#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:34:00 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179851 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/47/7014789.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7014789
loop_
_publ_author_name
'Deng, Zhao-Peng'
'Huo, Li-Hua'
'Xu, Hui'
'Zhao, Hui'
'Ng, Seik Weng'
'Gao, Shan'
_publ_section_title
;
 The first metal-organic framework containing an unprecedented in
 situ-generated C-substituted hexamethylenetetramine ligand.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1224
_journal_page_last               1226
_journal_paper_doi               10.1039/c0dt01153c
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C21 H22 Ag2 N4 O6'
_chemical_formula_sum            'C21 H22 Ag2 N4 O6'
_chemical_formula_weight         642.17
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.212(3)
_cell_angle_beta                 91.969(3)
_cell_angle_gamma                97.795(2)
_cell_formula_units_Z            2
_cell_length_a                   6.0834(5)
_cell_length_b                   12.8715(11)
_cell_length_c                   13.5851(12)
_cell_measurement_reflns_used    6440
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      25.00
_cell_measurement_theta_min      3.07
_cell_volume                     1031.78(15)
_computing_cell_refinement       RAPID-AUTO
_computing_data_collection       'RAPID-AUTO (Rigaku Corporation, 1998)'
_computing_data_reduction
'CrystalStructure (Rigaku/MSC and Rigaku Corporation, 2002)'
_computing_molecular_graphics    'ORTEP-II (Johnson, 1976)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      295(2)
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0455
_diffrn_reflns_av_sigmaI/netI    0.0637
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            7882
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.06
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.948
_exptl_absorpt_correction_T_max  0.763
_exptl_absorpt_correction_T_min  0.661
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Higashi, 1995)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.067
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             636
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.14
_refine_diff_density_max         1.255
_refine_diff_density_min         -1.461
_refine_diff_density_rms         0.183
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.094
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     302
_refine_ls_number_reflns         3585
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.095
_refine_ls_R_factor_all          0.0978
_refine_ls_R_factor_gt           0.0697
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1047P)²+6.1851P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1870
_refine_ls_wR_factor_ref         0.2196
_reflns_number_gt                2503
_reflns_number_total             3585
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            C0DT01153C.TXT
_cod_data_source_block           d
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_database_code               7014789
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 1.30828(14) 0.55832(7) 0.51144(6) 0.0536(3) Uani 1 1 d . . .
Ag2 Ag 0.4360(2) -0.04272(8) 0.85755(9) 0.0666(4) Uani 0.878(2) 1 d PU . 1
Ag2' Ag 0.5985(15) -0.0657(6) 0.8851(7) 0.0666(4) Uani 0.122(2) 1 d PU . 2
O1W O 0.2579(17) 0.0624(8) 0.9922(8) 0.093(3) Uani 1 1 d . . .
H1W1 H 0.1429 0.0702 0.9587 0.112 Uiso 1 1 d R . .
H1W2 H 0.2190 0.0182 1.0297 0.112 Uiso 1 1 d R . .
O1 O 0.5766(15) 0.1112(6) 0.8207(7) 0.068(2) Uani 1 1 d . . .
O2 O 0.8860(16) 0.0814(7) 0.8904(8) 0.079(3) Uani 1 1 d . . .
O3 O 1.5537(13) 0.6569(6) 0.4402(6) 0.062(2) Uani 1 1 d . . .
O4 O 1.8782(13) 0.6044(6) 0.4793(6) 0.0562(19) Uani 1 1 d . . .
O5 O 2.1303(16) 1.1232(7) 0.3216(7) 0.078(3) Uani 1 1 d . . .
N1 N 1.2633(12) 0.6291(6) 0.6865(5) 0.0365(17) Uani 1 1 d . . .
N2 N 1.3268(14) 0.7825(6) 0.8273(6) 0.046(2) Uani 1 1 d . . .
N3 N 1.3715(13) 0.6054(6) 0.8557(6) 0.0399(17) Uani 1 1 d . . .
N4 N 1.0025(12) 0.6451(6) 0.8203(6) 0.0391(17) Uani 1 1 d . . .
C1 C 1.3462(18) 0.7433(8) 0.7169(8) 0.051(3) Uani 1 1 d . . .
H1A H 1.2622 0.7830 0.6792 0.061 Uiso 1 1 calc R . .
H1B H 1.5008 0.7562 0.7014 0.061 Uiso 1 1 calc R . .
C2 C 1.3875(16) 0.5714(8) 0.7469(8) 0.046(2) Uani 1 1 d . . .
H2A H 1.5427 0.5817 0.7319 0.055 Uiso 1 1 calc R . .
H2B H 1.3326 0.4955 0.7276 0.055 Uiso 1 1 calc R . .
C3 C 1.0275(15) 0.6103(9) 0.7111(7) 0.044(2) Uani 1 1 d . . .
H3A H 0.9708 0.5346 0.6905 0.053 Uiso 1 1 calc R . .
H3B H 0.9402 0.6493 0.6740 0.053 Uiso 1 1 calc R . .
C4 C 1.4518(17) 0.7197(8) 0.8813(7) 0.046(2) Uani 1 1 d . . .
H4A H 1.6069 0.7317 0.8664 0.056 Uiso 1 1 calc R . .
H4B H 1.4430 0.7446 0.9530 0.056 Uiso 1 1 calc R . .
C5 C 1.0880(18) 0.7610(8) 0.8474(8) 0.049(2) Uani 1 1 d . . .
H5A H 1.0695 0.7870 0.9181 0.058 Uiso 1 1 calc R . .
H5B H 1.0025 0.7994 0.8088 0.058 Uiso 1 1 calc R . .
C6 C 1.1366(15) 0.5870(7) 0.8768(7) 0.039(2) Uani 1 1 d . . .
H6 H 1.1290 0.6193 0.9479 0.046 Uiso 1 1 calc R . .
C7 C 1.0472(16) 0.4696(7) 0.8664(7) 0.040(2) Uani 1 1 d . . .
C8 C 0.8243(16) 0.4324(8) 0.8418(8) 0.046(2) Uani 1 1 d . . .
H8 H 0.7294 0.4803 0.8304 0.056 Uiso 1 1 calc R . .
C9 C 0.7401(17) 0.3271(8) 0.8340(8) 0.050(3) Uani 1 1 d . . .
H9 H 0.5908 0.3038 0.8142 0.060 Uiso 1 1 calc R . .
C10 C 0.8736(17) 0.2546(8) 0.8550(7) 0.043(2) Uani 1 1 d . . .
C11 C 1.0998(17) 0.2888(8) 0.8808(8) 0.049(2) Uani 1 1 d . . .
H11 H 1.1928 0.2406 0.8934 0.059 Uiso 1 1 calc R . .
C12 C 1.1838(16) 0.3964(8) 0.8874(7) 0.045(2) Uani 1 1 d . . .
H12 H 1.3335 0.4200 0.9060 0.054 Uiso 1 1 calc R . .
C13 C 0.769(2) 0.1417(9) 0.8559(8) 0.052(3) Uani 1 1 d . . .
C14 C 1.7631(18) 0.6690(8) 0.4498(7) 0.043(2) Uani 1 1 d . . .
C15 C 1.8827(16) 0.7671(7) 0.4201(7) 0.039(2) Uani 1 1 d . . .
C16 C 1.7674(17) 0.8275(8) 0.3694(7) 0.046(2) Uani 1 1 d . . .
H16 H 1.6175 0.8053 0.3505 0.056 Uiso 1 1 calc R . .
C17 C 1.8734(17) 0.9213(8) 0.3463(8) 0.048(2) Uani 1 1 d . . .
H17 H 1.7949 0.9610 0.3110 0.058 Uiso 1 1 calc R . .
C18 C 2.0945(17) 0.9560(7) 0.3756(7) 0.044(2) Uani 1 1 d . . .
C19 C 2.2121(18) 0.8947(9) 0.4246(8) 0.052(3) Uani 1 1 d . . .
H19 H 2.3624 0.9170 0.4427 0.062 Uiso 1 1 calc R . .
C20 C 2.1084(17) 0.7997(9) 0.4471(8) 0.051(3) Uani 1 1 d . . .
H20 H 2.1886 0.7585 0.4799 0.062 Uiso 1 1 calc R . .
C21 C 2.214(2) 1.0586(9) 0.3559(9) 0.060(3) Uani 1 1 d . . .
H21 H 2.3661 1.0732 0.3718 0.072 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O3 Ag1 O4 149.9(3) . 2_866 ?
O3 Ag1 N1 114.9(3) . . ?
O4 Ag1 N1 92.0(3) 2_866 . ?
O3 Ag1 O4 111.4(4) . 1_455 ?
N1 Ag1 O4 85.1(3) . 1_455 ?
O4 Ag1 O4 82.6(4) 2_866 1_455 ?
O3 Ag1 Ag1 75.0(2) . 2_866 ?
O4 Ag1 Ag1 83.3(2) 2_866 2_866 ?
N1 Ag1 Ag1 110.96(19) . 2_866 ?
O1 Ag2 N2 155.6(3) . 1_445 ?
O1 Ag2 O1W 86.5(4) . . ?
O1 Ag2 O2 47.7(3) . . ?
O2 Ag2 O1W 98.8(4) . . ?
N2 Ag2 O1W 115.9(3) 1_445 . ?
N2 Ag2 O1W 90.2(4) 1_445 2_657 ?
O1 Ag2 O1W 101.6(4) . 2_657 ?
O1w Ag2 O1W 85.7(3) . 2_657 ?
O2 Ag2 O1W 57.1(3) . 2_657 ?
O2 Ag2 N2 130.6(4) . 1_445 ?
O1W Ag2' N2 114.9(5) 2_657 1_445 ?
O1W Ag2' O2 79.8(5) 2_657 . ?
N2 Ag2' O2 162.7(5) 1_445 . ?
Ag2' O1W Ag2 110.3(6) 2_657 . ?
Ag2' O1W H1W1 149.4 2_657 . ?
Ag2 O1W H1W1 98.7 . . ?
Ag2' O1W H1W2 56.6 2_657 . ?
Ag2 O1W H1W2 103.5 . . ?
H1W1 O1W H1W2 108.3 . . ?
C13 O1 Ag2 112.5(8) . . ?
C13 O2 Ag2' 97.2(8) . . ?
C14 O3 Ag1 129.3(7) . . ?
C14 O4 Ag1 116.0(6) . 2_866 ?
C1 N1 C2 108.2(8) . . ?
C1 N1 C3 108.9(7) . . ?
C2 N1 C3 106.9(7) . . ?
C1 N1 Ag1 113.2(5) . . ?
C2 N1 Ag1 108.0(5) . . ?
C3 N1 Ag1 111.5(5) . . ?
C4 N2 C5 108.8(7) . . ?
C4 N2 C1 107.7(8) . . ?
C5 N2 C1 107.4(8) . . ?
C4 N2 Ag2 116.8(6) . 1_665 ?
C5 N2 Ag2 109.4(6) . 1_665 ?
C1 N2 Ag2 106.4(5) . 1_665 ?
C4 N2 Ag2' 89.7(6) . 1_665 ?
C5 N2 Ag2' 131.2(6) . 1_665 ?
C1 N2 Ag2' 109.1(6) . 1_665 ?
C4 N3 C6 109.2(7) . . ?
C4 N3 C2 107.0(7) . . ?
C6 N3 C2 107.8(7) . . ?
C6 N4 C5 109.2(7) . . ?
C6 N4 C3 109.5(7) . . ?
C5 N4 C3 107.1(7) . . ?
N1 C1 N2 111.4(7) . . ?
N1 C1 H1A 109.4 . . ?
N2 C1 H1A 109.4 . . ?
N1 C1 H1B 109.4 . . ?
N2 C1 H1B 109.4 . . ?
H1A C1 H1B 108.0 . . ?
N1 C2 N3 113.8(7) . . ?
N1 C2 H2A 108.8 . . ?
N3 C2 H2A 108.8 . . ?
N1 C2 H2B 108.8 . . ?
N3 C2 H2B 108.8 . . ?
H2A C2 H2B 107.7 . . ?
N1 C3 N4 111.4(7) . . ?
N1 C3 H3A 109.3 . . ?
N4 C3 H3A 109.3 . . ?
N1 C3 H3B 109.3 . . ?
N4 C3 H3B 109.3 . . ?
H3A C3 H3B 108.0 . . ?
N3 C4 N2 113.2(8) . . ?
N3 C4 H4A 108.9 . . ?
N2 C4 H4A 108.9 . . ?
N3 C4 H4B 108.9 . . ?
N2 C4 H4B 108.9 . . ?
H4A C4 H4B 107.7 . . ?
N4 C5 N2 111.3(8) . . ?
N4 C5 H5A 109.4 . . ?
N2 C5 H5A 109.4 . . ?
N4 C5 H5B 109.4 . . ?
N2 C5 H5B 109.4 . . ?
H5A C5 H5B 108.0 . . ?
N3 C6 N4 111.2(7) . . ?
N3 C6 C7 112.9(8) . . ?
N4 C6 C7 114.2(8) . . ?
N3 C6 H6 105.9 . . ?
N4 C6 H6 105.9 . . ?
C7 C6 H6 105.9 . . ?
C8 C7 C12 117.8(9) . . ?
C8 C7 C6 120.8(9) . . ?
C12 C7 C6 121.3(8) . . ?
C9 C8 C7 121.5(10) . . ?
C9 C8 H8 119.2 . . ?
C7 C8 H8 119.2 . . ?
C8 C9 C10 120.9(9) . . ?
C8 C9 H9 119.5 . . ?
C10 C9 H9 119.5 . . ?
C9 C10 C11 119.4(9) . . ?
C9 C10 C13 119.0(9) . . ?
C11 C10 C13 121.4(10) . . ?
C12 C11 C10 119.0(10) . . ?
C12 C11 H11 120.5 . . ?
C10 C11 H11 120.5 . . ?
C11 C12 C7 121.3(9) . . ?
C11 C12 H12 119.4 . . ?
C7 C12 H12 119.4 . . ?
O1 C13 O2 122.9(10) . . ?
O1 C13 C10 119.0(11) . . ?
O2 C13 C10 118.1(10) . . ?
O3 C14 O4 125.6(9) . . ?
O3 C14 C15 116.1(9) . . ?
O4 C14 C15 118.3(9) . . ?
C16 C15 C20 119.7(9) . . ?
C16 C15 C14 119.9(9) . . ?
C20 C15 C14 120.4(9) . . ?
C15 C16 C17 120.4(9) . . ?
C15 C16 H16 119.8 . . ?
C17 C16 H16 119.8 . . ?
C18 C17 C16 120.3(10) . . ?
C18 C17 H17 119.9 . . ?
C16 C17 H17 119.9 . . ?
C17 C18 C19 119.5(9) . . ?
C17 C18 C21 122.2(10) . . ?
C19 C18 C21 118.2(10) . . ?
C18 C19 C20 120.7(10) . . ?
C18 C19 H19 119.6 . . ?
C20 C19 H19 119.6 . . ?
C19 C20 C15 119.3(10) . . ?
C19 C20 H20 120.3 . . ?
C15 C20 H20 120.3 . . ?
O5 C21 C18 125.6(12) . . ?
O5 C21 H21 117.2 . . ?
C18 C21 H21 117.2 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 O3 2.199(7) . ?
Ag1 O4 2.272(7) 2_866 ?
Ag1 O4 2.798(7) 1_455 ?
Ag1 N1 2.414(7) . ?
Ag1 Ag1 2.9343(18) 2_866 ?
Ag2 O1 2.205(8) . ?
Ag2 O2 2.949(11) . ?
Ag2 N2 2.211(8) 1_445 ?
Ag2 O1W 2.434(11) . ?
Ag2 O1W 2.786(11) 2_657 ?
Ag2' O1W 1.845(14) 2_657 ?
Ag2' N2 2.367(11) 1_445 ?
Ag2' O2 2.385(11) . ?
O1W Ag2' 1.845(14) 2_657 ?
O1W H1W1 0.8500 . ?
O1W H1W2 0.8501 . ?
O1 C13 1.231(14) . ?
O2 C13 1.264(14) . ?
O3 C14 1.261(13) . ?
O4 C14 1.269(12) . ?
O4 Ag1 2.272(7) 2_866 ?
O5 C21 1.189(15) . ?
N1 C1 1.461(12) . ?
N1 C2 1.464(13) . ?
N1 C3 1.483(11) . ?
N2 C4 1.459(14) . ?
N2 C5 1.486(13) . ?
N2 C1 1.500(13) . ?
N2 Ag2 2.211(8) 1_665 ?
N2 Ag2' 2.367(11) 1_665 ?
N3 C4 1.455(12) . ?
N3 C6 1.464(12) . ?
N3 C2 1.467(13) . ?
N4 C6 1.470(12) . ?
N4 C5 1.481(12) . ?
N4 C3 1.483(12) . ?
C1 H1A 0.9700 . ?
C1 H1B 0.9700 . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 H5A 0.9700 . ?
C5 H5B 0.9700 . ?
C6 C7 1.512(12) . ?
C6 H6 0.9800 . ?
C7 C8 1.382(14) . ?
C7 C12 1.400(14) . ?
C8 C9 1.366(14) . ?
C8 H8 0.9300 . ?
C9 C10 1.380(15) . ?
C9 H9 0.9300 . ?
C10 C11 1.398(14) . ?
C10 C13 1.508(14) . ?
C11 C12 1.394(14) . ?
C11 H11 0.9300 . ?
C12 H12 0.9300 . ?
C14 C15 1.502(13) . ?
C15 C16 1.377(14) . ?
C15 C20 1.394(14) . ?
C16 C17 1.386(14) . ?
C16 H16 0.9300 . ?
C17 C18 1.378(14) . ?
C17 H17 0.9300 . ?
C18 C19 1.380(15) . ?
C18 C21 1.494(14) . ?
C19 C20 1.391(15) . ?
C19 H19 0.9300 . ?
C20 H20 0.9300 . ?
C21 H21 0.9300 . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O1W H1W1 O2 0.85 1.83 2.675(14) 176.5 1_455
O1W H1W2 O2 0.85 1.90 2.745(14) 176.4 2_657
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 Ag2 O1W Ag2' -105.2(5) . . . 2_657 ?
N2 Ag2 O1W Ag2' 84.8(6) 1_445 . . 2_657 ?
N2 Ag2 O1 C13 -103.8(11) 1_445 . . . ?
O1W Ag2 O1 C13 98.5(8) . . . . ?
O1W Ag2' O2 C13 -138.4(8) 2_657 . . . ?
N2 Ag2' O2 C13 72(2) 1_445 . . . ?
O4 Ag1 O3 C14 -77.1(11) 2_866 . . . ?
N1 Ag1 O3 C14 74.7(10) . . . . ?
Ag1 Ag1 O3 C14 -31.8(9) 2_866 . . . ?
O3 Ag1 N1 C1 18.8(7) . . . . ?
O4 Ag1 N1 C1 -174.9(7) 2_866 . . . ?
Ag1 Ag1 N1 C1 101.5(6) 2_866 . . . ?
O3 Ag1 N1 C2 -101.0(6) . . . . ?
O4 Ag1 N1 C2 65.3(6) 2_866 . . . ?
Ag1 Ag1 N1 C2 -18.3(6) 2_866 . . . ?
O3 Ag1 N1 C3 141.9(6) . . . . ?
O4 Ag1 N1 C3 -51.8(6) 2_866 . . . ?
Ag1 Ag1 N1 C3 -135.4(6) 2_866 . . . ?
C2 N1 C1 N2 -57.1(10) . . . . ?
C3 N1 C1 N2 58.7(11) . . . . ?
Ag1 N1 C1 N2 -176.8(6) . . . . ?
C4 N2 C1 N1 58.0(11) . . . . ?
C5 N2 C1 N1 -58.9(11) . . . . ?
Ag2 N2 C1 N1 -176.0(7) 1_665 . . . ?
Ag2' N2 C1 N1 154.1(7) 1_665 . . . ?
C1 N1 C2 N3 58.1(10) . . . . ?
C3 N1 C2 N3 -59.0(10) . . . . ?
Ag1 N1 C2 N3 -179.1(6) . . . . ?
C4 N3 C2 N1 -57.6(10) . . . . ?
C6 N3 C2 N1 59.8(10) . . . . ?
C1 N1 C3 N4 -59.5(10) . . . . ?
C2 N1 C3 N4 57.2(10) . . . . ?
Ag1 N1 C3 N4 175.0(6) . . . . ?
C6 N4 C3 N1 -58.4(10) . . . . ?
C5 N4 C3 N1 59.8(10) . . . . ?
C6 N3 C4 N2 -57.9(10) . . . . ?
C2 N3 C4 N2 58.5(10) . . . . ?
C5 N2 C4 N3 56.6(10) . . . . ?
C1 N2 C4 N3 -59.4(10) . . . . ?
Ag2 N2 C4 N3 -179.0(6) 1_665 . . . ?
Ag2' N2 C4 N3 -169.4(7) 1_665 . . . ?
C6 N4 C5 N2 57.5(10) . . . . ?
C3 N4 C5 N2 -61.0(10) . . . . ?
C4 N2 C5 N4 -55.9(10) . . . . ?
C1 N2 C5 N4 60.3(10) . . . . ?
Ag2 N2 C5 N4 175.4(6) 1_665 . . . ?
Ag2' N2 C5 N4 -162.9(7) 1_665 . . . ?
C4 N3 C6 N4 58.1(9) . . . . ?
C2 N3 C6 N4 -57.8(9) . . . . ?
C4 N3 C6 C7 -171.9(8) . . . . ?
C2 N3 C6 C7 72.1(10) . . . . ?
C5 N4 C6 N3 -58.5(9) . . . . ?
C3 N4 C6 N3 58.5(9) . . . . ?
C5 N4 C6 C7 172.3(8) . . . . ?
C3 N4 C6 C7 -70.8(9) . . . . ?
N3 C6 C7 C8 -152.9(9) . . . . ?
N4 C6 C7 C8 -24.5(12) . . . . ?
N3 C6 C7 C12 31.3(12) . . . . ?
N4 C6 C7 C12 159.7(8) . . . . ?
C12 C7 C8 C9 -2.7(15) . . . . ?
C6 C7 C8 C9 -178.7(9) . . . . ?
C7 C8 C9 C10 3.1(16) . . . . ?
C8 C9 C10 C11 -2.6(15) . . . . ?
C8 C9 C10 C13 173.7(10) . . . . ?
C9 C10 C11 C12 1.8(15) . . . . ?
C13 C10 C11 C12 -174.4(9) . . . . ?
C10 C11 C12 C7 -1.5(15) . . . . ?
C8 C7 C12 C11 1.9(14) . . . . ?
C6 C7 C12 C11 177.9(9) . . . . ?
Ag2 O1 C13 O2 13.9(14) . . . . ?
Ag2 O1 C13 C10 -168.3(7) . . . . ?
Ag2' O2 C13 O1 -9.0(13) . . . . ?
Ag2' O2 C13 C10 173.2(8) . . . . ?
C9 C10 C13 O1 12.9(15) . . . . ?
C11 C10 C13 O1 -170.9(10) . . . . ?
C9 C10 C13 O2 -169.2(10) . . . . ?
C11 C10 C13 O2 7.0(15) . . . . ?
Ag1 O3 C14 O4 21.9(15) . . . . ?
Ag1 O3 C14 C15 -160.2(7) . . . . ?
Ag1 O4 C14 O3 11.3(13) 2_866 . . . ?
Ag1 O4 C14 C15 -166.6(6) 2_866 . . . ?
O3 C14 C15 C16 -10.9(13) . . . . ?
O4 C14 C15 C16 167.1(9) . . . . ?
O3 C14 C15 C20 166.5(10) . . . . ?
O4 C14 C15 C20 -15.4(14) . . . . ?
C20 C15 C16 C17 -0.9(15) . . . . ?
C14 C15 C16 C17 176.5(9) . . . . ?
C15 C16 C17 C18 -1.1(15) . . . . ?
C16 C17 C18 C19 2.5(15) . . . . ?
C16 C17 C18 C21 -177.6(9) . . . . ?
C17 C18 C19 C20 -1.7(16) . . . . ?
C21 C18 C19 C20 178.4(10) . . . . ?
C18 C19 C20 C15 -0.3(16) . . . . ?
C16 C15 C20 C19 1.7(15) . . . . ?
C14 C15 C20 C19 -175.8(9) . . . . ?
C17 C18 C21 O5 6.2(18) . . . . ?
C19 C18 C21 O5 -173.9(12) . . . . ?
