5042 0.0187 0.022 Uiso 1 1 calc R
C17 C 0.6025(4) 0.5623(4) 0.05149(18) 0.0234(13) Uani 1 1 d .
C18 C 0.6305(4) 0.6275(4) 0.07257(18) 0.0267(15) Uani 1 1 d .
H18 H 0.5960 0.6387 0.0846 0.032 Uiso 1 1 calc R
C19 C 0.7069(5) 0.6761(4) 0.0764(2) 0.0304(16) Uani 1 1 d .
H19 H 0.7246 0.7201 0.0911 0.036 Uiso 1 1 calc R
C20 C 0.7590(4) 0.6614(4) 0.05878(18) 0.0231(13) Uani 1 1 d .
H20 H 0.8118 0.6951 0.0615 0.028 Uiso 1 1 calc R
C21 C 0.5188(4) 0.5072(5) 0.0493(2) 0.0347(17) Uani 1 1 d .
H21A H 0.4968 0.4980 0.0738 0.052 Uiso 1 1 calc R
H21B H 0.5104 0.4594 0.0388 0.052 Uiso 1 1 calc R
H21C H 0.4947 0.5284 0.0339 0.052 Uiso 1 1 calc R
C22 C 0.8312(3) 0.6376(3) -0.02547(15) 0.0148(11) Uani 1 1 d .
C23 C 0.8652(4) 0.7162(3) -0.02051(16) 0.0203(12) Uani 1 1 d .
H23 H 0.8739 0.7363 0.0035 0.024 Uiso 1 1 calc R
C24 C 0.8862(4) 0.7649(4) -0.04997(18) 0.0232(13) Uani 1 1 d .
C25 C 0.8719(4) 0.7341(4) -0.08522(16) 0.0203(12) Uani 1 1 d .
H25 H 0.8851 0.7668 -0.1057 0.024 Uiso 1 1 calc R
C26 C 0.8389(4) 0.6571(4) -0.09046(16) 0.0196(12) Uani 1 1 d .
H26 H 0.8299 0.6372 -0.1145 0.024 Uiso 1 1 calc R
C27 C 0.8185(3) 0.6081(3) -0.06068(15) 0.0151(11) Uani 1 1 d .
H27 H 0.7961 0.5551 -0.0644 0.018 Uiso 1 1 calc R
C28 C 0.9244(6) 0.8496(4) -0.0445(2) 0.047(2) Uani 1 1 d .
H28A H 0.9138 0.8604 -0.0199 0.071 Uiso 1 1 calc R
H28B H 0.9050 0.8713 -0.0625 0.071 Uiso 1 1 calc R
H28C H 0.9792 0.8720 -0.0477 0.071 Uiso 1 1 calc R
Mo1 Mo 0.77933(3) 0.36565(3) 0.911431(12) 0.01287(10) Uani 1 1 d .
Mo2 Mo 0.82886(3) 0.31415(4) 0.82814(2) 0.03022(16) Uani 1 1 d .
O1 O 0.6667 0.3333 0.00210(17) 0.0100(12) Uani 1 3 d S
O2 O 0.8316(4) 0.3867(3) 0.94896(19) 0.0471(18) Uani 1 1 d .
O3 O 0.9026(3) 0.3005(3) 0.82882(12) 0.0264(11) Uani 1 1 d .
O4 O 0.6964(3) 0.2778(3) 0.92447(18) 0.0341(13) Uani 1 1 d .
O5 O 0.8396(6) 0.4643(4) 0.8851(2) 0.099(4) Uani 1 1 d .
O6 O 0.8727(7) 0.4156(4) 0.8248(2) 0.102(4) Uani 1 1 d .
O7 O 0.8212(6) 0.3261(4) 0.8821(2) 0.093(4) Uani 1 1 d .
O8 O 0.7534(4) 0.3668(4) 0.8515(2) 0.0543(17) Uani 1 1 d .
O9 O 0.6667 0.3333 0.8743(3) 0.053(3) Uani 1 3 d S
P1 P 0.6667 0.3333 0.11987(6) 0.0122(4) Uani 1 3 d S
P2 P 0.79718(8) 0.57448(8) 0.01355(4) 0.0122(3) Uani 1 1 d .
Si1 Si 0.6667 0.3333 0.8333 0.0118(7) Uani 1 6 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mo Mo -1.6832 0.6857 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Au1 P1 180.0 . .
O1 Au1 Au2 45.122(6) . .
P1 Au1 Au2 134.878(6) . .
O1 Au1 Au2 45.120(6) . 3_665
P1 Au1 Au2 134.880(6) . 3_665
Au2 Au1 Au2 75.709(10) . 3_665
O1 Au1 Au2 45.121(6) . 2_655
P1 Au1 Au2 134.879(6) . 2_655
Au2 Au1 Au2 75.710(10) . 2_655
Au2 Au1 Au2 75.709(10) 3_665 2_655
O1 Au2 P2 168.44(15) . .
O1 Au2 Au1 45.57(17) . .
P2 Au2 Au1 124.53(4) . .
C2 C1 C6 120.0(6) . .
C2 C1 P1 121.4(5) . .
C6 C1 P1 118.5(5) . .
C1 C2 C3 120.9(6) . .
C1 C2 H2 119.5 . .
C3 C2 H2 119.5 . .
C4 C3 C2 118.3(6) . .
C4 C3 C7 121.0(6) . .
C2 C3 C7 120.6(6) . .
C5 C4 C3 121.2(6) . .
C5 C4 H4 119.4 . .
C3 C4 H4 119.4 . .
C4 C5 C6 120.6(6) . .
C4 C5 H5 119.7 . .
C6 C5 H5 119.7 . .
C5 C6 C1 118.9(6) . .
C5 C6 H6 120.5 . .
C1 C6 H6 120.5 . .
C3 C7 H7A 109.5 . .
C3 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C3 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C13 C8 C9 119.8(5) . .
C13 C8 P2 121.2(4) . .
C9 C8 P2 118.9(4) . .
C10 C9 C8 120.7(6) . .
C10 C9 H9 119.7 . .
C8 C9 H9 119.7 . .
C11 C10 C9 118.9(6) . .
C11 C10 C14 120.6(6) . .
C9 C10 C14 120.5(6) . .
C10 C11 C12 121.3(6) . .
C10 C11 H11 119.3 . .
C12 C11 H11 119.3 . .
C11 C12 C13 120.0(6) . .
C11 C12 H12 120.0 . .
C13 C12 H12 120.0 . .
C8 C13 C12 119.3(6) . .
C8 C13 H13 120.3 . .
C12 C13 H13 120.3 . .
C10 C14 H14A 109.5 . .
C10 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C10 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 C20 119.3(6) . .
C16 C15 P2 119.5(4) . .
C20 C15 P2 121.2(5) . .
C17 C16 C15 121.4(6) . .
C17 C16 H16 119.3 . .
C15 C16 H16 119.3 . .
C18 C17 C16 118.1(6) . .
C18 C17 C21 120.9(6) . .
C16 C17 C21 121.0(6) . .
C19 C18 C17 121.4(6) . .
C19 C18 H18 119.3 . .
C17 C18 H18 119.3 . .
C18 C19 C20 120.5(6) . .
C18 C19 H19 119.7 . .
C20 C19 H19 119.7 . .
C19 C20 C15 119.2(6) . .
C19 C20 H20 120.4 . .
C15 C20 H20 120.4 . .
C17 C21 H21A 109.5 . .
C17 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C17 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C27 C22 C23 119.5(5) . .
C27 C22 P2 120.2(4) . .
C23 C22 P2 120.2(4) . .
C24 C23 C22 121.1(6) . .
C24 C23 H23 119.4 . .
C22 C23 H23 119.4 . .
C23 C24 C25 118.7(6) . .
C23 C24 C28 121.0(6) . .
C25 C24 C28 120.4(6) . .
C26 C25 C24 120.8(6) . .
C26 C25 H25 119.6 . .
C24 C25 H25 119.6 . .
C25 C26 C27 120.5(5) . .
C25 C26 H26 119.8 . .
C27 C26 H26 119.8 . .
C22 C27 C26 119.5(6) . .
C22 C27 H27 120.3 . .
C26 C27 H27 120.3 . .
C24 C28 H28A 109.5 . .
C24 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C24 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
O2 Mo1 O7 103.1(5) . .
O2 Mo1 O4 101.4(3) . .
O7 Mo1 O4 97.7(3) . .
O2 Mo1 O4 97.7(3) . 2_655
O7 Mo1 O4 157.0(4) . 2_655
O4 Mo1 O4 87.9(3) . 2_655
O2 Mo1 O5 98.5(4) . .
O7 Mo1 O5 88.3(2) . .
O4 Mo1 O5 157.3(4) . .
O4 Mo1 O5 78.8(2) 2_655 .
O2 Mo1 O8 157.7(3) . .
O7 Mo1 O8 65.6(4) . .
O4 Mo1 O8 99.2(3) . .
O4 Mo1 O8 91.4(3) 2_655 .
O5 Mo1 O8 63.3(4) . .
O2 Mo1 O9 157.0(4) . .
O7 Mo1 O9 97.9(5) . .
O4 Mo1 O9 66.2(2) . .
O4 Mo1 O9 63.9(2) 2_655 .
O5 Mo1 O9 91.4(4) . .
O8 Mo1 O9 43.4(3) . .
O3 Mo2 O5 101.8(4) . 17_556
O3 Mo2 O6 102.9(4) . .
O5 Mo2 O6 98.1(4) 17_556 .
O3 Mo2 O6 98.1(4) . 17_556
O5 Mo2 O6 88.2(3) 17_556 17_556
O6 Mo2 O6 156.3(6) . 17_556
O3 Mo2 O7 97.9(3) . .
O5 Mo2 O7 157.9(5) 17_556 .
O6 Mo2 O7 87.2(3) . .
O6 Mo2 O7 79.0(4) 17_556 .
O3 Mo2 O8 154.7(3) . 17_556
O5 Mo2 O8 62.9(4) 17_556 17_556
O6 Mo2 O8 99.3(4) . 17_556
O6 Mo2 O8 63.3(3) 17_556 17_556
O7 Mo2 O8 95.1(4) . 17_556
O3 Mo2 O8 153.5(2) . .
O5 Mo2 O8 103.2(4) 17_556 .
O6 Mo2 O8 64.9(3) . .
O6 Mo2 O8 91.4(4) 17_556 .
O7 Mo2 O8 59.6(3) . .
O8 Mo2 O8 49.9(3) 17_556 .
Au2 O1 Au2 119.985(8) 3_665 .
Au2 O1 Au2 119.986(8) 3_665 2_655
Au2 O1 Au2 119.986(8) . 2_655
Au2 O1 Au1 89.32(17) 3_665 .
Au2 O1 Au1 89.31(17) . .
Au2 O1 Au1 89.32(17) 2_655 .
Mo1 O4 Mo1 137.3(3) . 3_665
Mo2 O5 Mo1 135.6(6) 18_546 .
Mo2 O6 Mo2 137.6(5) . 18_546
Mo1 O7 Mo2 136.8(6) . .
Si1 O8 O9 51.8(4) . .
Si1 O8 Mo1 125.7(4) . .
O9 O8 Mo1 74.2(4) . .
Si1 O8 Mo2 118.2(4) . 18_546
O9 O8 Mo2 128.4(4) . 18_546
Mo1 O8 Mo2 98.0(3) . 18_546
Si1 O8 Mo2 116.8(4) . .
O9 O8 Mo2 137.1(4) . .
Mo1 O8 Mo2 97.8(3) . .
Mo2 O8 Mo2 94.2(3) 18_546 .
Si1 O9 O8 61.5(4) . .
Si1 O9 O8 61.5(4) . 3_665
O8 O9 O8 99.2(5) . 3_665
Si1 O9 O8 61.5(4) . 2_655
O8 O9 O8 99.2(5) . 2_655
O8 O9 O8 99.2(5) 3_665 2_655
Si1 O9 Mo1 123.6(2) . 3_665
O8 O9 Mo1 134.2(3) . 3_665
O8 O9 Mo1 62.4(3) 3_665 3_665
O8 O9 Mo1 123.9(3) 2_655 3_665
Si1 O9 Mo1 123.6(2) . 2_655
O8 O9 Mo1 123.9(3) . 2_655
O8 O9 Mo1 134.2(3) 3_665 2_655
O8 O9 Mo1 62.4(3) 2_655 2_655
Mo1 O9 Mo1 92.3(3) 3_665 2_655
Si1 O9 Mo1 123.6(2) . .
O8 O9 Mo1 62.4(3) . .
O8 O9 Mo1 123.9(3) 3_665 .
O8 O9 Mo1 134.2(3) 2_655 .
Mo1 O9 Mo1 92.3(3) 3_665 .
Mo1 O9 Mo1 92.3(3) 2_655 .
C1 P1 C1 105.5(2) 3_665 .
C1 P1 C1 105.5(2) 3_665 2_655
C1 P1 C1 105.5(2) . 2_655
C1 P1 Au1 113.21(19) 3_665 .
C1 P1 Au1 113.21(19) . .
C1 P1 Au1 113.21(19) 2_655 .
C8 P2 C15 105.1(3) . .
C8 P2 C22 106.5(3) . .
C15 P2 C22 105.5(3) . .
C8 P2 Au2 113.54(19) . .
C15 P2 Au2 107.6(2) . .
C22 P2 Au2 117.61(19) . .
O9 Si1 O9 179.994(2) 16_656 .
O9 Si1 O8 113.3(3) 16_656 3_665
O9 Si1 O8 66.7(3) . 3_665
O9 Si1 O8 113.3(3) 16_656 .
O9 Si1 O8 66.7(3) . .
O8 Si1 O8 105.4(3) 3_665 .
O9 Si1 O8 113.3(3) 16_656 2_655
O9 Si1 O8 66.7(3) . 2_655
O8 Si1 O8 105.4(3) 3_665 2_655
O8 Si1 O8 105.4(3) . 2_655
O9 Si1 O8 66.7(3) 16_656 16_656
O9 Si1 O8 113.3(3) . 16_656
O8 Si1 O8 74.6(3) 3_665 16_656
O8 Si1 O8 180.0(6) . 16_656
O8 Si1 O8 74.6(3) 2_655 16_656
O9 Si1 O8 66.7(3) 16_656 18_546
O9 Si1 O8 113.3(3) . 18_546
O8 Si1 O8 179.992(2) 3_665 18_546
O8 Si1 O8 74.6(3) . 18_546
O8 Si1 O8 74.6(3) 2_655 18_546
O8 Si1 O8 105.4(3) 16_656 18_546
O9 Si1 O8 66.7(3) 16_656 17_556
O9 Si1 O8 113.3(3) . 17_556
O8 Si1 O8 74.6(3) 3_665 17_556
O8 Si1 O8 74.6(3) . 17_556
O8 Si1 O8 179.993(5) 2_655 17_556
O8 Si1 O8 105.4(3) 16_656 17_556
O8 Si1 O8 105.4(3) 18_546 17_556
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 O1 2.106(6) .
Au1 P1 2.213(2) .
Au1 Au2 2.9499(3) .
Au1 Au2 2.9499(3) 3_665
Au1 Au2 2.9500(3) 2_655
Au2 O1 2.0905(2) .
Au2 P2 2.2132(14) .
C1 C2 1.393(8) .
C1 C6 1.400(8) .
C1 P1 1.808(6) .
C2 C3 1.400(9) .
C2 H2 0.9500 .
C3 C4 1.392(10) .
C3 C7 1.500(9) .
C4 C5 1.383(10) .
C4 H4 0.9500 .
C5 C6 1.395(9) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 C13 1.396(8) .
C8 C9 1.403(8) .
C8 P2 1.811(6) .
C9 C10 1.392(8) .
C9 H9 0.9500 .
C10 C11 1.385(9) .
C10 C14 1.509(8) .
C11 C12 1.387(9) .
C11 H11 0.9500 .
C12 C13 1.400(9) .
C12 H12 0.9500 .
C13 H13 0.9500 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 C16 1.396(9) .
C15 C20 1.398(8) .
C15 P2 1.814(6) .
C16 C17 1.393(9) .
C16 H16 0.9500 .
C17 C18 1.390(10) .
C17 C21 1.504(10) .
C18 C19 1.372(12) .
C18 H18 0.9500 .
C19 C20 1.396(10) .
C19 H19 0.9500 .
C20 H20 0.9500 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 C27 1.393(8) .
C22 C23 1.403(8) .
C22 P2 1.815(6) .
C23 C24 1.382(9) .
C23 H23 0.9500 .
C24 C25 1.402(9) .
C24 C28 1.511(10) .
C25 C26 1.377(9) .
C25 H25 0.9500 .
C26 C27 1.395(8) .
C26 H26 0.9500 .
C27 H27 0.9500 .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
Mo1 O2 1.660(5) .
Mo1 O7 1.795(6) .
Mo1 O4 1.806(5) .
Mo1 O4 2.002(5) 2_655
Mo1 O5 2.004(6) .
Mo1 O8 2.265(7) .
Mo1 O9 2.460(7) .
Mo2 O3 1.660(5) .
Mo2 O5 1.800(8) 17_556
Mo2 O6 1.800(7) .
Mo2 O6 1.994(6) 17_556
Mo2 O7 2.009(8) .
Mo2 O8 2.401(8) 17_556
Mo2 O8 2.429(7) .
O1 Au2 2.0904(2) 3_665
O1 Au2 2.0905(2) 2_655
O4 Mo1 2.002(5) 3_665
O5 Mo2 1.800(8) 18_546
O6 Mo2 1.994(6) 18_546
O8 Si1 1.682(7) .
O8 O9 1.757(9) .
O8 Mo2 2.401(8) 18_546
O9 Si1 1.502(12) .
O9 O8 1.757(9) 3_665
O9 O8 1.757(9) 2_655
O9 Mo1 2.459(6) 3_665
O9 Mo1 2.460(6) 2_655
P1 C1 1.808(6) 3_665
P1 C1 1.808(6) 2_655
Si1 O9 1.502(12) 16_656
Si1 O8 1.682(7) 3_665
Si1 O8 1.682(7) 2_655
Si1 O8 1.682(7) 16_656
Si1 O8 1.682(7) 18_546
Si1 O8 1.682(7) 17_556
