#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:34:00 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179851 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/47/7014764.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7014764
loop_
_publ_author_name
'Savjani, Nicky'
'Lancaster, Simon J.'
'Bew, Sean'
'Hughes, David L.'
'Bochmann, Manfred'
_publ_section_title
;
 Synthesis and structures of gold perfluorophthalimido complexes.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1079
_journal_page_last               1090
_journal_paper_doi               10.1039/c0dt01134g
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C20 H6 Ag Au F8 N4 O4, C2 H3 N'
_chemical_formula_structural     '[Au(F4-phthalimide)2-Ag(CNMe)2].MeCN'
_chemical_formula_sum            'C22 H9 Ag Au F8 N5 O4'
_chemical_formula_weight         864.18
_chemical_name_common            'Compound 10'
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'SHELXL-97 and CrysAlisPro RED'
_cell_angle_alpha                94.1577(13)
_cell_angle_beta                 94.4125(11)
_cell_angle_gamma                111.3597(12)
_cell_formula_units_Z            2
_cell_length_a                   8.24928(9)
_cell_length_b                   9.49150(15)
_cell_length_c                   16.8812(3)
_cell_measurement_reflns_used    26250
_cell_measurement_temperature    140(1)
_cell_measurement_theta_max      32.4749
_cell_measurement_theta_min      3.3964
_cell_volume                     1220.11(3)
_computing_cell_refinement
;
CrysAlisPro RED, Oxford Diffraction Ltd., Version 1.171.32.24
;
_computing_data_collection
;
CrysAlisPro CCD, Oxford Diffraction Ltd., Version 1.171.32.24
;
_computing_data_reduction
;
CrysAlisPro RED, Oxford Diffraction Ltd., Version 1.171.32.24
;
_computing_molecular_graphics    'ORTEP (Johnson, 1971 and Farrugia, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      140(1)
_diffrn_detector_area_resol_mean 16.0050
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Oxford Diffraction Xcalibur 3/CCD'
_diffrn_measurement_method       'Thin slice φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           Mo-K\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0412
_diffrn_reflns_av_sigmaI/netI    0.0263
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            34701
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         30.00
_diffrn_reflns_theta_min         3.41
_exptl_absorpt_coefficient_mu    6.911
_exptl_absorpt_correction_T_max  1.278
_exptl_absorpt_correction_T_min  0.676
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro RED, Oxford Diffraction Ltd., Version 1.171.32.24
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.352
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             812
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_refine_diff_density_max         0.863
_refine_diff_density_min         -0.911
_refine_diff_density_rms         0.090
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     390
_refine_ls_number_reflns         7115
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0211
_refine_ls_R_factor_gt           0.0174
_refine_ls_shift/su_max          0.058
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0220P)²+0.0535P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0411
_refine_ls_wR_factor_ref         0.0418
_reflns_number_gt                6535
_reflns_number_total             7115
_reflns_threshold_expression     I>2sigma(I)
_cod_data_source_file            C0DT01134G.TXT
_cod_data_source_block           nickys4
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_cell_volume        1220.12(3)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7014764
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au Au 0.414860(10) 0.491064(9) 0.646836(5) 0.01725(3) Uani 1 1 d . . .
Ag Ag 0.65298(2) 0.81385(2) 0.664045(10) 0.02398(4) Uani 1 1 d . . .
N1 N 0.3125(2) 0.5206(2) 0.54115(10) 0.0178(3) Uani 1 1 d . . .
C2 C 0.3729(3) 0.6521(2) 0.50515(13) 0.0184(4) Uani 1 1 d . . .
O2 O 0.4975(2) 0.76794(19) 0.53036(10) 0.0266(4) Uani 1 1 d . . .
C3 C 0.2567(3) 0.6300(2) 0.42893(13) 0.0180(4) Uani 1 1 d . . .
C4 C 0.2568(3) 0.7228(3) 0.37103(14) 0.0229(4) Uani 1 1 d . . .
F4 F 0.37363(18) 0.86534(17) 0.37462(9) 0.0355(4) Uani 1 1 d . . .
C5 C 0.1306(3) 0.6669(3) 0.30485(14) 0.0240(5) Uani 1 1 d . . .
F5 F 0.1319(2) 0.75400(19) 0.24608(10) 0.0390(4) Uani 1 1 d . . .
C6 C 0.0070(3) 0.5220(3) 0.29913(13) 0.0228(5) Uani 1 1 d . . .
F6 F -0.11067(19) 0.46950(17) 0.23427(8) 0.0322(3) Uani 1 1 d . . .
C7 C 0.0055(3) 0.4287(2) 0.35866(13) 0.0203(4) Uani 1 1 d . . .
F7 F -0.11858(18) 0.28876(15) 0.35096(9) 0.0292(3) Uani 1 1 d . . .
C8 C 0.1315(3) 0.4826(2) 0.42342(12) 0.0175(4) Uani 1 1 d . . .
C9 C 0.1650(3) 0.4125(2) 0.49647(12) 0.0171(4) Uani 1 1 d . . .
O9 O 0.0806(2) 0.28906(17) 0.51499(10) 0.0243(3) Uani 1 1 d . . .
N11 N 0.5124(2) 0.4660(2) 0.75496(11) 0.0190(4) Uani 1 1 d . . .
C12 C 0.4213(3) 0.3582(2) 0.80261(13) 0.0190(4) Uani 1 1 d . . .
O12 O 0.2805(2) 0.25692(18) 0.78320(10) 0.0284(4) Uani 1 1 d . . .
C13 C 0.5303(3) 0.3898(2) 0.88193(13) 0.0180(4) Uani 1 1 d . . .
C14 C 0.5023(3) 0.3243(2) 0.95183(13) 0.0201(4) Uani 1 1 d . . .
F14 F 0.35508(18) 0.20827(15) 0.96058(8) 0.0276(3) Uani 1 1 d . . .
C15 C 0.6296(3) 0.3833(2) 1.01700(13) 0.0222(4) Uani 1 1 d . . .
F15 F 0.6044(2) 0.32317(16) 1.08610(8) 0.0304(3) Uani 1 1 d . . .
C16 C 0.7806(3) 0.5058(3) 1.01157(13) 0.0225(4) Uani 1 1 d . . .
F16 F 0.9008(2) 0.56240(17) 1.07548(8) 0.0332(3) Uani 1 1 d . . .
C17 C 0.8093(3) 0.5735(2) 0.94082(14) 0.0211(4) Uani 1 1 d . . .
F17 F 0.95710(18) 0.69316(16) 0.93859(9) 0.0312(3) Uani 1 1 d . . .
C18 C 0.6834(3) 0.5143(2) 0.87652(12) 0.0177(4) Uani 1 1 d . . .
C19 C 0.6699(3) 0.5643(2) 0.79491(12) 0.0173(4) Uani 1 1 d . . .
O19 O 0.7770(2) 0.67233(17) 0.76928(9) 0.0224(3) Uani 1 1 d . . .
N21 N 0.4878(3) 0.8663(2) 0.74938(13) 0.0280(4) Uani 1 1 d . . .
C22 C 0.3882(3) 0.8852(2) 0.78643(14) 0.0227(4) Uani 1 1 d . . .
C23 C 0.2580(3) 0.9100(3) 0.83333(15) 0.0288(5) Uani 1 1 d . . .
H23A H 0.2406 1.0003 0.8197 0.043 Uiso 1 1 calc R . .
H23B H 0.2983 0.9218 0.8892 0.043 Uiso 1 1 calc R . .
H23C H 0.1494 0.8243 0.8220 0.043 Uiso 1 1 calc R . .
N31 N 0.9179(2) 0.9478(2) 0.63703(13) 0.0300(5) Uani 1 1 d . . .
C32 C 1.0514(3) 0.9920(3) 0.61586(14) 0.0249(5) Uani 1 1 d . . .
C33 C 1.2254(3) 1.0467(3) 0.58864(18) 0.0329(6) Uani 1 1 d D . .
N41 N 0.6842(3) 0.0995(3) 0.94332(16) 0.0415(6) Uani 1 1 d . . .
C42 C 0.7877(3) 0.0676(3) 0.91469(15) 0.0267(5) Uani 1 1 d . . .
C43 C 0.9218(3) 0.0272(3) 0.87867(17) 0.0331(6) Uani 1 1 d . . .
H43A H 0.9895 -0.0006 0.9190 0.050 Uiso 1 1 calc R . .
H43B H 0.9971 0.1128 0.8551 0.050 Uiso 1 1 calc R . .
H43C H 0.8670 -0.0571 0.8382 0.050 Uiso 1 1 calc R . .
H33A H 1.305(6) 1.125(6) 0.628(3) 0.050 Uiso 0.50 1 d PD . .
H33B H 1.209(7) 1.090(8) 0.540(2) 0.050 Uiso 0.50 1 d PD . .
H33C H 1.271(7) 0.969(4) 0.578(4) 0.050 Uiso 0.50 1 d PD . .
H33D H 1.209(7) 0.990(6) 0.537(2) 0.050 Uiso 0.50 1 d PD . .
H33E H 1.300(6) 1.019(7) 0.625(3) 0.050 Uiso 0.50 1 d PD . .
H33F H 1.275(7) 1.1540(18) 0.583(4) 0.050 Uiso 0.50 1 d PD . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Au N11 177.73(7) . . ?
N1 Au Ag 88.99(5) . . ?
N11 Au Ag 90.40(5) . . ?
N31 Ag N21 130.95(8) . . ?
N31 Ag O2 99.25(7) . . ?
N21 Ag O2 108.11(7) . . ?
N31 Ag O19 91.55(7) . . ?
N21 Ag O19 92.02(7) . . ?
O2 Ag O19 140.68(5) . . ?
N31 Ag Au 137.80(6) . . ?
N21 Ag Au 89.24(5) . . ?
O2 Ag Au 74.80(4) . . ?
O19 Ag Au 72.00(3) . . ?
C2 N1 C9 111.36(17) . . ?
C2 N1 Au 124.47(14) . . ?
C9 N1 Au 124.11(14) . . ?
O2 C2 N1 126.76(19) . . ?
O2 C2 C3 125.4(2) . . ?
N1 C2 C3 107.79(17) . . ?
C2 O2 Ag 124.14(14) . . ?
C4 C3 C8 121.1(2) . . ?
C4 C3 C2 132.3(2) . . ?
C8 C3 C2 106.56(18) . . ?
F4 C4 C3 122.8(2) . . ?
F4 C4 C5 118.5(2) . . ?
C3 C4 C5 118.7(2) . . ?
F5 C5 C6 119.8(2) . . ?
F5 C5 C4 119.7(2) . . ?
C6 C5 C4 120.5(2) . . ?
F6 C6 C5 119.5(2) . . ?
F6 C6 C7 119.8(2) . . ?
C5 C6 C7 120.7(2) . . ?
F7 C7 C8 122.3(2) . . ?
F7 C7 C6 118.69(19) . . ?
C8 C7 C6 119.0(2) . . ?
C7 C8 C3 120.0(2) . . ?
C7 C8 C9 132.0(2) . . ?
C3 C8 C9 107.92(17) . . ?
O9 C9 N1 125.92(19) . . ?
O9 C9 C8 127.71(19) . . ?
N1 C9 C8 106.35(17) . . ?
C19 N11 C12 111.35(17) . . ?
C19 N11 Au 124.29(14) . . ?
C12 N11 Au 123.98(14) . . ?
O12 C12 N11 125.95(19) . . ?
O12 C12 C13 126.8(2) . . ?
N11 C12 C13 107.28(17) . . ?
C14 C13 C18 120.52(19) . . ?
C14 C13 C12 132.6(2) . . ?
C18 C13 C12 106.83(18) . . ?
F14 C14 C13 122.59(19) . . ?
F14 C14 C15 118.6(2) . . ?
C13 C14 C15 118.8(2) . . ?
F15 C15 C16 119.3(2) . . ?
F15 C15 C14 120.0(2) . . ?
C16 C15 C14 120.6(2) . . ?
F16 C16 C15 119.7(2) . . ?
F16 C16 C17 119.5(2) . . ?
C15 C16 C17 120.8(2) . . ?
F17 C17 C18 123.0(2) . . ?
F17 C17 C16 118.71(19) . . ?
C18 C17 C16 118.3(2) . . ?
C17 C18 C13 120.9(2) . . ?
C17 C18 C19 131.4(2) . . ?
C13 C18 C19 107.54(18) . . ?
O19 C19 N11 126.69(19) . . ?
O19 C19 C18 126.33(19) . . ?
N11 C19 C18 106.98(18) . . ?
C19 O19 Ag 116.67(13) . . ?
C22 N21 Ag 172.22(19) . . ?
N21 C22 C23 179.2(3) . . ?
C22 C23 H23A 109.5 . . ?
C22 C23 H23B 109.5 . . ?
H23A C23 H23B 109.5 . . ?
C22 C23 H23C 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C32 N31 Ag 167.3(2) . . ?
N31 C32 C33 178.9(3) . . ?
C32 C33 H33A 109(3) . . ?
C32 C33 H33B 104(3) . . ?
H33A C33 H33B 109.4(15) . . ?
C32 C33 H33C 114(3) . . ?
H33A C33 H33C 110.0(15) . . ?
H33B C33 H33C 110.0(15) . . ?
C32 C33 H33D 104(3) . . ?
H33A C33 H33D 147(5) . . ?
H33B C33 H33D 59(3) . . ?
H33C C33 H33D 56(3) . . ?
C32 C33 H33E 107(3) . . ?
H33A C33 H33E 62(3) . . ?
H33B C33 H33E 149(5) . . ?
H33C C33 H33E 54(3) . . ?
H33D C33 H33E 110.3(15) . . ?
C32 C33 H33F 116(3) . . ?
H33A C33 H33F 53(3) . . ?
H33B C33 H33F 56(3) . . ?
H33C C33 H33F 130(5) . . ?
H33D C33 H33F 108.8(15) . . ?
H33E C33 H33F 110.3(15) . . ?
N41 C42 C43 179.4(3) . . ?
C42 C43 H43A 109.5 . . ?
C42 C43 H43B 109.5 . . ?
H43A C43 H43B 109.5 . . ?
C42 C43 H43C 109.5 . . ?
H43A C43 H43C 109.5 . . ?
H43B C43 H43C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au N1 1.9972(17) . ?
Au N11 2.0030(17) . ?
Au Ag 2.95442(19) . ?
Ag N31 2.194(2) . ?
Ag N21 2.207(2) . ?
Ag O2 2.4358(16) . ?
Ag O19 2.6598(15) . ?
N1 C2 1.371(3) . ?
N1 C9 1.393(3) . ?
C2 O2 1.219(3) . ?
C2 C3 1.498(3) . ?
C3 C4 1.362(3) . ?
C3 C8 1.395(3) . ?
C4 F4 1.339(3) . ?
C4 C5 1.395(3) . ?
C5 F5 1.335(2) . ?
C5 C6 1.372(3) . ?
C6 F6 1.339(2) . ?
C6 C7 1.385(3) . ?
C7 F7 1.339(3) . ?
C7 C8 1.376(3) . ?
C8 C9 1.497(3) . ?
C9 O9 1.203(3) . ?
N11 C19 1.380(3) . ?
N11 C12 1.382(3) . ?
C12 O12 1.210(3) . ?
C12 C13 1.500(3) . ?
C13 C14 1.370(3) . ?
C13 C18 1.395(3) . ?
C14 F14 1.336(2) . ?
C14 C15 1.390(3) . ?
C15 F15 1.333(2) . ?
C15 C16 1.375(3) . ?
C16 F16 1.341(2) . ?
C16 C17 1.393(3) . ?
C17 F17 1.335(3) . ?
C17 C18 1.373(3) . ?
C18 C19 1.498(3) . ?
C19 O19 1.218(3) . ?
N21 C22 1.126(3) . ?
C22 C23 1.457(3) . ?
C23 H23A 0.9600 . ?
C23 H23B 0.9600 . ?
C23 H23C 0.9600 . ?
N31 C32 1.124(3) . ?
C32 C33 1.461(3) . ?
C33 H33A 0.960(10) . ?
C33 H33B 0.961(10) . ?
C33 H33C 0.956(10) . ?
C33 H33D 0.961(10) . ?
C33 H33E 0.952(10) . ?
C33 H33F 0.964(10) . ?
N41 C42 1.134(3) . ?
C42 C43 1.455(4) . ?
C43 H43A 0.9600 . ?
C43 H43B 0.9600 . ?
C43 H43C 0.9600 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Au Ag N31 -92.34(10) . . . . ?
N11 Au Ag N31 89.85(10) . . . . ?
N1 Au Ag N21 103.71(8) . . . . ?
N11 Au Ag N21 -74.10(8) . . . . ?
N1 Au Ag O2 -5.30(7) . . . . ?
N11 Au Ag O2 176.89(7) . . . . ?
N1 Au Ag O19 -163.92(6) . . . . ?
N11 Au Ag O19 18.27(7) . . . . ?
N11 Au N1 C2 79.3(18) . . . . ?
Ag Au N1 C2 4.81(17) . . . . ?
N11 Au N1 C9 -97.5(17) . . . . ?
Ag Au N1 C9 -171.93(16) . . . . ?
C9 N1 C2 O2 178.6(2) . . . . ?
Au N1 C2 O2 1.5(3) . . . . ?
C9 N1 C2 C3 -0.6(2) . . . . ?
Au N1 C2 C3 -177.67(14) . . . . ?
N1 C2 O2 Ag -9.5(3) . . . . ?
C3 C2 O2 Ag 169.52(15) . . . . ?
N31 Ag O2 C2 146.28(18) . . . . ?
N21 Ag O2 C2 -74.97(19) . . . . ?
O19 Ag O2 C2 42.3(2) . . . . ?
Au Ag O2 C2 9.10(17) . . . . ?
O2 C2 C3 C4 0.6(4) . . . . ?
N1 C2 C3 C4 179.8(2) . . . . ?
O2 C2 C3 C8 -179.7(2) . . . . ?
N1 C2 C3 C8 -0.5(2) . . . . ?
C8 C3 C4 F4 179.3(2) . . . . ?
C2 C3 C4 F4 -1.0(4) . . . . ?
C8 C3 C4 C5 -1.1(4) . . . . ?
C2 C3 C4 C5 178.6(2) . . . . ?
F4 C4 C5 F5 1.9(4) . . . . ?
C3 C4 C5 F5 -177.8(2) . . . . ?
F4 C4 C5 C6 -179.2(2) . . . . ?
C3 C4 C5 C6 1.1(4) . . . . ?
F5 C5 C6 F6 0.3(3) . . . . ?
C4 C5 C6 F6 -178.6(2) . . . . ?
F5 C5 C6 C7 178.7(2) . . . . ?
C4 C5 C6 C7 -0.2(4) . . . . ?
F6 C6 C7 F7 -2.3(3) . . . . ?
C5 C6 C7 F7 179.4(2) . . . . ?
F6 C6 C7 C8 177.5(2) . . . . ?
C5 C6 C7 C8 -0.8(4) . . . . ?
F7 C7 C8 C3 -179.3(2) . . . . ?
C6 C7 C8 C3 0.9(3) . . . . ?
F7 C7 C8 C9 -0.6(4) . . . . ?
C6 C7 C8 C9 179.6(2) . . . . ?
C4 C3 C8 C7 0.0(3) . . . . ?
C2 C3 C8 C7 -179.7(2) . . . . ?
C4 C3 C8 C9 -179.0(2) . . . . ?
C2 C3 C8 C9 1.3(2) . . . . ?
C2 N1 C9 O9 -177.0(2) . . . . ?
Au N1 C9 O9 0.1(3) . . . . ?
C2 N1 C9 C8 1.3(2) . . . . ?
Au N1 C9 C8 178.46(13) . . . . ?
C7 C8 C9 O9 -2.2(4) . . . . ?
C3 C8 C9 O9 176.7(2) . . . . ?
C7 C8 C9 N1 179.5(2) . . . . ?
C3 C8 C9 N1 -1.6(2) . . . . ?
N1 Au N11 C19 -92.4(17) . . . . ?
Ag Au N11 C19 -17.94(17) . . . . ?
N1 Au N11 C12 79.9(18) . . . . ?
Ag Au N11 C12 154.31(17) . . . . ?
C19 N11 C12 O12 -179.2(2) . . . . ?
Au N11 C12 O12 7.6(3) . . . . ?
C19 N11 C12 C13 0.2(2) . . . . ?
Au N11 C12 C13 -172.91(14) . . . . ?
O12 C12 C13 C14 -3.6(4) . . . . ?
N11 C12 C13 C14 176.9(2) . . . . ?
O12 C12 C13 C18 178.4(2) . . . . ?
N11 C12 C13 C18 -1.1(2) . . . . ?
C18 C13 C14 F14 177.7(2) . . . . ?
C12 C13 C14 F14 -0.1(4) . . . . ?
C18 C13 C14 C15 -0.5(3) . . . . ?
C12 C13 C14 C15 -178.3(2) . . . . ?
F14 C14 C15 F15 0.7(3) . . . . ?
C13 C14 C15 F15 178.98(19) . . . . ?
F14 C14 C15 C16 -177.9(2) . . . . ?
C13 C14 C15 C16 0.4(3) . . . . ?
F15 C15 C16 F16 0.4(3) . . . . ?
C14 C15 C16 F16 179.1(2) . . . . ?
F15 C15 C16 C17 -178.5(2) . . . . ?
C14 C15 C16 C17 0.1(3) . . . . ?
F16 C16 C17 F17 0.4(3) . . . . ?
C15 C16 C17 F17 179.3(2) . . . . ?
F16 C16 C17 C18 -179.4(2) . . . . ?
C15 C16 C17 C18 -0.4(3) . . . . ?
F17 C17 C18 C13 -179.5(2) . . . . ?
C16 C17 C18 C13 0.3(3) . . . . ?
F17 C17 C18 C19 -3.3(4) . . . . ?
C16 C17 C18 C19 176.5(2) . . . . ?
C14 C13 C18 C17 0.2(3) . . . . ?
C12 C13 C18 C17 178.5(2) . . . . ?
C14 C13 C18 C19 -176.82(19) . . . . ?
C12 C13 C18 C19 1.4(2) . . . . ?
C12 N11 C19 O19 -178.5(2) . . . . ?
Au N11 C19 O19 -5.4(3) . . . . ?
C12 N11 C19 C18 0.7(2) . . . . ?
Au N11 C19 C18 173.77(13) . . . . ?
C17 C18 C19 O19 1.3(4) . . . . ?
C13 C18 C19 O19 177.9(2) . . . . ?
C17 C18 C19 N11 -177.9(2) . . . . ?
C13 C18 C19 N11 -1.3(2) . . . . ?
N11 C19 O19 Ag 30.7(3) . . . . ?
C18 C19 O19 Ag -148.33(17) . . . . ?
N31 Ag O19 C19 -170.18(16) . . . . ?
N21 Ag O19 C19 58.75(16) . . . . ?
O2 Ag O19 C19 -63.51(18) . . . . ?
Au Ag O19 C19 -29.79(14) . . . . ?
N31 Ag N21 C22 141.0(15) . . . . ?
O2 Ag N21 C22 20.5(15) . . . . ?
O19 Ag N21 C22 -125.2(15) . . . . ?
Au Ag N21 C22 -53.2(15) . . . . ?
Ag N21 C22 C23 -38(19) . . . . ?
N21 Ag N31 C32 168.3(9) . . . . ?
O2 Ag N31 C32 -67.8(9) . . . . ?
O19 Ag N31 C32 74.2(9) . . . . ?
Au Ag N31 C32 9.7(10) . . . . ?
Ag N31 C32 C33 -40(15) . . . . ?
