#------------------------------------------------------------------------------
#$Date: 2017-01-09 05:23:51 +0200 (Mon, 09 Jan 2017) $
#$Revision: 190148 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/08/7040857.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7040857
loop_
_publ_author_name
'Wang, Hui-Sheng'
'Yang, Feng-Jun'
'Long, Qiao-Qiao'
'Huang, Zhi-Yong'
'Chen, Wei'
'Pan, Zhi-Quan'
'Song, You'
_publ_section_title
;
 Two unprecedented decanuclear heterometallic [MnMnLn] (Ln = Dy, Tb)
 complexes displaying relaxation of magnetization.
;
_journal_issue                   45
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              18221
_journal_page_last               18228
_journal_paper_doi               10.1039/c6dt02945k
_journal_volume                  45
_journal_year                    2016
_chemical_formula_sum            'C92 H126 Dy2 Mn8 N18 O38'
_chemical_formula_weight         2856.62
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2016-08-29 deposited with the CCDC.
2016-10-11 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 94.4780(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   22.2955(10)
_cell_length_b                   14.4552(6)
_cell_length_c                   35.1699(16)
_cell_measurement_reflns_used    9628
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      24.8303
_cell_measurement_theta_min      3.0702
_cell_volume                     11300.2(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'PHOTON100 CMOS detector'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0549
_diffrn_reflns_av_unetI/netI     0.0855
_diffrn_reflns_Laue_measured_fraction_full 0.991
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       21
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       38
_diffrn_reflns_limit_l_min       -41
_diffrn_reflns_number            32988
_diffrn_reflns_point_group_measured_fraction_full 0.991
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         3.049
_exptl_absorpt_coefficient_mu    2.254
_exptl_absorpt_correction_T_max  0.7452
_exptl_absorpt_correction_T_min  0.6416
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2012)'
_exptl_crystal_colour            'dark red'
_exptl_crystal_density_diffrn    1.679
_exptl_crystal_description       rodlike
_exptl_crystal_F_000             5760
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.11
_refine_diff_density_max         1.042
_refine_diff_density_min         -0.716
_refine_diff_density_rms         0.125
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     723
_refine_ls_number_reflns         9857
_refine_ls_number_restraints     42
_refine_ls_restrained_S_all      1.023
_refine_ls_R_factor_all          0.0820
_refine_ls_R_factor_gt           0.0427
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0384P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0764
_refine_ls_wR_factor_ref         0.0839
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6888
_reflns_number_total             9857
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6dt02945k2.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 7040857--7040858.cif.'
_cod_database_code               7040857
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.2043(2) 0.9680(4) 0.22590(15) 0.0267(14) Uani 1 1 d . . . . .
H1 H 0.2207 1.0267 0.2203 0.032 Uiso 1 1 calc R U . . .
C2 C 0.2063(2) 0.9394(4) 0.26328(15) 0.0304(15) Uani 1 1 d . . . . .
H2 H 0.2239 0.9775 0.2832 0.037 Uiso 1 1 calc R U . . .
C3 C 0.1824(2) 0.8545(4) 0.27116(15) 0.0293(15) Uani 1 1 d . . . . .
H3 H 0.1833 0.8330 0.2967 0.035 Uiso 1 1 calc R U . . .
C4 C 0.1572(2) 0.8008(4) 0.24155(14) 0.0238(13) Uani 1 1 d . . . . .
H4 H 0.1405 0.7419 0.2465 0.029 Uiso 1 1 calc R U . . .
C5 C 0.1566(2) 0.8340(3) 0.20464(14) 0.0151(12) Uani 1 1 d . . . . .
C6 C 0.1345(2) 0.7788(3) 0.16972(13) 0.0151(12) Uani 1 1 d . . . . .
C7 C 0.0741(2) 0.7351(4) 0.17552(13) 0.0159(12) Uani 1 1 d . . . . .
C8 C 0.0265(2) 0.7886(4) 0.18612(15) 0.0297(14) Uani 1 1 d . . . . .
H8 H 0.0316 0.8532 0.1901 0.036 Uiso 1 1 calc R U . . .
C9 C -0.0281(2) 0.7477(4) 0.19088(16) 0.0364(16) Uani 1 1 d . . . . .
H9 H -0.0612 0.7835 0.1980 0.044 Uiso 1 1 calc R U . . .
C10 C -0.0338(2) 0.6546(4) 0.18521(15) 0.0327(15) Uani 1 1 d . . . . .
H10 H -0.0711 0.6247 0.1882 0.039 Uiso 1 1 calc R U . . .
C11 C 0.0146(2) 0.6047(4) 0.17517(15) 0.0275(14) Uani 1 1 d . . . . .
H11 H 0.0102 0.5397 0.1719 0.033 Uiso 1 1 calc R U . . .
C12 C 0.0936(2) 0.3822(4) 0.10911(15) 0.0247(13) Uani 1 1 d . . . . .
H12 H 0.1007 0.3549 0.1336 0.030 Uiso 1 1 calc R U . . .
C13 C 0.0687(2) 0.3285(4) 0.07977(16) 0.0283(14) Uani 1 1 d . . . . .
H13 H 0.0593 0.2653 0.0838 0.034 Uiso 1 1 calc R U . . .
C14 C 0.0579(2) 0.3681(4) 0.04488(16) 0.0280(14) Uani 1 1 d . . . . .
H14 H 0.0399 0.3332 0.0241 0.034 Uiso 1 1 calc R U . . .
C15 C 0.0732(2) 0.4590(4) 0.03997(14) 0.0200(13) Uani 1 1 d . . . . .
H15 H 0.0659 0.4878 0.0158 0.024 Uiso 1 1 calc R U . . .
C16 C 0.0994(2) 0.5083(3) 0.07065(14) 0.0167(12) Uani 1 1 d . . . . .
C17 C 0.1223(2) 0.6064(3) 0.06509(13) 0.0139(12) Uani 1 1 d . . . . .
C18 C 0.0708(2) 0.6742(3) 0.05427(13) 0.0133(12) Uani 1 1 d . . . . .
C19 C 0.0146(2) 0.6657(4) 0.06854(14) 0.0252(14) Uani 1 1 d . . . . .
H19 H 0.0064 0.6155 0.0848 0.030 Uiso 1 1 calc R U . . .
C20 C -0.0287(2) 0.7302(4) 0.05900(16) 0.0305(15) Uani 1 1 d . . . . .
H20 H -0.0674 0.7256 0.0684 0.037 Uiso 1 1 calc R U . . .
C22 C -0.0150(2) 0.8020(4) 0.03537(15) 0.0270(14) Uani 1 1 d . . . . .
H22 H -0.0443 0.8478 0.0281 0.032 Uiso 1 1 calc R U . . .
C23 C 0.0409(2) 0.8062(4) 0.02266(14) 0.0203(13) Uani 1 1 d . . . . .
H23 H 0.0498 0.8563 0.0066 0.024 Uiso 1 1 calc R U . . .
C24 C 0.1330(3) 0.4887(5) 0.22506(18) 0.0349(16) Uani 1 1 d . . . . .
C25 C 0.1036(4) 0.4372(5) 0.25662(18) 0.069(2) Uani 1 1 d . . . . .
H25A H 0.1340 0.4229 0.2774 0.104 Uiso 1 1 calc R U . . .
H25B H 0.0857 0.3796 0.2464 0.104 Uiso 1 1 calc R U . . .
H25C H 0.0721 0.4761 0.2663 0.104 Uiso 1 1 calc R U . . .
C26 C 0.2843(2) 0.5721(4) 0.13895(14) 0.0173(13) Uani 1 1 d . . . . .
C27 C 0.3465(2) 0.5302(4) 0.14139(16) 0.0351(16) Uani 1 1 d . . . . .
H27A H 0.3674 0.5492 0.1192 0.053 Uiso 1 1 calc R U . . .
H27B H 0.3432 0.4626 0.1418 0.053 Uiso 1 1 calc R U . . .
H27C H 0.3692 0.5514 0.1648 0.053 Uiso 1 1 calc R U . . .
C28 C 0.0896(3) 1.1204(5) 0.15371(18) 0.0401(17) Uani 1 1 d . . . . .
C29 C 0.0284(3) 1.1601(4) 0.1608(2) 0.079(3) Uani 1 1 d . . . . .
H29A H 0.0336 1.2204 0.1733 0.119 Uiso 1 1 calc R U . . .
H29B H 0.0077 1.1180 0.1773 0.119 Uiso 1 1 calc R U . . .
H29C H 0.0044 1.1674 0.1364 0.119 Uiso 1 1 calc R U . . .
C30 C 0.3557(2) 0.8327(4) 0.13383(14) 0.0244(14) Uani 1 1 d . . . . .
H30A H 0.3906 0.8351 0.1530 0.029 Uiso 1 1 calc R U . . .
H30B H 0.3556 0.7716 0.1212 0.029 Uiso 1 1 calc R U . . .
C31 C 0.2983(2) 0.8445(4) 0.15334(13) 0.0190(13) Uani 1 1 d . . . . .
H31A H 0.2928 0.7910 0.1703 0.023 Uiso 1 1 calc R U . . .
H31B H 0.3009 0.9012 0.1692 0.023 Uiso 1 1 calc R U . . .
C32 C 0.3745(2) 0.9954(4) 0.12440(15) 0.0248(14) Uani 1 1 d . . . . .
H32A H 0.4186 1.0043 0.1278 0.030 Uiso 1 1 calc R U . . .
H32B H 0.3590 0.9942 0.1500 0.030 Uiso 1 1 calc R U . . .
C33 C 0.3467(2) 1.0748(3) 0.10213(14) 0.0202(13) Uani 1 1 d . . . . .
H33A H 0.3503 1.1319 0.1177 0.024 Uiso 1 1 calc R U . . .
H33B H 0.3681 1.0848 0.0788 0.024 Uiso 1 1 calc R U . . .
C34 C 0.4088(2) 0.8848(4) 0.08014(15) 0.0287(15) Uani 1 1 d . . . . .
H34A H 0.4461 0.8689 0.0959 0.034 Uiso 1 1 calc R U . . .
H34B H 0.4172 0.9404 0.0650 0.034 Uiso 1 1 calc R U . . .
C35 C 0.3926(2) 0.8062(4) 0.05348(13) 0.0211(13) Uani 1 1 d . . . . .
H35A H 0.4228 0.8016 0.0343 0.025 Uiso 1 1 calc R U . . .
H35B H 0.3934 0.7475 0.0680 0.025 Uiso 1 1 calc R U . . .
C36 C 0.2360(2) 1.1116(3) 0.01335(15) 0.0237(14) Uani 1 1 d . . . . .
H36A H 0.2340 1.1409 0.0387 0.028 Uiso 1 1 calc R U . . .
H36B H 0.2173 1.1543 -0.0061 0.028 Uiso 1 1 calc R U . . .
C37 C 0.3013(2) 1.0954(4) 0.00585(14) 0.0222(13) Uani 1 1 d . . . . .
H37A H 0.3055 1.0979 -0.0219 0.027 Uiso 1 1 calc R U . . .
H37B H 0.3265 1.1452 0.0181 0.027 Uiso 1 1 calc R U . . .
C38 C 0.1418(2) 1.0378(4) 0.02591(14) 0.0254(14) Uani 1 1 d . . . . .
H38A H 0.1156 0.9861 0.0165 0.030 Uiso 1 1 calc R U . . .
H38B H 0.1245 1.0956 0.0147 0.030 Uiso 1 1 calc R U . . .
C39 C 0.1412(2) 1.0429(3) 0.06819(13) 0.0198(13) Uani 1 1 d . . . . .
H39A H 0.1625 1.0995 0.0777 0.024 Uiso 1 1 calc R U . . .
H39B H 0.0992 1.0463 0.0753 0.024 Uiso 1 1 calc R U . . .
C40 C 0.1981(2) 0.9869(4) -0.02680(14) 0.0226(13) Uani 1 1 d . . . . .
H40A H 0.2367 0.9984 -0.0381 0.027 Uiso 1 1 calc R U . . .
H40B H 0.1663 1.0208 -0.0423 0.027 Uiso 1 1 calc R U . . .
C41 C 0.1846(2) 0.8861(3) -0.02886(13) 0.0164(12) Uani 1 1 d . . . . .
H41A H 0.1418 0.8756 -0.0246 0.020 Uiso 1 1 calc R U . . .
H41B H 0.1917 0.8624 -0.0545 0.020 Uiso 1 1 calc R U . . .
C42 C 0.2443(3) 0.2989(5) 0.1247(2) 0.059(2) Uani 1 1 d . . . . .
H42A H 0.2569 0.2590 0.1464 0.089 Uiso 1 1 calc R U . . .
H42B H 0.2076 0.2739 0.1114 0.089 Uiso 1 1 calc R U . . .
H42C H 0.2364 0.3614 0.1339 0.089 Uiso 1 1 calc R U . . .
C43 C 0.2922(3) 0.3024(4) 0.0984(2) 0.0461(19) Uani 1 1 d . . . . .
C46 C 0.9803(3) 0.9326(4) 0.11345(17) 0.0461(18) Uani 1 1 d . . . . .
H46A H 0.9470 0.8882 0.1101 0.069 Uiso 1 1 calc R U . . .
H46B H 0.9794 0.9631 0.1383 0.069 Uiso 1 1 calc R U . . .
H46C H 1.0186 0.9000 0.1122 0.069 Uiso 1 1 calc R U . . .
C47 C 0.9740(3) 1.0011(5) 0.0835(2) 0.0453(18) Uani 1 1 d . . . . .
Dy1 Dy 0.25955(2) 0.90896(2) 0.06045(2) 0.01283(8) Uani 1 1 d . . . . .
Mn1 Mn 0.17086(3) 0.95091(5) 0.14015(2) 0.01721(19) Uani 1 1 d . . . . .
Mn2 Mn 0.15125(3) 0.56514(5) 0.15507(2) 0.01623(19) Uani 1 1 d . . . . .
Mn3 Mn 0.20163(3) 0.73770(5) 0.11280(2) 0.01280(18) Uani 1 1 d . . . . .
Mn4 Mn 0.18727(3) 0.72183(5) 0.01694(2) 0.01269(18) Uani 1 1 d . . . . .
N1 N 0.17994(17) 0.9165(3) 0.19700(11) 0.0192(10) Uani 1 1 d . . . . .
N2 N 0.06843(17) 0.6437(3) 0.16973(11) 0.0192(10) Uani 1 1 d . . . . .
N3 N 0.10834(17) 0.4710(3) 0.10497(12) 0.0194(10) Uani 1 1 d . . . . .
N4 N 0.08410(17) 0.7438(3) 0.03148(11) 0.0161(10) Uani 1 1 d . . . . .
N5 N 0.36131(16) 0.9064(3) 0.10526(11) 0.0151(9) Uani 1 1 d . . . . .
N6 N 0.20220(16) 1.0243(3) 0.01231(11) 0.0149(10) Uani 1 1 d . . . . .
N7 N 0.3306(3) 0.3066(4) 0.0793(2) 0.069(2) Uani 1 1 d . . . . .
N9 N 0.9686(3) 1.0544(5) 0.05999(18) 0.071(2) Uani 1 1 d . . . . .
O1 O 0.12776(13) 0.8365(2) 0.13755(9) 0.0159(8) Uani 1 1 d . . . . .
O2 O 0.17940(13) 0.7128(2) 0.16430(8) 0.0135(8) Uani 1 1 d . . . . .
O3 O 0.12565(18) 0.4563(3) 0.19198(11) 0.0371(10) Uani 1 1 d . . . . .
O4 O 0.16043(18) 0.5621(3) 0.23292(11) 0.0444(11) Uani 1 1 d . . . . .
O5 O 0.09267(15) 1.0334(3) 0.14959(10) 0.0291(9) Uani 1 1 d . . . . .
O6 O 0.13248(19) 1.1752(3) 0.15225(13) 0.0555(13) Uani 1 1 d . . . . .
O7 O 0.22207(14) 1.0539(2) 0.14892(9) 0.0214(8) Uani 1 1 d . . . . .
H7A H 0.1955 1.0938 0.1533 0.026 Uiso 1 1 d R U . . .
O8 O 0.24286(14) 0.5267(2) 0.15266(9) 0.0229(9) Uani 1 1 d . . . . .
O9 O 0.27866(14) 0.6502(2) 0.12346(9) 0.0192(8) Uani 1 1 d . . . . .
O10 O 0.14866(13) 0.6373(2) 0.10026(8) 0.0146(8) Uani 1 1 d . . . . .
O11 O 0.16220(13) 0.6051(2) 0.03651(8) 0.0137(8) Uani 1 1 d . . . . .
O13 O 0.24822(13) 0.8514(2) 0.12566(8) 0.0142(8) Uani 1 1 d . . . . .
O14 O 0.28489(14) 1.0554(2) 0.09189(9) 0.0181(8) Uani 1 1 d . . . . .
H14A H 0.2673 1.0562 0.1125 0.022 Uiso 1 1 d R U . . .
O15 O 0.33463(13) 0.8194(2) 0.03468(8) 0.0145(8) Uani 1 1 d . . . . .
O16 O 0.32183(14) 1.0082(2) 0.02032(9) 0.0179(8) Uani 1 1 d . . . . .
H16A H 0.3387 0.9768 0.0037 0.022 Uiso 1 1 d R U . . .
O17 O 0.16977(13) 0.9640(2) 0.08511(9) 0.0167(8) Uani 1 1 d . . . . .
O18 O 0.22199(13) 0.8373(2) -0.00064(8) 0.0121(8) Uani 1 1 d . . . . .
O19 O 0.21356(13) 0.7690(2) 0.06370(8) 0.0139(8) Uani 1 1 d . . . . .
O20 O 0.18083(15) 0.6326(3) 0.30614(10) 0.0410(11) Uani 1 1 d . . . . .
H20A H 0.1766 0.6089 0.2840 0.049 Uiso 1 1 d R U . . .
H20B H 0.2106 0.6068 0.3185 0.049 Uiso 1 1 d R U . . .
C44A C 0.3203(8) 0.7718(11) 0.2925(4) 0.028(4) Uani 0.302(7) 1 d D U P A 1
H44A H 0.2881 0.8154 0.2973 0.042 Uiso 0.302(7) 1 calc R U P A 1
H44B H 0.3582 0.8055 0.2914 0.042 Uiso 0.302(7) 1 calc R U P A 1
H44C H 0.3244 0.7262 0.3132 0.042 Uiso 0.302(7) 1 calc R U P A 1
C45A C 0.3049(9) 0.7225(14) 0.2548(5) 0.028(4) Uani 0.302(7) 1 d D U P A 1
N8A N 0.2887(7) 0.6793(11) 0.2282(4) 0.028(4) Uani 0.302(7) 1 d D U P A 1
C44B C 0.3010(6) 0.7039(15) 0.2450(5) 0.146(4) Uani 0.698(7) 1 d D U P A 2
H44D H 0.2716 0.6738 0.2269 0.219 Uiso 0.698(7) 1 calc R U P A 2
H44E H 0.2941 0.7709 0.2445 0.219 Uiso 0.698(7) 1 calc R U P A 2
H44F H 0.2964 0.6804 0.2708 0.219 Uiso 0.698(7) 1 calc R U P A 2
C45B C 0.3643(6) 0.6834(12) 0.2340(5) 0.146(4) Uani 0.698(7) 1 d D U P A 2
N8B N 0.4096(6) 0.6603(10) 0.2284(4) 0.146(4) Uani 0.698(7) 1 d D U P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C2 122.6(5) . .
N1 C1 H1 118.7 . .
C2 C1 H1 118.7 . .
C3 C2 C1 118.4(5) . .
C3 C2 H2 120.8 . .
C1 C2 H2 120.8 . .
C2 C3 C4 119.4(5) . .
C2 C3 H3 120.3 . .
C4 C3 H3 120.3 . .
C3 C4 C5 119.0(5) . .
C3 C4 H4 120.5 . .
C5 C4 H4 120.5 . .
N1 C5 C4 121.6(4) . .
N1 C5 C6 114.5(4) . .
C4 C5 C6 123.8(5) . .
O1 C6 O2 109.0(4) . .
O1 C6 C5 110.4(4) . .
O2 C6 C5 106.1(4) . .
O1 C6 C7 108.4(4) . .
O2 C6 C7 112.7(4) . .
C5 C6 C7 110.3(4) . .
N2 C7 C8 121.7(5) . .
N2 C7 C6 117.6(4) . .
C8 C7 C6 120.7(5) . .
C9 C8 C7 119.7(5) . .
C9 C8 H8 120.1 . .
C7 C8 H8 120.1 . .
C10 C9 C8 118.6(5) . .
C10 C9 H9 120.7 . .
C8 C9 H9 120.7 . .
C9 C10 C11 119.5(5) . .
C9 C10 H10 120.2 . .
C11 C10 H10 120.2 . .
N2 C11 C10 122.9(5) . .
N2 C11 H11 118.6 . .
C10 C11 H11 118.6 . .
N3 C12 C13 123.4(5) . .
N3 C12 H12 118.3 . .
C13 C12 H12 118.3 . .
C14 C13 C12 118.3(5) . .
C14 C13 H13 120.9 . .
C12 C13 H13 120.9 . .
C13 C14 C15 119.3(5) . .
C13 C14 H14 120.4 . .
C15 C14 H14 120.4 . .
C14 C15 C16 119.3(5) . .
C14 C15 H15 120.4 . .
C16 C15 H15 120.4 . .
N3 C16 C15 121.7(5) . .
N3 C16 C17 117.9(4) . .
C15 C16 C17 120.3(4) . .
O11 C17 O10 113.1(3) . .
O11 C17 C16 108.6(4) . .
O10 C17 C16 107.7(4) . .
O11 C17 C18 109.7(4) . .
O10 C17 C18 105.7(4) . .
C16 C17 C18 112.0(4) . .
N4 C18 C19 122.1(5) . .
N4 C18 C17 115.7(4) . .
C19 C18 C17 122.1(4) . .
C20 C19 C18 119.4(5) . .
C20 C19 H19 120.3 . .
C18 C19 H19 120.3 . .
C19 C20 C22 118.4(5) . .
C19 C20 H20 120.8 . .
C22 C20 H20 120.8 . .
C23 C22 C20 119.0(5) . .
C23 C22 H22 120.5 . .
C20 C22 H22 120.5 . .
N4 C23 C22 123.8(5) . .
N4 C23 H23 118.1 . .
C22 C23 H23 118.1 . .
O4 C24 O3 123.4(6) . .
O4 C24 C25 119.1(6) . .
O3 C24 C25 117.4(6) . .
C24 C25 H25A 109.5 . .
C24 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C24 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
O9 C26 O8 125.6(4) . .
O9 C26 C27 116.6(5) . .
O8 C26 C27 117.8(5) . .
C26 C27 H27A 109.5 . .
C26 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C26 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
O6 C28 O5 125.3(6) . .
O6 C28 C29 118.0(6) . .
O5 C28 C29 116.8(6) . .
C28 C29 H29A 109.5 . .
C28 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C28 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
N5 C30 C31 110.4(4) . .
N5 C30 H30A 109.6 . .
C31 C30 H30A 109.6 . .
N5 C30 H30B 109.6 . .
C31 C30 H30B 109.6 . .
H30A C30 H30B 108.1 . .
O13 C31 C30 110.1(4) . .
O13 C31 H31A 109.6 . .
C30 C31 H31A 109.6 . .
O13 C31 H31B 109.6 . .
C30 C31 H31B 109.6 . .
H31A C31 H31B 108.2 . .
N5 C32 C33 111.8(4) . .
N5 C32 H32A 109.3 . .
C33 C32 H32A 109.3 . .
N5 C32 H32B 109.3 . .
C33 C32 H32B 109.3 . .
H32A C32 H32B 107.9 . .
O14 C33 C32 109.5(4) . .
O14 C33 H33A 109.8 . .
C32 C33 H33A 109.8 . .
O14 C33 H33B 109.8 . .
C32 C33 H33B 109.8 . .
H33A C33 H33B 108.2 . .
N5 C34 C35 112.9(4) . .
N5 C34 H34A 109.0 . .
C35 C34 H34A 109.0 . .
N5 C34 H34B 109.0 . .
C35 C34 H34B 109.0 . .
H34A C34 H34B 107.8 . .
O15 C35 C34 110.8(4) . .
O15 C35 H35A 109.5 . .
C34 C35 H35A 109.5 . .
O15 C35 H35B 109.5 . .
C34 C35 H35B 109.5 . .
H35A C35 H35B 108.1 . .
N6 C36 C37 111.1(4) . .
N6 C36 H36A 109.4 . .
C37 C36 H36A 109.4 . .
N6 C36 H36B 109.4 . .
C37 C36 H36B 109.4 . .
H36A C36 H36B 108.0 . .
O16 C37 C36 111.1(4) . .
O16 C37 H37A 109.4 . .
C36 C37 H37A 109.4 . .
O16 C37 H37B 109.4 . .
C36 C37 H37B 109.4 . .
H37A C37 H37B 108.0 . .
N6 C38 C39 114.2(4) . .
N6 C38 H38A 108.7 . .
C39 C38 H38A 108.7 . .
N6 C38 H38B 108.7 . .
C39 C38 H38B 108.7 . .
H38A C38 H38B 107.6 . .
O17 C39 C38 109.9(4) . .
O17 C39 H39A 109.7 . .
C38 C39 H39A 109.7 . .
O17 C39 H39B 109.7 . .
C38 C39 H39B 109.7 . .
H39A C39 H39B 108.2 . .
N6 C40 C41 113.7(4) . .
N6 C40 H40A 108.8 . .
C41 C40 H40A 108.8 . .
N6 C40 H40B 108.8 . .
C41 C40 H40B 108.8 . .
H40A C40 H40B 107.7 . .
O18 C41 C40 110.1(4) . .
O18 C41 H41A 109.6 . .
C40 C41 H41A 109.6 . .
O18 C41 H41B 109.6 . .
C40 C41 H41B 109.6 . .
H41A C41 H41B 108.1 . .
C43 C42 H42A 109.5 . .
C43 C42 H42B 109.5 . .
H42A C42 H42B 109.5 . .
C43 C42 H42C 109.5 . .
H42A C42 H42C 109.5 . .
H42B C42 H42C 109.5 . .
N7 C43 C42 177.3(8) . .
C47 C46 H46A 109.5 . .
C47 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C47 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
N9 C47 C46 179.4(8) . .
O19 Dy1 O15 82.35(11) . .
O19 Dy1 O17 83.32(11) . .
O15 Dy1 O17 165.51(11) . .
O19 Dy1 O14 147.15(11) . .
O15 Dy1 O14 120.43(10) . .
O17 Dy1 O14 73.50(11) . .
O19 Dy1 O13 64.83(10) . .
O15 Dy1 O13 107.42(10) . .
O17 Dy1 O13 67.95(10) . .
O14 Dy1 O13 84.74(10) . .
O19 Dy1 O18 63.09(10) . .
O15 Dy1 O18 68.74(10) . .
O17 Dy1 O18 102.67(10) . .
O14 Dy1 O18 144.13(10) . .
O13 Dy1 O18 127.82(10) . .
O19 Dy1 O16 143.97(10) . .
O15 Dy1 O16 69.87(11) . .
O17 Dy1 O16 122.20(10) . .
O14 Dy1 O16 68.85(10) . .
O13 Dy1 O16 144.74(10) . .
O18 Dy1 O16 85.15(10) . .
O19 Dy1 N6 113.39(11) . .
O15 Dy1 N6 115.13(11) . .
O17 Dy1 N6 69.09(11) . .
O14 Dy1 N6 79.96(11) . .
O13 Dy1 N6 136.88(11) . .
O18 Dy1 N6 65.94(11) . .
O16 Dy1 N6 62.52(11) . .
O19 Dy1 N5 108.95(11) . .
O15 Dy1 N5 67.73(11) . .
O17 Dy1 N5 119.45(11) . .
O14 Dy1 N5 65.54(11) . .
O13 Dy1 N5 65.78(11) . .
O18 Dy1 N5 136.43(11) . .
O16 Dy1 N5 81.79(11) . .
N6 Dy1 N5 137.58(12) . .
O19 Dy1 Mn3 29.95(7) . .
O15 Dy1 Mn3 96.87(8) . .
O17 Dy1 Mn3 71.34(8) . .
O14 Dy1 Mn3 118.15(8) . .
O13 Dy1 Mn3 35.05(7) . .
O18 Dy1 Mn3 92.77(7) . .
O16 Dy1 Mn3 166.44(7) . .
N6 Dy1 Mn3 128.54(8) . .
N5 Dy1 Mn3 90.65(9) . .
O19 Dy1 Mn4 29.20(7) . .
O15 Dy1 Mn4 73.68(7) . .
O17 Dy1 Mn4 92.67(8) . .
O14 Dy1 Mn4 165.57(7) . .
O13 Dy1 Mn4 93.98(7) . .
O18 Dy1 Mn4 33.89(7) . .
O16 Dy1 Mn4 117.36(7) . .
N6 Dy1 Mn4 91.41(8) . .
N5 Dy1 Mn4 126.87(9) . .
Mn3 Dy1 Mn4 58.974(17) . .
O19 Dy1 Mn4 75.32(8) . 7_565
O15 Dy1 Mn4 29.70(7) . 7_565
O17 Dy1 Mn4 142.11(7) . 7_565
O14 Dy1 Mn4 136.35(8) . 7_565
O13 Dy1 Mn4 126.14(7) . 7_565
O18 Dy1 Mn4 39.63(7) . 7_565
O16 Dy1 Mn4 69.15(7) . 7_565
N6 Dy1 Mn4 91.05(9) . 7_565
N5 Dy1 Mn4 97.17(8) . 7_565
Mn3 Dy1 Mn4 100.893(18) . 7_565
Mn4 Dy1 Mn4 54.59(2) . 7_565
O7 Mn1 O1 170.42(14) . .
O7 Mn1 O17 92.67(13) . .
O1 Mn1 O17 93.97(13) . .
O7 Mn1 N1 91.11(15) . .
O1 Mn1 N1 81.25(15) . .
O17 Mn1 N1 170.18(15) . .
O7 Mn1 O5 91.41(14) . .
O1 Mn1 O5 94.39(14) . .
O17 Mn1 O5 98.75(13) . .
N1 Mn1 O5 90.20(15) . .
O7 Mn1 O13 94.24(13) . .
O1 Mn1 O13 80.40(12) . .
O17 Mn1 O13 78.13(12) . .
N1 Mn1 O13 92.56(13) . .
O5 Mn1 O13 173.66(12) . .
O7 Mn1 Dy1 84.15(10) . .
O1 Mn1 Dy1 96.98(10) . .
O17 Mn1 Dy1 37.52(9) . .
N1 Mn1 Dy1 134.21(11) . .
O5 Mn1 Dy1 135.30(10) . .
O13 Mn1 Dy1 42.85(7) . .
O7 Mn1 H7A 22.7 . .
O1 Mn1 H7A 161.5 . .
O17 Mn1 H7A 95.9 . .
N1 Mn1 H7A 91.1 . .
O5 Mn1 H7A 68.7 . .
O13 Mn1 H7A 116.9 . .
Dy1 Mn1 H7A 100.4 . .
O8 Mn2 O3 97.71(14) . .
O8 Mn2 O10 92.81(12) . .
O3 Mn2 O10 153.18(13) . .
O8 Mn2 O2 89.77(12) . .
O3 Mn2 O2 134.08(13) . .
O10 Mn2 O2 70.22(11) . .
O8 Mn2 N2 160.94(14) . .
O3 Mn2 N2 88.27(15) . .
O10 Mn2 N2 89.75(13) . .
O2 Mn2 N2 73.34(13) . .
O8 Mn2 N3 98.83(13) . .
O3 Mn2 N3 85.26(15) . .
O10 Mn2 N3 68.73(13) . .
O2 Mn2 N3 138.36(13) . .
N2 Mn2 N3 99.70(14) . .
O8 Mn2 Mn3 79.02(9) . .
O3 Mn2 Mn3 170.51(11) . .
O10 Mn2 Mn3 36.31(8) . .
O2 Mn2 Mn3 37.75(8) . .
N2 Mn2 Mn3 92.15(11) . .
N3 Mn2 Mn3 104.00(10) . .
O19 Mn3 O10 95.93(13) . .
O19 Mn3 O2 172.79(13) . .
O10 Mn3 O2 82.89(13) . .
O19 Mn3 O13 84.14(13) . .
O10 Mn3 O13 173.29(13) . .
O2 Mn3 O13 96.20(12) . .
O19 Mn3 O9 97.93(13) . .
O10 Mn3 O9 93.70(13) . .
O2 Mn3 O9 89.25(13) . .
O13 Mn3 O9 92.94(12) . .
O19 Mn3 O1 110.58(12) . .
O10 Mn3 O1 96.15(12) . .
O2 Mn3 O1 62.62(11) . .
O13 Mn3 O1 77.60(12) . .
O9 Mn3 O1 148.58(12) . .
O19 Mn3 Mn2 136.50(10) . .
O10 Mn3 Mn2 42.96(9) . .
O2 Mn3 Mn2 44.78(9) . .
O13 Mn3 Mn2 138.52(9) . .
O9 Mn3 Mn2 76.15(9) . .
O1 Mn3 Mn2 91.14(8) . .
O19 Mn3 Dy1 38.50(9) . .
O10 Mn3 Dy1 133.28(9) . .
O2 Mn3 Dy1 140.62(9) . .
O13 Mn3 Dy1 45.88(9) . .
O9 Mn3 Dy1 101.06(9) . .
O1 Mn3 Dy1 93.65(8) . .
Mn2 Mn3 Dy1 174.36(3) . .
O19 Mn4 O11 94.97(13) . .
O19 Mn4 O15 174.06(14) . 7_565
O11 Mn4 O15 90.37(13) . 7_565
O19 Mn4 O18 81.95(13) . .
O11 Mn4 O18 173.54(12) . .
O15 Mn4 O18 92.47(13) 7_565 .
O19 Mn4 O18 97.77(12) . 7_565
O11 Mn4 O18 92.81(12) . 7_565
O15 Mn4 O18 79.34(12) 7_565 7_565
O18 Mn4 O18 82.03(12) . 7_565
O19 Mn4 N4 90.25(13) . .
O11 Mn4 N4 74.42(13) . .
O15 Mn4 N4 93.69(13) 7_565 .
O18 Mn4 N4 111.15(13) . .
O18 Mn4 N4 165.52(12) 7_565 .
O19 Mn4 Mn4 90.68(10) . 7_565
O11 Mn4 Mn4 129.65(10) . 7_565
O15 Mn4 Mn4 83.91(9) 7_565 7_565
O18 Mn4 Mn4 45.09(9) . 7_565
O18 Mn4 Mn4 36.94(8) 7_565 7_565
N4 Mn4 Mn4 155.69(10) . 7_565
O19 Mn4 Dy1 37.26(9) . .
O11 Mn4 Dy1 132.01(9) . .
O15 Mn4 Dy1 137.12(10) 7_565 .
O18 Mn4 Dy1 44.69(9) . .
O18 Mn4 Dy1 90.70(8) 7_565 .
N4 Mn4 Dy1 102.87(9) . .
Mn4 Mn4 Dy1 65.00(2) 7_565 .
O19 Mn4 Dy1 140.73(10) . 7_565
O11 Mn4 Dy1 86.08(9) . 7_565
O15 Mn4 Dy1 37.00(9) 7_565 7_565
O18 Mn4 Dy1 92.70(9) . 7_565
O18 Mn4 Dy1 43.07(7) 7_565 7_565
N4 Mn4 Dy1 127.29(9) . 7_565
Mn4 Mn4 Dy1 60.41(2) 7_565 7_565
Dy1 Mn4 Dy1 125.41(2) . 7_565
C5 N1 C1 119.0(4) . .
C5 N1 Mn1 113.7(3) . .
C1 N1 Mn1 127.3(4) . .
C7 N2 C11 117.6(4) . .
C7 N2 Mn2 117.4(3) . .
C11 N2 Mn2 124.9(4) . .
C16 N3 C12 118.1(4) . .
C16 N3 Mn2 117.9(3) . .
C12 N3 Mn2 124.0(3) . .
C18 N4 C23 117.2(4) . .
C18 N4 Mn4 106.7(3) . .
C23 N4 Mn4 136.0(3) . .
C34 N5 C32 109.5(4) . .
C34 N5 C30 111.1(4) . .
C32 N5 C30 110.1(4) . .
C34 N5 Dy1 105.6(3) . .
C32 N5 Dy1 113.0(3) . .
C30 N5 Dy1 107.4(3) . .
C36 N6 C40 109.4(4) . .
C36 N6 C38 110.9(4) . .
C40 N6 C38 111.1(4) . .
C36 N6 Dy1 107.8(3) . .
C40 N6 Dy1 111.1(3) . .
C38 N6 Dy1 106.5(3) . .
C6 O1 Mn1 117.0(3) . .
C6 O1 Mn3 84.6(2) . .
Mn1 O1 Mn3 100.13(13) . .
C6 O2 Mn3 103.7(3) . .
C6 O2 Mn2 118.1(3) . .
Mn3 O2 Mn2 97.47(13) . .
C24 O3 Mn2 105.4(4) . .
C28 O5 Mn1 128.1(4) . .
Mn1 O7 H7A 98.2 . .
C26 O8 Mn2 127.9(3) . .
C26 O9 Mn3 131.3(3) . .
C17 O10 Mn3 131.2(3) . .
C17 O10 Mn2 127.3(3) . .
Mn3 O10 Mn2 100.73(13) . .
C17 O11 Mn4 117.8(3) . .
C31 O13 Mn3 117.9(3) . .
C31 O13 Mn1 116.5(3) . .
Mn3 O13 Mn1 100.28(12) . .
C31 O13 Dy1 121.7(3) . .
Mn3 O13 Dy1 99.07(11) . .
Mn1 O13 Dy1 97.22(11) . .
C33 O14 Dy1 118.1(3) . .
C33 O14 H14A 106.5 . .
Dy1 O14 H14A 107.0 . .
C35 O15 Mn4 123.3(3) . 7_565
C35 O15 Dy1 123.0(3) . .
Mn4 O15 Dy1 113.30(13) 7_565 .
C37 O16 Dy1 122.1(3) . .
C37 O16 H16A 112.0 . .
Dy1 O16 H16A 112.0 . .
C39 O17 Mn1 117.9(3) . .
C39 O17 Dy1 118.7(3) . .
Mn1 O17 Dy1 112.66(13) . .
C41 O18 Mn4 114.6(3) . .
C41 O18 Mn4 119.0(3) . 7_565
Mn4 O18 Mn4 97.97(12) . 7_565
C41 O18 Dy1 122.4(3) . .
Mn4 O18 Dy1 101.42(12) . .
Mn4 O18 Dy1 97.30(10) 7_565 .
Mn3 O19 Mn4 134.17(17) . .
Mn3 O19 Dy1 111.55(14) . .
Mn4 O19 Dy1 113.53(14) . .
H20A O20 H20B 108.5 . .
C45A C44A H44A 109.5 . .
C45A C44A H44B 109.5 . .
H44A C44A H44B 109.5 . .
C45A C44A H44C 109.5 . .
H44A C44A H44C 109.5 . .
H44B C44A H44C 109.5 . .
N8A C45A C44A 172(2) . .
C45B C44B H44D 109.5 . .
C45B C44B H44E 109.5 . .
H44D C44B H44E 109.5 . .
C45B C44B H44F 109.5 . .
H44D C44B H44F 109.5 . .
H44E C44B H44F 109.5 . .
N8B C45B C44B 172(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.340(6) .
C1 C2 1.376(7) .
C1 H1 0.9500 .
C2 C3 1.375(7) .
C2 H2 0.9500 .
C3 C4 1.383(7) .
C3 H3 0.9500 .
C4 C5 1.384(6) .
C4 H4 0.9500 .
C5 N1 1.336(6) .
C5 C6 1.515(6) .
C6 O1 1.404(5) .
C6 O2 1.407(5) .
C6 C7 1.516(6) .
C7 N2 1.342(6) .
C7 C8 1.387(7) .
C8 C9 1.375(7) .
C8 H8 0.9500 .
C9 C10 1.365(7) .
C9 H9 0.9500 .
C10 C11 1.367(7) .
C10 H10 0.9500 .
C11 N2 1.353(6) .
C11 H11 0.9500 .
C12 N3 1.335(6) .
C12 C13 1.374(7) .
C12 H12 0.9500 .
C13 C14 1.358(7) .
C13 H13 0.9500 .
C14 C15 1.371(7) .
C14 H14 0.9500 .
C15 C16 1.384(6) .
C15 H15 0.9500 .
C16 N3 1.323(6) .
C16 C17 1.525(6) .
C17 O11 1.394(5) .
C17 O10 1.401(5) .
C17 C18 1.535(6) .
C18 N4 1.334(6) .
C18 C19 1.392(6) .
C19 C20 1.364(7) .
C19 H19 0.9500 .
C20 C22 1.379(7) .
C20 H20 0.9500 .
C22 C23 1.358(7) .
C22 H22 0.9500 .
C23 N4 1.338(6) .
C23 H23 0.9500 .
C24 O4 1.245(7) .
C24 O3 1.253(7) .
C24 C25 1.526(8) .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 O9 1.254(6) .
C26 O8 1.261(6) .
C26 C27 1.508(7) .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 O6 1.246(7) .
C28 O5 1.268(7) .
C28 C29 1.518(8) .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 N5 1.476(6) .
C30 C31 1.507(6) .
C30 H30A 0.9900 .
C30 H30B 0.9900 .
C31 O13 1.427(5) .
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C32 N5 1.471(6) .
C32 C33 1.497(6) .
C32 H32A 0.9900 .
C32 H32B 0.9900 .
C33 O14 1.425(5) .
C33 H33A 0.9900 .
C33 H33B 0.9900 .
C34 N5 1.465(6) .
C34 C35 1.499(7) .
C34 H34A 0.9900 .
C34 H34B 0.9900 .
C35 O15 1.419(5) .
C35 H35A 0.9900 .
C35 H35B 0.9900 .
C36 N6 1.468(6) .
C36 C37 1.519(6) .
C36 H36A 0.9900 .
C36 H36B 0.9900 .
C37 O16 1.423(5) .
C37 H37A 0.9900 .
C37 H37B 0.9900 .
C38 N6 1.476(6) .
C38 C39 1.490(6) .
C38 H38A 0.9900 .
C38 H38B 0.9900 .
C39 O17 1.415(5) .
C39 H39A 0.9900 .
C39 H39B 0.9900 .
C40 N6 1.474(6) .
C40 C41 1.489(6) .
C40 H40A 0.9900 .
C40 H40B 0.9900 .
C41 O18 1.431(5) .
C41 H41A 0.9900 .
C41 H41B 0.9900 .
C42 C43 1.468(9) .
C42 H42A 0.9800 .
C42 H42B 0.9800 .
C42 H42C 0.9800 .
C43 N7 1.130(8) .
C46 C47 1.443(9) .
C46 H46A 0.9800 .
C46 H46B 0.9800 .
C46 H46C 0.9800 .
C47 N9 1.130(8) .
Dy1 O19 2.275(3) .
Dy1 O15 2.353(3) .
Dy1 O17 2.379(3) .
Dy1 O14 2.434(3) .
Dy1 O13 2.471(3) .
Dy1 O18 2.472(3) .
Dy1 O16 2.507(3) .
Dy1 N6 2.635(4) .
Dy1 N5 2.660(4) .
Dy1 Mn3 3.3996(8) .
Dy1 Mn4 3.4454(7) .
Dy1 Mn4 3.5909(8) 7_565
Mn1 O7 1.886(3) .
Mn1 O1 1.911(3) .
Mn1 O17 1.943(3) .
Mn1 N1 2.055(4) .
Mn1 O5 2.159(4) .
Mn1 O13 2.333(3) .
Mn1 H7A 2.1774 .
Mn2 O8 2.125(3) .
Mn2 O3 2.145(4) .
Mn2 O10 2.188(3) .
Mn2 O2 2.241(3) .
Mn2 N2 2.261(4) .
Mn2 N3 2.369(4) .
Mn2 Mn3 3.1550(10) .
Mn3 O19 1.825(3) .
Mn3 O10 1.901(3) .
Mn3 O2 1.948(3) .
Mn3 O13 1.977(3) .
Mn3 O9 2.143(3) .
Mn3 O1 2.394(3) .
Mn4 O19 1.834(3) .
Mn4 O11 1.921(3) .
Mn4 O15 1.937(3) 7_565
Mn4 O18 1.960(3) .
Mn4 O18 2.309(3) 7_565
Mn4 N4 2.416(4) .
Mn4 Mn4 3.2294(14) 7_565
Mn4 Dy1 3.5909(8) 7_565
O7 H7A 0.8501 .
O14 H14A 0.8495 .
O15 Mn4 1.937(3) 7_565
O16 H16A 0.8500 .
O18 Mn4 2.309(3) 7_565
O20 H20A 0.8501 .
O20 H20B 0.8498 .
C44A C45A 1.521(8) .
C44A H44A 0.9800 .
C44A H44B 0.9800 .
C44A H44C 0.9800 .
C45A N8A 1.159(8) .
C44B C45B 1.523(8) .
C44B H44D 0.9800 .
C44B H44E 0.9800 .
C44B H44F 0.9800 .
C45B N8B 1.097(8) .
