#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:04:38 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179739 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/35/7003507.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7003507
loop_
_publ_author_name
'Li, Peiyi'
'Ahrens, Birte'
'Bond, Andrew D.'
'Davies, John E.'
'Koentjoro, Olivia F.'
'Raithby, Paul R.'
'Teat, Simon J.'
_publ_section_title
;
 A new series of dinuclear Au(i) complexes linked by diethynylpyridine
 groups
;
_journal_issue                   12
_journal_name_full               'Dalton Transactions'
_journal_page_first              1635
_journal_page_last               1646
_journal_paper_doi               10.1039/b716664h
_journal_year                    2008
_chemical_formula_sum            'C46 H71 Au2 Cl2 N P2'
_chemical_formula_weight         1164.81
_chemical_name_common            'Complex 2'
_chemical_name_systematic        'Complex 2'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.998(2)
_cell_angle_beta                 100.256(2)
_cell_angle_gamma                96.941(2)
_cell_formula_units_Z            1
_cell_length_a                   9.1956(3)
_cell_length_b                   10.3609(3)
_cell_length_c                   12.8658(4)
_cell_measurement_reflns_used    9236
_cell_measurement_temperature    180(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      1.00
_cell_volume                     1153.00(6)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Nonius B.V. 1998)'
_computing_data_reduction
;
HKL Denzo and Scalepack (Otwinowski & Minor 1997)
;
_computing_publication_material  'SHELXL-97 (Sheldrick 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 1997)'
_diffrn_ambient_temperature      180(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_measurement_method       'Thin slice ω and φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1206
_diffrn_reflns_av_sigmaI/netI    0.0868
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            12208
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.62
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.571
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.493
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sortav Blessing (1995)'
_exptl_crystal_colour            plate
_exptl_crystal_density_diffrn    1.678
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       colourless
_exptl_crystal_F_000             576
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.05
_refine_diff_density_max         3.325
_refine_diff_density_min         -2.842
_refine_diff_density_rms         0.258
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     246
_refine_ls_number_reflns         5234
_refine_ls_number_restraints     38
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0658
_refine_ls_R_factor_gt           0.0579
_refine_ls_shift/su_max          0.028
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1011P)²+1.8974P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1525
_refine_ls_wR_factor_ref         0.1603
_reflns_number_gt                4596
_reflns_number_total             5234
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b716664h.txt
_cod_data_source_block           pr0105
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7003507
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.14189(3) 0.26423(3) 0.039015(19) 0.03295(14) Uani 1 1 d . . .
P1 P 0.0048(2) 0.2108(2) -0.13653(15) 0.0316(4) Uani 1 1 d . . .
C1 C 0.2616(10) 0.3254(9) 0.1931(6) 0.0368(17) Uani 1 1 d . . .
C2 C 0.3352(9) 0.3761(9) 0.2854(7) 0.0405(18) Uani 1 1 d . . .
C3 C 0.4188(9) 0.4378(10) 0.3945(6) 0.0393(18) Uani 1 1 d . . .
C4 C 0.4427(13) 0.5754(11) 0.4380(7) 0.059(3) Uani 0.75 1 d P . 1
H4 H 0.4032 0.6299 0.3940 0.071 Uiso 0.75 1 calc PR . 1
C5 C 0.4794(11) 0.3643(10) 0.4584(7) 0.052(2) Uani 0.75 1 d P . 1
H5 H 0.4673 0.2691 0.4305 0.062 Uiso 0.75 1 calc PR . 1
N1A N 0.4427(13) 0.5754(11) 0.4380(7) 0.059(3) Uani 0.25 1 d P . 2
N1B N 0.4794(11) 0.3643(10) 0.4584(7) 0.052(2) Uani 0.25 1 d P . 2
C6 C 0.0196(11) 0.0409(10) -0.2206(7) 0.059(3) Uani 1 1 d D . .
H6A H -0.0379 -0.0198 -0.1867 0.070 Uiso 1 1 calc R . .
C7 C 0.1666(15) 0.0012(11) -0.2031(9) 0.088(5) Uani 1 1 d D . .
H7A H 0.2020 0.0116 -0.1237 0.106 Uiso 1 1 calc R . .
H7B H 0.2379 0.0634 -0.2252 0.106 Uiso 1 1 calc R . .
C8 C 0.1699(12) -0.1416(8) -0.2648(7) 0.052(2) Uani 1 1 d D . .
H8A H 0.2756 -0.1529 -0.2632 0.063 Uiso 1 1 calc R . .
H8B H 0.1264 -0.2042 -0.2268 0.063 Uiso 1 1 calc R . .
C9 C 0.0857(17) -0.1796(12) -0.3817(9) 0.101(6) Uani 1 1 d D . .
H9A H 0.1479 -0.1383 -0.4245 0.121 Uiso 1 1 calc R . .
H9B H 0.0731 -0.2788 -0.4108 0.121 Uiso 1 1 calc R . .
C10 C -0.0603(13) -0.1404(13) -0.4004(9) 0.081(4) Uani 1 1 d D . .
H10A H -0.1324 -0.2059 -0.3820 0.098 Uiso 1 1 calc R . .
H10B H -0.0922 -0.1484 -0.4797 0.098 Uiso 1 1 calc R . .
C11 C -0.0722(10) 0.0011(8) -0.3370(6) 0.0419(19) Uani 1 1 d D . .
H11A H -0.0375 0.0666 -0.3758 0.050 Uiso 1 1 calc R . .
H11B H -0.1787 0.0056 -0.3352 0.050 Uiso 1 1 calc R . .
C12 C -0.1966(8) 0.2046(7) -0.1414(6) 0.0345(15) Uani 1 1 d D . .
H12A H -0.2485 0.1909 -0.2194 0.041 Uiso 1 1 calc R . .
C13 C -0.2246(8) 0.3396(8) -0.0738(7) 0.0428(19) Uani 1 1 d D . .
H13A H -0.1897 0.4134 -0.1048 0.051 Uiso 1 1 calc R . .
H13B H -0.1679 0.3595 0.0029 0.051 Uiso 1 1 calc R . .
C14 C -0.3934(10) 0.3312(10) -0.0763(9) 0.060(3) Uani 1 1 d D . .
H14A H -0.4110 0.4173 -0.0309 0.072 Uiso 1 1 calc R . .
H14B H -0.4482 0.3186 -0.1525 0.072 Uiso 1 1 calc R . .
C15 C -0.4544(11) 0.2171(11) -0.0343(9) 0.065(3) Uani 1 1 d D . .
H15A H -0.5632 0.2149 -0.0379 0.078 Uiso 1 1 calc R . .
H15B H -0.4040 0.2315 0.0433 0.078 Uiso 1 1 calc R . .
C16 C -0.4287(11) 0.0835(9) -0.1027(9) 0.059(3) Uani 1 1 d D . .
H16A H -0.4857 0.0658 -0.1791 0.070 Uiso 1 1 calc R . .
H16B H -0.4659 0.0095 -0.0728 0.070 Uiso 1 1 calc R . .
C17 C -0.2621(9) 0.0864(8) -0.1019(7) 0.0452(19) Uani 1 1 d D . .
H17A H -0.2484 0.0005 -0.1501 0.054 Uiso 1 1 calc R . .
H17B H -0.2069 0.0944 -0.0266 0.054 Uiso 1 1 calc R . .
C18 C 0.0591(8) 0.3470(8) -0.1996(6) 0.0356(16) Uani 1 1 d D . .
H18A H 0.0513 0.4326 -0.1464 0.043 Uiso 1 1 calc R . .
C19 C 0.2245(9) 0.3591(13) -0.2058(9) 0.062(3) Uani 1 1 d D . .
H19A H 0.2860 0.3637 -0.1331 0.074 Uiso 1 1 calc R . .
H19B H 0.2394 0.2778 -0.2591 0.074 Uiso 1 1 calc R . .
C20 C 0.2768(10) 0.4838(12) -0.2404(8) 0.056(3) Uani 1 1 d D . .
H20A H 0.3822 0.4855 -0.2479 0.068 Uiso 1 1 calc R . .
H20B H 0.2728 0.5656 -0.1829 0.068 Uiso 1 1 calc R . .
C21 C 0.1795(10) 0.4860(9) -0.3492(6) 0.046(2) Uani 1 1 d D . .
H21A H 0.2112 0.5717 -0.3666 0.055 Uiso 1 1 calc R . .
H21B H 0.1929 0.4106 -0.4087 0.055 Uiso 1 1 calc R . .
C22 C 0.0162(10) 0.4730(8) -0.3423(7) 0.045(2) Uani 1 1 d D . .
H22A H -0.0456 0.4694 -0.4147 0.054 Uiso 1 1 calc R . .
H22B H 0.0016 0.5539 -0.2885 0.054 Uiso 1 1 calc R . .
C23 C -0.0369(9) 0.3481(8) -0.3088(7) 0.0408(18) Uani 1 1 d D . .
H23A H -0.0316 0.2666 -0.3660 0.049 Uiso 1 1 calc R . .
H23B H -0.1428 0.3458 -0.3023 0.049 Uiso 1 1 calc R . .
Cl1 Cl 0.4459(7) 0.0803(5) 0.5875(3) 0.1174(16) Uani 1 1 d D . .
C24 C 0.469(4) -0.079(3) 0.523(3) 0.117(13) Uani 0.50 1 d PD . -1
H24A H 0.3692 -0.1386 0.4960 0.140 Uiso 0.50 1 calc PR . -1
H24B H 0.5302 -0.1164 0.5758 0.140 Uiso 0.50 1 calc PR . -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Au1 P1 175.7(2) . . ?
C12 P1 C18 105.3(3) . . ?
C12 P1 C6 104.6(4) . . ?
C18 P1 C6 112.4(5) . . ?
C12 P1 Au1 112.1(2) . . ?
C18 P1 Au1 108.7(2) . . ?
C6 P1 Au1 113.4(3) . . ?
C2 C1 Au1 173.2(8) . . ?
C1 C2 C3 178.6(10) . . ?
C5 C3 C4 117.2(8) . . ?
C5 C3 C2 121.6(9) . . ?
C4 C3 C2 121.2(8) . . ?
C5 C4 C3 122.1(9) 2_666 . ?
C5 C4 H4 119.0 2_666 . ?
C3 C4 H4 119.0 . . ?
C3 C5 C4 120.7(9) . 2_666 ?
C3 C5 H5 119.7 . . ?
C4 C5 H5 119.7 2_666 . ?
C7 C6 C11 117.5(8) . . ?
C7 C6 P1 116.3(6) . . ?
C11 C6 P1 114.8(6) . . ?
C7 C6 H6A 101.4 . . ?
C11 C6 H6A 101.4 . . ?
P1 C6 H6A 101.4 . . ?
C6 C7 C8 114.4(8) . . ?
C6 C7 H7A 108.7 . . ?
C8 C7 H7A 108.7 . . ?
C6 C7 H7B 108.7 . . ?
C8 C7 H7B 108.7 . . ?
H7A C7 H7B 107.6 . . ?
C9 C8 C7 113.6(7) . . ?
C9 C8 H8A 108.9 . . ?
C7 C8 H8A 108.9 . . ?
C9 C8 H8B 108.9 . . ?
C7 C8 H8B 108.9 . . ?
H8A C8 H8B 107.7 . . ?
C10 C9 C8 116.0(9) . . ?
C10 C9 H9A 108.3 . . ?
C8 C9 H9A 108.3 . . ?
C10 C9 H9B 108.3 . . ?
C8 C9 H9B 108.3 . . ?
H9A C9 H9B 107.4 . . ?
C9 C10 C11 116.5(8) . . ?
C9 C10 H10A 108.2 . . ?
C11 C10 H10A 108.2 . . ?
C9 C10 H10B 108.2 . . ?
C11 C10 H10B 108.2 . . ?
H10A C10 H10B 107.3 . . ?
C6 C11 C10 112.5(7) . . ?
C6 C11 H11A 109.1 . . ?
C10 C11 H11A 109.1 . . ?
C6 C11 H11B 109.1 . . ?
C10 C11 H11B 109.1 . . ?
H11A C11 H11B 107.8 . . ?
C17 C12 C13 111.2(6) . . ?
C17 C12 P1 111.6(5) . . ?
C13 C12 P1 110.0(5) . . ?
C17 C12 H12A 108.0 . . ?
C13 C12 H12A 108.0 . . ?
P1 C12 H12A 108.0 . . ?
C12 C13 C14 109.2(6) . . ?
C12 C13 H13A 109.8 . . ?
C14 C13 H13A 109.8 . . ?
C12 C13 H13B 109.8 . . ?
C14 C13 H13B 109.8 . . ?
H13A C13 H13B 108.3 . . ?
C15 C14 C13 112.3(8) . . ?
C15 C14 H14A 109.1 . . ?
C13 C14 H14A 109.1 . . ?
C15 C14 H14B 109.1 . . ?
C13 C14 H14B 109.1 . . ?
H14A C14 H14B 107.9 . . ?
C14 C15 C16 110.2(7) . . ?
C14 C15 H15A 109.6 . . ?
C16 C15 H15A 109.6 . . ?
C14 C15 H15B 109.6 . . ?
C16 C15 H15B 109.6 . . ?
H15A C15 H15B 108.1 . . ?
C15 C16 C17 110.6(7) . . ?
C15 C16 H16A 109.5 . . ?
C17 C16 H16A 109.5 . . ?
C15 C16 H16B 109.5 . . ?
C17 C16 H16B 109.5 . . ?
H16A C16 H16B 108.1 . . ?
C16 C17 C12 111.6(7) . . ?
C16 C17 H17A 109.3 . . ?
C12 C17 H17A 109.3 . . ?
C16 C17 H17B 109.3 . . ?
C12 C17 H17B 109.3 . . ?
H17A C17 H17B 108.0 . . ?
C23 C18 C19 110.3(6) . . ?
C23 C18 P1 118.5(5) . . ?
C19 C18 P1 111.0(6) . . ?
C23 C18 H18A 105.3 . . ?
C19 C18 H18A 105.3 . . ?
P1 C18 H18A 105.3 . . ?
C20 C19 C18 111.5(7) . . ?
C20 C19 H19A 109.3 . . ?
C18 C19 H19A 109.3 . . ?
C20 C19 H19B 109.3 . . ?
C18 C19 H19B 109.3 . . ?
H19A C19 H19B 108.0 . . ?
C19 C20 C21 111.5(7) . . ?
C19 C20 H20A 109.3 . . ?
C21 C20 H20A 109.3 . . ?
C19 C20 H20B 109.3 . . ?
C21 C20 H20B 109.3 . . ?
H20A C20 H20B 108.0 . . ?
C22 C21 C20 110.3(7) . . ?
C22 C21 H21A 109.6 . . ?
C20 C21 H21A 109.6 . . ?
C22 C21 H21B 109.6 . . ?
C20 C21 H21B 109.6 . . ?
H21A C21 H21B 108.1 . . ?
C21 C22 C23 112.3(7) . . ?
C21 C22 H22A 109.1 . . ?
C23 C22 H22A 109.1 . . ?
C21 C22 H22B 109.1 . . ?
C23 C22 H22B 109.1 . . ?
H22A C22 H22B 107.9 . . ?
C22 C23 C18 110.9(6) . . ?
C22 C23 H23A 109.5 . . ?
C18 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
C18 C23 H23B 109.5 . . ?
H23A C23 H23B 108.0 . . ?
C24 Cl1 C24 68.0(17) . 2_656 ?
Cl1 C24 Cl1 112.0(17) . 2_656 ?
Cl1 C24 H24A 109.2 . . ?
Cl1 C24 H24A 109.2 2_656 . ?
Cl1 C24 H24B 109.2 . . ?
Cl1 C24 H24B 109.2 2_656 . ?
H24A C24 H24B 107.9 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 C1 1.998(7) . ?
Au1 P1 2.2823(19) . ?
P1 C12 1.835(8) . ?
P1 C18 1.851(8) . ?
P1 C6 1.865(8) . ?
C1 C2 1.212(11) . ?
C2 C3 1.425(11) . ?
C3 C5 1.345(13) . ?
C3 C4 1.375(14) . ?
C4 C5 1.353(12) 2_666 ?
C4 H4 0.9500 . ?
C5 C4 1.353(12) 2_666 ?
C5 H5 0.9500 . ?
C6 C7 1.455(12) . ?
C6 C11 1.514(10) . ?
C6 H6A 1.0000 . ?
C7 C8 1.507(10) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
C8 C9 1.497(12) . ?
C8 H8A 0.9900 . ?
C8 H8B 0.9900 . ?
C9 C10 1.445(13) . ?
C9 H9A 0.9900 . ?
C9 H9B 0.9900 . ?
C10 C11 1.523(11) . ?
C10 H10A 0.9900 . ?
C10 H10B 0.9900 . ?
C11 H11A 0.9900 . ?
C11 H11B 0.9900 . ?
C12 C17 1.533(10) . ?
C12 C13 1.535(9) . ?
C12 H12A 1.0000 . ?
C13 C14 1.538(10) . ?
C13 H13A 0.9900 . ?
C13 H13B 0.9900 . ?
C14 C15 1.503(12) . ?
C14 H14A 0.9900 . ?
C14 H14B 0.9900 . ?
C15 C16 1.520(12) . ?
C15 H15A 0.9900 . ?
C15 H15B 0.9900 . ?
C16 C17 1.527(12) . ?
C16 H16A 0.9900 . ?
C16 H16B 0.9900 . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 C23 1.524(9) . ?
C18 C19 1.529(10) . ?
C18 H18A 1.0000 . ?
C19 C20 1.518(12) . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
C20 C21 1.527(11) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.511(11) . ?
C21 H21A 0.9900 . ?
C21 H21B 0.9900 . ?
C22 C23 1.514(10) . ?
C22 H22A 0.9900 . ?
C22 H22B 0.9900 . ?
C23 H23A 0.9900 . ?
C23 H23B 0.9900 . ?
Cl1 C24 1.72(2) . ?
Cl1 C24 1.74(2) 2_656 ?
C24 Cl1 1.74(2) 2_656 ?
C24 H24A 0.9900 . ?
C24 H24B 0.9900 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Au1 P1 C12 -84(3) . . . . ?
C1 Au1 P1 C18 32(3) . . . . ?
C1 Au1 P1 C6 158(3) . . . . ?
P1 Au1 C1 C2 -8(10) . . . . ?
Au1 C1 C2 C3 55(44) . . . . ?
C1 C2 C3 C5 136(41) . . . . ?
C1 C2 C3 C4 -45(41) . . . . ?
C5 C3 C4 C5 -1.5(17) . . . 2_666 ?
C2 C3 C4 C5 179.4(10) . . . 2_666 ?
C4 C3 C5 C4 1.5(17) . . . 2_666 ?
C2 C3 C5 C4 -179.4(9) . . . 2_666 ?
C12 P1 C6 C7 -160.8(11) . . . . ?
C18 P1 C6 C7 85.4(11) . . . . ?
Au1 P1 C6 C7 -38.3(12) . . . . ?
C12 P1 C6 C11 56.5(9) . . . . ?
C18 P1 C6 C11 -57.3(9) . . . . ?
Au1 P1 C6 C11 179.0(7) . . . . ?
C11 C6 C7 C8 -43.7(18) . . . . ?
P1 C6 C7 C8 174.5(9) . . . . ?
C6 C7 C8 C9 44.7(18) . . . . ?
C7 C8 C9 C10 -45.0(19) . . . . ?
C8 C9 C10 C11 43(2) . . . . ?
C7 C6 C11 C10 39.9(16) . . . . ?
P1 C6 C11 C10 -177.9(9) . . . . ?
C9 C10 C11 C6 -39.0(17) . . . . ?
C18 P1 C12 C17 174.4(5) . . . . ?
C6 P1 C12 C17 55.7(6) . . . . ?
Au1 P1 C12 C17 -67.6(5) . . . . ?
C18 P1 C12 C13 -61.7(6) . . . . ?
C6 P1 C12 C13 179.6(6) . . . . ?
Au1 P1 C12 C13 56.3(6) . . . . ?
C17 C12 C13 C14 -54.4(9) . . . . ?
P1 C12 C13 C14 -178.5(6) . . . . ?
C12 C13 C14 C15 57.2(11) . . . . ?
C13 C14 C15 C16 -58.8(12) . . . . ?
C14 C15 C16 C17 57.1(12) . . . . ?
C15 C16 C17 C12 -55.9(10) . . . . ?
C13 C12 C17 C16 55.1(9) . . . . ?
P1 C12 C17 C16 178.3(6) . . . . ?
C12 P1 C18 C23 -48.3(7) . . . . ?
C6 P1 C18 C23 65.0(7) . . . . ?
Au1 P1 C18 C23 -168.6(5) . . . . ?
C12 P1 C18 C19 -177.4(6) . . . . ?
C6 P1 C18 C19 -64.1(7) . . . . ?
Au1 P1 C18 C19 62.3(7) . . . . ?
C23 C18 C19 C20 55.7(11) . . . . ?
P1 C18 C19 C20 -171.0(7) . . . . ?
C18 C19 C20 C21 -55.6(12) . . . . ?
C19 C20 C21 C22 54.8(11) . . . . ?
C20 C21 C22 C23 -55.6(10) . . . . ?
C21 C22 C23 C18 56.7(9) . . . . ?
C19 C18 C23 C22 -55.7(10) . . . . ?
P1 C18 C23 C22 174.9(6) . . . . ?
C24 Cl1 C24 Cl1 0.000(1) 2_656 . . 2_656 ?
