#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:27:31 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179791 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/87/7008789.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7008789
loop_
_publ_author_name
'Chang, Xiaohong'
'Lee, Kyung-Eun'
'Il Jeon, Sang'
'Kim, Yong-Joo'
'Lee, H.-K.'
'Lee, Soon W.'
_publ_section_title
;
 Bis(isothiocyanato)bis(phosphine) complexes of group 10 metals:
 reactivity toward organic isocyanides
;
_journal_issue                   23
_journal_name_full               'Dalton Transactions'
_journal_page_first              3722
_journal_paper_doi               10.1039/b508134c
_journal_year                    2005
_chemical_formula_sum            'C38 H44 N4 P2 Pd S2'
_chemical_formula_weight         789.23
_chemical_name_systematic
;
?
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 103.217(16)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   10.029(4)
_cell_length_b                   11.899(3)
_cell_length_c                   17.761(5)
_cell_measurement_reflns_used    38
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      12.57
_cell_measurement_theta_min      4.98
_cell_volume                     2063.4(11)
_computing_cell_refinement       'Siemens XSCANS'
_computing_data_collection       'Siemens XSCANS'
_computing_data_reduction        'Siemens SHELXTL'
_computing_molecular_graphics    'Siemens SHELXTL'
_computing_publication_material  'Siemens SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device       'Siemens P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0185
_diffrn_reflns_av_sigmaI/netI    0.0330
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            4019
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.08
_diffrn_standards_interval_count 97
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.658
_exptl_absorpt_correction_T_max  0.8993
_exptl_absorpt_correction_T_min  0.6940
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            'YELLOW '
_exptl_crystal_density_diffrn    1.270
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'BLOCK '
_exptl_crystal_F_000             816
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.30
_refine_diff_density_max         0.531
_refine_diff_density_min         -0.279
_refine_diff_density_rms         0.051
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.00(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     424
_refine_ls_number_reflns         3795
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.058
_refine_ls_R_factor_all          0.0346
_refine_ls_R_factor_gt           0.0310
_refine_ls_shift/su_max          0.019
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0464P)²+0.4851P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0783
_refine_ls_wR_factor_ref         0.0812
_reflns_number_gt                3569
_reflns_number_total             3795
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b508134c.txt
_cod_data_source_block           lee192
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P2(1) '
_cod_database_code               7008789
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd -1.29101(3) -0.54640(3) -0.250297(17) 0.04289(10) Uani 1 1 d . . .
S1 S -0.9528(4) -0.2862(4) -0.2968(2) 0.1610(14) Uani 1 1 d . . .
S2 S -1.4666(2) -0.74578(16) -0.23499(16) 0.0983(7) Uani 1 1 d . . .
P1 P -1.47614(13) -0.43607(11) -0.31696(7) 0.0501(3) Uani 1 1 d . . .
P2 P -1.08306(13) -0.62414(11) -0.18031(7) 0.0478(3) Uani 1 1 d . . .
N1 N -1.3520(4) -0.4427(4) -0.1001(2) 0.0567(10) Uani 1 1 d . . .
N2 N -1.1862(5) -0.6049(5) -0.3982(3) 0.0650(12) Uani 1 1 d . . .
N3 N -1.1275(14) -0.1912(12) -0.4001(8) 0.172(6) Uani 1 1 d . . .
N4 N -1.5841(7) -0.6487(8) -0.1212(4) 0.106(2) Uani 1 1 d . . .
C1 C -1.4968(6) -0.4297(5) -0.4219(3) 0.0604(13) Uani 1 1 d . . .
C2 C -1.4323(9) -0.3472(7) -0.4551(4) 0.090(2) Uani 1 1 d . . .
H2 H -1.3789 -0.2937 -0.4239 0.108 Uiso 1 1 calc R . .
C3 C -1.4465(11) -0.3432(8) -0.5356(4) 0.111(3) Uani 1 1 d . . .
H3 H -1.4035 -0.2869 -0.5576 0.133 Uiso 1 1 calc R . .
C4 C -1.5227(12) -0.4213(9) -0.5806(4) 0.118(4) Uani 1 1 d . . .
H4 H -1.5315 -0.4188 -0.6338 0.142 Uiso 1 1 calc R . .
C5 C -1.5874(12) -0.5040(8) -0.5497(5) 0.119(4) Uani 1 1 d . . .
H5 H -1.6401 -0.5574 -0.5815 0.143 Uiso 1 1 calc R . .
C6 C -1.5738(9) -0.5078(6) -0.4703(4) 0.093(2) Uani 1 1 d . . .
H6 H -1.6177 -0.5644 -0.4493 0.112 Uiso 1 1 calc R . .
C7 C -1.4546(6) -0.2913(4) -0.2821(3) 0.0565(13) Uani 1 1 d . . .
C8 C -1.3267(8) -0.2471(6) -0.2557(3) 0.0717(16) Uani 1 1 d . . .
H8 H -1.2501 -0.2904 -0.2571 0.086 Uiso 1 1 calc R . .
C9 C -1.3097(11) -0.1373(7) -0.2266(4) 0.104(3) Uani 1 1 d . . .
H9 H -1.2222 -0.1084 -0.2078 0.125 Uiso 1 1 calc R . .
C10 C -1.4220(16) -0.0727(6) -0.2261(5) 0.124(4) Uani 1 1 d . . .
H10 H -1.4113 0.0007 -0.2077 0.149 Uiso 1 1 calc R . .
C11 C -1.5511(14) -0.1165(8) -0.2527(6) 0.120(4) Uani 1 1 d . . .
H11 H -1.6276 -0.0733 -0.2510 0.144 Uiso 1 1 calc R . .
C12 C -1.5672(9) -0.2232(7) -0.2816(5) 0.090(2) Uani 1 1 d . . .
H12 H -1.6550 -0.2509 -0.3014 0.108 Uiso 1 1 calc R . .
C13 C -1.6397(6) -0.4858(7) -0.3005(4) 0.0812(19) Uani 1 1 d . . .
H13A H -1.6548 -0.5619 -0.3182 0.122 Uiso 1 1 calc R . .
H13B H -1.7124 -0.4390 -0.3284 0.122 Uiso 1 1 calc R . .
H13C H -1.6376 -0.4824 -0.2462 0.122 Uiso 1 1 calc R . .
C14 C -1.0795(6) -0.6521(6) -0.0786(3) 0.0704(17) Uani 1 1 d . . .
C15 C -1.0200(10) -0.5774(9) -0.0212(4) 0.112(3) Uani 1 1 d . . .
H15 H -0.9770 -0.5129 -0.0334 0.135 Uiso 1 1 calc R . .
C16 C -1.0252(15) -0.5998(15) 0.0567(5) 0.168(7) Uani 1 1 d . . .
H16 H -0.9863 -0.5492 0.0954 0.202 Uiso 1 1 calc R . .
C17 C -1.0860(19) -0.6939(19) 0.0750(7) 0.195(10) Uani 1 1 d . . .
H17 H -1.0872 -0.7086 0.1262 0.234 Uiso 1 1 calc R . .
C18 C -1.1449(12) -0.7667(13) 0.0191(7) 0.141(5) Uani 1 1 d . . .
H18 H -1.1863 -0.8314 0.0324 0.170 Uiso 1 1 calc R . .
C19 C -1.1449(8) -0.7463(9) -0.0590(5) 0.102(3) Uani 1 1 d . . .
H19 H -1.1887 -0.7959 -0.0972 0.123 Uiso 1 1 calc R . .
C20 C -1.0288(5) -0.7535(5) -0.2187(3) 0.0531(11) Uani 1 1 d . . .
C21 C -1.1235(6) -0.8303(5) -0.2583(4) 0.0665(15) Uani 1 1 d . . .
H21 H -1.2167 -0.8153 -0.2664 0.080 Uiso 1 1 calc R . .
C22 C -1.0795(7) -0.9294(6) -0.2858(4) 0.0834(19) Uani 1 1 d . . .
H22 H -1.1433 -0.9814 -0.3113 0.100 Uiso 1 1 calc R . .
C23 C -0.9408(8) -0.9512(7) -0.2755(5) 0.093(2) Uani 1 1 d . . .
H23 H -0.9114 -1.0181 -0.2935 0.112 Uiso 1 1 calc R . .
C24 C -0.8473(7) -0.8737(7) -0.2388(4) 0.088(2) Uani 1 1 d . . .
H24 H -0.7542 -0.8869 -0.2335 0.106 Uiso 1 1 calc R . .
C25 C -0.8902(6) -0.7766(6) -0.2097(4) 0.0777(19) Uani 1 1 d . . .
H25 H -0.8256 -0.7256 -0.1837 0.093 Uiso 1 1 calc R . .
C26 C -0.9466(7) -0.5228(5) -0.1793(4) 0.081(2) Uani 1 1 d . . .
H26A H -0.9703 -0.4523 -0.1595 0.121 Uiso 1 1 calc R . .
H26B H -0.9347 -0.5123 -0.2310 0.121 Uiso 1 1 calc R . .
H26C H -0.8629 -0.5502 -0.1470 0.121 Uiso 1 1 calc R . .
C27 C -1.3291(5) -0.4842(4) -0.1535(3) 0.0491(11) Uani 1 1 d . . .
C28 C -1.3835(7) -0.3785(6) -0.0342(3) 0.0709(16) Uani 1 1 d . . .
C29 C -1.2676(10) -0.2947(9) -0.0106(6) 0.125(4) Uani 1 1 d . . .
H29A H -1.2657 -0.2457 -0.0532 0.188 Uiso 1 1 calc R . .
H29B H -1.1821 -0.3342 0.0040 0.188 Uiso 1 1 calc R . .
H29C H -1.2815 -0.2511 0.0325 0.188 Uiso 1 1 calc R . .
C30 C -1.3955(10) -0.4584(9) 0.0283(4) 0.112(3) Uani 1 1 d . . .
H30A H -1.3092 -0.4952 0.0473 0.168 Uiso 1 1 calc R . .
H30B H -1.4644 -0.5135 0.0082 0.168 Uiso 1 1 calc R . .
H30C H -1.4207 -0.4181 0.0698 0.168 Uiso 1 1 calc R . .
C31 C -1.5155(9) -0.3177(10) -0.0659(5) 0.118(3) Uani 1 1 d . . .
H31A H -1.5038 -0.2672 -0.1061 0.178 Uiso 1 1 calc R . .
H31B H -1.5412 -0.2757 -0.0253 0.178 Uiso 1 1 calc R . .
H31C H -1.5860 -0.3712 -0.0867 0.178 Uiso 1 1 calc R . .
C32 C -1.2303(5) -0.5853(5) -0.3460(3) 0.0550(13) Uani 1 1 d . . .
C33 C -1.1173(7) -0.6333(7) -0.4613(3) 0.0787(19) Uani 1 1 d . . .
C34 C -1.1881(16) -0.7271(18) -0.5035(8) 0.246(12) Uani 1 1 d . . .
H34A H -1.2818 -0.7068 -0.5249 0.369 Uiso 1 1 calc R . .
H34B H -1.1849 -0.7899 -0.4693 0.369 Uiso 1 1 calc R . .
H34C H -1.1449 -0.7470 -0.5446 0.369 Uiso 1 1 calc R . .
C35 C -0.9752(10) -0.653(2) -0.4268(6) 0.222(10) Uani 1 1 d . . .
H35A H -0.9356 -0.5872 -0.3998 0.333 Uiso 1 1 calc R . .
H35B H -0.9279 -0.6715 -0.4665 0.333 Uiso 1 1 calc R . .
H35C H -0.9672 -0.7149 -0.3911 0.333 Uiso 1 1 calc R . .
C36 C -1.134(2) -0.537(2) -0.5141(10) 0.313(16) Uani 1 1 d . . .
H36A H -1.0873 -0.4727 -0.4872 0.469 Uiso 1 1 calc R . .
H36B H -1.2291 -0.5198 -0.5322 0.469 Uiso 1 1 calc R . .
H36C H -1.0948 -0.5543 -0.5573 0.469 Uiso 1 1 calc R . .
C37 C -1.0718(13) -0.2564(17) -0.3658(7) 0.158(8) Uani 1 1 d . . .
C38 C -1.5351(7) -0.6910(6) -0.1667(4) 0.0742(18) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C32 Pd1 C27 169.7(2) . . ?
C32 Pd1 P2 87.27(15) . . ?
C27 Pd1 P2 90.69(14) . . ?
C32 Pd1 P1 93.46(15) . . ?
C27 Pd1 P1 86.67(14) . . ?
P2 Pd1 P1 169.12(5) . . ?
C7 P1 C13 107.0(3) . . ?
C7 P1 C1 106.5(2) . . ?
C13 P1 C1 106.3(3) . . ?
C7 P1 Pd1 109.63(18) . . ?
C13 P1 Pd1 111.8(2) . . ?
C1 P1 Pd1 115.3(2) . . ?
C20 P2 C26 106.0(3) . . ?
C20 P2 C14 106.0(3) . . ?
C26 P2 C14 105.4(3) . . ?
C20 P2 Pd1 116.06(17) . . ?
C26 P2 Pd1 108.5(2) . . ?
C14 P2 Pd1 114.03(18) . . ?
C27 N1 C28 174.8(6) . . ?
C32 N2 C33 174.9(6) . . ?
C6 C1 C2 117.6(6) . . ?
C6 C1 P1 121.7(5) . . ?
C2 C1 P1 120.6(5) . . ?
C1 C2 C3 120.7(7) . . ?
C4 C3 C2 119.5(9) . . ?
C3 C4 C5 121.2(7) . . ?
C4 C5 C6 119.2(8) . . ?
C1 C6 C5 121.6(8) . . ?
C8 C7 C12 118.3(6) . . ?
C8 C7 P1 120.5(5) . . ?
C12 C7 P1 121.2(5) . . ?
C7 C8 C9 120.7(8) . . ?
C10 C9 C8 119.8(9) . . ?
C9 C10 C11 119.9(7) . . ?
C12 C11 C10 120.2(9) . . ?
C11 C12 C7 121.1(9) . . ?
C15 C14 C19 119.0(7) . . ?
C15 C14 P2 121.3(7) . . ?
C19 C14 P2 119.6(6) . . ?
C14 C15 C16 119.5(12) . . ?
C17 C16 C15 120.6(14) . . ?
C18 C17 C16 120.1(11) . . ?
C17 C18 C19 121.1(14) . . ?
C14 C19 C18 119.7(11) . . ?
C21 C20 C25 118.6(5) . . ?
C21 C20 P2 121.3(4) . . ?
C25 C20 P2 120.2(4) . . ?
C22 C21 C20 120.2(5) . . ?
C23 C22 C21 120.3(6) . . ?
C24 C23 C22 119.6(6) . . ?
C23 C24 C25 120.4(6) . . ?
C24 C25 C20 120.9(6) . . ?
N1 C27 Pd1 176.1(5) . . ?
C30 C28 N1 109.0(6) . . ?
C30 C28 C31 112.0(7) . . ?
N1 C28 C31 106.2(5) . . ?
C30 C28 C29 113.7(7) . . ?
N1 C28 C29 105.5(5) . . ?
C31 C28 C29 110.0(8) . . ?
N2 C32 Pd1 175.0(5) . . ?
C35 C33 C34 114.6(14) . . ?
C35 C33 C36 110.9(13) . . ?
C34 C33 C36 107.8(13) . . ?
C35 C33 N2 107.7(6) . . ?
C34 C33 N2 108.1(7) . . ?
C36 C33 N2 107.5(8) . . ?
N3 C37 S1 146(2) . . ?
N4 C38 S2 176.9(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd1 C32 1.987(5) . ?
Pd1 C27 1.987(5) . ?
Pd1 P2 2.3590(14) . ?
Pd1 P1 2.3596(14) . ?
S1 C37 1.544(12) . ?
S2 C38 1.657(9) . ?
P1 C7 1.827(5) . ?
P1 C13 1.829(6) . ?
P1 C1 1.830(6) . ?
P2 C20 1.816(5) . ?
P2 C26 1.821(6) . ?
P2 C14 1.829(6) . ?
N1 C27 1.139(6) . ?
N1 C28 1.491(7) . ?
N2 C32 1.140(7) . ?
N2 C33 1.482(7) . ?
N3 C37 1.063(18) . ?
N4 C38 1.154(10) . ?
C1 C6 1.376(9) . ?
C1 C2 1.379(10) . ?
C2 C3 1.405(10) . ?
C3 C4 1.344(14) . ?
C4 C5 1.361(15) . ?
C5 C6 1.386(12) . ?
C7 C8 1.366(9) . ?
C7 C12 1.391(9) . ?
C8 C9 1.401(11) . ?
C9 C10 1.366(15) . ?
C10 C11 1.375(15) . ?
C11 C12 1.366(13) . ?
C14 C15 1.382(11) . ?
C14 C19 1.383(12) . ?
C15 C16 1.421(14) . ?
C16 C17 1.35(3) . ?
C17 C18 1.35(2) . ?
C18 C19 1.408(12) . ?
C20 C21 1.388(8) . ?
C20 C25 1.390(8) . ?
C21 C22 1.386(9) . ?
C22 C23 1.385(10) . ?
C23 C24 1.369(11) . ?
C24 C25 1.374(9) . ?
C28 C30 1.487(11) . ?
C28 C31 1.501(10) . ?
C28 C29 1.516(11) . ?
C33 C35 1.437(12) . ?
C33 C34 1.438(16) . ?
C33 C36 1.469(18) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C32 Pd1 P1 C7 -118.9(3) . . . . ?
C27 Pd1 P1 C7 50.8(2) . . . . ?
P2 Pd1 P1 C7 -25.3(4) . . . . ?
C32 Pd1 P1 C13 122.7(3) . . . . ?
C27 Pd1 P1 C13 -67.6(3) . . . . ?
P2 Pd1 P1 C13 -143.8(4) . . . . ?
C32 Pd1 P1 C1 1.2(3) . . . . ?
C27 Pd1 P1 C1 170.9(3) . . . . ?
P2 Pd1 P1 C1 94.8(3) . . . . ?
C32 Pd1 P2 C20 -41.3(3) . . . . ?
C27 Pd1 P2 C20 148.8(2) . . . . ?
P1 Pd1 P2 C20 -135.4(3) . . . . ?
C32 Pd1 P2 C26 77.9(3) . . . . ?
C27 Pd1 P2 C26 -92.0(3) . . . . ?
P1 Pd1 P2 C26 -16.2(4) . . . . ?
C32 Pd1 P2 C14 -165.0(3) . . . . ?
C27 Pd1 P2 C14 25.1(3) . . . . ?
P1 Pd1 P2 C14 100.9(4) . . . . ?
C7 P1 C1 C6 -149.8(6) . . . . ?
C13 P1 C1 C6 -36.0(7) . . . . ?
Pd1 P1 C1 C6 88.4(6) . . . . ?
C7 P1 C1 C2 31.7(7) . . . . ?
C13 P1 C1 C2 145.5(6) . . . . ?
Pd1 P1 C1 C2 -90.1(6) . . . . ?
C6 C1 C2 C3 0.6(12) . . . . ?
P1 C1 C2 C3 179.1(7) . . . . ?
C1 C2 C3 C4 -0.6(15) . . . . ?
C2 C3 C4 C5 0.5(16) . . . . ?
C3 C4 C5 C6 -0.2(16) . . . . ?
C2 C1 C6 C5 -0.3(12) . . . . ?
P1 C1 C6 C5 -178.9(7) . . . . ?
C4 C5 C6 C1 0.2(15) . . . . ?
C13 P1 C7 C8 152.0(5) . . . . ?
C1 P1 C7 C8 -94.7(5) . . . . ?
Pd1 P1 C7 C8 30.6(5) . . . . ?
C13 P1 C7 C12 -28.0(6) . . . . ?
C1 P1 C7 C12 85.3(6) . . . . ?
Pd1 P1 C7 C12 -149.4(5) . . . . ?
C12 C7 C8 C9 2.1(9) . . . . ?
P1 C7 C8 C9 -178.0(5) . . . . ?
C7 C8 C9 C10 -1.4(11) . . . . ?
C8 C9 C10 C11 1.1(13) . . . . ?
C9 C10 C11 C12 -1.8(14) . . . . ?
C10 C11 C12 C7 2.6(14) . . . . ?
C8 C7 C12 C11 -2.7(11) . . . . ?
P1 C7 C12 C11 177.4(6) . . . . ?
C20 P2 C14 C15 133.3(6) . . . . ?
C26 P2 C14 C15 21.2(6) . . . . ?
Pd1 P2 C14 C15 -97.7(6) . . . . ?
C20 P2 C14 C19 -50.8(5) . . . . ?
C26 P2 C14 C19 -163.0(5) . . . . ?
Pd1 P2 C14 C19 78.1(5) . . . . ?
C19 C14 C15 C16 1.2(12) . . . . ?
P2 C14 C15 C16 177.0(7) . . . . ?
C14 C15 C16 C17 0.8(17) . . . . ?
C15 C16 C17 C18 -1(2) . . . . ?
C16 C17 C18 C19 0(2) . . . . ?
C15 C14 C19 C18 -2.6(10) . . . . ?
P2 C14 C19 C18 -178.6(6) . . . . ?
C17 C18 C19 C14 2.2(15) . . . . ?
C26 P2 C20 C21 -151.7(5) . . . . ?
C14 P2 C20 C21 96.6(5) . . . . ?
Pd1 P2 C20 C21 -31.2(5) . . . . ?
C26 P2 C20 C25 27.4(6) . . . . ?
C14 P2 C20 C25 -84.4(6) . . . . ?
Pd1 P2 C20 C25 147.9(5) . . . . ?
C25 C20 C21 C22 2.1(10) . . . . ?
P2 C20 C21 C22 -178.8(5) . . . . ?
C20 C21 C22 C23 -1.5(11) . . . . ?
C21 C22 C23 C24 -0.8(13) . . . . ?
C22 C23 C24 C25 2.4(13) . . . . ?
C23 C24 C25 C20 -1.7(12) . . . . ?
C21 C20 C25 C24 -0.5(11) . . . . ?
P2 C20 C25 C24 -179.6(6) . . . . ?
C28 N1 C27 Pd1 0(12) . . . . ?
C32 Pd1 C27 N1 49(7) . . . . ?
P2 Pd1 C27 N1 127(7) . . . . ?
P1 Pd1 C27 N1 -42(7) . . . . ?
C27 N1 C28 C30 173(6) . . . . ?
C27 N1 C28 C31 52(6) . . . . ?
C27 N1 C28 C29 -64(6) . . . . ?
C33 N2 C32 Pd1 36(12) . . . . ?
C27 Pd1 C32 N2 36(7) . . . . ?
P2 Pd1 C32 N2 -42(6) . . . . ?
P1 Pd1 C32 N2 127(6) . . . . ?
C32 N2 C33 C35 -9(8) . . . . ?
C32 N2 C33 C34 115(7) . . . . ?
C32 N2 C33 C36 -129(7) . . . . ?
