#------------------------------------------------------------------------------
#$Date: 2016-03-25 15:35:39 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179926 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/21/7022102.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7022102
loop_
_publ_author_name
'Devillers, Charles H.'
'Milet, Anne'
'Moutet, Jean-Claude'
'Pécaut, Jacques'
'Royal, Guy'
'Saint-Aman, Eric'
'Bucher, Christophe'
_publ_section_title
;
 Long-range electronic connection in picket-fence like ferrocene-porphyrin
 derivatives.
;
_journal_issue                   4
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1196
_journal_page_last               1209
_journal_paper_doi               10.1039/c2dt31667f
_journal_volume                  42
_journal_year                    2013
_chemical_formula_sum            'C58 H48 Fe2 N4 O4 Zn'
_chemical_formula_weight         1042.07
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   difmap
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                67.731(5)
_cell_angle_beta                 72.240(5)
_cell_angle_gamma                76.832(5)
_cell_formula_units_Z            1
_cell_length_a                   8.236(2)
_cell_length_b                   12.414(4)
_cell_length_c                   12.620(4)
_cell_measurement_reflns_used    3967
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      26.37
_cell_measurement_theta_min      1.79
_cell_volume                     1127.9(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      223(2)
_diffrn_measured_fraction_theta_full 0.968
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0132
_diffrn_reflns_av_sigmaI/netI    0.0258
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            6557
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         1.79
_exptl_absorpt_coefficient_mu    1.219
_exptl_absorpt_correction_T_max  0.941
_exptl_absorpt_correction_T_min  0.929
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            dark
_exptl_crystal_density_diffrn    1.534
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             538
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.534
_refine_diff_density_min         -0.521
_refine_diff_density_rms         0.068
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.109
_refine_ls_hydrogen_treatment    refall
_refine_ls_matrix_type           full
_refine_ls_number_parameters     409
_refine_ls_number_reflns         4461
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.109
_refine_ls_R_factor_all          0.0483
_refine_ls_R_factor_gt           0.0418
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0445P)²+1.5379P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1023
_refine_ls_wR_factor_ref         0.1049
_reflns_number_gt                3967
_reflns_number_total             4461
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt31667f.txt
_cod_data_source_block           8Zn
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7022102
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn Zn 0.0000 1.0000 0.0000 0.02685(14) Uani 1 2 d S
Fe Fe 0.72450(5) 0.77907(4) -0.25174(4) 0.02789(13) Uani 1 1 d .
N1 N 0.1263(3) 1.0612(2) -0.17384(19) 0.0226(5) Uani 1 1 d .
N2 N 0.2319(3) 0.9155(2) 0.03815(19) 0.0227(5) Uani 1 1 d .
C1 C 0.0544(4) 1.1447(2) -0.2618(2) 0.0229(5) Uani 1 1 d .
C2 C 0.1883(4) 1.1853(2) -0.3659(2) 0.0265(6) Uani 1 1 d .
H2 H 0.168(4) 1.244(3) -0.435(3) 0.029(8) Uiso 1 1 d .
C3 C 0.3385(4) 1.1252(3) -0.3420(2) 0.0272(6) Uani 1 1 d .
H3 H 0.442(5) 1.133(3) -0.387(3) 0.036(9) Uiso 1 1 d .
C4 C 0.3001(3) 1.0454(2) -0.2218(2) 0.0233(6) Uani 1 1 d .
C5 C 0.4234(3) 0.9660(2) -0.1628(2) 0.0228(5) Uani 1 1 d .
C6 C 0.3907(3) 0.9100(2) -0.0395(2) 0.0233(6) Uani 1 1 d .
C7 C 0.5144(4) 0.8357(3) 0.0262(3) 0.0289(6) Uani 1 1 d .
H7 H 0.626(5) 0.819(3) -0.006(3) 0.032(9) Uiso 1 1 d .
C8 C 0.4303(4) 0.7967(3) 0.1404(3) 0.0283(6) Uani 1 1 d .
H8 H 0.469(5) 0.749(3) 0.203(3) 0.044(10) Uiso 1 1 d .
C9 C 0.2521(3) 0.8439(2) 0.1485(2) 0.0228(5) Uani 1 1 d .
C10 C 0.5946(4) 0.9413(2) -0.2398(2) 0.0243(6) Uani 1 1 d .
C11 C 0.6216(4) 0.9325(3) -0.3546(3) 0.0277(6) Uani 1 1 d .
H11 H 0.533(5) 0.936(3) -0.385(3) 0.034(9) Uiso 1 1 d .
C12 C 0.8010(4) 0.9128(3) -0.4036(3) 0.0325(7) Uani 1 1 d .
H12 H 0.852(5) 0.903(3) -0.478(3) 0.038(9) Uiso 1 1 d .
C13 C 0.8871(4) 0.9057(3) -0.3188(3) 0.0306(6) Uani 1 1 d .
H13 H 1.005(5) 0.890(3) -0.329(3) 0.038(9) Uiso 1 1 d .
C14 C 0.7618(4) 0.9234(2) -0.2194(3) 0.0266(6) Uani 1 1 d .
H14 H 0.787(4) 0.929(3) -0.155(3) 0.029(8) Uiso 1 1 d .
C15 C 0.5710(4) 0.6492(3) -0.1628(3) 0.0389(8) Uani 1 1 d .
C16 C 0.6468(4) 0.6506(3) -0.2816(3) 0.0395(8) Uani 1 1 d .
H16 H 0.585(5) 0.661(3) -0.342(3) 0.041(10) Uiso 1 1 d .
C17 C 0.8272(5) 0.6302(3) -0.2961(4) 0.0426(8) Uani 1 1 d .
H17 H 0.910(6) 0.626(4) -0.365(4) 0.057(12) Uiso 1 1 d .
C18 C 0.8634(5) 0.6182(3) -0.1892(4) 0.0454(9) Uani 1 1 d .
H18 H 0.971(6) 0.612(4) -0.176(4) 0.063(13) Uiso 1 1 d .
C19 C 0.7070(5) 0.6297(3) -0.1062(3) 0.0421(8) Uani 1 1 d .
H19 H 0.695(5) 0.621(3) -0.028(4) 0.046(11) Uiso 1 1 d .
C20 C 0.3886(5) 0.6802(3) -0.1118(4) 0.0501(9) Uani 1 1 d .
H20 H 0.358(6) 0.686(4) -0.028(4) 0.062(12) Uiso 1 1 d .
C21 C 0.1209(4) 0.8152(2) 0.2521(2) 0.0225(5) Uani 1 1 d .
C22 C 0.1731(3) 0.7309(2) 0.3618(2) 0.0230(6) Uani 1 1 d .
C23 C 0.1802(5) 0.6112(3) 0.3899(3) 0.0376(7) Uani 1 1 d .
H23 H 0.157(5) 0.586(3) 0.342(4) 0.051(11) Uiso 1 1 d .
C24 C 0.2291(5) 0.5330(3) 0.4905(3) 0.0398(8) Uani 1 1 d .
H24 H 0.233(5) 0.457(4) 0.508(3) 0.049(11) Uiso 1 1 d .
C25 C 0.2715(4) 0.5716(3) 0.5665(3) 0.0318(7) Uani 1 1 d .
C26 C 0.2630(4) 0.6915(3) 0.5393(3) 0.0347(7) Uani 1 1 d .
H26 H 0.282(4) 0.714(3) 0.587(3) 0.027(9) Uiso 1 1 d .
C27 C 0.2142(4) 0.7701(3) 0.4385(3) 0.0299(6) Uani 1 1 d .
H27 H 0.206(4) 0.849(3) 0.421(3) 0.035(9) Uiso 1 1 d .
C28 C 0.3228(6) 0.4858(4) 0.6768(4) 0.0494(10) Uani 1 1 d .
H28A H 0.294(8) 0.510(5) 0.734(6) 0.09(2) Uiso 1 1 d .
H28B H 0.425(9) 0.483(5) 0.673(5) 0.10(2) Uiso 1 1 d .
H28C H 0.289(8) 0.425(5) 0.696(5) 0.10(2) Uiso 1 1 d .
C31 C -0.0440(6) 0.7107(4) 0.0706(4) 0.0435(8) Uani 1 1 d .
H31A H 0.052(6) 0.683(4) 0.103(4) 0.058(12) Uiso 1 1 d .
H31B H -0.056(5) 0.656(3) 0.050(3) 0.034(9) Uiso 1 1 d .
H31C H -0.131(6) 0.728(4) 0.123(4) 0.066(15) Uiso 1 1 d .
O1 O 0.2732(3) 0.7039(3) -0.1618(3) 0.0616(8) Uani 1 1 d .
O2 O -0.0174(3) 0.8142(2) -0.0265(2) 0.0416(6) Uani 1 1 d .
H2O H 0.081(7) 0.787(5) -0.085(5) 0.100(19) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Zn N1 180.0 2_575 .
N1 Zn N2 91.38(9) 2_575 .
N1 Zn N2 88.62(9) . .
N1 Zn N2 88.62(9) 2_575 2_575
N1 Zn N2 91.38(9) . 2_575
N2 Zn N2 180.00(15) . 2_575
C11 Fe C15 117.14(14) . .
C11 Fe C12 40.94(12) . .
C15 Fe C12 147.51(14) . .
C11 Fe C16 105.65(14) . .
C15 Fe C16 41.14(14) . .
C12 Fe C16 112.29(14) . .
C11 Fe C19 152.37(14) . .
C15 Fe C19 41.07(15) . .
C12 Fe C19 166.68(14) . .
C16 Fe C19 69.11(16) . .
C11 Fe C17 126.46(15) . .
C15 Fe C17 68.08(14) . .
C12 Fe C17 104.08(14) . .
C16 Fe C17 40.43(14) . .
C19 Fe C17 67.94(16) . .
C11 Fe C13 68.30(12) . .
C15 Fe C13 171.79(14) . .
C12 Fe C13 40.58(13) . .
C16 Fe C13 145.52(13) . .
C19 Fe C13 131.55(14) . .
C17 Fe C13 114.38(14) . .
C11 Fe C18 164.96(14) . .
C15 Fe C18 68.01(15) . .
C12 Fe C18 127.12(14) . .
C16 Fe C18 68.27(16) . .
C19 Fe C18 40.07(15) . .
C17 Fe C18 40.25(16) . .
C13 Fe C18 108.41(14) . .
C11 Fe C14 67.77(12) . .
C15 Fe C14 134.64(13) . .
C12 Fe C14 67.71(12) . .
C16 Fe C14 170.48(13) . .
C19 Fe C14 113.25(14) . .
C17 Fe C14 149.02(13) . .
C13 Fe C14 39.92(12) . .
C18 Fe C14 119.82(14) . .
C11 Fe C10 40.92(11) . .
C15 Fe C10 111.65(12) . .
C12 Fe C10 68.65(12) . .
C16 Fe C10 130.56(13) . .
C19 Fe C10 121.26(13) . .
C17 Fe C10 166.68(14) . .
C13 Fe C10 67.91(12) . .
C18 Fe C10 152.93(14) . .
C14 Fe C10 40.03(11) . .
C4 N1 C1 106.7(2) . .
C4 N1 Zn 127.46(18) . .
C1 N1 Zn 124.84(18) . .
C9 N2 C6 106.9(2) . .
C9 N2 Zn 124.73(18) . .
C6 N2 Zn 128.09(18) . .
N1 C1 C21 125.9(2) . 2_575
N1 C1 C2 109.3(2) . .
C21 C1 C2 124.8(2) 2_575 .
C3 C2 C1 107.5(2) . .
C3 C2 H2 129(2) . .
C1 C2 H2 123(2) . .
C2 C3 C4 107.4(3) . .
C2 C3 H3 128(2) . .
C4 C3 H3 124(2) . .
N1 C4 C5 125.8(2) . .
N1 C4 C3 109.1(2) . .
C5 C4 C3 125.1(2) . .
C6 C5 C4 123.9(2) . .
C6 C5 C10 120.3(2) . .
C4 C5 C10 115.9(2) . .
N2 C6 C5 124.9(2) . .
N2 C6 C7 108.7(2) . .
C5 C6 C7 126.3(3) . .
C8 C7 C6 107.6(3) . .
C8 C7 H7 128(2) . .
C6 C7 H7 124(2) . .
C7 C8 C9 107.6(3) . .
C7 C8 H8 130(2) . .
C9 C8 H8 122(2) . .
N2 C9 C21 126.3(2) . .
N2 C9 C8 109.1(2) . .
C21 C9 C8 124.5(2) . .
C14 C10 C11 106.0(2) . .
C14 C10 C5 129.2(3) . .
C11 C10 C5 124.8(3) . .
C14 C10 Fe 69.79(16) . .
C11 C10 Fe 66.97(16) . .
C5 C10 Fe 128.23(19) . .
C12 C11 C10 109.1(3) . .
C12 C11 Fe 70.12(17) . .
C10 C11 Fe 72.11(16) . .
C12 C11 H11 129(2) . .
C10 C11 H11 122(2) . .
Fe C11 H11 122(2) . .
C11 C12 C13 107.5(3) . .
C11 C12 Fe 68.94(17) . .
C13 C12 Fe 70.49(18) . .
C11 C12 H12 125(2) . .
C13 C12 H12 127(2) . .
Fe C12 H12 124(2) . .
C14 C13 C12 108.3(3) . .
C14 C13 Fe 71.09(17) . .
C12 C13 Fe 68.93(18) . .
C14 C13 H13 128(2) . .
C12 C13 H13 123(2) . .
Fe C13 H13 124(2) . .
C13 C14 C10 109.1(3) . .
C13 C14 Fe 69.00(17) . .
C10 C14 Fe 70.18(16) . .
C13 C14 H14 124(2) . .
C10 C14 H14 126(2) . .
Fe C14 H14 131(2) . .
C16 C15 C19 108.1(3) . .
C16 C15 C20 126.5(4) . .
C19 C15 C20 124.7(3) . .
C16 C15 Fe 69.55(19) . .
C19 C15 Fe 70.05(19) . .
C20 C15 Fe 119.0(2) . .
C17 C16 C15 107.1(3) . .
C17 C16 Fe 70.38(19) . .
C15 C16 Fe 69.30(19) . .
C17 C16 H16 126(2) . .
C15 C16 H16 127(2) . .
Fe C16 H16 127(2) . .
C18 C17 C16 108.7(3) . .
C18 C17 Fe 70.0(2) . .
C16 C17 Fe 69.20(19) . .
C18 C17 H17 125(3) . .
C16 C17 H17 127(3) . .
Fe C17 H17 126(3) . .
C19 C18 C17 108.8(3) . .
C19 C18 Fe 69.7(2) . .
C17 C18 Fe 69.8(2) . .
C19 C18 H18 124(3) . .
C17 C18 H18 127(3) . .
Fe C18 H18 122(3) . .
C18 C19 C15 107.3(3) . .
C18 C19 Fe 70.2(2) . .
C15 C19 Fe 68.9(2) . .
C18 C19 H19 126(2) . .
C15 C19 H19 126(2) . .
Fe C19 H19 129(2) . .
O1 C20 C15 125.3(4) . .
O1 C20 H20 118(2) . .
C15 C20 H20 116(2) . .
C1 C21 C9 126.0(2) 2_575 .
C1 C21 C22 117.2(2) 2_575 .
C9 C21 C22 116.8(2) . .
C23 C22 C27 117.8(3) . .
C23 C22 C21 120.8(3) . .
C27 C22 C21 121.4(3) . .
C22 C23 C24 121.1(3) . .
C22 C23 H23 118(3) . .
C24 C23 H23 121(3) . .
C25 C24 C23 121.2(3) . .
C25 C24 H24 118(3) . .
C23 C24 H24 120(3) . .
C24 C25 C26 117.9(3) . .
C24 C25 C28 120.9(4) . .
C26 C25 C28 121.2(4) . .
C25 C26 C27 121.0(3) . .
C25 C26 H26 118(2) . .
C27 C26 H26 121(2) . .
C22 C27 C26 121.0(3) . .
C22 C27 H27 117(2) . .
C26 C27 H27 122(2) . .
C25 C28 H28A 115(4) . .
C25 C28 H28B 112(4) . .
H28A C28 H28B 91(5) . .
C25 C28 H28C 111(4) . .
H28A C28 H28C 110(6) . .
H28B C28 H28C 116(6) . .
O2 C31 H31A 111(3) . .
O2 C31 H31B 111(2) . .
H31A C31 H31B 106(3) . .
O2 C31 H31C 107(3) . .
H31A C31 H31C 108(4) . .
H31B C31 H31C 113(4) . .
C31 O2 H2O 103(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn N1 2.044(2) 2_575
Zn N1 2.044(2) .
Zn N2 2.060(2) .
Zn N2 2.060(2) 2_575
Fe C11 2.023(3) .
Fe C15 2.037(3) .
Fe C12 2.038(3) .
Fe C16 2.040(3) .
Fe C19 2.053(4) .
Fe C17 2.056(3) .
Fe C13 2.059(3) .
Fe C18 2.058(3) .
Fe C14 2.086(3) .
Fe C10 2.092(3) .
N1 C4 1.374(4) .
N1 C1 1.381(3) .
N2 C9 1.376(3) .
N2 C6 1.379(4) .
C1 C21 1.399(4) 2_575
C1 C2 1.437(4) .
C2 C3 1.346(4) .
C2 H2 0.93(3) .
C3 C4 1.447(4) .
C3 H3 0.87(4) .
C4 C5 1.416(4) .
C5 C6 1.410(4) .
C5 C10 1.490(4) .
C6 C7 1.444(4) .
C7 C8 1.344(4) .
C7 H7 0.89(4) .
C8 C9 1.439(4) .
C8 H8 0.88(4) .
C9 C21 1.401(4) .
C10 C14 1.430(4) .
C10 C11 1.440(4) .
C11 C12 1.420(4) .
C11 H11 0.91(3) .
C12 C13 1.421(5) .
C12 H12 0.95(4) .
C13 C14 1.415(4) .
C13 H13 0.92(4) .
C14 H14 0.92(3) .
C15 C16 1.433(5) .
C15 C19 1.435(5) .
C15 C20 1.467(5) .
C16 C17 1.415(5) .
C16 H16 0.99(4) .
C17 C18 1.415(6) .
C17 H17 0.94(4) .
C18 C19 1.408(5) .
C18 H18 0.92(5) .
C19 H19 0.92(4) .
C20 O1 1.219(5) .
C20 H20 1.03(4) .
C21 C1 1.399(4) 2_575
C21 C22 1.502(4) .
C22 C23 1.383(4) .
C22 C27 1.386(4) .
C23 C24 1.384(5) .
C23 H23 0.86(4) .
C24 C25 1.379(5) .
C24 H24 0.88(4) .
C25 C26 1.385(5) .
C25 C28 1.510(4) .
C26 C27 1.387(4) .
C26 H26 0.81(3) .
C27 H27 0.91(4) .
C28 H28A 0.83(6) .
C28 H28B 0.83(6) .
C28 H28C 0.79(6) .
C31 O2 1.404(4) .
C31 H31A 0.94(5) .
C31 H31B 0.86(4) .
C31 H31C 0.86(5) .
O2 H2O 1.00(6) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2 H2O O1 1.00(6) 1.90(6) 2.881(4) 166(5) .
C14 H14 O2 0.92(3) 2.46(3) 3.185(4) 135(3) 1_655
