#------------------------------------------------------------------------------
#$Date: 2016-03-24 17:31:00 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179688 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/10/7001053.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7001053
loop_
_publ_author_name
'Hoshino, Manabu'
'Uekusa, Hidehiro'
'Sonoda, Shintaro'
'Otsuka, Takuhiro'
'Kaizu, Youkoh'
_publ_section_title
;
 Photocrystallographic analysis of [AuCl(PPh3)2] for elucidation of the
 crystal packing effect on the photophysical properties
;
_journal_issue                   16
_journal_name_full               'Dalton Transactions'
_journal_page_first              3085
_journal_page_last               3091
_journal_paper_doi               10.1039/b820066a
_journal_year                    2009
_chemical_formula_sum            'C36 H30 Au Cl P2'
_chemical_formula_weight         756.96
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.1999(9)
_cell_angle_beta                 95.3789(8)
_cell_angle_gamma                109.5993(8)
_cell_formula_units_Z            2
_cell_length_a                   10.8666(2)
_cell_length_b                   11.83540(10)
_cell_length_c                   14.1974(2)
_cell_measurement_temperature    156(2)
_cell_volume                     1526.30(4)
_computing_cell_refinement       'HKL Research, Inc. HKL-2000'
_computing_data_collection       'Rigaku RAPID AUTO'
_computing_data_reduction        'HKL Research, Inc. HKL-2000'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 1998)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR2002 (Giacovazzo, 2003)'
_diffrn_ambient_temperature      156(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID Imaging Plate'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Rigaku rotating anode Ultrax18'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.021
_diffrn_reflns_av_sigmaI/netI    0.0156
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            45112
_diffrn_reflns_theta_full        32.31
_diffrn_reflns_theta_max         32.31
_diffrn_reflns_theta_min         1.62
_exptl_absorpt_coefficient_mu    5.036
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.752
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'HKL SCALEPACK (Otwinowski & Minor, 1997)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.647
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             744
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.940
_refine_diff_density_min         -0.675
_refine_diff_density_rms         0.083
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.171
_refine_ls_hydrogen_treatment    refxyz
_refine_ls_matrix_type           full
_refine_ls_number_parameters     451
_refine_ls_number_reflns         10803
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.171
_refine_ls_R_factor_all          0.0142
_refine_ls_R_factor_gt           0.0140
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+1.5259P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0367
_refine_ls_wR_factor_ref         0.0399
_reflns_number_gt                10735
_reflns_number_total             10803
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b820066a.txt
_cod_data_source_block           156Koff
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7001053
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.211187(5) 0.245511(5) 0.275436(4) 0.01776(2) Uani 1 1 d . . .
P1 P 0.30610(4) 0.09646(4) 0.27610(3) 0.01667(6) Uani 1 1 d . . .
C111 C 0.25529(14) 0.00347(14) 0.35140(11) 0.0174(2) Uani 1 1 d . . .
C112 C 0.34094(16) -0.04302(17) 0.38976(14) 0.0232(3) Uani 1 1 d . . .
H112 H 0.429(2) -0.026(2) 0.3744(19) 0.028 Uiso 1 1 d . . .
C113 C 0.29961(18) -0.11469(18) 0.44680(15) 0.0265(3) Uani 1 1 d . . .
H113 H 0.355(2) -0.148(2) 0.471(2) 0.032 Uiso 1 1 d . . .
C114 C 0.17293(18) -0.13988(17) 0.46648(14) 0.0255(3) Uani 1 1 d . . .
H114 H 0.143(2) -0.190(2) 0.5054(19) 0.031 Uiso 1 1 d . . .
C115 C 0.08759(17) -0.09374(17) 0.42881(14) 0.0244(3) Uani 1 1 d . . .
H115 H -0.001(2) -0.112(2) 0.4412(19) 0.029 Uiso 1 1 d . . .
C116 C 0.12811(15) -0.02177(15) 0.37177(13) 0.0202(3) Uani 1 1 d . . .
H116 H 0.070(2) 0.011(2) 0.3480(18) 0.024 Uiso 1 1 d . . .
C121 C 0.28915(15) -0.02769(16) 0.14321(12) 0.0203(3) Uani 1 1 d . . .
C122 C 0.2788(3) -0.15627(19) 0.12000(15) 0.0367(4) Uani 1 1 d . . .
H122 H 0.273(3) -0.186(3) 0.171(2) 0.044 Uiso 1 1 d . . .
C123 C 0.2729(3) -0.2443(2) 0.01792(18) 0.0465(6) Uani 1 1 d . . .
H123 H 0.262(3) -0.337(3) 0.003(3) 0.056 Uiso 1 1 d . . .
C124 C 0.2763(3) -0.2051(2) -0.06147(16) 0.0419(5) Uani 1 1 d . . .
H124 H 0.271(3) -0.262(3) -0.128(2) 0.050 Uiso 1 1 d . . .
C125 C 0.2858(3) -0.0779(3) -0.03906(17) 0.0473(6) Uani 1 1 d . . .
H125 H 0.296(3) -0.044(3) -0.086(3) 0.057 Uiso 1 1 d . . .
C126 C 0.2917(2) 0.0107(2) 0.06241(15) 0.0357(4) Uani 1 1 d . . .
H126 H 0.298(3) 0.099(3) 0.076(2) 0.043 Uiso 1 1 d . . .
C131 C 0.48762(15) 0.19052(15) 0.33290(12) 0.0185(2) Uani 1 1 d . . .
C132 C 0.58253(17) 0.15009(18) 0.28570(13) 0.0252(3) Uani 1 1 d . . .
H132 H 0.551(2) 0.067(2) 0.217(2) 0.030 Uiso 1 1 d . . .
C133 C 0.72014(17) 0.2287(2) 0.33257(15) 0.0297(3) Uani 1 1 d . . .
H133 H 0.787(3) 0.199(3) 0.298(2) 0.036 Uiso 1 1 d . . .
C134 C 0.76344(17) 0.34715(19) 0.42577(15) 0.0287(3) Uani 1 1 d . . .
H134 H 0.858(3) 0.399(3) 0.457(2) 0.034 Uiso 1 1 d . . .
C135 C 0.66955(18) 0.38758(18) 0.47339(14) 0.0286(3) Uani 1 1 d . . .
H135 H 0.695(3) 0.470(3) 0.534(2) 0.034 Uiso 1 1 d . . .
C136 C 0.53204(17) 0.30969(17) 0.42723(13) 0.0246(3) Uani 1 1 d . . .
H136 H 0.469(2) 0.337(2) 0.4588(19) 0.029 Uiso 1 1 d . . .
P2 P 0.23103(4) 0.39023(4) 0.20032(3) 0.01816(6) Uani 1 1 d . . .
C211 C 0.39812(15) 0.52850(16) 0.26032(12) 0.0199(3) Uani 1 1 d . . .
C212 C 0.50562(18) 0.5034(2) 0.29568(17) 0.0307(4) Uani 1 1 d . . .
H212 H 0.490(3) 0.413(3) 0.281(2) 0.037 Uiso 1 1 d . . .
C213 C 0.63372(19) 0.6072(2) 0.34729(18) 0.0361(4) Uani 1 1 d . . .
H213 H 0.703(3) 0.587(3) 0.368(2) 0.043 Uiso 1 1 d . . .
C214 C 0.65609(18) 0.7358(2) 0.36293(16) 0.0334(4) Uani 1 1 d . . .
H214 H 0.741(3) 0.803(3) 0.396(2) 0.040 Uiso 1 1 d . . .
C215 C 0.55135(19) 0.76143(19) 0.32703(17) 0.0341(4) Uani 1 1 d . . .
H215 H 0.565(3) 0.849(3) 0.335(2) 0.041 Uiso 1 1 d . . .
C216 C 0.42197(18) 0.65863(17) 0.27646(15) 0.0278(3) Uani 1 1 d . . .
H216 H 0.348(3) 0.676(3) 0.249(2) 0.033 Uiso 1 1 d . . .
C221 C 0.11137(15) 0.46783(15) 0.20663(12) 0.0198(2) Uani 1 1 d . . .
C222 C 0.09349(18) 0.52434(19) 0.13938(14) 0.0269(3) Uani 1 1 d . . .
H222 H 0.145(2) 0.519(2) 0.086(2) 0.032 Uiso 1 1 d . . .
C223 C 0.0048(2) 0.58749(19) 0.14951(15) 0.0301(3) Uani 1 1 d . . .
H223 H -0.006(3) 0.623(3) 0.102(2) 0.036 Uiso 1 1 d . . .
C224 C -0.06735(19) 0.59312(19) 0.22564(16) 0.0295(3) Uani 1 1 d . . .
H224 H -0.131(3) 0.631(3) 0.228(2) 0.035 Uiso 1 1 d . . .
C225 C -0.05058(19) 0.53665(19) 0.29225(16) 0.0295(3) Uani 1 1 d . . .
H225 H -0.101(3) 0.542(3) 0.345(2) 0.035 Uiso 1 1 d . . .
C226 C 0.03832(17) 0.47364(17) 0.28254(13) 0.0235(3) Uani 1 1 d . . .
H226 H 0.048(2) 0.432(2) 0.3236(19) 0.028 Uiso 1 1 d . . .
C231 C 0.22066(16) 0.30703(17) 0.05948(12) 0.0225(3) Uani 1 1 d . . .
C232 C 0.3241(2) 0.3491(3) 0.01515(17) 0.0464(6) Uani 1 1 d . . .
H232 H 0.399(3) 0.419(3) 0.052(3) 0.056 Uiso 1 1 d . . .
C233 C 0.3127(3) 0.2762(3) -0.0920(2) 0.0617(9) Uani 1 1 d . . .
H233 H 0.385(4) 0.304(4) -0.118(3) 0.074 Uiso 1 1 d . . .
C234 C 0.1998(3) 0.1603(3) -0.15509(17) 0.0454(5) Uani 1 1 d . . .
H234 H 0.197(3) 0.113(3) -0.224(3) 0.054 Uiso 1 1 d . . .
C235 C 0.0956(2) 0.1179(2) -0.11179(16) 0.0400(5) Uani 1 1 d . . .
H235 H 0.019(3) 0.038(3) -0.151(2) 0.048 Uiso 1 1 d . . .
C236 C 0.1054(2) 0.1908(2) -0.00526(15) 0.0338(4) Uani 1 1 d . . .
H236 H 0.033(3) 0.160(3) 0.024(2) 0.041 Uiso 1 1 d . . .
Cl1 Cl 0.06777(4) 0.26590(4) 0.40795(4) 0.02835(8) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P2 Au1 P1 136.754(13) . . ?
P2 Au1 Cl1 114.205(14) . . ?
P1 Au1 Cl1 108.686(13) . . ?
P2 Au1 Au1 80.020(10) . 2 ?
P1 Au1 Au1 89.716(9) . 2 ?
Cl1 Au1 Au1 111.377(11) . 2 ?
C111 P1 C131 103.92(7) . . ?
C111 P1 C121 106.10(7) . . ?
C131 P1 C121 104.38(7) . . ?
C111 P1 Au1 119.56(5) . . ?
C131 P1 Au1 108.44(5) . . ?
C121 P1 Au1 113.07(5) . . ?
C116 C111 C112 119.29(14) . . ?
C116 C111 P1 119.33(11) . . ?
C112 C111 P1 121.38(11) . . ?
C113 C112 C111 120.39(15) . . ?
C113 C112 H112 121.1(14) . . ?
C111 C112 H112 118.5(14) . . ?
C114 C113 C112 120.06(15) . . ?
C114 C113 H113 119.2(15) . . ?
C112 C113 H113 120.7(16) . . ?
C115 C114 C113 119.82(15) . . ?
C115 C114 H114 119.3(15) . . ?
C113 C114 H114 120.9(15) . . ?
C114 C115 C116 120.54(15) . . ?
C114 C115 H115 120.0(15) . . ?
C116 C115 H115 119.5(15) . . ?
C115 C116 C111 119.89(14) . . ?
C115 C116 H116 119.6(14) . . ?
C111 C116 H116 120.5(14) . . ?
C122 C121 C126 118.69(16) . . ?
C122 C121 P1 123.17(13) . . ?
C126 C121 P1 118.10(13) . . ?
C121 C122 C123 120.40(19) . . ?
C121 C122 H122 120.9(18) . . ?
C123 C122 H122 118.7(18) . . ?
C124 C123 C122 120.5(2) . . ?
C124 C123 H123 120.7(19) . . ?
C122 C123 H123 118.8(19) . . ?
C125 C124 C123 119.38(19) . . ?
C125 C124 H124 120(2) . . ?
C123 C124 H124 121(2) . . ?
C124 C125 C126 120.6(2) . . ?
C124 C125 H125 124(2) . . ?
C126 C125 H125 116(2) . . ?
C125 C126 C121 120.40(19) . . ?
C125 C126 H126 118.9(17) . . ?
C121 C126 H126 120.7(17) . . ?
C136 C131 C132 119.47(14) . . ?
C136 C131 P1 117.45(12) . . ?
C132 C131 P1 123.07(12) . . ?
C133 C132 C131 119.95(16) . . ?
C133 C132 H132 120.1(14) . . ?
C131 C132 H132 119.9(14) . . ?
C134 C133 C132 120.25(16) . . ?
C134 C133 H133 120.5(15) . . ?
C132 C133 H133 119.3(15) . . ?
C133 C134 C135 120.08(16) . . ?
C133 C134 H134 118.8(15) . . ?
C135 C134 H134 121.1(16) . . ?
C136 C135 C134 120.05(16) . . ?
C136 C135 H135 117.4(16) . . ?
C134 C135 H135 122.4(16) . . ?
C135 C136 C131 120.20(16) . . ?
C135 C136 H136 120.3(15) . . ?
C131 C136 H136 119.5(15) . . ?
C221 P2 C231 104.29(7) . . ?
C221 P2 C211 105.87(7) . . ?
C231 P2 C211 105.55(7) . . ?
C221 P2 Au1 119.53(5) . . ?
C231 P2 Au1 111.19(5) . . ?
C211 P2 Au1 109.42(5) . . ?
C216 C211 C212 118.72(15) . . ?
C216 C211 P2 123.04(12) . . ?
C212 C211 P2 118.18(13) . . ?
C213 C212 C211 120.45(18) . . ?
C213 C212 H212 121.0(16) . . ?
C211 C212 H212 118.5(16) . . ?
C214 C213 C212 120.30(18) . . ?
C214 C213 H213 121.1(18) . . ?
C212 C213 H213 118.6(18) . . ?
C215 C214 C213 119.80(17) . . ?
C215 C214 H214 120.8(18) . . ?
C213 C214 H214 119.4(18) . . ?
C214 C215 C216 120.47(19) . . ?
C214 C215 H215 121.5(17) . . ?
C216 C215 H215 118.1(17) . . ?
C211 C216 C215 120.24(17) . . ?
C211 C216 H216 119.1(15) . . ?
C215 C216 H216 120.6(15) . . ?
C226 C221 C222 119.46(15) . . ?
C226 C221 P2 118.66(12) . . ?
C222 C221 P2 121.86(12) . . ?
C223 C222 C221 120.10(16) . . ?
C223 C222 H222 121.2(15) . . ?
C221 C222 H222 118.7(15) . . ?
C224 C223 C222 120.03(16) . . ?
C224 C223 H223 122.3(16) . . ?
C222 C223 H223 117.7(16) . . ?
C225 C224 C223 120.14(16) . . ?
C225 C224 H224 121.6(16) . . ?
C223 C224 H224 118.2(16) . . ?
C224 C225 C226 120.00(17) . . ?
C224 C225 H225 119.1(16) . . ?
C226 C225 H225 120.9(16) . . ?
C221 C226 C225 120.26(15) . . ?
C221 C226 H226 118.1(15) . . ?
C225 C226 H226 121.6(15) . . ?
C232 C231 C236 118.71(17) . . ?
C232 C231 P2 123.36(14) . . ?
C236 C231 P2 117.84(13) . . ?
C231 C232 C233 120.4(2) . . ?
C231 C232 H232 122(2) . . ?
C233 C232 H232 117(2) . . ?
C234 C233 C232 120.7(2) . . ?
C234 C233 H233 121(2) . . ?
C232 C233 H233 118(2) . . ?
C233 C234 C235 119.4(2) . . ?
C233 C234 H234 119(2) . . ?
C235 C234 H234 122(2) . . ?
C234 C235 C236 120.4(2) . . ?
C234 C235 H235 122.3(18) . . ?
C236 C235 H235 117.2(18) . . ?
C235 C236 C231 120.48(18) . . ?
C235 C236 H236 119.7(16) . . ?
C231 C236 H236 119.8(16) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 P2 2.3134(4) . ?
Au1 P1 2.3254(4) . ?
Au1 Cl1 2.5438(4) . ?
Au1 Au1 7.45465(18) 2 ?
P1 C111 1.8135(14) . ?
P1 C131 1.8171(15) . ?
P1 C121 1.8226(15) . ?
C111 C116 1.396(2) . ?
C111 C112 1.397(2) . ?
C112 C113 1.390(2) . ?
C112 H112 0.97(2) . ?
C113 C114 1.387(2) . ?
C113 H113 0.93(3) . ?
C114 C115 1.386(2) . ?
C114 H114 0.97(2) . ?
C115 C116 1.391(2) . ?
C115 H115 0.96(2) . ?
C116 H116 0.94(2) . ?
C121 C122 1.386(2) . ?
C121 C126 1.389(2) . ?
C122 C123 1.392(3) . ?
C122 H122 0.93(3) . ?
C123 C124 1.376(3) . ?
C123 H123 0.99(3) . ?
C124 C125 1.375(3) . ?
C124 H124 0.90(3) . ?
C125 C126 1.388(3) . ?
C125 H125 0.91(3) . ?
C126 H126 0.96(3) . ?
C131 C136 1.396(2) . ?
C131 C132 1.396(2) . ?
C132 C133 1.392(2) . ?
C132 H132 1.00(2) . ?
C133 C134 1.385(3) . ?
C133 H133 0.99(3) . ?
C134 C135 1.389(3) . ?
C134 H134 0.95(3) . ?
C135 C136 1.389(2) . ?
C135 H135 0.94(3) . ?
C136 H136 0.93(2) . ?
P2 C221 1.8168(16) . ?
P2 C231 1.8201(16) . ?
P2 C211 1.8217(16) . ?
C211 C216 1.391(2) . ?
C211 C212 1.394(2) . ?
C212 C213 1.391(3) . ?
C212 H212 0.95(3) . ?
C213 C214 1.378(3) . ?
C213 H213 0.91(3) . ?
C214 C215 1.375(3) . ?
C214 H214 0.92(3) . ?
C215 C216 1.395(2) . ?
C215 H215 0.96(3) . ?
C216 H216 0.98(3) . ?
C221 C226 1.391(2) . ?
C221 C222 1.397(2) . ?
C222 C223 1.390(3) . ?
C222 H222 0.98(3) . ?
C223 C224 1.387(3) . ?
C223 H223 0.93(3) . ?
C224 C225 1.386(3) . ?
C224 H224 0.94(3) . ?
C225 C226 1.391(2) . ?
C225 H225 0.96(3) . ?
C226 H226 0.92(2) . ?
C231 C232 1.382(3) . ?
C231 C236 1.392(2) . ?
C232 C233 1.390(3) . ?
C232 H232 0.87(3) . ?
C233 C234 1.373(4) . ?
C233 H233 0.92(4) . ?
C234 C235 1.380(3) . ?
C234 H234 0.90(3) . ?
C235 C236 1.387(3) . ?
C235 H235 0.93(3) . ?
C236 H236 0.95(3) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C114 H114 Cl1 0.97(2) 2.75(2) 3.5491(17) 140.6(19) 2_556
C116 H116 Cl1 0.94(2) 2.81(2) 3.5312(16) 134.6(17) .
C226 H226 Cl1 0.92(2) 2.73(2) 3.6314(17) 169(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
P2 Au1 P1 C111 179.56(5) . . . . ?
Cl1 Au1 P1 C111 7.13(6) . . . . ?
Au1 Au1 P1 C111 -105.40(6) 2 . . . ?
P2 Au1 P1 C131 60.83(5) . . . . ?
Cl1 Au1 P1 C131 -111.60(5) . . . . ?
Au1 Au1 P1 C131 135.87(5) 2 . . . ?
P2 Au1 P1 C121 -54.42(6) . . . . ?
Cl1 Au1 P1 C121 133.14(5) . . . . ?
Au1 Au1 P1 C121 20.62(5) 2 . . . ?
C131 P1 C111 C116 146.68(12) . . . . ?
C121 P1 C111 C116 -103.58(13) . . . . ?
Au1 P1 C111 C116 25.66(14) . . . . ?
C131 P1 C111 C112 -33.09(15) . . . . ?
C121 P1 C111 C112 76.65(14) . . . . ?
Au1 P1 C111 C112 -154.11(11) . . . . ?
C116 C111 C112 C113 0.6(2) . . . . ?
P1 C111 C112 C113 -179.66(13) . . . . ?
C111 C112 C113 C114 -0.4(3) . . . . ?
C112 C113 C114 C115 0.2(3) . . . . ?
C113 C114 C115 C116 -0.3(3) . . . . ?
C114 C115 C116 C111 0.5(2) . . . . ?
C112 C111 C116 C115 -0.7(2) . . . . ?
P1 C111 C116 C115 179.57(12) . . . . ?
C111 P1 C121 C122 -16.81(18) . . . . ?
C131 P1 C121 C122 92.61(17) . . . . ?
Au1 P1 C121 C122 -149.73(15) . . . . ?
C111 P1 C121 C126 165.60(15) . . . . ?
C131 P1 C121 C126 -84.98(16) . . . . ?
Au1 P1 C121 C126 32.68(16) . . . . ?
C126 C121 C122 C123 0.8(3) . . . . ?
P1 C121 C122 C123 -176.77(19) . . . . ?
C121 C122 C123 C124 -0.5(4) . . . . ?
C122 C123 C124 C125 0.2(4) . . . . ?
C123 C124 C125 C126 -0.2(4) . . . . ?
C124 C125 C126 C121 0.5(4) . . . . ?
C122 C121 C126 C125 -0.8(3) . . . . ?
P1 C121 C126 C125 176.9(2) . . . . ?
C111 P1 C131 C136 -81.01(13) . . . . ?
C121 P1 C131 C136 167.98(13) . . . . ?
Au1 P1 C131 C136 47.19(13) . . . . ?
C111 P1 C131 C132 100.11(14) . . . . ?
C121 P1 C131 C132 -10.90(15) . . . . ?
Au1 P1 C131 C132 -131.69(13) . . . . ?
C136 C131 C132 C133 -0.2(3) . . . . ?
P1 C131 C132 C133 178.66(14) . . . . ?
C131 C132 C133 C134 -0.2(3) . . . . ?
C132 C133 C134 C135 0.5(3) . . . . ?
C133 C134 C135 C136 -0.4(3) . . . . ?
C134 C135 C136 C131 0.0(3) . . . . ?
C132 C131 C136 C135 0.3(2) . . . . ?
P1 C131 C136 C135 -178.63(13) . . . . ?
P1 Au1 P2 C221 169.91(6) . . . . ?
Cl1 Au1 P2 C221 -17.94(6) . . . . ?
Au1 Au1 P2 C221 91.12(6) 2 . . . ?
P1 Au1 P2 C231 48.32(6) . . . . ?
Cl1 Au1 P2 C231 -139.54(6) . . . . ?
Au1 Au1 P2 C231 -30.47(6) 2 . . . ?
P1 Au1 P2 C211 -67.89(6) . . . . ?
Cl1 Au1 P2 C211 104.25(5) . . . . ?
Au1 Au1 P2 C211 -146.68(5) 2 . . . ?
C221 P2 C211 C216 -16.38(16) . . . . ?
C231 P2 C211 C216 93.84(15) . . . . ?
Au1 P2 C211 C216 -146.43(13) . . . . ?
C221 P2 C211 C212 160.80(14) . . . . ?
C231 P2 C211 C212 -88.99(15) . . . . ?
Au1 P2 C211 C212 30.75(15) . . . . ?
C216 C211 C212 C213 0.8(3) . . . . ?
P2 C211 C212 C213 -176.48(16) . . . . ?
C211 C212 C213 C214 -0.8(3) . . . . ?
C212 C213 C214 C215 -0.2(3) . . . . ?
C213 C214 C215 C216 1.1(3) . . . . ?
C212 C211 C216 C215 0.1(3) . . . . ?
P2 C211 C216 C215 177.22(15) . . . . ?
C214 C215 C216 C211 -1.0(3) . . . . ?
C231 P2 C221 C226 144.76(13) . . . . ?
C211 P2 C221 C226 -104.14(13) . . . . ?
Au1 P2 C221 C226 19.80(15) . . . . ?
C231 P2 C221 C222 -36.84(16) . . . . ?
C211 P2 C221 C222 74.26(15) . . . . ?
Au1 P2 C221 C222 -161.80(12) . . . . ?
C226 C221 C222 C223 0.9(3) . . . . ?
P2 C221 C222 C223 -177.46(14) . . . . ?
C221 C222 C223 C224 -0.8(3) . . . . ?
C222 C223 C224 C225 0.4(3) . . . . ?
C223 C224 C225 C226 -0.3(3) . . . . ?
C222 C221 C226 C225 -0.8(3) . . . . ?
P2 C221 C226 C225 177.66(14) . . . . ?
C224 C225 C226 C221 0.5(3) . . . . ?
C221 P2 C231 C232 110.9(2) . . . . ?
C211 P2 C231 C232 -0.5(2) . . . . ?
Au1 P2 C231 C232 -119.01(19) . . . . ?
C221 P2 C231 C236 -72.81(16) . . . . ?
C211 P2 C231 C236 175.86(15) . . . . ?
Au1 P2 C231 C236 57.30(16) . . . . ?
C236 C231 C232 C233 -0.2(4) . . . . ?
P2 C231 C232 C233 176.1(3) . . . . ?
C231 C232 C233 C234 -1.0(5) . . . . ?
C232 C233 C234 C235 1.5(5) . . . . ?
C233 C234 C235 C236 -0.8(4) . . . . ?
C234 C235 C236 C231 -0.4(4) . . . . ?
C232 C231 C236 C235 0.9(3) . . . . ?
P2 C231 C236 C235 -175.63(18) . . . . ?
