#------------------------------------------------------------------------------
#$Date: 2017-03-05 07:19:08 +0200 (Sun, 05 Mar 2017) $
#$Revision: 193840 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/18/7041884.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7041884
loop_
_publ_author_name
'Guo, Zhiqiang'
'Wang, Yakong'
'Cao, Wei'
'Chao, Jianbin'
'Wei, Xuehong'
_publ_section_title
;
 Structural diversity of alkali-metal (Li, Na, K) alkyl zincates
 containing bidentate aminopyrrolyl ligands: from molecular complexes to
 coordination polymers.
;
_journal_issue                   9
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2765
_journal_page_last               2769
_journal_paper_doi               10.1039/c7dt00052a
_journal_volume                  46
_journal_year                    2017
_chemical_formula_sum            'C124 H216 K8 N16 O9 Zn8'
_chemical_formula_weight         2910.89
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           18
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2 2ab'
_symmetry_space_group_name_H-M   'P 21 21 2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-12-21 deposited with the CCDC.
2017-01-30 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            1
_cell_length_a                   10.7556(8)
_cell_length_b                   14.6395(11)
_cell_length_c                   24.3304(18)
_cell_measurement_reflns_used    8150
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.93
_cell_measurement_theta_min      2.87
_cell_volume                     3831.0(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0515
_diffrn_reflns_av_sigmaI/netI    0.0608
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            22661
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         2.87
_exptl_absorpt_coefficient_mu    1.500
_exptl_absorpt_correction_T_max  0.6618
_exptl_absorpt_correction_T_min  0.6219
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.262
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1536
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.33
_exptl_crystal_size_min          0.30
_refine_diff_density_max         1.346
_refine_diff_density_min         -1.556
_refine_diff_density_rms         0.138
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.50(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     392
_refine_ls_number_reflns         6765
_refine_ls_number_restraints     99
_refine_ls_restrained_S_all      1.073
_refine_ls_R_factor_all          0.1134
_refine_ls_R_factor_gt           0.0767
_refine_ls_shift/su_max          0.027
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0123P)²+47.5070P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1638
_refine_ls_wR_factor_ref         0.1852
_reflns_number_gt                4911
_reflns_number_total             6765
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7dt00052a2.cif
_cod_data_source_block           4
_cod_depositor_comments
'Adding full bibliography for 7041881--7041884.cif.'
_cod_original_sg_symbol_H-M      P21212
_cod_database_code               7041884
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.01035(5) 0.90292(3) 0.806036(19) 0.03045(12) Uani 1 1 d .
Zn2 Zn 0.49442(5) 0.59720(3) 0.713626(18) 0.02712(11) Uani 1 1 d .
K1 K 0.0000 1.0000 0.62598(6) 0.0416(4) Uani 1 2 d S
K2 K 0.25673(13) 0.75305(8) 0.75943(5) 0.0440(3) Uani 1 1 d .
K3 K 0.5000 0.5000 0.89520(6) 0.0455(4) Uani 1 2 d S
N1 N 0.0651(3) 0.8847(2) 0.72444(15) 0.0277(6) Uani 1 1 d U
N2 N 0.1425(3) 1.0102(3) 0.80359(13) 0.0291(10) Uani 1 1 d .
N3 N 0.4449(4) 0.6164(2) 0.79574(16) 0.0358(12) Uani 1 1 d .
N4 N 0.3571(3) 0.4937(3) 0.71579(13) 0.0243(9) Uani 1 1 d .
O1 O -0.1287(5) 0.8941(3) 0.55671(19) 0.0905(13) Uani 1 1 d U
O2 O 0.3388(5) 0.4058(4) 0.9558(2) 0.0975(13) Uani 1 1 d U
O3 O 0.5000 1.0000 0.5724(5) 0.102(5) Uani 0.50 2 d SP
C1 C 0.0535(5) 0.8198(3) 0.6848(2) 0.0385(14) Uani 1 1 d .
H1 H -0.0125 0.7769 0.6822 0.046 Uiso 1 1 calc R
C2 C 0.1536(5) 0.8260(3) 0.6483(2) 0.0430(15) Uani 1 1 d .
H2 H 0.1690 0.7884 0.6172 0.052 Uiso 1 1 calc R
C3 C 0.2268(4) 0.8994(3) 0.66708(19) 0.0395(13) Uani 1 1 d .
H3 H 0.3013 0.9213 0.6507 0.047 Uiso 1 1 calc R
C4 C 0.1713(4) 0.9330(3) 0.71284(19) 0.0309(13) Uani 1 1 d .
C5 C 0.2037(4) 1.0151(3) 0.74947(16) 0.0298(6) Uani 1 1 d U
H5A H 0.2949 1.0174 0.7548 0.036 Uiso 1 1 calc R
H5B H 0.1780 1.0721 0.7307 0.036 Uiso 1 1 calc R
C6 C 0.2359(5) 1.0186(3) 0.84938(18) 0.0373(5) Uani 1 1 d U
C7 C 0.3060(4) 1.1097(3) 0.8475(2) 0.0458(16) Uani 1 1 d .
H7A H 0.3564 1.1126 0.8140 0.069 Uiso 1 1 calc R
H7B H 0.3602 1.1147 0.8798 0.069 Uiso 1 1 calc R
H7C H 0.2461 1.1602 0.8476 0.069 Uiso 1 1 calc R
C8 C 0.1664(5) 1.0140(3) 0.90445(17) 0.0412(11) Uani 1 1 d U
H8A H 0.1068 1.0645 0.9067 0.062 Uiso 1 1 calc R
H8B H 0.2261 1.0188 0.9347 0.062 Uiso 1 1 calc R
H8C H 0.1218 0.9558 0.9071 0.062 Uiso 1 1 calc R
C9 C 0.3296(5) 0.9396(3) 0.8476(2) 0.0452(16) Uani 1 1 d .
H9A H 0.2850 0.8813 0.8498 0.068 Uiso 1 1 calc R
H9B H 0.3870 0.9448 0.8787 0.068 Uiso 1 1 calc R
H9C H 0.3765 0.9422 0.8131 0.068 Uiso 1 1 calc R
C10 C 0.4553(5) 0.6830(3) 0.83524(19) 0.0354(14) Uani 1 1 d .
H10 H 0.5217 0.7257 0.8372 0.043 Uiso 1 1 calc R
C11 C 0.3586(6) 0.6801(3) 0.8711(2) 0.0497(17) Uani 1 1 d .
H11 H 0.3457 0.7187 0.9020 0.060 Uiso 1 1 calc R
C12 C 0.2811(5) 0.6082(3) 0.8533(2) 0.0461(15) Uani 1 1 d .
H12 H 0.2063 0.5883 0.8703 0.055 Uiso 1 1 calc R
C13 C 0.3354(4) 0.5720(3) 0.80612(18) 0.0291(12) Uani 1 1 d .
C14 C 0.2966(4) 0.4913(3) 0.76991(17) 0.0365(12) Uani 1 1 d .
H14A H 0.3186 0.4336 0.7887 0.044 Uiso 1 1 calc R
H14B H 0.2053 0.4924 0.7649 0.044 Uiso 1 1 calc R
C15 C 0.2659(4) 0.4872(3) 0.67022(17) 0.0293(12) Uani 1 1 d .
C16 C 0.3312(4) 0.4912(4) 0.61620(16) 0.0342(12) Uani 1 1 d .
H16A H 0.3788 0.5482 0.6137 0.051 Uiso 1 1 calc R
H16B H 0.2698 0.4891 0.5864 0.051 Uiso 1 1 calc R
H16C H 0.3878 0.4391 0.6129 0.051 Uiso 1 1 calc R
C17 C 0.1910(4) 0.3969(4) 0.6732(2) 0.0440(15) Uani 1 1 d .
H17A H 0.2480 0.3449 0.6702 0.066 Uiso 1 1 calc R
H17B H 0.1310 0.3948 0.6429 0.066 Uiso 1 1 calc R
H17C H 0.1465 0.3938 0.7083 0.066 Uiso 1 1 calc R
C18 C 0.1708(4) 0.5710(3) 0.6731(2) 0.0404(15) Uani 1 1 d .
H18A H 0.0893 0.5474 0.6855 0.048 Uiso 1 1 calc R
H18B H 0.1595 0.5952 0.6354 0.048 Uiso 1 1 calc R
C19 C 0.0212(5) 0.7835(3) 0.84852(17) 0.0320(13) Uani 1 1 d .
H19A H 0.1095 0.7709 0.8572 0.038 Uiso 1 1 calc R
H19B H -0.0240 0.7903 0.8837 0.038 Uiso 1 1 calc R
C20 C -0.0338(5) 0.7005(4) 0.8164(2) 0.0553(7) Uani 1 1 d U
H20A H -0.1073 0.7131 0.7931 0.066 Uiso 1 1 calc R
H20B H -0.0396 0.6422 0.8369 0.066 Uiso 1 1 calc R
C21 C 0.4919(5) 0.7153(3) 0.67070(17) 0.0323(11) Uani 1 1 d .
H21A H 0.5343 0.7050 0.6351 0.039 Uiso 1 1 calc R
H21B H 0.4043 0.7310 0.6626 0.039 Uiso 1 1 calc R
C22 C 0.5539(4) 0.7988(3) 0.6994(2) 0.0462(16) Uani 1 1 d .
H22A H 0.5064 0.8150 0.7323 0.069 Uiso 1 1 calc R
H22B H 0.5551 0.8508 0.6740 0.069 Uiso 1 1 calc R
H22C H 0.6393 0.7831 0.7098 0.069 Uiso 1 1 calc R
C23 C -0.0774(8) 0.8660(6) 0.5071(3) 0.1023(17) Uani 1 1 d U
H23A H 0.0046 0.8367 0.5126 0.123 Uiso 1 1 calc R
H23B H -0.0682 0.9178 0.4812 0.123 Uiso 1 1 calc R
C24 C -0.1733(9) 0.7977(6) 0.4867(4) 0.1150(17) Uani 1 1 d U
H24A H -0.2305 0.8279 0.4605 0.138 Uiso 1 1 calc R
H24B H -0.1311 0.7470 0.4672 0.138 Uiso 1 1 calc R
C25 C -0.2407(9) 0.7632(6) 0.5313(3) 0.1146(17) Uani 1 1 d U
H25A H -0.2186 0.6986 0.5386 0.137 Uiso 1 1 calc R
H25B H -0.3313 0.7676 0.5247 0.137 Uiso 1 1 calc R
C26 C -0.2042(9) 0.8198(6) 0.5749(3) 0.1108(17) Uani 1 1 d U
H26A H -0.1571 0.7832 0.6021 0.133 Uiso 1 1 calc R
H26B H -0.2791 0.8441 0.5934 0.133 Uiso 1 1 calc R
C27 C 0.2052(8) 0.4182(6) 0.9509(3) 0.1128(16) Uani 1 1 d U
H27A H 0.1802 0.4168 0.9118 0.135 Uiso 1 1 calc R
H27B H 0.1805 0.4779 0.9666 0.135 Uiso 1 1 calc R
C28 C 0.1428(9) 0.3413(6) 0.9821(4) 0.1201(17) Uani 1 1 d U
H28A H 0.1213 0.3594 1.0201 0.144 Uiso 1 1 calc R
H28B H 0.0674 0.3191 0.9630 0.144 Uiso 1 1 calc R
C29 C 0.2440(10) 0.2728(6) 0.9809(4) 0.1220(17) Uani 1 1 d U
H29A H 0.2360 0.2345 0.9476 0.146 Uiso 1 1 calc R
H29B H 0.2375 0.2325 1.0135 0.146 Uiso 1 1 calc R
C30 C 0.3723(9) 0.3212(6) 0.9808(4) 0.1144(17) Uani 1 1 d U
H30A H 0.4046 0.3300 1.0186 0.137 Uiso 1 1 calc R
H30B H 0.4342 0.2874 0.9587 0.137 Uiso 1 1 calc R
C31 C 0.4255(6) 0.9491(5) 0.5369(6) 0.0921(7) Uani 0.50 1 d PDU
H31A H 0.4269 0.8840 0.5480 0.110 Uiso 0.50 1 calc PR
H31B H 0.3385 0.9710 0.5391 0.110 Uiso 0.50 1 calc PR
C32 C 0.46644(9) 0.95706(4) 0.4857(5) 0.0746(7) Uani 0.50 1 d PDU
H32A H 0.3963 0.9587 0.4593 0.089 Uiso 0.50 1 calc PR
H32B H 0.5221 0.9057 0.4760 0.089 Uiso 0.50 1 calc PR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C19 Zn1 N2 125.85(17) . 2_575
C19 Zn1 N1 110.94(15) . .
N2 Zn1 N1 105.88(13) 2_575 .
C19 Zn1 N2 127.78(17) . .
N2 Zn1 N2 94.37(13) 2_575 .
N1 Zn1 N2 83.03(13) . .
C19 Zn1 Zn1 149.45(12) . 2_575
N2 Zn1 Zn1 47.82(10) 2_575 2_575
N1 Zn1 Zn1 98.58(9) . 2_575
N2 Zn1 Zn1 46.64(10) . 2_575
C19 Zn1 K2 66.20(13) . .
N2 Zn1 K2 160.03(9) 2_575 .
N1 Zn1 K2 54.47(10) . .
N2 Zn1 K2 87.11(10) . .
Zn1 Zn1 K2 131.38(3) 2_575 .
C21 Zn2 N4 124.83(18) . 2_665
C21 Zn2 N3 112.10(15) . .
N4 Zn2 N3 104.95(13) 2_665 .
C21 Zn2 N4 128.05(18) . .
N4 Zn2 N4 94.41(11) 2_665 .
N3 Zn2 N4 83.95(13) . .
C21 Zn2 Zn2 148.84(12) . 2_665
N4 Zn2 Zn2 47.80(10) 2_665 2_665
N3 Zn2 Zn2 98.36(9) . 2_665
N4 Zn2 Zn2 46.69(10) . 2_665
C21 Zn2 K2 66.95(14) . .
N4 Zn2 K2 160.44(9) 2_665 .
N3 Zn2 K2 55.77(10) . .
N4 Zn2 K2 87.18(10) . .
Zn2 Zn2 K2 131.50(3) 2_665 .
O1 K1 O1 101.9(2) . 2_575
O1 K1 C4 108.58(14) . 2_575
O1 K1 C4 125.30(14) 2_575 2_575
O1 K1 C4 125.30(14) . .
O1 K1 C4 108.58(14) 2_575 .
C4 K1 C4 89.27(18) 2_575 .
O1 K1 N1 134.84(13) . 2_575
O1 K1 N1 107.26(13) 2_575 2_575
C4 K1 N1 26.51(11) 2_575 2_575
C4 K1 N1 76.30(11) . 2_575
O1 K1 N1 107.26(13) . .
O1 K1 N1 134.84(13) 2_575 .
C4 K1 N1 76.30(11) 2_575 .
C4 K1 N1 26.51(11) . .
N1 K1 N1 74.65(14) 2_575 .
O1 K1 C3 94.20(15) . 2_575
O1 K1 C3 110.13(15) 2_575 2_575
C4 K1 C3 26.15(12) 2_575 2_575
C4 K1 C3 115.23(13) . 2_575
N1 K1 C3 43.60(11) 2_575 2_575
N1 K1 C3 101.39(12) . 2_575
O1 K1 C3 110.13(15) . .
O1 K1 C3 94.20(15) 2_575 .
C4 K1 C3 115.23(13) 2_575 .
C4 K1 C3 26.15(12) . .
N1 K1 C3 101.39(12) 2_575 .
N1 K1 C3 43.60(11) . .
C3 K1 C3 141.32(18) 2_575 .
O1 K1 C1 134.24(15) . 2_575
O1 K1 C1 83.82(14) 2_575 2_575
C4 K1 C1 42.69(13) 2_575 2_575
C4 K1 C1 93.93(13) . 2_575
N1 K1 C1 25.89(11) 2_575 2_575
N1 K1 C1 98.91(12) . 2_575
C3 K1 C1 43.27(13) 2_575 2_575
C3 K1 C1 114.71(14) . 2_575
O1 K1 C1 83.82(14) . .
O1 K1 C1 134.24(15) 2_575 .
C4 K1 C1 93.93(13) 2_575 .
C4 K1 C1 42.69(13) . .
N1 K1 C1 98.91(12) 2_575 .
N1 K1 C1 25.89(11) . .
C3 K1 C1 114.71(14) 2_575 .
C3 K1 C1 43.27(13) . .
C1 K1 C1 124.16(18) 2_575 .
O1 K1 C2 108.19(15) . 2_575
O1 K1 C2 84.81(15) 2_575 2_575
C4 K1 C2 43.11(13) 2_575 2_575
C4 K1 C2 118.66(14) . 2_575
N1 K1 C2 43.37(12) 2_575 2_575
N1 K1 C2 116.55(12) . 2_575
C3 K1 C2 26.66(14) 2_575 2_575
C3 K1 C2 141.00(14) . 2_575
C1 K1 C2 26.33(14) 2_575 2_575
C1 K1 C2 137.01(14) . 2_575
O1 K1 C2 84.81(15) . .
O1 K1 C2 108.19(15) 2_575 .
C4 K1 C2 118.66(14) 2_575 .
C4 K1 C2 43.11(13) . .
N1 K1 C2 116.55(12) 2_575 .
N1 K1 C2 43.37(12) . .
C3 K1 C2 141.00(14) 2_575 .
C3 K1 C2 26.66(14) . .
C1 K1 C2 137.01(14) 2_575 .
C1 K1 C2 26.33(14) . .
C2 K1 C2 159.7(2) 2_575 .
N1 K2 N3 178.42(12) . .
N1 K2 C10 153.91(12) . .
N3 K2 C10 26.54(11) . .
N1 K2 C1 26.39(11) . .
N3 K2 C1 153.07(12) . .
C10 K2 C1 178.58(14) . .
N1 K2 C13 151.98(12) . .
N3 K2 C13 26.44(11) . .
C10 K2 C13 42.80(12) . .
C1 K2 C13 136.06(13) . .
N1 K2 C4 26.60(11) . .
N3 K2 C4 154.98(13) . .
C10 K2 C4 138.34(13) . .
C1 K2 C4 42.78(13) . .
C13 K2 C4 178.58(14) . .
N1 K2 C2 43.56(12) . .
N3 K2 C2 136.91(13) . .
C10 K2 C2 154.77(15) . .
C1 K2 C2 26.35(14) . .
C13 K2 C2 137.02(13) . .
C4 K2 C2 42.60(12) . .
N1 K2 C11 136.15(13) . .
N3 K2 C11 43.38(13) . .
C10 K2 C11 25.56(14) . .
C1 K2 C11 153.32(16) . .
C13 K2 C11 43.09(12) . .
C4 K2 C11 137.29(13) . .
C2 K2 C11 179.67(16) . .
N1 K2 C3 43.21(11) . .
N3 K2 C3 138.10(12) . .
C10 K2 C3 138.59(13) . .
C1 K2 C3 42.84(13) . .
C13 K2 C3 155.03(13) . .
C4 K2 C3 25.46(12) . .
C2 K2 C3 26.12(13) . .
C11 K2 C3 153.97(14) . .
N1 K2 C12 135.46(13) . .
N3 K2 C12 43.24(13) . .
C10 K2 C12 42.29(14) . .
C1 K2 C12 136.29(15) . .
C13 K2 C12 26.17(12) . .
C4 K2 C12 153.31(13) . .
C2 K2 C12 153.80(14) . .
C11 K2 C12 26.10(14) . .
C3 K2 C12 178.65(14) . .
N1 K2 C19 64.71(10) . .
N3 K2 C19 114.17(11) . .
C10 K2 C19 100.67(12) . .
C1 K2 C19 78.38(13) . .
C13 K2 C19 94.90(12) . .
C4 K2 C19 84.07(12) . .
C2 K2 C19 104.24(13) . .
C11 K2 C19 75.43(14) . .
C3 K2 C19 107.17(11) . .
C12 K2 C19 71.47(12) . .
N1 K2 C21 116.54(11) . .
N3 K2 C21 64.55(11) . .
C10 K2 C21 78.68(13) . .
C1 K2 C21 102.24(13) . .
C13 K2 C21 83.47(12) . .
C4 K2 C21 97.55(12) . .
C2 K2 C21 76.54(13) . .
C11 K2 C21 103.79(14) . .
C3 K2 C21 74.26(11) . .
C12 K2 C21 107.09(12) . .
C19 K2 C21 178.19(10) . .
O2 K3 O2 112.7(2) 2_665 .
O2 K3 C13 127.20(14) 2_665 .
O2 K3 C13 101.44(15) . .
O2 K3 C13 101.44(15) 2_665 2_665
O2 K3 C13 127.20(14) . 2_665
C13 K3 C13 87.11(18) . 2_665
O2 K3 C12 115.07(15) 2_665 .
O2 K3 C12 87.18(15) . .
C13 K3 C12 26.82(12) . .
C13 K3 C12 113.74(13) 2_665 .
O2 K3 C12 87.18(15) 2_665 2_665
O2 K3 C12 115.07(15) . 2_665
C13 K3 C12 113.74(13) . 2_665
C13 K3 C12 26.82(12) 2_665 2_665
C12 K3 C12 140.50(19) . 2_665
O2 K3 N3 127.50(14) 2_665 2_665
O2 K3 N3 106.23(13) . 2_665
C13 K3 N3 74.59(11) . 2_665
C13 K3 N3 26.33(11) 2_665 2_665
C12 K3 N3 100.31(12) . 2_665
C12 K3 N3 43.87(12) 2_665 2_665
O2 K3 N3 106.23(13) 2_665 .
O2 K3 N3 127.50(14) . .
C13 K3 N3 26.33(11) . .
C13 K3 N3 74.59(11) 2_665 .
C12 K3 N3 43.87(12) . .
C12 K3 N3 100.31(12) 2_665 .
N3 K3 N3 73.41(14) 2_665 .
O2 K3 C10 127.58(15) 2_665 2_665
O2 K3 C10 85.05(15) . 2_665
C13 K3 C10 93.19(13) . 2_665
C13 K3 C10 42.24(12) 2_665 2_665
C12 K3 C10 114.69(13) . 2_665
C12 K3 C10 42.52(13) 2_665 2_665
N3 K3 C10 25.96(11) 2_665 2_665
N3 K3 C10 98.14(12) . 2_665
O2 K3 C10 85.05(15) 2_665 .
O2 K3 C10 127.58(15) . .
C13 K3 C10 42.24(12) . .
C13 K3 C10 93.19(13) 2_665 .
C12 K3 C10 42.52(13) . .
C12 K3 C10 114.69(13) 2_665 .
N3 K3 C10 98.14(12) 2_665 .
N3 K3 C10 25.96(11) . .
C10 K3 C10 123.62(18) 2_665 .
O2 K3 C11 103.05(16) 2_665 2_665
O2 K3 C11 89.07(16) . 2_665
C13 K3 C11 116.95(14) . 2_665
C13 K3 C11 43.33(13) 2_665 2_665
C12 K3 C11 140.01(15) . 2_665
C12 K3 C11 26.62(14) 2_665 2_665
N3 K3 C11 43.27(12) 2_665 2_665
N3 K3 C11 115.14(13) . 2_665
C10 K3 C11 25.36(14) 2_665 2_665
C10 K3 C11 136.46(14) . 2_665
O2 K3 C11 89.07(16) 2_665 .
O2 K3 C11 103.05(16) . .
C13 K3 C11 43.33(13) . .
C13 K3 C11 116.95(14) 2_665 .
C12 K3 C11 26.62(14) . .
C12 K3 C11 140.01(15) 2_665 .
N3 K3 C11 115.14(13) 2_665 .
N3 K3 C11 43.27(12) . .
C10 K3 C11 136.46(14) 2_665 .
C10 K3 C11 25.36(14) . .
C11 K3 C11 158.2(2) 2_665 .
C1 N1 C4 106.9(4) . .
C1 N1 Zn1 137.6(3) . .
C4 N1 Zn1 111.4(3) . .
C1 N1 K2 79.2(3) . .
C4 N1 K2 79.3(2) . .
Zn1 N1 K2 90.34(12) . .
C1 N1 K1 78.8(2) . .
C4 N1 K1 75.0(2) . .
Zn1 N1 K1 128.26(14) . .
K2 N1 K1 139.32(13) . .
C5 N2 C6 111.0(3) . .
C5 N2 Zn1 110.4(3) . 2_575
C6 N2 Zn1 117.2(3) . 2_575
C5 N2 Zn1 111.1(3) . .
C6 N2 Zn1 119.1(3) . .
Zn1 N2 Zn1 85.54(13) 2_575 .
C13 N3 C10 106.1(4) . .
C13 N3 Zn2 109.4(3) . .
C10 N3 Zn2 138.1(3) . .
C13 N3 K2 77.8(2) . .
C10 N3 K2 77.7(2) . .
Zn2 N3 K2 88.85(13) . .
C13 N3 K3 75.7(2) . .
C10 N3 K3 79.9(3) . .
Zn2 N3 K3 129.90(15) . .
K2 N3 K3 138.59(14) . .
C14 N4 C15 112.1(3) . .
C14 N4 Zn2 110.4(3) . 2_665
C15 N4 Zn2 116.6(3) . 2_665
C14 N4 Zn2 110.4(3) . .
C15 N4 Zn2 119.2(3) . .
Zn2 N4 Zn2 85.52(11) 2_665 .
C23 O1 C26 105.6(6) . .
C23 O1 K1 120.9(5) . .
C26 O1 K1 122.7(4) . .
C30 O2 C27 113.1(6) . .
C30 O2 K3 121.5(5) . .
C27 O2 K3 122.3(4) . .
C31 O3 C31 103.5(13) . 2_675
N1 C1 C2 109.6(4) . .
N1 C1 K2 74.4(3) . .
C2 C1 K2 81.1(3) . .
N1 C1 K1 75.3(2) . .
C2 C1 K1 78.0(3) . .
K2 C1 K1 134.49(17) . .
N1 C1 H1 125.2 . .
C2 C1 H1 125.2 . .
K2 C1 H1 111.5 . .
K1 C1 H1 113.6 . .
C1 C2 C3 105.9(4) . .
C1 C2 K1 75.7(3) . .
C3 C2 K1 74.1(3) . .
C1 C2 K2 72.6(3) . .
C3 C2 K2 77.3(3) . .
K1 C2 K2 128.86(17) . .
C1 C2 H2 127.1 . .
C3 C2 H2 127.1 . .
K1 C2 H2 115.6 . .
K2 C2 H2 115.5 . .
C4 C3 C2 107.3(4) . .
C4 C3 K1 74.9(3) . .
C2 C3 K1 79.2(3) . .
C4 C3 K2 72.8(3) . .
C2 C3 K2 76.6(3) . .
K1 C3 K2 131.02(16) . .
C4 C3 H3 126.4 . .
C2 C3 H3 126.4 . .
K1 C3 H3 112.2 . .
K2 C3 H3 116.5 . .
C3 C4 N1 110.4(4) . .
C3 C4 C5 131.3(4) . .
N1 C4 C5 118.2(4) . .
C3 C4 K1 79.0(3) . .
N1 C4 K1 78.5(2) . .
C5 C4 K1 107.2(3) . .
C3 C4 K2 81.8(3) . .
N1 C4 K2 74.1(2) . .
C5 C4 K2 113.4(3) . .
K1 C4 K2 138.23(16) . .
N2 C5 C4 112.3(3) . .
N2 C5 H5A 109.1 . .
C4 C5 H5A 109.1 . .
N2 C5 H5B 109.1 . .
C4 C5 H5B 109.1 . .
H5A C5 H5B 107.9 . .
N2 C6 C9 110.9(4) . .
N2 C6 C7 112.2(4) . .
C9 C6 C7 109.4(4) . .
N2 C6 C8 108.5(4) . .
C9 C6 C8 108.1(4) . .
C7 C6 C8 107.6(4) . .
C6 C7 H7A 109.5 . .
C6 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C6 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C6 C8 H8A 109.5 . .
C6 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C6 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C6 C9 H9A 109.5 . .
C6 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C6 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C11 C10 N3 111.4(4) . .
C11 C10 K2 82.0(3) . .
N3 C10 K2 75.8(3) . .
C11 C10 K3 77.8(3) . .
N3 C10 K3 74.2(2) . .
K2 C10 K3 134.20(16) . .
C11 C10 H10 124.3 . .
N3 C10 H10 124.3 . .
K2 C10 H10 110.0 . .
K3 C10 H10 115.4 . .
C10 C11 C12 106.2(4) . .
C10 C11 K3 76.8(3) . .
C12 C11 K3 73.3(3) . .
C10 C11 K2 72.5(3) . .
C12 C11 K2 77.3(3) . .
K3 C11 K2 128.94(18) . .
C10 C11 H11 126.9 . .
C12 C11 H11 126.9 . .
K3 C11 H11 115.4 . .
K2 C11 H11 115.7 . .
C13 C12 C11 106.8(5) . .
C13 C12 K3 75.6(3) . .
C11 C12 K3 80.0(3) . .
C13 C12 K2 72.0(3) . .
C11 C12 K2 76.6(3) . .
K3 C12 K2 131.95(19) . .
C13 C12 H12 126.6 . .
C11 C12 H12 126.6 . .
K3 C12 H12 110.7 . .
K2 C12 H12 117.0 . .
N3 C13 C12 109.4(4) . .
N3 C13 C14 119.6(4) . .
C12 C13 C14 130.8(4) . .
N3 C13 K3 78.0(2) . .
C12 C13 K3 77.6(3) . .
C14 C13 K3 107.8(3) . .
N3 C13 K2 75.8(2) . .
C12 C13 K2 81.8(3) . .
C14 C13 K2 112.7(3) . .
K3 C13 K2 138.72(16) . .
N4 C14 C13 112.2(4) . .
N4 C14 H14A 109.2 . .
C13 C14 H14A 109.2 . .
N4 C14 H14B 109.2 . .
C13 C14 H14B 109.2 . .
H14A C14 H14B 107.9 . .
N4 C15 C16 110.2(3) . .
N4 C15 C17 111.3(4) . .
C16 C15 C17 108.6(4) . .
N4 C15 C18 110.0(3) . .
C16 C15 C18 108.0(4) . .
C17 C15 C18 108.6(4) . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C15 C17 H17A 109.5 . .
C15 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C15 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C15 C18 K2 116.1(3) . .
C15 C18 H18A 108.3 . .
K2 C18 H18A 108.3 . .
C15 C18 H18B 108.3 . .
K2 C18 H18B 108.3 . .
H18A C18 H18B 107.4 . .
C20 C19 Zn1 113.1(3) . .
C20 C19 K2 82.0(3) . .
Zn1 C19 K2 80.20(14) . .
C20 C19 H19A 108.9 . .
Zn1 C19 H19A 108.9 . .
K2 C19 H19A 52.5 . .
C20 C19 H19B 109.0 . .
Zn1 C19 H19B 108.9 . .
K2 C19 H19B 160.2 . .
H19A C19 H19B 107.8 . .
C19 C20 K2 71.9(3) . .
C19 C20 H20A 116.4 . .
K2 C20 H20A 116.4 . .
C19 C20 H20B 116.4 . .
K2 C20 H20B 116.4 . .
H20A C20 H20B 113.4 . .
C22 C21 Zn2 115.7(3) . .
C22 C21 K2 84.6(3) . .
Zn2 C21 K2 79.58(14) . .
C22 C21 H21A 108.3 . .
Zn2 C21 H21A 108.3 . .
K2 C21 H21A 158.5 . .
C22 C21 H21B 108.3 . .
Zn2 C21 H21B 108.3 . .
K2 C21 H21B 51.3 . .
H21A C21 H21B 107.4 . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
O1 C23 C24 102.1(7) . .
O1 C23 H23A 111.4 . .
C24 C23 H23A 111.4 . .
O1 C23 H23B 111.4 . .
C24 C23 H23B 111.4 . .
H23A C23 H23B 109.2 . .
C25 C24 C23 109.6(7) . .
C25 C24 H24A 109.7 . .
C23 C24 H24A 109.7 . .
C25 C24 H24B 109.7 . .
C23 C24 H24B 109.7 . .
H24A C24 H24B 108.2 . .
C24 C25 C26 103.2(8) . .
C24 C25 H25A 111.1 . .
C26 C25 H25A 111.1 . .
C24 C25 H25B 111.1 . .
C26 C25 H25B 111.1 . .
H25A C25 H25B 109.1 . .
C25 C26 O1 112.0(7) . .
C25 C26 H26A 109.2 . .
O1 C26 H26A 109.2 . .
C25 C26 H26B 109.2 . .
O1 C26 H26B 109.2 . .
H26A C26 H26B 107.9 . .
O2 C27 C28 107.7(7) . .
O2 C27 H27A 110.2 . .
C28 C27 H27A 110.2 . .
O2 C27 H27B 110.2 . .
C28 C27 H27B 110.2 . .
H27A C27 H27B 108.5 . .
C29 C28 C27 99.7(8) . .
C29 C28 H28A 111.8 . .
C27 C28 H28A 111.8 . .
C29 C28 H28B 111.8 . .
C27 C28 H28B 111.8 . .
H28A C28 H28B 109.6 . .
C28 C29 C30 110.2(7) . .
C28 C29 H29A 109.6 . .
C30 C29 H29A 109.6 . .
C28 C29 H29B 109.6 . .
C30 C29 H29B 109.6 . .
H29A C29 H29B 108.1 . .
O2 C30 C29 99.9(7) . .
O2 C30 H30A 111.8 . .
C29 C30 H30A 111.8 . .
O2 C30 H30B 111.8 . .
C29 C30 H30B 111.8 . .
H30A C30 H30B 109.5 . .
C32 C31 O3 110.1(6) . .
C32 C31 H31A 109.6 . .
O3 C31 H31A 109.6 . .
C32 C31 H31B 109.6 . .
O3 C31 H31B 109.6 . .
H31A C31 H31B 108.2 . .
C31 C32 C32 104.0(3) . 2_675
C31 C32 H32A 111.0 . .
C32 C32 H32A 111.0 2_675 .
C31 C32 H32B 111.0 . .
C32 C32 H32B 111.0 2_675 .
H32A C32 H32B 109.0 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 C19 2.034(4) .
Zn1 N2 2.079(4) 2_575
Zn1 N1 2.088(4) .
Zn1 N2 2.119(4) .
Zn1 Zn1 2.8510(9) 2_575
Zn1 K2 3.6224(14) .
Zn2 C21 2.020(4) .
Zn2 N4 2.079(3) 2_665
Zn2 N3 2.087(4) .
Zn2 N4 2.117(4) .
Zn2 Zn2 2.8484(9) 2_665
Zn2 K2 3.6032(14) .
K1 O1 2.675(5) .
K1 O1 2.675(5) 2_575
K1 C4 2.970(5) 2_575
K1 C4 2.970(5) .
K1 N1 3.013(4) 2_575
K1 N1 3.013(4) .
K1 C3 3.020(5) 2_575
K1 C3 3.020(5) .
K1 C1 3.055(5) 2_575
K1 C1 3.055(5) .
K1 C2 3.084(5) 2_575
K1 C2 3.084(5) .
K2 N1 2.948(4) .
K2 N3 2.980(4) .
K2 C10 3.002(5) .
K2 C1 3.006(5) .
K2 C13 3.005(4) .
K2 C4 3.012(4) .
K2 C2 3.112(5) .
K2 C11 3.118(5) .
K2 C3 3.121(5) .
K2 C12 3.127(5) .
K2 C19 3.363(5) .
K2 C21 3.371(5) .
K3 O2 2.660(5) 2_665
K3 O2 2.660(5) .
K3 C13 2.991(5) .
K3 C13 2.991(5) 2_665
K3 C12 3.015(5) .
K3 C12 3.015(5) 2_665
K3 N3 3.018(4) 2_665
K3 N3 3.018(4) .
K3 C10 3.088(4) 2_665
K3 C10 3.088(4) .
K3 C11 3.100(5) 2_665
K3 C11 3.100(5) .
N1 C1 1.360(6) .
N1 C4 1.372(6) .
N2 C5 1.474(5) .
N2 C6 1.505(6) .
N2 Zn1 2.079(4) 2_575
N3 C13 1.369(6) .
N3 C10 1.374(6) .
N4 C14 1.469(5) .
N4 C15 1.484(5) .
N4 Zn2 2.079(3) 2_665
O1 C23 1.390(9) .
O1 C26 1.429(10) .
O2 C30 1.427(10) .
O2 C27 1.453(10) .
O3 C31 1.394(13) .
O3 C31 1.394(13) 2_675
C1 C2 1.398(7) .
C1 H1 0.9500 .
C2 C3 1.409(7) .
C2 H2 0.9500 .
C3 C4 1.356(6) .
C3 H3 0.9500 .
C4 C5 1.536(6) .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
C6 C9 1.534(7) .
C6 C7 1.533(7) .
C6 C8 1.536(6) .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
C8 H8C 0.9800 .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 C11 1.359(8) .
C10 H10 0.9500 .
C11 C12 1.410(7) .
C11 H11 0.9500 .
C12 C13 1.393(7) .
C12 H12 0.9500 .
C13 C14 1.531(6) .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 C16 1.491(6) .
C15 C17 1.551(6) .
C15 C18 1.598(6) .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 H18A 0.9900 .
C18 H18B 0.9900 .
C19 C20 1.561(7) .
C19 H19A 0.9900 .
C19 H19B 0.9900 .
C20 H20A 0.9900 .
C20 H20B 0.9900 .
C21 C22 1.558(6) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 C24 1.520(12) .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 C25 1.399(12) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 C26 1.403(11) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
C26 H26A 0.9900 .
C26 H26B 0.9900 .
C27 C28 1.515(12) .
C27 H27A 0.9900 .
C27 H27B 0.9900 .
C28 C29 1.480(13) .
C28 H28A 0.9900 .
C28 H28B 0.9900 .
C29 C30 1.550(14) .
C29 H29A 0.9900 .
C29 H29B 0.9900 .
C30 H30A 0.9900 .
C30 H30B 0.9900 .
C31 C32 1.327(18) .
C31 H31A 0.9900 .
C31 H31B 0.9900 .
C32 C32 1.4496(12) 2_675
C32 H32A 0.9900 .
C32 H32B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C19 Zn1 N1 C1 37.8(5) . .
N2 Zn1 N1 C1 -101.8(5) 2_575 .
N2 Zn1 N1 C1 165.6(5) . .
Zn1 Zn1 N1 C1 -150.2(4) 2_575 .
K2 Zn1 N1 C1 74.2(4) . .
C19 Zn1 N1 C4 -115.1(3) . .
N2 Zn1 N1 C4 105.4(3) 2_575 .
N2 Zn1 N1 C4 12.8(3) . .
Zn1 Zn1 N1 C4 56.9(3) 2_575 .
K2 Zn1 N1 C4 -78.6(3) . .
C19 Zn1 N1 K2 -36.46(18) . .
N2 Zn1 N1 K2 -176.00(12) 2_575 .
N2 Zn1 N1 K2 91.42(12) . .
Zn1 Zn1 N1 K2 135.54(7) 2_575 .
C19 Zn1 N1 K1 157.48(19) . .
N2 Zn1 N1 K1 17.9(2) 2_575 .
N2 Zn1 N1 K1 -74.64(19) . .
Zn1 Zn1 N1 K1 -30.52(18) 2_575 .
K2 Zn1 N1 K1 -166.1(2) . .
N3 K2 N1 C1 -72(4) . .
C10 K2 N1 C1 -176.9(3) . .
C13 K2 N1 C1 -70.2(4) . .
C4 K2 N1 C1 109.7(4) . .
C2 K2 N1 C1 36.3(3) . .
C11 K2 N1 C1 -143.5(3) . .
C3 K2 N1 C1 74.7(3) . .
C12 K2 N1 C1 -105.7(3) . .
C19 K2 N1 C1 -116.8(3) . .
C21 K2 N1 C1 61.7(3) . .
N3 K2 N1 C4 179(100) . .
C10 K2 N1 C4 73.5(4) . .
C1 K2 N1 C4 -109.7(4) . .
C13 K2 N1 C4 -179.9(3) . .
C2 K2 N1 C4 -73.4(3) . .
C11 K2 N1 C4 106.8(3) . .
C3 K2 N1 C4 -35.0(3) . .
C12 K2 N1 C4 144.6(3) . .
C19 K2 N1 C4 133.5(3) . .
C21 K2 N1 C4 -47.9(3) . .
N3 K2 N1 Zn1 67(4) . .
C10 K2 N1 Zn1 -38.2(3) . .
C1 K2 N1 Zn1 138.6(3) . .
C13 K2 N1 Zn1 68.4(3) . .
C4 K2 N1 Zn1 -111.7(3) . .
C2 K2 N1 Zn1 174.9(2) . .
C11 K2 N1 Zn1 -4.9(2) . .
C3 K2 N1 Zn1 -146.7(2) . .
C12 K2 N1 Zn1 32.9(2) . .
C19 K2 N1 Zn1 21.79(11) . .
C21 K2 N1 Zn1 -159.66(11) . .
N3 K2 N1 K1 -130(4) . .
C10 K2 N1 K1 124.9(3) . .
C1 K2 N1 K1 -58.3(3) . .
C13 K2 N1 K1 -128.5(2) . .
C4 K2 N1 K1 51.4(2) . .
C2 K2 N1 K1 -21.98(19) . .
C11 K2 N1 K1 158.26(19) . .
C3 K2 N1 K1 16.43(18) . .
C12 K2 N1 K1 -163.95(18) . .
C19 K2 N1 K1 -175.1(2) . .
C21 K2 N1 K1 3.5(2) . .
O1 K1 N1 C1 26.1(3) . .
O1 K1 N1 C1 -101.8(3) 2_575 .
C4 K1 N1 C1 131.6(3) 2_575 .
C4 K1 N1 C1 -111.1(4) . .
N1 K1 N1 C1 158.9(3) 2_575 .
C3 K1 N1 C1 124.2(3) 2_575 .
C3 K1 N1 C1 -75.2(3) . .
C1 K1 N1 C1 168.08(18) 2_575 .
C2 K1 N1 C1 147.5(3) 2_575 .
C2 K1 N1 C1 -36.1(3) . .
O1 K1 N1 C4 137.1(3) . .
O1 K1 N1 C4 9.3(3) 2_575 .
C4 K1 N1 C4 -117.4(3) 2_575 .
N1 K1 N1 C4 -90.0(2) 2_575 .
C3 K1 N1 C4 -124.8(2) 2_575 .
C3 K1 N1 C4 35.8(2) . .
C1 K1 N1 C4 -80.9(3) 2_575 .
C1 K1 N1 C4 111.1(4) . .
C2 K1 N1 C4 -101.5(3) 2_575 .
C2 K1 N1 C4 75.0(3) . .
O1 K1 N1 Zn1 -117.2(2) . .
O1 K1 N1 Zn1 114.9(2) 2_575 .
C4 K1 N1 Zn1 -11.72(18) 2_575 .
C4 K1 N1 Zn1 105.6(3) . .
N1 K1 N1 Zn1 15.63(9) 2_575 .
C3 K1 N1 Zn1 -19.2(2) 2_575 .
C3 K1 N1 Zn1 141.4(3) . .
C1 K1 N1 Zn1 24.8(2) 2_575 .
C1 K1 N1 Zn1 -143.3(4) . .
C2 K1 N1 Zn1 4.1(2) 2_575 .
C2 K1 N1 Zn1 -179.4(3) . .
O1 K1 N1 K2 84.4(2) . .
O1 K1 N1 K2 -43.4(3) 2_575 .
C4 K1 N1 K2 -170.0(2) 2_575 .
C4 K1 N1 K2 -52.7(2) . .
N1 K1 N1 K2 -142.7(3) 2_575 .
C3 K1 N1 K2 -177.46(19) 2_575 .
C3 K1 N1 K2 -16.87(18) . .
C1 K1 N1 K2 -133.5(2) 2_575 .
C1 K1 N1 K2 58.4(3) . .
C2 K1 N1 K2 -154.17(19) 2_575 .
C2 K1 N1 K2 22.28(19) . .
C19 Zn1 N2 C5 109.7(3) . .
N2 Zn1 N2 C5 -106.9(3) 2_575 .
N1 Zn1 N2 C5 -1.4(3) . .
Zn1 Zn1 N2 C5 -110.2(3) 2_575 .
K2 Zn1 N2 C5 53.1(3) . .
C19 Zn1 N2 C6 -21.3(4) . .
N2 Zn1 N2 C6 122.1(3) 2_575 .
N1 Zn1 N2 C6 -132.4(3) . .
Zn1 Zn1 N2 C6 118.8(3) 2_575 .
K2 Zn1 N2 C6 -77.9(3) . .
C19 Zn1 N2 Zn1 -140.06(16) . 2_575
N2 Zn1 N2 Zn1 3.29(18) 2_575 2_575
N1 Zn1 N2 Zn1 108.79(13) . 2_575
K2 Zn1 N2 Zn1 163.33(9) . 2_575
C21 Zn2 N3 C13 114.7(3) . .
N4 Zn2 N3 C13 -107.0(3) 2_665 .
N4 Zn2 N3 C13 -14.1(3) . .
Zn2 Zn2 N3 C13 -58.6(3) 2_665 .
K2 Zn2 N3 C13 76.6(3) . .
C21 Zn2 N3 C10 -31.9(5) . .
N4 Zn2 N3 C10 106.4(5) 2_665 .
N4 Zn2 N3 C10 -160.6(5) . .
Zn2 Zn2 N3 C10 154.8(5) 2_665 .
K2 Zn2 N3 C10 -69.9(5) . .
C21 Zn2 N3 K2 38.1(2) . .
N4 Zn2 N3 K2 176.33(12) 2_665 .
N4 Zn2 N3 K2 -90.70(12) . .
Zn2 Zn2 N3 K2 -135.23(7) 2_665 .
C21 Zn2 N3 K3 -158.0(2) . .
N4 Zn2 N3 K3 -19.7(2) 2_665 .
N4 Zn2 N3 K3 73.3(2) . .
Zn2 Zn2 N3 K3 28.7(2) 2_665 .
K2 Zn2 N3 K3 164.0(3) . .
N1 K2 N3 C13 1(4) . .
C10 K2 N3 C13 109.8(4) . .
C1 K2 N3 C13 -67.2(4) . .
C4 K2 N3 C13 -179.9(3) . .
C2 K2 N3 C13 -104.8(3) . .
C11 K2 N3 C13 74.9(3) . .
C3 K2 N3 C13 -143.8(3) . .
C12 K2 N3 C13 36.5(3) . .
C19 K2 N3 C13 46.2(3) . .
C21 K2 N3 C13 -132.4(3) . .
N1 K2 N3 C10 -108(4) . .
C1 K2 N3 C10 -177.0(3) . .
C13 K2 N3 C10 -109.8(4) . .
C4 K2 N3 C10 70.3(4) . .
C2 K2 N3 C10 145.4(3) . .
C11 K2 N3 C10 -34.8(3) . .
C3 K2 N3 C10 106.4(3) . .
C12 K2 N3 C10 -73.3(3) . .
C19 K2 N3 C10 -63.6(3) . .
C21 K2 N3 C10 117.8(3) . .
N1 K2 N3 Zn2 112(4) . .
C10 K2 N3 Zn2 -140.1(3) . .
C1 K2 N3 Zn2 43.0(3) . .
C13 K2 N3 Zn2 110.1(3) . .
C4 K2 N3 Zn2 -69.7(3) . .
C2 K2 N3 Zn2 5.3(2) . .
C11 K2 N3 Zn2 -174.9(2) . .
C3 K2 N3 Zn2 -33.7(2) . .
C12 K2 N3 Zn2 146.6(2) . .
C19 K2 N3 Zn2 156.31(11) . .
C21 K2 N3 Zn2 -22.28(11) . .
N1 K2 N3 K3 -50(4) . .
C10 K2 N3 K3 58.6(3) . .
C1 K2 N3 K3 -118.3(3) . .
C13 K2 N3 K3 -51.2(2) . .
C4 K2 N3 K3 128.9(3) . .
C2 K2 N3 K3 -155.97(19) . .
C11 K2 N3 K3 23.8(2) . .
C3 K2 N3 K3 164.98(18) . .
C12 K2 N3 K3 -14.68(18) . .
C19 K2 N3 K3 -5.0(2) . .
C21 K2 N3 K3 176.4(2) . .
O2 K3 N3 C13 -146.2(3) 2_665 .
O2 K3 N3 C13 -9.3(3) . .
C13 K3 N3 C13 116.0(3) 2_665 .
C12 K3 N3 C13 -36.7(3) . .
C12 K3 N3 C13 123.7(3) 2_665 .
N3 K3 N3 C13 88.7(2) 2_665 .
C10 K3 N3 C13 80.7(3) 2_665 .
C10 K3 N3 C13 -109.7(4) . .
C11 K3 N3 C13 100.4(3) 2_665 .
C11 K3 N3 C13 -75.8(3) . .
O2 K3 N3 C10 -36.6(3) 2_665 .
O2 K3 N3 C10 100.4(3) . .
C13 K3 N3 C10 109.7(4) . .
C13 K3 N3 C10 -134.3(3) 2_665 .
C12 K3 N3 C10 73.0(3) . .
C12 K3 N3 C10 -126.6(3) 2_665 .
N3 K3 N3 C10 -161.6(3) 2_665 .
C10 K3 N3 C10 -169.65(19) 2_665 .
C11 K3 N3 C10 -149.9(3) 2_665 .
C11 K3 N3 C10 33.9(3) . .
O2 K3 N3 Zn2 110.2(2) 2_665 .
O2 K3 N3 Zn2 -112.9(2) . .
C13 K3 N3 Zn2 -103.5(3) . .
C13 K3 N3 Zn2 12.5(2) 2_665 .
C12 K3 N3 Zn2 -140.3(3) . .
C12 K3 N3 Zn2 20.2(2) 2_665 .
N3 K3 N3 Zn2 -14.86(11) 2_665 .
C10 K3 N3 Zn2 -22.9(2) 2_665 .
C10 K3 N3 Zn2 146.8(4) . .
C11 K3 N3 Zn2 -3.1(3) 2_665 .
C11 K3 N3 Zn2 -179.3(3) . .
O2 K3 N3 K2 -94.5(2) 2_665 .
O2 K3 N3 K2 42.5(3) . .
C13 K3 N3 K2 51.8(2) . .
C13 K3 N3 K2 167.8(2) 2_665 .
C12 K3 N3 K2 15.05(18) . .
C12 K3 N3 K2 175.5(2) 2_665 .
N3 K3 N3 K2 140.5(3) 2_665 .
C10 K3 N3 K2 132.4(2) 2_665 .
C10 K3 N3 K2 -57.9(3) . .
C11 K3 N3 K2 152.2(2) 2_665 .
C11 K3 N3 K2 -24.0(2) . .
C21 Zn2 N4 C14 -110.9(3) . .
N4 Zn2 N4 C14 107.2(3) 2_665 .
N3 Zn2 N4 C14 2.6(3) . .
Zn2 Zn2 N4 C14 110.1(3) 2_665 .
K2 Zn2 N4 C14 -53.3(3) . .
C21 Zn2 N4 C15 20.9(4) . .
N4 Zn2 N4 C15 -121.0(3) 2_665 .
N3 Zn2 N4 C15 134.4(3) . .
Zn2 Zn2 N4 C15 -118.1(3) 2_665 .
K2 Zn2 N4 C15 78.5(3) . .
C21 Zn2 N4 Zn2 139.07(17) . 2_665
N4 Zn2 N4 Zn2 -2.91(17) 2_665 2_665
N3 Zn2 N4 Zn2 -107.51(13) . 2_665
K2 Zn2 N4 Zn2 -163.37(8) . 2_665
O1 K1 O1 C23 35.1(5) 2_575 .
C4 K1 O1 C23 169.1(5) 2_575 .
C4 K1 O1 C23 -88.1(5) . .
N1 K1 O1 C23 164.7(5) 2_575 .
N1 K1 O1 C23 -110.0(5) . .
C3 K1 O1 C23 146.7(5) 2_575 .
C3 K1 O1 C23 -63.9(5) . .
C1 K1 O1 C23 128.1(5) 2_575 .
C1 K1 O1 C23 -98.8(5) . .
C2 K1 O1 C23 123.5(5) 2_575 .
C2 K1 O1 C23 -72.4(5) . .
O1 K1 O1 C26 174.3(6) 2_575 .
C4 K1 O1 C26 -51.8(6) 2_575 .
C4 K1 O1 C26 51.0(6) . .
N1 K1 O1 C26 -56.1(6) 2_575 .
N1 K1 O1 C26 29.2(6) . .
C3 K1 O1 C26 -74.1(6) 2_575 .
C3 K1 O1 C26 75.3(6) . .
C1 K1 O1 C26 -92.8(6) 2_575 .
C1 K1 O1 C26 40.3(6) . .
C2 K1 O1 C26 -97.3(6) 2_575 .
C2 K1 O1 C26 66.8(6) . .
O2 K3 O2 C30 -78.8(5) 2_665 .
C13 K3 O2 C30 142.3(5) . .
C13 K3 O2 C30 47.2(6) 2_665 .
C12 K3 O2 C30 165.1(6) . .
C12 K3 O2 C30 19.1(6) 2_665 .
N3 K3 O2 C30 65.2(6) 2_665 .
N3 K3 O2 C30 146.5(5) . .
C10 K3 O2 C30 50.1(5) 2_665 .
C10 K3 O2 C30 179.4(5) . .
C11 K3 O2 C30 25.0(6) 2_665 .
C11 K3 O2 C30 -173.3(5) . .
O2 K3 O2 C27 122.4(6) 2_665 .
C13 K3 O2 C27 -16.5(5) . .
C13 K3 O2 C27 -111.6(5) 2_665 .
C12 K3 O2 C27 6.4(5) . .
C12 K3 O2 C27 -139.7(5) 2_665 .
N3 K3 O2 C27 -93.6(5) 2_665 .
N3 K3 O2 C27 -12.3(6) . .
C10 K3 O2 C27 -108.7(5) 2_665 .
C10 K3 O2 C27 20.7(6) . .
C11 K3 O2 C27 -133.8(5) 2_665 .
C11 K3 O2 C27 27.9(5) . .
C4 N1 C1 C2 0.9(5) . .
Zn1 N1 C1 C2 -152.8(4) . .
K2 N1 C1 C2 -74.3(4) . .
K1 N1 C1 C2 71.3(4) . .
C4 N1 C1 K2 75.2(3) . .
Zn1 N1 C1 K2 -78.5(4) . .
K1 N1 C1 K2 145.59(11) . .
C4 N1 C1 K1 -70.4(3) . .
Zn1 N1 C1 K1 136.0(4) . .
K2 N1 C1 K1 -145.59(11) . .
N3 K2 C1 N1 176.7(3) . .
C10 K2 C1 N1 104(6) . .
C13 K2 C1 N1 140.4(2) . .
C4 K2 C1 N1 -38.4(2) . .
C2 K2 C1 N1 -113.3(4) . .
C11 K2 C1 N1 66.6(4) . .
C3 K2 C1 N1 -76.2(3) . .
C12 K2 C1 N1 102.3(3) . .
C19 K2 C1 N1 55.5(2) . .
C21 K2 C1 N1 -126.3(2) . .
N1 K2 C1 C2 113.3(4) . .
N3 K2 C1 C2 -70.0(4) . .
C10 K2 C1 C2 -143(6) . .
C13 K2 C1 C2 -106.3(3) . .
C4 K2 C1 C2 74.9(3) . .
C11 K2 C1 C2 179.9(3) . .
C3 K2 C1 C2 37.1(3) . .
C12 K2 C1 C2 -144.4(3) . .
C19 K2 C1 C2 168.8(3) . .
C21 K2 C1 C2 -13.0(3) . .
N1 K2 C1 K1 50.0(2) . .
N3 K2 C1 K1 -133.3(2) . .
C10 K2 C1 K1 154(5) . .
C13 K2 C1 K1 -169.55(18) . .
C4 K2 C1 K1 11.65(18) . .
C2 K2 C1 K1 -63.3(3) . .
C11 K2 C1 K1 116.6(3) . .
C3 K2 C1 K1 -26.20(19) . .
C12 K2 C1 K1 152.3(2) . .
C19 K2 C1 K1 105.5(2) . .
C21 K2 C1 K1 -76.3(2) . .
O1 K1 C1 N1 -155.0(3) . .
O1 K1 C1 N1 104.4(3) 2_575 .
C4 K1 C1 N1 -46.7(3) 2_575 .
C4 K1 C1 N1 37.9(2) . .
N1 K1 C1 N1 -20.5(3) 2_575 .
C3 K1 C1 N1 -63.2(3) 2_575 .
C3 K1 C1 N1 76.7(3) . .
C1 K1 C1 N1 -14.3(2) 2_575 .
C2 K1 C1 N1 -44.9(4) 2_575 .
C2 K1 C1 N1 114.2(4) . .
O1 K1 C1 C2 90.8(3) . .
O1 K1 C1 C2 -9.8(4) 2_575 .
C4 K1 C1 C2 -160.9(3) 2_575 .
C4 K1 C1 C2 -76.3(3) . .
N1 K1 C1 C2 -134.7(3) 2_575 .
N1 K1 C1 C2 -114.2(4) . .
C3 K1 C1 C2 -177.4(3) 2_575 .
C3 K1 C1 C2 -37.5(3) . .
C1 K1 C1 C2 -128.5(3) 2_575 .
C2 K1 C1 C2 -159.1(2) 2_575 .
O1 K1 C1 K2 155.2(3) . .
O1 K1 C1 K2 54.6(3) 2_575 .
C4 K1 C1 K2 -96.5(2) 2_575 .
C4 K1 C1 K2 -11.84(19) . .
N1 K1 C1 K2 -70.3(2) 2_575 .
N1 K1 C1 K2 -49.7(2) . .
C3 K1 C1 K2 -113.0(2) 2_575 .
C3 K1 C1 K2 26.9(2) . .
C1 K1 C1 K2 -64.0(2) 2_575 .
C2 K1 C1 K2 -94.6(3) 2_575 .
C2 K1 C1 K2 64.4(3) . .
N1 C1 C2 C3 -0.9(5) . .
K2 C1 C2 C3 -70.8(3) . .
K1 C1 C2 C3 68.5(3) . .
N1 C1 C2 K1 -69.5(3) . .
K2 C1 C2 K1 -139.35(13) . .
N1 C1 C2 K2 69.9(3) . .
K1 C1 C2 K2 139.35(13) . .
O1 K1 C2 C1 -86.5(3) . .
O1 K1 C2 C1 172.6(3) 2_575 .
C4 K1 C2 C1 21.8(3) 2_575 .
C4 K1 C2 C1 74.6(3) . .
N1 K1 C2 C1 51.7(3) 2_575 .
N1 K1 C2 C1 35.5(3) . .
C3 K1 C2 C1 3.7(4) 2_575 .
C3 K1 C2 C1 111.5(4) . .
C1 K1 C2 C1 71.9(4) 2_575 .
C2 K1 C2 C1 44.7(3) 2_575 .
O1 K1 C2 C3 162.0(3) . .
O1 K1 C2 C3 61.1(3) 2_575 .
C4 K1 C2 C3 -89.7(3) 2_575 .
C4 K1 C2 C3 -36.9(3) . .
N1 K1 C2 C3 -59.8(3) 2_575 .
N1 K1 C2 C3 -76.0(3) . .
C3 K1 C2 C3 -107.8(4) 2_575 .
C1 K1 C2 C3 -39.6(4) 2_575 .
C1 K1 C2 C3 -111.5(4) . .
C2 K1 C2 C3 -66.8(3) 2_575 .
O1 K1 C2 K2 -139.5(2) . .
O1 K1 C2 K2 119.6(2) 2_575 .
C4 K1 C2 K2 -31.1(3) 2_575 .
C4 K1 C2 K2 21.62(18) . .
N1 K1 C2 K2 -1.2(3) 2_575 .
N1 K1 C2 K2 -17.49(15) . .
C3 K1 C2 K2 -49.2(3) 2_575 .
C3 K1 C2 K2 58.5(3) . .
C1 K1 C2 K2 18.9(3) 2_575 .
C1 K1 C2 K2 -53.0(3) . .
C2 K1 C2 K2 -8.3(2) 2_575 .
N1 K2 C2 C1 -36.3(2) . .
N3 K2 C2 C1 141.5(3) . .
C10 K2 C2 C1 178.0(3) . .
C13 K2 C2 C1 102.3(3) . .
C4 K2 C2 C1 -75.7(3) . .
C11 K2 C2 C1 -6(25) . .
C3 K2 C2 C1 -111.4(4) . .
C12 K2 C2 C1 65.5(4) . .
C19 K2 C2 C1 -11.4(3) . .
C21 K2 C2 C1 167.0(3) . .
N1 K2 C2 C3 75.1(3) . .
N3 K2 C2 C3 -107.1(3) . .
C10 K2 C2 C3 -70.6(4) . .
C1 K2 C2 C3 111.4(4) . .
C13 K2 C2 C3 -146.3(3) . .
C4 K2 C2 C3 35.7(3) . .
C11 K2 C2 C3 106(24) . .
C12 K2 C2 C3 176.9(3) . .
C19 K2 C2 C3 100.0(3) . .
C21 K2 C2 C3 -81.6(3) . .
N1 K2 C2 K1 17.83(15) . .
N3 K2 C2 K1 -164.37(16) . .
C10 K2 C2 K1 -127.9(3) . .
C1 K2 C2 K1 54.2(3) . .
C13 K2 C2 K1 156.47(18) . .
C4 K2 C2 K1 -21.51(17) . .
C11 K2 C2 K1 48(25) . .
C3 K2 C2 K1 -57.2(3) . .
C12 K2 C2 K1 119.7(3) . .
C19 K2 C2 K1 42.8(2) . .
C21 K2 C2 K1 -138.9(2) . .
C1 C2 C3 C4 0.6(5) . .
K1 C2 C3 C4 70.3(3) . .
K2 C2 C3 C4 -66.8(3) . .
C1 C2 C3 K1 -69.6(3) . .
K2 C2 C3 K1 -137.10(13) . .
C1 C2 C3 K2 67.5(3) . .
K1 C2 C3 K2 137.10(13) . .
O1 K1 C3 C4 -130.6(3) . .
O1 K1 C3 C4 125.1(3) 2_575 .
C4 K1 C3 C4 -7.3(4) 2_575 .
N1 K1 C3 C4 16.6(3) 2_575 .
N1 K1 C3 C4 -36.3(2) . .
C3 K1 C3 C4 -4.9(2) 2_575 .
C1 K1 C3 C4 40.0(3) 2_575 .
C1 K1 C3 C4 -74.4(3) . .
C2 K1 C3 C4 38.2(4) 2_575 .
C2 K1 C3 C4 -111.4(4) . .
O1 K1 C3 C2 -19.2(3) . .
O1 K1 C3 C2 -123.5(3) 2_575 .
C4 K1 C3 C2 104.1(3) 2_575 .
C4 K1 C3 C2 111.4(4) . .
N1 K1 C3 C2 128.0(3) 2_575 .
N1 K1 C3 C2 75.1(3) . .
C3 K1 C3 C2 106.5(3) 2_575 .
C1 K1 C3 C2 151.4(3) 2_575 .
C1 K1 C3 C2 37.0(3) . .
C2 K1 C3 C2 149.6(3) 2_575 .
O1 K1 C3 K2 -80.5(2) . .
O1 K1 C3 K2 175.2(2) 2_575 .
C4 K1 C3 K2 42.7(3) 2_575 .
C4 K1 C3 K2 50.0(2) . .
N1 K1 C3 K2 66.6(2) 2_575 .
N1 K1 C3 K2 13.70(15) . .
C3 K1 C3 K2 45.10(18) 2_575 .
C1 K1 C3 K2 90.0(2) 2_575 .
C1 K1 C3 K2 -24.34(18) . .
C2 K1 C3 K2 88.2(3) 2_575 .
C2 K1 C3 K2 -61.4(3) . .
N1 K2 C3 C4 36.7(3) . .
N3 K2 C3 C4 -144.6(3) . .
C10 K2 C3 C4 -104.2(3) . .
C1 K2 C3 C4 75.8(3) . .
C13 K2 C3 C4 176.9(3) . .
C2 K2 C3 C4 113.2(4) . .
C11 K2 C3 C4 -66.1(4) . .
C12 K2 C3 C4 25(6) . .
C19 K2 C3 C4 25.8(3) . .
C21 K2 C3 C4 -155.4(3) . .
N1 K2 C3 C2 -76.5(3) . .
N3 K2 C3 C2 102.2(3) . .
C10 K2 C3 C2 142.6(3) . .
C1 K2 C3 C2 -37.4(3) . .
C13 K2 C3 C2 63.7(4) . .
C4 K2 C3 C2 -113.2(4) . .
C11 K2 C3 C2 -179.3(4) . .
C12 K2 C3 C2 -88(6) . .
C19 K2 C3 C2 -87.4(3) . .
C21 K2 C3 C2 91.4(3) . .
N1 K2 C3 K1 -14.11(15) . .
N3 K2 C3 K1 164.58(16) . .
C10 K2 C3 K1 -155.02(18) . .
C1 K2 C3 K1 24.98(18) . .
C13 K2 C3 K1 126.1(3) . .
C4 K2 C3 K1 -50.8(3) . .
C2 K2 C3 K1 62.4(3) . .
C11 K2 C3 K1 -116.9(3) . .
C12 K2 C3 K1 -25(6) . .
C19 K2 C3 K1 -25.0(2) . .
C21 K2 C3 K1 153.9(2) . .
C2 C3 C4 N1 -0.1(5) . .
K1 C3 C4 N1 73.2(3) . .
K2 C3 C4 N1 -69.6(3) . .
C2 C3 C4 C5 -176.6(5) . .
K1 C3 C4 C5 -103.3(5) . .
K2 C3 C4 C5 114.0(5) . .
C2 C3 C4 K1 -73.3(3) . .
K2 C3 C4 K1 -142.74(13) . .
C2 C3 C4 K2 69.4(4) . .
K1 C3 C4 K2 142.74(13) . .
C1 N1 C4 C3 -0.5(5) . .
Zn1 N1 C4 C3 160.8(3) . .
K2 N1 C4 C3 74.6(3) . .
K1 N1 C4 C3 -73.5(3) . .
C1 N1 C4 C5 176.5(4) . .
Zn1 N1 C4 C5 -22.2(5) . .
K2 N1 C4 C5 -108.4(4) . .
K1 N1 C4 C5 103.5(4) . .
C1 N1 C4 K1 73.1(3) . .
Zn1 N1 C4 K1 -125.70(19) . .
K2 N1 C4 K1 148.16(11) . .
C1 N1 C4 K2 -75.1(3) . .
Zn1 N1 C4 K2 86.13(18) . .
K1 N1 C4 K2 -148.16(11) . .
O1 K1 C4 C3 60.9(3) . .
O1 K1 C4 C3 -59.4(3) 2_575 .
C4 K1 C4 C3 173.4(3) 2_575 .
N1 K1 C4 C3 -163.3(3) 2_575 .
N1 K1 C4 C3 113.7(4) . .
C3 K1 C4 C3 176.59(17) 2_575 .
C1 K1 C4 C3 -144.2(3) 2_575 .
C1 K1 C4 C3 76.8(3) . .
C2 K1 C4 C3 -153.7(3) 2_575 .
C2 K1 C4 C3 37.7(3) . .
O1 K1 C4 N1 -52.8(3) . .
O1 K1 C4 N1 -173.1(2) 2_575 .
C4 K1 C4 N1 59.7(2) 2_575 .
N1 K1 C4 N1 83.0(3) 2_575 .
C3 K1 C4 N1 62.9(3) 2_575 .
C3 K1 C4 N1 -113.7(4) . .
C1 K1 C4 N1 102.1(2) 2_575 .
C1 K1 C4 N1 -36.9(2) . .
C2 K1 C4 N1 92.6(3) 2_575 .
C2 K1 C4 N1 -76.0(3) . .
O1 K1 C4 C5 -169.0(3) . .
O1 K1 C4 C5 70.7(3) 2_575 .
C4 K1 C4 C5 -56.6(2) 2_575 .
N1 K1 C4 C5 -33.2(3) 2_575 .
N1 K1 C4 C5 -116.2(4) . .
C3 K1 C4 C5 -53.3(3) 2_575 .
C3 K1 C4 C5 130.1(4) . .
C1 K1 C4 C5 -14.1(3) 2_575 .
C1 K1 C4 C5 -153.2(4) . .
C2 K1 C4 C5 -23.6(3) 2_575 .
C2 K1 C4 C5 167.8(4) . .
O1 K1 C4 K2 -3.2(3) . .
O1 K1 C4 K2 -123.5(3) 2_575 .
C4 K1 C4 K2 109.3(3) 2_575 .
N1 K1 C4 K2 132.6(3) 2_575 .
N1 K1 C4 K2 49.6(2) . .
C3 K1 C4 K2 112.5(2) 2_575 .
C3 K1 C4 K2 -64.1(3) . .
C1 K1 C4 K2 151.7(3) 2_575 .
C1 K1 C4 K2 12.7(2) . .
C2 K1 C4 K2 142.2(2) 2_575 .
C2 K1 C4 K2 -26.4(2) . .
N1 K2 C4 C3 -114.1(4) . .
N3 K2 C4 C3 66.0(4) . .
C10 K2 C4 C3 105.3(3) . .
C1 K2 C4 C3 -76.0(3) . .
C13 K2 C4 C3 -112(5) . .
C2 K2 C4 C3 -36.7(3) . .
C11 K2 C4 C3 143.7(3) . .
C12 K2 C4 C3 -178.7(3) . .
C19 K2 C4 C3 -155.3(3) . .
C21 K2 C4 C3 23.9(3) . .
N3 K2 C4 N1 -179.9(3) . .
C10 K2 C4 N1 -140.6(2) . .
C1 K2 C4 N1 38.0(2) . .
C13 K2 C4 N1 2(5) . .
C2 K2 C4 N1 77.3(3) . .
C11 K2 C4 N1 -102.2(3) . .
C3 K2 C4 N1 114.1(4) . .
C12 K2 C4 N1 -64.7(4) . .
C19 K2 C4 N1 -41.2(2) . .
C21 K2 C4 N1 137.9(2) . .
N1 K2 C4 C5 114.3(4) . .
N3 K2 C4 C5 -65.6(4) . .
C10 K2 C4 C5 -26.3(4) . .
C1 K2 C4 C5 152.4(4) . .
C13 K2 C4 C5 117(5) . .
C2 K2 C4 C5 -168.3(4) . .
C11 K2 C4 C5 12.1(4) . .
C3 K2 C4 C5 -131.6(5) . .
C12 K2 C4 C5 49.7(5) . .
C19 K2 C4 C5 73.1(3) . .
C21 K2 C4 C5 -107.7(3) . .
N1 K2 C4 K1 -50.9(2) . .
N3 K2 C4 K1 129.2(3) . .
C10 K2 C4 K1 168.5(2) . .
C1 K2 C4 K1 -12.9(2) . .
C13 K2 C4 K1 -49(5) . .
C2 K2 C4 K1 26.4(2) . .
C11 K2 C4 K1 -153.1(2) . .
C3 K2 C4 K1 63.2(3) . .
C12 K2 C4 K1 -115.6(3) . .
C19 K2 C4 K1 -92.1(3) . .
C21 K2 C4 K1 87.0(3) . .
C6 N2 C5 C4 126.1(4) . .
Zn1 N2 C5 C4 -102.2(3) 2_575 .
Zn1 N2 C5 C4 -9.0(4) . .
C3 C4 C5 N2 -162.4(5) . .
N1 C4 C5 N2 21.4(5) . .
K1 C4 C5 N2 107.3(3) . .
K2 C4 C5 N2 -62.5(4) . .
C5 N2 C6 C9 -62.0(5) . .
Zn1 N2 C6 C9 169.8(3) 2_575 .
Zn1 N2 C6 C9 69.1(4) . .
C5 N2 C6 C7 60.7(5) . .
Zn1 N2 C6 C7 -67.5(4) 2_575 .
Zn1 N2 C6 C7 -168.2(3) . .
C5 N2 C6 C8 179.4(4) . .
Zn1 N2 C6 C8 51.2(4) 2_575 .
Zn1 N2 C6 C8 -49.5(4) . .
C13 N3 C10 C11 2.1(5) . .
Zn2 N3 C10 C11 149.3(4) . .
K2 N3 C10 C11 75.3(4) . .
K3 N3 C10 C11 -69.7(4) . .
C13 N3 C10 K2 -73.2(3) . .
Zn2 N3 C10 K2 74.0(4) . .
K3 N3 C10 K2 -145.00(12) . .
C13 N3 C10 K3 71.8(3) . .
Zn2 N3 C10 K3 -141.0(4) . .
K2 N3 C10 K3 145.00(12) . .
N1 K2 C10 C11 62.0(4) . .
N3 K2 C10 C11 -114.6(4) . .
C1 K2 C10 C11 -39(6) . .
C13 K2 C10 C11 -76.5(3) . .
C4 K2 C10 C11 102.2(3) . .
C2 K2 C10 C11 179.9(3) . .
C3 K2 C10 C11 141.1(3) . .
C12 K2 C10 C11 -37.4(3) . .
C19 K2 C10 C11 9.2(3) . .
C21 K2 C10 C11 -169.1(3) . .
N1 K2 C10 N3 176.6(3) . .
C1 K2 C10 N3 76(6) . .
C13 K2 C10 N3 38.1(2) . .
C4 K2 C10 N3 -143.2(3) . .
C2 K2 C10 N3 -65.5(4) . .
C11 K2 C10 N3 114.6(4) . .
C3 K2 C10 N3 -104.4(3) . .
C12 K2 C10 N3 77.2(3) . .
C19 K2 C10 N3 123.7(3) . .
C21 K2 C10 N3 -54.5(3) . .
N1 K2 C10 K3 126.3(2) . .
N3 K2 C10 K3 -50.3(2) . .
C1 K2 C10 K3 26(6) . .
C13 K2 C10 K3 -12.26(18) . .
C4 K2 C10 K3 166.47(18) . .
C2 K2 C10 K3 -115.8(3) . .
C11 K2 C10 K3 64.2(3) . .
C3 K2 C10 K3 -154.71(19) . .
C12 K2 C10 K3 26.84(19) . .
C19 K2 C10 K3 73.4(2) . .
C21 K2 C10 K3 -104.9(2) . .
O2 K3 C10 C11 -98.3(3) 2_665 .
O2 K3 C10 C11 16.6(4) . .
C13 K3 C10 C11 78.3(3) . .
C13 K3 C10 C11 160.4(3) 2_665 .
C12 K3 C10 C11 38.0(3) . .
C12 K3 C10 C11 177.1(3) 2_665 .
N3 K3 C10 C11 134.4(3) 2_665 .
N3 K3 C10 C11 116.7(4) . .
C10 K3 C10 C11 129.0(3) 2_665 .
C11 K3 C10 C11 157.9(3) 2_665 .
O2 K3 C10 N3 145.0(3) 2_665 .
O2 K3 C10 N3 -100.0(3) . .
C13 K3 C10 N3 -38.4(3) . .
C13 K3 C10 N3 43.7(3) 2_665 .
C12 K3 C10 N3 -78.7(3) . .
C12 K3 C10 N3 60.4(3) 2_665 .
N3 K3 C10 N3 17.8(3) 2_665 .
C10 K3 C10 N3 12.3(2) 2_665 .
C11 K3 C10 N3 41.2(4) 2_665 .
C11 K3 C10 N3 -116.7(4) . .
O2 K3 C10 K2 -164.2(2) 2_665 .
O2 K3 C10 K2 -49.2(3) . .
C13 K3 C10 K2 12.46(18) . .
C13 K3 C10 K2 94.6(2) 2_665 .
C12 K3 C10 K2 -27.8(2) . .
C12 K3 C10 K2 111.2(2) 2_665 .
N3 K3 C10 K2 68.6(2) 2_665 .
N3 K3 C10 K2 50.9(2) . .
C10 K3 C10 K2 63.2(2) 2_665 .
C11 K3 C10 K2 92.1(3) 2_665 .
C11 K3 C10 K2 -65.8(3) . .
N3 C10 C11 C12 -0.6(6) . .
K2 C10 C11 C12 70.7(4) . .
K3 C10 C11 C12 -68.0(3) . .
N3 C10 C11 K3 67.4(3) . .
K2 C10 C11 K3 138.66(13) . .
N3 C10 C11 K2 -71.3(3) . .
K3 C10 C11 K2 -138.66(13) . .
O2 K3 C11 C10 80.4(3) 2_665 .
O2 K3 C11 C10 -166.5(3) . .
C13 K3 C11 C10 -73.6(3) . .
C13 K3 C11 C10 -22.0(4) 2_665 .
C12 K3 C11 C10 -111.6(4) . .
C12 K3 C11 C10 -4.1(4) 2_665 .
N3 K3 C11 C10 -51.3(3) 2_665 .
N3 K3 C11 C10 -34.8(3) . .
C10 K3 C11 C10 -69.9(4) 2_665 .
C11 K3 C11 C10 -44.2(3) 2_665 .
O2 K3 C11 C12 -168.0(3) 2_665 .
O2 K3 C11 C12 -54.9(3) . .
C13 K3 C11 C12 38.1(3) . .
C13 K3 C11 C12 89.6(3) 2_665 .
C12 K3 C11 C12 107.5(4) 2_665 .
N3 K3 C11 C12 60.3(3) 2_665 .
N3 K3 C11 C12 76.8(3) . .
C10 K3 C11 C12 41.7(4) 2_665 .
C10 K3 C11 C12 111.6(4) . .
C11 K3 C11 C12 67.4(3) 2_665 .
O2 K3 C11 K2 134.4(3) 2_665 .
O2 K3 C11 K2 -112.5(3) . .
C13 K3 C11 K2 -19.52(18) . .
C13 K3 C11 K2 32.0(3) 2_665 .
C12 K3 C11 K2 -57.6(3) . .
C12 K3 C11 K2 49.9(4) 2_665 .
N3 K3 C11 K2 2.7(3) 2_665 .
N3 K3 C11 K2 19.27(17) . .
C10 K3 C11 K2 -15.8(4) 2_665 .
C10 K3 C11 K2 54.1(3) . .
C11 K3 C11 K2 9.9(2) 2_665 .
N1 K2 C11 C10 -145.9(3) . .
N3 K2 C11 C10 36.3(3) . .
C1 K2 C11 C10 178.0(3) . .
C13 K2 C11 C10 75.3(3) . .
C4 K2 C11 C10 -106.7(3) . .
C2 K2 C11 C10 -176(100) . .
C3 K2 C11 C10 -71.3(4) . .
C12 K2 C11 C10 111.8(4) . .
C19 K2 C11 C10 -170.7(3) . .
C21 K2 C11 C10 11.0(3) . .
N1 K2 C11 C12 102.3(3) . .
N3 K2 C11 C12 -75.5(3) . .
C10 K2 C11 C12 -111.8(4) . .
C1 K2 C11 C12 66.3(4) . .
C13 K2 C11 C12 -36.5(3) . .
C4 K2 C11 C12 141.5(3) . .
C2 K2 C11 C12 72(25) . .
C3 K2 C11 C12 176.9(3) . .
C19 K2 C11 C12 77.6(3) . .
C21 K2 C11 C12 -100.8(3) . .
N1 K2 C11 K3 158.33(17) . .
N3 K2 C11 K3 -19.49(17) . .
C10 K2 C11 K3 -55.8(3) . .
C1 K2 C11 K3 122.2(3) . .
C13 K2 C11 K3 19.52(18) . .
C4 K2 C11 K3 -162.50(18) . .
C2 K2 C11 K3 128(24) . .
C3 K2 C11 K3 -127.1(3) . .
C12 K2 C11 K3 56.0(3) . .
C19 K2 C11 K3 133.5(3) . .
C21 K2 C11 K3 -44.8(3) . .
C10 C11 C12 C13 -1.1(6) . .
K3 C11 C12 C13 -71.5(3) . .
K2 C11 C12 C13 66.2(3) . .
C10 C11 C12 K3 70.5(4) . .
K2 C11 C12 K3 137.70(14) . .
C10 C11 C12 K2 -67.2(4) . .
K3 C11 C12 K2 -137.70(14) . .
O2 K3 C12 C13 123.7(3) 2_665 .
O2 K3 C12 C13 -122.5(3) . .
C13 K3 C12 C13 7.2(4) 2_665 .
C12 K3 C12 C13 4.8(2) 2_665 .
N3 K3 C12 C13 -16.5(3) 2_665 .
N3 K3 C12 C13 36.0(2) . .
C10 K3 C12 C13 -39.3(3) 2_665 .
C10 K3 C12 C13 74.3(3) . .
C11 K3 C12 C13 -37.4(4) 2_665 .
C11 K3 C12 C13 110.4(4) . .
O2 K3 C12 C11 13.3(3) 2_665 .
O2 K3 C12 C11 127.1(3) . .
C13 K3 C12 C11 -110.4(4) . .
C13 K3 C12 C11 -103.2(3) 2_665 .
C12 K3 C12 C11 -105.5(3) 2_665 .
N3 K3 C12 C11 -126.9(3) 2_665 .
N3 K3 C12 C11 -74.4(3) . .
C10 K3 C12 C11 -149.7(3) 2_665 .
C10 K3 C12 C11 -36.1(3) . .
C11 K3 C12 C11 -147.7(3) 2_665 .
O2 K3 C12 K2 74.9(3) 2_665 .
O2 K3 C12 K2 -171.3(2) . .
C13 K3 C12 K2 -48.7(2) . .
C13 K3 C12 K2 -41.5(3) 2_665 .
C12 K3 C12 K2 -43.88(18) 2_665 .
N3 K3 C12 K2 -65.3(2) 2_665 .
N3 K3 C12 K2 -12.71(15) . .
C10 K3 C12 K2 -88.0(2) 2_665 .
C10 K3 C12 K2 25.56(18) . .
C11 K3 C12 K2 -86.1(3) 2_665 .
C11 K3 C12 K2 61.7(3) . .
N1 K2 C12 C13 141.8(3) . .
N3 K2 C12 C13 -36.9(3) . .
C10 K2 C12 C13 -76.4(3) . .
C1 K2 C12 C13 103.5(3) . .
C4 K2 C12 C13 177.0(3) . .
C2 K2 C12 C13 67.8(5) . .
C11 K2 C12 C13 -113.0(5) . .
C3 K2 C12 C13 153(6) . .
C19 K2 C12 C13 152.4(3) . .
C21 K2 C12 C13 -26.4(3) . .
N1 K2 C12 C11 -105.2(3) . .
N3 K2 C12 C11 76.1(3) . .
C10 K2 C12 C11 36.6(3) . .
C1 K2 C12 C11 -143.5(3) . .
C13 K2 C12 C11 113.0(5) . .
C4 K2 C12 C11 -70.0(5) . .
C2 K2 C12 C11 -179.3(4) . .
C3 K2 C12 C11 -94(6) . .
C19 K2 C12 C11 -94.6(3) . .
C21 K2 C12 C11 86.5(3) . .
N1 K2 C12 K3 -168.26(16) . .
N3 K2 C12 K3 13.03(16) . .
C10 K2 C12 K3 -26.47(19) . .
C1 K2 C12 K3 153.48(19) . .
C13 K2 C12 K3 49.9(3) . .
C4 K2 C12 K3 -133.0(3) . .
C2 K2 C12 K3 117.7(3) . .
C11 K2 C12 K3 -63.0(3) . .
C3 K2 C12 K3 -157(6) . .
C19 K2 C12 K3 -157.7(2) . .
C21 K2 C12 K3 23.5(3) . .
C10 N3 C13 C12 -2.7(5) . .
Zn2 N3 C13 C12 -160.2(3) . .
K2 N3 C13 C12 -75.8(3) . .
K3 N3 C13 C12 72.0(3) . .
C10 N3 C13 C14 -178.6(4) . .
Zn2 N3 C13 C14 23.9(5) . .
K2 N3 C13 C14 108.3(4) . .
K3 N3 C13 C14 -103.8(4) . .
C10 N3 C13 K3 -74.8(3) . .
Zn2 N3 C13 K3 127.74(18) . .
K2 N3 C13 K3 -147.88(11) . .
C10 N3 C13 K2 73.1(3) . .
Zn2 N3 C13 K2 -84.38(18) . .
K3 N3 C13 K2 147.88(11) . .
C11 C12 C13 N3 2.4(5) . .
K3 C12 C13 N3 -72.3(3) . .
K2 C12 C13 N3 71.7(3) . .
C11 C12 C13 C14 177.6(5) . .
K3 C12 C13 C14 102.9(5) . .
K2 C12 C13 C14 -113.1(5) . .
C11 C12 C13 K3 74.7(4) . .
K2 C12 C13 K3 144.00(13) . .
C11 C12 C13 K2 -69.3(4) . .
K3 C12 C13 K2 -144.00(13) . .
O2 K3 C13 N3 42.0(3) 2_665 .
O2 K3 C13 N3 172.5(2) . .
C13 K3 C13 N3 -60.1(2) 2_665 .
C12 K3 C13 N3 113.2(4) . .
C12 K3 C13 N3 -63.4(3) 2_665 .
N3 K3 C13 N3 -83.7(3) 2_665 .
C10 K3 C13 N3 -102.0(2) 2_665 .
C10 K3 C13 N3 37.8(2) . .
C11 K3 C13 N3 -92.7(3) 2_665 .
C11 K3 C13 N3 75.5(3) . .
O2 K3 C13 C12 -71.2(3) 2_665 .
O2 K3 C13 C12 59.2(3) . .
C13 K3 C13 C12 -173.4(3) 2_665 .
C12 K3 C13 C12 -176.64(17) 2_665 .
N3 K3 C13 C12 163.1(3) 2_665 .
N3 K3 C13 C12 -113.2(4) . .
C10 K3 C13 C12 144.8(3) 2_665 .
C10 K3 C13 C12 -75.4(3) . .
C11 K3 C13 C12 154.1(3) 2_665 .
C11 K3 C13 C12 -37.7(3) . .
O2 K3 C13 C14 159.6(3) 2_665 .
O2 K3 C13 C14 -70.0(3) . .
C13 K3 C13 C14 57.4(2) 2_665 .
C12 K3 C13 C14 -129.2(4) . .
C12 K3 C13 C14 54.1(3) 2_665 .
N3 K3 C13 C14 33.9(3) 2_665 .
N3 K3 C13 C14 117.5(4) . .
C10 K3 C13 C14 15.6(3) 2_665 .
C10 K3 C13 C14 155.4(4) . .
C11 K3 C13 C14 24.8(3) 2_665 .
C11 K3 C13 C14 -167.0(4) . .
O2 K3 C13 K2 -9.3(3) 2_665 .
O2 K3 C13 K2 121.1(3) . .
C13 K3 C13 K2 -111.5(3) 2_665 .
C12 K3 C13 K2 61.9(3) . .
C12 K3 C13 K2 -114.8(2) 2_665 .
N3 K3 C13 K2 -135.0(3) 2_665 .
N3 K3 C13 K2 -51.4(2) . .
C10 K3 C13 K2 -153.3(3) 2_665 .
C10 K3 C13 K2 -13.5(2) . .
C11 K3 C13 K2 -144.1(2) 2_665 .
C11 K3 C13 K2 24.1(2) . .
N1 K2 C13 N3 -179.9(2) . .
C10 K2 C13 N3 -38.2(2) . .
C1 K2 C13 N3 143.0(3) . .
C4 K2 C13 N3 178(100) . .
C2 K2 C13 N3 104.3(3) . .
C11 K2 C13 N3 -76.1(3) . .
C3 K2 C13 N3 69.0(4) . .
C12 K2 C13 N3 -112.5(4) . .
C19 K2 C13 N3 -138.7(2) . .
C21 K2 C13 N3 42.1(2) . .
N1 K2 C13 C12 -67.4(4) . .
N3 K2 C13 C12 112.5(4) . .
C10 K2 C13 C12 74.3(3) . .
C1 K2 C13 C12 -104.5(3) . .
C4 K2 C13 C12 -70(5) . .
C2 K2 C13 C12 -143.2(3) . .
C11 K2 C13 C12 36.4(3) . .
C3 K2 C13 C12 -178.5(3) . .
C19 K2 C13 C12 -26.2(3) . .
C21 K2 C13 C12 154.6(3) . .
N1 K2 C13 C14 63.6(4) . .
N3 K2 C13 C14 -116.5(4) . .
C10 K2 C13 C14 -154.8(4) . .
C1 K2 C13 C14 26.5(4) . .
C4 K2 C13 C14 61(5) . .
C2 K2 C13 C14 -12.2(4) . .
C11 K2 C13 C14 167.4(4) . .
C3 K2 C13 C14 -47.5(5) . .
C12 K2 C13 C14 131.0(5) . .
C19 K2 C13 C14 104.8(3) . .
C21 K2 C13 C14 -74.4(3) . .
N1 K2 C13 K3 -127.9(3) . .
N3 K2 C13 K3 52.0(3) . .
C10 K2 C13 K3 13.8(2) . .
C1 K2 C13 K3 -165.0(2) . .
C4 K2 C13 K3 -130(5) . .
C2 K2 C13 K3 156.4(2) . .
C11 K2 C13 K3 -24.1(2) . .
C3 K2 C13 K3 121.0(3) . .
C12 K2 C13 K3 -60.5(3) . .
C19 K2 C13 K3 -86.6(3) . .
C21 K2 C13 K3 94.2(3) . .
C15 N4 C14 C13 -127.1(4) . .
Zn2 N4 C14 C13 101.2(4) 2_665 .
Zn2 N4 C14 C13 8.4(4) . .
N3 C13 C14 N4 -22.5(6) . .
C12 C13 C14 N4 162.7(5) . .
K3 C13 C14 N4 -108.5(3) . .
K2 C13 C14 N4 63.6(4) . .
C14 N4 C15 C16 179.2(4) . .
Zn2 N4 C15 C16 -52.3(4) 2_665 .
Zn2 N4 C15 C16 48.1(4) . .
C14 N4 C15 C17 -60.3(5) . .
Zn2 N4 C15 C17 68.3(4) 2_665 .
Zn2 N4 C15 C17 168.7(3) . .
C14 N4 C15 C18 60.2(5) . .
Zn2 N4 C15 C18 -171.3(3) 2_665 .
Zn2 N4 C15 C18 -70.9(4) . .
N4 C15 C18 K2 14.2(4) . .
C16 C15 C18 K2 -106.1(3) . .
C17 C15 C18 K2 136.2(3) . .
N1 K2 C18 C15 169.8(3) . .
N3 K2 C18 C15 -11.6(3) . .
C10 K2 C18 C15 -17.2(3) . .
C1 K2 C18 C15 164.2(3) . .
C13 K2 C18 C15 -35.7(3) . .
C4 K2 C18 C15 145.7(3) . .
C2 K2 C18 C15 136.4(3) . .
C11 K2 C18 C15 -44.0(3) . .
C3 K2 C18 C15 126.5(3) . .
C12 K2 C18 C15 -54.8(3) . .
C19 K2 C18 C15 -124.3(3) . .
C21 K2 C18 C15 54.4(3) . .
N2 Zn1 C19 C20 84.8(4) 2_575 .
N1 Zn1 C19 C20 -44.9(4) . .
N2 Zn1 C19 C20 -142.5(3) . .
Zn1 Zn1 C19 C20 150.8(3) 2_575 .
K2 Zn1 C19 C20 -76.8(3) . .
N2 Zn1 C19 K2 161.55(13) 2_575 .
N1 Zn1 C19 K2 31.91(15) . .
N2 Zn1 C19 K2 -65.69(17) . .
Zn1 Zn1 C19 K2 -132.4(2) 2_575 .
N1 K2 C19 C20 92.6(3) . .
N3 K2 C19 C20 -86.2(3) . .
C10 K2 C19 C20 -110.3(3) . .
C1 K2 C19 C20 68.7(3) . .
C13 K2 C19 C20 -67.4(3) . .
C4 K2 C19 C20 111.6(3) . .
C2 K2 C19 C20 73.8(3) . .
C11 K2 C19 C20 -106.2(3) . .
C3 K2 C19 C20 100.8(3) . .
C12 K2 C19 C20 -79.2(3) . .
C21 K2 C19 C20 -42(4) . .
N1 K2 C19 Zn1 -22.75(11) . .
N3 K2 C19 Zn1 158.48(12) . .
C10 K2 C19 Zn1 134.44(14) . .
C1 K2 C19 Zn1 -46.63(14) . .
C13 K2 C19 Zn1 177.29(14) . .
C4 K2 C19 Zn1 -3.69(14) . .
C2 K2 C19 Zn1 -41.51(16) . .
C11 K2 C19 Zn1 138.52(16) . .
C3 K2 C19 Zn1 -14.53(17) . .
C12 K2 C19 Zn1 165.46(17) . .
C21 K2 C19 Zn1 -157(4) . .
Zn1 C19 C20 K2 75.7(2) . .
N1 K2 C20 C19 -76.0(3) . .
N3 K2 C20 C19 104.4(3) . .
C10 K2 C20 C19 76.4(3) . .
C1 K2 C20 C19 -104.2(3) . .
C13 K2 C20 C19 112.5(3) . .
C4 K2 C20 C19 -68.0(3) . .
C2 K2 C20 C19 -110.7(3) . .
C11 K2 C20 C19 69.2(3) . .
C3 K2 C20 C19 -88.2(3) . .
C12 K2 C20 C19 91.1(3) . .
C21 K2 C20 C19 177.4(2) . .
N4 Zn2 C21 C22 -83.3(4) 2_665 .
N3 Zn2 C21 C22 45.1(4) . .
N4 Zn2 C21 C22 145.1(3) . .
Zn2 Zn2 C21 C22 -147.8(2) 2_665 .
K2 Zn2 C21 C22 78.8(3) . .
N4 Zn2 C21 K2 -162.07(12) 2_665 .
N3 Zn2 C21 K2 -33.63(17) . .
N4 Zn2 C21 K2 66.36(17) . .
Zn2 Zn2 C21 K2 133.5(2) 2_665 .
N1 K2 C21 C22 87.3(3) . .
N3 K2 C21 C22 -94.0(3) . .
C10 K2 C21 C22 -70.2(3) . .
C1 K2 C21 C22 110.9(3) . .
C13 K2 C21 C22 -113.3(3) . .
C4 K2 C21 C22 67.7(3) . .
C2 K2 C21 C22 105.0(3) . .
C11 K2 C21 C22 -75.0(3) . .
C3 K2 C21 C22 78.1(3) . .
C12 K2 C21 C22 -101.9(3) . .
C19 K2 C21 C22 -139(4) . .
N1 K2 C21 Zn2 -155.27(12) . .
N3 K2 C21 Zn2 23.45(12) . .
C10 K2 C21 Zn2 47.23(14) . .
C1 K2 C21 Zn2 -131.66(15) . .
C13 K2 C21 Zn2 4.13(14) . .
C4 K2 C21 Zn2 -174.87(15) . .
C2 K2 C21 Zn2 -137.54(17) . .
C11 K2 C21 Zn2 42.41(17) . .
C3 K2 C21 Zn2 -164.45(17) . .
C12 K2 C21 Zn2 15.53(18) . .
C19 K2 C21 Zn2 -22(4) . .
C26 O1 C23 C24 26.6(8) . .
K1 O1 C23 C24 171.8(5) . .
O1 C23 C24 C25 -23.9(9) . .
C23 C24 C25 C26 10.2(10) . .
C24 C25 C26 O1 7.1(10) . .
C23 O1 C26 C25 -23.0(10) . .
K1 O1 C26 C25 -167.4(6) . .
C30 O2 C27 C28 8.0(9) . .
K3 O2 C27 C28 168.4(5) . .
O2 C27 C28 C29 -23.4(9) . .
C27 C28 C29 C30 31.1(9) . .
C27 O2 C30 C29 10.7(9) . .
K3 O2 C30 C29 -149.9(5) . .
C28 C29 C30 O2 -26.9(9) . .
C31 O3 C31 C32 9.9(3) 2_675 .
O3 C31 C32 C32 -23.9(5) . 2_675
