#------------------------------------------------------------------------------
#$Date: 2016-10-08 01:08:46 +0300 (Sat, 08 Oct 2016) $
#$Revision: 187087 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/04/7040481.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7040481
loop_
_publ_author_name
'Li, Chuan-Ti'
'Zhao, Yi-Fan'
'Hu, Huai-Ming'
'Zhao, Hui'
'Wang, Xiaofang'
'Xue, Ganglin'
_publ_section_title
;
 Lanthanide coordination frameworks constructed from
 3,3',4,4'-diphenylsulfonetetracarboxylic and 1,10-phenanthroline:
 synthesis, crystal structures and luminescence properties.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15436
_journal_paper_doi               10.1039/c6dt02646j
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C16 H10 Eu O13 S'
_chemical_formula_weight         594.26
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-07-01 deposited with the CCDC.
2016-08-25 downloaded from the CCDC.
;
_cell_angle_alpha                109.572(2)
_cell_angle_beta                 94.896(2)
_cell_angle_gamma                93.260(3)
_cell_formula_units_Z            2
_cell_length_a                   5.9204(10)
_cell_length_b                   13.177(2)
_cell_length_c                   13.667(2)
_cell_measurement_reflns_used    4043
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.08
_cell_measurement_theta_min      2.65
_cell_volume                     996.8(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0278
_diffrn_reflns_av_sigmaI/netI    0.0525
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            4882
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.86
_exptl_absorpt_coefficient_mu    3.319
_exptl_absorpt_correction_T_max  0.647
_exptl_absorpt_correction_T_min  0.534
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.980
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             578
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.13
_refine_diff_density_max         1.945
_refine_diff_density_min         -1.412
_refine_diff_density_rms         0.162
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.029
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     301
_refine_ls_number_reflns         3459
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.028
_refine_ls_R_factor_all          0.0408
_refine_ls_R_factor_gt           0.0394
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0650P)²+3.0822P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1066
_refine_ls_wR_factor_ref         0.1086
_reflns_number_gt                3354
_reflns_number_total             3459
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6dt02646j2.cif
_cod_data_source_block           nw1946_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7040480--7040491.cif.
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7040481
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.62418(4) 0.63678(2) 0.13594(2) 0.02017(13) Uani 1 1 d .
S1 S 0.5339(3) 0.11328(13) 0.24942(12) 0.0271(3) Uani 1 1 d .
O1 O 0.6103(7) 0.4251(3) 0.0266(3) 0.0256(9) Uani 1 1 d .
O2 O 0.8283(8) 0.4941(4) 0.1744(4) 0.0313(10) Uani 1 1 d .
O3 O 1.0882(7) 0.3800(4) -0.0161(4) 0.0301(10) Uani 1 1 d .
O4 O 1.2454(8) 0.2262(4) -0.0635(4) 0.0337(11) Uani 1 1 d .
O5 O 1.3151(7) 0.3221(4) 0.6712(4) 0.0321(10) Uani 1 1 d .
O6 O 1.0496(8) 0.2565(4) 0.7418(3) 0.0362(11) Uani 1 1 d .
O7 O 1.3455(8) 0.0930(4) 0.5730(4) 0.0371(11) Uani 1 1 d .
O8 O 1.2836(8) 0.0015(4) 0.4029(4) 0.0374(11) Uani 1 1 d .
O9 O 0.3312(8) 0.1677(4) 0.2662(4) 0.0385(12) Uani 1 1 d .
O10 O 0.5193(9) -0.0034(4) 0.2060(4) 0.0413(12) Uani 1 1 d .
C1 C 0.7445(9) 0.4142(5) 0.0987(4) 0.0210(12) Uani 1 1 d .
C2 C 0.7880(10) 0.3031(5) 0.0998(4) 0.0209(12) Uani 1 1 d .
C3 C 0.6544(10) 0.2611(5) 0.1598(5) 0.0260(13) Uani 1 1 d .
H3 H 0.5402 0.3000 0.1934 0.031 Uiso 1 1 calc R
C4 C 0.6917(11) 0.1630(5) 0.1692(5) 0.0269(13) Uani 1 1 d .
C5 C 0.8604(11) 0.1031(5) 0.1199(5) 0.0309(14) Uani 1 1 d .
H5 H 0.8838 0.0363 0.1262 0.037 Uiso 1 1 calc R
C6 C 0.9940(12) 0.1447(6) 0.0607(5) 0.0311(14) Uani 1 1 d .
H6 H 1.1088 0.1057 0.0279 0.037 Uiso 1 1 calc R
C7 C 0.9573(10) 0.2445(5) 0.0503(4) 0.0234(12) Uani 1 1 d .
C8 C 1.1057(10) 0.2857(5) -0.0136(5) 0.0263(13) Uani 1 1 d .
C9 C 1.1290(11) 0.2680(5) 0.6631(5) 0.0265(13) Uani 1 1 d .
C10 C 0.9853(11) 0.2232(5) 0.5582(5) 0.0274(13) Uani 1 1 d .
C11 C 0.7923(12) 0.2736(6) 0.5467(5) 0.0360(16) Uani 1 1 d .
H11 H 0.7535 0.3299 0.6032 0.043 Uiso 1 1 calc R
C12 C 0.6561(11) 0.2421(5) 0.4530(5) 0.0330(15) Uani 1 1 d .
H12 H 0.5296 0.2786 0.4454 0.040 Uiso 1 1 calc R
C13 C 0.7094(10) 0.1552(5) 0.3698(5) 0.0240(12) Uani 1 1 d .
C14 C 0.9018(10) 0.1020(5) 0.3812(5) 0.0258(13) Uani 1 1 d .
H14 H 0.9381 0.0442 0.3255 0.031 Uiso 1 1 calc R
C15 C 1.0383(10) 0.1355(5) 0.4755(5) 0.0251(13) Uani 1 1 d .
C16 C 1.2382(10) 0.0745(5) 0.4860(5) 0.0248(13) Uani 1 1 d .
O11 O 0.3020(8) 0.5465(4) 0.1775(4) 0.0425(12) Uani 1 1 d D
H11A H 0.165(6) 0.553(7) 0.189(7) 0.051 Uiso 1 1 d D
H11B H 0.215(13) 0.524(7) 0.120(4) 0.051 Uiso 1 1 d D
O12 O 0.3759(8) 0.7798(4) 0.1909(4) 0.0340(11) Uani 1 1 d D
H12A H 0.412(14) 0.840(3) 0.184(6) 0.041 Uiso 1 1 d D
H12B H 0.259(8) 0.774(6) 0.220(6) 0.041 Uiso 1 1 d D
O13 O 0.264(5) 0.5001(15) 0.5872(17) 0.160(12) Uani 0.50 1 d P
O14 O 0.255(5) 0.4263(17) 0.3298(18) 0.158(12) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 O11 78.38(17) 2_665 .
O1 Eu1 O12 86.67(16) 2_665 .
O11 Eu1 O12 77.76(18) . .
O1 Eu1 O3 79.70(15) 2_665 2_765
O11 Eu1 O3 145.12(17) . 2_765
O12 Eu1 O3 127.54(15) . 2_765
O1 Eu1 O4 80.76(16) 2_665 2_765
O11 Eu1 O4 145.95(18) . 2_765
O12 Eu1 O4 74.43(15) . 2_765
O3 Eu1 O4 53.52(14) 2_765 2_765
O1 Eu1 O6 154.17(15) 2_665 2_766
O11 Eu1 O6 126.88(17) . 2_766
O12 Eu1 O6 93.34(17) . 2_766
O3 Eu1 O6 79.90(15) 2_765 2_766
O4 Eu1 O6 74.41(17) 2_765 2_766
O1 Eu1 O2 113.80(14) 2_665 .
O11 Eu1 O2 83.19(18) . .
O12 Eu1 O2 148.56(16) . .
O3 Eu1 O2 81.27(15) 2_765 .
O4 Eu1 O2 130.15(15) 2_765 .
O6 Eu1 O2 78.36(16) 2_766 .
O1 Eu1 O5 151.81(15) 2_665 2_766
O11 Eu1 O5 74.41(17) . 2_766
O12 Eu1 O5 80.58(16) . 2_766
O3 Eu1 O5 127.75(15) 2_765 2_766
O4 Eu1 O5 119.08(16) 2_765 2_766
O6 Eu1 O5 52.49(14) 2_766 2_766
O2 Eu1 O5 70.27(15) . 2_766
O1 Eu1 O1 63.87(15) 2_665 .
O11 Eu1 O1 71.74(16) . .
O12 Eu1 O1 140.87(15) . .
O3 Eu1 O1 74.34(14) 2_765 .
O4 Eu1 O1 121.38(14) 2_765 .
O6 Eu1 O1 124.53(15) 2_766 .
O2 Eu1 O1 49.97(13) . .
O5 Eu1 O1 113.07(14) 2_766 .
O1 Eu1 C8 79.38(16) 2_665 2_765
O11 Eu1 C8 157.76(19) . 2_765
O12 Eu1 C8 100.95(17) . 2_765
O3 Eu1 C8 26.86(16) 2_765 2_765
O4 Eu1 C8 26.66(17) 2_765 2_765
O6 Eu1 C8 75.26(16) 2_766 2_765
O2 Eu1 C8 105.98(17) . 2_765
O5 Eu1 C8 127.61(16) 2_766 2_765
O1 Eu1 C8 98.31(16) . 2_765
O1 Eu1 C9 173.06(15) 2_665 2_766
O11 Eu1 C9 100.61(19) . 2_766
O12 Eu1 C9 86.41(17) . 2_766
O3 Eu1 C9 104.22(17) 2_765 2_766
O4 Eu1 C9 96.89(18) 2_765 2_766
O6 Eu1 C9 26.29(17) 2_766 2_766
O2 Eu1 C9 72.71(16) . 2_766
O5 Eu1 C9 26.20(17) 2_766 2_766
O1 Eu1 C9 122.50(16) . 2_766
C8 Eu1 C9 101.47(18) 2_765 2_766
O1 Eu1 Eu1 34.05(10) 2_665 2_665
O11 Eu1 Eu1 72.12(13) . 2_665
O12 Eu1 Eu1 116.85(12) . 2_665
O3 Eu1 Eu1 74.49(11) 2_765 2_665
O4 Eu1 Eu1 103.64(12) 2_765 2_665
O6 Eu1 Eu1 148.43(12) 2_766 2_665
O2 Eu1 Eu1 79.77(11) . 2_665
O5 Eu1 Eu1 137.10(11) 2_766 2_665
O1 Eu1 Eu1 29.82(8) . 2_665
C8 Eu1 Eu1 89.32(13) 2_765 2_665
C9 Eu1 Eu1 152.24(12) 2_766 2_665
O1 Eu1 H11B 60.5(10) 2_665 .
O11 Eu1 H11B 17.9(10) . .
O12 Eu1 H11B 77.9(19) . .
O3 Eu1 H11B 132.4(15) 2_765 .
O4 Eu1 H11B 133.2(14) 2_765 .
O6 Eu1 H11B 144.6(11) 2_766 .
O2 Eu1 H11B 91.3(17) . .
O5 Eu1 H11B 92.1(11) 2_766 .
O1 Eu1 H11B 65.5(19) . .
C8 Eu1 H11B 139.9(10) 2_765 .
C9 Eu1 H11B 118.3(11) 2_766 .
Eu1 Eu1 H11B 57.9(15) 2_665 .
O9 S1 O10 120.1(3) . .
O9 S1 C4 108.9(3) . .
O10 S1 C4 107.1(3) . .
O9 S1 C13 107.7(3) . .
O10 S1 C13 108.2(3) . .
C4 S1 C13 103.6(3) . .
C1 O1 Eu1 154.8(4) . 2_665
C1 O1 Eu1 89.1(3) . .
Eu1 O1 Eu1 116.13(15) 2_665 .
C1 O2 Eu1 99.7(4) . .
C8 O3 Eu1 92.9(4) . 2_765
C8 O4 Eu1 92.1(4) . 2_765
C9 O5 Eu1 92.2(4) . 2_766
C9 O6 Eu1 93.7(4) . 2_766
O2 C1 O1 121.0(5) . .
O2 C1 C2 118.5(5) . .
O1 C1 C2 120.3(5) . .
C7 C2 C3 119.4(5) . .
C7 C2 C1 123.8(5) . .
C3 C2 C1 116.7(5) . .
C4 C3 C2 120.2(6) . .
C4 C3 H3 119.9 . .
C2 C3 H3 119.9 . .
C3 C4 C5 121.2(6) . .
C3 C4 S1 120.3(5) . .
C5 C4 S1 118.5(5) . .
C4 C5 C6 118.8(6) . .
C4 C5 H5 120.6 . .
C6 C5 H5 120.6 . .
C5 C6 C7 120.6(6) . .
C5 C6 H6 119.7 . .
C7 C6 H6 119.7 . .
C2 C7 C6 119.8(6) . .
C2 C7 C8 121.7(5) . .
C6 C7 C8 118.5(6) . .
O4 C8 O3 121.5(6) . .
O4 C8 C7 119.4(6) . .
O3 C8 C7 119.2(5) . .
O4 C8 Eu1 61.2(3) . 2_765
O3 C8 Eu1 60.3(3) . 2_765
C7 C8 Eu1 178.8(4) . 2_765
O5 C9 O6 121.6(6) . .
O5 C9 C10 119.6(6) . .
O6 C9 C10 118.6(6) . .
O5 C9 Eu1 61.6(3) . 2_766
O6 C9 Eu1 60.0(3) . 2_766
C10 C9 Eu1 175.9(4) . 2_766
C11 C10 C15 119.7(6) . .
C11 C10 C9 116.6(6) . .
C15 C10 C9 123.7(6) . .
C12 C11 C10 121.1(6) . .
C12 C11 H11 119.5 . .
C10 C11 H11 119.5 . .
C11 C12 C13 119.4(6) . .
C11 C12 H12 120.3 . .
C13 C12 H12 120.3 . .
C12 C13 C14 120.0(6) . .
C12 C13 S1 119.7(5) . .
C14 C13 S1 120.2(5) . .
C15 C14 C13 119.9(6) . .
C15 C14 H14 120.1 . .
C13 C14 H14 120.1 . .
C14 C15 C10 119.9(6) . .
C14 C15 C16 118.4(5) . .
C10 C15 C16 121.7(6) . .
O7 C16 O8 123.4(6) . .
O7 C16 C15 119.9(6) . .
O8 C16 C15 116.7(5) . .
Eu1 O11 H11A 142(6) . .
Eu1 O11 H11B 103(6) . .
H11A O11 H11B 70(7) . .
Eu1 O12 H12A 119(6) . .
Eu1 O12 H12B 123(5) . .
H12A O12 H12B 119(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1 2.379(4) 2_665
Eu1 O11 2.399(5) .
Eu1 O12 2.415(5) .
Eu1 O3 2.431(4) 2_765
Eu1 O4 2.451(5) 2_765
Eu1 O6 2.463(5) 2_766
Eu1 O2 2.466(4) .
Eu1 O5 2.497(5) 2_766
Eu1 O1 2.679(4) .
Eu1 C8 2.795(6) 2_765
Eu1 C9 2.837(6) 2_766
Eu1 Eu1 4.2959(7) 2_665
Eu1 H11B 2.72(8) .
S1 O9 1.429(5) .
S1 O10 1.445(5) .
S1 C4 1.758(6) .
S1 C13 1.768(6) .
O1 C1 1.263(7) .
O1 Eu1 2.379(4) 2_665
O2 C1 1.244(7) .
O3 C8 1.264(8) .
O3 Eu1 2.431(4) 2_765
O4 C8 1.255(8) .
O4 Eu1 2.451(5) 2_765
O5 C9 1.253(8) .
O5 Eu1 2.497(5) 2_766
O6 C9 1.259(8) .
O6 Eu1 2.463(5) 2_766
O7 C16 1.240(8) .
O8 C16 1.279(8) .
C1 C2 1.506(8) .
C2 C7 1.383(8) .
C2 C3 1.404(8) .
C3 C4 1.368(9) .
C3 H3 0.9300 .
C4 C5 1.387(9) .
C5 C6 1.392(9) .
C5 H5 0.9300 .
C6 C7 1.396(9) .
C6 H6 0.9300 .
C7 C8 1.491(8) .
C8 Eu1 2.795(6) 2_765
C9 C10 1.515(9) .
C9 Eu1 2.837(6) 2_766
C10 C11 1.378(9) .
C10 C15 1.393(9) .
C11 C12 1.375(10) .
C11 H11 0.9300 .
C12 C13 1.391(9) .
C12 H12 0.9300 .
C13 C14 1.395(9) .
C14 C15 1.381(9) .
C14 H14 0.9300 .
C15 C16 1.491(8) .
O11 H11A 0.84(2) .
O11 H11B 0.86(2) .
O12 H12A 0.85(2) .
O12 H12B 0.84(2) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Eu1 O1 C1 -179.5(4) 2_665 .
O11 Eu1 O1 C1 -93.8(3) . .
O12 Eu1 O1 C1 -134.4(3) . .
O3 Eu1 O1 C1 94.5(3) 2_765 .
O4 Eu1 O1 C1 121.0(3) 2_765 .
O6 Eu1 O1 C1 28.9(4) 2_766 .
O2 Eu1 O1 C1 2.8(3) . .
O5 Eu1 O1 C1 -30.4(4) 2_766 .
C8 Eu1 O1 C1 106.7(3) 2_765 .
C9 Eu1 O1 C1 -2.7(4) 2_766 .
Eu1 Eu1 O1 C1 -179.5(4) 2_665 .
O1 Eu1 O1 Eu1 0.0 2_665 2_665
O11 Eu1 O1 Eu1 85.7(2) . 2_665
O12 Eu1 O1 Eu1 45.1(3) . 2_665
O3 Eu1 O1 Eu1 -86.0(2) 2_765 2_665
O4 Eu1 O1 Eu1 -59.4(2) 2_765 2_665
O6 Eu1 O1 Eu1 -151.58(17) 2_766 2_665
O2 Eu1 O1 Eu1 -177.7(3) . 2_665
O5 Eu1 O1 Eu1 149.11(17) 2_766 2_665
C8 Eu1 O1 Eu1 -73.8(2) 2_765 2_665
C9 Eu1 O1 Eu1 176.86(18) 2_766 2_665
O1 Eu1 O2 C1 -5.1(4) 2_665 .
O11 Eu1 O2 C1 69.0(4) . .
O12 Eu1 O2 C1 121.8(4) . .
O3 Eu1 O2 C1 -79.7(4) 2_765 .
O4 Eu1 O2 C1 -103.3(4) 2_765 .
O6 Eu1 O2 C1 -161.1(4) 2_766 .
O5 Eu1 O2 C1 144.8(4) 2_766 .
O1 Eu1 O2 C1 -2.8(3) . .
C8 Eu1 O2 C1 -90.3(4) 2_765 .
C9 Eu1 O2 C1 172.4(4) 2_766 .
Eu1 Eu1 O2 C1 -4.0(3) 2_665 .
Eu1 O2 C1 O1 5.4(6) . .
Eu1 O2 C1 C2 -168.7(4) . .
Eu1 O1 C1 O2 176.1(6) 2_665 .
Eu1 O1 C1 O2 -4.9(6) . .
Eu1 O1 C1 C2 -9.9(12) 2_665 .
Eu1 O1 C1 C2 169.1(5) . .
O2 C1 C2 C7 -96.9(7) . .
O1 C1 C2 C7 89.0(7) . .
O2 C1 C2 C3 79.5(7) . .
O1 C1 C2 C3 -94.6(7) . .
C7 C2 C3 C4 0.0(9) . .
C1 C2 C3 C4 -176.6(6) . .
C2 C3 C4 C5 -0.2(10) . .
C2 C3 C4 S1 176.9(5) . .
O9 S1 C4 C3 20.0(6) . .
O10 S1 C4 C3 151.3(5) . .
C13 S1 C4 C3 -94.4(6) . .
O9 S1 C4 C5 -162.8(5) . .
O10 S1 C4 C5 -31.5(6) . .
C13 S1 C4 C5 82.8(6) . .
C3 C4 C5 C6 0.5(10) . .
S1 C4 C5 C6 -176.6(5) . .
C4 C5 C6 C7 -0.7(10) . .
C3 C2 C7 C6 -0.2(9) . .
C1 C2 C7 C6 176.2(6) . .
C3 C2 C7 C8 -179.4(5) . .
C1 C2 C7 C8 -3.1(9) . .
C5 C6 C7 C2 0.5(10) . .
C5 C6 C7 C8 179.8(6) . .
Eu1 O4 C8 O3 -1.3(6) 2_765 .
Eu1 O4 C8 C7 178.8(5) 2_765 .
Eu1 O3 C8 O4 1.4(6) 2_765 .
Eu1 O3 C8 C7 -178.8(5) 2_765 .
C2 C7 C8 O4 -174.6(6) . .
C6 C7 C8 O4 6.2(9) . .
C2 C7 C8 O3 5.5(9) . .
C6 C7 C8 O3 -173.7(6) . .
C2 C7 C8 Eu1 -57(22) . 2_765
C6 C7 C8 Eu1 124(22) . 2_765
Eu1 O5 C9 O6 0.9(6) 2_766 .
Eu1 O5 C9 C10 175.5(5) 2_766 .
Eu1 O6 C9 O5 -0.9(6) 2_766 .
Eu1 O6 C9 C10 -175.6(5) 2_766 .
O5 C9 C10 C11 -106.3(7) . .
O6 C9 C10 C11 68.6(8) . .
Eu1 C9 C10 C11 -1(7) 2_766 .
O5 C9 C10 C15 73.8(8) . .
O6 C9 C10 C15 -111.3(7) . .
Eu1 C9 C10 C15 179(100) 2_766 .
C15 C10 C11 C12 -3.1(11) . .
C9 C10 C11 C12 177.0(7) . .
C10 C11 C12 C13 2.5(11) . .
C11 C12 C13 C14 -1.1(10) . .
C11 C12 C13 S1 179.4(6) . .
O9 S1 C13 C12 -11.1(6) . .
O10 S1 C13 C12 -142.4(5) . .
C4 S1 C13 C12 104.1(6) . .
O9 S1 C13 C14 169.4(5) . .
O10 S1 C13 C14 38.2(6) . .
C4 S1 C13 C14 -75.3(5) . .
C12 C13 C14 C15 0.4(9) . .
S1 C13 C14 C15 179.9(5) . .
C13 C14 C15 C10 -1.0(9) . .
C13 C14 C15 C16 178.0(5) . .
C11 C10 C15 C14 2.3(10) . .
C9 C10 C15 C14 -177.8(6) . .
C11 C10 C15 C16 -176.7(6) . .
C9 C10 C15 C16 3.2(10) . .
C14 C15 C16 O7 -170.3(6) . .
C10 C15 C16 O7 8.7(9) . .
C14 C15 C16 O8 7.0(9) . .
C10 C15 C16 O8 -174.0(6) . .
