#------------------------------------------------------------------------------
#$Date: 2016-03-25 14:22:13 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179892 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/88/7018831.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7018831
loop_
_publ_author_name
'Ni, Jia'
'Wei, Kai-Ju'
'Min, Yuanzeng'
'Chen, Yaowen'
'Zhan, Shunze'
'Li, Dan'
'Liu, Yangzhong'
_publ_section_title
;
 Copper(i) coordination polymers of 2,2'-dipyridylamine derivatives:
 syntheses, structures, and luminescence.
;
_journal_issue                   17
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5280
_journal_page_last               5293
_journal_paper_doi               10.1039/c2dt12032a
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C24 H18 Cu I N5'
_chemical_formula_weight         566.87
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 95.2010(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   9.7052(8)
_cell_length_b                   15.6248(12)
_cell_length_c                   30.199(2)
_cell_measurement_temperature    293(2)
_cell_volume                     4560.6(6)
_computing_cell_refinement       'SAINT (Bruker, 2002)'
_computing_data_collection       'SMART (Bruker, 2002)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'ORTEP-II (Johnson, 1976)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEX area-dectector diffractometer'
_diffrn_measurement_method       'φ and ω-scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0594
_diffrn_reflns_av_sigmaI/netI    0.0507
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            17020
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.52
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.332
_exptl_absorpt_correction_T_max  0.2732
_exptl_absorpt_correction_T_min  0.1038
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2002)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.651
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             2232
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.211
_refine_diff_density_min         -0.460
_refine_diff_density_rms         0.075
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     282
_refine_ls_number_reflns         4007
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0642
_refine_ls_R_factor_gt           0.0445
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0284P)²+9.4546P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0940
_refine_ls_wR_factor_ref         0.0985
_reflns_number_gt                2741
_reflns_number_total             4007
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt12032a.txt
_cod_data_source_block           8
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'no' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        4560.5(6)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7018831
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cu1 Cu 0.58719(7) 0.05321(5) 0.48565(2) 0.0741(2) Uani 1 1 d .
C1 C 0.5329(7) 0.2215(4) 0.52483(18) 0.0743(16) Uani 1 1 d .
H1 H 0.5611 0.2000 0.5529 0.089 Uiso 1 1 calc R
C2 C 0.4349(9) 0.2780(5) 0.5214(2) 0.105(2) Uani 1 1 d .
H2 H 0.3966 0.2981 0.5466 0.126 Uiso 1 1 calc R
C3 C 0.3888(9) 0.3074(5) 0.4799(3) 0.125(3) Uani 1 1 d .
H3 H 0.3128 0.3438 0.4761 0.150 Uiso 1 1 calc R
C4 C 0.4574(7) 0.2821(4) 0.44396(19) 0.094(2) Uani 1 1 d .
H4 H 0.4304 0.3028 0.4156 0.112 Uiso 1 1 calc R
C5 C 0.5654(5) 0.2264(3) 0.45074(15) 0.0554(13) Uani 1 1 d .
C6 C 0.7371(5) 0.1368(3) 0.41478(16) 0.0580(13) Uani 1 1 d .
C7 C 0.8365(6) 0.1412(4) 0.38468(17) 0.0714(15) Uani 1 1 d .
H7 H 0.8345 0.1858 0.3642 0.086 Uiso 1 1 calc R
C8 C 0.9364(7) 0.0808(5) 0.3850(2) 0.092(2) Uani 1 1 d .
H8 H 0.9989 0.0809 0.3634 0.110 Uiso 1 1 calc R
C9 C 0.9445(7) 0.0188(5) 0.4178(3) 0.106(2) Uani 1 1 d .
H9 H 1.0155 -0.0213 0.4201 0.127 Uiso 1 1 calc R
C10 C 0.8430(7) 0.0190(5) 0.4468(3) 0.113(3) Uani 1 1 d .
H10 H 0.8478 -0.0220 0.4692 0.135 Uiso 1 1 calc R
C11 C 0.6009(5) 0.2435(4) 0.37210(14) 0.0582(13) Uani 1 1 d .
C12 C 0.5122(6) 0.2055(4) 0.34008(16) 0.0713(15) Uani 1 1 d .
H12 H 0.4741 0.1523 0.3454 0.086 Uiso 1 1 calc R
C13 C 0.4792(6) 0.2463(4) 0.29956(16) 0.0728(16) Uani 1 1 d .
H13 H 0.4192 0.2197 0.2780 0.087 Uiso 1 1 calc R
C14 C 0.5327(6) 0.3240(4) 0.29080(14) 0.0635(14) Uani 1 1 d .
C15 C 0.6192(6) 0.3629(4) 0.32400(15) 0.0690(15) Uani 1 1 d .
H15 H 0.6554 0.4167 0.3190 0.083 Uiso 1 1 calc R
C16 C 0.6523(6) 0.3234(4) 0.36399(16) 0.0697(15) Uani 1 1 d .
H16 H 0.7099 0.3508 0.3858 0.084 Uiso 1 1 calc R
C17 C 0.5000 0.4586(5) 0.2500 0.067(2) Uani 1 2 d S
C18 C 0.3999(7) 0.5035(4) 0.26962(18) 0.0789(17) Uani 1 1 d .
H18 H 0.3320 0.4742 0.2833 0.095 Uiso 1 1 calc R
C19 C 0.3994(7) 0.5919(4) 0.26910(17) 0.0774(16) Uani 1 1 d .
H19 H 0.3301 0.6216 0.2819 0.093 Uiso 1 1 calc R
C20 C 0.5000 0.6358(5) 0.2500 0.069(2) Uani 1 2 d S
C21 C 0.5360(6) 0.7715(4) 0.29029(17) 0.0723(16) Uani 1 1 d .
C22 C 0.4836(8) 0.8500(5) 0.2977(2) 0.098(2) Uani 1 1 d .
H22 H 0.4219 0.8766 0.2767 0.118 Uiso 1 1 calc R
C23 C 0.5252(10) 0.8884(5) 0.3373(3) 0.120(3) Uani 1 1 d .
H23 H 0.4914 0.9424 0.3433 0.144 Uiso 1 1 calc R
C24 C 0.6142(9) 0.8497(7) 0.3679(3) 0.118(3) Uani 1 1 d .
H24 H 0.6443 0.8772 0.3943 0.141 Uiso 1 1 calc R
C25 C 0.6589(8) 0.7693(6) 0.3591(2) 0.110(3) Uani 1 1 d .
H25 H 0.7166 0.7412 0.3806 0.132 Uiso 1 1 calc R
I1 I 0.34788(4) 0.02272(3) 0.440196(12) 0.07646(19) Uani 1 1 d .
N1 N 0.5956(5) 0.1926(3) 0.49026(14) 0.0726(13) Uani 1 1 d .
N2 N 0.6347(4) 0.1995(3) 0.41408(12) 0.0592(11) Uani 1 1 d .
N3 N 0.7377(5) 0.0748(3) 0.44481(16) 0.0754(13) Uani 1 1 d .
N4 N 0.5000 0.3667(4) 0.2500 0.077(2) Uani 1 2 d S
N5 N 0.5000 0.7278(5) 0.2500 0.0790(19) Uani 1 2 d S
N6 N 0.6225(6) 0.7285(4) 0.31998(16) 0.0895(16) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Cu1 N1 81.24(18) . .
N3 Cu1 I1 118.41(14) . 5_656
N1 Cu1 I1 113.66(11) . 5_656
N3 Cu1 Cu1 147.62(15) . 5_656
N1 Cu1 Cu1 130.09(13) . 5_656
I1 Cu1 Cu1 61.60(3) 5_656 5_656
N3 Cu1 I1 111.35(15) . .
N1 Cu1 I1 103.89(12) . .
I1 Cu1 I1 120.50(3) 5_656 .
Cu1 Cu1 I1 58.90(3) 5_656 .
C2 C1 N1 123.6(6) . .
C2 C1 H1 118.2 . .
N1 C1 H1 118.2 . .
C1 C2 C3 118.5(6) . .
C1 C2 H2 120.7 . .
C3 C2 H2 120.7 . .
C2 C3 C4 118.8(7) . .
C2 C3 H3 120.6 . .
C4 C3 H3 120.6 . .
C5 C4 C3 118.9(6) . .
C5 C4 H4 120.6 . .
C3 C4 H4 120.6 . .
N1 C5 C4 119.9(5) . .
N1 C5 N2 120.7(5) . .
C4 C5 N2 119.1(4) . .
N3 C6 C7 121.7(5) . .
N3 C6 N2 118.9(5) . .
C7 C6 N2 119.5(5) . .
C8 C7 C6 120.0(6) . .
C8 C7 H7 120.0 . .
C6 C7 H7 120.0 . .
C7 C8 C9 119.3(6) . .
C7 C8 H8 120.4 . .
C9 C8 H8 120.4 . .
C10 C9 C8 117.2(7) . .
C10 C9 H9 121.4 . .
C8 C9 H9 121.4 . .
N3 C10 C9 124.0(7) . .
N3 C10 H10 118.0 . .
C9 C10 H10 118.0 . .
C12 C11 C16 118.9(4) . .
C12 C11 N2 119.2(5) . .
C16 C11 N2 121.9(4) . .
C11 C12 C13 120.1(5) . .
C11 C12 H12 119.9 . .
C13 C12 H12 119.9 . .
C14 C13 C12 121.3(5) . .
C14 C13 H13 119.3 . .
C12 C13 H13 119.3 . .
C13 C14 C15 117.9(4) . .
C13 C14 N4 122.3(5) . .
C15 C14 N4 119.8(5) . .
C16 C15 C14 121.2(5) . .
C16 C15 H15 119.4 . .
C14 C15 H15 119.4 . .
C15 C16 C11 120.5(5) . .
C15 C16 H16 119.8 . .
C11 C16 H16 119.8 . .
C18 C17 C18 118.6(8) 2_655 .
C18 C17 N4 120.7(4) 2_655 .
C18 C17 N4 120.7(4) . .
C17 C18 C19 120.5(6) . .
C17 C18 H18 119.8 . .
C19 C18 H18 119.8 . .
C20 C19 C18 120.5(6) . .
C20 C19 H19 119.8 . .
C18 C19 H19 119.8 . .
C19 C20 C19 119.5(8) . 2_655
C19 C20 N5 120.3(4) . .
C19 C20 N5 120.3(4) 2_655 .
N6 C21 C22 124.2(5) . .
N6 C21 N5 114.9(5) . .
C22 C21 N5 120.9(6) . .
C21 C22 C23 117.2(7) . .
C21 C22 H22 121.4 . .
C23 C22 H22 121.4 . .
C24 C23 C22 121.6(8) . .
C24 C23 H23 119.2 . .
C22 C23 H23 119.2 . .
C23 C24 C25 118.2(7) . .
C23 C24 H24 120.9 . .
C25 C24 H24 120.9 . .
N6 C25 C24 122.7(7) . .
N6 C25 H25 118.7 . .
C24 C25 H25 118.7 . .
Cu1 I1 Cu1 59.50(3) 5_656 .
C5 N1 C1 119.6(5) . .
C5 N1 Cu1 109.8(3) . .
C1 N1 Cu1 111.8(4) . .
C6 N2 C5 125.9(4) . .
C6 N2 C11 116.7(4) . .
C5 N2 C11 117.3(4) . .
C6 N3 C10 117.5(5) . .
C6 N3 Cu1 125.4(4) . .
C10 N3 Cu1 117.0(4) . .
C14 N4 C14 123.6(7) 2_655 .
C14 N4 C17 118.2(3) 2_655 .
C14 N4 C17 118.2(3) . .
C21 N5 C21 122.1(7) . 2_655
C21 N5 C20 119.0(4) . .
C21 N5 C20 119.0(4) 2_655 .
C21 N6 C25 116.1(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 N3 2.024(4) .
Cu1 N1 2.183(5) .
Cu1 I1 2.5619(8) 5_656
Cu1 Cu1 2.5780(14) 5_656
Cu1 I1 2.6320(8) .
C1 C2 1.294(9) .
C1 N1 1.335(7) .
C1 H1 0.9300 .
C2 C3 1.372(10) .
C2 H2 0.9300 .
C3 C4 1.382(9) .
C3 H3 0.9300 .
C4 C5 1.364(7) .
C4 H4 0.9300 .
C5 N1 1.314(6) .
C5 N2 1.410(6) .
C6 N3 1.327(6) .
C6 C7 1.386(7) .
C6 N2 1.395(6) .
C7 C8 1.353(9) .
C7 H7 0.9300 .
C8 C9 1.381(10) .
C8 H8 0.9300 .
C9 C10 1.377(10) .
C9 H9 0.9300 .
C10 N3 1.340(8) .
C10 H10 0.9300 .
C11 C12 1.370(7) .
C11 C16 1.374(7) .
C11 N2 1.453(6) .
C12 C13 1.391(7) .
C12 H12 0.9300 .
C13 C14 1.356(7) .
C13 H13 0.9300 .
C14 C15 1.388(7) .
C14 N4 1.412(6) .
C15 C16 1.368(7) .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 C18 1.376(7) 2_655
C17 C18 1.376(7) .
C17 N4 1.435(10) .
C18 C19 1.380(8) .
C18 H18 0.9300 .
C19 C20 1.364(7) .
C19 H19 0.9300 .
C20 C19 1.364(7) 2_655
C20 N5 1.437(10) .
C21 N6 1.351(7) .
C21 C22 1.353(8) .
C21 N5 1.412(6) .
C22 C23 1.365(10) .
C22 H22 0.9300 .
C23 C24 1.350(11) .
C23 H23 0.9300 .
C24 C25 1.363(11) .
C24 H24 0.9300 .
C25 N6 1.360(8) .
C25 H25 0.9300 .
I1 Cu1 2.5619(8) 5_656
N4 C14 1.412(6) 2_655
N5 C21 1.412(6) 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 C3 2.7(12) . .
C1 C2 C3 C4 -6.2(12) . .
C2 C3 C4 C5 2.3(12) . .
C3 C4 C5 N1 5.3(10) . .
C3 C4 C5 N2 179.2(6) . .
N3 C6 C7 C8 0.9(8) . .
N2 C6 C7 C8 180.0(5) . .
C6 C7 C8 C9 -5.1(10) . .
C7 C8 C9 C10 4.3(11) . .
C8 C9 C10 N3 0.6(13) . .
C16 C11 C12 C13 2.2(9) . .
N2 C11 C12 C13 -179.6(5) . .
C11 C12 C13 C14 -0.3(9) . .
C12 C13 C14 C15 -1.5(9) . .
C12 C13 C14 N4 -179.7(5) . .
C13 C14 C15 C16 1.5(9) . .
N4 C14 C15 C16 179.6(5) . .
C14 C15 C16 C11 0.5(9) . .
C12 C11 C16 C15 -2.3(9) . .
N2 C11 C16 C15 179.6(5) . .
C18 C17 C18 C19 0.7(4) 2_655 .
N4 C17 C18 C19 -179.3(4) . .
C17 C18 C19 C20 -1.5(8) . .
C18 C19 C20 C19 0.7(4) . 2_655
C18 C19 C20 N5 -179.3(4) . .
N6 C21 C22 C23 2.1(11) . .
N5 C21 C22 C23 -179.1(6) . .
C21 C22 C23 C24 -0.3(12) . .
C22 C23 C24 C25 -2.2(14) . .
C23 C24 C25 N6 3.1(13) . .
N3 Cu1 I1 Cu1 145.40(15) . 5_656
N1 Cu1 I1 Cu1 -128.72(13) . 5_656
I1 Cu1 I1 Cu1 0.0 5_656 5_656
C4 C5 N1 C1 -9.0(8) . .
N2 C5 N1 C1 177.2(5) . .
C4 C5 N1 Cu1 122.2(5) . .
N2 C5 N1 Cu1 -51.6(5) . .
C2 C1 N1 C5 5.1(9) . .
C2 C1 N1 Cu1 -125.2(6) . .
N3 Cu1 N1 C5 60.7(4) . .
I1 Cu1 N1 C5 178.0(3) 5_656 .
Cu1 Cu1 N1 C5 -110.1(3) 5_656 .
I1 Cu1 N1 C5 -49.3(4) . .
N3 Cu1 N1 C1 -164.1(4) . .
I1 Cu1 N1 C1 -46.8(4) 5_656 .
Cu1 Cu1 N1 C1 25.1(5) 5_656 .
I1 Cu1 N1 C1 86.0(4) . .
N3 C6 N2 C5 27.3(7) . .
C7 C6 N2 C5 -151.7(5) . .
N3 C6 N2 C11 -155.4(5) . .
C7 C6 N2 C11 25.5(7) . .
N1 C5 N2 C6 0.7(8) . .
C4 C5 N2 C6 -173.2(5) . .
N1 C5 N2 C11 -176.6(5) . .
C4 C5 N2 C11 9.6(7) . .
C12 C11 N2 C6 81.7(6) . .
C16 C11 N2 C6 -100.2(6) . .
C12 C11 N2 C5 -100.8(6) . .
C16 C11 N2 C5 77.3(6) . .
C7 C6 N3 C10 3.8(8) . .
N2 C6 N3 C10 -175.2(6) . .
C7 C6 N3 Cu1 -172.5(4) . .
N2 C6 N3 Cu1 8.4(7) . .
C9 C10 N3 C6 -4.6(11) . .
C9 C10 N3 Cu1 172.0(7) . .
N1 Cu1 N3 C6 -42.0(5) . .
I1 Cu1 N3 C6 -154.2(4) 5_656 .
Cu1 Cu1 N3 C6 124.8(4) 5_656 .
I1 Cu1 N3 C6 59.6(5) . .
N1 Cu1 N3 C10 141.7(6) . .
I1 Cu1 N3 C10 29.4(6) 5_656 .
Cu1 Cu1 N3 C10 -51.6(7) 5_656 .
I1 Cu1 N3 C10 -116.8(5) . .
C13 C14 N4 C14 -30.3(4) . 2_655
C15 C14 N4 C14 151.6(6) . 2_655
C13 C14 N4 C17 149.7(4) . .
C15 C14 N4 C17 -28.4(6) . .
C18 C17 N4 C14 -69.6(4) 2_655 2_655
C18 C17 N4 C14 110.4(4) . 2_655
C18 C17 N4 C14 110.4(4) 2_655 .
C18 C17 N4 C14 -69.6(4) . .
N6 C21 N5 C21 -152.2(6) . 2_655
C22 C21 N5 C21 28.9(5) . 2_655
N6 C21 N5 C20 27.8(5) . .
C22 C21 N5 C20 -151.1(5) . .
C19 C20 N5 C21 72.0(4) . .
C19 C20 N5 C21 -108.0(4) 2_655 .
C19 C20 N5 C21 -108.0(4) . 2_655
C19 C20 N5 C21 72.0(4) 2_655 2_655
C22 C21 N6 C25 -1.2(9) . .
N5 C21 N6 C25 179.9(5) . .
C24 C25 N6 C21 -1.5(10) . .
