#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:18:57 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179747 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/43/7004394.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7004394
loop_
_publ_author_name
'Jones, Cameron'
'Mills, David P.'
'Stasch, Andreas'
_publ_section_title
;
 Flexible coordination of bulky amidinates and guanidinates towards
 rhodium(i): conversion of kinetic to thermodymanic isomers
;
_journal_issue                   35
_journal_name_full               'Dalton Transactions'
_journal_page_first              4799
_journal_page_last               4804
_journal_paper_doi               10.1039/b806542j
_journal_year                    2008
_chemical_formula_sum            'C36 H60 O4 Rh4 Si2'
_chemical_formula_weight         1024.66
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                111.7230(10)
_cell_angle_beta                 97.0880(10)
_cell_angle_gamma                97.2930(10)
_cell_formula_units_Z            4
_cell_length_a                   11.7331(2)
_cell_length_b                   18.5200(3)
_cell_length_c                   19.0441(3)
_cell_measurement_temperature    123(2)
_cell_volume                     3747.50(11)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker X8 CCD'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0315
_diffrn_reflns_av_sigmaI/netI    0.0542
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            36903
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.20
_exptl_absorpt_coefficient_mu    1.832
_exptl_absorpt_correction_T_max  0.710
_exptl_absorpt_correction_T_min  0.621
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SABABS (Blessing, 1995)'
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.816
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2064
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.874
_refine_diff_density_min         -0.767
_refine_diff_density_rms         0.140
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.139
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     837
_refine_ls_number_reflns         16908
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.139
_refine_ls_R_factor_all          0.0508
_refine_ls_R_factor_gt           0.0414
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0109P)²+7.8121P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0749
_refine_ls_wR_factor_ref         0.0819
_reflns_number_gt                14607
_reflns_number_total             16908
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b806542j.txt
_cod_data_source_block           '[{Rh(COD)}4(O2SiMe2)2]'
_cod_original_cell_volume        3747.49(11)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7004394
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.69010(3) 0.83083(2) 0.803114(19) 0.01840(8) Uani 1 1 d . . .
Rh2 Rh 0.42163(3) 0.87847(2) 0.757304(19) 0.01819(8) Uani 1 1 d . . .
Rh3 Rh 0.31644(3) 0.68120(2) 0.654363(18) 0.01744(7) Uani 1 1 d . . .
Rh4 Rh 0.58295(3) 0.62976(2) 0.700593(18) 0.01625(7) Uani 1 1 d . . .
Rh5 Rh 0.90074(3) 1.27396(2) 0.898293(18) 0.01751(7) Uani 1 1 d . . .
Rh6 Rh 1.17276(3) 1.31627(2) 0.865424(19) 0.01982(8) Uani 1 1 d . . .
Rh7 Rh 1.07537(3) 1.23259(2) 0.673479(19) 0.01851(8) Uani 1 1 d . . .
Rh8 Rh 0.78611(3) 1.18367(2) 0.697290(19) 0.01871(8) Uani 1 1 d . . .
Si1 Si 0.45453(9) 0.74356(7) 0.82549(6) 0.0157(2) Uani 1 1 d . . .
Si2 Si 0.55376(10) 0.76419(8) 0.63277(7) 0.0198(3) Uani 1 1 d . . .
Si3 Si 0.94166(10) 1.35573(8) 0.78098(7) 0.0201(3) Uani 1 1 d . . .
Si4 Si 1.00529(10) 1.14205(7) 0.77931(6) 0.0172(2) Uani 1 1 d . . .
O1 O 0.5805(2) 0.72829(17) 0.79980(15) 0.0165(6) Uani 1 1 d . . .
O2 O 0.3731(2) 0.77031(17) 0.76676(15) 0.0170(6) Uani 1 1 d . . .
O3 O 0.5680(2) 0.83862(17) 0.71515(15) 0.0162(6) Uani 1 1 d . . .
O4 O 0.4916(2) 0.68131(17) 0.63588(15) 0.0169(6) Uani 1 1 d . . .
O5 O 1.0062(2) 1.34564(17) 0.85682(16) 0.0183(6) Uani 1 1 d . . .
O6 O 1.1067(2) 1.20723(17) 0.77336(16) 0.0180(6) Uani 1 1 d . . .
O7 O 0.9214(2) 1.27392(18) 0.70407(16) 0.0199(6) Uani 1 1 d . . .
O8 O 0.8845(2) 1.17575(17) 0.79343(15) 0.0174(6) Uani 1 1 d . . .
C1 C 0.7867(4) 0.8363(3) 0.9062(3) 0.0342(13) Uani 1 1 d . . .
H1 H 0.7200 0.8043 0.9103 0.041 Uiso 1 1 calc R . .
C2 C 0.8445(4) 0.8019(3) 0.8461(3) 0.0329(12) Uani 1 1 d . . .
H2 H 0.8137 0.7487 0.8118 0.039 Uiso 1 1 calc R . .
C3 C 0.9542(4) 0.8443(4) 0.8319(4) 0.0474(16) Uani 1 1 d . . .
H3A H 1.0012 0.8818 0.8820 0.057 Uiso 1 1 calc R . .
H3B H 1.0018 0.8047 0.8075 0.057 Uiso 1 1 calc R . .
C4 C 0.9295(4) 0.8888(4) 0.7818(4) 0.0494(16) Uani 1 1 d . . .
H4A H 0.9334 0.8553 0.7281 0.059 Uiso 1 1 calc R . .
H4B H 0.9909 0.9368 0.7988 0.059 Uiso 1 1 calc R . .
C5 C 0.8108(4) 0.9131(3) 0.7836(3) 0.0295(11) Uani 1 1 d . . .
H5 H 0.7618 0.9006 0.7355 0.035 Uiso 1 1 calc R . .
C6 C 0.7676(4) 0.9518(3) 0.8491(3) 0.0315(11) Uani 1 1 d . . .
H6 H 0.6902 0.9615 0.8428 0.038 Uiso 1 1 calc R . .
C7 C 0.8356(6) 0.9797(4) 0.9296(3) 0.0578(19) Uani 1 1 d . . .
H7A H 0.8102 1.0280 0.9626 0.069 Uiso 1 1 calc R . .
H7B H 0.9196 0.9941 0.9292 0.069 Uiso 1 1 calc R . .
C8 C 0.8205(5) 0.9188(4) 0.9644(3) 0.0513(17) Uani 1 1 d . . .
H8A H 0.8948 0.9238 0.9982 0.062 Uiso 1 1 calc R . .
H8B H 0.7598 0.9298 0.9967 0.062 Uiso 1 1 calc R . .
C9 C 0.4899(5) 0.9946(3) 0.7685(3) 0.0375(13) Uani 1 1 d . . .
H9 H 0.5655 0.9820 0.7748 0.045 Uiso 1 1 calc R . .
C10 C 0.4161(4) 0.9541(3) 0.6983(3) 0.0366(13) Uani 1 1 d . . .
H10 H 0.4470 0.9171 0.6594 0.044 Uiso 1 1 calc R . .
C11 C 0.2923(5) 0.9622(6) 0.6767(5) 0.092(3) Uani 1 1 d . . .
H11A H 0.2927 1.0167 0.6794 0.111 Uiso 1 1 calc R . .
H11B H 0.2622 0.9256 0.6225 0.111 Uiso 1 1 calc R . .
C12 C 0.2106(4) 0.9463(4) 0.7242(3) 0.0397(13) Uani 1 1 d . . .
H12A H 0.1368 0.9134 0.6898 0.048 Uiso 1 1 calc R . .
H12B H 0.1923 0.9972 0.7576 0.048 Uiso 1 1 calc R . .
C13 C 0.2546(4) 0.9051(3) 0.7742(3) 0.0251(10) Uani 1 1 d . . .
H13 H 0.2265 0.8498 0.7567 0.030 Uiso 1 1 calc R . .
C14 C 0.3324(4) 0.9409(3) 0.8434(3) 0.0285(11) Uani 1 1 d . . .
H14 H 0.3527 0.9083 0.8698 0.034 Uiso 1 1 calc R . .
C15 C 0.3881(5) 1.0282(3) 0.8807(3) 0.0446(15) Uani 1 1 d . . .
H15A H 0.3252 1.0594 0.8924 0.053 Uiso 1 1 calc R . .
H15B H 0.4385 1.0381 0.9303 0.053 Uiso 1 1 calc R . .
C16 C 0.4577(8) 1.0570(4) 0.8350(4) 0.087(3) Uani 1 1 d . . .
H16A H 0.5305 1.0917 0.8692 0.105 Uiso 1 1 calc R . .
H16B H 0.4137 1.0900 0.8154 0.105 Uiso 1 1 calc R . .
C17 C 0.2641(4) 0.6178(3) 0.5347(3) 0.0310(12) Uani 1 1 d . . .
H17 H 0.3393 0.6378 0.5287 0.037 Uiso 1 1 calc R . .
C18 C 0.2577(4) 0.5657(3) 0.5718(3) 0.0325(12) Uani 1 1 d . . .
H18 H 0.3289 0.5545 0.5912 0.039 Uiso 1 1 calc R . .
C19 C 0.1443(4) 0.5256(3) 0.5833(3) 0.0431(15) Uani 1 1 d . . .
H19A H 0.0800 0.5208 0.5420 0.052 Uiso 1 1 calc R . .
H19B H 0.1517 0.4715 0.5791 0.052 Uiso 1 1 calc R . .
C20 C 0.1137(4) 0.5708(3) 0.6606(3) 0.0427(15) Uani 1 1 d . . .
H20A H 0.0279 0.5600 0.6566 0.051 Uiso 1 1 calc R . .
H20B H 0.1492 0.5518 0.6989 0.051 Uiso 1 1 calc R . .
C21 C 0.1560(4) 0.6584(3) 0.6880(3) 0.0307(11) Uani 1 1 d . . .
H21 H 0.1947 0.6857 0.7400 0.037 Uiso 1 1 calc R . .
C22 C 0.1429(3) 0.7029(3) 0.6435(3) 0.0244(10) Uani 1 1 d . . .
H22 H 0.1772 0.7575 0.6663 0.029 Uiso 1 1 calc R . .
C23 C 0.0776(4) 0.6699(3) 0.5608(3) 0.0321(11) Uani 1 1 d . . .
H23A H 0.0382 0.7107 0.5516 0.039 Uiso 1 1 calc R . .
H23B H 0.0168 0.6237 0.5522 0.039 Uiso 1 1 calc R . .
C24 C 0.1609(4) 0.6446(3) 0.5036(3) 0.0341(12) Uani 1 1 d . . .
H24A H 0.1172 0.6010 0.4557 0.041 Uiso 1 1 calc R . .
H24B H 0.1895 0.6898 0.4903 0.041 Uiso 1 1 calc R . .
C25 C 0.5580(4) 0.5198(3) 0.6051(2) 0.0220(9) Uani 1 1 d . . .
H25 H 0.4858 0.5314 0.5879 0.026 Uiso 1 1 calc R . .
C26 C 0.6598(4) 0.5685(3) 0.6078(2) 0.0211(9) Uani 1 1 d . . .
H26 H 0.6513 0.6083 0.5884 0.025 Uiso 1 1 calc R . .
C27 C 0.7840(4) 0.5645(3) 0.6385(3) 0.0270(10) Uani 1 1 d . . .
H27A H 0.8368 0.6141 0.6467 0.032 Uiso 1 1 calc R . .
H27B H 0.8099 0.5203 0.5998 0.032 Uiso 1 1 calc R . .
C28 C 0.7936(4) 0.5526(3) 0.7141(3) 0.0316(11) Uani 1 1 d . . .
H28A H 0.7782 0.4952 0.7027 0.038 Uiso 1 1 calc R . .
H28B H 0.8742 0.5749 0.7436 0.038 Uiso 1 1 calc R . .
C29 C 0.7085(4) 0.5917(3) 0.7626(2) 0.0229(9) Uani 1 1 d . . .
H29 H 0.7341 0.6454 0.7971 0.027 Uiso 1 1 calc R . .
C30 C 0.5962(4) 0.5559(3) 0.7610(3) 0.0233(10) Uani 1 1 d . . .
H30 H 0.5524 0.5875 0.7950 0.028 Uiso 1 1 calc R . .
C31 C 0.5369(4) 0.4723(3) 0.7111(3) 0.0310(11) Uani 1 1 d . . .
H31A H 0.4523 0.4665 0.7126 0.037 Uiso 1 1 calc R . .
H31B H 0.5691 0.4358 0.7317 0.037 Uiso 1 1 calc R . .
C32 C 0.5536(4) 0.4495(3) 0.6276(3) 0.0315(11) Uani 1 1 d . . .
H32A H 0.6272 0.4290 0.6213 0.038 Uiso 1 1 calc R . .
H32B H 0.4882 0.4070 0.5931 0.038 Uiso 1 1 calc R . .
C33 C 0.3728(3) 0.6501(3) 0.8263(2) 0.0203(9) Uani 1 1 d . . .
H33A H 0.2956 0.6581 0.8387 0.030 Uiso 1 1 calc R . .
H33B H 0.4166 0.6360 0.8652 0.030 Uiso 1 1 calc R . .
H33C H 0.3636 0.6072 0.7756 0.030 Uiso 1 1 calc R . .
C34 C 0.4823(4) 0.8224(3) 0.9245(2) 0.0249(10) Uani 1 1 d . . .
H34A H 0.5252 0.8714 0.9245 0.037 Uiso 1 1 calc R . .
H34B H 0.5288 0.8056 0.9600 0.037 Uiso 1 1 calc R . .
H34C H 0.4076 0.8316 0.9408 0.037 Uiso 1 1 calc R . .
C35 C 0.7016(4) 0.7561(3) 0.6077(3) 0.0335(12) Uani 1 1 d . . .
H35A H 0.7389 0.8067 0.6079 0.050 Uiso 1 1 calc R . .
H35B H 0.6941 0.7144 0.5565 0.050 Uiso 1 1 calc R . .
H35C H 0.7496 0.7430 0.6456 0.050 Uiso 1 1 calc R . .
C36 C 0.4662(5) 0.7825(3) 0.5546(3) 0.0392(13) Uani 1 1 d . . .
H36A H 0.3884 0.7896 0.5664 0.059 Uiso 1 1 calc R . .
H36B H 0.4584 0.7372 0.5057 0.059 Uiso 1 1 calc R . .
H36C H 0.5056 0.8304 0.5505 0.059 Uiso 1 1 calc R . .
C37 C 0.7473(4) 1.2254(3) 0.9238(2) 0.0251(10) Uani 1 1 d . . .
H37 H 0.7181 1.2073 0.8702 0.030 Uiso 1 1 calc R . .
C38 C 0.8380(4) 1.1938(3) 0.9462(3) 0.0305(11) Uani 1 1 d . . .
H38 H 0.8639 1.1537 0.9071 0.037 Uiso 1 1 calc R . .
C39 C 0.8995(5) 1.2179(4) 1.0278(3) 0.0487(16) Uani 1 1 d . . .
H39A H 0.9705 1.1942 1.0276 0.058 Uiso 1 1 calc R . .
H39B H 0.8475 1.1968 1.0556 0.058 Uiso 1 1 calc R . .
C40 C 0.9340(5) 1.3066(4) 1.0699(3) 0.0459(15) Uani 1 1 d . . .
H40A H 1.0054 1.3191 1.1091 0.055 Uiso 1 1 calc R . .
H40B H 0.8708 1.3269 1.0970 0.055 Uiso 1 1 calc R . .
C41 C 0.9571(4) 1.3488(3) 1.0160(3) 0.0341(12) Uani 1 1 d . . .
H41 H 1.0337 1.3553 1.0050 0.041 Uiso 1 1 calc R . .
C42 C 0.8726(4) 1.3780(3) 0.9823(3) 0.0292(11) Uani 1 1 d . . .
H42 H 0.8956 1.4046 0.9507 0.035 Uiso 1 1 calc R . .
C43 C 0.7456(4) 1.3705(3) 0.9924(3) 0.0349(12) Uani 1 1 d . . .
H43A H 0.7413 1.4052 1.0456 0.042 Uiso 1 1 calc R . .
H43B H 0.7005 1.3888 0.9569 0.042 Uiso 1 1 calc R . .
C44 C 0.6905(4) 1.2862(3) 0.9770(3) 0.0337(12) Uani 1 1 d . . .
H44A H 0.6956 1.2796 1.0265 0.040 Uiso 1 1 calc R . .
H44B H 0.6066 1.2768 0.9544 0.040 Uiso 1 1 calc R . .
C45 C 1.3031(4) 1.2774(3) 0.9211(3) 0.0352(12) Uani 1 1 d . . .
H45 H 1.2498 1.2291 0.9070 0.042 Uiso 1 1 calc R . .
C46 C 1.3447(4) 1.2937(3) 0.8619(3) 0.0376(13) Uani 1 1 d . . .
H46 H 1.3180 1.2562 0.8105 0.045 Uiso 1 1 calc R . .
C47 C 1.4309(5) 1.3687(4) 0.8754(5) 0.071(2) Uani 1 1 d . . .
H47A H 1.4895 1.3811 0.9223 0.086 Uiso 1 1 calc R . .
H47B H 1.4729 1.3579 0.8317 0.086 Uiso 1 1 calc R . .
C48 C 1.3787(5) 1.4376(4) 0.8841(4) 0.0578(18) Uani 1 1 d . . .
H48A H 1.3749 1.4461 0.8355 0.069 Uiso 1 1 calc R . .
H48B H 1.4309 1.4844 0.9250 0.069 Uiso 1 1 calc R . .
C49 C 1.2589(5) 1.4335(3) 0.9034(3) 0.0366(12) Uani 1 1 d . . .
H49 H 1.1987 1.4400 0.8692 0.044 Uiso 1 1 calc R . .
C50 C 1.2270(4) 1.4212(3) 0.9663(3) 0.0311(11) Uani 1 1 d . . .
H50 H 1.1473 1.4196 0.9714 0.037 Uiso 1 1 calc R . .
C51 C 1.3092(5) 1.4102(4) 1.0272(3) 0.0470(15) Uani 1 1 d . . .
H51A H 1.3835 1.4482 1.0399 0.056 Uiso 1 1 calc R . .
H51B H 1.2748 1.4233 1.0743 0.056 Uiso 1 1 calc R . .
C52 C 1.3356(7) 1.3302(4) 1.0057(4) 0.072(2) Uani 1 1 d . . .
H52A H 1.2943 1.3038 1.0346 0.087 Uiso 1 1 calc R . .
H52B H 1.4205 1.3349 1.0224 0.087 Uiso 1 1 calc R . .
C53 C 1.2505(4) 1.2359(3) 0.6584(3) 0.0324(12) Uani 1 1 d . . .
H53 H 1.2711 1.2634 0.7126 0.039 Uiso 1 1 calc R . .
C54 C 1.1931(5) 1.1587(3) 0.6299(3) 0.0469(16) Uani 1 1 d . . .
H54 H 1.1785 1.1357 0.6658 0.056 Uiso 1 1 calc R . .
C55 C 1.1519(7) 1.1084(4) 0.5468(4) 0.078(3) Uani 1 1 d . . .
H55A H 1.1018 1.0588 0.5415 0.093 Uiso 1 1 calc R . .
H55B H 1.2204 1.0942 0.5227 0.093 Uiso 1 1 calc R . .
C56 C 1.0827(6) 1.1496(4) 0.5037(3) 0.070(3) Uani 1 1 d . . .
H56A H 1.1363 1.1756 0.4802 0.084 Uiso 1 1 calc R . .
H56B H 1.0224 1.1094 0.4617 0.084 Uiso 1 1 calc R . .
C57 C 1.0241(5) 1.2109(4) 0.5567(3) 0.0479(17) Uani 1 1 d . . .
H57 H 0.9477 1.1932 0.5628 0.057 Uiso 1 1 calc R . .
C58 C 1.0719(4) 1.2900(3) 0.5969(3) 0.0326(12) Uani 1 1 d . . .
H58 H 1.0248 1.3228 0.6267 0.039 Uiso 1 1 calc R . .
C59 C 1.1943(4) 1.3285(3) 0.5972(3) 0.0347(12) Uani 1 1 d . . .
H59A H 1.1959 1.3349 0.5479 0.042 Uiso 1 1 calc R . .
H59B H 1.2148 1.3818 0.6393 0.042 Uiso 1 1 calc R . .
C60 C 1.2832(4) 1.2800(3) 0.6079(3) 0.0342(12) Uani 1 1 d . . .
H60A H 1.3604 1.3151 0.6318 0.041 Uiso 1 1 calc R . .
H60B H 1.2901 1.2412 0.5570 0.041 Uiso 1 1 calc R . .
C61 C 0.6872(4) 1.0708(3) 0.6697(3) 0.0368(13) Uani 1 1 d . . .
H61 H 0.7532 1.0610 0.6966 0.044 Uiso 1 1 calc R . .
C62 C 0.6290(4) 1.1264(3) 0.7119(3) 0.0341(12) Uani 1 1 d . . .
H62 H 0.6585 1.1529 0.7655 0.041 Uiso 1 1 calc R . .
C63 C 0.5216(4) 1.1486(4) 0.6795(4) 0.0505(16) Uani 1 1 d . . .
H63A H 0.4724 1.1005 0.6384 0.061 Uiso 1 1 calc R . .
H63B H 0.4757 1.1686 0.7207 0.061 Uiso 1 1 calc R . .
C64 C 0.5475(5) 1.2096(5) 0.6475(4) 0.061(2) Uani 1 1 d . . .
H64A H 0.5376 1.2612 0.6850 0.073 Uiso 1 1 calc R . .
H64B H 0.4895 1.1959 0.6000 0.073 Uiso 1 1 calc R . .
C65 C 0.6678(4) 1.2185(3) 0.6290(3) 0.0353(13) Uani 1 1 d . . .
H65 H 0.7150 1.2699 0.6518 0.042 Uiso 1 1 calc R . .
C66 C 0.7158(4) 1.1587(4) 0.5818(3) 0.0390(14) Uani 1 1 d . . .
H66 H 0.7935 1.1710 0.5746 0.047 Uiso 1 1 calc R . .
C67 C 0.6501(6) 1.0743(4) 0.5409(4) 0.067(2) Uani 1 1 d . . .
H67A H 0.5669 1.0753 0.5251 0.080 Uiso 1 1 calc R . .
H67B H 0.6812 1.0490 0.4935 0.080 Uiso 1 1 calc R . .
C68 C 0.6563(5) 1.0248(4) 0.5861(4) 0.061(2) Uani 1 1 d . . .
H68A H 0.5796 0.9895 0.5743 0.074 Uiso 1 1 calc R . .
H68B H 0.7151 0.9910 0.5701 0.074 Uiso 1 1 calc R . .
C69 C 1.0290(4) 1.4377(3) 0.7647(3) 0.0335(12) Uani 1 1 d . . .
H69A H 1.0412 1.4867 0.8109 0.050 Uiso 1 1 calc R . .
H69B H 0.9867 1.4453 0.7210 0.050 Uiso 1 1 calc R . .
H69C H 1.1048 1.4244 0.7538 0.050 Uiso 1 1 calc R . .
C70 C 0.7974(4) 1.3853(3) 0.7993(3) 0.0324(12) Uani 1 1 d . . .
H70A H 0.7488 1.3442 0.8091 0.049 Uiso 1 1 calc R . .
H70B H 0.7576 1.3917 0.7542 0.049 Uiso 1 1 calc R . .
H70C H 0.8106 1.4355 0.8442 0.049 Uiso 1 1 calc R . .
C71 C 0.9762(4) 1.0518(3) 0.6878(3) 0.0252(10) Uani 1 1 d . . .
H71A H 0.9402 1.0642 0.6455 0.038 Uiso 1 1 calc R . .
H71B H 0.9231 1.0095 0.6930 0.038 Uiso 1 1 calc R . .
H71C H 1.0500 1.0344 0.6771 0.038 Uiso 1 1 calc R . .
C72 C 1.0594(4) 1.1151(3) 0.8608(3) 0.0272(10) Uani 1 1 d . . .
H72A H 1.1308 1.0936 0.8520 0.041 Uiso 1 1 calc R . .
H72B H 0.9995 1.0752 0.8643 0.041 Uiso 1 1 calc R . .
H72C H 1.0762 1.1623 0.9088 0.041 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 C2 38.6(2) . . ?
C1 Rh1 C6 81.75(19) . . ?
C2 Rh1 C6 91.1(2) . . ?
C1 Rh1 C5 97.65(18) . . ?
C2 Rh1 C5 82.33(19) . . ?
C6 Rh1 C5 38.21(18) . . ?
C1 Rh1 O3 167.27(17) . . ?
C2 Rh1 O3 154.13(16) . . ?
C6 Rh1 O3 94.72(16) . . ?
C5 Rh1 O3 86.74(15) . . ?
C1 Rh1 O1 87.21(15) . . ?
C2 Rh1 O1 93.93(16) . . ?
C6 Rh1 O1 155.33(15) . . ?
C5 Rh1 O1 166.42(16) . . ?
O3 Rh1 O1 91.24(10) . . ?
O3 Rh2 O2 88.70(11) . . ?
O3 Rh2 C10 92.80(16) . . ?
O2 Rh2 C10 152.51(18) . . ?
O3 Rh2 C14 154.53(15) . . ?
O2 Rh2 C14 94.28(16) . . ?
C10 Rh2 C14 96.0(2) . . ?
O3 Rh2 C13 167.22(15) . . ?
O2 Rh2 C13 90.07(15) . . ?
C10 Rh2 C13 82.50(19) . . ?
C14 Rh2 C13 38.24(17) . . ?
O3 Rh2 C9 90.59(16) . . ?
O2 Rh2 C9 169.28(18) . . ?
C10 Rh2 C9 38.2(2) . . ?
C14 Rh2 C9 81.85(19) . . ?
C13 Rh2 C9 92.9(2) . . ?
C18 Rh3 C21 82.3(2) . . ?
C18 Rh3 C17 38.60(19) . . ?
C21 Rh3 C17 98.83(19) . . ?
C18 Rh3 O2 156.05(17) . . ?
C21 Rh3 O2 86.90(16) . . ?
C17 Rh3 O2 165.34(17) . . ?
C18 Rh3 C22 89.88(18) . . ?
C21 Rh3 C22 38.45(17) . . ?
C17 Rh3 C22 81.80(18) . . ?
O2 Rh3 C22 94.82(14) . . ?
C18 Rh3 O4 92.80(15) . . ?
C21 Rh3 O4 163.14(16) . . ?
C17 Rh3 O4 86.88(15) . . ?
O2 Rh3 O4 91.46(10) . . ?
C22 Rh3 O4 158.23(14) . . ?
O1 Rh4 O4 88.60(11) . . ?
O1 Rh4 C26 152.22(14) . . ?
O4 Rh4 C26 91.64(14) . . ?
O1 Rh4 C30 92.88(15) . . ?
O4 Rh4 C30 154.15(14) . . ?
C26 Rh4 C30 98.75(17) . . ?
O1 Rh4 C29 91.12(15) . . ?
O4 Rh4 C29 167.39(14) . . ?
C26 Rh4 C29 82.77(17) . . ?
C30 Rh4 C29 38.45(16) . . ?
O1 Rh4 C25 169.39(14) . . ?
O4 Rh4 C25 92.62(14) . . ?
C26 Rh4 C25 38.32(16) . . ?
C30 Rh4 C25 81.47(18) . . ?
C29 Rh4 C25 89.97(17) . . ?
C42 Rh5 C37 82.12(18) . . ?
C42 Rh5 O8 161.95(16) . . ?
C37 Rh5 O8 92.55(14) . . ?
C42 Rh5 C38 98.15(19) . . ?
C37 Rh5 C38 38.07(18) . . ?
O8 Rh5 C38 87.82(16) . . ?
C42 Rh5 C41 38.45(19) . . ?
C37 Rh5 C41 90.03(18) . . ?
O8 Rh5 C41 159.42(17) . . ?
C38 Rh5 C41 81.7(2) . . ?
C42 Rh5 O5 88.21(15) . . ?
C37 Rh5 O5 157.01(16) . . ?
O8 Rh5 O5 90.26(11) . . ?
C38 Rh5 O5 164.92(16) . . ?
C41 Rh5 O5 95.30(17) . . ?
C49 Rh6 O6 148.32(16) . . ?
C49 Rh6 O5 93.43(18) . . ?
O6 Rh6 O5 89.37(11) . . ?
C49 Rh6 C45 96.7(2) . . ?
O6 Rh6 C45 96.65(16) . . ?
O5 Rh6 C45 149.68(17) . . ?
C49 Rh6 C46 82.5(2) . . ?
O6 Rh6 C46 90.21(17) . . ?
O5 Rh6 C46 171.57(17) . . ?
C45 Rh6 C46 38.7(2) . . ?
C49 Rh6 C50 38.43(19) . . ?
O6 Rh6 C50 173.05(16) . . ?
O5 Rh6 C50 88.16(16) . . ?
C45 Rh6 C50 82.3(2) . . ?
C46 Rh6 C50 93.2(2) . . ?
C54 Rh7 C58 98.6(2) . . ?
C54 Rh7 C57 82.2(2) . . ?
C58 Rh7 C57 38.3(2) . . ?
C54 Rh7 C53 38.1(2) . . ?
C58 Rh7 C53 81.69(18) . . ?
C57 Rh7 C53 89.5(2) . . ?
C54 Rh7 O7 162.61(19) . . ?
C58 Rh7 O7 88.10(15) . . ?
C57 Rh7 O7 93.68(18) . . ?
C53 Rh7 O7 159.19(17) . . ?
C54 Rh7 O6 86.79(17) . . ?
C58 Rh7 O6 163.32(18) . . ?
C57 Rh7 O6 158.2(2) . . ?
C53 Rh7 O6 93.38(15) . . ?
O7 Rh7 O6 91.26(11) . . ?
C61 Rh8 O8 89.83(16) . . ?
C61 Rh8 C66 81.8(2) . . ?
O8 Rh8 C66 160.08(18) . . ?
C61 Rh8 C65 96.3(2) . . ?
O8 Rh8 C65 161.69(17) . . ?
C66 Rh8 C65 38.2(2) . . ?
C61 Rh8 O7 161.06(17) . . ?
O8 Rh8 O7 88.64(11) . . ?
C66 Rh8 O7 93.50(17) . . ?
C65 Rh8 O7 91.02(16) . . ?
C61 Rh8 C62 38.0(2) . . ?
O8 Rh8 C62 92.99(15) . . ?
C66 Rh8 C62 91.39(19) . . ?
C65 Rh8 C62 81.5(2) . . ?
O7 Rh8 C62 160.97(18) . . ?
O2 Si1 O1 112.20(14) . . ?
O2 Si1 C34 109.41(19) . . ?
O1 Si1 C34 108.65(18) . . ?
O2 Si1 C33 108.23(17) . . ?
O1 Si1 C33 109.32(18) . . ?
C34 Si1 C33 108.99(19) . . ?
O3 Si2 O4 111.57(15) . . ?
O3 Si2 C36 110.7(2) . . ?
O4 Si2 C36 109.3(2) . . ?
O3 Si2 C35 108.41(19) . . ?
O4 Si2 C35 110.4(2) . . ?
C36 Si2 C35 106.4(2) . . ?
O5 Si3 O7 111.65(16) . . ?
O5 Si3 C69 110.5(2) . . ?
O7 Si3 C69 109.6(2) . . ?
O5 Si3 C70 108.50(19) . . ?
O7 Si3 C70 110.0(2) . . ?
C69 Si3 C70 106.5(2) . . ?
O6 Si4 O8 111.93(16) . . ?
O6 Si4 C72 108.80(19) . . ?
O8 Si4 C72 109.04(18) . . ?
O6 Si4 C71 108.41(18) . . ?
O8 Si4 C71 109.63(18) . . ?
C72 Si4 C71 109.0(2) . . ?
Si1 O1 Rh4 118.68(15) . . ?
Si1 O1 Rh1 114.36(16) . . ?
Rh4 O1 Rh1 110.86(12) . . ?
Si1 O2 Rh2 121.30(15) . . ?
Si1 O2 Rh3 114.12(16) . . ?
Rh2 O2 Rh3 108.37(12) . . ?
Si2 O3 Rh2 120.95(15) . . ?
Si2 O3 Rh1 112.67(15) . . ?
Rh2 O3 Rh1 110.98(12) . . ?
Si2 O4 Rh4 119.73(15) . . ?
Si2 O4 Rh3 113.13(15) . . ?
Rh4 O4 Rh3 111.39(12) . . ?
Si3 O5 Rh6 122.83(15) . . ?
Si3 O5 Rh5 114.94(15) . . ?
Rh6 O5 Rh5 106.26(13) . . ?
Si4 O6 Rh6 121.63(15) . . ?
Si4 O6 Rh7 115.23(15) . . ?
Rh6 O6 Rh7 106.24(13) . . ?
Si3 O7 Rh8 115.28(15) . . ?
Si3 O7 Rh7 115.26(15) . . ?
Rh8 O7 Rh7 113.35(14) . . ?
Si4 O8 Rh8 115.51(14) . . ?
Si4 O8 Rh5 114.22(14) . . ?
Rh8 O8 Rh5 115.24(13) . . ?
C2 C1 C8 125.5(5) . . ?
C2 C1 Rh1 70.9(3) . . ?
C8 C1 Rh1 111.6(4) . . ?
C1 C2 C3 124.1(5) . . ?
C1 C2 Rh1 70.5(3) . . ?
C3 C2 Rh1 112.5(3) . . ?
C4 C3 C2 113.9(4) . . ?
C3 C4 C5 113.0(4) . . ?
C6 C5 C4 125.8(5) . . ?
C6 C5 Rh1 70.8(3) . . ?
C4 C5 Rh1 110.8(3) . . ?
C5 C6 C7 124.1(5) . . ?
C5 C6 Rh1 71.0(3) . . ?
C7 C6 Rh1 113.0(4) . . ?
C6 C7 C8 113.4(5) . . ?
C1 C8 C7 113.4(4) . . ?
C10 C9 C16 123.8(6) . . ?
C10 C9 Rh2 70.0(3) . . ?
C16 C9 Rh2 112.7(4) . . ?
C9 C10 C11 127.1(6) . . ?
C9 C10 Rh2 71.8(3) . . ?
C11 C10 Rh2 110.4(3) . . ?
C12 C11 C10 115.7(5) . . ?
C11 C12 C13 114.9(4) . . ?
C14 C13 C12 125.6(5) . . ?
C14 C13 Rh2 70.7(2) . . ?
C12 C13 Rh2 111.7(3) . . ?
C13 C14 C15 125.2(5) . . ?
C13 C14 Rh2 71.1(2) . . ?
C15 C14 Rh2 110.9(3) . . ?
C16 C15 C14 115.3(5) . . ?
C15 C16 C9 115.5(5) . . ?
C18 C17 C24 124.8(5) . . ?
C18 C17 Rh3 70.3(3) . . ?
C24 C17 Rh3 111.2(3) . . ?
C17 C18 C19 124.3(4) . . ?
C17 C18 Rh3 71.1(3) . . ?
C19 C18 Rh3 112.8(4) . . ?
C20 C19 C18 112.3(4) . . ?
C21 C20 C19 112.1(4) . . ?
C22 C21 C20 125.3(5) . . ?
C22 C21 Rh3 71.5(3) . . ?
C20 C21 Rh3 110.2(3) . . ?
C21 C22 C23 124.4(5) . . ?
C21 C22 Rh3 70.0(2) . . ?
C23 C22 Rh3 113.6(3) . . ?
C22 C23 C24 111.3(4) . . ?
C17 C24 C23 112.8(4) . . ?
C26 C25 C32 124.7(4) . . ?
C26 C25 Rh4 69.7(2) . . ?
C32 C25 Rh4 113.4(3) . . ?
C25 C26 C27 126.6(4) . . ?
C25 C26 Rh4 72.0(2) . . ?
C27 C26 Rh4 108.8(3) . . ?
C26 C27 C28 112.4(4) . . ?
C29 C28 C27 112.2(4) . . ?
C30 C29 C28 125.7(4) . . ?
C30 C29 Rh4 69.7(2) . . ?
C28 C29 Rh4 112.2(3) . . ?
C29 C30 C31 126.6(4) . . ?
C29 C30 Rh4 71.8(2) . . ?
C31 C30 Rh4 110.8(3) . . ?
C30 C31 C32 111.9(4) . . ?
C25 C32 C31 111.1(4) . . ?
C38 C37 C44 125.4(4) . . ?
C38 C37 Rh5 71.5(3) . . ?
C44 C37 Rh5 113.6(3) . . ?
C37 C38 C39 125.1(5) . . ?
C37 C38 Rh5 70.5(3) . . ?
C39 C38 Rh5 111.5(4) . . ?
C38 C39 C40 112.6(5) . . ?
C39 C40 C41 112.6(4) . . ?
C42 C41 C40 123.7(4) . . ?
C42 C41 Rh5 69.9(3) . . ?
C40 C41 Rh5 112.9(4) . . ?
C41 C42 C43 124.6(5) . . ?
C41 C42 Rh5 71.6(3) . . ?
C43 C42 Rh5 110.9(3) . . ?
C44 C43 C42 112.3(4) . . ?
C37 C44 C43 113.3(4) . . ?
C46 C45 C52 125.5(6) . . ?
C46 C45 Rh6 71.2(3) . . ?
C52 C45 Rh6 110.7(4) . . ?
C45 C46 C47 123.4(6) . . ?
C45 C46 Rh6 70.2(3) . . ?
C47 C46 Rh6 111.0(4) . . ?
C48 C47 C46 114.9(5) . . ?
C47 C48 C49 115.5(5) . . ?
C50 C49 C48 126.4(5) . . ?
C50 C49 Rh6 72.0(3) . . ?
C48 C49 Rh6 111.0(4) . . ?
C49 C50 C51 124.9(5) . . ?
C49 C50 Rh6 69.5(3) . . ?
C51 C50 Rh6 112.4(4) . . ?
C52 C51 C50 114.7(5) . . ?
C51 C52 C45 115.8(5) . . ?
C54 C53 C60 123.8(5) . . ?
C54 C53 Rh7 70.5(3) . . ?
C60 C53 Rh7 113.2(3) . . ?
C53 C54 C55 124.6(5) . . ?
C53 C54 Rh7 71.3(3) . . ?
C55 C54 Rh7 111.3(5) . . ?
C54 C55 C56 112.8(5) . . ?
C57 C56 C55 111.8(5) . . ?
C58 C57 C56 125.8(5) . . ?
C58 C57 Rh7 70.7(3) . . ?
C56 C57 Rh7 113.4(4) . . ?
C57 C58 C59 124.8(5) . . ?
C57 C58 Rh7 71.0(3) . . ?
C59 C58 Rh7 111.0(3) . . ?
C60 C59 C58 111.5(4) . . ?
C59 C60 C53 112.1(4) . . ?
C62 C61 C68 125.6(5) . . ?
C62 C61 Rh8 71.4(3) . . ?
C68 C61 Rh8 112.2(4) . . ?
C61 C62 C63 124.8(5) . . ?
C61 C62 Rh8 70.7(3) . . ?
C63 C62 Rh8 113.4(4) . . ?
C64 C63 C62 113.7(4) . . ?
C63 C64 C65 114.5(5) . . ?
C66 C65 C64 125.8(6) . . ?
C66 C65 Rh8 70.9(3) . . ?
C64 C65 Rh8 111.4(4) . . ?
C65 C66 C67 122.8(5) . . ?
C65 C66 Rh8 70.9(3) . . ?
C67 C66 Rh8 111.5(4) . . ?
C68 C67 C66 115.3(5) . . ?
C61 C68 C67 113.5(6) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 2.103(4) . ?
Rh1 C2 2.108(4) . ?
Rh1 C6 2.110(5) . ?
Rh1 C5 2.113(4) . ?
Rh1 O3 2.126(3) . ?
Rh1 O1 2.130(3) . ?
Rh2 O3 2.088(3) . ?
Rh2 O2 2.091(3) . ?
Rh2 C10 2.098(5) . ?
Rh2 C14 2.109(4) . ?
Rh2 C13 2.114(4) . ?
Rh2 C9 2.120(5) . ?
Rh3 C18 2.096(5) . ?
Rh3 C21 2.105(4) . ?
Rh3 C17 2.106(4) . ?
Rh3 O2 2.122(3) . ?
Rh3 C22 2.125(4) . ?
Rh3 O4 2.127(3) . ?
Rh4 O1 2.092(3) . ?
Rh4 O4 2.094(3) . ?
Rh4 C26 2.097(4) . ?
Rh4 C30 2.097(4) . ?
Rh4 C29 2.124(4) . ?
Rh4 C25 2.126(4) . ?
Rh5 C42 2.096(4) . ?
Rh5 C37 2.101(4) . ?
Rh5 O8 2.112(3) . ?
Rh5 C38 2.113(4) . ?
Rh5 C41 2.118(5) . ?
Rh5 O5 2.125(3) . ?
Rh6 C49 2.088(5) . ?
Rh6 O6 2.097(3) . ?
Rh6 O5 2.098(3) . ?
Rh6 C45 2.103(5) . ?
Rh6 C46 2.116(5) . ?
Rh6 C50 2.120(5) . ?
Rh7 C54 2.096(5) . ?
Rh7 C58 2.097(5) . ?
Rh7 C57 2.101(5) . ?
Rh7 C53 2.106(4) . ?
Rh7 O7 2.114(3) . ?
Rh7 O6 2.123(3) . ?
Rh8 C61 2.101(5) . ?
Rh8 O8 2.104(3) . ?
Rh8 C66 2.106(5) . ?
Rh8 C65 2.107(5) . ?
Rh8 O7 2.109(3) . ?
Rh8 C62 2.110(5) . ?
Si1 O2 1.636(3) . ?
Si1 O1 1.639(3) . ?
Si1 C34 1.866(4) . ?
Si1 C33 1.876(4) . ?
Si2 O3 1.633(3) . ?
Si2 O4 1.639(3) . ?
Si2 C36 1.864(5) . ?
Si2 C35 1.865(5) . ?
Si3 O5 1.631(3) . ?
Si3 O7 1.636(3) . ?
Si3 C69 1.866(5) . ?
Si3 C70 1.878(4) . ?
Si4 O6 1.630(3) . ?
Si4 O8 1.633(3) . ?
Si4 C72 1.862(4) . ?
Si4 C71 1.870(5) . ?
C1 C2 1.391(7) . ?
C1 C8 1.485(8) . ?
C2 C3 1.528(7) . ?
C3 C4 1.499(7) . ?
C4 C5 1.518(7) . ?
C5 C6 1.382(7) . ?
C6 C7 1.505(7) . ?
C7 C8 1.507(8) . ?
C9 C10 1.380(7) . ?
C9 C16 1.494(7) . ?
C10 C11 1.502(7) . ?
C11 C12 1.471(8) . ?
C12 C13 1.507(7) . ?
C13 C14 1.384(6) . ?
C14 C15 1.521(7) . ?
C15 C16 1.455(8) . ?
C17 C18 1.389(7) . ?
C17 C24 1.504(7) . ?
C18 C19 1.521(7) . ?
C19 C20 1.514(8) . ?
C20 C21 1.503(7) . ?
C21 C22 1.393(6) . ?
C22 C23 1.520(6) . ?
C23 C24 1.537(7) . ?
C25 C26 1.386(6) . ?
C25 C32 1.510(6) . ?
C26 C27 1.523(6) . ?
C27 C28 1.526(6) . ?
C28 C29 1.513(6) . ?
C29 C30 1.390(6) . ?
C30 C31 1.502(7) . ?
C31 C32 1.532(6) . ?
C37 C38 1.374(7) . ?
C37 C44 1.501(7) . ?
C38 C39 1.504(7) . ?
C39 C40 1.509(8) . ?
C40 C41 1.532(7) . ?
C41 C42 1.388(7) . ?
C42 C43 1.521(6) . ?
C43 C44 1.516(7) . ?
C45 C46 1.397(7) . ?
C45 C52 1.512(7) . ?
C46 C47 1.527(8) . ?
C47 C48 1.450(9) . ?
C48 C49 1.497(7) . ?
C49 C50 1.385(7) . ?
C50 C51 1.505(7) . ?
C51 C52 1.469(8) . ?
C53 C54 1.373(8) . ?
C53 C60 1.526(6) . ?
C54 C55 1.486(9) . ?
C55 C56 1.540(11) . ?
C56 C57 1.518(9) . ?
C57 C58 1.378(8) . ?
C58 C59 1.519(7) . ?
C59 C60 1.503(7) . ?
C61 C62 1.370(7) . ?
C61 C68 1.471(8) . ?
C62 C63 1.505(7) . ?
C63 C64 1.487(8) . ?
C64 C65 1.500(7) . ?
C65 C66 1.378(8) . ?
C66 C67 1.513(9) . ?
C67 C68 1.475(10) . ?
