#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:32:45 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179753 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/49/7004907.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7004907
loop_
_publ_author_name
'Zhang, Jing'
'Gandelman, Mark'
'Shimon, Linda J. W.'
'Milstein, David'
_publ_section_title
;
 Electron-rich, bulky PNN-type ruthenium complexes: synthesis,
 characterization and catalysis of alcohol dehydrogenation.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              107
_journal_page_last               113
_journal_paper_doi               10.1039/b613438f
_journal_year                    2007
_chemical_formula_sum            'C43 H80 Cl4 N6 P2 Ru2'
_chemical_formula_weight         1087.01
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.87(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.296(4)
_cell_length_b                   11.907(2)
_cell_length_c                   23.054(5)
_cell_measurement_reflns_used    11763
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.55
_cell_volume                     5277.7(18)
_computing_cell_refinement       HKL
_computing_data_collection       'Collect package (Bruker Nonius)'
_computing_data_reduction        HKL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Nonius KappaCCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0490
_diffrn_reflns_av_sigmaI/netI    0.0435
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            11997
_diffrn_reflns_theta_full        27.46
_diffrn_reflns_theta_max         27.46
_diffrn_reflns_theta_min         2.62
_exptl_absorpt_coefficient_mu    0.870
_exptl_absorpt_correction_T_max  0.9181
_exptl_absorpt_correction_T_min  0.9181
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.368
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2264
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.774
_refine_diff_density_min         -1.047
_refine_diff_density_rms         0.136
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     520
_refine_ls_number_reflns         11997
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0842
_refine_ls_R_factor_gt           0.0610
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0623P)²+28.2925P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1513
_refine_ls_wR_factor_ref         0.1607
_reflns_number_gt                9283
_reflns_number_total             11997
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b613438f.txt
_cod_data_source_block           m394new
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7004907
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.112542(18) 0.45005(3) 0.152701(16) 0.02362(11) Uani 1 1 d . . .
Cl1 Cl 0.13964(6) 0.56206(10) 0.06980(5) 0.0279(2) Uani 1 1 d . . .
Cl2 Cl 0.07941(6) 0.32435(12) 0.22735(5) 0.0350(3) Uani 1 1 d . . .
P1 P 0.11633(6) 0.59785(13) 0.21823(5) 0.0287(3) Uani 1 1 d . . .
N1 N 0.01022(19) 0.4900(4) 0.14277(17) 0.0246(8) Uani 1 1 d . . .
C1 C 0.0249(2) 0.5861(5) 0.2363(2) 0.0309(11) Uani 1 1 d . . .
H1A H 0.0217 0.5307 0.2679 0.037 Uiso 1 1 calc R . .
H1B H 0.0087 0.6596 0.2500 0.037 Uiso 1 1 calc R . .
C2 C -0.0206(2) 0.5496(4) 0.1834(2) 0.0276(10) Uani 1 1 d . . .
C3 C -0.0916(3) 0.5738(5) 0.1756(2) 0.0311(11) Uani 1 1 d . . .
H3 H -0.1129 0.6180 0.2034 0.037 Uiso 1 1 calc R . .
C4 C -0.1306(3) 0.5330(5) 0.1273(2) 0.0319(11) Uani 1 1 d . . .
H4 H -0.1789 0.5490 0.1217 0.038 Uiso 1 1 calc R . .
C5 C -0.0988(3) 0.4685(5) 0.0869(2) 0.0318(11) Uani 1 1 d . . .
H5 H -0.1254 0.4387 0.0539 0.038 Uiso 1 1 calc R . .
C6 C -0.0278(2) 0.4480(4) 0.0952(2) 0.0258(10) Uani 1 1 d . . .
C7 C 0.0130(2) 0.3864(4) 0.0527(2) 0.0287(10) Uani 1 1 d . . .
H7A H -0.0184 0.3349 0.0293 0.034 Uiso 1 1 calc R . .
H7B H 0.0318 0.4411 0.0258 0.034 Uiso 1 1 calc R . .
N2 N 0.0719(2) 0.3200(3) 0.08238(18) 0.0272(9) Uani 1 1 d . . .
C8 C 0.1686(3) 0.5914(6) 0.2917(2) 0.0399(14) Uani 1 1 d . . .
C9 C 0.1334(3) 0.6541(7) 0.3397(2) 0.0523(18) Uani 1 1 d . . .
H9A H 0.0874 0.6216 0.3435 0.078 Uiso 1 1 calc R . .
H9B H 0.1285 0.7337 0.3293 0.078 Uiso 1 1 calc R . .
H9C H 0.1620 0.6468 0.3767 0.078 Uiso 1 1 calc R . .
C10 C 0.2420(3) 0.6392(7) 0.2866(3) 0.0518(17) Uani 1 1 d . . .
H10A H 0.2718 0.6211 0.3219 0.078 Uiso 1 1 calc R . .
H10B H 0.2392 0.7209 0.2819 0.078 Uiso 1 1 calc R . .
H10C H 0.2617 0.6060 0.2527 0.078 Uiso 1 1 calc R . .
C11 C 0.1774(3) 0.4715(6) 0.3121(2) 0.0459(15) Uani 1 1 d . . .
H11A H 0.1979 0.4270 0.2822 0.069 Uiso 1 1 calc R . .
H11B H 0.1318 0.4402 0.3192 0.069 Uiso 1 1 calc R . .
H11C H 0.2080 0.4692 0.3482 0.069 Uiso 1 1 calc R . .
C12 C 0.1215(3) 0.7478(5) 0.1897(2) 0.0364(12) Uani 1 1 d . . .
C13 C 0.1143(3) 0.8392(6) 0.2360(3) 0.0454(14) Uani 1 1 d . . .
H13A H 0.1544 0.8361 0.2650 0.068 Uiso 1 1 calc R . .
H13B H 0.0715 0.8265 0.2552 0.068 Uiso 1 1 calc R . .
H13C H 0.1122 0.9132 0.2173 0.068 Uiso 1 1 calc R . .
C14 C 0.0597(3) 0.7639(5) 0.1432(2) 0.0388(13) Uani 1 1 d . . .
H14A H 0.0640 0.8367 0.1240 0.058 Uiso 1 1 calc R . .
H14B H 0.0160 0.7615 0.1618 0.058 Uiso 1 1 calc R . .
H14C H 0.0600 0.7038 0.1142 0.058 Uiso 1 1 calc R . .
C15 C 0.1906(3) 0.7646(5) 0.1621(3) 0.0416(14) Uani 1 1 d . . .
H15A H 0.1894 0.8362 0.1410 0.062 Uiso 1 1 calc R . .
H15B H 0.1973 0.7030 0.1349 0.062 Uiso 1 1 calc R . .
H15C H 0.2290 0.7654 0.1927 0.062 Uiso 1 1 calc R . .
C16 C 0.0963(3) 0.1311(5) 0.1294(3) 0.0474(15) Uani 1 1 d . . .
H16A H 0.1197 0.0977 0.0975 0.071 Uiso 1 1 calc R . .
H16B H 0.0736 0.0719 0.1504 0.071 Uiso 1 1 calc R . .
H16C H 0.1306 0.1697 0.1562 0.071 Uiso 1 1 calc R . .
C17 C 0.1237(3) 0.2936(5) 0.0393(2) 0.0323(11) Uani 1 1 d . . .
H17A H 0.1622 0.2501 0.0596 0.039 Uiso 1 1 calc R . .
H17B H 0.1435 0.3653 0.0265 0.039 Uiso 1 1 calc R . .
C18 C 0.0965(3) 0.2285(6) -0.0144(2) 0.0441(14) Uani 1 1 d . . .
H18A H 0.0794 0.1551 -0.0028 0.066 Uiso 1 1 calc R . .
H18B H 0.1340 0.2180 -0.0400 0.066 Uiso 1 1 calc R . .
H18C H 0.0583 0.2704 -0.0353 0.066 Uiso 1 1 calc R . .
C19 C 0.0420(3) 0.2151(5) 0.1048(3) 0.0370(12) Uani 1 1 d . . .
H19A H 0.0127 0.1787 0.0728 0.044 Uiso 1 1 calc R . .
H19B H 0.0115 0.2349 0.1357 0.044 Uiso 1 1 calc R . .
N3 N 0.2666(2) 0.3787(4) 0.16535(19) 0.0293(9) Uani 1 1 d . . .
N4 N 0.2106(2) 0.4048(4) 0.16249(17) 0.0263(9) Uani 1 1 d . . .
Ru2 Ru 0.36140(2) 0.32626(3) 0.156964(19) 0.02845(12) Uani 1 1 d . . .
Cl3 Cl 0.41827(6) 0.47395(11) 0.21354(6) 0.0332(3) Uani 1 1 d . . .
Cl4 Cl 0.30751(8) 0.18925(13) 0.09029(9) 0.0595(5) Uani 1 1 d . . .
P2 P 0.37986(7) 0.20742(14) 0.23703(8) 0.0440(4) Uani 1 1 d . . .
N5 N 0.3791(2) 0.4287(4) 0.07418(19) 0.0353(10) Uani 1 1 d . . .
N6 N 0.4588(2) 0.2764(4) 0.1420(2) 0.0314(9) Uani 1 1 d . . .
C20 C 0.4258(3) 0.3500(6) 0.0451(3) 0.0479(16) Uani 1 1 d . . .
H20A H 0.4491 0.3910 0.0148 0.058 Uiso 1 1 calc R . .
H20B H 0.3977 0.2889 0.0259 0.058 Uiso 1 1 calc R . .
C21 C 0.4803(3) 0.3002(5) 0.0890(2) 0.0395(13) Uani 1 1 d . . .
C22 C 0.5468(3) 0.2723(6) 0.0757(3) 0.0478(16) Uani 1 1 d . . .
H22 H 0.5618 0.2896 0.0385 0.057 Uiso 1 1 calc R . .
C23 C 0.5914(3) 0.2187(6) 0.1175(3) 0.0448(14) Uani 1 1 d . . .
H23 H 0.6369 0.1978 0.1089 0.054 Uiso 1 1 calc R . .
C24 C 0.5693(3) 0.1961(5) 0.1713(3) 0.0371(12) Uani 1 1 d . . .
H24 H 0.5994 0.1593 0.2001 0.044 Uiso 1 1 calc R . .
C25 C 0.5025(2) 0.2277(4) 0.1835(2) 0.0318(11) Uani 1 1 d . . .
C26 C 0.4758(3) 0.2137(5) 0.2425(3) 0.0369(12) Uani 1 1 d . . .
H26A H 0.4918 0.2776 0.2677 0.044 Uiso 1 1 calc R . .
H26B H 0.4950 0.1439 0.2608 0.044 Uiso 1 1 calc R . .
C27 C 0.3616(3) 0.0518(6) 0.2269(5) 0.072(3) Uani 1 1 d . . .
C28 C 0.3808(4) -0.0242(8) 0.2789(5) 0.100(4) Uani 1 1 d . . .
H28A H 0.3736 -0.1028 0.2673 0.149 Uiso 1 1 calc R . .
H28B H 0.3514 -0.0061 0.3102 0.149 Uiso 1 1 calc R . .
H28C H 0.4298 -0.0125 0.2925 0.149 Uiso 1 1 calc R . .
C29 C 0.2826(4) 0.0346(7) 0.2078(6) 0.098(4) Uani 1 1 d . . .
H29A H 0.2758 -0.0383 0.1885 0.147 Uiso 1 1 calc R . .
H29B H 0.2665 0.0946 0.1808 0.147 Uiso 1 1 calc R . .
H29C H 0.2560 0.0370 0.2422 0.147 Uiso 1 1 calc R . .
C30 C 0.4041(4) 0.0121(6) 0.1783(4) 0.074(3) Uani 1 1 d . . .
H30A H 0.4536 0.0117 0.1921 0.111 Uiso 1 1 calc R . .
H30B H 0.3966 0.0629 0.1449 0.111 Uiso 1 1 calc R . .
H30C H 0.3897 -0.0640 0.1665 0.111 Uiso 1 1 calc R . .
C31 C 0.3574(3) 0.2471(8) 0.3147(3) 0.065(2) Uani 1 1 d . . .
C32 C 0.4101(4) 0.1965(9) 0.3618(4) 0.083(3) Uani 1 1 d . . .
H32A H 0.4562 0.2293 0.3583 0.124 Uiso 1 1 calc R . .
H32B H 0.4124 0.1150 0.3565 0.124 Uiso 1 1 calc R . .
H32C H 0.3952 0.2132 0.4004 0.124 Uiso 1 1 calc R . .
C33 C 0.3580(4) 0.3739(7) 0.3226(3) 0.060(2) Uani 1 1 d . . .
H33A H 0.3425 0.3925 0.3608 0.091 Uiso 1 1 calc R . .
H33B H 0.3266 0.4085 0.2920 0.091 Uiso 1 1 calc R . .
H33C H 0.4053 0.4023 0.3200 0.091 Uiso 1 1 calc R . .
C34 C 0.2833(4) 0.2045(9) 0.3237(5) 0.093(4) Uani 1 1 d . . .
H34A H 0.2671 0.2395 0.3586 0.139 Uiso 1 1 calc R . .
H34B H 0.2842 0.1227 0.3286 0.139 Uiso 1 1 calc R . .
H34C H 0.2516 0.2241 0.2897 0.139 Uiso 1 1 calc R . .
C35 C 0.4152(3) 0.5366(5) 0.0828(3) 0.0430(14) Uani 1 1 d . . .
H35A H 0.4335 0.5590 0.0457 0.052 Uiso 1 1 calc R . .
H35B H 0.4555 0.5261 0.1119 0.052 Uiso 1 1 calc R . .
C36 C 0.3710(3) 0.6306(6) 0.1029(3) 0.0509(16) Uani 1 1 d . . .
H36A H 0.3378 0.6543 0.0707 0.076 Uiso 1 1 calc R . .
H36B H 0.4008 0.6942 0.1155 0.076 Uiso 1 1 calc R . .
H36C H 0.3457 0.6047 0.1355 0.076 Uiso 1 1 calc R . .
C37 C 0.3127(3) 0.4417(6) 0.0353(3) 0.0452(15) Uani 1 1 d . . .
H37A H 0.2802 0.4884 0.0560 0.054 Uiso 1 1 calc R . .
H37B H 0.2913 0.3666 0.0294 0.054 Uiso 1 1 calc R . .
C38 C 0.3198(4) 0.4941(8) -0.0245(3) 0.067(2) Uani 1 1 d . . .
H38A H 0.3344 0.5726 -0.0196 0.100 Uiso 1 1 calc R . .
H38B H 0.2749 0.4908 -0.0477 0.100 Uiso 1 1 calc R . .
H38C H 0.3546 0.4525 -0.0444 0.100 Uiso 1 1 calc R . .
C39 C 0.7255(4) 0.1651(7) 0.0327(3) 0.069(2) Uani 1 1 d . . .
H39A H 0.7302 0.1562 0.0755 0.083 Uiso 1 1 calc R . .
H39B H 0.6801 0.2008 0.0212 0.083 Uiso 1 1 calc R . .
C40 C 0.7769(4) 0.2277(7) 0.0157(4) 0.069(2) Uani 1 1 d . . .
H40A H 0.7935 0.2797 0.0474 0.083 Uiso 1 1 calc R . .
H40B H 0.7599 0.2731 -0.0186 0.083 Uiso 1 1 calc R . .
C41 C 0.8345(5) 0.1561(9) 0.0006(4) 0.087(3) Uani 1 1 d . . .
H41A H 0.8714 0.1503 0.0331 0.104 Uiso 1 1 calc R . .
H41B H 0.8550 0.1830 -0.0348 0.104 Uiso 1 1 calc R . .
C42 C 0.7941(10) 0.0405(16) -0.0105(8) 0.166(6) Uiso 1 1 d . . .
H42A H 0.7908 0.0190 -0.0521 0.199 Uiso 1 1 calc R . .
H42B H 0.8162 -0.0211 0.0132 0.199 Uiso 1 1 calc R . .
C43 C 0.7295(14) 0.069(2) 0.0077(12) 0.239(11) Uiso 1 1 d . . .
H43A H 0.6951 0.0672 -0.0267 0.287 Uiso 1 1 calc R . .
H43B H 0.7159 0.0102 0.0350 0.287 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N4 Ru1 N1 177.65(17) . . ?
N4 Ru1 P1 99.02(13) . . ?
N1 Ru1 P1 82.63(12) . . ?
N4 Ru1 N2 99.33(16) . . ?
N1 Ru1 N2 79.05(15) . . ?
P1 Ru1 N2 161.64(10) . . ?
N4 Ru1 Cl2 93.39(12) . . ?
N1 Ru1 Cl2 84.91(12) . . ?
P1 Ru1 Cl2 90.10(5) . . ?
N2 Ru1 Cl2 89.44(11) . . ?
N4 Ru1 Cl1 88.35(12) . . ?
N1 Ru1 Cl1 93.16(12) . . ?
P1 Ru1 Cl1 95.70(5) . . ?
N2 Ru1 Cl1 84.22(11) . . ?
Cl2 Ru1 Cl1 173.62(5) . . ?
C1 P1 C8 103.9(2) . . ?
C1 P1 C12 103.1(3) . . ?
C8 P1 C12 107.8(3) . . ?
C1 P1 Ru1 96.37(18) . . ?
C8 P1 Ru1 122.4(2) . . ?
C12 P1 Ru1 119.05(17) . . ?
C2 N1 C6 120.7(4) . . ?
C2 N1 Ru1 121.8(3) . . ?
C6 N1 Ru1 117.3(3) . . ?
C2 C1 P1 110.0(3) . . ?
C2 C1 H1A 109.7 . . ?
P1 C1 H1A 109.7 . . ?
C2 C1 H1B 109.7 . . ?
P1 C1 H1B 109.7 . . ?
H1A C1 H1B 108.2 . . ?
N1 C2 C3 120.2(4) . . ?
N1 C2 C1 116.8(4) . . ?
C3 C2 C1 123.0(4) . . ?
C4 C3 C2 119.6(5) . . ?
C4 C3 H3 120.2 . . ?
C2 C3 H3 120.2 . . ?
C3 C4 C5 119.7(5) . . ?
C3 C4 H4 120.2 . . ?
C5 C4 H4 120.2 . . ?
C6 C5 C4 119.4(5) . . ?
C6 C5 H5 120.3 . . ?
C4 C5 H5 120.3 . . ?
N1 C6 C5 120.3(5) . . ?
N1 C6 C7 115.4(4) . . ?
C5 C6 C7 124.2(4) . . ?
N2 C7 C6 112.3(4) . . ?
N2 C7 H7A 109.1 . . ?
C6 C7 H7A 109.1 . . ?
N2 C7 H7B 109.1 . . ?
C6 C7 H7B 109.1 . . ?
H7A C7 H7B 107.9 . . ?
C19 N2 C7 107.4(4) . . ?
C19 N2 C17 110.7(4) . . ?
C7 N2 C17 109.3(4) . . ?
C19 N2 Ru1 115.7(3) . . ?
C7 N2 Ru1 99.5(3) . . ?
C17 N2 Ru1 113.3(3) . . ?
C11 C8 C9 106.2(5) . . ?
C11 C8 C10 107.1(5) . . ?
C9 C8 C10 110.0(5) . . ?
C11 C8 P1 110.6(4) . . ?
C9 C8 P1 112.8(4) . . ?
C10 C8 P1 109.8(4) . . ?
C8 C9 H9A 109.5 . . ?
C8 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C8 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C8 C10 H10A 109.5 . . ?
C8 C10 H10B 109.5 . . ?
H10A C10 H10B 109.5 . . ?
C8 C10 H10C 109.5 . . ?
H10A C10 H10C 109.5 . . ?
H10B C10 H10C 109.5 . . ?
C8 C11 H11A 109.5 . . ?
C8 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C8 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C15 C12 C13 109.1(5) . . ?
C15 C12 C14 109.9(5) . . ?
C13 C12 C14 106.5(5) . . ?
C15 C12 P1 109.7(4) . . ?
C13 C12 P1 114.3(4) . . ?
C14 C12 P1 107.2(4) . . ?
C12 C13 H13A 109.5 . . ?
C12 C13 H13B 109.5 . . ?
H13A C13 H13B 109.5 . . ?
C12 C13 H13C 109.5 . . ?
H13A C13 H13C 109.5 . . ?
H13B C13 H13C 109.5 . . ?
C12 C14 H14A 109.5 . . ?
C12 C14 H14B 109.5 . . ?
H14A C14 H14B 109.5 . . ?
C12 C14 H14C 109.5 . . ?
H14A C14 H14C 109.5 . . ?
H14B C14 H14C 109.5 . . ?
C12 C15 H15A 109.5 . . ?
C12 C15 H15B 109.5 . . ?
H15A C15 H15B 109.5 . . ?
C12 C15 H15C 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C19 C16 H16A 109.5 . . ?
C19 C16 H16B 109.5 . . ?
H16A C16 H16B 109.5 . . ?
C19 C16 H16C 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
N2 C17 C18 116.3(4) . . ?
N2 C17 H17A 108.2 . . ?
C18 C17 H17A 108.2 . . ?
N2 C17 H17B 108.2 . . ?
C18 C17 H17B 108.2 . . ?
H17A C17 H17B 107.4 . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
N2 C19 C16 113.9(5) . . ?
N2 C19 H19A 108.8 . . ?
C16 C19 H19A 108.8 . . ?
N2 C19 H19B 108.8 . . ?
C16 C19 H19B 108.8 . . ?
H19A C19 H19B 107.7 . . ?
N4 N3 Ru2 170.7(4) . . ?
N3 N4 Ru1 176.8(4) . . ?
N3 Ru2 N6 175.68(18) . . ?
N3 Ru2 N5 96.76(16) . . ?
N6 Ru2 N5 79.10(17) . . ?
N3 Ru2 P2 101.34(13) . . ?
N6 Ru2 P2 82.82(14) . . ?
N5 Ru2 P2 161.88(11) . . ?
N3 Ru2 Cl3 95.78(13) . . ?
N6 Ru2 Cl3 85.39(13) . . ?
N5 Ru2 Cl3 88.24(12) . . ?
P2 Ru2 Cl3 88.99(6) . . ?
N3 Ru2 Cl4 85.56(13) . . ?
N6 Ru2 Cl4 92.81(13) . . ?
N5 Ru2 Cl4 85.23(13) . . ?
P2 Ru2 Cl4 97.04(7) . . ?
Cl3 Ru2 Cl4 173.45(6) . . ?
C26 P2 C27 102.9(3) . . ?
C26 P2 C31 103.2(3) . . ?
C27 P2 C31 107.4(4) . . ?
C26 P2 Ru2 96.57(19) . . ?
C27 P2 Ru2 118.8(3) . . ?
C31 P2 Ru2 123.6(2) . . ?
C35 N5 C20 108.2(5) . . ?
C35 N5 C37 111.1(5) . . ?
C20 N5 C37 108.2(4) . . ?
C35 N5 Ru2 116.8(3) . . ?
C20 N5 Ru2 100.1(4) . . ?
C37 N5 Ru2 111.5(4) . . ?
C25 N6 C21 120.5(4) . . ?
C25 N6 Ru2 122.5(4) . . ?
C21 N6 Ru2 116.8(3) . . ?
N5 C20 C21 110.9(5) . . ?
N5 C20 H20A 109.5 . . ?
C21 C20 H20A 109.5 . . ?
N5 C20 H20B 109.5 . . ?
C21 C20 H20B 109.5 . . ?
H20A C20 H20B 108.0 . . ?
N6 C21 C22 120.7(5) . . ?
N6 C21 C20 115.8(5) . . ?
C22 C21 C20 123.3(6) . . ?
C21 C22 C23 119.1(6) . . ?
C21 C22 H22 120.4 . . ?
C23 C22 H22 120.4 . . ?
C24 C23 C22 119.7(5) . . ?
C24 C23 H23 120.2 . . ?
C22 C23 H23 120.2 . . ?
C23 C24 C25 119.5(5) . . ?
C23 C24 H24 120.2 . . ?
C25 C24 H24 120.2 . . ?
N6 C25 C24 120.4(5) . . ?
N6 C25 C26 116.5(4) . . ?
C24 C25 C26 123.1(5) . . ?
C25 C26 P2 111.2(4) . . ?
C25 C26 H26A 109.4 . . ?
P2 C26 H26A 109.4 . . ?
C25 C26 H26B 109.4 . . ?
P2 C26 H26B 109.4 . . ?
H26A C26 H26B 108.0 . . ?
C30 C27 C28 106.6(7) . . ?
C30 C27 C29 109.0(8) . . ?
C28 C27 C29 108.1(7) . . ?
C30 C27 P2 106.8(5) . . ?
C28 C27 P2 116.9(7) . . ?
C29 C27 P2 109.2(5) . . ?
C27 C28 H28A 109.5 . . ?
C27 C28 H28B 109.5 . . ?
H28A C28 H28B 109.5 . . ?
C27 C28 H28C 109.5 . . ?
H28A C28 H28C 109.5 . . ?
H28B C28 H28C 109.5 . . ?
C27 C29 H29A 109.5 . . ?
C27 C29 H29B 109.5 . . ?
H29A C29 H29B 109.5 . . ?
C27 C29 H29C 109.5 . . ?
H29A C29 H29C 109.5 . . ?
H29B C29 H29C 109.5 . . ?
C27 C30 H30A 109.5 . . ?
C27 C30 H30B 109.5 . . ?
H30A C30 H30B 109.5 . . ?
C27 C30 H30C 109.5 . . ?
H30A C30 H30C 109.5 . . ?
H30B C30 H30C 109.5 . . ?
C33 C31 C32 107.8(8) . . ?
C33 C31 C34 107.9(6) . . ?
C32 C31 C34 109.7(6) . . ?
C33 C31 P2 110.7(4) . . ?
C32 C31 P2 111.7(5) . . ?
C34 C31 P2 109.0(7) . . ?
C31 C32 H32A 109.5 . . ?
C31 C32 H32B 109.5 . . ?
H32A C32 H32B 109.5 . . ?
C31 C32 H32C 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
C31 C33 H33A 109.5 . . ?
C31 C33 H33B 109.5 . . ?
H33A C33 H33B 109.5 . . ?
C31 C33 H33C 109.5 . . ?
H33A C33 H33C 109.5 . . ?
H33B C33 H33C 109.5 . . ?
C31 C34 H34A 109.5 . . ?
C31 C34 H34B 109.5 . . ?
H34A C34 H34B 109.5 . . ?
C31 C34 H34C 109.5 . . ?
H34A C34 H34C 109.5 . . ?
H34B C34 H34C 109.5 . . ?
N5 C35 C36 114.8(5) . . ?
N5 C35 H35A 108.6 . . ?
C36 C35 H35A 108.6 . . ?
N5 C35 H35B 108.6 . . ?
C36 C35 H35B 108.6 . . ?
H35A C35 H35B 107.6 . . ?
C35 C36 H36A 109.5 . . ?
C35 C36 H36B 109.5 . . ?
H36A C36 H36B 109.5 . . ?
C35 C36 H36C 109.5 . . ?
H36A C36 H36C 109.5 . . ?
H36B C36 H36C 109.5 . . ?
N5 C37 C38 116.2(5) . . ?
N5 C37 H37A 108.2 . . ?
C38 C37 H37A 108.2 . . ?
N5 C37 H37B 108.2 . . ?
C38 C37 H37B 108.2 . . ?
H37A C37 H37B 107.4 . . ?
C37 C38 H38A 109.5 . . ?
C37 C38 H38B 109.5 . . ?
H38A C38 H38B 109.5 . . ?
C37 C38 H38C 109.5 . . ?
H38A C38 H38C 109.5 . . ?
H38B C38 H38C 109.5 . . ?
C43 C39 C40 107.0(13) . . ?
C43 C39 H39A 110.3 . . ?
C40 C39 H39A 110.3 . . ?
C43 C39 H39B 110.3 . . ?
C40 C39 H39B 110.3 . . ?
H39A C39 H39B 108.6 . . ?
C39 C40 C41 110.2(8) . . ?
C39 C40 H40A 109.6 . . ?
C41 C40 H40A 109.6 . . ?
C39 C40 H40B 109.6 . . ?
C41 C40 H40B 109.6 . . ?
H40A C40 H40B 108.1 . . ?
C40 C41 C42 99.8(10) . . ?
C40 C41 H41A 111.8 . . ?
C42 C41 H41A 111.8 . . ?
C40 C41 H41B 111.8 . . ?
C42 C41 H41B 111.8 . . ?
H41A C41 H41B 109.5 . . ?
C43 C42 C41 100.5(17) . . ?
C43 C42 H42A 111.7 . . ?
C41 C42 H42A 111.7 . . ?
C43 C42 H42B 111.7 . . ?
C41 C42 H42B 111.7 . . ?
H42A C42 H42B 109.5 . . ?
C39 C43 C42 116(2) . . ?
C39 C43 H43A 108.3 . . ?
C42 C43 H43A 108.3 . . ?
C39 C43 H43B 108.3 . . ?
C42 C43 H43B 108.3 . . ?
H43A C43 H43B 107.4 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 N4 1.961(4) . ?
Ru1 N1 2.025(4) . ?
Ru1 P1 2.3165(14) . ?
Ru1 N2 2.329(4) . ?
Ru1 Cl2 2.4079(13) . ?
Ru1 Cl1 2.4238(13) . ?
P1 C1 1.852(5) . ?
P1 C8 1.899(5) . ?
P1 C12 1.908(6) . ?
N1 C2 1.354(6) . ?
N1 C6 1.361(6) . ?
C1 C2 1.503(7) . ?
C1 H1A 0.9900 . ?
C1 H1B 0.9900 . ?
C2 C3 1.395(7) . ?
C3 C4 1.378(7) . ?
C3 H3 0.9500 . ?
C4 C5 1.389(8) . ?
C4 H4 0.9500 . ?
C5 C6 1.389(7) . ?
C5 H5 0.9500 . ?
C6 C7 1.501(7) . ?
C7 N2 1.500(6) . ?
C7 H7A 0.9900 . ?
C7 H7B 0.9900 . ?
N2 C19 1.488(7) . ?
N2 C17 1.501(6) . ?
C8 C11 1.509(9) . ?
C8 C9 1.539(8) . ?
C8 C10 1.540(8) . ?
C9 H9A 0.9800 . ?
C9 H9B 0.9800 . ?
C9 H9C 0.9800 . ?
C10 H10A 0.9800 . ?
C10 H10B 0.9800 . ?
C10 H10C 0.9800 . ?
C11 H11A 0.9800 . ?
C11 H11B 0.9800 . ?
C11 H11C 0.9800 . ?
C12 C15 1.539(8) . ?
C12 C13 1.540(8) . ?
C12 C14 1.545(7) . ?
C13 H13A 0.9800 . ?
C13 H13B 0.9800 . ?
C13 H13C 0.9800 . ?
C14 H14A 0.9800 . ?
C14 H14B 0.9800 . ?
C14 H14C 0.9800 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 C19 1.523(8) . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
C17 C18 1.517(8) . ?
C17 H17A 0.9900 . ?
C17 H17B 0.9900 . ?
C18 H18A 0.9800 . ?
C18 H18B 0.9800 . ?
C18 H18C 0.9800 . ?
C19 H19A 0.9900 . ?
C19 H19B 0.9900 . ?
N3 N4 1.121(6) . ?
N3 Ru2 1.958(4) . ?
Ru2 N6 2.028(4) . ?
Ru2 N5 2.315(5) . ?
Ru2 P2 2.3291(17) . ?
Ru2 Cl3 2.3988(14) . ?
Ru2 Cl4 2.4154(16) . ?
P2 C26 1.847(5) . ?
P2 C27 1.897(8) . ?
P2 C31 1.935(8) . ?
N5 C35 1.466(8) . ?
N5 C20 1.498(7) . ?
N5 C37 1.507(7) . ?
N6 C25 1.351(7) . ?
N6 C21 1.355(7) . ?
C20 C21 1.516(8) . ?
C20 H20A 0.9900 . ?
C20 H20B 0.9900 . ?
C21 C22 1.384(8) . ?
C22 C23 1.393(8) . ?
C22 H22 0.9500 . ?
C23 C24 1.372(9) . ?
C23 H23 0.9500 . ?
C24 C25 1.395(7) . ?
C24 H24 0.9500 . ?
C25 C26 1.504(8) . ?
C26 H26A 0.9900 . ?
C26 H26B 0.9900 . ?
C27 C30 1.520(13) . ?
C27 C28 1.521(12) . ?
C27 C29 1.563(10) . ?
C28 H28A 0.9800 . ?
C28 H28B 0.9800 . ?
C28 H28C 0.9800 . ?
C29 H29A 0.9800 . ?
C29 H29B 0.9800 . ?
C29 H29C 0.9800 . ?
C30 H30A 0.9800 . ?
C30 H30B 0.9800 . ?
C30 H30C 0.9800 . ?
C31 C33 1.520(12) . ?
C31 C32 1.546(9) . ?
C31 C34 1.549(10) . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
C33 H33A 0.9800 . ?
C33 H33B 0.9800 . ?
C33 H33C 0.9800 . ?
C34 H34A 0.9800 . ?
C34 H34B 0.9800 . ?
C34 H34C 0.9800 . ?
C35 C36 1.503(9) . ?
C35 H35A 0.9900 . ?
C35 H35B 0.9900 . ?
C36 H36A 0.9800 . ?
C36 H36B 0.9800 . ?
C36 H36C 0.9800 . ?
C37 C38 1.529(10) . ?
C37 H37A 0.9900 . ?
C37 H37B 0.9900 . ?
C38 H38A 0.9800 . ?
C38 H38B 0.9800 . ?
C38 H38C 0.9800 . ?
C39 C43 1.29(2) . ?
C39 C40 1.326(10) . ?
C39 H39A 0.9900 . ?
C39 H39B 0.9900 . ?
C40 C41 1.465(12) . ?
C40 H40A 0.9900 . ?
C40 H40B 0.9900 . ?
C41 C42 1.592(19) . ?
C41 H41A 0.9900 . ?
C41 H41B 0.9900 . ?
C42 C43 1.39(2) . ?
C42 H42A 0.9900 . ?
C42 H42B 0.9900 . ?
C43 H43A 0.9900 . ?
C43 H43B 0.9900 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N4 Ru1 P1 C1 -151.7(2) . . . . ?
N1 Ru1 P1 C1 26.6(2) . . . . ?
N2 Ru1 P1 C1 30.3(4) . . . . ?
Cl2 Ru1 P1 C1 -58.22(18) . . . . ?
Cl1 Ru1 P1 C1 119.11(18) . . . . ?
N4 Ru1 P1 C8 -40.7(3) . . . . ?
N1 Ru1 P1 C8 137.6(3) . . . . ?
N2 Ru1 P1 C8 141.3(4) . . . . ?
Cl2 Ru1 P1 C8 52.8(2) . . . . ?
Cl1 Ru1 P1 C8 -129.9(2) . . . . ?
N4 Ru1 P1 C12 99.5(2) . . . . ?
N1 Ru1 P1 C12 -82.2(2) . . . . ?
N2 Ru1 P1 C12 -78.5(4) . . . . ?
Cl2 Ru1 P1 C12 -167.04(19) . . . . ?
Cl1 Ru1 P1 C12 10.28(19) . . . . ?
N4 Ru1 N1 C2 114(4) . . . . ?
P1 Ru1 N1 C2 -20.2(4) . . . . ?
N2 Ru1 N1 C2 161.0(4) . . . . ?
Cl2 Ru1 N1 C2 70.6(4) . . . . ?
Cl1 Ru1 N1 C2 -115.5(4) . . . . ?
N4 Ru1 N1 C6 -61(4) . . . . ?
P1 Ru1 N1 C6 164.2(4) . . . . ?
N2 Ru1 N1 C6 -14.6(3) . . . . ?
Cl2 Ru1 N1 C6 -105.1(3) . . . . ?
Cl1 Ru1 N1 C6 68.8(3) . . . . ?
C8 P1 C1 C2 -160.3(4) . . . . ?
C12 P1 C1 C2 87.3(4) . . . . ?
Ru1 P1 C1 C2 -34.5(4) . . . . ?
C6 N1 C2 C3 -3.3(7) . . . . ?
Ru1 N1 C2 C3 -178.8(4) . . . . ?
C6 N1 C2 C1 176.1(5) . . . . ?
Ru1 N1 C2 C1 0.6(6) . . . . ?
P1 C1 C2 N1 26.0(6) . . . . ?
P1 C1 C2 C3 -154.6(4) . . . . ?
N1 C2 C3 C4 2.4(8) . . . . ?
C1 C2 C3 C4 -177.0(5) . . . . ?
C2 C3 C4 C5 -0.1(8) . . . . ?
C3 C4 C5 C6 -1.3(8) . . . . ?
C2 N1 C6 C5 1.9(7) . . . . ?
Ru1 N1 C6 C5 177.5(4) . . . . ?
C2 N1 C6 C7 178.4(4) . . . . ?
Ru1 N1 C6 C7 -6.0(6) . . . . ?
C4 C5 C6 N1 0.5(8) . . . . ?
C4 C5 C6 C7 -175.7(5) . . . . ?
N1 C6 C7 N2 36.5(6) . . . . ?
C5 C6 C7 N2 -147.1(5) . . . . ?
C6 C7 N2 C19 78.9(5) . . . . ?
C6 C7 N2 C17 -161.0(4) . . . . ?
C6 C7 N2 Ru1 -42.0(4) . . . . ?
N4 Ru1 N2 C19 93.7(3) . . . . ?
N1 Ru1 N2 C19 -84.5(3) . . . . ?
P1 Ru1 N2 C19 -88.2(5) . . . . ?
Cl2 Ru1 N2 C19 0.4(3) . . . . ?
Cl1 Ru1 N2 C19 -178.9(3) . . . . ?
N4 Ru1 N2 C7 -151.6(3) . . . . ?
N1 Ru1 N2 C7 30.1(3) . . . . ?
P1 Ru1 N2 C7 26.4(5) . . . . ?
Cl2 Ru1 N2 C7 115.1(3) . . . . ?
Cl1 Ru1 N2 C7 -64.2(3) . . . . ?
N4 Ru1 N2 C17 -35.7(3) . . . . ?
N1 Ru1 N2 C17 146.0(3) . . . . ?
P1 Ru1 N2 C17 142.3(3) . . . . ?
Cl2 Ru1 N2 C17 -129.1(3) . . . . ?
Cl1 Ru1 N2 C17 51.6(3) . . . . ?
C1 P1 C8 C11 80.9(4) . . . . ?
C12 P1 C8 C11 -170.1(4) . . . . ?
Ru1 P1 C8 C11 -26.1(5) . . . . ?
C1 P1 C8 C9 -38.0(6) . . . . ?
C12 P1 C8 C9 71.0(5) . . . . ?
Ru1 P1 C8 C9 -145.0(4) . . . . ?
C1 P1 C8 C10 -161.0(5) . . . . ?
C12 P1 C8 C10 -52.0(5) . . . . ?
Ru1 P1 C8 C10 91.9(5) . . . . ?
C1 P1 C12 C15 -169.6(4) . . . . ?
C8 P1 C12 C15 80.9(4) . . . . ?
Ru1 P1 C12 C15 -64.5(4) . . . . ?
C1 P1 C12 C13 67.5(4) . . . . ?
C8 P1 C12 C13 -42.0(5) . . . . ?
Ru1 P1 C12 C13 172.6(3) . . . . ?
C1 P1 C12 C14 -50.3(4) . . . . ?
C8 P1 C12 C14 -159.8(4) . . . . ?
Ru1 P1 C12 C14 54.8(4) . . . . ?
C19 N2 C17 C18 59.9(6) . . . . ?
C7 N2 C17 C18 -58.2(6) . . . . ?
Ru1 N2 C17 C18 -168.1(4) . . . . ?
C7 N2 C19 C16 172.6(5) . . . . ?
C17 N2 C19 C16 53.3(6) . . . . ?
Ru1 N2 C19 C16 -77.4(5) . . . . ?
Ru2 N3 N4 Ru1 -14(9) . . . . ?
N1 Ru1 N4 N3 91(8) . . . . ?
P1 Ru1 N4 N3 -135(7) . . . . ?
N2 Ru1 N4 N3 44(7) . . . . ?
Cl2 Ru1 N4 N3 134(7) . . . . ?
Cl1 Ru1 N4 N3 -39(7) . . . . ?
N4 N3 Ru2 N6 34(4) . . . . ?
N4 N3 Ru2 N5 51(3) . . . . ?
N4 N3 Ru2 P2 -130(3) . . . . ?
N4 N3 Ru2 Cl3 140(3) . . . . ?
N4 N3 Ru2 Cl4 -34(3) . . . . ?
N3 Ru2 P2 C26 -157.1(2) . . . . ?
N6 Ru2 P2 C26 24.0(2) . . . . ?
N5 Ru2 P2 C26 19.8(5) . . . . ?
Cl3 Ru2 P2 C26 -61.4(2) . . . . ?
Cl4 Ru2 P2 C26 116.0(2) . . . . ?
N3 Ru2 P2 C27 94.2(3) . . . . ?
N6 Ru2 P2 C27 -84.6(3) . . . . ?
N5 Ru2 P2 C27 -88.8(5) . . . . ?
Cl3 Ru2 P2 C27 -170.1(3) . . . . ?
Cl4 Ru2 P2 C27 7.4(3) . . . . ?
N3 Ru2 P2 C31 -46.5(3) . . . . ?
N6 Ru2 P2 C31 134.7(3) . . . . ?
N5 Ru2 P2 C31 130.4(5) . . . . ?
Cl3 Ru2 P2 C31 49.2(3) . . . . ?
Cl4 Ru2 P2 C31 -133.4(3) . . . . ?
N3 Ru2 N5 C35 95.9(4) . . . . ?
N6 Ru2 N5 C35 -85.3(4) . . . . ?
P2 Ru2 N5 C35 -81.0(6) . . . . ?
Cl3 Ru2 N5 C35 0.3(4) . . . . ?
Cl4 Ru2 N5 C35 -179.1(4) . . . . ?
N3 Ru2 N5 C20 -147.7(3) . . . . ?
N6 Ru2 N5 C20 31.1(3) . . . . ?
P2 Ru2 N5 C20 35.4(6) . . . . ?
Cl3 Ru2 N5 C20 116.7(3) . . . . ?
Cl4 Ru2 N5 C20 -62.7(3) . . . . ?
N3 Ru2 N5 C37 -33.4(4) . . . . ?
N6 Ru2 N5 C37 145.3(4) . . . . ?
P2 Ru2 N5 C37 149.6(4) . . . . ?
Cl3 Ru2 N5 C37 -129.0(4) . . . . ?
Cl4 Ru2 N5 C37 51.5(4) . . . . ?
N3 Ru2 N6 C25 178(51) . . . . ?
N5 Ru2 N6 C25 161.3(4) . . . . ?
P2 Ru2 N6 C25 -17.3(4) . . . . ?
Cl3 Ru2 N6 C25 72.2(4) . . . . ?
Cl4 Ru2 N6 C25 -114.1(4) . . . . ?
N3 Ru2 N6 C21 2(3) . . . . ?
N5 Ru2 N6 C21 -14.7(4) . . . . ?
P2 Ru2 N6 C21 166.6(4) . . . . ?
Cl3 Ru2 N6 C21 -103.8(4) . . . . ?
Cl4 Ru2 N6 C21 69.8(4) . . . . ?
C35 N5 C20 C21 80.0(6) . . . . ?
C37 N5 C20 C21 -159.5(6) . . . . ?
Ru2 N5 C20 C21 -42.7(6) . . . . ?
C25 N6 C21 C22 1.8(9) . . . . ?
Ru2 N6 C21 C22 177.9(5) . . . . ?
C25 N6 C21 C20 177.4(5) . . . . ?
Ru2 N6 C21 C20 -6.4(7) . . . . ?
N5 C20 C21 N6 37.1(8) . . . . ?
N5 C20 C21 C22 -147.4(6) . . . . ?
N6 C21 C22 C23 0.4(10) . . . . ?
C20 C21 C22 C23 -174.9(6) . . . . ?
C21 C22 C23 C24 -1.1(10) . . . . ?
C22 C23 C24 C25 -0.3(9) . . . . ?
C21 N6 C25 C24 -3.2(8) . . . . ?
Ru2 N6 C25 C24 -179.1(4) . . . . ?
C21 N6 C25 C26 174.9(5) . . . . ?
Ru2 N6 C25 C26 -1.1(6) . . . . ?
C23 C24 C25 N6 2.4(8) . . . . ?
C23 C24 C25 C26 -175.5(6) . . . . ?
N6 C25 C26 P2 25.3(6) . . . . ?
C24 C25 C26 P2 -156.6(5) . . . . ?
C27 P2 C26 C25 89.4(5) . . . . ?
C31 P2 C26 C25 -159.0(4) . . . . ?
Ru2 P2 C26 C25 -32.2(4) . . . . ?
C26 P2 C27 C30 -49.8(6) . . . . ?
C31 P2 C27 C30 -158.3(5) . . . . ?
Ru2 P2 C27 C30 55.2(5) . . . . ?
C26 P2 C27 C28 69.4(7) . . . . ?
C31 P2 C27 C28 -39.1(7) . . . . ?
Ru2 P2 C27 C28 174.4(5) . . . . ?
C26 P2 C27 C29 -167.6(7) . . . . ?
C31 P2 C27 C29 83.9(8) . . . . ?
Ru2 P2 C27 C29 -62.5(8) . . . . ?
C26 P2 C31 C33 82.0(5) . . . . ?
C27 P2 C31 C33 -169.7(5) . . . . ?
Ru2 P2 C31 C33 -25.3(6) . . . . ?
C26 P2 C31 C32 -38.1(7) . . . . ?
C27 P2 C31 C32 70.2(7) . . . . ?
Ru2 P2 C31 C32 -145.3(5) . . . . ?
C26 P2 C31 C34 -159.5(5) . . . . ?
C27 P2 C31 C34 -51.2(6) . . . . ?
Ru2 P2 C31 C34 93.3(6) . . . . ?
C20 N5 C35 C36 170.7(5) . . . . ?
C37 N5 C35 C36 52.1(7) . . . . ?
Ru2 N5 C35 C36 -77.4(5) . . . . ?
C35 N5 C37 C38 55.7(7) . . . . ?
C20 N5 C37 C38 -62.9(7) . . . . ?
Ru2 N5 C37 C38 -172.0(5) . . . . ?
C43 C39 C40 C41 -27.0(16) . . . . ?
C39 C40 C41 C42 20.7(11) . . . . ?
C40 C41 C42 C43 -7.4(17) . . . . ?
C40 C39 C43 C42 22(3) . . . . ?
C41 C42 C43 C39 -8(3) . . . . ?
