#------------------------------------------------------------------------------
#$Date: 2019-03-05 10:52:05 +0200 (Tue, 05 Mar 2019) $
#$Revision: 213973 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/01/33/7013301.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7013301
loop_
_publ_author_name
'Opris, Laura M.'
'Silvestru, Anca'
'Silvestru, Cristian'
'Breunig, Hans J.'
'Lork, Enno'
_publ_section_title
;
 Solid-state structure and solution behaviour of hypervalent
 organoantimony halides containing 2-(Me2NCH2)C6H4? moieties
;
_journal_issue                   22
_journal_name_full               'Dalton Transactions'
_journal_page_first              4367
_journal_paper_doi               10.1039/b306299f
_journal_year                    2003
_chemical_formula_moiety         'C18 H24 Br N2 Sb'
_chemical_formula_sum            'C18 H24 Br N2 Sb'
_chemical_formula_weight         470.05
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                93.11(3)
_cell_angle_beta                 91.45(3)
_cell_angle_gamma                110.24(3)
_cell_formula_units_Z            4
_cell_length_a                   9.762(2)
_cell_length_b                   12.890(3)
_cell_length_c                   16.109(3)
_cell_measurement_reflns_used    8000
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      26.05
_cell_measurement_theta_min      2.04
_cell_volume                     1897.0(8)
_computing_cell_refinement       'STOE Cell'
_computing_data_collection       'STOE Exposed'
_computing_data_reduction        'STOE Integrate'
_computing_molecular_graphics    Diamond
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.917
_diffrn_measured_fraction_theta_max 0.917
_diffrn_measurement_device_type  'STOE IPDS'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0422
_diffrn_reflns_av_sigmaI/netI    0.0325
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            24429
_diffrn_reflns_theta_full        26.05
_diffrn_reflns_theta_max         26.05
_diffrn_reflns_theta_min         2.04
_diffrn_standards_decay_%        'random variation +/-2.0'
_exptl_absorpt_coefficient_mu    3.560
_exptl_absorpt_correction_T_max  0.3301
_exptl_absorpt_correction_T_min  0.2691
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details   'Stuart & Walker Acta Cryst. 1983'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.646
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blocks
_exptl_crystal_F_000             928
_exptl_crystal_size_max          0.50
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.40
_refine_diff_density_max         0.457
_refine_diff_density_min         -0.511
_refine_diff_density_rms         0.067
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.922
_refine_ls_hydrogen_treatment    refU
_refine_ls_matrix_type           full
_refine_ls_number_parameters     408
_refine_ls_number_reflns         6851
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.922
_refine_ls_R_factor_all          0.0382
_refine_ls_R_factor_gt           0.0227
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0313P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0525
_refine_ls_wR_factor_ref         0.0566
_reflns_number_gt                5027
_reflns_number_total             6851
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            b306299f.txt
_cod_data_source_block           cs11i
_cod_original_cell_volume        1897.0(7)
_cod_database_code               7013301
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sb1 Sb 0.61960(2) 0.679041(15) 0.028644(11) 0.02649(6) Uani 1 1 d . . .
Br1 Br 0.89416(4) 0.66006(3) 0.04087(2) 0.03895(9) Uani 1 1 d . . .
N1 N 0.3839(3) 0.6943(2) 0.05522(15) 0.0315(6) Uani 1 1 d . . .
N2 N 0.5810(3) 0.8105(2) -0.13380(16) 0.0391(6) Uani 1 1 d . . .
Sb2 Sb 0.13302(2) 0.682488(15) -0.464484(11) 0.02610(6) Uani 1 1 d . . .
Br2 Br 0.40946(4) 0.67125(3) -0.45064(2) 0.03611(8) Uani 1 1 d . . .
N3 N -0.0985(3) 0.7061(2) -0.43517(15) 0.0316(6) Uani 1 1 d . . .
N4 N 0.1189(3) 0.8217(2) -0.63232(16) 0.0382(6) Uani 1 1 d . . .
C1 C 0.5886(3) 0.6495(2) 0.15884(17) 0.0301(6) Uani 1 1 d . . .
C6 C 0.6978(4) 0.6560(3) 0.21806(18) 0.0352(7) Uani 1 1 d . . .
H6 H 0.7965 0.6769 0.2027 0.042(2) Uiso 1 1 calc R . .
C5 C 0.6632(4) 0.6321(3) 0.29980(19) 0.0424(8) Uani 1 1 d . . .
H5 H 0.7386 0.6370 0.3399 0.042(2) Uiso 1 1 calc R . .
C4 C 0.5195(4) 0.6012(3) 0.3230(2) 0.0437(8) Uani 1 1 d . . .
H4 H 0.4961 0.5845 0.3788 0.042(2) Uiso 1 1 calc R . .
C3 C 0.4104(4) 0.5950(3) 0.2644(2) 0.0424(8) Uani 1 1 d . . .
H3 H 0.3119 0.5742 0.2802 0.042(2) Uiso 1 1 calc R . .
C2 C 0.4435(3) 0.6188(2) 0.18258(18) 0.0323(7) Uani 1 1 d . . .
C7 C 0.3268(3) 0.6090(3) 0.11627(19) 0.0360(7) Uani 1 1 d . . .
H7A H 0.2948 0.5343 0.0873 0.036(3) Uiso 1 1 calc R . .
H7B H 0.2410 0.6189 0.1424 0.036(3) Uiso 1 1 calc R . .
C8 C 0.3895(4) 0.8040(3) 0.0908(2) 0.0425(8) Uani 1 1 d . . .
H8A H 0.4339 0.8603 0.0515 0.052(2) Uiso 1 1 calc R . .
H8B H 0.4481 0.8223 0.1433 0.052(2) Uiso 1 1 calc R . .
H8C H 0.2901 0.8021 0.1010 0.052(2) Uiso 1 1 calc R . .
C9 C 0.2895(4) 0.6641(3) -0.0217(2) 0.0438(8) Uani 1 1 d . . .
H9A H 0.1904 0.6603 -0.0088 0.052(2) Uiso 1 1 calc R . .
H9B H 0.2867 0.5918 -0.0456 0.052(2) Uiso 1 1 calc R . .
H9C H 0.3288 0.7202 -0.0619 0.052(2) Uiso 1 1 calc R . .
C10 C 0.7291(3) 0.8573(2) 0.04380(18) 0.0286(6) Uani 1 1 d . . .
C15 C 0.7662(4) 0.9113(2) 0.12290(19) 0.0349(7) Uani 1 1 d . . .
H15 H 0.7421 0.8697 0.1707 0.042(2) Uiso 1 1 calc R . .
C14 C 0.8382(4) 1.0253(3) 0.1326(2) 0.0398(8) Uani 1 1 d . . .
H14 H 0.8615 1.0614 0.1867 0.042(2) Uiso 1 1 calc R . .
C13 C 0.8758(4) 1.0858(3) 0.0633(2) 0.0385(7) Uani 1 1 d . . .
H13 H 0.9239 1.1638 0.0696 0.042(2) Uiso 1 1 calc R . .
C12 C 0.8430(3) 1.0323(3) -0.0155(2) 0.0353(7) Uani 1 1 d . . .
H12 H 0.8713 1.0741 -0.0629 0.042(2) Uiso 1 1 calc R . .
C11 C 0.7691(3) 0.9180(2) -0.02639(18) 0.0302(6) Uani 1 1 d . . .
C16 C 0.7382(3) 0.8599(3) -0.11278(19) 0.0345(7) Uani 1 1 d . . .
H16A H 0.7848 0.9139 -0.1541 0.036(3) Uiso 1 1 calc R . .
H16B H 0.7820 0.8011 -0.1158 0.036(3) Uiso 1 1 calc R . .
C17 C 0.5169(4) 0.8951(4) -0.1472(2) 0.0569(11) Uani 1 1 d . . .
H17A H 0.5638 0.9387 -0.1932 0.052(2) Uiso 1 1 calc R . .
H17B H 0.5317 0.9440 -0.0964 0.052(2) Uiso 1 1 calc R . .
H17C H 0.4119 0.8596 -0.1608 0.052(2) Uiso 1 1 calc R . .
C18 C 0.5539(5) 0.7330(4) -0.2073(2) 0.0624(11) Uani 1 1 d . . .
H18A H 0.4484 0.6992 -0.2198 0.052(2) Uiso 1 1 calc R . .
H18B H 0.5942 0.6749 -0.1964 0.052(2) Uiso 1 1 calc R . .
H18C H 0.6010 0.7729 -0.2549 0.052(2) Uiso 1 1 calc R . .
C19 C 0.0937(3) 0.6415(2) -0.33688(17) 0.0292(6) Uani 1 1 d . . .
C24 C 0.1649(3) 0.5824(3) -0.29384(18) 0.0324(7) Uani 1 1 d . . .
H24 H 0.2399 0.5627 -0.3195 0.042(2) Uiso 1 1 calc R . .
C23 C 0.1272(4) 0.5518(3) -0.21356(19) 0.0388(7) Uani 1 1 d . . .
H23 H 0.1759 0.5109 -0.1851 0.042(2) Uiso 1 1 calc R . .
C22 C 0.0200(4) 0.5806(3) -0.17529(19) 0.0403(8) Uani 1 1 d . . .
H22 H -0.0045 0.5605 -0.1203 0.042(2) Uiso 1 1 calc R . .
C21 C -0.0527(4) 0.6395(3) -0.21766(19) 0.0391(7) Uani 1 1 d . . .
H21 H -0.1268 0.6596 -0.1914 0.042(2) Uiso 1 1 calc R . .
C20 C -0.0168(3) 0.6688(3) -0.29835(18) 0.0328(7) Uani 1 1 d . . .
C25 C -0.0940(4) 0.7337(3) -0.34468(19) 0.0367(7) Uani 1 1 d . . .
H25A H -0.1948 0.7155 -0.3257 0.036(3) Uiso 1 1 calc R . .
H25B H -0.0416 0.8141 -0.3326 0.036(3) Uiso 1 1 calc R . .
C26 C -0.2104(3) 0.5967(3) -0.4581(2) 0.0385(7) Uani 1 1 d . . .
H26A H -0.1921 0.5408 -0.4249 0.052(2) Uiso 1 1 calc R . .
H26B H -0.2059 0.5771 -0.5173 0.052(2) Uiso 1 1 calc R . .
H26C H -0.3075 0.5993 -0.4472 0.052(2) Uiso 1 1 calc R . .
C27 C -0.1324(4) 0.7906(3) -0.4822(2) 0.0418(8) Uani 1 1 d . . .
H27A H -0.2278 0.7931 -0.4670 0.052(2) Uiso 1 1 calc R . .
H27B H -0.1348 0.7711 -0.5420 0.052(2) Uiso 1 1 calc R . .
H27C H -0.0570 0.8633 -0.4687 0.052(2) Uiso 1 1 calc R . .
C28 C 0.2348(3) 0.8599(2) -0.44318(18) 0.0289(6) Uani 1 1 d . . .
C33 C 0.2584(4) 0.9105(3) -0.36315(19) 0.0349(7) Uani 1 1 d . . .
H33 H 0.2303 0.8667 -0.3167 0.042(2) Uiso 1 1 calc R . .
C32 C 0.3235(4) 1.0259(3) -0.3506(2) 0.0415(8) Uani 1 1 d . . .
H32 H 0.3382 1.0603 -0.2958 0.042(2) Uiso 1 1 calc R . .
C31 C 0.3663(4) 1.0896(3) -0.4181(2) 0.0410(8) Uani 1 1 d . . .
H31 H 0.4078 1.1680 -0.4101 0.042(2) Uiso 1 1 calc R . .
C30 C 0.3482(3) 1.0385(3) -0.4974(2) 0.0368(7) Uani 1 1 d . . .
H30 H 0.3810 1.0823 -0.5434 0.042(2) Uiso 1 1 calc R . .
C29 C 0.2830(3) 0.9244(2) -0.51099(18) 0.0298(6) Uani 1 1 d . . .
C34 C 0.2701(3) 0.8710(3) -0.59839(19) 0.0353(7) Uani 1 1 d . . .
H34A H 0.3265 0.9276 -0.6355 0.036(3) Uiso 1 1 calc R . .
H34B H 0.3144 0.8126 -0.5981 0.036(3) Uiso 1 1 calc R . .
C36 C 0.0618(4) 0.9084(3) -0.6549(2) 0.0555(10) Uani 1 1 d . . .
H36A H 0.1195 0.9501 -0.6989 0.052(2) Uiso 1 1 calc R . .
H36B H 0.0684 0.9587 -0.6059 0.052(2) Uiso 1 1 calc R . .
H36C H -0.0406 0.8742 -0.6749 0.052(2) Uiso 1 1 calc R . .
C35 C 0.1117(5) 0.7452(4) -0.7045(2) 0.0644(12) Uani 1 1 d . . .
H35A H 0.0105 0.7128 -0.7269 0.052(2) Uiso 1 1 calc R . .
H35B H 0.1458 0.6861 -0.6875 0.052(2) Uiso 1 1 calc R . .
H35C H 0.1740 0.7857 -0.7474 0.052(2) Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Sb1 C10 97.54(11) . . ?
C1 Sb1 N1 75.08(10) . . ?
C10 Sb1 N1 92.19(10) . . ?
C1 Sb1 Br1 90.82(9) . . ?
C10 Sb1 Br1 87.46(8) . . ?
N1 Sb1 Br1 165.73(6) . . ?
C9 N1 C8 109.5(3) . . ?
C9 N1 C7 110.0(2) . . ?
C8 N1 C7 110.3(3) . . ?
C9 N1 Sb1 110.06(19) . . ?
C8 N1 Sb1 115.0(2) . . ?
C7 N1 Sb1 101.71(17) . . ?
C17 N2 C18 110.6(3) . . ?
C17 N2 C16 111.4(3) . . ?
C18 N2 C16 110.4(3) . . ?
C28 Sb2 C19 98.54(11) . . ?
C28 Sb2 N3 87.38(10) . . ?
C19 Sb2 N3 74.52(10) . . ?
C28 Sb2 Br2 87.23(8) . . ?
C19 Sb2 Br2 91.37(9) . . ?
N3 Sb2 Br2 163.96(6) . . ?
C26 N3 C25 110.7(3) . . ?
C26 N3 C27 108.8(2) . . ?
C25 N3 C27 110.5(2) . . ?
C26 N3 Sb2 104.66(18) . . ?
C25 N3 Sb2 106.44(18) . . ?
C27 N3 Sb2 115.5(2) . . ?
C34 N4 C35 109.9(3) . . ?
C34 N4 C36 110.6(3) . . ?
C35 N4 C36 110.9(3) . . ?
C6 C1 C2 119.1(3) . . ?
C6 C1 Sb1 125.8(2) . . ?
C2 C1 Sb1 115.1(2) . . ?
C1 C6 C5 120.3(3) . . ?
C4 C5 C6 120.4(3) . . ?
C3 C4 C5 119.5(3) . . ?
C4 C3 C2 120.6(3) . . ?
C3 C2 C1 120.0(3) . . ?
C3 C2 C7 122.1(3) . . ?
C1 C2 C7 117.9(3) . . ?
N1 C7 C2 110.3(2) . . ?
C15 C10 C11 119.5(3) . . ?
C15 C10 Sb1 120.8(2) . . ?
C11 C10 Sb1 119.7(2) . . ?
C14 C15 C10 120.8(3) . . ?
C13 C14 C15 119.8(3) . . ?
C14 C13 C12 119.8(3) . . ?
C13 C12 C11 121.1(3) . . ?
C10 C11 C12 119.0(3) . . ?
C10 C11 C16 120.4(3) . . ?
C12 C11 C16 120.6(3) . . ?
N2 C16 C11 111.9(3) . . ?
C24 C19 C20 118.8(3) . . ?
C24 C19 Sb2 123.5(2) . . ?
C20 C19 Sb2 117.5(2) . . ?
C23 C24 C19 120.6(3) . . ?
C22 C23 C24 120.4(3) . . ?
C23 C22 C21 119.7(3) . . ?
C20 C21 C22 120.1(3) . . ?
C21 C20 C19 120.4(3) . . ?
C21 C20 C25 120.6(3) . . ?
C19 C20 C25 119.0(3) . . ?
N3 C25 C20 110.0(2) . . ?
C33 C28 C29 119.5(3) . . ?
C33 C28 Sb2 121.1(2) . . ?
C29 C28 Sb2 119.3(2) . . ?
C28 C33 C32 120.3(3) . . ?
C31 C32 C33 119.8(3) . . ?
C30 C31 C32 119.6(3) . . ?
C31 C30 C29 121.2(3) . . ?
C30 C29 C28 119.4(3) . . ?
C30 C29 C34 119.7(3) . . ?
C28 C29 C34 120.9(3) . . ?
N4 C34 C29 113.6(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Sb1 C1 2.162(3) . ?
Sb1 C10 2.169(3) . ?
Sb1 N1 2.422(3) . ?
Sb1 Br1 2.7776(7) . ?
N1 C9 1.476(4) . ?
N1 C8 1.480(4) . ?
N1 C7 1.485(4) . ?
N2 C17 1.456(4) . ?
N2 C18 1.464(5) . ?
N2 C16 1.467(4) . ?
Sb2 C28 2.159(3) . ?
Sb2 C19 2.161(3) . ?
Sb2 N3 2.437(3) . ?
Sb2 Br2 2.7562(7) . ?
N3 C26 1.475(4) . ?
N3 C25 1.477(4) . ?
N3 C27 1.481(4) . ?
N4 C34 1.467(4) . ?
N4 C35 1.467(5) . ?
N4 C36 1.469(4) . ?
C1 C6 1.389(4) . ?
C1 C2 1.402(4) . ?
C6 C5 1.392(4) . ?
C5 C4 1.387(5) . ?
C4 C3 1.383(5) . ?
C3 C2 1.390(4) . ?
C2 C7 1.510(4) . ?
C10 C15 1.395(4) . ?
C10 C11 1.397(4) . ?
C15 C14 1.390(4) . ?
C14 C13 1.381(5) . ?
C13 C12 1.386(5) . ?
C12 C11 1.397(4) . ?
C11 C16 1.516(4) . ?
C19 C24 1.395(4) . ?
C19 C20 1.395(4) . ?
C24 C23 1.393(4) . ?
C23 C22 1.374(5) . ?
C22 C21 1.397(5) . ?
C21 C20 1.393(4) . ?
C20 C25 1.517(4) . ?
C28 C33 1.389(4) . ?
C28 C29 1.400(4) . ?
C33 C32 1.401(4) . ?
C32 C31 1.384(5) . ?
C31 C30 1.383(5) . ?
C30 C29 1.388(4) . ?
C29 C34 1.516(4) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C1 Sb1 N1 C9 -152.1(2) . . . . ?
C10 Sb1 N1 C9 110.7(2) . . . . ?
Br1 Sb1 N1 C9 -161.0(2) . . . . ?
C1 Sb1 N1 C8 83.7(2) . . . . ?
C10 Sb1 N1 C8 -13.5(2) . . . . ?
Br1 Sb1 N1 C8 74.8(3) . . . . ?
C1 Sb1 N1 C7 -35.44(18) . . . . ?
C10 Sb1 N1 C7 -132.66(19) . . . . ?
Br1 Sb1 N1 C7 -44.4(4) . . . . ?
C28 Sb2 N3 C26 170.47(19) . . . . ?
C19 Sb2 N3 C26 -89.92(19) . . . . ?
Br2 Sb2 N3 C26 -119.0(2) . . . . ?
C28 Sb2 N3 C25 -72.21(19) . . . . ?
C19 Sb2 N3 C25 27.40(19) . . . . ?
Br2 Sb2 N3 C25 -1.7(3) . . . . ?
C28 Sb2 N3 C27 50.8(2) . . . . ?
C19 Sb2 N3 C27 150.5(2) . . . . ?
Br2 Sb2 N3 C27 121.3(2) . . . . ?
C10 Sb1 C1 C6 -71.6(3) . . . . ?
N1 Sb1 C1 C6 -161.9(3) . . . . ?
Br1 Sb1 C1 C6 15.9(3) . . . . ?
C10 Sb1 C1 C2 110.0(2) . . . . ?
N1 Sb1 C1 C2 19.7(2) . . . . ?
Br1 Sb1 C1 C2 -162.5(2) . . . . ?
C2 C1 C6 C5 0.1(5) . . . . ?
Sb1 C1 C6 C5 -178.3(2) . . . . ?
C1 C6 C5 C4 0.2(5) . . . . ?
C6 C5 C4 C3 -0.4(5) . . . . ?
C5 C4 C3 C2 0.3(5) . . . . ?
C4 C3 C2 C1 0.0(5) . . . . ?
C4 C3 C2 C7 177.9(3) . . . . ?
C6 C1 C2 C3 -0.2(4) . . . . ?
Sb1 C1 C2 C3 178.4(2) . . . . ?
C6 C1 C2 C7 -178.2(3) . . . . ?
Sb1 C1 C2 C7 0.4(3) . . . . ?
C9 N1 C7 C2 162.5(3) . . . . ?
C8 N1 C7 C2 -76.6(3) . . . . ?
Sb1 N1 C7 C2 45.9(3) . . . . ?
C3 C2 C7 N1 146.8(3) . . . . ?
C1 C2 C7 N1 -35.3(4) . . . . ?
C1 Sb1 C10 C15 5.2(3) . . . . ?
N1 Sb1 C10 C15 80.4(3) . . . . ?
Br1 Sb1 C10 C15 -85.3(2) . . . . ?
C1 Sb1 C10 C11 -177.9(2) . . . . ?
N1 Sb1 C10 C11 -102.7(2) . . . . ?
Br1 Sb1 C10 C11 91.6(2) . . . . ?
C11 C10 C15 C14 2.2(5) . . . . ?
Sb1 C10 C15 C14 179.1(2) . . . . ?
C10 C15 C14 C13 -1.1(5) . . . . ?
C15 C14 C13 C12 -0.8(5) . . . . ?
C14 C13 C12 C11 1.6(5) . . . . ?
C15 C10 C11 C12 -1.3(4) . . . . ?
Sb1 C10 C11 C12 -178.3(2) . . . . ?
C15 C10 C11 C16 176.1(3) . . . . ?
Sb1 C10 C11 C16 -0.8(4) . . . . ?
C13 C12 C11 C10 -0.5(5) . . . . ?
C13 C12 C11 C16 -178.0(3) . . . . ?
C17 N2 C16 C11 70.8(3) . . . . ?
C18 N2 C16 C11 -166.0(3) . . . . ?
C10 C11 C16 N2 66.1(4) . . . . ?
C12 C11 C16 N2 -116.5(3) . . . . ?
C28 Sb2 C19 C24 -112.5(3) . . . . ?
N3 Sb2 C19 C24 162.6(3) . . . . ?
Br2 Sb2 C19 C24 -25.1(3) . . . . ?
C28 Sb2 C19 C20 72.5(2) . . . . ?
N3 Sb2 C19 C20 -12.4(2) . . . . ?
Br2 Sb2 C19 C20 159.9(2) . . . . ?
C20 C19 C24 C23 -0.5(4) . . . . ?
Sb2 C19 C24 C23 -175.4(2) . . . . ?
C19 C24 C23 C22 -0.7(5) . . . . ?
C24 C23 C22 C21 0.9(5) . . . . ?
C23 C22 C21 C20 0.1(5) . . . . ?
C22 C21 C20 C19 -1.2(5) . . . . ?
C22 C21 C20 C25 -179.4(3) . . . . ?
C24 C19 C20 C21 1.4(4) . . . . ?
Sb2 C19 C20 C21 176.7(2) . . . . ?
C24 C19 C20 C25 179.6(3) . . . . ?
Sb2 C19 C20 C25 -5.1(4) . . . . ?
C26 N3 C25 C20 76.1(3) . . . . ?
C27 N3 C25 C20 -163.2(3) . . . . ?
Sb2 N3 C25 C20 -37.1(3) . . . . ?
C21 C20 C25 N3 -150.7(3) . . . . ?
C19 C20 C25 N3 31.0(4) . . . . ?
C19 Sb2 C28 C33 1.6(3) . . . . ?
N3 Sb2 C28 C33 75.5(3) . . . . ?
Br2 Sb2 C28 C33 -89.4(3) . . . . ?
C19 Sb2 C28 C29 179.0(2) . . . . ?
N3 Sb2 C28 C29 -107.1(2) . . . . ?
Br2 Sb2 C28 C29 88.0(2) . . . . ?
C29 C28 C33 C32 3.2(5) . . . . ?
Sb2 C28 C33 C32 -179.4(2) . . . . ?
C28 C33 C32 C31 -0.9(5) . . . . ?
C33 C32 C31 C30 -1.8(5) . . . . ?
C32 C31 C30 C29 2.3(5) . . . . ?
C31 C30 C29 C28 0.0(5) . . . . ?
C31 C30 C29 C34 -177.8(3) . . . . ?
C33 C28 C29 C30 -2.7(4) . . . . ?
Sb2 C28 C29 C30 179.8(2) . . . . ?
C33 C28 C29 C34 175.1(3) . . . . ?
Sb2 C28 C29 C34 -2.4(4) . . . . ?
C35 N4 C34 C29 -163.5(3) . . . . ?
C36 N4 C34 C29 73.7(3) . . . . ?
C30 C29 C34 N4 -112.9(3) . . . . ?
C28 C29 C34 N4 69.4(4) . . . . ?
