#------------------------------------------------------------------------------
#$Date: 2016-03-25 13:35:19 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179852 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/48/7014821.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7014821
loop_
_publ_author_name
'Zhang, Wei Hong'
'Dong, Zhe'
'Wang, Yao Yu'
'Hou, Lei'
'Jin, Jun Cheng'
'Huang, Wen Huan'
'Shi, Qi Zhen'
_publ_section_title
;
 Synthesis, structural diversity and fluorescent characterisation of a
 series of d10 metal--organic frameworks (MOFs): reaction conditions,
 secondary ligand and metal effects
;
_journal_issue                   11
_journal_name_full               'Dalton Transactions'
_journal_page_first              2509
_journal_paper_doi               10.1039/c0dt01206h
_journal_volume                  40
_journal_year                    2011
_chemical_formula_moiety         'C19 H22 N O4 Zn'
_chemical_formula_sum            'C19 H22 N O4 Zn'
_chemical_formula_weight         393.75
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 113.450(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   22.602(5)
_cell_length_b                   14.062(3)
_cell_length_c                   11.233(2)
_cell_measurement_reflns_used    1237
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      22.766
_cell_measurement_theta_min      2.328
_cell_volume                     3275.3(12)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      295(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0488
_diffrn_reflns_av_sigmaI/netI    0.0606
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            8099
_diffrn_reflns_theta_full        25.10
_diffrn_reflns_theta_max         25.10
_diffrn_reflns_theta_min         1.75
_exptl_absorpt_coefficient_mu    1.525
_exptl_absorpt_correction_T_max  0.7816
_exptl_absorpt_correction_T_min  0.7502
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.597
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1640
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.17
_refine_diff_density_max         0.555
_refine_diff_density_min         -0.502
_refine_diff_density_rms         0.082
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     229
_refine_ls_number_reflns         2904
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.003
_refine_ls_R_factor_all          0.0556
_refine_ls_R_factor_gt           0.0366
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0446P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0868
_refine_ls_wR_factor_ref         0.0919
_reflns_number_gt                2026
_reflns_number_total             2904
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            C0DT01206H.TXT
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1555 2011-01-17 13:19:09Z saulius 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7014821
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.0000 0.30424(3) -0.2500 0.02250(16) Uani 1 2 d S . .
Zn2 Zn 0.0000 0.09764(3) -0.2500 0.02081(17) Uani 1 2 d S . .
N1 N 0.0000 0.4515(2) -0.2500 0.0234(9) Uani 1 2 d S . .
N2 N 0.0000 0.9529(2) -0.2500 0.0194(8) Uani 1 2 d S . .
O1 O 0.07115(11) 0.29063(14) -0.0716(2) 0.0287(5) Uani 1 1 d . . .
O2 O 0.08225(11) 0.13443(15) -0.0898(2) 0.0324(6) Uani 1 1 d . . .
O3 O 0.43215(11) 0.22890(15) 0.3306(2) 0.0301(6) Uani 1 1 d . . .
O4 O 0.44809(11) 0.38511(15) 0.3567(2) 0.0299(6) Uani 1 1 d . . .
C1 C 0.10277(16) 0.2134(2) -0.0370(3) 0.0247(8) Uani 1 1 d . . .
C2 C 0.16876(16) 0.2121(2) 0.0697(3) 0.0285(8) Uani 1 1 d . . .
H2A H 0.1983 0.1939 0.0303 0.034 Uiso 1 1 calc R . .
H2B H 0.1691 0.1607 0.1275 0.034 Uiso 1 1 calc R . .
C3 C 0.19896(16) 0.2990(2) 0.1563(3) 0.0220(7) Uani 1 1 d . . .
C4 C 0.16309(16) 0.3240(2) 0.2430(3) 0.0272(8) Uani 1 1 d . . .
H4A H 0.1192 0.3427 0.1894 0.033 Uiso 1 1 calc R . .
H4B H 0.1614 0.2686 0.2931 0.033 Uiso 1 1 calc R . .
C5 C 0.19758(16) 0.4053(2) 0.3346(3) 0.0335(9) Uani 1 1 d . . .
H5 H 0.1744 0.4203 0.3898 0.040 Uiso 1 1 calc R . .
C6 C 0.19883(17) 0.4927(2) 0.2566(3) 0.0368(9) Uani 1 1 d . . .
H6A H 0.2197 0.5450 0.3146 0.044 Uiso 1 1 calc R . .
H6B H 0.1551 0.5118 0.2020 0.044 Uiso 1 1 calc R . .
C7 C 0.23597(16) 0.4689(2) 0.1725(3) 0.0307(8) Uani 1 1 d . . .
H7 H 0.2370 0.5253 0.1220 0.037 Uiso 1 1 calc R . .
C8 C 0.20151(17) 0.3882(2) 0.0790(3) 0.0289(8) Uani 1 1 d . . .
H8A H 0.2243 0.3737 0.0241 0.035 Uiso 1 1 calc R . .
H8B H 0.1581 0.4078 0.0237 0.035 Uiso 1 1 calc R . .
C9 C 0.26830(15) 0.2712(2) 0.2444(3) 0.0236(8) Uani 1 1 d . . .
H9A H 0.2673 0.2154 0.2945 0.028 Uiso 1 1 calc R . .
H9B H 0.2915 0.2544 0.1909 0.028 Uiso 1 1 calc R . .
C10 C 0.26679(16) 0.3766(2) 0.4204(3) 0.0310(9) Uani 1 1 d . . .
H10A H 0.2662 0.3223 0.4732 0.037 Uiso 1 1 calc R . .
H10B H 0.2881 0.4287 0.4781 0.037 Uiso 1 1 calc R . .
C11 C 0.30462(15) 0.3509(2) 0.3376(3) 0.0217(7) Uani 1 1 d . . .
C12 C 0.37257(16) 0.3183(2) 0.4283(3) 0.0259(8) Uani 1 1 d . . .
H12A H 0.3895 0.3631 0.4996 0.031 Uiso 1 1 calc R . .
H12B H 0.3689 0.2571 0.4647 0.031 Uiso 1 1 calc R . .
C13 C 0.42092(15) 0.3090(2) 0.3665(3) 0.0231(7) Uani 1 1 d . . .
C14 C 0.02224(16) 0.5007(2) -0.1391(3) 0.0282(8) Uani 1 1 d . . .
H14 H 0.0386 0.4674 -0.0612 0.034 Uiso 1 1 calc R . .
C15 C 0.02216(16) 0.5980(2) -0.1347(3) 0.0266(8) Uani 1 1 d . . .
H15 H 0.0368 0.6293 -0.0553 0.032 Uiso 1 1 calc R . .
C16 C 0.0000 0.6497(3) -0.2500 0.0207(10) Uani 1 2 d S . .
C17 C 0.0000 0.7547(3) -0.2500 0.0186(10) Uani 1 2 d S . .
C18 C 0.01998(15) 0.8057(2) -0.3328(3) 0.0216(7) Uani 1 1 d . . .
H18 H 0.0331 0.7741 -0.3909 0.026 Uiso 1 1 calc R . .
C19 C 0.02030(15) 0.9031(2) -0.3285(3) 0.0233(7) Uani 1 1 d . . .
H19 H 0.0353 0.9363 -0.3825 0.028 Uiso 1 1 calc R . .
C26 C 0.30524(16) 0.4394(2) 0.2572(3) 0.0273(8) Uani 1 1 d . . .
H26A H 0.3273 0.4912 0.3148 0.033 Uiso 1 1 calc R . .
H26B H 0.3283 0.4253 0.2027 0.033 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Zn1 O1 169.11(12) . 2_554 ?
O1 Zn1 N1 95.44(6) . . ?
O1 Zn1 N1 95.44(6) 2_554 . ?
O1 Zn1 O3 88.93(9) . 8_455 ?
O1 Zn1 O3 88.68(9) 2_554 8_455 ?
N1 Zn1 O3 102.70(6) . 8_455 ?
O1 Zn1 O3 88.68(9) . 7 ?
O1 Zn1 O3 88.93(9) 2_554 7 ?
N1 Zn1 O3 102.70(6) . 7 ?
O3 Zn1 O3 154.60(12) 8_455 7 ?
O1 Zn1 Zn2 84.56(6) . . ?
O1 Zn1 Zn2 84.56(6) 2_554 . ?
N1 Zn1 Zn2 180.0 . . ?
O3 Zn1 Zn2 77.30(6) 8_455 . ?
O3 Zn1 Zn2 77.30(6) 7 . ?
O4 Zn2 O4 166.05(12) 7 8_455 ?
O4 Zn2 N2 96.97(6) 7 1_545 ?
O4 Zn2 N2 96.97(6) 8_455 1_545 ?
O4 Zn2 O2 87.30(9) 7 . ?
O4 Zn2 O2 89.23(9) 8_455 . ?
N2 Zn2 O2 104.45(6) 1_545 . ?
O4 Zn2 O2 89.23(9) 7 2_554 ?
O4 Zn2 O2 87.30(9) 8_455 2_554 ?
N2 Zn2 O2 104.45(6) 1_545 2_554 ?
O2 Zn2 O2 151.10(12) . 2_554 ?
O4 Zn2 Zn1 83.03(6) 7 . ?
O4 Zn2 Zn1 83.03(6) 8_455 . ?
N2 Zn2 Zn1 180.0 1_545 . ?
O2 Zn2 Zn1 75.55(6) . . ?
O2 Zn2 Zn1 75.55(6) 2_554 . ?
C14 N1 C14 117.5(4) . 2_554 ?
C14 N1 Zn1 121.23(19) . . ?
C14 N1 Zn1 121.23(19) 2_554 . ?
C19 N2 C19 117.1(4) . 2_554 ?
C19 N2 Zn2 121.47(18) . 1_565 ?
C19 N2 Zn2 121.47(18) 2_554 1_565 ?
C1 O1 Zn1 120.9(2) . . ?
C1 O2 Zn2 131.7(2) . . ?
C13 O3 Zn1 127.4(2) . 7 ?
C13 O4 Zn2 125.3(2) . 7 ?
O2 C1 O1 123.5(3) . . ?
O2 C1 C2 115.5(3) . . ?
O1 C1 C2 120.9(3) . . ?
C1 C2 C3 123.1(3) . . ?
C1 C2 H2A 106.6 . . ?
C3 C2 H2A 106.6 . . ?
C1 C2 H2B 106.6 . . ?
C3 C2 H2B 106.6 . . ?
H2A C2 H2B 106.5 . . ?
C9 C3 C4 108.1(3) . . ?
C9 C3 C8 108.3(3) . . ?
C4 C3 C8 108.6(2) . . ?
C9 C3 C2 106.7(2) . . ?
C4 C3 C2 111.6(3) . . ?
C8 C3 C2 113.3(3) . . ?
C5 C4 C3 110.0(2) . . ?
C5 C4 H4A 109.7 . . ?
C3 C4 H4A 109.7 . . ?
C5 C4 H4B 109.7 . . ?
C3 C4 H4B 109.7 . . ?
H4A C4 H4B 108.2 . . ?
C6 C5 C4 109.8(3) . . ?
C6 C5 C10 109.2(3) . . ?
C4 C5 C10 110.2(3) . . ?
C6 C5 H5 109.2 . . ?
C4 C5 H5 109.2 . . ?
C10 C5 H5 109.2 . . ?
C5 C6 C7 108.7(3) . . ?
C5 C6 H6A 109.9 . . ?
C7 C6 H6A 109.9 . . ?
C5 C6 H6B 109.9 . . ?
C7 C6 H6B 109.9 . . ?
H6A C6 H6B 108.3 . . ?
C6 C7 C26 110.6(3) . . ?
C6 C7 C8 109.3(3) . . ?
C26 C7 C8 109.9(3) . . ?
C6 C7 H7 109.0 . . ?
C26 C7 H7 109.0 . . ?
C8 C7 H7 109.0 . . ?
C7 C8 C3 109.9(3) . . ?
C7 C8 H8A 109.7 . . ?
C3 C8 H8A 109.7 . . ?
C7 C8 H8B 109.7 . . ?
C3 C8 H8B 109.7 . . ?
H8A C8 H8B 108.2 . . ?
C11 C9 C3 112.7(2) . . ?
C11 C9 H9A 109.0 . . ?
C3 C9 H9A 109.0 . . ?
C11 C9 H9B 109.0 . . ?
C3 C9 H9B 109.0 . . ?
H9A C9 H9B 107.8 . . ?
C5 C10 C11 110.9(3) . . ?
C5 C10 H10A 109.5 . . ?
C11 C10 H10A 109.5 . . ?
C5 C10 H10B 109.5 . . ?
C11 C10 H10B 109.5 . . ?
H10A C10 H10B 108.0 . . ?
C9 C11 C10 108.0(2) . . ?
C9 C11 C12 110.9(3) . . ?
C10 C11 C12 108.6(3) . . ?
C9 C11 C26 108.6(3) . . ?
C10 C11 C26 107.6(3) . . ?
C12 C11 C26 113.0(3) . . ?
C13 C12 C11 115.8(3) . . ?
C13 C12 H12A 108.3 . . ?
C11 C12 H12A 108.3 . . ?
C13 C12 H12B 108.3 . . ?
C11 C12 H12B 108.3 . . ?
H12A C12 H12B 107.4 . . ?
O3 C13 O4 124.5(3) . . ?
O3 C13 C12 120.0(3) . . ?
O4 C13 C12 115.6(3) . . ?
N1 C14 C15 123.1(3) . . ?
N1 C14 H14 118.4 . . ?
C15 C14 H14 118.4 . . ?
C14 C15 C16 119.6(3) . . ?
C14 C15 H15 120.2 . . ?
C16 C15 H15 120.2 . . ?
C15 C16 C15 117.1(4) 2_554 . ?
C15 C16 C17 121.47(19) 2_554 . ?
C15 C16 C17 121.47(19) . . ?
C18 C17 C18 117.6(4) 2_554 . ?
C18 C17 C16 121.22(18) 2_554 . ?
C18 C17 C16 121.22(18) . . ?
C19 C18 C17 119.5(3) . . ?
C19 C18 H18 120.2 . . ?
C17 C18 H18 120.2 . . ?
N2 C19 C18 123.1(3) . . ?
N2 C19 H19 118.4 . . ?
C18 C19 H19 118.4 . . ?
C7 C26 C11 109.7(3) . . ?
C7 C26 H26A 109.7 . . ?
C11 C26 H26A 109.7 . . ?
C7 C26 H26B 109.7 . . ?
C11 C26 H26B 109.7 . . ?
H26A C26 H26B 108.2 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Zn1 O1 2.018(2) . ?
Zn1 O1 2.018(2) 2_554 ?
Zn1 N1 2.070(4) . ?
Zn1 O3 2.120(2) 8_455 ?
Zn1 O3 2.120(2) 7 ?
Zn1 Zn2 2.9053(9) . ?
Zn2 O4 1.998(2) 7 ?
Zn2 O4 1.998(2) 8_455 ?
Zn2 N2 2.035(3) 1_545 ?
Zn2 O2 2.074(2) . ?
Zn2 O2 2.074(2) 2_554 ?
N1 C14 1.336(4) . ?
N1 C14 1.336(4) 2_554 ?
N2 C19 1.342(3) . ?
N2 C19 1.342(3) 2_554 ?
N2 Zn2 2.035(3) 1_565 ?
O1 C1 1.273(4) . ?
O2 C1 1.257(3) . ?
O3 C13 1.256(3) . ?
O3 Zn1 2.120(2) 7 ?
O4 C13 1.260(3) . ?
O4 Zn2 1.998(2) 7 ?
C1 C2 1.496(4) . ?
C2 C3 1.541(4) . ?
C2 H2A 0.9700 . ?
C2 H2B 0.9700 . ?
C3 C9 1.534(4) . ?
C3 C4 1.535(4) . ?
C3 C8 1.540(4) . ?
C4 C5 1.529(4) . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C5 C6 1.517(5) . ?
C5 C10 1.529(5) . ?
C5 H5 0.9800 . ?
C6 C7 1.530(4) . ?
C6 H6A 0.9700 . ?
C6 H6B 0.9700 . ?
C7 C26 1.531(4) . ?
C7 C8 1.533(4) . ?
C7 H7 0.9800 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C9 C11 1.531(4) . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C10 C11 1.536(4) . ?
C10 H10A 0.9700 . ?
C10 H10B 0.9700 . ?
C11 C12 1.537(4) . ?
C11 C26 1.541(4) . ?
C12 C13 1.515(4) . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C14 C15 1.368(4) . ?
C14 H14 0.9300 . ?
C15 C16 1.393(4) . ?
C15 H15 0.9300 . ?
C16 C15 1.393(4) 2_554 ?
C16 C17 1.476(6) . ?
C17 C18 1.385(4) 2_554 ?
C17 C18 1.385(4) . ?
C18 C19 1.370(4) . ?
C18 H18 0.9300 . ?
C19 H19 0.9300 . ?
C26 H26A 0.9700 . ?
C26 H26B 0.9700 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O1 Zn1 Zn2 O4 -99.88(9) . . . 7 ?
O1 Zn1 Zn2 O4 80.12(9) 2_554 . . 7 ?
N1 Zn1 Zn2 O4 146(100) . . . 7 ?
O3 Zn1 Zn2 O4 169.99(9) 8_455 . . 7 ?
O3 Zn1 Zn2 O4 -10.01(9) 7 . . 7 ?
O1 Zn1 Zn2 O4 80.12(9) . . . 8_455 ?
O1 Zn1 Zn2 O4 -99.88(9) 2_554 . . 8_455 ?
N1 Zn1 Zn2 O4 -34(100) . . . 8_455 ?
O3 Zn1 Zn2 O4 -10.01(9) 8_455 . . 8_455 ?
O3 Zn1 Zn2 O4 169.99(9) 7 . . 8_455 ?
O1 Zn1 Zn2 N2 -119(100) . . . 1_545 ?
O1 Zn1 Zn2 N2 61(100) 2_554 . . 1_545 ?
N1 Zn1 Zn2 N2 0.0 . . . 1_545 ?
O3 Zn1 Zn2 N2 151(100) 8_455 . . 1_545 ?
O3 Zn1 Zn2 N2 -29(100) 7 . . 1_545 ?
O1 Zn1 Zn2 O2 -10.88(9) . . . . ?
O1 Zn1 Zn2 O2 169.12(9) 2_554 . . . ?
N1 Zn1 Zn2 O2 -125(100) . . . . ?
O3 Zn1 Zn2 O2 -101.01(9) 8_455 . . . ?
O3 Zn1 Zn2 O2 78.99(9) 7 . . . ?
O1 Zn1 Zn2 O2 169.12(9) . . . 2_554 ?
O1 Zn1 Zn2 O2 -10.88(9) 2_554 . . 2_554 ?
N1 Zn1 Zn2 O2 55(100) . . . 2_554 ?
O3 Zn1 Zn2 O2 78.99(9) 8_455 . . 2_554 ?
O3 Zn1 Zn2 O2 -101.01(9) 7 . . 2_554 ?
O1 Zn1 N1 C14 -23.45(18) . . . . ?
O1 Zn1 N1 C14 156.55(18) 2_554 . . . ?
O3 Zn1 N1 C14 66.68(18) 8_455 . . . ?
O3 Zn1 N1 C14 -113.32(18) 7 . . . ?
Zn2 Zn1 N1 C14 90(100) . . . . ?
O1 Zn1 N1 C14 156.55(18) . . . 2_554 ?
O1 Zn1 N1 C14 -23.45(18) 2_554 . . 2_554 ?
O3 Zn1 N1 C14 -113.32(18) 8_455 . . 2_554 ?
O3 Zn1 N1 C14 66.68(18) 7 . . 2_554 ?
Zn2 Zn1 N1 C14 -90(100) . . . 2_554 ?
O1 Zn1 O1 C1 19.7(2) 2_554 . . . ?
N1 Zn1 O1 C1 -160.3(2) . . . . ?
O3 Zn1 O1 C1 97.0(2) 8_455 . . . ?
O3 Zn1 O1 C1 -57.7(2) 7 . . . ?
Zn2 Zn1 O1 C1 19.7(2) . . . . ?
O4 Zn2 O2 C1 91.0(3) 7 . . . ?
O4 Zn2 O2 C1 -75.5(3) 8_455 . . . ?
N2 Zn2 O2 C1 -172.5(3) 1_545 . . . ?
O2 Zn2 O2 C1 7.5(3) 2_554 . . . ?
Zn1 Zn2 O2 C1 7.5(3) . . . . ?
Zn2 O2 C1 O1 5.3(5) . . . . ?
Zn2 O2 C1 C2 -173.4(2) . . . . ?
Zn1 O1 C1 O2 -21.3(4) . . . . ?
Zn1 O1 C1 C2 157.3(2) . . . . ?
O2 C1 C2 C3 -172.7(3) . . . . ?
O1 C1 C2 C3 8.6(5) . . . . ?
C1 C2 C3 C9 -175.2(3) . . . . ?
C1 C2 C3 C4 66.9(4) . . . . ?
C1 C2 C3 C8 -56.1(4) . . . . ?
C9 C3 C4 C5 58.5(3) . . . . ?
C8 C3 C4 C5 -58.7(3) . . . . ?
C2 C3 C4 C5 175.6(3) . . . . ?
C3 C4 C5 C6 60.7(3) . . . . ?
C3 C4 C5 C10 -59.7(3) . . . . ?
C4 C5 C6 C7 -61.1(3) . . . . ?
C10 C5 C6 C7 59.8(3) . . . . ?
C5 C6 C7 C26 -60.1(3) . . . . ?
C5 C6 C7 C8 61.1(3) . . . . ?
C6 C7 C8 C3 -60.6(3) . . . . ?
C26 C7 C8 C3 61.0(3) . . . . ?
C9 C3 C8 C7 -58.2(3) . . . . ?
C4 C3 C8 C7 58.9(3) . . . . ?
C2 C3 C8 C7 -176.4(3) . . . . ?
C4 C3 C9 C11 -59.4(3) . . . . ?
C8 C3 C9 C11 58.1(3) . . . . ?
C2 C3 C9 C11 -179.6(2) . . . . ?
C6 C5 C10 C11 -61.6(3) . . . . ?
C4 C5 C10 C11 59.2(3) . . . . ?
C3 C9 C11 C10 58.3(3) . . . . ?
C3 C9 C11 C12 177.2(2) . . . . ?
C3 C9 C11 C26 -58.1(3) . . . . ?
C5 C10 C11 C9 -57.1(3) . . . . ?
C5 C10 C11 C12 -177.4(3) . . . . ?
C5 C10 C11 C26 60.0(3) . . . . ?
C9 C11 C12 C13 73.2(3) . . . . ?
C10 C11 C12 C13 -168.2(2) . . . . ?
C26 C11 C12 C13 -48.9(4) . . . . ?
Zn1 O3 C13 O4 2.0(5) 7 . . . ?
Zn1 O3 C13 C12 -177.03(19) 7 . . . ?
Zn2 O4 C13 O3 13.9(4) 7 . . . ?
Zn2 O4 C13 C12 -167.07(19) 7 . . . ?
C11 C12 C13 O3 -98.4(3) . . . . ?
C11 C12 C13 O4 82.5(3) . . . . ?
C14 N1 C14 C15 1.1(2) 2_554 . . . ?
Zn1 N1 C14 C15 -178.9(2) . . . . ?
N1 C14 C15 C16 -2.2(5) . . . . ?
C14 C15 C16 C15 1.0(2) . . . 2_554 ?
C14 C15 C16 C17 -179.0(2) . . . . ?
C15 C16 C17 C18 136.8(2) 2_554 . . 2_554 ?
C15 C16 C17 C18 -43.2(2) . . . 2_554 ?
C15 C16 C17 C18 -43.2(2) 2_554 . . . ?
C15 C16 C17 C18 136.8(2) . . . . ?
C18 C17 C18 C19 1.1(2) 2_554 . . . ?
C16 C17 C18 C19 -178.9(2) . . . . ?
C19 N2 C19 C18 1.2(2) 2_554 . . . ?
Zn2 N2 C19 C18 -178.8(2) 1_565 . . . ?
C17 C18 C19 N2 -2.3(4) . . . . ?
C6 C7 C26 C11 60.1(3) . . . . ?
C8 C7 C26 C11 -60.8(3) . . . . ?
C9 C11 C26 C7 58.1(3) . . . . ?
C10 C11 C26 C7 -58.6(3) . . . . ?
C12 C11 C26 C7 -178.4(3) . . . . ?
