#------------------------------------------------------------------------------
#$Date: 2017-07-11 15:10:40 +0300 (Tue, 11 Jul 2017) $
#$Revision: 198633 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/01/91/7019165.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7019165
loop_
_publ_author_name
'Fang, Ming'
'Shi, Peng-Fei'
'Zhao, Bin'
'Jiang, Dong-Xue'
'Cheng, Peng'
'Shi, Wei'
_publ_section_title
;
 A series of 3d-4f heterometallic three-dimensional coordination polymers:
 syntheses, structures and magnetic properties.
;
_journal_issue                   22
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6820
_journal_page_last               6826
_journal_paper_doi               10.1039/c2dt30391d
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C72 H69 Cl2 Co2 Eu3 N12 O48'
_chemical_formula_weight         2515.03
_chemical_name_systematic
;
?
;
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   49.3489(8)
_cell_length_b                   18.5280(4)
_cell_length_c                   18.4705(5)
_cell_measurement_temperature    293(2)
_cell_volume                     16888.3(6)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0580
_diffrn_reflns_av_sigmaI/netI    0.0867
_diffrn_reflns_limit_h_max       56
_diffrn_reflns_limit_h_min       -58
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            45027
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.46
_exptl_absorpt_coefficient_mu    2.759
_exptl_absorpt_correction_T_max  0.8519
_exptl_absorpt_correction_T_min  0.7699
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sabdas
_exptl_crystal_density_diffrn    1.978
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             9966
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_refine_diff_density_max         3.544
_refine_diff_density_min         -2.432
_refine_diff_density_rms         0.212
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1280
_refine_ls_number_reflns         14863
_refine_ls_number_restraints     1615
_refine_ls_restrained_S_all      1.029
_refine_ls_R_factor_all          0.1003
_refine_ls_R_factor_gt           0.0672
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0690P)²+206.9581P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1602
_refine_ls_wR_factor_ref         0.1709
_reflns_number_gt                9952
_reflns_number_total             14863
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt30391d.txt
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_refine_ls_hydrogen_treatment' value 'constra' was replaced with the
value 'constr' as specified in the replacement file
'src/cod-tools/trunk/data/replacement-values/replacement_values.lst'.

Automatic conversion script
Id: cif_fix_values 5376 2017-05-30 11:51:03Z andrius 
;
_cod_original_sg_symbol_H-M      Pbca
_cod_database_code               7019165
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.121311(9) 0.58068(3) 0.69833(3) 0.01162(13) Uani 1 1 d U
Eu2 Eu -0.122222(9) 0.60114(3) 1.14371(3) 0.01277(13) Uani 1 1 d U
Eu3 Eu 0.124338(9) 0.47843(3) 1.29880(3) 0.01595(14) Uani 1 1 d U
Co4 Co 0.24658(2) 0.61658(7) 1.03495(7) 0.0082(3) Uani 1 1 d U
Co5 Co 0.00235(2) 0.75185(7) 0.88617(7) 0.0089(3) Uani 1 1 d U
O1 O -0.10013(13) 0.7108(4) 1.1163(4) 0.0183(9) Uani 1 1 d U
O2 O -0.08935(14) 0.8082(4) 1.0507(4) 0.0214(11) Uani 1 1 d U
O3 O 0.09297(13) 0.4942(4) 0.8704(4) 0.0169(8) Uani 1 1 d U
O4 O 0.08848(13) 0.5894(4) 0.7950(4) 0.0175(8) Uani 1 1 d U
O5 O 0.08689(16) 0.4135(4) 1.2069(5) 0.0332(10) Uani 1 1 d U
O6 O 0.07714(15) 0.4462(5) 1.3165(5) 0.0320(10) Uani 1 1 d U
O7 O 0.09654(16) 0.5855(5) 1.3364(5) 0.0351(14) Uani 1 1 d U
O8 O 0.09981(16) 0.5678(5) 1.2186(5) 0.0355(14) Uani 1 1 d U
O9 O 0.08693(14) 0.7534(4) 0.5861(4) 0.0230(11) Uani 1 1 d U
O10 O 0.08655(14) 0.6468(4) 0.6417(4) 0.0215(9) Uani 1 1 d U
O11 O 0.08601(13) 0.3748(4) 0.7621(4) 0.0206(11) Uani 1 1 d U
O12 O 0.09559(13) 0.4749(4) 0.7007(4) 0.0210(11) Uani 1 1 d U
O13 O 0.14782(14) 0.4345(4) 1.1934(4) 0.0266(9) Uani 1 1 d U
O14 O 0.15962(15) 0.5448(4) 1.2223(4) 0.0264(9) Uani 1 1 d U
O15 O 0.34731(14) 0.4431(4) 0.8810(4) 0.0240(9) Uani 1 1 d U
O16 O 0.33151(14) 0.5507(4) 0.8500(4) 0.0236(9) Uani 1 1 d U
O17 O 0.15441(13) 0.4891(4) 0.8999(4) 0.0178(9) Uani 1 1 d U
O18 O 0.14546(13) 0.5578(4) 0.8038(4) 0.0180(8) Uani 1 1 d U
O19 O 0.33889(15) 0.8067(4) 1.0114(4) 0.0277(11) Uani 1 1 d U
O20 O 0.33978(14) 0.8312(4) 0.8946(4) 0.0214(9) Uani 1 1 d U
O21 O 0.14615(15) 0.4064(4) 0.7537(4) 0.0274(9) Uani 1 1 d U
O22 O 0.15701(15) 0.4885(4) 0.6687(4) 0.0269(9) Uani 1 1 d U
O23 O 0.15379(16) 0.6452(5) 0.6350(5) 0.0378(15) Uani 1 1 d U
O24 O 0.15537(17) 0.7099(5) 0.5327(5) 0.0389(16) Uani 1 1 d U
O25 O 0.11545(19) 0.5375(5) 0.5707(5) 0.049(3) Uani 1 1 d U
H1C H 0.1058 0.5755 0.5654 0.059 Uiso 1 1 d R
H1D H 0.1320 0.5499 0.5657 0.059 Uiso 1 1 d R
O26 O 0.12527(16) 0.6998(5) 0.7575(5) 0.041(2) Uani 1 1 d U
H1A H 0.1101 0.7158 0.7399 0.049 Uiso 1 1 d R
H1B H 0.1382 0.7140 0.7298 0.049 Uiso 1 1 d R
O27 O -0.11738(16) 0.6029(4) 1.0128(4) 0.032(2) Uani 1 1 d U
H27A H -0.1048 0.5739 0.9973 0.038 Uiso 1 1 d R
H27B H -0.1320 0.5926 0.9900 0.038 Uiso 1 1 d R
O29 O 0.12628(17) 0.3456(5) 1.3099(6) 0.051(3) Uani 1 1 d U
H29A H 0.1251 0.3159 1.2752 0.061 Uiso 1 1 d R
H29B H 0.1240 0.3221 1.3512 0.061 Uiso 1 1 d R
O30 O 0.11432(17) 0.4444(5) 1.4255(5) 0.040(2) Uani 1 1 d U
H30A H 0.0986 0.4326 1.4398 0.048 Uiso 1 1 d R
H30B H 0.1160 0.4304 1.3819 0.048 Uiso 1 1 d R
N1 N -0.02269(16) 0.7100(4) 0.9627(5) 0.0163(7) Uani 1 1 d U
N2 N 0.02292(16) 0.6644(5) 0.9084(5) 0.0157(7) Uani 1 1 d U
N3 N 0.01436(18) 0.2926(5) 1.1973(5) 0.0250(8) Uani 1 1 d U
N4 N -0.02729(17) 0.2102(5) 1.1897(5) 0.0218(8) Uani 1 1 d U
N5 N 0.01944(16) 0.6946(5) 0.4655(5) 0.0169(7) Uani 1 1 d U
N6 N -0.02133(16) 0.6633(4) 0.3809(5) 0.0150(8) Uani 1 1 d U
N7 N 0.22597(17) 0.5338(5) 1.0797(5) 0.0232(8) Uani 1 1 d U
N8 N 0.26748(17) 0.5347(5) 0.9927(5) 0.0221(8) Uani 1 1 d U
N9 N 0.21981(16) 0.6243(4) 0.9501(5) 0.0158(7) Uani 1 1 d U
N10 N 0.26543(16) 0.6960(5) 0.9745(5) 0.0174(7) Uani 1 1 d U
N11 N 0.22672(17) 0.3686(5) 0.6177(5) 0.0241(8) Uani 1 1 d U
N12 N 0.27261(17) 0.3031(5) 0.5895(5) 0.0225(8) Uani 1 1 d U
C1 C -0.0853(2) 0.7458(6) 1.0736(6) 0.0180(8) Uani 1 1 d U
C2 C -0.04666(19) 0.7359(6) 0.9865(6) 0.0167(7) Uani 1 1 d U
H2 H -0.0548 0.7733 0.9609 0.020 Uiso 1 1 calc R
C3 C -0.0596(2) 0.7089(6) 1.0476(6) 0.0170(7) Uani 1 1 d U
C4 C -0.04792(19) 0.6516(5) 1.0844(6) 0.0166(7) Uani 1 1 d U
H4 H -0.0564 0.6320 1.1248 0.020 Uiso 1 1 calc R
C5 C -0.02330(19) 0.6239(6) 1.0602(6) 0.0163(7) Uani 1 1 d U
H5 H -0.0151 0.5859 1.0845 0.020 Uiso 1 1 calc R
C6 C -0.01122(19) 0.6537(5) 0.9993(6) 0.0161(7) Uani 1 1 d U
C7 C 0.01409(19) 0.6286(6) 0.9685(6) 0.0159(7) Uani 1 1 d U
C8 C 0.02916(19) 0.5709(5) 0.9958(6) 0.0161(7) Uani 1 1 d U
H8 H 0.0240 0.5487 1.0388 0.019 Uiso 1 1 calc R
C9 C 0.05155(19) 0.5470(6) 0.9594(6) 0.0164(7) Uani 1 1 d U
H9 H 0.0617 0.5089 0.9776 0.020 Uiso 1 1 calc R
C10 C 0.05893(19) 0.5802(6) 0.8951(6) 0.0164(7) Uani 1 1 d U
C11 C 0.04457(19) 0.6405(5) 0.8719(6) 0.0160(7) Uani 1 1 d U
H11 H 0.0501 0.6646 0.8302 0.019 Uiso 1 1 calc R
C12 C 0.08246(19) 0.5530(6) 0.8489(6) 0.0168(7) Uani 1 1 d U
C13 C 0.0722(2) 0.4116(7) 1.2598(7) 0.0312(8) Uani 1 1 d U
C14 C 0.0360(2) 0.3388(6) 1.1961(7) 0.0266(8) Uani 1 1 d U
H14 H 0.0429 0.3536 1.1518 0.032 Uiso 1 1 calc R
C15 C 0.0478(2) 0.3641(7) 1.2594(7) 0.0282(8) Uani 1 1 d U
C16 C 0.0382(2) 0.3416(6) 1.3244(7) 0.0270(8) Uani 1 1 d U
H16 H 0.0461 0.3575 1.3671 0.032 Uiso 1 1 calc R
C17 C 0.0162(2) 0.2944(6) 1.3266(7) 0.0256(8) Uani 1 1 d U
H17 H 0.0093 0.2783 1.3705 0.031 Uiso 1 1 calc R
C18 C 0.0050(2) 0.2721(6) 1.2614(6) 0.0243(7) Uani 1 1 d U
C19 C -0.0189(2) 0.2234(6) 1.2576(6) 0.0227(8) Uani 1 1 d U
C20 C -0.0315(2) 0.1950(6) 1.3169(6) 0.0225(8) Uani 1 1 d U
H20 H -0.0246 0.2035 1.3631 0.027 Uiso 1 1 calc R
C21 C -0.0547(2) 0.1530(6) 1.3078(6) 0.0222(9) Uani 1 1 d U
H21 H -0.0636 0.1333 1.3475 0.027 Uiso 1 1 calc R
C22 C -0.0640(2) 0.1416(6) 1.2394(6) 0.0218(9) Uani 1 1 d U
C23 C -0.0494(2) 0.1699(6) 1.1812(6) 0.0216(9) Uani 1 1 d U
H23 H -0.0554 0.1602 1.1345 0.026 Uiso 1 1 calc R
C24 C 0.0889(2) 0.5967(7) 1.2738(7) 0.0351(14) Uani 1 1 d U
C25 C 0.0777(2) 0.6937(6) 0.5994(6) 0.0203(8) Uani 1 1 d U
C26 C 0.0421(2) 0.7111(6) 0.5001(6) 0.0177(8) Uani 1 1 d U
H26 H 0.0525 0.7497 0.4835 0.021 Uiso 1 1 calc R
C27 C 0.0512(2) 0.6725(6) 0.5610(6) 0.0187(7) Uani 1 1 d U
C28 C 0.03539(19) 0.6155(6) 0.5843(6) 0.0182(8) Uani 1 1 d U
H28 H 0.0407 0.5889 0.6247 0.022 Uiso 1 1 calc R
C29 C 0.0116(2) 0.5974(6) 0.5478(6) 0.0175(8) Uani 1 1 d U
H29 H 0.0007 0.5598 0.5641 0.021 Uiso 1 1 calc R
C30 C 0.00457(19) 0.6368(5) 0.4866(6) 0.0166(7) Uani 1 1 d U
C31 C -0.01887(19) 0.6204(5) 0.4394(6) 0.0157(7) Uani 1 1 d U
C32 C -0.03730(19) 0.5676(5) 0.4542(6) 0.0157(8) Uani 1 1 d U
H32 H -0.0356 0.5401 0.4961 0.019 Uiso 1 1 calc R
C33 C -0.05864(19) 0.5548(6) 0.4065(6) 0.0156(8) Uani 1 1 d U
H33 H -0.0715 0.5196 0.4165 0.019 Uiso 1 1 calc R
C34 C -0.06022(19) 0.5961(6) 0.3433(6) 0.0152(8) Uani 1 1 d U
C35 C -0.04105(19) 0.6501(5) 0.3331(6) 0.0149(8) Uani 1 1 d U
H35 H -0.0420 0.6782 0.2914 0.018 Uiso 1 1 calc R
C36 C 0.0821(2) 0.4184(6) 0.7117(6) 0.0207(11) Uani 1 1 d U
C37 C 0.1636(2) 0.4876(6) 1.1875(6) 0.0259(8) Uani 1 1 d U
C38 C 0.2038(2) 0.5380(6) 1.1216(6) 0.0238(8) Uani 1 1 d U
H38 H 0.1985 0.5833 1.1379 0.029 Uiso 1 1 calc R
C39 C 0.1886(2) 0.4793(6) 1.1418(7) 0.0246(7) Uani 1 1 d U
C40 C 0.1969(2) 0.4110(6) 1.1198(6) 0.0242(8) Uani 1 1 d U
H40 H 0.1870 0.3701 1.1323 0.029 Uiso 1 1 calc R
C41 C 0.2207(2) 0.4057(6) 1.0781(6) 0.0237(8) Uani 1 1 d U
H41 H 0.2268 0.3607 1.0627 0.028 Uiso 1 1 calc R
C42 C 0.2348(2) 0.4666(6) 1.0601(6) 0.0230(7) Uani 1 1 d U
C43 C 0.2596(2) 0.4672(6) 1.0152(6) 0.0225(7) Uani 1 1 d U
C44 C 0.2739(2) 0.4064(6) 0.9968(6) 0.0226(8) Uani 1 1 d U
H44 H 0.2679 0.3613 1.0121 0.027 Uiso 1 1 calc R
C45 C 0.2974(2) 0.4121(6) 0.9555(6) 0.0227(8) Uani 1 1 d U
H45 H 0.3079 0.3717 0.9453 0.027 Uiso 1 1 calc R
C46 C 0.3045(2) 0.4782(6) 0.9303(6) 0.0227(7) Uani 1 1 d U
C47 C 0.2896(2) 0.5388(6) 0.9505(6) 0.0222(8) Uani 1 1 d U
H47 H 0.2953 0.5838 0.9342 0.027 Uiso 1 1 calc R
C48 C 0.3294(2) 0.4915(6) 0.8833(6) 0.0234(8) Uani 1 1 d U
C49 C 0.1579(2) 0.5433(6) 0.8614(6) 0.0174(7) Uani 1 1 d U
C50 C 0.19928(19) 0.5809(6) 0.9363(6) 0.0160(7) Uani 1 1 d U
H50 H 0.1974 0.5387 0.9633 0.019 Uiso 1 1 calc R
C51 C 0.17981(19) 0.5965(6) 0.8814(6) 0.0166(7) Uani 1 1 d U
C52 C 0.18247(19) 0.6611(5) 0.8449(6) 0.0165(7) Uani 1 1 d U
H52 H 0.1697 0.6744 0.8105 0.020 Uiso 1 1 calc R
C53 C 0.20422(19) 0.7060(6) 0.8597(6) 0.0164(7) Uani 1 1 d U
H53 H 0.2059 0.7501 0.8360 0.020 Uiso 1 1 calc R
C54 C 0.22368(19) 0.6845(5) 0.9103(6) 0.0163(7) Uani 1 1 d U
C55 C 0.2489(2) 0.7233(6) 0.9229(6) 0.0171(7) Uani 1 1 d U
C56 C 0.2567(2) 0.7836(6) 0.8807(6) 0.0179(7) Uani 1 1 d U
H56 H 0.2448 0.8043 0.8478 0.021 Uiso 1 1 calc R
C57 C 0.28238(19) 0.8107(6) 0.8896(6) 0.0187(8) Uani 1 1 d U
H57 H 0.2882 0.8490 0.8610 0.022 Uiso 1 1 calc R
C58 C 0.2999(2) 0.7806(6) 0.9420(6) 0.0193(7) Uani 1 1 d U
C59 C 0.2901(2) 0.7236(6) 0.9835(6) 0.0182(8) Uani 1 1 d U
H59 H 0.3013 0.7040 1.0190 0.022 Uiso 1 1 calc R
C60 C 0.3284(2) 0.8079(6) 0.9496(6) 0.0213(8) Uani 1 1 d U
C61 C 0.1609(2) 0.4315(6) 0.7029(7) 0.0267(8) Uani 1 1 d U
C62 C 0.2043(2) 0.4069(6) 0.6330(6) 0.0248(8) Uani 1 1 d U
H62 H 0.2015 0.4502 0.6086 0.030 Uiso 1 1 calc R
C63 C 0.1852(2) 0.3850(6) 0.6834(7) 0.0258(8) Uani 1 1 d U
C64 C 0.1885(2) 0.3198(6) 0.7173(6) 0.0257(8) Uani 1 1 d U
H64 H 0.1753 0.3029 0.7489 0.031 Uiso 1 1 calc R
C65 C 0.2116(2) 0.2790(6) 0.7043(6) 0.0251(8) Uani 1 1 d U
H65 H 0.2144 0.2352 0.7277 0.030 Uiso 1 1 calc R
C66 C 0.2305(2) 0.3059(6) 0.6549(6) 0.0241(7) Uani 1 1 d U
C67 C 0.2569(2) 0.2710(6) 0.6408(6) 0.0232(8) Uani 1 1 d U
C68 C 0.2662(2) 0.2092(6) 0.6782(6) 0.0233(8) Uani 1 1 d U
H68 H 0.2552 0.1870 0.7124 0.028 Uiso 1 1 calc R
C69 C 0.2913(2) 0.1824(6) 0.6637(6) 0.0232(9) Uani 1 1 d U
H69 H 0.2976 0.1420 0.6883 0.028 Uiso 1 1 calc R
C70 C 0.3072(2) 0.2154(6) 0.6126(6) 0.0229(9) Uani 1 1 d U
C71 C 0.2974(2) 0.2765(6) 0.5767(6) 0.0226(9) Uani 1 1 d U
H71 H 0.3085 0.2994 0.5430 0.027 Uiso 1 1 calc R
C72 C 0.1647(3) 0.6877(7) 0.5909(8) 0.0377(15) Uani 1 1 d U
Cl2 Cl 0.26304(8) 0.5046(2) 0.2810(2) 0.0613(9) Uani 1 1 d DU
O31 O 0.2517(3) 0.5768(9) 0.2653(9) 0.0615(10) Uani 0.69 1 d PDU
O32 O 0.2516(3) 0.4747(9) 0.3366(9) 0.0614(11) Uani 0.69 1 d PDU
O33 O 0.2629(2) 0.4665(6) 0.2151(6) 0.0619(10) Uani 1 1 d DU
O34 O 0.2916(3) 0.5229(9) 0.2985(9) 0.0613(10) Uani 0.69 1 d PDU
O31' O 0.2402(7) 0.5132(19) 0.237(2) 0.0616(10) Uani 0.31 1 d PDU
O32' O 0.2494(7) 0.419(2) 0.305(2) 0.0614(12) Uani 0.31 1 d PDU
O34' O 0.2875(7) 0.471(2) 0.257(2) 0.0615(10) Uani 0.31 1 d PDU
Cl1 Cl 0.00796(5) 0.00218(15) 0.27699(15) 0.0235(5) Uani 1 1 d U
O35 O -0.00740(15) 0.0494(4) 0.2304(5) 0.0297(11) Uani 1 1 d U
O36 O 0.03321(14) 0.0371(4) 0.2957(4) 0.0263(10) Uani 1 1 d U
O37 O 0.01349(14) -0.0638(4) 0.2410(4) 0.0245(10) Uani 1 1 d U
O38 O -0.00706(14) -0.0119(4) 0.3416(4) 0.0270(11) Uani 1 1 d U
O28 O 0.1005(4) 0.2582(13) 0.1900(12) 0.196(9) Uani 1 1 d U
H28A H 0.0973 0.2913 0.2208 0.235 Uiso 1 1 d R
H28B H 0.0941 0.2191 0.2066 0.235 Uiso 1 1 d R
O39 O 0.1080(4) 0.5199(11) 0.0639(12) 0.168(8) Uani 1 1 d U
H39A H 0.0917 0.5335 0.0579 0.201 Uiso 1 1 d R
H39B H 0.1087 0.4969 0.1038 0.201 Uiso 1 1 d R
O40 O 0.1341(2) 0.6880(6) 0.1639(6) 0.060(3) Uani 1 1 d U
H40A H 0.1175 0.7006 0.1654 0.072 Uiso 1 1 d R
H40B H 0.1426 0.7197 0.1397 0.072 Uiso 1 1 d R
O41 O 0.09692(19) 0.7606(6) 0.3810(6) 0.057(3) Uani 1 1 d U
H41A H 0.1064 0.7804 0.3481 0.068 Uiso 1 1 d R
H41B H 0.0907 0.7940 0.4080 0.068 Uiso 1 1 d R
O42 O 0.1529(2) 0.0859(7) 0.0258(7) 0.081(4) Uani 1 1 d U
H42A H 0.1429 0.0596 -0.0009 0.098 Uiso 1 1 d R
H42B H 0.1634 0.0610 0.0524 0.098 Uiso 1 1 d R
O43 O 0.2957(2) 0.1417(5) 0.2697(6) 0.059(3) Uani 1 1 d U
H43A H 0.2918 0.1447 0.3145 0.071 Uiso 1 1 d R
H43B H 0.3116 0.1241 0.2664 0.071 Uiso 1 1 d R
O44 O 0.11409(19) 0.6423(5) 0.4685(6) 0.054(3) Uani 1 1 d U
H44A H 0.1149 0.6793 0.4415 0.065 Uiso 1 1 d R
H44B H 0.1306 0.6262 0.4761 0.065 Uiso 1 1 d R
O45 O 0.1340(4) 0.1999(12) 0.0831(12) 0.178(8) Uani 1 1 d U
H45A H 0.1279 0.2423 0.0527 0.213 Uiso 1 1 d R
H45B H 0.1305 0.1514 0.0556 0.213 Uiso 1 1 d R
O46 O 0.1210(3) 0.8347(10) 0.4915(11) 0.155(7) Uani 1 1 d U
H46A H 0.1295 0.8593 0.4599 0.186 Uiso 1 1 d R
H46B H 0.1268 0.8475 0.5329 0.186 Uiso 1 1 d R
O47 O 0.03635(16) 0.5194(4) 0.3941(5) 0.034(2) Uani 1 1 d U
H47A H 0.0515 0.5337 0.4103 0.041 Uiso 1 1 d R
H47B H 0.0245 0.5538 0.3984 0.041 Uiso 1 1 d R
O48 O 0.2122(2) 0.3626(7) 0.2987(7) 0.081(4) Uani 1 1 d U
H48A H 0.2005 0.3343 0.3220 0.098 Uiso 1 1 d R
H48B H 0.2016 0.3929 0.2766 0.098 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O23 Eu1 O18 99.4(3) . .
O23 Eu1 O12 144.9(3) . .
O18 Eu1 O12 96.3(2) . .
O23 Eu1 O10 90.6(3) . .
O18 Eu1 O10 147.4(2) . .
O12 Eu1 O10 92.8(2) . .
O23 Eu1 O4 143.4(3) . .
O18 Eu1 O4 74.7(2) . .
O12 Eu1 O4 71.2(2) . .
O10 Eu1 O4 78.7(2) . .
O23 Eu1 O26 73.0(3) . .
O18 Eu1 O26 75.6(3) . .
O12 Eu1 O26 141.6(3) . .
O10 Eu1 O26 77.9(3) . .
O4 Eu1 O26 70.5(3) . .
O23 Eu1 O25 76.7(3) . .
O18 Eu1 O25 142.2(3) . .
O12 Eu1 O25 71.8(3) . .
O10 Eu1 O25 70.3(3) . .
O4 Eu1 O25 129.7(3) . .
O26 Eu1 O25 135.3(3) . .
O23 Eu1 O22 75.8(3) . .
O18 Eu1 O22 72.5(3) . .
O12 Eu1 O22 79.3(2) . .
O10 Eu1 O22 140.1(3) . .
O4 Eu1 O22 132.6(2) . .
O26 Eu1 O22 130.4(3) . .
O25 Eu1 O22 70.1(3) . .
O23 Eu1 Eu2 135.5(2) . 5_567
O18 Eu1 Eu2 46.19(17) . 5_567
O12 Eu1 Eu2 50.11(18) . 5_567
O10 Eu1 Eu2 133.77(17) . 5_567
O4 Eu1 Eu2 64.78(16) . 5_567
O26 Eu1 Eu2 112.6(2) . 5_567
O25 Eu1 Eu2 112.1(2) . 5_567
O22 Eu1 Eu2 67.80(18) . 5_567
O23 Eu1 H1C 75.1 . .
O18 Eu1 H1C 161.1 . .
O12 Eu1 H1C 80.0 . .
O10 Eu1 H1C 51.6 . .
O4 Eu1 H1C 120.5 . .
O26 Eu1 H1C 118.6 . .
O25 Eu1 H1C 19.3 . .
O22 Eu1 H1C 88.6 . .
Eu2 Eu1 H1C 126.9 5_567 .
O23 Eu1 H1D 59.4 . .
O18 Eu1 H1D 130.8 . .
O12 Eu1 H1D 86.8 . .
O10 Eu1 H1D 80.9 . .
O4 Eu1 H1D 149.0 . .
O26 Eu1 H1D 127.1 . .
O25 Eu1 H1D 19.4 . .
O22 Eu1 H1D 59.8 . .
Eu2 Eu1 H1D 117.0 5_567 .
H1C Eu1 H1D 31.1 . .
O23 Eu1 H1A 78.8 . .
O18 Eu1 H1A 92.0 . .
O12 Eu1 H1A 131.9 . .
O10 Eu1 H1A 59.4 . .
O4 Eu1 H1A 65.6 . .
O26 Eu1 H1A 18.8 . .
O25 Eu1 H1A 123.0 . .
O22 Eu1 H1A 147.4 . .
Eu2 Eu1 H1A 121.4 5_567 .
H1C Eu1 H1A 104.3 . .
H1D Eu1 H1A 121.6 . .
O23 Eu1 H1B 54.4 . .
O18 Eu1 H1B 80.0 . .
O12 Eu1 H1B 160.3 . .
O10 Eu1 H1B 80.9 . .
O4 Eu1 H1B 89.2 . .
O26 Eu1 H1B 18.7 . .
O25 Eu1 H1B 122.4 . .
O22 Eu1 H1B 117.2 . .
Eu2 Eu1 H1B 123.6 5_567 .
H1C Eu1 H1B 109.5 . .
H1D Eu1 H1B 110.4 . .
H1A Eu1 H1B 30.3 . .
O21 Eu2 O3 112.3(3) 5_567 5_567
O21 Eu2 O1 118.6(3) 5_567 .
O3 Eu2 O1 110.3(2) 5_567 .
O21 Eu2 O20 82.4(3) 5_567 3_467
O3 Eu2 O20 150.8(3) 5_567 3_467
O1 Eu2 O20 81.1(2) . 3_467
O21 Eu2 O27 153.6(3) 5_567 .
O3 Eu2 O27 80.5(3) 5_567 .
O1 Eu2 O27 74.3(3) . .
O20 Eu2 O27 76.9(3) 3_467 .
O21 Eu2 O17 83.9(3) 5_567 5_567
O3 Eu2 O17 81.1(2) 5_567 5_567
O1 Eu2 O17 144.9(2) . 5_567
O20 Eu2 O17 75.4(2) 3_467 5_567
O27 Eu2 O17 75.2(3) . 5_567
O21 Eu2 O11 78.6(3) 5_567 5_567
O3 Eu2 O11 76.7(2) 5_567 5_567
O1 Eu2 O11 70.7(2) . 5_567
O20 Eu2 O11 132.2(2) 3_467 5_567
O27 Eu2 O11 127.7(2) . 5_567
O17 Eu2 O11 143.7(2) 5_567 5_567
O21 Eu2 Eu1 53.4(2) 5_567 5_567
O3 Eu2 Eu1 59.10(18) 5_567 5_567
O1 Eu2 Eu1 141.86(17) . 5_567
O20 Eu2 Eu1 127.22(18) 3_467 5_567
O27 Eu2 Eu1 131.34(19) . 5_567
O17 Eu2 Eu1 72.85(17) 5_567 5_567
O11 Eu2 Eu1 71.14(17) 5_567 5_567
O13 Eu3 O6 119.2(3) . .
O13 Eu3 O16 79.0(3) . 2_565
O6 Eu3 O16 138.8(3) . 2_565
O13 Eu3 O29 73.3(3) . .
O6 Eu3 O29 77.3(3) . .
O16 Eu3 O29 73.3(3) 2_565 .
O13 Eu3 O30 140.8(3) . .
O6 Eu3 O30 67.5(3) . .
O16 Eu3 O30 75.8(3) 2_565 .
O29 Eu3 O30 71.1(3) . .
O13 Eu3 O7 138.9(3) . .
O6 Eu3 O7 68.4(3) . .
O16 Eu3 O7 123.8(3) 2_565 .
O29 Eu3 O7 141.8(3) . .
O30 Eu3 O7 80.2(3) . .
O13 Eu3 O15 114.5(2) . 2_565
O6 Eu3 O15 126.3(3) . 2_565
O16 Eu3 O15 53.0(2) 2_565 2_565
O29 Eu3 O15 120.1(3) . 2_565
O30 Eu3 O15 71.8(3) . 2_565
O7 Eu3 O15 71.4(3) . 2_565
O13 Eu3 O8 88.7(3) . .
O6 Eu3 O8 77.3(3) . .
O16 Eu3 O8 143.2(3) 2_565 .
O29 Eu3 O8 136.0(3) . .
O30 Eu3 O8 128.7(3) . .
O7 Eu3 O8 51.9(3) . .
O15 Eu3 O8 103.9(3) 2_565 .
O13 Eu3 O14 52.2(3) . .
O6 Eu3 O14 147.8(3) . .
O16 Eu3 O14 73.3(2) 2_565 .
O29 Eu3 O14 119.9(3) . .
O30 Eu3 O14 141.4(3) . .
O7 Eu3 O14 98.3(3) . .
O15 Eu3 O14 71.3(2) 2_565 .
O8 Eu3 O14 71.8(3) . .
O13 Eu3 O5 71.4(2) . .
O6 Eu3 O5 48.6(3) . .
O16 Eu3 O5 137.3(2) 2_565 .
O29 Eu3 O5 69.2(3) . .
O30 Eu3 O5 109.5(3) . .
O7 Eu3 O5 98.5(3) . .
O15 Eu3 O5 169.6(2) 2_565 .
O8 Eu3 O5 66.9(3) . .
O14 Eu3 O5 108.8(2) . .
O13 Eu3 C48 97.2(3) . 2_565
O6 Eu3 C48 138.7(3) . 2_565
O16 Eu3 C48 26.5(3) 2_565 2_565
O29 Eu3 C48 96.9(3) . 2_565
O30 Eu3 C48 71.8(3) . 2_565
O7 Eu3 C48 97.7(3) . 2_565
O15 Eu3 C48 26.5(3) 2_565 2_565
O8 Eu3 C48 125.6(3) . 2_565
O14 Eu3 C48 70.1(3) . 2_565
O5 Eu3 C48 163.8(3) . 2_565
O13 Eu3 C37 26.3(3) . .
O6 Eu3 C37 140.3(3) . .
O16 Eu3 C37 71.5(3) 2_565 .
O29 Eu3 C37 95.3(3) . .
O30 Eu3 C37 147.1(3) . .
O7 Eu3 C37 121.9(3) . .
O15 Eu3 C37 91.3(3) 2_565 .
O8 Eu3 C37 82.1(3) . .
O14 Eu3 C37 26.3(3) . .
O5 Eu3 C37 92.2(3) . .
C48 Eu3 C37 80.6(3) 2_565 .
O13 Eu3 H30B 128.7 . .
O6 Eu3 H30B 63.2 . .
O16 Eu3 H30B 76.6 2_565 .
O29 Eu3 H30B 56.8 . .
O30 Eu3 H30B 14.8 . .
O7 Eu3 H30B 91.7 . .
O15 Eu3 H30B 84.3 2_565 .
O8 Eu3 H30B 134.8 . .
O14 Eu3 H30B 148.8 . .
O5 Eu3 H30B 98.7 . .
C48 Eu3 H30B 79.3 2_565 .
C37 Eu3 H30B 142.8 . .
N8 Co4 N7 80.9(4) . .
N8 Co4 N12 173.2(4) . 2_565
N7 Co4 N12 96.8(4) . 2_565
N8 Co4 N11 93.5(4) . 2_565
N7 Co4 N11 97.0(4) . 2_565
N12 Co4 N11 80.3(4) 2_565 2_565
N8 Co4 N9 95.0(4) . .
N7 Co4 N9 92.4(4) . .
N12 Co4 N9 91.6(3) 2_565 .
N11 Co4 N9 168.2(4) 2_565 .
N8 Co4 N10 95.6(4) . .
N7 Co4 N10 171.5(4) . .
N12 Co4 N10 87.5(4) 2_565 .
N11 Co4 N10 91.0(4) 2_565 .
N9 Co4 N10 80.1(3) . .
N3 Co5 N2 92.0(4) 5_567 .
N3 Co5 N5 174.6(4) 5_567 8_576
N2 Co5 N5 92.2(4) . 8_576
N3 Co5 N6 92.8(4) 5_567 8_576
N2 Co5 N6 169.7(4) . 8_576
N5 Co5 N6 83.6(3) 8_576 8_576
N3 Co5 N4 81.6(4) 5_567 5_567
N2 Co5 N4 96.9(4) . 5_567
N5 Co5 N4 94.7(4) 8_576 5_567
N6 Co5 N4 92.9(4) 8_576 5_567
N3 Co5 N1 97.6(4) 5_567 .
N2 Co5 N1 81.5(3) . .
N5 Co5 N1 86.2(3) 8_576 .
N6 Co5 N1 88.8(3) 8_576 .
N4 Co5 N1 178.2(4) 5_567 .
C1 O1 Eu2 148.1(7) . .
C12 O3 Eu2 151.8(7) . 5_567
C12 O4 Eu1 135.9(6) . .
C13 O5 Eu3 85.2(7) . .
C13 O6 Eu3 101.5(7) . .
C24 O7 Eu3 92.3(8) . .
C24 O8 Eu3 90.5(8) . .
C25 O10 Eu1 153.7(7) . .
C36 O11 Eu2 120.5(6) . 5_567
C36 O12 Eu1 171.8(8) . .
C37 O13 Eu3 96.0(7) . .
C37 O14 Eu3 89.1(6) . .
C48 O15 Eu3 89.8(7) . 2_564
C48 O16 Eu3 94.0(6) . 2_564
C49 O17 Eu2 117.0(6) . 5_567
C49 O18 Eu1 177.6(7) . .
C60 O20 Eu2 142.1(7) . 3_567
C61 O21 Eu2 161.3(8) . 5_567
C61 O22 Eu1 124.9(7) . .
C72 O23 Eu1 161.6(9) . .
Eu1 O25 H1C 84.8 . .
Eu1 O25 H1D 84.5 . .
H1C O25 H1D 107.4 . .
Eu1 O26 H1A 94.2 . .
Eu1 O26 H1B 94.0 . .
H1A O26 H1B 108.0 . .
Eu2 O27 H27A 112.9 . .
Eu2 O27 H27B 113.8 . .
H27A O27 H27B 107.7 . .
Eu3 O29 H29A 125.6 . .
Eu3 O29 H29B 123.7 . .
H29A O29 H29B 108.9 . .
Eu3 O30 H30A 122.9 . .
Eu3 O30 H30B 33.1 . .
H30A O30 H30B 107.7 . .
C2 N1 C6 118.3(9) . .
C2 N1 Co5 128.5(7) . .
C6 N1 Co5 112.6(6) . .
C11 N2 C7 120.3(9) . .
C11 N2 Co5 125.6(7) . .
C7 N2 Co5 114.1(6) . .
C18 N3 C14 117.7(10) . .
C18 N3 Co5 116.2(7) . 5_567
C14 N3 Co5 125.9(8) . 5_567
C23 N4 C19 117.8(10) . .
C23 N4 Co5 128.4(8) . 5_567
C19 N4 Co5 113.7(7) . 5_567
C26 N5 C30 120.0(9) . .
C26 N5 Co5 127.5(7) . 8_575
C30 N5 Co5 112.4(7) . 8_575
C35 N6 C31 119.2(9) . .
C35 N6 Co5 127.8(7) . 8_575
C31 N6 Co5 112.3(7) . 8_575
C38 N7 C42 117.7(10) . .
C38 N7 Co4 127.1(8) . .
C42 N7 Co4 115.0(7) . .
C47 N8 C43 117.2(9) . .
C47 N8 Co4 127.2(8) . .
C43 N8 Co4 115.3(7) . .
C50 N9 C54 120.6(9) . .
C50 N9 Co4 126.8(7) . .
C54 N9 Co4 112.4(6) . .
C59 N10 C55 119.8(9) . .
C59 N10 Co4 128.1(7) . .
C55 N10 Co4 112.0(7) . .
C62 N11 C66 117.2(10) . .
C62 N11 Co4 128.2(8) . 2_564
C66 N11 Co4 113.8(7) . 2_564
C71 N12 C67 118.8(10) . .
C71 N12 Co4 127.4(8) . 2_564
C67 N12 Co4 113.6(7) . 2_564
O2 C1 O1 126.8(10) . .
O2 C1 C3 116.3(9) . .
O1 C1 C3 116.9(9) . .
N1 C2 C3 122.5(10) . .
N1 C2 H2 118.8 . .
C3 C2 H2 118.8 . .
C4 C3 C2 119.0(10) . .
C4 C3 C1 122.4(10) . .
C2 C3 C1 118.6(9) . .
C3 C4 C5 119.1(10) . .
C3 C4 H4 120.5 . .
C5 C4 H4 120.5 . .
C6 C5 C4 119.3(10) . .
C6 C5 H5 120.4 . .
C4 C5 H5 120.4 . .
N1 C6 C5 121.8(9) . .
N1 C6 C7 114.1(9) . .
C5 C6 C7 124.1(9) . .
N2 C7 C8 119.7(9) . .
N2 C7 C6 116.0(9) . .
C8 C7 C6 124.2(10) . .
C9 C8 C7 120.0(10) . .
C9 C8 H8 120.0 . .
C7 C8 H8 120.0 . .
C8 C9 C10 119.4(10) . .
C8 C9 H9 120.3 . .
C10 C9 H9 120.3 . .
C9 C10 C11 119.1(10) . .
C9 C10 C12 122.2(9) . .
C11 C10 C12 118.7(9) . .
N2 C11 C10 121.1(10) . .
N2 C11 H11 119.5 . .
C10 C11 H11 119.5 . .
O4 C12 O3 128.3(10) . .
O4 C12 C10 116.9(9) . .
O3 C12 C10 114.7(9) . .
O5 C13 O6 122.9(11) . .
O5 C13 C15 119.5(12) . .
O6 C13 C15 117.5(11) . .
O5 C13 Eu3 70.4(7) . .
O6 C13 Eu3 53.9(6) . .
C15 C13 Eu3 162.7(9) . .
N3 C14 C15 121.7(11) . .
N3 C14 H14 119.1 . .
C15 C14 H14 119.1 . .
C16 C15 C14 119.6(11) . .
C16 C15 C13 117.4(11) . .
C14 C15 C13 122.9(11) . .
C15 C16 C17 119.4(12) . .
C15 C16 H16 120.3 . .
C17 C16 H16 120.3 . .
C18 C17 C16 118.2(11) . .
C18 C17 H17 120.9 . .
C16 C17 H17 120.9 . .
N3 C18 C17 123.4(10) . .
N3 C18 C19 114.0(10) . .
C17 C18 C19 122.6(11) . .
N4 C19 C20 122.6(10) . .
N4 C19 C18 113.6(10) . .
C20 C19 C18 123.7(11) . .
C19 C20 C21 119.4(11) . .
C19 C20 H20 120.3 . .
C21 C20 H20 120.3 . .
C22 C21 C20 118.6(11) . .
C22 C21 H21 120.7 . .
C20 C21 H21 120.7 . .
C21 C22 C23 118.7(10) . .
C21 C22 C24 120.9(11) . 4_547
C23 C22 C24 120.4(11) . 4_547
N4 C23 C22 123.0(11) . .
N4 C23 H23 118.5 . .
C22 C23 H23 118.5 . .
O7 C24 O8 123.4(12) . .
O7 C24 C22 119.6(12) . 4_557
O8 C24 C22 116.7(11) . 4_557
O9 C25 O10 128.7(10) . .
O9 C25 C27 117.2(10) . .
O10 C25 C27 114.1(9) . .
N5 C26 C27 122.6(10) . .
N5 C26 H26 118.7 . .
C27 C26 H26 118.7 . .
C28 C27 C26 117.3(10) . .
C28 C27 C25 122.1(10) . .
C26 C27 C25 120.6(9) . .
C27 C28 C29 120.5(10) . .
C27 C28 H28 119.7 . .
C29 C28 H28 119.7 . .
C30 C29 C28 118.5(10) . .
C30 C29 H29 120.7 . .
C28 C29 H29 120.7 . .
N5 C30 C29 120.9(9) . .
N5 C30 C31 114.6(9) . .
C29 C30 C31 124.5(9) . .
N6 C31 C32 121.6(9) . .
N6 C31 C30 115.0(9) . .
C32 C31 C30 123.4(10) . .
C31 C32 C33 120.0(10) . .
C31 C32 H32 120.0 . .
C33 C32 H32 120.0 . .
C32 C33 C34 118.4(9) . .
C32 C33 H33 120.8 . .
C34 C33 H33 120.8 . .
C35 C34 C33 118.0(9) . .
C35 C34 C36 121.6(10) . 5_566
C33 C34 C36 120.4(9) . 5_566
N6 C35 C34 122.5(10) . .
N6 C35 H35 118.8 . .
C34 C35 H35 118.8 . .
O11 C36 O12 125.2(10) . .
O11 C36 C34 120.0(9) . 5_566
O12 C36 C34 114.8(10) . 5_566
O14 C37 O13 121.2(10) . .
O14 C37 C39 120.2(10) . .
O13 C37 C39 118.5(10) . .
O14 C37 Eu3 64.6(6) . .
O13 C37 Eu3 57.8(6) . .
C39 C37 Eu3 164.6(8) . .
N7 C38 C39 123.8(11) . .
N7 C38 H38 118.1 . .
C39 C38 H38 118.1 . .
C38 C39 C40 118.6(10) . .
C38 C39 C37 121.4(10) . .
C40 C39 C37 120.0(10) . .
C39 C40 C41 118.1(11) . .
C39 C40 H40 121.0 . .
C41 C40 H40 121.0 . .
C42 C41 C40 120.0(11) . .
C42 C41 H41 120.0 . .
C40 C41 H41 120.0 . .
N7 C42 C41 121.7(10) . .
N7 C42 C43 114.0(10) . .
C41 C42 C43 124.3(10) . .
C44 C43 N8 121.7(10) . .
C44 C43 C42 124.0(10) . .
N8 C43 C42 114.3(9) . .
C43 C44 C45 120.2(11) . .
C43 C44 H44 119.9 . .
C45 C44 H44 119.9 . .
C46 C45 C44 118.2(10) . .
C46 C45 H45 120.9 . .
C44 C45 H45 120.9 . .
C45 C46 C47 120.0(10) . .
C45 C46 C48 123.3(10) . .
C47 C46 C48 116.5(10) . .
N8 C47 C46 122.5(10) . .
N8 C47 H47 118.7 . .
C46 C47 H47 118.7 . .
O15 C48 O16 123.2(10) . .
O15 C48 C46 117.9(10) . .
O16 C48 C46 118.9(10) . .
O15 C48 Eu3 63.6(6) . 2_564
O16 C48 Eu3 59.5(5) . 2_564
C46 C48 Eu3 177.8(8) . 2_564
O17 C49 O18 126.2(10) . .
O17 C49 C51 119.1(9) . .
O18 C49 C51 114.6(9) . .
N9 C50 C51 122.0(10) . .
N9 C50 H50 119.0 . .
C51 C50 H50 119.0 . .
C52 C51 C50 117.3(9) . .
C52 C51 C49 121.0(9) . .
C50 C51 C49 121.6(9) . .
C51 C52 C53 120.0(10) . .
C51 C52 H52 120.0 . .
C53 C52 H52 120.0 . .
C52 C53 C54 119.5(10) . .
C52 C53 H53 120.3 . .
C54 C53 H53 120.3 . .
N9 C54 C53 120.1(9) . .
N9 C54 C55 116.2(9) . .
C53 C54 C55 123.6(10) . .
N10 C55 C56 121.2(9) . .
N10 C55 C54 116.4(9) . .
C56 C55 C54 122.4(9) . .
C57 C56 C55 118.4(10) . .
C57 C56 H56 120.8 . .
C55 C56 H56 120.8 . .
C56 C57 C58 120.0(10) . .
C56 C57 H57 120.0 . .
C58 C57 H57 120.0 . .
C59 C58 C57 117.8(10) . .
C59 C58 C60 121.9(10) . .
C57 C58 C60 120.3(10) . .
N10 C59 C58 122.6(10) . .
N10 C59 H59 118.7 . .
C58 C59 H59 118.7 . .
O20 C60 O19 124.6(10) . .
O20 C60 C58 117.6(10) . .
O19 C60 C58 117.8(10) . .
O22 C61 O21 126.6(11) . .
O22 C61 C63 118.7(10) . .
O21 C61 C63 114.7(10) . .
N11 C62 C63 123.1(11) . .
N11 C62 H62 118.5 . .
C63 C62 H62 118.5 . .
C64 C63 C62 119.0(11) . .
C64 C63 C61 119.0(10) . .
C62 C63 C61 122.0(11) . .
C63 C64 C65 119.9(11) . .
C63 C64 H64 120.0 . .
C65 C64 H64 120.0 . .
C64 C65 C66 117.9(11) . .
C64 C65 H65 121.1 . .
C66 C65 H65 121.1 . .
N11 C66 C65 122.7(10) . .
N11 C66 C67 114.0(10) . .
C65 C66 C67 123.2(10) . .
N12 C67 C68 120.6(10) . .
N12 C67 C66 115.6(10) . .
C68 C67 C66 123.7(10) . .
C69 C68 C67 119.7(11) . .
C69 C68 H68 120.2 . .
C67 C68 H68 120.2 . .
C68 C69 C70 119.5(11) . .
C68 C69 H69 120.3 . .
C70 C69 H69 120.3 . .
C69 C70 C71 119.4(10) . .
C69 C70 C72 123.2(11) . 7_655
C71 C70 C72 117.3(10) . 7_655
N12 C71 C70 121.9(10) . .
N12 C71 H71 119.0 . .
C70 C71 H71 119.0 . .
O24 C72 O23 127.7(12) . .
O24 C72 C70 116.9(12) . 7_665
O23 C72 C70 115.4(12) . 7_665
O32 Cl2 O31' 99.2(16) . .
O32 Cl2 O33 118.0(9) . .
O31' Cl2 O33 63.2(15) . .
O32 Cl2 O34' 115.3(17) . .
O31' Cl2 O34' 124(2) . .
O33 Cl2 O34' 61.5(15) . .
O32 Cl2 O31 112.2(10) . .
O31' Cl2 O31 58.7(15) . .
O33 Cl2 O31 106.4(8) . .
O34' Cl2 O31 130.6(16) . .
O32 Cl2 O34 109.7(10) . .
O31' Cl2 O34 149.8(16) . .
O33 Cl2 O34 107.9(8) . .
O34' Cl2 O34 50.2(15) . .
O31 Cl2 O34 101.2(9) . .
O32 Cl2 O32' 42.1(13) . .
O31' Cl2 O32' 86.7(18) . .
O33 Cl2 O32' 76.4(13) . .
O34' Cl2 O32' 90.6(18) . .
O31 Cl2 O32' 135.6(13) . .
O34 Cl2 O32' 120.5(13) . .
O31' O31 Cl2 58.0(15) . .
O32' O32 Cl2 91(2) . .
Cl2 O33 O34' 59.8(15) . .
Cl2 O33 O31' 58.2(15) . .
O34' O33 O31' 117(2) . .
O34' O34 Cl2 62.4(17) . .
Cl2 O31' O31 63.4(16) . .
Cl2 O31' O33 58.6(14) . .
O31 O31' O33 107(2) . .
O32 O32' Cl2 46.6(15) . .
O34 O34' Cl2 67.4(19) . .
O34 O34' O33 121(3) . .
Cl2 O34' O33 58.7(14) . .
O37 Cl1 O38 109.4(5) . .
O37 Cl1 O35 110.2(5) . .
O38 Cl1 O35 109.6(5) . .
O37 Cl1 O36 109.4(5) . .
O38 Cl1 O36 109.2(5) . .
O35 Cl1 O36 108.9(5) . .
H28A O28 H28B 107.7 . .
H39A O39 H39B 107.7 . .
H40A O40 H40B 107.7 . .
H41A O41 H41B 107.7 . .
H42A O42 H42B 112.2 . .
H43A O43 H43B 107.7 . .
H44A O44 H44B 109.1 . .
H45A O45 H45B 110.4 . .
H46A O46 H46B 107.7 . .
H47A O47 H47B 109.5 . .
H48A O48 H48B 102.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O23 2.316(9) .
Eu1 O18 2.323(7) .
Eu1 O12 2.336(7) .
Eu1 O10 2.353(7) .
Eu1 O4 2.416(7) .
Eu1 O26 2.470(9) .
Eu1 O25 2.506(10) .
Eu1 O22 2.514(8) .
Eu1 Eu2 4.4567(7) 5_567
Eu1 H1C 2.5737 .
Eu1 H1D 2.5697 .
Eu1 H1A 2.6767 .
Eu1 H1B 2.6711 .
Eu2 O21 2.237(8) 5_567
Eu2 O3 2.297(7) 5_567
Eu2 O1 2.360(7) .
Eu2 O20 2.364(7) 3_467
Eu2 O27 2.431(8) .
Eu2 O17 2.443(7) 5_567
Eu2 O11 2.533(7) 5_567
Eu2 Eu1 4.4567(7) 5_567
Eu3 O13 2.407(8) .
Eu3 O6 2.427(8) .
Eu3 O16 2.436(7) 2_565
Eu3 O29 2.471(10) .
Eu3 O30 2.474(9) .
Eu3 O7 2.510(8) .
Eu3 O15 2.526(8) 2_565
Eu3 O8 2.530(9) .
Eu3 O14 2.558(8) .
Eu3 O5 2.783(8) .
Eu3 C48 2.819(11) 2_565
Eu3 C37 2.830(11) .
Eu3 H30B 1.8217 .
Co4 N8 1.994(9) .
Co4 N7 2.018(9) .
Co4 N12 2.031(9) 2_565
Co4 N11 2.036(9) 2_565
Co4 N9 2.055(8) .
Co4 N10 2.068(9) .
Co5 N3 1.933(10) 5_567
Co5 N2 1.956(8) .
Co5 N5 1.960(9) 8_576
Co5 N6 1.961(8) 8_576
Co5 N4 1.994(9) 5_567
Co5 N1 2.032(9) .
O1 C1 1.255(12) .
O2 C1 1.247(12) .
O3 C12 1.270(12) .
O3 Eu2 2.297(7) 5_567
O4 C12 1.239(12) .
O5 C13 1.215(14) .
O6 C13 1.251(14) .
O7 C24 1.234(15) .
O8 C24 1.271(15) .
O9 C25 1.222(13) .
O10 C25 1.248(12) .
O11 C36 1.248(13) .
O11 Eu2 2.533(7) 5_567
O12 C36 1.258(12) .
O13 C37 1.259(13) .
O14 C37 1.255(13) .
O15 C48 1.259(13) .
O15 Eu3 2.526(7) 2_564
O16 C48 1.260(13) .
O16 Eu3 2.436(7) 2_564
O17 C49 1.242(12) .
O17 Eu2 2.443(7) 5_567
O18 C49 1.257(13) .
O19 C60 1.253(13) .
O20 C60 1.238(13) .
O20 Eu2 2.364(7) 3_567
O21 C61 1.274(14) .
O21 Eu2 2.237(8) 5_567
O22 C61 1.246(13) .
O23 C72 1.255(15) .
O24 C72 1.240(15) .
O25 H1C 0.8553 .
O25 H1D 0.8555 .
O26 H1A 0.8669 .
O26 H1B 0.8583 .
O27 H27A 0.8705 .
O27 H27B 0.8564 .
O29 H29A 0.8458 .
O29 H29B 0.8864 .
O30 H30A 0.8495 .
O30 H30B 0.8502 .
N1 C2 1.350(12) .
N1 C6 1.365(13) .
N2 C11 1.339(13) .
N2 C7 1.364(13) .
N3 C18 1.328(15) .
N3 C14 1.367(14) .
N3 Co5 1.933(10) 5_567
N4 C23 1.331(13) .
N4 C19 1.342(14) .
N4 Co5 1.994(9) 5_567
N5 C26 1.325(13) .
N5 C30 1.356(13) .
N5 Co5 1.960(9) 8_575
N6 C35 1.337(13) .
N6 C31 1.346(13) .
N6 Co5 1.961(8) 8_575
N7 C38 1.341(14) .
N7 C42 1.367(14) .
N8 C47 1.345(14) .
N8 C43 1.374(14) .
N9 C50 1.319(12) .
N9 C54 1.350(13) .
N10 C59 1.332(12) .
N10 C55 1.354(13) .
N11 C62 1.344(14) .
N11 C66 1.362(14) .
N11 Co4 2.036(9) 2_564
N12 C71 1.341(13) .
N12 C67 1.362(14) .
N12 Co4 2.031(9) 2_564
C1 C3 1.521(14) .
C2 C3 1.390(14) .
C2 H2 0.9300 .
C3 C4 1.386(14) .
C4 C5 1.393(14) .
C4 H4 0.9300 .
C5 C6 1.386(14) .
C5 H5 0.9300 .
C6 C7 1.450(14) .
C7 C8 1.397(14) .
C8 C9 1.367(14) .
C8 H8 0.9300 .
C9 C10 1.386(14) .
C9 H9 0.9300 .
C10 C11 1.391(14) .
C10 C12 1.526(14) .
C11 H11 0.9300 .
C13 C15 1.494(16) .
C14 C15 1.388(16) .
C14 H14 0.9300 .
C15 C16 1.358(17) .
C16 C17 1.392(15) .
C16 H16 0.9300 .
C17 C18 1.387(16) .
C17 H17 0.9300 .
C18 C19 1.486(15) .
C19 C20 1.365(15) .
C20 C21 1.396(15) .
C20 H20 0.9300 .
C21 C22 1.361(15) .
C21 H21 0.9300 .
C22 C23 1.397(15) .
C22 C24 1.501(16) 4_547
C23 H23 0.9300 .
C24 C22 1.501(16) 4_557
C25 C27 1.537(14) .
C26 C27 1.405(14) .
C26 H26 0.9300 .
C27 C28 1.383(14) .
C28 C29 1.394(14) .
C28 H28 0.9300 .
C29 C30 1.390(14) .
C29 H29 0.9300 .
C30 C31 1.481(14) .
C31 C32 1.364(14) .
C32 C33 1.393(14) .
C32 H32 0.9300 .
C33 C34 1.398(14) .
C33 H33 0.9300 .
C34 C35 1.390(14) .
C34 C36 1.506(14) 5_566
C35 H35 0.9300 .
C36 C34 1.506(14) 5_566
C37 C39 1.502(15) .
C38 C39 1.374(15) .
C38 H38 0.9300 .
C39 C40 1.390(15) .
C40 C41 1.407(15) .
C40 H40 0.9300 .
C41 C42 1.368(15) .
C41 H41 0.9300 .
C42 C43 1.477(15) .
C43 C44 1.372(15) .
C44 C45 1.391(15) .
C44 H44 0.9300 .
C45 C46 1.355(15) .
C45 H45 0.9300 .
C46 C47 1.391(15) .
C46 C48 1.528(15) .
C47 H47 0.9300 .
C48 Eu3 2.819(11) 2_564
C49 C51 1.510(14) .
C50 C51 1.427(14) .
C50 H50 0.9300 .
C51 C52 1.379(14) .
C52 C53 1.385(14) .
C52 H52 0.9300 .
C53 C54 1.399(14) .
C53 H53 0.9300 .
C54 C55 1.455(14) .
C55 C56 1.415(14) .
C56 C57 1.372(14) .
C56 H56 0.9300 .
C57 C58 1.413(15) .
C57 H57 0.9300 .
C58 C59 1.391(15) .
C58 C60 1.504(14) .
C59 H59 0.9300 .
C61 C63 1.522(16) .
C62 C63 1.386(16) .
C62 H62 0.9300 .
C63 C64 1.369(16) .
C64 C65 1.388(15) .
C64 H64 0.9300 .
C65 C66 1.398(16) .
C65 H65 0.9300 .
C66 C67 1.476(15) .
C67 C68 1.412(15) .
C68 C69 1.363(15) .
C68 H68 0.9300 .
C69 C70 1.371(16) .
C69 H69 0.9300 .
C70 C71 1.398(15) .
C70 C72 1.533(16) 7_655
C71 H71 0.9300 .
C72 C70 1.533(16) 7_665
Cl2 O32 1.296(16) .
Cl2 O31' 1.40(3) .
Cl2 O33 1.407(12) .
Cl2 O34' 1.42(3) .
Cl2 O31 1.478(16) .
Cl2 O34 1.484(15) .
Cl2 O32' 1.78(4) .
O31 O31' 1.41(4) .
O32 O32' 1.20(4) .
O33 O34' 1.45(4) .
O33 O31' 1.47(3) .
O34 O34' 1.24(4) .
Cl1 O37 1.418(8) .
Cl1 O38 1.428(8) .
Cl1 O35 1.443(8) .
Cl1 O36 1.446(8) .
O28 H28A 0.8500 .
O28 H28B 0.8499 .
O39 H39A 0.8505 .
O39 H39B 0.8503 .
O40 H40A 0.8494 .
O40 H40B 0.8502 .
O41 H41A 0.8496 .
O41 H41B 0.8504 .
O42 H42A 0.8498 .
O42 H42B 0.8496 .
O43 H43A 0.8500 .
O43 H43B 0.8495 .
O44 H44A 0.8469 .
O44 H44B 0.8781 .
O45 H45A 1.0121 .
O45 H45B 1.0471 .
O46 H46A 0.8496 .
O46 H46B 0.8497 .
O47 H47A 0.8496 .
O47 H47B 0.8703 .
O48 H48A 0.8900 .
O48 H48B 0.8677 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3 Eu2 O1 C1 47.7(13) 5_567 .
O20 Eu2 O1 C1 -104.5(13) 3_467 .
O27 Eu2 O1 C1 -25.7(12) . .
O17 Eu2 O1 C1 -56.2(14) 5_567 .
O11 Eu2 O1 C1 114.8(13) 5_567 .
Eu1 Eu2 O1 C1 113.2(12) 5_567 .
O23 Eu1 O4 C12 -131.7(9) . .
O18 Eu1 O4 C12 -46.6(9) . .
O12 Eu1 O4 C12 55.7(9) . .
O10 Eu1 O4 C12 152.6(10) . .
O26 Eu1 O4 C12 -126.4(10) . .
O25 Eu1 O4 C12 100.3(10) . .
O22 Eu1 O4 C12 1.0(10) . .
Eu2 Eu1 O4 C12 1.8(9) 5_567 .
O13 Eu3 O5 C13 162.4(8) . .
O6 Eu3 O5 C13 -7.5(7) . .
O16 Eu3 O5 C13 114.0(7) 2_565 .
O29 Eu3 O5 C13 83.8(8) . .
O30 Eu3 O5 C13 24.0(8) . .
O7 Eu3 O5 C13 -58.6(8) . .
O15 Eu3 O5 C13 -71.8(16) 2_565 .
O8 Eu3 O5 C13 -100.8(8) . .
O14 Eu3 O5 C13 -160.5(7) . .
C48 Eu3 O5 C13 115.9(12) 2_565 .
C37 Eu3 O5 C13 178.7(8) . .
O13 Eu3 O6 C13 -3.6(8) . .
O16 Eu3 O6 C13 -111.3(8) 2_565 .
O29 Eu3 O6 C13 -66.0(8) . .
O30 Eu3 O6 C13 -140.5(8) . .
O7 Eu3 O6 C13 131.5(8) . .
O15 Eu3 O6 C13 175.8(7) 2_565 .
O8 Eu3 O6 C13 77.7(8) . .
O14 Eu3 O6 C13 61.0(9) . .
O5 Eu3 O6 C13 7.4(7) . .
C48 Eu3 O6 C13 -152.0(7) 2_565 .
C37 Eu3 O6 C13 17.1(10) . .
O13 Eu3 O7 C24 27.0(9) . .
O6 Eu3 O7 C24 -83.2(8) . .
O16 Eu3 O7 C24 141.7(7) 2_565 .
O29 Eu3 O7 C24 -111.4(8) . .
O30 Eu3 O7 C24 -152.8(8) . .
O15 Eu3 O7 C24 133.2(8) 2_565 .
O8 Eu3 O7 C24 7.4(7) . .
O14 Eu3 O7 C24 66.3(8) . .
O5 Eu3 O7 C24 -44.3(8) . .
C48 Eu3 O7 C24 137.2(8) 2_565 .
C37 Eu3 O7 C24 53.6(8) . .
O13 Eu3 O8 C24 -174.4(7) . .
O6 Eu3 O8 C24 65.2(7) . .
O16 Eu3 O8 C24 -104.8(8) 2_565 .
O29 Eu3 O8 C24 121.5(8) . .
O30 Eu3 O8 C24 18.2(8) . .
O7 Eu3 O8 C24 -7.2(7) . .
O15 Eu3 O8 C24 -59.5(7) 2_565 .
O14 Eu3 O8 C24 -124.0(8) . .
O5 Eu3 O8 C24 115.3(8) . .
C48 Eu3 O8 C24 -76.5(8) 2_565 .
C37 Eu3 O8 C24 -148.9(8) . .
O23 Eu1 O10 C25 0.1(16) . .
O18 Eu1 O10 C25 108.8(16) . .
O12 Eu1 O10 C25 -145.0(16) . .
O4 Eu1 O10 C25 144.8(16) . .
O26 Eu1 O10 C25 72.6(16) . .
O25 Eu1 O10 C25 -75.5(16) . .
O22 Eu1 O10 C25 -68.3(17) . .
Eu2 Eu1 O10 C25 -177.6(15) 5_567 .
O23 Eu1 O12 C36 145(5) . .
O18 Eu1 O12 C36 29(5) . .
O10 Eu1 O12 C36 -119(5) . .
O4 Eu1 O12 C36 -42(5) . .
O26 Eu1 O12 C36 -46(5) . .
O25 Eu1 O12 C36 172(5) . .
O22 Eu1 O12 C36 100(5) . .
Eu2 Eu1 O12 C36 30(5) 5_567 .
O6 Eu3 O13 C37 149.4(6) . .
O16 Eu3 O13 C37 -70.4(7) 2_565 .
O29 Eu3 O13 C37 -146.1(7) . .
O30 Eu3 O13 C37 -121.0(7) . .
O7 Eu3 O13 C37 59.3(8) . .
O15 Eu3 O13 C37 -30.1(7) 2_565 .
O8 Eu3 O13 C37 74.7(7) . .
O14 Eu3 O13 C37 6.9(6) . .
O5 Eu3 O13 C37 140.7(7) . .
C48 Eu3 O13 C37 -51.1(7) 2_565 .
O13 Eu3 O14 C37 -6.9(6) . .
O6 Eu3 O14 C37 -92.7(8) . .
O16 Eu3 O14 C37 82.0(7) 2_565 .
O29 Eu3 O14 C37 23.2(7) . .
O30 Eu3 O14 C37 120.1(7) . .
O7 Eu3 O14 C37 -155.1(7) . .
O15 Eu3 O14 C37 137.8(7) 2_565 .
O8 Eu3 O14 C37 -109.9(7) . .
O5 Eu3 O14 C37 -53.1(7) . .
C48 Eu3 O14 C37 109.7(7) 2_565 .
O23 Eu1 O18 C49 -160(18) . .
O12 Eu1 O18 C49 -12(18) . .
O10 Eu1 O18 C49 94(18) . .
O4 Eu1 O18 C49 57(18) . .
O26 Eu1 O18 C49 130(18) . .
O25 Eu1 O18 C49 -80(18) . .
O22 Eu1 O18 C49 -88(18) . .
Eu2 Eu1 O18 C49 -13(18) 5_567 .
O23 Eu1 O22 C61 156.3(9) . .
O18 Eu1 O22 C61 51.5(9) . .
O12 Eu1 O22 C61 -48.7(9) . .
O10 Eu1 O22 C61 -130.2(8) . .
O4 Eu1 O22 C61 3.1(10) . .
O26 Eu1 O22 C61 103.8(9) . .
O25 Eu1 O22 C61 -123.0(9) . .
Eu2 Eu1 O22 C61 2.4(8) 5_567 .
O18 Eu1 O23 C72 -156(3) . .
O12 Eu1 O23 C72 89(3) . .
O10 Eu1 O23 C72 -7(3) . .
O4 Eu1 O23 C72 -79(3) . .
O26 Eu1 O23 C72 -84(3) . .
O25 Eu1 O23 C72 62(3) . .
O22 Eu1 O23 C72 135(3) . .
Eu2 Eu1 O23 C72 170(3) 5_567 .
N3 Co5 N1 C2 -86.6(9) 5_567 .
N2 Co5 N1 C2 -177.6(9) . .
N5 Co5 N1 C2 89.6(9) 8_576 .
N6 Co5 N1 C2 6.0(9) 8_576 .
N4 Co5 N1 C2 -149(11) 5_567 .
N3 Co5 N1 C6 102.3(7) 5_567 .
N2 Co5 N1 C6 11.4(7) . .
N5 Co5 N1 C6 -81.4(7) 8_576 .
N6 Co5 N1 C6 -165.1(7) 8_576 .
N4 Co5 N1 C6 40(12) 5_567 .
N3 Co5 N2 C11 74.0(9) 5_567 .
N5 Co5 N2 C11 -102.7(9) 8_576 .
N6 Co5 N2 C11 -168.3(16) 8_576 .
N4 Co5 N2 C11 -7.7(9) 5_567 .
N1 Co5 N2 C11 171.4(9) . .
N3 Co5 N2 C7 -108.6(7) 5_567 .
N5 Co5 N2 C7 74.7(7) 8_576 .
N6 Co5 N2 C7 9(2) 8_576 .
N4 Co5 N2 C7 169.7(7) 5_567 .
N1 Co5 N2 C7 -11.2(7) . .
N8 Co4 N7 C38 -176.5(10) . .
N12 Co4 N7 C38 10.0(10) 2_565 .
N11 Co4 N7 C38 91.0(10) 2_565 .
N9 Co4 N7 C38 -81.8(10) . .
N10 Co4 N7 C38 -110(2) . .
N8 Co4 N7 C42 -1.6(8) . .
N12 Co4 N7 C42 -175.1(8) 2_565 .
N11 Co4 N7 C42 -94.1(8) 2_565 .
N9 Co4 N7 C42 93.1(8) . .
N10 Co4 N7 C42 65(3) . .
N7 Co4 N8 C47 -176.6(10) . .
N12 Co4 N8 C47 -105(3) 2_565 .
N11 Co4 N8 C47 -80.1(10) 2_565 .
N9 Co4 N8 C47 91.8(9) . .
N10 Co4 N8 C47 11.3(10) . .
N7 Co4 N8 C43 -3.1(8) . .
N12 Co4 N8 C43 68(3) 2_565 .
N11 Co4 N8 C43 93.4(8) 2_565 .
N9 Co4 N8 C43 -94.8(8) . .
N10 Co4 N8 C43 -175.3(8) . .
N8 Co4 N9 C50 75.9(9) . .
N7 Co4 N9 C50 -5.2(9) . .
N12 Co4 N9 C50 -102.1(9) 2_565 .
N11 Co4 N9 C50 -147.8(15) 2_565 .
N10 Co4 N9 C50 170.7(9) . .
N8 Co4 N9 C54 -109.7(7) . .
N7 Co4 N9 C54 169.2(7) . .
N12 Co4 N9 C54 72.3(7) 2_565 .
N11 Co4 N9 C54 27(2) 2_565 .
N10 Co4 N9 C54 -14.8(7) . .
N8 Co4 N10 C59 -75.8(9) . .
N7 Co4 N10 C59 -141(2) . .
N12 Co4 N10 C59 98.1(9) 2_565 .
N11 Co4 N10 C59 17.9(9) 2_565 .
N9 Co4 N10 C59 -169.9(9) . .
N8 Co4 N10 C55 107.9(7) . .
N7 Co4 N10 C55 42(3) . .
N12 Co4 N10 C55 -78.2(7) 2_565 .
N11 Co4 N10 C55 -158.4(7) 2_565 .
N9 Co4 N10 C55 13.8(7) . .
Eu2 O1 C1 O2 133.0(11) . .
Eu2 O1 C1 C3 -47.8(17) . .
C6 N1 C2 C3 1.9(15) . .
Co5 N1 C2 C3 -168.8(8) . .
N1 C2 C3 C4 -2.1(16) . .
N1 C2 C3 C1 175.0(9) . .
O2 C1 C3 C4 158.7(10) . .
O1 C1 C3 C4 -20.6(15) . .
O2 C1 C3 C2 -18.3(14) . .
O1 C1 C3 C2 162.4(10) . .
C2 C3 C4 C5 1.5(15) . .
C1 C3 C4 C5 -175.5(10) . .
C3 C4 C5 C6 -0.7(15) . .
C2 N1 C6 C5 -1.1(15) . .
Co5 N1 C6 C5 171.0(8) . .
C2 N1 C6 C7 178.4(9) . .
Co5 N1 C6 C7 -9.5(11) . .
C4 C5 C6 N1 0.5(15) . .
C4 C5 C6 C7 -178.9(10) . .
C11 N2 C7 C8 6.0(14) . .
Co5 N2 C7 C8 -171.5(8) . .
C11 N2 C7 C6 -173.1(9) . .
Co5 N2 C7 C6 9.3(11) . .
N1 C6 C7 N2 0.4(13) . .
C5 C6 C7 N2 179.9(9) . .
N1 C6 C7 C8 -178.7(9) . .
C5 C6 C7 C8 0.8(16) . .
N2 C7 C8 C9 -4.9(15) . .
C6 C7 C8 C9 174.2(10) . .
C7 C8 C9 C10 -0.6(15) . .
C8 C9 C10 C11 4.8(15) . .
C8 C9 C10 C12 -175.6(10) . .
C7 N2 C11 C10 -1.8(15) . .
Co5 N2 C11 C10 175.5(7) . .
C9 C10 C11 N2 -3.7(15) . .
C12 C10 C11 N2 176.6(9) . .
Eu1 O4 C12 O3 -0.5(17) . .
Eu1 O4 C12 C10 -178.7(6) . .
Eu2 O3 C12 O4 -5(2) 5_567 .
Eu2 O3 C12 C10 173.2(9) 5_567 .
C9 C10 C12 O4 -175.3(9) . .
C11 C10 C12 O4 4.3(14) . .
C9 C10 C12 O3 6.3(14) . .
C11 C10 C12 O3 -174.1(9) . .
Eu3 O5 C13 O6 13.0(12) . .
Eu3 O5 C13 C15 -164.5(11) . .
Eu3 O6 C13 O5 -15.3(14) . .
Eu3 O6 C13 C15 162.3(9) . .
O13 Eu3 C13 O5 -16.7(7) . .
O6 Eu3 C13 O5 166.4(13) . .
O16 Eu3 C13 O5 -94.7(8) 2_565 .
O29 Eu3 C13 O5 -86.7(8) . .
O30 Eu3 C13 O5 -157.5(7) . .
O7 Eu3 C13 O5 122.1(7) . .
O15 Eu3 C13 O5 159.4(6) 2_565 .
O8 Eu3 C13 O5 70.6(7) . .
O14 Eu3 C13 O5 24.9(9) . .
C48 Eu3 C13 O5 -138.5(9) 2_565 .
C37 Eu3 C13 O5 -1.5(8) . .
O13 Eu3 C13 O6 176.8(7) . .
O16 Eu3 C13 O6 98.8(8) 2_565 .
O29 Eu3 C13 O6 106.9(8) . .
O30 Eu3 C13 O6 36.1(7) . .
O7 Eu3 C13 O6 -44.4(7) . .
O15 Eu3 C13 O6 -7.0(12) 2_565 .
O8 Eu3 C13 O6 -95.9(8) . .
O14 Eu3 C13 O6 -141.6(7) . .
O5 Eu3 C13 O6 -166.4(13) . .
C48 Eu3 C13 O6 55.0(13) 2_565 .
C37 Eu3 C13 O6 -167.9(7) . .
O13 Eu3 C13 C15 112(3) . .
O6 Eu3 C13 C15 -65(3) . .
O16 Eu3 C13 C15 34(3) 2_565 .
O29 Eu3 C13 C15 42(3) . .
O30 Eu3 C13 C15 -29(3) . .
O7 Eu3 C13 C15 -110(3) . .
O15 Eu3 C13 C15 -72(3) 2_565 .
O8 Eu3 C13 C15 -161(3) . .
O14 Eu3 C13 C15 153(3) . .
O5 Eu3 C13 C15 128(3) . .
C48 Eu3 C13 C15 -10(4) 2_565 .
C37 Eu3 C13 C15 127(3) . .
C18 N3 C14 C15 -0.5(16) . .
Co5 N3 C14 C15 -175.4(9) 5_567 .
N3 C14 C15 C16 1.5(18) . .
N3 C14 C15 C13 176.8(10) . .
O5 C13 C15 C16 155.1(12) . .
O6 C13 C15 C16 -22.5(17) . .
Eu3 C13 C15 C16 33(4) . .
O5 C13 C15 C14 -20.4(19) . .
O6 C13 C15 C14 162.0(11) . .
Eu3 C13 C15 C14 -142(2) . .
C14 C15 C16 C17 -1.2(18) . .
C13 C15 C16 C17 -176.9(10) . .
C15 C16 C17 C18 0.1(17) . .
C14 N3 C18 C17 -0.8(17) . .
Co5 N3 C18 C17 174.7(9) 5_567 .
C14 N3 C18 C19 178.6(9) . .
Co5 N3 C18 C19 -6.0(12) 5_567 .
C16 C17 C18 N3 0.9(17) . .
C16 C17 C18 C19 -178.3(10) . .
C23 N4 C19 C20 2.6(16) . .
Co5 N4 C19 C20 -172.5(9) 5_567 .
C23 N4 C19 C18 -176.8(9) . .
Co5 N4 C19 C18 8.1(12) 5_567 .
N3 C18 C19 N4 -1.6(14) . .
C17 C18 C19 N4 177.7(10) . .
N3 C18 C19 C20 179.0(11) . .
C17 C18 C19 C20 -1.7(18) . .
N4 C19 C20 C21 -2.9(17) . .
C18 C19 C20 C21 176.4(10) . .
C19 C20 C21 C22 0.2(16) . .
C20 C21 C22 C23 2.5(16) . .
C20 C21 C22 C24 179.9(10) . 4_547
C19 N4 C23 C22 0.3(16) . .
Co5 N4 C23 C22 174.6(8) 5_567 .
C21 C22 C23 N4 -2.8(17) . .
C24 C22 C23 N4 179.8(10) 4_547 .
Eu3 O7 C24 O8 -14.0(14) . .
Eu3 O7 C24 C22 160.6(10) . 4_557
Eu3 O8 C24 O7 13.8(14) . .
Eu3 O8 C24 C22 -160.8(10) . 4_557
Eu1 O10 C25 O9 -38(2) . .
Eu1 O10 C25 C27 143.6(12) . .
C30 N5 C26 C27 -2.8(15) . .
Co5 N5 C26 C27 173.8(8) 8_575 .
N5 C26 C27 C28 0.0(15) . .
N5 C26 C27 C25 -179.9(10) . .
O9 C25 C27 C28 -163.6(10) . .
O10 C25 C27 C28 15.2(15) . .
O9 C25 C27 C26 16.2(15) . .
O10 C25 C27 C26 -164.9(10) . .
C26 C27 C28 C29 0.6(15) . .
C25 C27 C28 C29 -179.5(10) . .
C27 C28 C29 C30 1.6(15) . .
C26 N5 C30 C29 5.0(15) . .
Co5 N5 C30 C29 -172.0(8) 8_575 .
C26 N5 C30 C31 -174.6(9) . .
Co5 N5 C30 C31 8.4(11) 8_575 .
C28 C29 C30 N5 -4.4(15) . .
C28 C29 C30 C31 175.2(10) . .
C35 N6 C31 C32 -5.5(15) . .
Co5 N6 C31 C32 165.8(8) 8_575 .
C35 N6 C31 C30 176.5(9) . .
Co5 N6 C31 C30 -12.3(11) 8_575 .
N5 C30 C31 N6 2.7(13) . .
C29 C30 C31 N6 -177.0(9) . .
N5 C30 C31 C32 -175.4(9) . .
C29 C30 C31 C32 5.0(16) . .
N6 C31 C32 C33 2.9(15) . .
C30 C31 C32 C33 -179.1(10) . .
C31 C32 C33 C34 1.3(15) . .
C32 C33 C34 C35 -2.9(14) . .
C32 C33 C34 C36 176.9(9) . 5_566
C31 N6 C35 C34 3.7(15) . .
Co5 N6 C35 C34 -166.0(7) 8_575 .
C33 C34 C35 N6 0.4(15) . .
C36 C34 C35 N6 -179.3(9) 5_566 .
Eu2 O11 C36 O12 2.7(14) 5_567 .
Eu2 O11 C36 C34 -179.1(7) 5_567 5_566
Eu1 O12 C36 O11 -33(5) . .
Eu1 O12 C36 C34 149(4) . 5_566
Eu3 O14 C37 O13 12.2(11) . .
Eu3 O14 C37 C39 -163.4(10) . .
Eu3 O13 C37 O14 -13.1(12) . .
Eu3 O13 C37 C39 162.7(9) . .
O13 Eu3 C37 O14 167.7(11) . .
O6 Eu3 C37 O14 123.5(6) . .
O16 Eu3 C37 O14 -89.5(6) 2_565 .
O29 Eu3 C37 O14 -159.9(6) . .
O30 Eu3 C37 O14 -97.0(8) . .
O7 Eu3 C37 O14 29.4(8) . .
O15 Eu3 C37 O14 -39.5(6) 2_565 .
O8 Eu3 C37 O14 64.4(6) . .
O5 Eu3 C37 O14 130.7(6) . .
C48 Eu3 C37 O14 -63.8(6) 2_565 .
O6 Eu3 C37 O13 -44.2(9) . .
O16 Eu3 C37 O13 102.8(7) 2_565 .
O29 Eu3 C37 O13 32.4(7) . .
O30 Eu3 C37 O13 95.4(8) . .
O7 Eu3 C37 O13 -138.3(6) . .
O15 Eu3 C37 O13 152.9(7) 2_565 .
O8 Eu3 C37 O13 -103.3(7) . .
O14 Eu3 C37 O13 -167.7(11) . .
O5 Eu3 C37 O13 -36.9(7) . .
C48 Eu3 C37 O13 128.5(7) 2_565 .
O13 Eu3 C37 C39 -80(3) . .
O6 Eu3 C37 C39 -125(3) . .
O16 Eu3 C37 C39 22(3) 2_565 .
O29 Eu3 C37 C39 -48(3) . .
O30 Eu3 C37 C39 15(3) . .
O7 Eu3 C37 C39 141(3) . .
O15 Eu3 C37 C39 72(3) 2_565 .
O8 Eu3 C37 C39 176(3) . .
O14 Eu3 C37 C39 112(3) . .
O5 Eu3 C37 C39 -117(3) . .
C48 Eu3 C37 C39 48(3) 2_565 .
C42 N7 C38 C39 -4.4(17) . .
Co4 N7 C38 C39 170.3(9) . .
N7 C38 C39 C40 2.1(18) . .
N7 C38 C39 C37 -178.6(11) . .
O14 C37 C39 C38 -17.0(18) . .
O13 C37 C39 C38 167.3(11) . .
Eu3 C37 C39 C38 -121(3) . .
O14 C37 C39 C40 162.3(11) . .
O13 C37 C39 C40 -13.5(17) . .
Eu3 C37 C39 C40 58(4) . .
C38 C39 C40 C41 0.3(17) . .
C37 C39 C40 C41 -179.0(10) . .
C39 C40 C41 C42 -0.2(17) . .
C38 N7 C42 C41 4.4(17) . .
Co4 N7 C42 C41 -171.0(9) . .
C38 N7 C42 C43 -178.9(10) . .
Co4 N7 C42 C43 5.7(13) . .
C40 C41 C42 N7 -2.1(18) . .
C40 C41 C42 C43 -178.5(11) . .
C47 N8 C43 C44 1.3(16) . .
Co4 N8 C43 C44 -172.9(9) . .
C47 N8 C43 C42 -178.8(10) . .
Co4 N8 C43 C42 7.0(13) . .
N7 C42 C43 C44 171.6(11) . .
C41 C42 C43 C44 -11.8(19) . .
N7 C42 C43 N8 -8.3(15) . .
C41 C42 C43 N8 168.3(11) . .
N8 C43 C44 C45 1.2(18) . .
C42 C43 C44 C45 -178.8(11) . .
C43 C44 C45 C46 -4.2(17) . .
C44 C45 C46 C47 4.8(17) . .
C44 C45 C46 C48 -178.9(10) . .
C43 N8 C47 C46 -0.6(16) . .
Co4 N8 C47 C46 172.7(8) . .
C45 C46 C47 N8 -2.5(18) . .
C48 C46 C47 N8 -179.0(10) . .
Eu3 O15 C48 O16 0.2(11) 2_564 .
Eu3 O15 C48 C46 -178.2(9) 2_564 .
Eu3 O16 C48 O15 -0.2(12) 2_564 .
Eu3 O16 C48 C46 178.2(9) 2_564 .
C45 C46 C48 O15 -16.2(17) . .
C47 C46 C48 O15 160.1(10) . .
C45 C46 C48 O16 165.3(11) . .
C47 C46 C48 O16 -18.3(16) . .
C45 C46 C48 Eu3 -150(21) . 2_564
C47 C46 C48 Eu3 26(22) . 2_564
Eu2 O17 C49 O18 3.5(14) 5_567 .
Eu2 O17 C49 C51 -173.0(7) 5_567 .
Eu1 O18 C49 O17 10(19) . .
Eu1 O18 C49 C51 -173(100) . .
C54 N9 C50 C51 -2.4(15) . .
Co4 N9 C50 C51 171.6(7) . .
N9 C50 C51 C52 -3.0(15) . .
N9 C50 C51 C49 174.4(9) . .
O17 C49 C51 C52 -173.0(9) . .
O18 C49 C51 C52 10.1(14) . .
O17 C49 C51 C50 9.7(15) . .
O18 C49 C51 C50 -167.2(9) . .
C50 C51 C52 C53 3.3(15) . .
C49 C51 C52 C53 -174.1(10) . .
C51 C52 C53 C54 1.5(15) . .
C50 N9 C54 C53 7.5(15) . .
Co4 N9 C54 C53 -167.4(8) . .
C50 N9 C54 C55 -171.6(9) . .
Co4 N9 C54 C55 13.6(11) . .
C52 C53 C54 N9 -7.0(15) . .
C52 C53 C54 C55 171.9(10) . .
C59 N10 C55 C56 -3.7(15) . .
Co4 N10 C55 C56 173.0(8) . .
C59 N10 C55 C54 172.5(9) . .
Co4 N10 C55 C54 -10.8(11) . .
N9 C54 C55 N10 -1.8(14) . .
C53 C54 C55 N10 179.2(10) . .
N9 C54 C55 C56 174.3(9) . .
C53 C54 C55 C56 -4.7(16) . .
N10 C55 C56 C57 4.8(15) . .
C54 C55 C56 C57 -171.2(10) . .
C55 C56 C57 C58 -2.8(16) . .
C56 C57 C58 C59 -0.2(16) . .
C56 C57 C58 C60 177.2(10) . .
C55 N10 C59 C58 0.6(16) . .
Co4 N10 C59 C58 -175.5(8) . .
C57 C58 C59 N10 1.4(16) . .
C60 C58 C59 N10 -176.0(10) . .
Eu2 O20 C60 O19 -13(2) 3_567 .
Eu2 O20 C60 C58 165.8(7) 3_567 .
C59 C58 C60 O20 146.6(11) . .
C57 C58 C60 O20 -30.7(16) . .
C59 C58 C60 O19 -34.6(16) . .
C57 C58 C60 O19 148.1(11) . .
Eu1 O22 C61 O21 7.3(17) . .
Eu1 O22 C61 C63 -173.5(7) . .
Eu2 O21 C61 O22 -51(3) 5_567 .
Eu2 O21 C61 C63 130(2) 5_567 .
C66 N11 C62 C63 -0.9(17) . .
Co4 N11 C62 C63 169.0(9) 2_564 .
N11 C62 C63 C64 -2.9(18) . .
N11 C62 C63 C61 176.4(11) . .
O22 C61 C63 C64 -175.4(11) . .
O21 C61 C63 C64 3.9(16) . .
O22 C61 C63 C62 5.3(17) . .
O21 C61 C63 C62 -175.4(11) . .
C62 C63 C64 C65 4.1(17) . .
C61 C63 C64 C65 -175.2(11) . .
C63 C64 C65 C66 -1.6(17) . .
C62 N11 C66 C65 3.5(16) . .
Co4 N11 C66 C65 -167.8(9) 2_564 .
C62 N11 C66 C67 -173.8(10) . .
Co4 N11 C66 C67 14.9(12) 2_564 .
C64 C65 C66 N11 -2.4(17) . .
C64 C65 C66 C67 174.7(11) . .
C71 N12 C67 C68 -2.2(16) . .
Co4 N12 C67 C68 173.2(8) 2_564 .
C71 N12 C67 C66 176.5(10) . .
Co4 N12 C67 C66 -8.1(12) 2_564 .
N11 C66 C67 N12 -4.6(15) . .
C65 C66 C67 N12 178.2(11) . .
N11 C66 C67 C68 174.1(10) . .
C65 C66 C67 C68 -3.2(18) . .
N12 C67 C68 C69 1.3(17) . .
C66 C67 C68 C69 -177.3(11) . .
C67 C68 C69 C70 -0.6(17) . .
C68 C69 C70 C71 0.7(17) . .
C68 C69 C70 C72 -177.9(11) . 7_655
C67 N12 C71 C70 2.4(16) . .
Co4 N12 C71 C70 -172.3(8) 2_564 .
C69 C70 C71 N12 -1.7(17) . .
C72 C70 C71 N12 177.0(11) 7_655 .
Eu1 O23 C72 O24 -24(4) . .
Eu1 O23 C72 C70 156(2) . 7_665
O32 Cl2 O31 O31' -87(2) . .
O33 Cl2 O31 O31' 43.1(18) . .
O34' Cl2 O31 O31' 109(3) . .
O34 Cl2 O31 O31' 155.7(19) . .
O32' Cl2 O31 O31' -44(3) . .
O31' Cl2 O32 O32' 75(2) . .
O33 Cl2 O32 O32' 10(2) . .
O34' Cl2 O32 O32' -60(3) . .
O31 Cl2 O32 O32' 134(2) . .
O34 Cl2 O32 O32' -114(2) . .
O32 Cl2 O33 O34' -105.2(19) . .
O31' Cl2 O33 O34' 168(2) . .
O31 Cl2 O33 O34' 127.7(18) . .
O34 Cl2 O33 O34' 19.8(18) . .
O32' Cl2 O33 O34' -98(2) . .
O32 Cl2 O33 O31' 86.3(18) . .
O34' Cl2 O33 O31' -168(2) . .
O31 Cl2 O33 O31' -40.8(17) . .
O34 Cl2 O33 O31' -148.7(18) . .
O32' Cl2 O33 O31' 93(2) . .
O32 Cl2 O34 O34' 107(2) . .
O31' Cl2 O34 O34' -90(4) . .
O33 Cl2 O34 O34' -23(2) . .
O31 Cl2 O34 O34' -134(2) . .
O32' Cl2 O34 O34' 62(2) . .
O32 Cl2 O31' O31 110.4(14) . .
O33 Cl2 O31' O31 -132.8(18) . .
O34' Cl2 O31' O31 -121(2) . .
O34 Cl2 O31' O31 -53(4) . .
O32' Cl2 O31' O31 150.8(17) . .
O32 Cl2 O31' O33 -116.8(11) . .
O34' Cl2 O31' O33 12(3) . .
O31 Cl2 O31' O33 132.8(18) . .
O34 Cl2 O31' O33 79(3) . .
O32' Cl2 O31' O33 -76.4(15) . .
Cl2 O31 O31' O33 -40.8(15) . .
O34' O33 O31' Cl2 -11(2) . .
Cl2 O33 O31' O31 43.2(17) . .
O34' O33 O31' O31 32(3) . .
O31' Cl2 O32' O32 -108(2) . .
O33 Cl2 O32' O32 -171(2) . .
O34' Cl2 O32' O32 129(2) . .
O31 Cl2 O32' O32 -71(3) . .
O34 Cl2 O32' O32 86(2) . .
Cl2 O34 O34' O33 25(2) . .
O32 Cl2 O34' O34 -95.3(18) . .
O31' Cl2 O34' O34 143(2) . .
O33 Cl2 O34' O34 155(2) . .
O31 Cl2 O34' O34 68(2) . .
O32' Cl2 O34' O34 -130.7(19) . .
O32 Cl2 O34' O33 109.5(14) . .
O31' Cl2 O34' O33 -12(3) . .
O31 Cl2 O34' O33 -87.7(19) . .
O34 Cl2 O34' O33 -155(2) . .
O32' Cl2 O34' O33 74.1(15) . .
Cl2 O33 O34' O34 -27(2) . .
O31' O33 O34' O34 -16(4) . .
O31' O33 O34' Cl2 11(2) . .
