#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:15:23 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179960 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/54/7025460.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7025460
loop_
_publ_author_name
'Uhl, Werner'
'Voss, Matthias'
'Layh, Marcus'
'Rogel, Friedhelm'
_publ_section_title
;
 Gallium-gallium bonds as efficient templates for the generation of a
 large cage containing twelve gallium atoms.
;
_journal_issue                   13
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              3160
_journal_page_last               3162
_journal_paper_doi               10.1039/c001032b
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C130 H254 Ga12 N18 O13 Si24'
_chemical_formula_weight         3788.31
_chemical_name_systematic
;
?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 105.759(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   21.602(2)
_cell_length_b                   39.935(4)
_cell_length_c                   31.387(3)
_cell_measurement_reflns_used    9950
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      21.676
_cell_measurement_theta_min      2.149
_cell_volume                     26059(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0686
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -25
_diffrn_reflns_limit_k_max       46
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            21720
_diffrn_reflns_theta_full        24.51
_diffrn_reflns_theta_max         24.51
_diffrn_reflns_theta_min         1.02
_exptl_absorpt_coefficient_mu    1.367
_exptl_absorpt_correction_T_max  0.8985
_exptl_absorpt_correction_T_min  0.8212
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    0.966
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       octahedral
_exptl_crystal_F_000             7888
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_platon_squeeze_details
;
Structure contains disordered thf molecules. A treatment of platon
squeeze accounted for 3043 electrons, which results in 9.5 thf
molecules per asymmetric unit (76 per unit cell).
;
_refine_diff_density_max         0.486
_refine_diff_density_min         -0.522
_refine_diff_density_rms         0.066
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.846
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     921
_refine_ls_number_reflns         21720
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      0.847
_refine_ls_R_factor_all          0.0573
_refine_ls_R_factor_gt           0.0372
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0444P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0791
_refine_ls_wR_factor_ref         0.0830
_reflns_number_gt                14035
_reflns_number_total             21720
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c001032b.txt
_cod_data_source_block           squeezed
_cod_original_cell_volume        26060(5)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7025460
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ga1 Ga 0.460178(16) 0.239967(9) 0.645804(11) 0.02809(9) Uani 1 1 d . . .
C1 C 0.48863(15) 0.22480(8) 0.59476(10) 0.0345(8) Uani 1 1 d . . .
H1 H 0.5300 0.2349 0.5980 0.041 Uiso 1 1 calc R . .
Si11 Si 0.50334(5) 0.17867(3) 0.59960(3) 0.0439(3) Uani 1 1 d . . .
C111 C 0.54746(18) 0.16793(10) 0.65790(11) 0.0535(11) Uani 1 1 d . . .
H11A H 0.5894 0.1780 0.6651 0.064 Uiso 1 1 calc R . .
H11B H 0.5517 0.1441 0.6609 0.064 Uiso 1 1 calc R . .
H11C H 0.5239 0.1762 0.6776 0.064 Uiso 1 1 calc R . .
C112 C 0.5545(2) 0.16388(11) 0.56386(13) 0.0694(13) Uani 1 1 d . . .
H11D H 0.5292 0.1632 0.5336 0.083 Uiso 1 1 calc R . .
H11E H 0.5705 0.1419 0.5730 0.083 Uiso 1 1 calc R . .
H11F H 0.5900 0.1790 0.5667 0.083 Uiso 1 1 calc R . .
C113 C 0.42535(19) 0.15532(9) 0.58471(13) 0.0622(12) Uani 1 1 d . . .
H11G H 0.3982 0.1636 0.6021 0.075 Uiso 1 1 calc R . .
H11H H 0.4334 0.1319 0.5906 0.075 Uiso 1 1 calc R . .
H11I H 0.4043 0.1585 0.5538 0.075 Uiso 1 1 calc R . .
Si12 Si 0.43606(5) 0.24078(3) 0.54087(3) 0.0452(3) Uani 1 1 d . . .
C121 C 0.4457(2) 0.21620(11) 0.49180(12) 0.0728(14) Uani 1 1 d . . .
H12A H 0.4899 0.2167 0.4913 0.087 Uiso 1 1 calc R . .
H12B H 0.4193 0.2259 0.4650 0.087 Uiso 1 1 calc R . .
H12C H 0.4327 0.1934 0.4941 0.087 Uiso 1 1 calc R . .
C122 C 0.4590(2) 0.28522(10) 0.53207(13) 0.0661(13) Uani 1 1 d . . .
H12D H 0.4548 0.2989 0.5563 0.079 Uiso 1 1 calc R . .
H12E H 0.4312 0.2936 0.5049 0.079 Uiso 1 1 calc R . .
H12F H 0.5028 0.2858 0.5305 0.079 Uiso 1 1 calc R . .
C123 C 0.34925(17) 0.23921(10) 0.54056(13) 0.0612(12) Uani 1 1 d . . .
H12G H 0.3390 0.2172 0.5487 0.073 Uiso 1 1 calc R . .
H12H H 0.3228 0.2444 0.5114 0.073 Uiso 1 1 calc R . .
H12I H 0.3415 0.2552 0.5613 0.073 Uiso 1 1 calc R . .
Ga2 Ga 0.370124(16) 0.232786(9) 0.676501(11) 0.02910(9) Uani 1 1 d . . .
C2 C 0.29559(15) 0.20245(8) 0.66286(11) 0.0386(9) Uani 1 1 d . . .
H2 H 0.2945 0.1946 0.6338 0.046 Uiso 1 1 calc R . .
Si21 Si 0.21335(5) 0.22001(3) 0.65468(4) 0.0579(3) Uani 1 1 d . . .
C211 C 0.2035(2) 0.24106(13) 0.70595(17) 0.0991(19) Uani 1 1 d . . .
H21A H 0.1862 0.2254 0.7228 0.119 Uiso 1 1 calc R . .
H21B H 0.1747 0.2597 0.6977 0.119 Uiso 1 1 calc R . .
H21C H 0.2446 0.2488 0.7235 0.119 Uiso 1 1 calc R . .
C212 C 0.1956(2) 0.25039(13) 0.60912(18) 0.110(2) Uani 1 1 d . . .
H21D H 0.2262 0.2684 0.6160 0.132 Uiso 1 1 calc R . .
H21E H 0.1530 0.2592 0.6051 0.132 Uiso 1 1 calc R . .
H21F H 0.1982 0.2395 0.5824 0.132 Uiso 1 1 calc R . .
C213 C 0.15009(19) 0.18675(12) 0.63988(17) 0.0892(17) Uani 1 1 d . . .
H21G H 0.1086 0.1970 0.6294 0.107 Uiso 1 1 calc R . .
H21H H 0.1513 0.1734 0.6656 0.107 Uiso 1 1 calc R . .
H21I H 0.1580 0.1727 0.6171 0.107 Uiso 1 1 calc R . .
Si22 Si 0.31703(6) 0.16356(3) 0.69720(4) 0.0555(3) Uani 1 1 d . . .
C221 C 0.40528(19) 0.15674(10) 0.71441(13) 0.0656(13) Uani 1 1 d . . .
H22A H 0.4261 0.1761 0.7301 0.079 Uiso 1 1 calc R . .
H22B H 0.4203 0.1531 0.6887 0.079 Uiso 1 1 calc R . .
H22C H 0.4150 0.1375 0.7333 0.079 Uiso 1 1 calc R . .
C222 C 0.2813(2) 0.12537(11) 0.66496(18) 0.103(2) Uani 1 1 d . . .
H22D H 0.2885 0.1261 0.6361 0.124 Uiso 1 1 calc R . .
H22E H 0.2359 0.1248 0.6620 0.124 Uiso 1 1 calc R . .
H22F H 0.3011 0.1057 0.6803 0.124 Uiso 1 1 calc R . .
C223 C 0.2902(2) 0.16733(13) 0.74874(14) 0.0886(16) Uani 1 1 d . . .
H22G H 0.3096 0.1499 0.7690 0.106 Uiso 1 1 calc R . .
H22H H 0.2442 0.1653 0.7415 0.106 Uiso 1 1 calc R . .
H22I H 0.3029 0.1887 0.7622 0.106 Uiso 1 1 calc R . .
O1 O 0.43182(10) 0.28859(5) 0.63318(7) 0.0300(5) Uani 1 1 d . . .
O2 O 0.34201(9) 0.27933(5) 0.65452(7) 0.0283(5) Uani 1 1 d . . .
C11 C 0.37926(15) 0.29801(8) 0.64005(10) 0.0260(7) Uani 1 1 d . . .
C12 C 0.36000(14) 0.33370(8) 0.63150(10) 0.0271(7) Uani 1 1 d . . .
C13 C 0.39863(15) 0.35626(8) 0.61502(10) 0.0324(8) Uani 1 1 d . . .
H13 H 0.4366 0.3480 0.6083 0.039 Uiso 1 1 calc R . .
C14 C 0.38363(15) 0.38941(8) 0.60845(10) 0.0317(8) Uani 1 1 d . . .
H14 H 0.4088 0.4043 0.5959 0.038 Uiso 1 1 calc R . .
C15 C 0.32953(14) 0.40054(8) 0.62105(10) 0.0267(7) Uani 1 1 d . . .
C16 C 0.29201(14) 0.37871(8) 0.63805(10) 0.0258(7) Uani 1 1 d . . .
C17 C 0.30575(14) 0.34474(8) 0.64247(10) 0.0278(8) Uani 1 1 d . . .
H17 H 0.2786 0.3295 0.6528 0.033 Uiso 1 1 calc R . .
N11 N 0.24522(11) 0.39768(6) 0.64870(8) 0.0261(6) Uani 1 1 d . . .
N12 N 0.25314(12) 0.42937(6) 0.63868(8) 0.0270(6) Uani 1 1 d . . .
N13 N 0.30332(12) 0.43176(6) 0.62161(8) 0.0276(6) Uani 1 1 d . . .
Ga3 Ga 0.182803(15) 0.387565(9) 0.685782(11) 0.02703(9) Uani 1 1 d . . .
C3 C 0.10930(14) 0.36247(8) 0.64792(10) 0.0322(8) Uani 1 1 d . . .
H3 H 0.1276 0.3425 0.6394 0.039 Uiso 1 1 calc R . .
Si31 Si 0.05526(4) 0.34774(3) 0.68149(3) 0.0401(3) Uani 1 1 d . . .
C311 C 0.00607(17) 0.38372(10) 0.69141(12) 0.0536(11) Uani 1 1 d . . .
H31A H 0.0339 0.4007 0.7079 0.064 Uiso 1 1 calc R . .
H31B H -0.0229 0.3762 0.7078 0.064 Uiso 1 1 calc R . .
H31C H -0.0182 0.3928 0.6635 0.064 Uiso 1 1 calc R . .
C312 C 0.0013(2) 0.31293(11) 0.65329(14) 0.0709(13) Uani 1 1 d . . .
H31D H -0.0301 0.3216 0.6279 0.085 Uiso 1 1 calc R . .
H31E H -0.0201 0.3033 0.6735 0.085 Uiso 1 1 calc R . .
H31F H 0.0265 0.2960 0.6440 0.085 Uiso 1 1 calc R . .
C313 C 0.10203(17) 0.33115(9) 0.73624(12) 0.0491(10) Uani 1 1 d . . .
H31G H 0.1306 0.3138 0.7319 0.059 Uiso 1 1 calc R . .
H31H H 0.0730 0.3221 0.7516 0.059 Uiso 1 1 calc R . .
H31I H 0.1266 0.3489 0.7534 0.059 Uiso 1 1 calc R . .
Si32 Si 0.07270(5) 0.38512(3) 0.59517(3) 0.0398(3) Uani 1 1 d . . .
C321 C 0.12193(17) 0.37784(10) 0.55611(12) 0.0516(10) Uani 1 1 d . . .
H32A H 0.1642 0.3870 0.5682 0.062 Uiso 1 1 calc R . .
H32B H 0.1020 0.3885 0.5284 0.062 Uiso 1 1 calc R . .
H32C H 0.1252 0.3542 0.5515 0.062 Uiso 1 1 calc R . .
C322 C -0.01095(17) 0.37094(11) 0.56601(12) 0.0591(12) Uani 1 1 d . . .
H32D H -0.0104 0.3475 0.5591 0.071 Uiso 1 1 calc R . .
H32E H -0.0266 0.3835 0.5391 0.071 Uiso 1 1 calc R . .
H32F H -0.0387 0.3745 0.5848 0.071 Uiso 1 1 calc R . .
C323 C 0.06887(18) 0.43074(9) 0.60664(12) 0.0532(11) Uani 1 1 d . . .
H32G H 0.0430 0.4342 0.6268 0.064 Uiso 1 1 calc R . .
H32H H 0.0501 0.4424 0.5795 0.064 Uiso 1 1 calc R . .
H32I H 0.1115 0.4391 0.6196 0.064 Uiso 1 1 calc R . .
Ga4 Ga 0.216293(15) 0.418457(9) 0.754510(11) 0.02779(9) Uani 1 1 d . . .
C4 C 0.16889(15) 0.42929(8) 0.79870(11) 0.0351(8) Uani 1 1 d . . .
H4 H 0.1292 0.4175 0.7870 0.042 Uiso 1 1 calc R . .
Si41 Si 0.19756(5) 0.41108(3) 0.85542(3) 0.0435(3) Uani 1 1 d . . .
C411 C 0.18716(19) 0.36481(10) 0.85407(13) 0.0577(11) Uani 1 1 d . . .
H41A H 0.1426 0.3594 0.8414 0.069 Uiso 1 1 calc R . .
H41B H 0.2010 0.3561 0.8837 0.069 Uiso 1 1 calc R . .
H41C H 0.2125 0.3550 0.8365 0.069 Uiso 1 1 calc R . .
C412 C 0.15266(18) 0.42764(11) 0.89441(12) 0.0587(12) Uani 1 1 d . . .
H41D H 0.1589 0.4514 0.8976 0.070 Uiso 1 1 calc R . .
H41E H 0.1684 0.4171 0.9228 0.070 Uiso 1 1 calc R . .
H41F H 0.1076 0.4229 0.8828 0.070 Uiso 1 1 calc R . .
C413 C 0.28458(17) 0.41925(11) 0.88229(12) 0.0621(12) Uani 1 1 d . . .
H41G H 0.3103 0.4043 0.8703 0.075 Uiso 1 1 calc R . .
H41H H 0.2935 0.4157 0.9136 0.075 Uiso 1 1 calc R . .
H41I H 0.2947 0.4420 0.8768 0.075 Uiso 1 1 calc R . .
Si42 Si 0.14188(6) 0.47380(3) 0.79211(4) 0.0525(3) Uani 1 1 d . . .
C421 C 0.12043(18) 0.48535(10) 0.73235(13) 0.0591(11) Uani 1 1 d . . .
H42A H 0.1587 0.4861 0.7224 0.071 Uiso 1 1 calc R . .
H42B H 0.1002 0.5070 0.7284 0.071 Uiso 1 1 calc R . .
H42C H 0.0913 0.4690 0.7155 0.071 Uiso 1 1 calc R . .
C422 C 0.0674(2) 0.48052(13) 0.81159(17) 0.0957(18) Uani 1 1 d . . .
H42D H 0.0367 0.4632 0.7998 0.115 Uiso 1 1 calc R . .
H42E H 0.0491 0.5019 0.8015 0.115 Uiso 1 1 calc R . .
H42F H 0.0787 0.4798 0.8433 0.115 Uiso 1 1 calc R . .
C423 C 0.2072(2) 0.50247(10) 0.82301(14) 0.0735(14) Uani 1 1 d . . .
H42G H 0.2182 0.4971 0.8540 0.088 Uiso 1 1 calc R . .
H42H H 0.1925 0.5252 0.8188 0.088 Uiso 1 1 calc R . .
H42I H 0.2444 0.4998 0.8121 0.088 Uiso 1 1 calc R . .
O3 O 0.24115(9) 0.35071(5) 0.71739(7) 0.0290(5) Uani 1 1 d . . .
O4 O 0.27943(9) 0.38117(5) 0.77915(7) 0.0304(5) Uani 1 1 d . . .
C21 C 0.27888(14) 0.35535(8) 0.75594(10) 0.0266(8) Uani 1 1 d . . .
C22 C 0.32654(14) 0.32811(8) 0.77295(10) 0.0272(8) Uani 1 1 d . . .
C23 C 0.36935(14) 0.33020(8) 0.81630(10) 0.0319(8) Uani 1 1 d . . .
H23 H 0.3658 0.3487 0.8351 0.038 Uiso 1 1 calc R . .
C24 C 0.41569(15) 0.30624(8) 0.83167(10) 0.0321(8) Uani 1 1 d . . .
H24 H 0.4441 0.3073 0.8611 0.039 Uiso 1 1 calc R . .
C25 C 0.41974(14) 0.28041(8) 0.80293(10) 0.0259(7) Uani 1 1 d . . .
C26 C 0.37667(14) 0.27793(8) 0.76070(10) 0.0262(7) Uani 1 1 d . . .
C27 C 0.32934(14) 0.30189(8) 0.74556(10) 0.0285(8) Uani 1 1 d . . .
H27 H 0.2995 0.3001 0.7168 0.034 Uiso 1 1 calc R . .
N21 N 0.45977(12) 0.25345(6) 0.80673(8) 0.0279(6) Uani 1 1 d . . .
N22 N 0.44395(12) 0.23561(6) 0.76944(8) 0.0282(6) Uani 1 1 d . . .
N23 N 0.39374(12) 0.24976(6) 0.74105(8) 0.0283(6) Uani 1 1 d . . .
Ga5 Ga 0.334112(16) 0.516839(9) 0.665549(12) 0.02980(9) Uani 1 1 d . . .
C5 C 0.30756(15) 0.56386(8) 0.66398(12) 0.0390(9) Uani 1 1 d . . .
H5 H 0.3001 0.5691 0.6331 0.047 Uiso 1 1 calc R . .
Si51 Si 0.22392(5) 0.56592(3) 0.67075(4) 0.0451(3) Uani 1 1 d . . .
C511 C 0.17620(16) 0.52891(9) 0.64351(12) 0.0482(10) Uani 1 1 d . . .
H51A H 0.1725 0.5294 0.6123 0.058 Uiso 1 1 calc R . .
H51B H 0.1341 0.5297 0.6481 0.058 Uiso 1 1 calc R . .
H51C H 0.1975 0.5087 0.6561 0.058 Uiso 1 1 calc R . .
C512 C 0.17874(19) 0.60341(10) 0.64192(16) 0.0738(14) Uani 1 1 d . . .
H51D H 0.2004 0.6235 0.6547 0.089 Uiso 1 1 calc R . .
H51E H 0.1359 0.6033 0.6453 0.089 Uiso 1 1 calc R . .
H51F H 0.1769 0.6026 0.6110 0.089 Uiso 1 1 calc R . .
C513 C 0.2256(2) 0.56648(11) 0.73035(13) 0.0659(12) Uani 1 1 d . . .
H51G H 0.2471 0.5468 0.7446 0.079 Uiso 1 1 calc R . .
H51H H 0.1823 0.5669 0.7330 0.079 Uiso 1 1 calc R . .
H51I H 0.2482 0.5860 0.7442 0.079 Uiso 1 1 calc R . .
Si52 Si 0.36706(5) 0.59653(3) 0.69025(4) 0.0573(3) Uani 1 1 d . . .
C521 C 0.4346(2) 0.59702(11) 0.66477(19) 0.0979(19) Uani 1 1 d . . .
H52A H 0.4594 0.5769 0.6726 0.117 Uiso 1 1 calc R . .
H52B H 0.4614 0.6161 0.6753 0.117 Uiso 1 1 calc R . .
H52C H 0.4181 0.5983 0.6332 0.117 Uiso 1 1 calc R . .
C522 C 0.3327(2) 0.63938(10) 0.68379(17) 0.0808(15) Uani 1 1 d . . .
H52D H 0.3091 0.6429 0.6535 0.097 Uiso 1 1 calc R . .
H52E H 0.3668 0.6555 0.6921 0.097 Uiso 1 1 calc R . .
H52F H 0.3044 0.6419 0.7024 0.097 Uiso 1 1 calc R . .
C523 C 0.3987(3) 0.58875(13) 0.75060(17) 0.117(2) Uani 1 1 d . . .
H52G H 0.4284 0.6062 0.7637 0.141 Uiso 1 1 calc R . .
H52H H 0.4204 0.5675 0.7553 0.141 Uiso 1 1 calc R . .
H52I H 0.3638 0.5885 0.7640 0.141 Uiso 1 1 calc R . .
Ga6 Ga 0.327943(16) 0.477847(9) 0.606234(12) 0.02740(9) Uani 1 1 d . . .
C6 C 0.31453(15) 0.47877(8) 0.54165(10) 0.0337(8) Uani 1 1 d . . .
H6 H 0.3186 0.4560 0.5330 0.040 Uiso 1 1 calc R . .
Si61 Si 0.38067(5) 0.50244(3) 0.52711(4) 0.0520(3) Uani 1 1 d . . .
C611 C 0.45305(19) 0.47471(12) 0.53594(14) 0.0789(15) Uani 1 1 d . . .
H61A H 0.4643 0.4662 0.5657 0.095 Uiso 1 1 calc R . .
H61B H 0.4884 0.4874 0.5312 0.095 Uiso 1 1 calc R . .
H61C H 0.4435 0.4564 0.5154 0.095 Uiso 1 1 calc R . .
C612 C 0.3999(2) 0.54089(11) 0.56181(14) 0.0752(14) Uani 1 1 d . . .
H61D H 0.3625 0.5550 0.5562 0.090 Uiso 1 1 calc R . .
H61E H 0.4343 0.5528 0.5546 0.090 Uiso 1 1 calc R . .
H61F H 0.4128 0.5347 0.5925 0.090 Uiso 1 1 calc R . .
C613 C 0.3593(2) 0.51652(12) 0.46778(13) 0.0798(15) Uani 1 1 d . . .
H61G H 0.3483 0.4974 0.4487 0.096 Uiso 1 1 calc R . .
H61H H 0.3953 0.5279 0.4620 0.096 Uiso 1 1 calc R . .
H61I H 0.3232 0.5315 0.4623 0.096 Uiso 1 1 calc R . .
Si62 Si 0.23015(5) 0.49149(3) 0.51343(3) 0.0424(3) Uani 1 1 d . . .
C621 C 0.21900(19) 0.53747(9) 0.51854(13) 0.0598(12) Uani 1 1 d . . .
H62A H 0.2331 0.5438 0.5491 0.072 Uiso 1 1 calc R . .
H62B H 0.1743 0.5430 0.5069 0.072 Uiso 1 1 calc R . .
H62C H 0.2438 0.5493 0.5022 0.072 Uiso 1 1 calc R . .
C622 C 0.17287(16) 0.47000(10) 0.53922(12) 0.0552(11) Uani 1 1 d . . .
H62D H 0.1759 0.4462 0.5358 0.066 Uiso 1 1 calc R . .
H62E H 0.1298 0.4773 0.5250 0.066 Uiso 1 1 calc R . .
H62F H 0.1833 0.4755 0.5701 0.066 Uiso 1 1 calc R . .
C623 C 0.2069(2) 0.47946(11) 0.45339(12) 0.0685(13) Uani 1 1 d . . .
H62G H 0.2343 0.4908 0.4386 0.082 Uiso 1 1 calc R . .
H62H H 0.1630 0.4858 0.4401 0.082 Uiso 1 1 calc R . .
H62I H 0.2114 0.4557 0.4508 0.082 Uiso 1 1 calc R . .
O5 O 0.43189(9) 0.51033(5) 0.68272(7) 0.0299(5) Uani 1 1 d . . .
O6 O 0.42273(9) 0.46828(5) 0.63341(7) 0.0297(5) Uani 1 1 d . . .
C31 C 0.45419(14) 0.48574(8) 0.66578(11) 0.0287(8) Uani 1 1 d . . .
C32 C 0.52394(14) 0.47622(8) 0.68563(10) 0.0283(8) Uani 1 1 d . . .
C33 C 0.54974(14) 0.44949(8) 0.66635(10) 0.0325(8) Uani 1 1 d . . .
H33 H 0.5231 0.4385 0.6407 0.039 Uiso 1 1 calc R . .
C34 C 0.61175(14) 0.43896(8) 0.68342(11) 0.0331(8) Uani 1 1 d . . .
H34 H 0.6293 0.4209 0.6703 0.040 Uiso 1 1 calc R . .
C35 C 0.64865(14) 0.45578(8) 0.72098(10) 0.0271(8) Uani 1 1 d . . .
C36 C 0.62276(14) 0.48163(8) 0.74051(10) 0.0270(7) Uani 1 1 d . . .
C37 C 0.55942(14) 0.49271(8) 0.72233(10) 0.0273(8) Uani 1 1 d . . .
H37 H 0.5418 0.5110 0.7351 0.033 Uiso 1 1 calc R . .
N31 N 0.71132(11) 0.45150(7) 0.74641(8) 0.0286(6) Uani 1 1 d . . .
N32 N 0.72254(11) 0.47298(7) 0.78034(9) 0.0298(6) Uani 1 1 d . . .
N33 N 0.67033(12) 0.49152(6) 0.77760(8) 0.0287(6) Uani 1 1 d . . .
O91 O 0.4375(4) 0.3778(2) 0.7378(3) 0.100(2) Uiso 0.50 1 d PD A -1
C911 C 0.4774(4) 0.4090(2) 0.7381(4) 0.059(3) Uiso 0.50 1 d PD A -1
H91A H 0.4819 0.4141 0.7092 0.070 Uiso 0.50 1 calc PR A -1
H91B H 0.4599 0.4280 0.7495 0.070 Uiso 0.50 1 calc PR A -1
C912 C 0.5359(9) 0.3982(4) 0.7673(6) 0.148(7) Uiso 0.50 1 d PD A -1
H91C H 0.5376 0.4049 0.7970 0.177 Uiso 0.50 1 calc PR A -1
H91D H 0.5713 0.4085 0.7593 0.177 Uiso 0.50 1 calc PR A -1
C913 C 0.5418(8) 0.3587(4) 0.7651(6) 0.128(6) Uiso 0.50 1 d PD A -1
H91E H 0.5756 0.3524 0.7521 0.153 Uiso 0.50 1 calc PR A -1
H91F H 0.5502 0.3490 0.7940 0.153 Uiso 0.50 1 calc PR A -1
C914 C 0.4798(5) 0.3483(3) 0.7375(4) 0.088(4) Uiso 0.50 1 d PD A -1
H91G H 0.4646 0.3289 0.7496 0.105 Uiso 0.50 1 calc PR A -1
H91H H 0.4820 0.3433 0.7080 0.105 Uiso 0.50 1 calc PR A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ga1 N21 106.78(12) . 2_656
C1 Ga1 O1 106.21(11) . .
N21 Ga1 O1 92.36(9) 2_656 .
C1 Ga1 Ga2 139.08(10) . .
N21 Ga1 Ga2 110.98(7) 2_656 .
O1 Ga1 Ga2 87.62(6) . .
Si11 C1 Si12 117.19(17) . .
Si11 C1 Ga1 108.79(16) . .
Si12 C1 Ga1 112.61(16) . .
Si11 C1 H1 105.8 . .
Si12 C1 H1 105.8 . .
Ga1 C1 H1 105.8 . .
C1 Si11 C111 109.63(16) . .
C1 Si11 C113 110.45(16) . .
C111 Si11 C113 108.38(19) . .
C1 Si11 C112 112.18(18) . .
C111 Si11 C112 106.71(18) . .
C113 Si11 C112 109.4(2) . .
Si11 C111 H11A 109.5 . .
Si11 C111 H11B 109.5 . .
H11A C111 H11B 109.5 . .
Si11 C111 H11C 109.5 . .
H11A C111 H11C 109.5 . .
H11B C111 H11C 109.5 . .
Si11 C112 H11D 109.5 . .
Si11 C112 H11E 109.5 . .
H11D C112 H11E 109.5 . .
Si11 C112 H11F 109.5 . .
H11D C112 H11F 109.5 . .
H11E C112 H11F 109.5 . .
Si11 C113 H11G 109.5 . .
Si11 C113 H11H 109.5 . .
H11G C113 H11H 109.5 . .
Si11 C113 H11I 109.5 . .
H11G C113 H11I 109.5 . .
H11H C113 H11I 109.5 . .
C123 Si12 C1 110.71(17) . .
C123 Si12 C122 109.52(19) . .
C1 Si12 C122 109.51(17) . .
C123 Si12 C121 108.1(2) . .
C1 Si12 C121 112.69(16) . .
C122 Si12 C121 106.2(2) . .
Si12 C121 H12A 109.5 . .
Si12 C121 H12B 109.5 . .
H12A C121 H12B 109.5 . .
Si12 C121 H12C 109.5 . .
H12A C121 H12C 109.5 . .
H12B C121 H12C 109.5 . .
Si12 C122 H12D 109.5 . .
Si12 C122 H12E 109.5 . .
H12D C122 H12E 109.5 . .
Si12 C122 H12F 109.5 . .
H12D C122 H12F 109.5 . .
H12E C122 H12F 109.5 . .
Si12 C123 H12G 109.5 . .
Si12 C123 H12H 109.5 . .
H12G C123 H12H 109.5 . .
Si12 C123 H12I 109.5 . .
H12G C123 H12I 109.5 . .
H12H C123 H12I 109.5 . .
C2 Ga2 O2 109.90(11) . .
C2 Ga2 N23 112.66(12) . .
O2 Ga2 N23 90.24(9) . .
C2 Ga2 Ga1 133.47(10) . .
O2 Ga2 Ga1 87.39(6) . .
N23 Ga2 Ga1 109.99(7) . .
Si21 C2 Si22 117.95(18) . .
Si21 C2 Ga2 119.49(18) . .
Si22 C2 Ga2 108.97(16) . .
Si21 C2 H2 102.4 . .
Si22 C2 H2 102.4 . .
Ga2 C2 H2 102.4 . .
C212 Si21 C2 110.3(2) . .
C212 Si21 C213 107.0(2) . .
C2 Si21 C213 111.85(19) . .
C212 Si21 C211 108.9(3) . .
C2 Si21 C211 112.11(19) . .
C213 Si21 C211 106.6(2) . .
Si21 C211 H21A 109.5 . .
Si21 C211 H21B 109.5 . .
H21A C211 H21B 109.5 . .
Si21 C211 H21C 109.5 . .
H21A C211 H21C 109.5 . .
H21B C211 H21C 109.5 . .
Si21 C212 H21D 109.5 . .
Si21 C212 H21E 109.5 . .
H21D C212 H21E 109.5 . .
Si21 C212 H21F 109.5 . .
H21D C212 H21F 109.5 . .
H21E C212 H21F 109.5 . .
Si21 C213 H21G 109.5 . .
Si21 C213 H21H 109.5 . .
H21G C213 H21H 109.5 . .
Si21 C213 H21I 109.5 . .
H21G C213 H21I 109.5 . .
H21H C213 H21I 109.5 . .
C221 Si22 C223 107.2(2) . .
C221 Si22 C2 111.27(17) . .
C223 Si22 C2 110.2(2) . .
C221 Si22 C222 106.1(2) . .
C223 Si22 C222 110.7(2) . .
C2 Si22 C222 111.21(19) . .
Si22 C221 H22A 109.5 . .
Si22 C221 H22B 109.5 . .
H22A C221 H22B 109.5 . .
Si22 C221 H22C 109.5 . .
H22A C221 H22C 109.5 . .
H22B C221 H22C 109.5 . .
Si22 C222 H22D 109.5 . .
Si22 C222 H22E 109.5 . .
H22D C222 H22E 109.5 . .
Si22 C222 H22F 109.5 . .
H22D C222 H22F 109.5 . .
H22E C222 H22F 109.5 . .
Si22 C223 H22G 109.5 . .
Si22 C223 H22H 109.5 . .
H22G C223 H22H 109.5 . .
Si22 C223 H22I 109.5 . .
H22G C223 H22I 109.5 . .
H22H C223 H22I 109.5 . .
C11 O1 Ga1 118.95(19) . .
C11 O2 Ga2 120.20(19) . .
O2 C11 O1 124.8(3) . .
O2 C11 C12 117.0(3) . .
O1 C11 C12 118.2(3) . .
C17 C12 C13 120.8(3) . .
C17 C12 C11 118.4(3) . .
C13 C12 C11 120.7(3) . .
C14 C13 C12 122.1(3) . .
C14 C13 H13 118.9 . .
C12 C13 H13 118.9 . .
C13 C14 C15 116.5(3) . .
C13 C14 H14 121.8 . .
C15 C14 H14 121.8 . .
N13 C15 C16 106.2(3) . .
N13 C15 C14 132.0(3) . .
C16 C15 C14 121.7(3) . .
N11 C16 C17 131.7(3) . .
N11 C16 C15 106.9(3) . .
C17 C16 C15 121.3(3) . .
C12 C17 C16 117.4(3) . .
C12 C17 H17 121.3 . .
C16 C17 H17 121.3 . .
N12 N11 C16 108.5(2) . .
N12 N11 Ga3 118.07(19) . .
C16 N11 Ga3 132.1(2) . .
N11 N12 N13 109.5(2) . .
N12 N13 C15 108.8(2) . .
N12 N13 Ga6 117.24(19) . .
C15 N13 Ga6 133.8(2) . .
C3 Ga3 O3 102.62(11) . .
C3 Ga3 N11 107.68(11) . .
O3 Ga3 N11 90.20(9) . .
C3 Ga3 Ga4 142.28(9) . .
O3 Ga3 Ga4 86.44(6) . .
N11 Ga3 Ga4 108.83(7) . .
Si32 C3 Si31 118.34(17) . .
Si32 C3 Ga3 111.43(16) . .
Si31 C3 Ga3 110.08(15) . .
Si32 C3 H3 105.3 . .
Si31 C3 H3 105.3 . .
Ga3 C3 H3 105.3 . .
C313 Si31 C311 108.14(17) . .
C313 Si31 C3 111.53(15) . .
C311 Si31 C3 108.89(16) . .
C313 Si31 C312 106.48(19) . .
C311 Si31 C312 109.94(19) . .
C3 Si31 C312 111.77(17) . .
Si31 C311 H31A 109.5 . .
Si31 C311 H31B 109.5 . .
H31A C311 H31B 109.5 . .
Si31 C311 H31C 109.5 . .
H31A C311 H31C 109.5 . .
H31B C311 H31C 109.5 . .
Si31 C312 H31D 109.5 . .
Si31 C312 H31E 109.5 . .
H31D C312 H31E 109.5 . .
Si31 C312 H31F 109.5 . .
H31D C312 H31F 109.5 . .
H31E C312 H31F 109.5 . .
Si31 C313 H31G 109.5 . .
Si31 C313 H31H 109.5 . .
H31G C313 H31H 109.5 . .
Si31 C313 H31I 109.5 . .
H31G C313 H31I 109.5 . .
H31H C313 H31I 109.5 . .
C321 Si32 C323 110.20(18) . .
C321 Si32 C3 109.30(16) . .
C323 Si32 C3 109.47(16) . .
C321 Si32 C322 106.24(17) . .
C323 Si32 C322 107.56(18) . .
C3 Si32 C322 113.99(17) . .
Si32 C321 H32A 109.5 . .
Si32 C321 H32B 109.5 . .
H32A C321 H32B 109.5 . .
Si32 C321 H32C 109.5 . .
H32A C321 H32C 109.5 . .
H32B C321 H32C 109.5 . .
Si32 C322 H32D 109.5 . .
Si32 C322 H32E 109.5 . .
H32D C322 H32E 109.5 . .
Si32 C322 H32F 109.5 . .
H32D C322 H32F 109.5 . .
H32E C322 H32F 109.5 . .
Si32 C323 H32G 109.5 . .
Si32 C323 H32H 109.5 . .
H32G C323 H32H 109.5 . .
Si32 C323 H32I 109.5 . .
H32G C323 H32I 109.5 . .
H32H C323 H32I 109.5 . .
C4 Ga4 O4 108.39(11) . .
C4 Ga4 N31 114.19(12) . 2_656
O4 Ga4 N31 92.37(9) . 2_656
C4 Ga4 Ga3 130.47(9) . .
O4 Ga4 Ga3 88.44(6) . .
N31 Ga4 Ga3 111.09(7) 2_656 .
Si42 C4 Si41 119.34(17) . .
Si42 C4 Ga4 109.64(16) . .
Si41 C4 Ga4 118.79(16) . .
Si42 C4 H4 101.8 . .
Si41 C4 H4 101.8 . .
Ga4 C4 H4 101.8 . .
C411 Si41 C4 111.02(16) . .
C411 Si41 C413 106.50(19) . .
C4 Si41 C413 113.28(17) . .
C411 Si41 C412 106.51(19) . .
C4 Si41 C412 112.86(17) . .
C413 Si41 C412 106.20(17) . .
Si41 C411 H41A 109.5 . .
Si41 C411 H41B 109.5 . .
H41A C411 H41B 109.5 . .
Si41 C411 H41C 109.5 . .
H41A C411 H41C 109.5 . .
H41B C411 H41C 109.5 . .
Si41 C412 H41D 109.5 . .
Si41 C412 H41E 109.5 . .
H41D C412 H41E 109.5 . .
Si41 C412 H41F 109.5 . .
H41D C412 H41F 109.5 . .
H41E C412 H41F 109.5 . .
Si41 C413 H41G 109.5 . .
Si41 C413 H41H 109.5 . .
H41G C413 H41H 109.5 . .
Si41 C413 H41I 109.5 . .
H41G C413 H41I 109.5 . .
H41H C413 H41I 109.5 . .
C421 Si42 C4 109.41(16) . .
C421 Si42 C423 108.5(2) . .
C4 Si42 C423 110.89(18) . .
C421 Si42 C422 106.8(2) . .
C4 Si42 C422 111.59(19) . .
C423 Si42 C422 109.5(2) . .
Si42 C421 H42A 109.5 . .
Si42 C421 H42B 109.5 . .
H42A C421 H42B 109.5 . .
Si42 C421 H42C 109.5 . .
H42A C421 H42C 109.5 . .
H42B C421 H42C 109.5 . .
Si42 C422 H42D 109.5 . .
Si42 C422 H42E 109.5 . .
H42D C422 H42E 109.5 . .
Si42 C422 H42F 109.5 . .
H42D C422 H42F 109.5 . .
H42E C422 H42F 109.5 . .
Si42 C423 H42G 109.5 . .
Si42 C423 H42H 109.5 . .
H42G C423 H42H 109.5 . .
Si42 C423 H42I 109.5 . .
H42G C423 H42I 109.5 . .
H42H C423 H42I 109.5 . .
C21 O3 Ga3 120.9(2) . .
C21 O4 Ga4 118.75(19) . .
O4 C21 O3 124.8(3) . .
O4 C21 C22 119.5(3) . .
O3 C21 C22 115.7(3) . .
C27 C22 C23 121.2(3) . .
C27 C22 C21 118.5(3) . .
C23 C22 C21 120.3(3) . .
C24 C23 C22 121.1(3) . .
C24 C23 H23 119.5 . .
C22 C23 H23 119.5 . .
C23 C24 C25 117.2(3) . .
C23 C24 H24 121.4 . .
C25 C24 H24 121.4 . .
N21 C25 C24 132.8(3) . .
N21 C25 C26 105.6(3) . .
C24 C25 C26 121.6(3) . .
N23 C26 C27 132.1(3) . .
N23 C26 C25 106.9(3) . .
C27 C26 C25 120.9(3) . .
C22 C27 C26 117.9(3) . .
C22 C27 H27 121.1 . .
C26 C27 H27 121.1 . .
N22 N21 C25 109.8(2) . .
N22 N21 Ga1 117.90(19) . 2_656
C25 N21 Ga1 131.9(2) . 2_656
N23 N22 N21 109.2(2) . .
N22 N23 C26 108.4(2) . .
N22 N23 Ga2 117.23(19) . .
C26 N23 Ga2 132.9(2) . .
C5 Ga5 O5 113.68(11) . .
C5 Ga5 N33 114.00(13) . 2_656
O5 Ga5 N33 89.84(9) . 2_656
C5 Ga5 Ga6 130.32(11) . .
O5 Ga5 Ga6 87.59(6) . .
N33 Ga5 Ga6 110.16(7) 2_656 .
Si52 C5 Si51 119.30(18) . .
Si52 C5 Ga5 119.91(17) . .
Si51 C5 Ga5 108.86(17) . .
Si52 C5 H5 101.6 . .
Si51 C5 H5 101.6 . .
Ga5 C5 H5 101.6 . .
C513 Si51 C511 109.06(19) . .
C513 Si51 C5 110.96(18) . .
C511 Si51 C5 109.96(16) . .
C513 Si51 C512 109.9(2) . .
C511 Si51 C512 105.06(18) . .
C5 Si51 C512 111.74(18) . .
Si51 C511 H51A 109.5 . .
Si51 C511 H51B 109.5 . .
H51A C511 H51B 109.5 . .
Si51 C511 H51C 109.5 . .
H51A C511 H51C 109.5 . .
H51B C511 H51C 109.5 . .
Si51 C512 H51D 109.5 . .
Si51 C512 H51E 109.5 . .
H51D C512 H51E 109.5 . .
Si51 C512 H51F 109.5 . .
H51D C512 H51F 109.5 . .
H51E C512 H51F 109.5 . .
Si51 C513 H51G 109.5 . .
Si51 C513 H51H 109.5 . .
H51G C513 H51H 109.5 . .
Si51 C513 H51I 109.5 . .
H51G C513 H51I 109.5 . .
H51H C513 H51I 109.5 . .
C521 Si52 C522 106.5(2) . .
C521 Si52 C523 109.2(3) . .
C522 Si52 C523 106.9(2) . .
C521 Si52 C5 110.36(19) . .
C522 Si52 C5 113.01(18) . .
C523 Si52 C5 110.7(2) . .
Si52 C521 H52A 109.5 . .
Si52 C521 H52B 109.5 . .
H52A C521 H52B 109.5 . .
Si52 C521 H52C 109.5 . .
H52A C521 H52C 109.5 . .
H52B C521 H52C 109.5 . .
Si52 C522 H52D 109.5 . .
Si52 C522 H52E 109.5 . .
H52D C522 H52E 109.5 . .
Si52 C522 H52F 109.5 . .
H52D C522 H52F 109.5 . .
H52E C522 H52F 109.5 . .
Si52 C523 H52G 109.5 . .
Si52 C523 H52H 109.5 . .
H52G C523 H52H 109.5 . .
Si52 C523 H52I 109.5 . .
H52G C523 H52I 109.5 . .
H52H C523 H52I 109.5 . .
C6 Ga6 N13 106.83(12) . .
C6 Ga6 O6 106.62(11) . .
N13 Ga6 O6 91.68(9) . .
C6 Ga6 Ga5 138.37(10) . .
N13 Ga6 Ga5 111.71(7) . .
O6 Ga6 Ga5 87.65(6) . .
Si62 C6 Si61 117.30(17) . .
Si62 C6 Ga6 110.19(16) . .
Si61 C6 Ga6 110.62(16) . .
Si62 C6 H6 106.0 . .
Si61 C6 H6 106.0 . .
Ga6 C6 H6 106.0 . .
C612 Si61 C6 109.73(18) . .
C612 Si61 C611 110.9(2) . .
C6 Si61 C611 109.11(18) . .
C612 Si61 C613 106.8(2) . .
C6 Si61 C613 113.23(18) . .
C611 Si61 C613 107.12(19) . .
Si61 C611 H61A 109.5 . .
Si61 C611 H61B 109.5 . .
H61A C611 H61B 109.5 . .
Si61 C611 H61C 109.5 . .
H61A C611 H61C 109.5 . .
H61B C611 H61C 109.5 . .
Si61 C612 H61D 109.5 . .
Si61 C612 H61E 109.5 . .
H61D C612 H61E 109.5 . .
Si61 C612 H61F 109.5 . .
H61D C612 H61F 109.5 . .
H61E C612 H61F 109.5 . .
Si61 C613 H61G 109.5 . .
Si61 C613 H61H 109.5 . .
H61G C613 H61H 109.5 . .
Si61 C613 H61I 109.5 . .
H61G C613 H61I 109.5 . .
H61H C613 H61I 109.5 . .
C622 Si62 C621 107.46(18) . .
C622 Si62 C6 110.28(15) . .
C621 Si62 C6 111.06(17) . .
C622 Si62 C623 106.87(19) . .
C621 Si62 C623 109.45(19) . .
C6 Si62 C623 111.55(17) . .
Si62 C621 H62A 109.5 . .
Si62 C621 H62B 109.5 . .
H62A C621 H62B 109.5 . .
Si62 C621 H62C 109.5 . .
H62A C621 H62C 109.5 . .
H62B C621 H62C 109.5 . .
Si62 C622 H62D 109.5 . .
Si62 C622 H62E 109.5 . .
H62D C622 H62E 109.5 . .
Si62 C622 H62F 109.5 . .
H62D C622 H62F 109.5 . .
H62E C622 H62F 109.5 . .
Si62 C623 H62G 109.5 . .
Si62 C623 H62H 109.5 . .
H62G C623 H62H 109.5 . .
Si62 C623 H62I 109.5 . .
H62G C623 H62I 109.5 . .
H62H C623 H62I 109.5 . .
C31 O5 Ga5 117.91(19) . .
C31 O6 Ga6 119.59(19) . .
O6 C31 O5 125.3(3) . .
O6 C31 C32 116.7(3) . .
O5 C31 C32 118.0(3) . .
C37 C32 C33 121.9(3) . .
C37 C32 C31 119.6(3) . .
C33 C32 C31 118.5(3) . .
C34 C33 C32 121.5(3) . .
C34 C33 H33 119.2 . .
C32 C33 H33 119.2 . .
C33 C34 C35 117.1(3) . .
C33 C34 H34 121.5 . .
C35 C34 H34 121.5 . .
N31 C35 C36 106.5(3) . .
N31 C35 C34 132.1(3) . .
C36 C35 C34 121.4(3) . .
N33 C36 C35 106.6(3) . .
N33 C36 C37 132.1(3) . .
C35 C36 C37 121.2(3) . .
C32 C37 C36 116.9(3) . .
C32 C37 H37 121.5 . .
C36 C37 H37 121.5 . .
N32 N31 C35 108.5(2) . .
N32 N31 Ga4 116.73(18) . 2_656
C35 N31 Ga4 134.6(2) . 2_656
N33 N32 N31 109.8(2) . .
N32 N33 C36 108.5(2) . .
N32 N33 Ga5 116.82(19) . 2_656
C36 N33 Ga5 131.7(2) . 2_656
C914 O91 C911 107.6(7) . .
C912 C911 O91 99.2(10) . .
C912 C911 H91A 111.9 . .
O91 C911 H91A 111.9 . .
C912 C911 H91B 111.9 . .
O91 C911 H91B 111.9 . .
H91A C911 H91B 109.6 . .
C911 C912 C913 110.2(14) . .
C911 C912 H91C 109.6 . .
C913 C912 H91C 109.6 . .
C911 C912 H91D 109.6 . .
C913 C912 H91D 109.6 . .
H91C C912 H91D 108.1 . .
C914 C913 C912 103.9(14) . .
C914 C913 H91E 111.0 . .
C912 C913 H91E 111.0 . .
C914 C913 H91F 111.0 . .
C912 C913 H91F 111.0 . .
H91E C913 H91F 109.0 . .
C913 C914 O91 103.8(11) . .
C913 C914 H91G 111.0 . .
O91 C914 H91G 111.0 . .
C913 C914 H91H 111.0 . .
O91 C914 H91H 111.0 . .
H91G C914 H91H 109.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ga1 C1 1.961(3) .
Ga1 N21 2.025(2) 2_656
Ga1 O1 2.042(2) .
Ga1 Ga2 2.4111(5) .
C1 Si11 1.869(3) .
C1 Si12 1.875(3) .
C1 H1 0.9600 .
Si11 C111 1.869(4) .
Si11 C113 1.871(4) .
Si11 C112 1.871(4) .
C111 H11A 0.9599 .
C111 H11B 0.9599 .
C111 H11C 0.9599 .
C112 H11D 0.9599 .
C112 H11E 0.9599 .
C112 H11F 0.9599 .
C113 H11G 0.9599 .
C113 H11H 0.9599 .
C113 H11I 0.9599 .
Si12 C123 1.874(4) .
Si12 C122 1.884(4) .
Si12 C121 1.885(4) .
C121 H12A 0.9599 .
C121 H12B 0.9599 .
C121 H12C 0.9599 .
C122 H12D 0.9599 .
C122 H12E 0.9599 .
C122 H12F 0.9599 .
C123 H12G 0.9599 .
C123 H12H 0.9599 .
C123 H12I 0.9599 .
Ga2 C2 1.967(3) .
Ga2 O2 2.018(2) .
Ga2 N23 2.065(3) .
C2 Si21 1.862(4) .
C2 Si22 1.876(3) .
C2 H2 0.9600 .
Si21 C212 1.835(5) .
Si21 C213 1.872(4) .
Si21 C211 1.878(5) .
C211 H21A 0.9599 .
C211 H21B 0.9599 .
C211 H21C 0.9599 .
C212 H21D 0.9599 .
C212 H21E 0.9599 .
C212 H21F 0.9599 .
C213 H21G 0.9599 .
C213 H21H 0.9599 .
C213 H21I 0.9599 .
Si22 C221 1.855(4) .
Si22 C223 1.867(5) .
Si22 C222 1.877(4) .
C221 H22A 0.9599 .
C221 H22B 0.9599 .
C221 H22C 0.9599 .
C222 H22D 0.9599 .
C222 H22E 0.9599 .
C222 H22F 0.9599 .
C223 H22G 0.9599 .
C223 H22H 0.9599 .
C223 H22I 0.9599 .
O1 C11 1.269(3) .
O2 C11 1.268(4) .
C11 C12 1.489(4) .
C12 C17 1.380(4) .
C12 C13 1.418(4) .
C13 C14 1.365(4) .
C13 H13 0.9600 .
C14 C15 1.404(4) .
C14 H14 0.9600 .
C15 N13 1.371(4) .
C15 C16 1.392(4) .
C16 N11 1.375(4) .
C16 C17 1.388(4) .
C17 H17 0.9600 .
N11 N12 1.326(3) .
N11 Ga3 2.047(2) .
N12 N13 1.337(3) .
N13 Ga6 2.010(3) .
Ga3 C3 1.978(3) .
Ga3 O3 2.015(2) .
Ga3 Ga4 2.4189(5) .
C3 Si32 1.864(3) .
C3 Si31 1.867(3) .
C3 H3 0.9600 .
Si31 C313 1.863(4) .
Si31 C311 1.863(4) .
Si31 C312 1.875(4) .
C311 H31A 0.9599 .
C311 H31B 0.9599 .
C311 H31C 0.9599 .
C312 H31D 0.9599 .
C312 H31E 0.9599 .
C312 H31F 0.9599 .
C313 H31G 0.9599 .
C313 H31H 0.9599 .
C313 H31I 0.9599 .
Si32 C321 1.851(4) .
Si32 C323 1.863(4) .
Si32 C322 1.878(4) .
C321 H32A 0.9599 .
C321 H32B 0.9599 .
C321 H32C 0.9599 .
C322 H32D 0.9599 .
C322 H32E 0.9599 .
C322 H32F 0.9599 .
C323 H32G 0.9599 .
C323 H32H 0.9599 .
C323 H32I 0.9599 .
Ga4 C4 1.983(3) .
Ga4 O4 2.025(2) .
Ga4 N31 2.052(3) 2_656
C4 Si42 1.865(3) .
C4 Si41 1.866(3) .
C4 H4 0.9600 .
Si41 C411 1.861(4) .
Si41 C413 1.868(4) .
Si41 C412 1.876(4) .
C411 H41A 0.9599 .
C411 H41B 0.9599 .
C411 H41C 0.9599 .
C412 H41D 0.9599 .
C412 H41E 0.9599 .
C412 H41F 0.9599 .
C413 H41G 0.9599 .
C413 H41H 0.9599 .
C413 H41I 0.9599 .
Si42 C421 1.864(4) .
Si42 C423 1.870(4) .
Si42 C422 1.888(4) .
C421 H42A 0.9599 .
C421 H42B 0.9599 .
C421 H42C 0.9599 .
C422 H42D 0.9599 .
C422 H42E 0.9599 .
C422 H42F 0.9599 .
C423 H42G 0.9599 .
C423 H42H 0.9599 .
C423 H42I 0.9599 .
O3 C21 1.275(3) .
O4 C21 1.261(3) .
C21 C22 1.493(4) .
C22 C27 1.366(4) .
C22 C23 1.425(4) .
C23 C24 1.374(4) .
C23 H23 0.9600 .
C24 C25 1.389(4) .
C24 H24 0.9600 .
C25 N21 1.366(4) .
C25 C26 1.401(4) .
C26 N23 1.381(4) .
C26 C27 1.387(4) .
C27 H27 0.9600 .
N21 N22 1.333(3) .
N21 Ga1 2.025(2) 2_656
N22 N23 1.328(3) .
Ga5 C5 1.960(3) .
Ga5 O5 2.050(2) .
Ga5 N33 2.076(3) 2_656
Ga5 Ga6 2.4028(5) .
C5 Si52 1.860(3) .
C5 Si51 1.878(3) .
C5 H5 0.9600 .
Si51 C513 1.861(4) .
Si51 C511 1.871(4) .
Si51 C512 1.880(4) .
C511 H51A 0.9599 .
C511 H51B 0.9599 .
C511 H51C 0.9599 .
C512 H51D 0.9599 .
C512 H51E 0.9599 .
C512 H51F 0.9599 .
C513 H51G 0.9599 .
C513 H51H 0.9599 .
C513 H51I 0.9599 .
Si52 C521 1.844(5) .
Si52 C522 1.855(4) .
Si52 C523 1.857(5) .
C521 H52A 0.9599 .
C521 H52B 0.9599 .
C521 H52C 0.9599 .
C522 H52D 0.9599 .
C522 H52E 0.9599 .
C522 H52F 0.9599 .
C523 H52G 0.9599 .
C523 H52H 0.9599 .
C523 H52I 0.9599 .
Ga6 C6 1.969(3) .
Ga6 O6 2.029(2) .
C6 Si62 1.868(3) .
C6 Si61 1.870(3) .
C6 H6 0.9600 .
Si61 C612 1.863(4) .
Si61 C611 1.874(4) .
Si61 C613 1.879(4) .
C611 H61A 0.9599 .
C611 H61B 0.9599 .
C611 H61C 0.9599 .
C612 H61D 0.9599 .
C612 H61E 0.9599 .
C612 H61F 0.9599 .
C613 H61G 0.9599 .
C613 H61H 0.9599 .
C613 H61I 0.9599 .
Si62 C622 1.862(4) .
Si62 C621 1.864(4) .
Si62 C623 1.876(4) .
C621 H62A 0.9599 .
C621 H62B 0.9599 .
C621 H62C 0.9599 .
C622 H62D 0.9599 .
C622 H62E 0.9599 .
C622 H62F 0.9599 .
C623 H62G 0.9599 .
C623 H62H 0.9599 .
C623 H62I 0.9599 .
O5 C31 1.272(4) .
O6 C31 1.267(4) .
C31 C32 1.514(4) .
C32 C37 1.367(4) .
C32 C33 1.414(4) .
C33 C34 1.367(4) .
C33 H33 0.9600 .
C34 C35 1.402(4) .
C34 H34 0.9600 .
C35 N31 1.383(4) .
C35 C36 1.393(4) .
C36 N33 1.385(4) .
C36 C37 1.403(4) .
C37 H37 0.9600 .
N31 N32 1.337(3) .
N31 Ga4 2.052(2) 2_656
N32 N33 1.332(3) .
N33 Ga5 2.076(3) 2_656
O91 C914 1.493(12) .
O91 C911 1.513(12) .
C911 C912 1.413(14) .
C911 H91A 0.9600 .
C911 H91B 0.9600 .
C912 C913 1.585(15) .
C912 H91C 0.9600 .
C912 H91D 0.9600 .
C913 C914 1.444(12) .
C913 H91E 0.9600 .
C913 H91F 0.9600 .
C914 H91G 0.9600 .
C914 H91H 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N21 Ga1 C1 Si11 91.07(16) 2_656 .
O1 Ga1 C1 Si11 -171.32(13) . .
Ga2 Ga1 C1 Si11 -65.7(2) . .
N21 Ga1 C1 Si12 -137.28(16) 2_656 .
O1 Ga1 C1 Si12 -39.68(19) . .
Ga2 Ga1 C1 Si12 66.0(2) . .
Si12 C1 Si11 C111 -172.57(19) . .
Ga1 C1 Si11 C111 -43.4(2) . .
Si12 C1 Si11 C113 -53.2(2) . .
Ga1 C1 Si11 C113 76.0(2) . .
Si12 C1 Si11 C112 69.1(2) . .
Ga1 C1 Si11 C112 -161.78(17) . .
Si11 C1 Si12 C123 86.8(2) . .
Ga1 C1 Si12 C123 -40.5(2) . .
Si11 C1 Si12 C122 -152.3(2) . .
Ga1 C1 Si12 C122 80.3(2) . .
Si11 C1 Si12 C121 -34.4(3) . .
Ga1 C1 Si12 C121 -161.7(2) . .
C1 Ga1 Ga2 C2 10.02(19) . .
N21 Ga1 Ga2 C2 -146.11(15) 2_656 .
O1 Ga1 Ga2 C2 122.27(14) . .
C1 Ga1 Ga2 O2 -105.20(15) . .
N21 Ga1 Ga2 O2 98.66(10) 2_656 .
O1 Ga1 Ga2 O2 7.05(8) . .
C1 Ga1 Ga2 N23 165.49(16) . .
N21 Ga1 Ga2 N23 9.36(11) 2_656 .
O1 Ga1 Ga2 N23 -82.26(9) . .
O2 Ga2 C2 Si21 -23.8(2) . .
N23 Ga2 C2 Si21 75.2(2) . .
Ga1 Ga2 C2 Si21 -129.84(15) . .
O2 Ga2 C2 Si22 -163.60(14) . .
N23 Ga2 C2 Si22 -64.63(19) . .
Ga1 Ga2 C2 Si22 90.36(18) . .
Si22 C2 Si21 C212 -164.9(2) . .
Ga2 C2 Si21 C212 58.8(3) . .
Si22 C2 Si21 C213 -46.0(3) . .
Ga2 C2 Si21 C213 177.7(2) . .
Si22 C2 Si21 C211 73.7(3) . .
Ga2 C2 Si21 C211 -62.6(3) . .
Si21 C2 Si22 C221 -164.2(2) . .
Ga2 C2 Si22 C221 -23.7(2) . .
Si21 C2 Si22 C223 -45.4(3) . .
Ga2 C2 Si22 C223 95.1(2) . .
Si21 C2 Si22 C222 77.7(3) . .
Ga2 C2 Si22 C222 -141.8(2) . .
C1 Ga1 O1 C11 134.5(2) . .
N21 Ga1 O1 C11 -117.3(2) 2_656 .
Ga2 Ga1 O1 C11 -6.4(2) . .
C2 Ga2 O2 C11 -146.1(2) . .
N23 Ga2 O2 C11 99.6(2) . .
Ga1 Ga2 O2 C11 -10.4(2) . .
Ga2 O2 C11 O1 8.6(4) . .
Ga2 O2 C11 C12 -170.10(19) . .
Ga1 O1 C11 O2 0.2(4) . .
Ga1 O1 C11 C12 178.82(19) . .
O2 C11 C12 C17 4.2(4) . .
O1 C11 C12 C17 -174.6(3) . .
O2 C11 C12 C13 -179.6(3) . .
O1 C11 C12 C13 1.6(4) . .
C17 C12 C13 C14 -1.3(5) . .
C11 C12 C13 C14 -177.4(3) . .
C12 C13 C14 C15 3.2(5) . .
C13 C14 C15 N13 175.7(3) . .
C13 C14 C15 C16 -1.9(5) . .
N13 C15 C16 N11 -0.7(3) . .
C14 C15 C16 N11 177.4(3) . .
N13 C15 C16 C17 -179.5(3) . .
C14 C15 C16 C17 -1.3(5) . .
C13 C12 C17 C16 -2.0(4) . .
C11 C12 C17 C16 174.2(3) . .
N11 C16 C17 C12 -175.1(3) . .
C15 C16 C17 C12 3.3(4) . .
C17 C16 N11 N12 178.8(3) . .
C15 C16 N11 N12 0.3(3) . .
C17 C16 N11 Ga3 12.5(5) . .
C15 C16 N11 Ga3 -166.1(2) . .
C16 N11 N12 N13 0.3(3) . .
Ga3 N11 N12 N13 168.91(17) . .
N11 N12 N13 C15 -0.8(3) . .
N11 N12 N13 Ga6 -177.24(17) . .
C16 C15 N13 N12 1.0(3) . .
C14 C15 N13 N12 -176.9(3) . .
C16 C15 N13 Ga6 176.5(2) . .
C14 C15 N13 Ga6 -1.3(5) . .
N12 N11 Ga3 C3 113.3(2) . .
C16 N11 Ga3 C3 -81.4(3) . .
N12 N11 Ga3 O3 -143.4(2) . .
C16 N11 Ga3 O3 21.9(3) . .
N12 N11 Ga3 Ga4 -57.1(2) . .
C16 N11 Ga3 Ga4 108.2(3) . .
O3 Ga3 C3 Si32 -147.94(14) . .
N11 Ga3 C3 Si32 -53.63(18) . .
Ga4 Ga3 C3 Si32 111.38(15) . .
O3 Ga3 C3 Si31 78.70(17) . .
N11 Ga3 C3 Si31 173.01(14) . .
Ga4 Ga3 C3 Si31 -22.0(3) . .
Si32 C3 Si31 C313 -172.07(18) . .
Ga3 C3 Si31 C313 -42.3(2) . .
Si32 C3 Si31 C311 -52.8(2) . .
Ga3 C3 Si31 C311 76.9(2) . .
Si32 C3 Si31 C312 68.8(3) . .
Ga3 C3 Si31 C312 -161.42(19) . .
Si31 C3 Si32 C321 -151.06(19) . .
Ga3 C3 Si32 C321 79.8(2) . .
Si31 C3 Si32 C323 88.2(2) . .
Ga3 C3 Si32 C323 -41.0(2) . .
Si31 C3 Si32 C322 -32.4(3) . .
Ga3 C3 Si32 C322 -161.47(17) . .
C3 Ga3 Ga4 C4 -1.4(2) . .
O3 Ga3 Ga4 C4 -107.49(14) . .
N11 Ga3 Ga4 C4 163.51(15) . .
C3 Ga3 Ga4 O4 111.67(17) . .
O3 Ga3 Ga4 O4 5.57(8) . .
N11 Ga3 Ga4 O4 -83.42(10) . .
C3 Ga3 Ga4 N31 -156.39(18) . 2_656
O3 Ga3 Ga4 N31 97.51(10) . 2_656
N11 Ga3 Ga4 N31 8.52(11) . 2_656
O4 Ga4 C4 Si42 152.82(13) . .
N31 Ga4 C4 Si42 51.45(19) 2_656 .
Ga3 Ga4 C4 Si42 -102.93(15) . .
O4 Ga4 C4 Si41 10.7(2) . .
N31 Ga4 C4 Si41 -90.71(19) 2_656 .
Ga3 Ga4 C4 Si41 114.91(15) . .
Si42 C4 Si41 C411 154.79(19) . .
Ga4 C4 Si41 C411 -66.7(2) . .
Si42 C4 Si41 C413 -85.4(2) . .
Ga4 C4 Si41 C413 53.0(3) . .
Si42 C4 Si41 C412 35.3(3) . .
Ga4 C4 Si41 C412 173.78(18) . .
Si41 C4 Si42 C421 176.98(19) . .
Ga4 C4 Si42 C421 35.1(2) . .
Si41 C4 Si42 C423 57.4(2) . .
Ga4 C4 Si42 C423 -84.5(2) . .
Si41 C4 Si42 C422 -65.0(3) . .
Ga4 C4 Si42 C422 153.1(2) . .
C3 Ga3 O3 C21 -151.1(2) . .
N11 Ga3 O3 C21 100.7(2) . .
Ga4 Ga3 O3 C21 -8.2(2) . .
C4 Ga4 O4 C21 127.4(2) . .
N31 Ga4 O4 C21 -116.1(2) 2_656 .
Ga3 Ga4 O4 C21 -5.1(2) . .
Ga4 O4 C21 O3 0.2(4) . .
Ga4 O4 C21 C22 178.0(2) . .
Ga3 O3 C21 O4 6.8(4) . .
Ga3 O3 C21 C22 -171.08(19) . .
O4 C21 C22 C27 -173.6(3) . .
O3 C21 C22 C27 4.4(4) . .
O4 C21 C22 C23 4.3(4) . .
O3 C21 C22 C23 -177.7(3) . .
C27 C22 C23 C24 1.3(5) . .
C21 C22 C23 C24 -176.6(3) . .
C22 C23 C24 C25 1.2(5) . .
C23 C24 C25 N21 178.5(3) . .
C23 C24 C25 C26 -2.8(5) . .
N21 C25 C26 N23 -0.8(3) . .
C24 C25 C26 N23 -179.9(3) . .
N21 C25 C26 C27 -179.1(3) . .
C24 C25 C26 C27 1.9(5) . .
C23 C22 C27 C26 -2.2(5) . .
C21 C22 C27 C26 175.7(3) . .
N23 C26 C27 C22 -177.1(3) . .
C25 C26 C27 C22 0.7(5) . .
C24 C25 N21 N22 179.9(3) . .
C26 C25 N21 N22 1.0(3) . .
C24 C25 N21 Ga1 -7.3(5) . 2_656
C26 C25 N21 Ga1 173.8(2) . 2_656
C25 N21 N22 N23 -0.8(3) . .
Ga1 N21 N22 N23 -174.79(18) 2_656 .
N21 N22 N23 C26 0.3(3) . .
N21 N22 N23 Ga2 168.40(18) . .
C27 C26 N23 N22 178.3(3) . .
C25 C26 N23 N22 0.3(3) . .
C27 C26 N23 Ga2 12.9(5) . .
C25 C26 N23 Ga2 -165.2(2) . .
C2 Ga2 N23 N22 102.6(2) . .
O2 Ga2 N23 N22 -145.7(2) . .
Ga1 Ga2 N23 N22 -58.4(2) . .
C2 Ga2 N23 C26 -92.9(3) . .
O2 Ga2 N23 C26 18.8(3) . .
Ga1 Ga2 N23 C26 106.1(3) . .
O5 Ga5 C5 Si52 -15.0(3) . .
N33 Ga5 C5 Si52 86.1(2) 2_656 .
Ga6 Ga5 C5 Si52 -123.19(17) . .
O5 Ga5 C5 Si51 -157.50(13) . .
N33 Ga5 C5 Si51 -56.4(2) 2_656 .
Ga6 Ga5 C5 Si51 94.32(18) . .
Si52 C5 Si51 C513 -56.3(3) . .
Ga5 C5 Si51 C513 86.4(2) . .
Si52 C5 Si51 C511 -177.1(2) . .
Ga5 C5 Si51 C511 -34.3(2) . .
Si52 C5 Si51 C512 66.7(3) . .
Ga5 C5 Si51 C512 -150.6(2) . .
Si51 C5 Si52 C521 -161.9(2) . .
Ga5 C5 Si52 C521 59.5(3) . .
Si51 C5 Si52 C522 -42.8(3) . .
Ga5 C5 Si52 C522 178.5(2) . .
Si51 C5 Si52 C523 77.1(3) . .
Ga5 C5 Si52 C523 -61.5(3) . .
N12 N13 Ga6 C6 -116.0(2) . .
C15 N13 Ga6 C6 68.7(3) . .
N12 N13 Ga6 O6 136.1(2) . .
C15 N13 Ga6 O6 -39.2(3) . .
N12 N13 Ga6 Ga5 47.9(2) . .
C15 N13 Ga6 Ga5 -127.4(3) . .
C5 Ga5 Ga6 C6 15.71(19) . .
O5 Ga5 Ga6 C6 -103.74(15) . .
N33 Ga5 Ga6 C6 167.32(16) 2_656 .
C5 Ga5 Ga6 N13 -140.80(15) . .
O5 Ga5 Ga6 N13 99.75(9) . .
N33 Ga5 Ga6 N13 10.82(11) 2_656 .
C5 Ga5 Ga6 O6 128.33(14) . .
O5 Ga5 Ga6 O6 8.88(8) . .
N33 Ga5 Ga6 O6 -80.06(9) 2_656 .
N13 Ga6 C6 Si62 88.42(17) . .
O6 Ga6 C6 Si62 -174.56(14) . .
Ga5 Ga6 C6 Si62 -68.8(2) . .
N13 Ga6 C6 Si61 -140.25(15) . .
O6 Ga6 C6 Si61 -43.22(18) . .
Ga5 Ga6 C6 Si61 62.5(2) . .
Si62 C6 Si61 C612 85.3(2) . .
Ga6 C6 Si61 C612 -42.2(2) . .
Si62 C6 Si61 C611 -153.0(2) . .
Ga6 C6 Si61 C611 79.4(2) . .
Si62 C6 Si61 C613 -33.8(3) . .
Ga6 C6 Si61 C613 -161.4(2) . .
Si61 C6 Si62 C622 -170.5(2) . .
Ga6 C6 Si62 C622 -42.7(2) . .
Si61 C6 Si62 C621 -51.5(2) . .
Ga6 C6 Si62 C621 76.3(2) . .
Si61 C6 Si62 C623 70.9(2) . .
Ga6 C6 Si62 C623 -161.34(18) . .
C5 Ga5 O5 C31 -147.5(2) . .
N33 Ga5 O5 C31 96.2(2) 2_656 .
Ga6 Ga5 O5 C31 -14.0(2) . .
C6 Ga6 O6 C31 133.3(2) . .
N13 Ga6 O6 C31 -118.6(2) . .
Ga5 Ga6 O6 C31 -6.9(2) . .
Ga6 O6 C31 O5 -2.4(4) . .
Ga6 O6 C31 C32 177.44(19) . .
Ga5 O5 C31 O6 13.1(4) . .
Ga5 O5 C31 C32 -166.7(2) . .
O6 C31 C32 C37 -175.9(3) . .
O5 C31 C32 C37 3.9(4) . .
O6 C31 C32 C33 1.7(4) . .
O5 C31 C32 C33 -178.4(3) . .
C37 C32 C33 C34 -0.4(5) . .
C31 C32 C33 C34 -178.0(3) . .
C32 C33 C34 C35 0.2(5) . .
C33 C34 C35 N31 179.2(3) . .
C33 C34 C35 C36 1.2(5) . .
N31 C35 C36 N33 -1.3(3) . .
C34 C35 C36 N33 177.2(3) . .
N31 C35 C36 C37 179.1(3) . .
C34 C35 C36 C37 -2.5(5) . .
C33 C32 C37 C36 -0.7(5) . .
C31 C32 C37 C36 176.9(3) . .
N33 C36 C37 C32 -177.3(3) . .
C35 C36 C37 C32 2.1(4) . .
C36 C35 N31 N32 1.6(3) . .
C34 C35 N31 N32 -176.6(3) . .
C36 C35 N31 Ga4 176.1(2) . 2_656
C34 C35 N31 Ga4 -2.2(5) . 2_656
C35 N31 N32 N33 -1.2(3) . .
Ga4 N31 N32 N33 -176.84(18) 2_656 .
N31 N32 N33 C36 0.4(3) . .
N31 N32 N33 Ga5 163.13(18) . 2_656
C35 C36 N33 N32 0.6(3) . .
C37 C36 N33 N32 -179.9(3) . .
C35 C36 N33 Ga5 -158.7(2) . 2_656
C37 C36 N33 Ga5 20.9(5) . 2_656
C914 O91 C911 C912 -39.4(10) . .
O91 C911 C912 C913 27.5(13) . .
C911 C912 C913 C914 -7.2(16) . .
C912 C913 C914 O91 -17.4(14) . .
C911 O91 C914 C913 36.3(11) . .
