#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:15:23 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179960 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/54/7025457.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7025457
loop_
_publ_author_name
'Lin, Po-Heng'
'Leclère, Mathieu'
'Long, Jérôme'
'Burchell, Tara J.'
'Korobkov, Ilia'
'Clérac, Rodolphe'
'Murugesu, Muralee'
_publ_section_title
;
 Fluorescent dialdehyde ligand for the encapsulation of dinuclear
 luminescent lanthanide complexes.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              5698
_journal_page_last               5704
_journal_paper_doi               10.1039/c000978d
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C52 H36 Gd2 N2 O18'
_chemical_formula_weight         1291.33
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.7070(10)
_cell_angle_beta                 103.6610(10)
_cell_angle_gamma                101.4350(10)
_cell_formula_units_Z            1
_cell_length_a                   8.5998(2)
_cell_length_b                   12.0493(3)
_cell_length_c                   12.5679(3)
_cell_measurement_reflns_used    7313
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      28.19
_cell_measurement_theta_min      2.53
_cell_volume                     1190.69(5)
_computing_cell_refinement       'APEX II, Bruker (2009)'
_computing_data_collection       'APEX II, Bruker (2009)'
_computing_data_reduction        'XPREP, Bruker (2009)'
_computing_molecular_graphics    'SHELXTL, Bruker (2004)'
_computing_publication_material  'SHELXTL, Bruker (2004)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.969
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0286
_diffrn_reflns_av_sigmaI/netI    0.0415
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            13331
_diffrn_reflns_theta_full        28.27
_diffrn_reflns_theta_max         28.27
_diffrn_reflns_theta_min         1.74
_exptl_absorpt_coefficient_mu    2.842
_exptl_absorpt_correction_T_max  0.6751
_exptl_absorpt_correction_T_min  0.5736
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS, Bruker (2003)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.801
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             634
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.937
_refine_diff_density_min         -1.250
_refine_diff_density_rms         0.113
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.056
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         5734
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0381
_refine_ls_R_factor_gt           0.0301
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0275P)²+1.0975P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0649
_refine_ls_wR_factor_ref         0.0676
_reflns_number_gt                5056
_reflns_number_total             5734
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c000978d.txt
_cod_data_source_block           mm011
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7025457
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Gd1 Gd 0.16226(2) 0.155910(15) 0.059285(13) 0.02344(6) Uani 1 1 d .
O1 O 0.2538(3) 0.2207(2) 0.25476(19) 0.0305(5) Uani 1 1 d .
O2 O 0.4120(3) 0.3121(2) 0.1130(2) 0.0336(6) Uani 1 1 d .
O3 O 0.2857(4) 0.1873(3) 0.5715(2) 0.0601(9) Uani 1 1 d .
O4 O 0.0771(3) 0.2946(2) -0.0177(2) 0.0310(5) Uani 1 1 d .
O5 O -0.0826(3) 0.1833(2) 0.1125(2) 0.0351(6) Uani 1 1 d .
O6 O 0.0611(4) 0.4806(3) -0.2471(3) 0.0559(8) Uani 1 1 d .
O7 O 0.0617(3) -0.0239(2) 0.09516(18) 0.0249(5) Uani 1 1 d .
O8 O 0.3885(3) 0.0597(2) 0.1006(2) 0.0354(6) Uani 1 1 d .
O9 O -0.2438(3) -0.1249(2) 0.11726(19) 0.0325(5) Uani 1 1 d .
C1 C 0.3867(4) 0.2807(3) 0.3347(3) 0.0261(7) Uani 1 1 d .
C2 C 0.5172(4) 0.3611(3) 0.3158(3) 0.0292(7) Uani 1 1 d .
C3 C 0.6549(5) 0.4313(4) 0.4073(3) 0.0382(8) Uani 1 1 d .
H3A H 0.7382 0.4864 0.3936 0.046 Uiso 1 1 calc R
C4 C 0.6717(5) 0.4218(4) 0.5166(3) 0.0441(10) Uani 1 1 d .
H4A H 0.7664 0.4687 0.5776 0.053 Uiso 1 1 calc R
C5 C 0.5490(5) 0.3434(4) 0.5358(3) 0.0380(9) Uani 1 1 d .
H5A H 0.5608 0.3369 0.6112 0.046 Uiso 1 1 calc R
C6 C 0.4089(5) 0.2737(3) 0.4496(3) 0.0297(7) Uani 1 1 d .
C7 C 0.5171(5) 0.3707(3) 0.2044(3) 0.0329(8) Uani 1 1 d .
H7A H 0.6070 0.4279 0.2000 0.039 Uiso 1 1 calc R
C8 C 0.2835(5) 0.1920(3) 0.4757(3) 0.0362(8) Uani 1 1 d .
H8A H 0.1945 0.1392 0.4139 0.043 Uiso 1 1 calc R
C9 C -0.0585(4) 0.3243(3) -0.0507(3) 0.0280(7) Uani 1 1 d .
C10 C -0.1985(4) 0.2896(3) -0.0123(3) 0.0290(7) Uani 1 1 d .
C11 C -0.3445(5) 0.3226(4) -0.0518(3) 0.0407(9) Uani 1 1 d .
H11A H -0.4376 0.2977 -0.0263 0.049 Uiso 1 1 calc R
C12 C -0.3553(6) 0.3907(4) -0.1272(4) 0.0484(11) Uani 1 1 d .
H12A H -0.4545 0.4128 -0.1532 0.058 Uiso 1 1 calc R
C13 C -0.2193(5) 0.4259(4) -0.1642(3) 0.0400(9) Uani 1 1 d .
H13A H -0.2258 0.4741 -0.2148 0.048 Uiso 1 1 calc R
C14 C -0.0739(5) 0.3934(3) -0.1300(3) 0.0305(7) Uani 1 1 d .
C15 C -0.1968(5) 0.2226(3) 0.0701(3) 0.0343(8) Uani 1 1 d .
H15A H -0.2937 0.2072 0.0941 0.041 Uiso 1 1 calc R
C16 C 0.0639(5) 0.4287(3) -0.1746(3) 0.0401(9) Uani 1 1 d .
H16A H 0.1641 0.4096 -0.1444 0.048 Uiso 1 1 calc R
C17 C 0.1247(4) -0.0511(3) 0.1888(3) 0.0238(6) Uani 1 1 d .
C18 C 0.2971(4) -0.0392(3) 0.2292(3) 0.0285(7) Uani 1 1 d .
C19 C 0.3600(5) -0.0734(3) 0.3273(3) 0.0363(8) Uani 1 1 d .
H19A H 0.4748 -0.0697 0.3513 0.044 Uiso 1 1 calc R
C20 C 0.2596(5) -0.1120(4) 0.3892(3) 0.0398(9) Uani 1 1 d .
H20A H 0.3050 -0.1320 0.4568 0.048 Uiso 1 1 calc R
C21 C 0.0916(5) -0.1215(3) 0.3520(3) 0.0348(8) Uani 1 1 d .
H21A H 0.0226 -0.1459 0.3960 0.042 Uiso 1 1 calc R
C22 C 0.0208(4) -0.0959(3) 0.2507(3) 0.0273(7) Uani 1 1 d .
C23 C 0.4120(5) 0.0029(3) 0.1698(3) 0.0352(8) Uani 1 1 d .
H23A H 0.5160 -0.0154 0.1863 0.042 Uiso 1 1 calc R
C24 C -0.1577(5) -0.1168(3) 0.2130(3) 0.0318(8) Uani 1 1 d .
H24A H -0.2142 -0.1250 0.2684 0.038 Uiso 1 1 calc R
N1 N 0.2321(7) 0.8796(5) 0.6512(4) 0.0841(16) Uani 1 1 d .
C25 C 0.1384(6) 0.7938(5) 0.6372(4) 0.0509(11) Uani 1 1 d .
C26 C 0.0182(6) 0.6850(4) 0.6171(5) 0.0586(12) Uani 1 1 d .
H26A H -0.0293 0.6483 0.5348 0.088 Uiso 1 1 calc R
H26B H -0.0701 0.7002 0.6506 0.088 Uiso 1 1 calc R
H26C H 0.0717 0.6319 0.6522 0.088 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Gd1 O1 111.78(9) . .
O4 Gd1 O7 142.13(8) . .
O1 Gd1 O7 82.33(8) . .
O4 Gd1 O7 83.23(8) . 2
O1 Gd1 O7 142.07(8) . 2
O7 Gd1 O7 67.07(8) . 2
O4 Gd1 O2 76.80(9) . .
O1 Gd1 O2 72.16(8) . .
O7 Gd1 O2 140.35(8) . .
O7 Gd1 O2 145.55(8) 2 .
O4 Gd1 O5 72.42(8) . .
O1 Gd1 O5 76.20(9) . .
O7 Gd1 O5 77.72(8) . .
O7 Gd1 O5 75.82(8) 2 .
O2 Gd1 O5 122.71(9) . .
O4 Gd1 O9 77.17(8) . 2
O1 Gd1 O9 145.68(9) . 2
O7 Gd1 O9 111.46(8) . 2
O7 Gd1 O9 69.94(8) 2 2
O2 Gd1 O9 78.35(8) . 2
O5 Gd1 O9 136.24(8) . 2
O4 Gd1 O8 145.12(9) . .
O1 Gd1 O8 78.86(8) . .
O7 Gd1 O8 70.21(8) . .
O7 Gd1 O8 109.14(8) 2 .
O2 Gd1 O8 75.34(9) . .
O5 Gd1 O8 141.48(8) . .
O9 Gd1 O8 77.01(8) 2 .
O4 Gd1 Gd1 113.52(6) . 2
O1 Gd1 Gd1 113.38(6) . 2
O7 Gd1 Gd1 33.80(5) . 2
O7 Gd1 Gd1 33.28(5) 2 2
O2 Gd1 Gd1 163.08(6) . 2
O5 Gd1 Gd1 74.06(6) . 2
O9 Gd1 Gd1 90.62(6) 2 2
O8 Gd1 Gd1 89.78(6) . 2
C1 O1 Gd1 139.1(2) . .
C7 O2 Gd1 134.9(2) . .
C9 O4 Gd1 138.4(2) . .
C15 O5 Gd1 131.9(2) . .
C17 O7 Gd1 124.0(2) . .
C17 O7 Gd1 123.1(2) . 2
Gd1 O7 Gd1 112.93(8) . 2
C23 O8 Gd1 127.2(2) . .
C24 O9 Gd1 127.0(2) . 2
O1 C1 C2 122.5(3) . .
O1 C1 C6 121.1(3) . .
C2 C1 C6 116.4(3) . .
C3 C2 C7 117.2(3) . .
C3 C2 C1 120.6(3) . .
C7 C2 C1 122.2(3) . .
C4 C3 C2 121.2(4) . .
C3 C4 C5 118.9(4) . .
C4 C5 C6 122.4(3) . .
C5 C6 C1 120.4(3) . .
C5 C6 C8 119.7(3) . .
C1 C6 C8 119.9(3) . .
O2 C7 C2 126.8(3) . .
O3 C8 C6 124.1(4) . .
O4 C9 C10 122.3(3) . .
O4 C9 C14 120.4(3) . .
C10 C9 C14 117.2(3) . .
C11 C10 C9 120.4(3) . .
C11 C10 C15 117.2(3) . .
C9 C10 C15 122.4(3) . .
C12 C11 C10 121.2(4) . .
C11 C12 C13 118.9(4) . .
C14 C13 C12 122.2(4) . .
C13 C14 C9 120.1(3) . .
C13 C14 C16 120.3(3) . .
C9 C14 C16 119.6(3) . .
O5 C15 C10 126.8(3) . .
O6 C16 C14 125.3(4) . .
O7 C17 C18 121.0(3) . .
O7 C17 C22 120.7(3) . .
C18 C17 C22 118.3(3) . .
C19 C18 C17 119.7(3) . .
C19 C18 C23 118.2(3) . .
C17 C18 C23 122.0(3) . .
C20 C19 C18 121.6(4) . .
C19 C20 C21 119.2(3) . .
C20 C21 C22 121.5(3) . .
C21 C22 C17 119.6(3) . .
C21 C22 C24 118.1(3) . .
C17 C22 C24 122.4(3) . .
O8 C23 C18 126.6(3) . .
O9 C24 C22 127.0(3) . .
N1 C25 C26 178.8(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Gd1 O4 2.264(2) .
Gd1 O1 2.294(2) .
Gd1 O7 2.349(2) .
Gd1 O7 2.381(2) 2
Gd1 O2 2.401(2) .
Gd1 O5 2.415(3) .
Gd1 O9 2.455(2) 2
Gd1 O8 2.466(3) .
Gd1 Gd1 3.9422(3) 2
O1 C1 1.284(4) .
O2 C7 1.239(4) .
O3 C8 1.214(4) .
O4 C9 1.290(4) .
O5 C15 1.233(4) .
O6 C16 1.212(4) .
O7 C17 1.314(4) .
O7 Gd1 2.381(2) 2
O8 C23 1.224(4) .
O9 C24 1.227(4) .
O9 Gd1 2.455(2) 2
C1 C2 1.431(5) .
C1 C6 1.436(4) .
C2 C3 1.404(5) .
C2 C7 1.430(5) .
C3 C4 1.380(5) .
C4 C5 1.374(6) .
C5 C6 1.383(5) .
C6 C8 1.459(5) .
C9 C10 1.422(5) .
C9 C14 1.432(5) .
C10 C11 1.404(5) .
C10 C15 1.445(5) .
C11 C12 1.382(6) .
C12 C13 1.382(6) .
C13 C14 1.385(5) .
C14 C16 1.456(6) .
C17 C18 1.416(5) .
C17 C22 1.420(5) .
C18 C19 1.407(4) .
C18 C23 1.452(5) .
C19 C20 1.373(6) .
C20 C21 1.382(6) .
C21 C22 1.402(4) .
C22 C24 1.447(5) .
N1 C25 1.129(6) .
C25 C26 1.430(7) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O4 Gd1 O1 C1 -84.7(3) . .
O7 Gd1 O1 C1 131.8(3) . .
O7 Gd1 O1 C1 167.4(3) 2 .
O2 Gd1 O1 C1 -17.5(3) . .
O5 Gd1 O1 C1 -149.1(3) . .
O9 Gd1 O1 C1 14.5(4) 2 .
O8 Gd1 O1 C1 60.5(3) . .
Gd1 Gd1 O1 C1 145.4(3) 2 .
O4 Gd1 O2 C7 125.0(4) . .
O1 Gd1 O2 C7 6.6(3) . .
O7 Gd1 O2 C7 -45.9(4) . .
O7 Gd1 O2 C7 -178.8(3) 2 .
O5 Gd1 O2 C7 66.3(4) . .
O9 Gd1 O2 C7 -155.6(4) 2 .
O8 Gd1 O2 C7 -76.2(3) . .
Gd1 Gd1 O2 C7 -105.4(4) 2 .
O1 Gd1 O4 C9 -92.6(3) . .
O7 Gd1 O4 C9 13.7(4) . .
O7 Gd1 O4 C9 51.3(3) 2 .
O2 Gd1 O4 C9 -156.9(3) . .
O5 Gd1 O4 C9 -25.9(3) . .
O9 Gd1 O4 C9 122.2(3) 2 .
O8 Gd1 O4 C9 165.4(3) . .
Gd1 Gd1 O4 C9 37.2(3) 2 .
O4 Gd1 O5 C15 22.0(3) . .
O1 Gd1 O5 C15 140.6(3) . .
O7 Gd1 O5 C15 -134.4(3) . .
O7 Gd1 O5 C15 -65.3(3) 2 .
O2 Gd1 O5 C15 82.8(3) . .
O9 Gd1 O5 C15 -26.1(4) 2 .
O8 Gd1 O5 C15 -168.3(3) . .
Gd1 Gd1 O5 C15 -99.7(3) 2 .
O4 Gd1 O7 C17 -140.8(2) . .
O1 Gd1 O7 C17 -24.9(2) . .
O7 Gd1 O7 C17 178.0(3) 2 .
O2 Gd1 O7 C17 24.8(3) . .
O5 Gd1 O7 C17 -102.3(2) . .
O9 Gd1 O7 C17 122.5(2) 2 .
O8 Gd1 O7 C17 56.0(2) . .
Gd1 Gd1 O7 C17 178.0(3) 2 .
O4 Gd1 O7 Gd1 41.19(18) . 2
O1 Gd1 O7 Gd1 157.09(11) . 2
O7 Gd1 O7 Gd1 0.0 2 2
O2 Gd1 O7 Gd1 -153.22(10) . 2
O5 Gd1 O7 Gd1 79.62(10) . 2
O9 Gd1 O7 Gd1 -55.50(11) 2 2
O8 Gd1 O7 Gd1 -122.04(11) . 2
O4 Gd1 O8 C23 160.9(3) . .
O1 Gd1 O8 C23 48.7(3) . .
O7 Gd1 O8 C23 -37.1(3) . .
O7 Gd1 O8 C23 -92.8(3) 2 .
O2 Gd1 O8 C23 122.9(3) . .
O5 Gd1 O8 C23 -1.7(4) . .
O9 Gd1 O8 C23 -155.9(3) 2 .
Gd1 Gd1 O8 C23 -65.3(3) 2 .
Gd1 O1 C1 C2 21.1(5) . .
Gd1 O1 C1 C6 -161.3(2) . .
O1 C1 C2 C3 175.4(3) . .
C6 C1 C2 C3 -2.3(5) . .
O1 C1 C2 C7 -7.1(5) . .
C6 C1 C2 C7 175.3(3) . .
C7 C2 C3 C4 -175.3(4) . .
C1 C2 C3 C4 2.4(6) . .
C2 C3 C4 C5 -1.2(6) . .
C3 C4 C5 C6 -0.1(6) . .
C4 C5 C6 C1 0.1(6) . .
C4 C5 C6 C8 179.8(4) . .
O1 C1 C6 C5 -176.6(3) . .
C2 C1 C6 C5 1.0(5) . .
O1 C1 C6 C8 3.7(5) . .
C2 C1 C6 C8 -178.7(3) . .
Gd1 O2 C7 C2 -1.0(6) . .
C3 C2 C7 O2 175.9(4) . .
C1 C2 C7 O2 -1.7(6) . .
C5 C6 C8 O3 6.6(6) . .
C1 C6 C8 O3 -173.7(4) . .
Gd1 O4 C9 C10 20.4(5) . .
Gd1 O4 C9 C14 -158.7(2) . .
O4 C9 C10 C11 -179.1(3) . .
C14 C9 C10 C11 0.1(5) . .
O4 C9 C10 C15 2.5(5) . .
C14 C9 C10 C15 -178.3(3) . .
C9 C10 C11 C12 -1.0(6) . .
C15 C10 C11 C12 177.5(4) . .
C10 C11 C12 C13 0.3(7) . .
C11 C12 C13 C14 1.3(7) . .
C12 C13 C14 C9 -2.2(6) . .
C12 C13 C14 C16 177.6(4) . .
O4 C9 C14 C13 -179.4(3) . .
C10 C9 C14 C13 1.4(5) . .
O4 C9 C14 C16 0.8(5) . .
C10 C9 C14 C16 -178.4(3) . .
Gd1 O5 C15 C10 -15.1(6) . .
C11 C10 C15 O5 178.1(4) . .
C9 C10 C15 O5 -3.5(6) . .
C13 C14 C16 O6 -4.7(6) . .
C9 C14 C16 O6 175.1(4) . .
Gd1 O7 C17 C18 -51.1(4) . .
Gd1 O7 C17 C18 126.7(3) 2 .
Gd1 O7 C17 C22 130.5(3) . .
Gd1 O7 C17 C22 -51.7(4) 2 .
O7 C17 C18 C19 -177.5(3) . .
C22 C17 C18 C19 1.0(5) . .
O7 C17 C18 C23 -0.1(5) . .
C22 C17 C18 C23 178.4(3) . .
C17 C18 C19 C20 -3.8(6) . .
C23 C18 C19 C20 178.7(4) . .
C18 C19 C20 C21 2.3(6) . .
C19 C20 C21 C22 1.9(6) . .
C20 C21 C22 C17 -4.6(5) . .
C20 C21 C22 C24 175.3(3) . .
O7 C17 C22 C21 -178.4(3) . .
C18 C17 C22 C21 3.1(5) . .
O7 C17 C22 C24 1.7(5) . .
C18 C17 C22 C24 -176.8(3) . .
Gd1 O8 C23 C18 11.9(5) . .
C19 C18 C23 O8 -162.5(4) . .
C17 C18 C23 O8 20.0(6) . .
Gd1 O9 C24 C22 15.6(5) 2 .
C21 C22 C24 O9 -162.6(4) . .
C17 C22 C24 O9 17.2(6) . .
