#------------------------------------------------------------------------------
#$Date: 2016-03-25 16:15:23 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179960 $
#$URL: svn://www.crystallography.net/cod/cif/7/02/54/7025482.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7025482
loop_
_publ_author_name
'Kurzbach, Dennis'
'Yao, Shenglai'
'Hinderberger, Dariush'
'Klinkhammer, Karl W.'
_publ_section_title
;
 EPR spectroscopic characterization of persistent germyl-substituted
 Pb(III)- and Sn(III)-radicals.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              6449
_journal_page_last               6459
_journal_paper_doi               10.1039/c001144d
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C43 H121 Ge K O4 Pb Si11'
_chemical_formula_weight         1330.27
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.962(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.223(2)
_cell_length_b                   24.446(4)
_cell_length_c                   24.960(4)
_cell_measurement_temperature    173(2)
_cell_volume                     7346(2)
_computing_cell_refinement       'Bruker APEX-2'
_computing_data_collection       'Bruker APEX-2'
_computing_data_reduction        'Bruker APEX-2'
_computing_molecular_graphics    SHELXTL-Plus
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'APEX II CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1034
_diffrn_reflns_av_sigmaI/netI    0.0754
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       34
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            111571
_diffrn_reflns_theta_full        30.71
_diffrn_reflns_theta_max         30.71
_diffrn_reflns_theta_min         2.31
_exptl_absorpt_coefficient_mu    2.965
_exptl_absorpt_correction_T_max  0.3835
_exptl_absorpt_correction_T_min  0.3187
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.203
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             2792
_exptl_crystal_size_max          0.53
_exptl_crystal_size_mid          0.42
_exptl_crystal_size_min          0.39
_refine_diff_density_max         2.735
_refine_diff_density_min         -3.253
_refine_diff_density_rms         0.135
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.189
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     599
_refine_ls_number_reflns         22597
_refine_ls_number_restraints     136
_refine_ls_restrained_S_all      1.191
_refine_ls_R_factor_all          0.0852
_refine_ls_R_factor_gt           0.0455
_refine_ls_shift/su_max          0.011
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0330P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0886
_refine_ls_wR_factor_ref         0.0991
_reflns_number_gt                16124
_reflns_number_total             22597
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c001144d.txt
_cod_data_source_block           kpbhge2hyp
_cod_original_cell_volume        7345(2)
_cod_database_code               7025482
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pb1A Pb -1.151715(10) 0.920898(5) 1.249310(5) 0.01891(4) Uani 1 1 d . . .
Ge1 Ge -1.22582(4) 1.00598(2) 1.31180(2) 0.01939(18) Uani 0.4602(15) 1 d P . .
Ge2 Ge -0.96533(4) 0.87113(2) 1.31703(2) 0.01953(17) Uani 0.5076(15) 1 d P . .
Ge3 Ge -1.06745(4) 0.97511(2) 1.16345(2) 0.02003(18) Uani 0.4887(15) 1 d P . .
Si1 Si -1.22582(4) 1.00598(2) 1.31180(2) 0.01939(18) Uani 0.54 1 d P . .
Si11 Si -1.14403(9) 1.09252(4) 1.33603(4) 0.0249(2) Uani 1 1 d . . .
Si12 Si -1.24385(9) 0.96552(4) 1.39633(4) 0.0240(2) Uani 1 1 d . . .
Si13 Si -1.41818(9) 1.01827(5) 1.27475(4) 0.0300(2) Uani 1 1 d . . .
C121 C -1.3176(4) 1.00769(17) 1.44281(15) 0.0383(10) Uani 1 1 d . . .
H12D H -1.3205 0.9871 1.4762 0.058 Uiso 1 1 calc R . .
H12E H -1.3933 1.0158 1.4244 0.058 Uiso 1 1 calc R . .
H12F H -1.2771 1.0420 1.4519 0.058 Uiso 1 1 calc R . .
C131 C -1.5035(3) 1.03740(19) 1.32784(17) 0.0420(11) Uani 1 1 d . . .
H13C H -1.5814 1.0418 1.3106 0.063 Uiso 1 1 calc R . .
H13D H -1.4758 1.0719 1.3452 0.063 Uiso 1 1 calc R . .
H13E H -1.4978 1.0085 1.3554 0.063 Uiso 1 1 calc R . .
C122 C -1.3258(3) 0.90050(16) 1.38332(17) 0.0371(10) Uani 1 1 d . . .
H12G H -1.3335 0.8836 1.4181 0.056 Uiso 1 1 calc R . .
H12H H -1.2870 0.8752 1.3625 0.056 Uiso 1 1 calc R . .
H12I H -1.3996 0.9087 1.3626 0.056 Uiso 1 1 calc R . .
C112 C -1.0918(4) 1.09999(18) 1.41102(16) 0.0403(10) Uani 1 1 d . . .
H11C H -1.0593 1.1364 1.4184 0.060 Uiso 1 1 calc R . .
H11D H -1.0352 1.0721 1.4229 0.060 Uiso 1 1 calc R . .
H11E H -1.1537 1.0953 1.4309 0.060 Uiso 1 1 calc R . .
C132 C -1.4770(3) 0.9523(2) 1.24370(18) 0.0486(12) Uani 1 1 d . . .
H13F H -1.5558 0.9573 1.2285 0.073 Uiso 1 1 calc R . .
H13G H -1.4691 0.9238 1.2717 0.073 Uiso 1 1 calc R . .
H13H H -1.4367 0.9414 1.2147 0.073 Uiso 1 1 calc R . .
C111 C -1.2464(4) 1.15022(17) 1.3180(2) 0.0473(12) Uani 1 1 d . . .
H11F H -1.2097 1.1852 1.3287 0.071 Uiso 1 1 calc R . .
H11G H -1.3090 1.1453 1.3374 0.071 Uiso 1 1 calc R . .
H11H H -1.2737 1.1501 1.2787 0.071 Uiso 1 1 calc R . .
C123 C -1.1045(3) 0.95021(16) 1.43777(15) 0.0339(9) Uani 1 1 d . . .
H12J H -1.1142 0.9335 1.4723 0.051 Uiso 1 1 calc R . .
H12K H -1.0621 0.9842 1.4449 0.051 Uiso 1 1 calc R . .
H12L H -1.0643 0.9249 1.4177 0.051 Uiso 1 1 calc R . .
C113 C -1.0199(3) 1.10561(17) 1.30235(17) 0.0391(10) Uani 1 1 d . . .
H11I H -0.9886 1.1416 1.3134 0.059 Uiso 1 1 calc R . .
H11J H -1.0429 1.1047 1.2628 0.059 Uiso 1 1 calc R . .
H11K H -0.9637 1.0773 1.3134 0.059 Uiso 1 1 calc R . .
C133 C -1.4563(4) 1.07080(19) 1.21985(18) 0.0471(12) Uani 1 1 d . . .
H13I H -1.5371 1.0714 1.2084 0.071 Uiso 1 1 calc R . .
H13J H -1.4209 1.0615 1.1887 0.071 Uiso 1 1 calc R . .
H13K H -1.4307 1.1069 1.2338 0.071 Uiso 1 1 calc R . .
Si2 Si -0.96533(4) 0.87113(2) 1.31703(2) 0.01953(17) Uani 0.49 1 d P . .
Si22 Si -0.81882(9) 0.91192(4) 1.37967(4) 0.0250(2) Uani 1 1 d . . .
Si21 Si -1.04009(10) 0.79663(4) 1.36183(5) 0.0318(2) Uani 1 1 d . . .
Si23 Si -0.87261(9) 0.81849(4) 1.25858(4) 0.0291(2) Uani 1 1 d . . .
C211 C -0.9455(4) 0.73562(17) 1.3753(2) 0.0584(14) Uani 1 1 d . . .
H21C H -0.9818 0.7071 1.3936 0.088 Uiso 1 1 calc R . .
H21D H -0.8760 0.7465 1.3985 0.088 Uiso 1 1 calc R . .
H21E H -0.9296 0.7214 1.3407 0.088 Uiso 1 1 calc R . .
C221 C -0.6795(3) 0.90758(19) 1.35870(18) 0.0431(11) Uani 1 1 d . . .
H22D H -0.6238 0.9251 1.3863 0.065 Uiso 1 1 calc R . .
H22E H -0.6820 0.9263 1.3238 0.065 Uiso 1 1 calc R . .
H22F H -0.6597 0.8691 1.3550 0.065 Uiso 1 1 calc R . .
C212 C -1.0804(4) 0.80980(17) 1.43042(17) 0.0421(11) Uani 1 1 d . . .
H21F H -1.1093 0.7760 1.4439 0.063 Uiso 1 1 calc R . .
H21G H -1.1376 0.8383 1.4269 0.063 Uiso 1 1 calc R . .
H21H H -1.0150 0.8219 1.4561 0.063 Uiso 1 1 calc R . .
C231 C -0.9757(4) 0.77391(18) 1.21418(17) 0.0470(12) Uani 1 1 d . . .
H23C H -0.9374 0.7522 1.1901 0.070 Uiso 1 1 calc R . .
H23D H -1.0323 0.7969 1.1923 0.070 Uiso 1 1 calc R . .
H23E H -1.0114 0.7494 1.2370 0.070 Uiso 1 1 calc R . .
C232 C -0.8039(3) 0.86319(18) 1.21325(16) 0.0391(10) Uani 1 1 d . . .
H23F H -0.7665 0.8403 1.1897 0.059 Uiso 1 1 calc R . .
H23G H -0.7492 0.8868 1.2355 0.059 Uiso 1 1 calc R . .
H23H H -0.8600 0.8859 1.1908 0.059 Uiso 1 1 calc R . .
C222 C -0.8430(4) 0.98694(16) 1.39058(17) 0.0413(11) Uani 1 1 d . . .
H22G H -0.7808 1.0018 1.4166 0.062 Uiso 1 1 calc R . .
H22H H -0.9121 0.9916 1.4050 0.062 Uiso 1 1 calc R . .
H22I H -0.8487 1.0064 1.3559 0.062 Uiso 1 1 calc R . .
C233 C -0.7581(4) 0.77163(19) 1.29218(19) 0.0504(12) Uani 1 1 d . . .
H23I H -0.7262 0.7522 1.2642 0.076 Uiso 1 1 calc R . .
H23J H -0.7886 0.7451 1.3151 0.076 Uiso 1 1 calc R . .
H23K H -0.7002 0.7933 1.3147 0.076 Uiso 1 1 calc R . .
C213 C -1.1702(4) 0.77135(19) 1.31703(19) 0.0539(13) Uani 1 1 d . . .
H21I H -1.2015 0.7409 1.3350 0.081 Uiso 1 1 calc R . .
H21J H -1.1523 0.7588 1.2823 0.081 Uiso 1 1 calc R . .
H21K H -1.2245 0.8011 1.3105 0.081 Uiso 1 1 calc R . .
C223 C -0.8014(4) 0.87687(18) 1.44755(15) 0.0430(11) Uani 1 1 d . . .
H22J H -0.7408 0.8942 1.4726 0.064 Uiso 1 1 calc R . .
H22K H -0.7839 0.8382 1.4432 0.064 Uiso 1 1 calc R . .
H22L H -0.8705 0.8799 1.4623 0.064 Uiso 1 1 calc R . .
Si3 Si -1.06745(4) 0.97511(2) 1.16345(2) 0.02003(18) Uani 0.51 1 d P . .
Si31 Si -1.09443(9) 0.91029(4) 1.09095(4) 0.0258(2) Uani 1 1 d . . .
Si32 Si -0.88942(8) 1.01701(4) 1.16998(4) 0.0267(2) Uani 1 1 d . . .
Si33 Si -1.19523(9) 1.04238(5) 1.12317(4) 0.0293(2) Uani 1 1 d . . .
C311 C -0.9803(3) 0.85954(19) 1.08603(17) 0.0444(11) Uani 1 1 d . . .
H31C H -1.0030 0.8357 1.0545 0.067 Uiso 1 1 calc R . .
H31D H -0.9662 0.8373 1.1192 0.067 Uiso 1 1 calc R . .
H31E H -0.9124 0.8792 1.0818 0.067 Uiso 1 1 calc R . .
C321 C -0.8025(3) 0.98769(18) 1.12220(17) 0.0408(10) Uani 1 1 d . . .
H32D H -0.7310 1.0068 1.1269 0.061 Uiso 1 1 calc R . .
H32E H -0.8411 0.9923 1.0846 0.061 Uiso 1 1 calc R . .
H32F H -0.7899 0.9487 1.1300 0.061 Uiso 1 1 calc R . .
C312 C -1.1205(4) 0.94122(19) 1.02135(16) 0.0432(11) Uani 1 1 d . . .
H31F H -1.1308 0.9120 0.9940 0.065 Uiso 1 1 calc R . .
H31G H -1.0569 0.9639 1.0164 0.065 Uiso 1 1 calc R . .
H31H H -1.1876 0.9639 1.0171 0.065 Uiso 1 1 calc R . .
C331 C -1.3371(3) 1.01040(19) 1.10176(18) 0.0455(11) Uani 1 1 d . . .
H33C H -1.3897 1.0384 1.0851 0.068 Uiso 1 1 calc R . .
H33D H -1.3626 0.9951 1.1337 0.068 Uiso 1 1 calc R . .
H33E H -1.3323 0.9812 1.0754 0.068 Uiso 1 1 calc R . .
C332 C -1.1600(5) 1.07765(19) 1.06105(18) 0.0553(14) Uani 1 1 d . . .
H33F H -1.2178 1.1045 1.0476 0.083 Uiso 1 1 calc R . .
H33G H -1.1557 1.0505 1.0326 0.083 Uiso 1 1 calc R . .
H33H H -1.0883 1.0963 1.0706 0.083 Uiso 1 1 calc R . .
C333 C -1.2094(4) 1.09950(17) 1.17160(18) 0.0426(11) Uani 1 1 d . . .
H33I H -1.2627 1.1265 1.1536 0.064 Uiso 1 1 calc R . .
H33J H -1.1370 1.1171 1.1829 0.064 Uiso 1 1 calc R . .
H33K H -1.2358 1.0848 1.2036 0.064 Uiso 1 1 calc R . .
C322 C -0.8950(4) 1.09232(16) 1.1565(2) 0.0464(12) Uani 1 1 d . . .
H32G H -0.8193 1.1067 1.1597 0.070 Uiso 1 1 calc R . .
H32H H -0.9332 1.1106 1.1829 0.070 Uiso 1 1 calc R . .
H32I H -0.9354 1.0991 1.1196 0.070 Uiso 1 1 calc R . .
C323 C -0.8114(3) 1.00888(18) 1.24104(16) 0.0387(10) Uani 1 1 d . . .
H32J H -0.7382 1.0261 1.2440 0.058 Uiso 1 1 calc R . .
H32K H -0.8023 0.9699 1.2498 0.058 Uiso 1 1 calc R . .
H32L H -0.8529 1.0264 1.2666 0.058 Uiso 1 1 calc R . .
C313 C -1.2206(3) 0.86689(16) 1.09626(16) 0.0342(9) Uani 1 1 d . A .
H31I H -1.2321 0.8401 1.0666 0.051 Uiso 1 1 calc R . .
H31J H -1.2862 0.8904 1.0937 0.051 Uiso 1 1 calc R . .
H31K H -1.2087 0.8477 1.1313 0.051 Uiso 1 1 calc R . .
K1 K -1.41079(9) 0.76723(4) 1.07083(5) 0.0557(3) Uani 1 1 d . . .
O1 O -1.3152(2) 0.66901(11) 1.05229(11) 0.0387(7) Uani 1 1 d . A .
C11 C -1.1973(4) 0.66343(19) 1.0626(2) 0.0503(12) Uani 1 1 d . . .
H11A H -1.1722 0.6467 1.0308 0.060 Uiso 1 1 calc R A .
H11B H -1.1746 0.6392 1.0944 0.060 Uiso 1 1 calc R . .
C12 C -1.1456(4) 0.7175(2) 1.0736(2) 0.0644(15) Uani 1 1 d . A .
H12A H -1.0646 0.7135 1.0807 0.097 Uiso 1 1 calc R . .
H12B H -1.1700 0.7338 1.1054 0.097 Uiso 1 1 calc R . .
H12C H -1.1676 0.7412 1.0419 0.097 Uiso 1 1 calc R . .
C13 C -1.3678(5) 0.6174(2) 1.0424(2) 0.0597(14) Uani 1 1 d . . .
H13A H -1.3523 0.5944 1.0754 0.072 Uiso 1 1 calc R A .
H13B H -1.3395 0.5982 1.0126 0.072 Uiso 1 1 calc R . .
C14 C -1.4894(6) 0.6270(3) 1.0269(3) 0.127(3) Uani 1 1 d . A .
H14A H -1.5276 0.5919 1.0194 0.190 Uiso 1 1 calc R . .
H14B H -1.5037 0.6501 0.9944 0.190 Uiso 1 1 calc R . .
H14C H -1.5168 0.6454 1.0569 0.190 Uiso 1 1 calc R . .
O2 O -1.6158(3) 0.81165(16) 1.06089(18) 0.0844(13) Uani 1 1 d D A .
C21 C -1.6486(5) 0.8641(2) 1.0736(2) 0.0751(17) Uani 1 1 d D . .
H21A H -1.7074 0.8774 1.0442 0.090 Uiso 1 1 calc R A .
H21B H -1.6800 0.8628 1.1076 0.090 Uiso 1 1 calc R . .
C22 C -1.5611(6) 0.8995(3) 1.0801(4) 0.135(4) Uani 1 1 d D A .
H22A H -1.5860 0.9359 1.0895 0.203 Uiso 1 1 calc R . .
H22B H -1.5315 0.9018 1.0461 0.203 Uiso 1 1 calc R . .
H22C H -1.5029 0.8864 1.1093 0.203 Uiso 1 1 calc R . .
C23 C -1.7058(8) 0.7831(4) 1.0310(5) 0.288(10) Uani 1 1 d D . .
H23A H -1.7682 0.8089 1.0201 0.346 Uiso 1 1 calc R A .
H23B H -1.6838 0.7686 0.9974 0.346 Uiso 1 1 calc R . .
C24 C -1.7403(11) 0.7420(5) 1.0586(5) 0.251(8) Uani 1 1 d D A .
H24A H -1.8014 0.7229 1.0355 0.377 Uiso 1 1 calc R . .
H24B H -1.7661 0.7563 1.0909 0.377 Uiso 1 1 calc R . .
H24C H -1.6788 0.7165 1.0698 0.377 Uiso 1 1 calc R . .
O3 O -1.4154(4) 0.79372(19) 0.96549(18) 0.0957(15) Uani 1 1 d . A .
C31 C -1.3894(7) 0.7526(4) 0.9288(3) 0.129(3) Uani 1 1 d . . .
H31A H -1.3341 0.7666 0.9075 0.154 Uiso 1 1 calc R A .
H31B H -1.3581 0.7198 0.9492 0.154 Uiso 1 1 calc R . .
C32 C -1.4907(9) 0.7389(5) 0.8933(5) 0.234(7) Uani 1 1 d . A .
H32A H -1.4765 0.7100 0.8682 0.351 Uiso 1 1 calc R . .
H32B H -1.5196 0.7714 0.8725 0.351 Uiso 1 1 calc R . .
H32C H -1.5454 0.7261 0.9149 0.351 Uiso 1 1 calc R . .
C33 C -1.4542(14) 0.8486(9) 0.9430(5) 0.375(17) Uani 1 1 d . . .
H33A H -1.5197 0.8454 0.9137 0.450 Uiso 1 1 calc R A .
H33B H -1.4723 0.8732 0.9718 0.450 Uiso 1 1 calc R . .
C34 C -1.3634(11) 0.8663(7) 0.9235(5) 0.294(11) Uani 1 1 d . A .
H34A H -1.3792 0.9019 0.9059 0.441 Uiso 1 1 calc R . .
H34B H -1.3450 0.8399 0.8968 0.441 Uiso 1 1 calc R . .
H34C H -1.3006 0.8697 0.9535 0.441 Uiso 1 1 calc R . .
O4A O -1.4304(10) 0.7338(4) 1.1708(4) 0.055(3) Uani 0.571(11) 1 d PDU A 3
C41A C -1.3965(9) 0.6780(5) 1.1802(6) 0.085(4) Uani 0.571(11) 1 d PDU A 3
H41A H -1.4368 0.6628 1.2080 0.102 Uiso 0.571(11) 1 calc PR A 3
H41B H -1.4212 0.6574 1.1461 0.102 Uiso 0.571(11) 1 calc PR A 3
C42A C -1.2876(11) 0.6684(7) 1.1965(7) 0.079(5) Uani 0.571(11) 1 d PDU A 3
H42A H -1.2776 0.6331 1.2152 0.118 Uiso 0.571(11) 1 calc PR A 3
H42B H -1.2554 0.6975 1.2213 0.118 Uiso 0.571(11) 1 calc PR A 3
H42C H -1.2503 0.6677 1.1647 0.118 Uiso 0.571(11) 1 calc PR A 3
C43A C -1.4918(12) 0.7555(4) 1.2086(6) 0.101(5) Uani 0.571(11) 1 d PDU A 3
H43A H -1.5714 0.7532 1.1921 0.121 Uiso 0.571(11) 1 calc PR A 3
H43B H -1.4804 0.7311 1.2407 0.121 Uiso 0.571(11) 1 calc PR A 3
C44A C -1.4718(9) 0.8069(6) 1.2266(9) 0.117(7) Uani 0.571(11) 1 d PDU A 3
H44A H -1.5318 0.8190 1.2453 0.175 Uiso 0.571(11) 1 calc PR A 3
H44B H -1.4680 0.8312 1.1957 0.175 Uiso 0.571(11) 1 calc PR A 3
H44C H -1.4010 0.8081 1.2519 0.175 Uiso 0.571(11) 1 calc PR A 3
O4B O -1.3994(17) 0.7360(6) 1.1768(5) 0.085(6) Uani 0.429(11) 1 d PDU A 4
C41B C -1.3731(9) 0.6928(5) 1.2162(4) 0.046(3) Uani 0.429(11) 1 d PDU A 4
H41C H -1.3664 0.7092 1.2529 0.056 Uiso 0.429(11) 1 calc PR A 4
H41D H -1.4367 0.6672 1.2117 0.056 Uiso 0.429(11) 1 calc PR A 4
C42B C -1.2806(13) 0.6637(8) 1.2144(11) 0.098(10) Uani 0.429(11) 1 d PDU A 4
H42D H -1.2727 0.6352 1.2424 0.147 Uiso 0.429(11) 1 calc PR A 4
H42E H -1.2159 0.6880 1.2210 0.147 Uiso 0.429(11) 1 calc PR A 4
H42F H -1.2859 0.6467 1.1785 0.147 Uiso 0.429(11) 1 calc PR A 4
C43B C -1.4199(14) 0.7862(6) 1.2013(8) 0.131(7) Uani 0.429(11) 1 d PDU A 4
H43C H -1.3636 0.7906 1.2347 0.157 Uiso 0.429(11) 1 calc PR A 4
H43D H -1.4079 0.8160 1.1761 0.157 Uiso 0.429(11) 1 calc PR A 4
C44B C -1.5209(15) 0.7931(10) 1.2148(14) 0.163(12) Uani 0.429(11) 1 d PDU A 4
H44D H -1.5254 0.8296 1.2306 0.244 Uiso 0.429(11) 1 calc PR A 4
H44E H -1.5329 0.7652 1.2414 0.244 Uiso 0.429(11) 1 calc PR A 4
H44F H -1.5780 0.7896 1.1822 0.244 Uiso 0.429(11) 1 calc PR A 4
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
Ge1 Pb1A Ge3 105.23(2)
Ge1 Pb1A Ge2 106.482(18)
Ge3 Pb1A Ge2 106.650(19)
Si11 Ge1 Si12 104.16(4)
Si11 Ge1 Si13 109.21(4)
Si12 Ge1 Si13 99.20(4)
Si11 Ge1 Pb1A 129.23(4)
Si12 Ge1 Pb1A 105.69(3)
Si13 Ge1 Pb1A 105.38(3)
Si23 Ge2 Si22 104.21(4)
Si23 Ge2 Si21 97.80(4)
Si22 Ge2 Si21 108.39(4)
Si23 Ge2 Pb1A 106.44(3)
Si22 Ge2 Pb1A 129.84(3)
Si21 Ge2 Pb1A 105.63(3)
Si33 Ge3 Si31 98.32(4)
Si33 Ge3 Si32 104.93(4)
Si31 Ge3 Si32 110.00(4)
Si33 Ge3 Pb1A 110.08(4)
Si31 Ge3 Pb1A 103.91(3)
Si32 Ge3 Pb1A 126.20(3)
C112 Si11 C113 105.5(2)
C112 Si11 C111 105.1(2)
C113 Si11 C111 108.6(2)
C112 Si11 Ge1 113.33(14)
C113 Si11 Ge1 111.95(14)
C111 Si11 Ge1 111.89(15)
C123 Si12 C122 109.48(19)
C123 Si12 C121 104.75(19)
C122 Si12 C121 105.7(2)
C123 Si12 Ge1 111.04(13)
C122 Si12 Ge1 109.13(14)
C121 Si12 Ge1 116.43(13)
C133 Si13 C132 104.9(2)
C133 Si13 C131 104.3(2)
C132 Si13 C131 106.6(2)
C133 Si13 Ge1 118.12(15)
C132 Si13 Ge1 109.40(15)
C131 Si13 Ge1 112.73(13)
C221 Si22 C223 105.1(2)
C221 Si22 C222 105.6(2)
C223 Si22 C222 108.0(2)
C221 Si22 Ge2 114.23(14)
C223 Si22 Ge2 110.86(14)
C222 Si22 Ge2 112.53(14)
C211 Si21 C213 106.0(2)
C211 Si21 C212 102.8(2)
C213 Si21 C212 105.6(2)
C211 Si21 Ge2 114.40(16)
C213 Si21 Ge2 108.84(16)
C212 Si21 Ge2 118.22(14)
C232 Si23 C231 107.9(2)
C232 Si23 C233 104.3(2)
C231 Si23 C233 106.3(2)
C232 Si23 Ge2 111.50(14)
C231 Si23 Ge2 109.54(15)
C233 Si23 Ge2 116.83(15)
C312 Si31 C311 102.4(2)
C312 Si31 C313 106.33(19)
C311 Si31 C313 104.8(2)
C312 Si31 Ge3 114.53(15)
C311 Si31 Ge3 118.65(14)
C313 Si31 Ge3 109.04(13)
C322 Si32 C321 105.6(2)
C322 Si32 C323 105.8(2)
C321 Si32 C323 108.1(2)
C322 Si32 Ge3 113.95(15)
C321 Si32 Ge3 113.81(14)
C323 Si32 Ge3 109.15(15)
C333 Si33 C332 104.4(2)
C333 Si33 C331 107.9(2)
C332 Si33 C331 106.5(2)
C333 Si33 Ge3 111.79(14)
C332 Si33 Ge3 116.01(17)
C331 Si33 Ge3 109.72(14)
Si31 C313 K1 160.02(19)
O4A K1 O3 172.6(3)
O4A K1 O2 88.7(2)
O3 K1 O2 87.22(15)
O4A K1 O4B 8.1(6)
O3 K1 O4B 177.1(3)
O2 K1 O4B 95.3(4)
O4A K1 O1 89.99(18)
O3 K1 O1 89.05(12)
O2 K1 O1 138.69(11)
O4B K1 O1 88.1(2)
O4A K1 C43B 26.0(4)
O3 K1 C43B 157.9(3)
O2 K1 C43B 81.1(3)
O4B K1 C43B 24.8(2)
O1 K1 C43B 112.1(3)
O4A K1 C313 102.5(3)
O3 K1 C313 84.66(13)
O2 K1 C313 109.09(12)
O4B K1 C313 95.9(4)
O1 K1 C313 111.48(10)
C43B K1 C313 81.5(3)
O4A K1 C12 96.3(2)
O3 K1 C12 87.98(15)
O2 K1 C12 174.84(15)
O4B K1 C12 89.5(4)
O1 K1 C12 43.07(10)
C43B K1 C12 102.8(3)
C313 K1 C12 68.52(11)
O4A K1 C41A 22.5(2)
O3 K1 C41A 154.9(2)
O2 K1 C41A 104.1(2)
O4B K1 C41A 22.7(4)
O1 K1 C41A 67.6(2)
C43B K1 C41A 47.2(4)
C313 K1 C41A 111.6(2)
C12 K1 C41A 81.0(2)
C13 O1 C11 111.1(4)
C13 O1 K1 127.9(3)
C11 O1 K1 120.0(2)
O1 C11 C12 109.7(4)
C11 C12 K1 86.6(3)
O1 C13 C14 107.9(5)
C21 O2 C23 110.3(6)
C21 O2 K1 130.3(3)
C23 O2 K1 118.6(6)
C22 C21 O2 111.1(5)
C24 C23 O2 112.9(8)
C31 O3 C33 118.7(7)
C31 O3 K1 119.0(4)
C33 O3 K1 122.1(5)
C32 C31 O3 107.2(8)
C34 C33 O3 101.2(11)
C43A O4A C41A 114.9(8)
C43A O4A K1 131.0(7)
C41A O4A K1 111.9(6)
C42A C41A O4A 117.3(9)
C42A C41A K1 105.0(9)
O4A C41A K1 45.6(5)
C44A C43A O4A 119.3(10)
C43B O4B C41B 112.2(9)
C43B O4B K1 101.1(8)
C41B O4B K1 146.4(8)
C42B C41B O4B 117.1(10)
C44B C43B O4B 117.2(12)
C44B C43B K1 116.9(16)
O4B C43B K1 54.2(6)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Pb1A Ge1 2.8404(6)
Pb1A Ge3 2.8589(6)
Pb1A Ge2 2.8626(6)
Ge1 Si11 2.3732(12)
Ge1 Si12 2.3745(12)
Ge1 Si13 2.3919(12)
Ge2 Si23 2.3750(12)
Ge2 Si22 2.3825(11)
Ge2 Si21 2.3992(12)
Ge3 Si33 2.3689(12)
Ge3 Si31 2.3848(12)
Ge3 Si32 2.3851(12)
Si11 C112 1.879(4)
Si11 C113 1.885(4)
Si11 C111 1.888(4)
Si12 C123 1.871(4)
Si12 C122 1.877(4)
Si12 C121 1.893(4)
Si13 C133 1.877(4)
Si13 C132 1.877(4)
Si13 C131 1.882(4)
Si22 C221 1.869(4)
Si22 C223 1.878(4)
Si22 C222 1.885(4)
Si21 C211 1.881(4)
Si21 C213 1.883(5)
Si21 C212 1.889(4)
Si23 C232 1.873(4)
Si23 C231 1.877(4)
Si23 C233 1.889(4)
Si31 C312 1.871(4)
Si31 C311 1.887(4)
Si31 C313 1.895(4)
Si32 C322 1.871(4)
Si32 C321 1.872(4)
Si32 C323 1.873(4)
Si33 C333 1.874(4)
Si33 C332 1.888(4)
Si33 C331 1.892(4)
C313 K1 3.352(4)
K1 O4A 2.675(8)
K1 O3 2.699(5)
K1 O2 2.703(4)
K1 O4B 2.734(12)
K1 O1 2.744(3)
K1 C43B 3.31(2)
K1 C12 3.452(5)
K1 C41A 3.474(13)
O1 C13 1.419(5)
O1 C11 1.425(5)
C11 C12 1.471(6)
C13 C14 1.487(8)
O2 C21 1.397(5)
O2 C23 1.404(6)
C21 C22 1.364(7)
C23 C24 1.329(8)
O3 C31 1.432(9)
O3 C33 1.500(16)
C31 C32 1.432(10)
C33 C34 1.356(19)
O4A C43A 1.406(10)
O4A C41A 1.434(9)
C41A C42A 1.344(10)
C43A C44A 1.344(12)
O4B C43B 1.412(10)
O4B C41B 1.439(9)
C41B C42B 1.343(10)
C43B C44B 1.346(12)
