#------------------------------------------------------------------------------
#$Date: 2017-06-06 05:15:30 +0300 (Tue, 06 Jun 2017) $
#$Revision: 197550 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/32/7043247.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7043247
loop_
_publ_author_name
'Ohno, Keiji'
'Tanuma, Honami'
'Kusano, Yukiko'
'Kaizaki, Sumio'
'Nagasawa, Akira'
'Fujihara, Takashi'
_publ_section_title
;
 Luminescence of tartrate bridged dinuclear 2,2′-bipyridine
 platinum(ii) complexes: emission color controlled by intra- and
 inter-molecular interactions in the solid state
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT00745K
_journal_year                    2017
_chemical_formula_sum            'C48 H86 N8 O37 Pt4'
_chemical_formula_weight         2147.60
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2017-05-16 deposited with the CCDC.
2017-05-18 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 120.006(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   23.328(6)
_cell_length_b                   15.799(4)
_cell_length_c                   22.403(6)
_cell_measurement_reflns_used    9011
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      26.21
_cell_measurement_theta_min      2.23
_cell_volume                     7150(3)
_computing_cell_refinement       'Bruker SAINT (Bruker 2014)'
_computing_data_collection       'Bruker APEX2 (Bruker 2014)'
_computing_data_reduction        'Bruker SAINT and XPREP (Bruker 2014)'
_computing_molecular_graphics    'ORTEP-3 for Windows (Farrugia, 2012)'
_computing_publication_material  'XCIF (Bruker, 2014)'
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXL-2016/6 (Sheldrick, 2016)'
_diffrn_ambient_temperature      200(2)
_diffrn_detector_area_resol_mean 8.333
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  'Bruker Helios multilayer confocal mirror'
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0709
_diffrn_reflns_av_unetI/netI     0.0557
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            35844
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.000
_diffrn_reflns_theta_min         1.636
_exptl_absorpt_coefficient_mu    7.897
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS-2014/2 - Bruker 2014'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.995
_exptl_crystal_description       Prism
_exptl_crystal_F_000             4152
_exptl_crystal_size_max          0.065
_exptl_crystal_size_mid          0.034
_exptl_crystal_size_min          0.021
_exptl_transmission_factor_max   0.8621
_exptl_transmission_factor_min   0.5991
_refine_diff_density_max         5.030
_refine_diff_density_min         -1.102
_refine_diff_density_rms         0.254
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.129
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     448
_refine_ls_number_reflns         7030
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.136
_refine_ls_R_factor_all          0.0861
_refine_ls_R_factor_gt           0.0549
_refine_ls_shift/su_max          0.100
_refine_ls_shift/su_mean         0.004
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0754P)²+167.0237P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1439
_refine_ls_wR_factor_ref         0.1708
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5090
_reflns_number_total             7030
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7dt00745k2.cif
_cod_data_source_block           2_125H2O
_cod_database_code               7043247
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.628
_shelx_estimated_absorpt_t_max   0.852
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
O11S O 0.5401(12) 0.2378(14) 0.4721(9) 0.153(8) Uani 1 1 d . . . . .
C1 C 0.0439(7) 0.2591(9) 0.1316(7) 0.048(3) Uani 1 1 d . . . . .
C2 C 0.0431(6) 0.2564(8) 0.1992(7) 0.043(3) Uani 1 1 d . . . . .
H2 H 0.012513 0.301878 0.197407 0.052 Uiso 1 1 calc R U . . .
C3 C 0.1120(6) 0.2745(8) 0.2616(7) 0.042(3) Uani 1 1 d . . . . .
H3 H 0.131700 0.323722 0.250141 0.050 Uiso 1 1 calc R U . . .
C4 C 0.1541(7) 0.1980(9) 0.2721(8) 0.050(3) Uani 1 1 d . . . . .
C5 C -0.0606(7) 0.0734(10) -0.0248(7) 0.050(3) Uani 1 1 d . . . . .
H5 H -0.039681 0.125490 -0.023362 0.060 Uiso 1 1 calc R U . . .
C6 C -0.0874(7) 0.0231(11) -0.0830(7) 0.057(4) Uani 1 1 d . . . . .
H6 H -0.086507 0.042485 -0.122736 0.069 Uiso 1 1 calc R U . . .
C7 C -0.1142(9) -0.0518(14) -0.0848(9) 0.077(5) Uani 1 1 d . . . . .
H7 H -0.131553 -0.085435 -0.125353 0.092 Uiso 1 1 calc R U . . .
C8 C -0.1171(8) -0.0808(11) -0.0287(9) 0.065(4) Uani 1 1 d . . . . .
H8 H -0.134579 -0.135241 -0.029024 0.078 Uiso 1 1 calc R U . . .
C9 C -0.0941(7) -0.0293(9) 0.0278(7) 0.047(3) Uani 1 1 d . . . . .
C10 C -0.0979(7) -0.0473(8) 0.0908(7) 0.047(3) Uani 1 1 d . . . . .
C11 C -0.1270(9) -0.1168(11) 0.1019(9) 0.069(5) Uani 1 1 d . . . . .
H11 H -0.142951 -0.161361 0.069081 0.083 Uiso 1 1 calc R U . . .
C12 C -0.1333(9) -0.1230(11) 0.1580(10) 0.073(5) Uani 1 1 d . . . . .
H12 H -0.154028 -0.170576 0.165217 0.088 Uiso 1 1 calc R U . . .
C13 C -0.1085(8) -0.0572(10) 0.2050(8) 0.061(4) Uani 1 1 d . . . . .
H13 H -0.112050 -0.059605 0.245358 0.073 Uiso 1 1 calc R U . . .
C14 C -0.0797(4) 0.0092(8) 0.1945(6) 0.046(3) Uani 1 1 d . . . . .
H14 H -0.063870 0.053911 0.227266 0.055 Uiso 1 1 calc R U . . .
C15 C 0.1078(7) 0.3428(9) 0.4597(8) 0.055(4) Uani 1 1 d . . . . .
H15 H 0.089926 0.372558 0.417294 0.066 Uiso 1 1 calc R U . . .
C16 C 0.0977(8) 0.3742(10) 0.5115(9) 0.062(4) Uani 1 1 d . . . . .
H16 H 0.072165 0.423958 0.504445 0.075 Uiso 1 1 calc R U . . .
C17 C 0.1256(9) 0.3316(12) 0.5738(9) 0.070(5) Uani 1 1 d . . . . .
H17 H 0.119495 0.351912 0.610137 0.084 Uiso 1 1 calc R U . . .
C18 C 0.1614(8) 0.2611(10) 0.5826(8) 0.058(4) Uani 1 1 d . . . . .
H18 H 0.180915 0.232132 0.625444 0.070 Uiso 1 1 calc R U . . .
C19 C 0.1698(7) 0.2311(9) 0.5306(8) 0.051(3) Uani 1 1 d . . . . .
C20 C 0.2064(6) 0.1547(9) 0.5345(8) 0.049(3) Uani 1 1 d . . . . .
C21 C 0.2371(7) 0.0996(10) 0.5921(8) 0.055(4) Uani 1 1 d . . . . .
H21 H 0.236215 0.111229 0.633228 0.066 Uiso 1 1 calc R U . . .
C22 C 0.2681(8) 0.0288(11) 0.5861(9) 0.063(4) Uani 1 1 d . . . . .
H22 H 0.288144 -0.010447 0.623140 0.075 Uiso 1 1 calc R U . . .
C23 C 0.2703(7) 0.0148(11) 0.5278(9) 0.067(5) Uani 1 1 d . . . . .
H23 H 0.293647 -0.032950 0.525071 0.080 Uiso 1 1 calc R U . . .
C24 C 0.2396(6) 0.0680(9) 0.4729(8) 0.052(4) Uani 1 1 d . . . . .
H24 H 0.240469 0.055776 0.431803 0.063 Uiso 1 1 calc R U . . .
N1 N -0.0650(5) 0.0465(7) 0.0308(5) 0.040(2) Uani 1 1 d . . . . .
N2 N -0.0723(5) 0.0150(6) 0.1389(5) 0.040(2) Uani 1 1 d . . . . .
N3 N 0.1423(5) 0.2713(7) 0.4679(6) 0.048(3) Uani 1 1 d . . . . .
N4 N 0.2081(5) 0.1374(7) 0.4760(6) 0.045(3) Uani 1 1 d . . . . .
O1 O 0.0137(5) 0.1985(6) 0.0884(5) 0.047(2) Uani 1 1 d . . . . .
O2 O 0.0688(6) 0.3186(7) 0.1177(6) 0.066(3) Uani 1 1 d . . . . .
O3 O 0.0180(4) 0.1768(5) 0.2077(4) 0.0362(18) Uani 1 1 d . . . . .
O4 O 0.1068(5) 0.2954(5) 0.3185(5) 0.046(2) Uani 1 1 d . . . . .
O5 O 0.1790(4) 0.1607(6) 0.3319(5) 0.049(2) Uani 1 1 d . . . . .
O6 O 0.1641(5) 0.1701(7) 0.2259(5) 0.064(3) Uani 1 1 d . . . . .
O1S O 0.0557(10) 0.4955(10) 0.1080(13) 0.170(9) Uani 1 1 d . . . . .
H1SA H 0.021362 0.528582 0.087295 0.255 Uiso 1 1 d R U . . .
H1SB H 0.042842 0.442982 0.100106 0.255 Uiso 1 1 d R U . . .
O2SA O 0.0742(17) 0.463(2) 0.2896(19) 0.056(7) Uani 0.5 1 d . . P A 1
H2SA H 0.037053 0.463541 0.250547 0.083 Uiso 0.5 1 d R U P A 1
H2SB H 0.091763 0.413221 0.297179 0.083 Uiso 0.5 1 d R U P A 1
O2SB O 0.055(2) 0.453(3) 0.307(2) 0.084(12) Uani 0.5 1 d . . P B 2
H2SC H 0.045730 0.458107 0.259774 0.126 Uiso 0.5 1 d R U P B 2
H2SD H 0.092440 0.407787 0.306404 0.126 Uiso 0.5 1 d R U P B 2
O3S O 0.0975(11) 0.6250(12) 0.3466(11) 0.160(8) Uani 1 1 d . . . . .
H3SA H 0.098399 0.579112 0.325572 0.240 Uiso 1 1 d R U . . .
H3SB H 0.086199 0.612439 0.377072 0.240 Uiso 1 1 d R U . . .
O4S O 0.2695(12) 0.1979(14) 0.0789(18) 0.254(18) Uani 1 1 d . . . . .
H4SA H 0.309094 0.176461 0.100152 0.381 Uiso 1 1 d R U . . .
H4SB H 0.246973 0.175421 0.038092 0.381 Uiso 1 1 d R U . . .
O5S O 0.2168(8) 0.2765(11) 0.1540(9) 0.122(6) Uani 1 1 d . . . . .
H5SA H 0.237716 0.242620 0.140848 0.183 Uiso 1 1 d R U . . .
H5SB H 0.183176 0.250070 0.152118 0.183 Uiso 1 1 d R U . . .
O6S O 0.1876(9) 0.4393(12) 0.0905(9) 0.127(6) Uani 1 1 d . . . . .
H6SA H 0.196242 0.389321 0.109245 0.191 Uiso 1 1 d R U . . .
H6SB H 0.202403 0.477731 0.122615 0.191 Uiso 1 1 d R U . . .
O7S O 0.2974(9) 0.3568(11) 0.2783(8) 0.169(10) Uani 1 1 d . . . . .
H7SA H 0.275339 0.329721 0.239451 0.254 Uiso 1 1 d R U . . .
H7SB H 0.329180 0.385570 0.278141 0.254 Uiso 1 1 d R U . . .
O8S O 0.2529(9) 0.0261(10) 0.2754(11) 0.144(7) Uani 1 1 d . . . . .
H8SA H 0.232571 0.072390 0.275111 0.215 Uiso 1 1 d R U . . .
H8SB H 0.225410 -0.007070 0.242402 0.215 Uiso 1 1 d R U . . .
O9S O 0.4604(10) 0.3199(13) 0.3629(11) 0.223(14) Uani 1 1 d . . . . .
H9SA H 0.417916 0.324687 0.346229 0.334 Uiso 1 1 d R U . . .
H9SB H 0.469048 0.320907 0.329419 0.334 Uiso 1 1 d R U . . .
O10S O 0.0668(11) 0.5784(13) 0.4499(14) 0.197(11) Uani 1 1 d . . . . .
H10A H 0.047919 0.625435 0.451008 0.295 Uiso 1 1 d R U . . .
H10B H 0.104569 0.573195 0.487889 0.295 Uiso 1 1 d R U . . .
H11A H 0.515165 0.259158 0.431511 0.295 Uiso 1 1 d R U . . .
H11B H 0.535505 0.264601 0.502692 0.295 Uiso 1 1 d R U . . .
O12S O 0.500000 0.2215(16) 0.250000 0.187(15) Uani 1 2 d S T P . .
H12A H 0.476650 0.252418 0.262110 0.281 Uiso 0.5 1 d R U P . .
H12B H 0.533170 0.199368 0.286520 0.281 Uiso 0.5 1 d R U P . .
O13S O 0.1373(12) 0.5574(19) 0.2358(12) 0.197(11) Uani 1 1 d . . . . .
H13A H 0.110735 0.538170 0.194587 0.296 Uiso 1 1 d R U . . .
H13B H 0.178056 0.553101 0.244658 0.296 Uiso 1 1 d R U . . .
Pt1 Pt -0.02833(2) 0.11030(3) 0.11760(2) 0.03600(16) Uani 1 1 d . . . . .
Pt2 Pt 0.15884(2) 0.21765(3) 0.39858(3) 0.04045(17) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
H11A O11S H11B 111.0 . .
O2 C1 O1 121.9(13) . .
O2 C1 C2 121.2(13) . .
O1 C1 C2 116.8(12) . .
O3 C2 C1 111.3(11) . .
O3 C2 C3 110.6(10) . .
C1 C2 C3 111.9(11) . .
O3 C2 H2 107.6 . .
C1 C2 H2 107.6 . .
C3 C2 H2 107.6 . .
O4 C3 C4 113.6(11) . .
O4 C3 C2 110.5(11) . .
C4 C3 C2 107.2(10) . .
O4 C3 H3 108.4 . .
C4 C3 H3 108.4 . .
C2 C3 H3 108.4 . .
O6 C4 O5 121.3(13) . .
O6 C4 C3 122.3(14) . .
O5 C4 C3 116.4(13) . .
N1 C5 C6 118.6(15) . .
N1 C5 H5 120.7 . .
C6 C5 H5 120.7 . .
C7 C6 C5 121.5(16) . .
C7 C6 H6 119.2 . .
C5 C6 H6 119.2 . .
C6 C7 C8 120.5(16) . .
C6 C7 H7 119.7 . .
C8 C7 H7 119.7 . .
C9 C8 C7 118.2(17) . .
C9 C8 H8 120.9 . .
C7 C8 H8 120.9 . .
N1 C9 C8 121.6(15) . .
N1 C9 C10 112.7(11) . .
C8 C9 C10 125.7(15) . .
N2 C10 C11 119.7(14) . .
N2 C10 C9 113.9(12) . .
C11 C10 C9 126.3(13) . .
C12 C11 C10 121.5(15) . .
C12 C11 H11 119.2 . .
C10 C11 H11 119.2 . .
C11 C12 C13 117.2(16) . .
C11 C12 H12 121.4 . .
C13 C12 H12 121.4 . .
C14 C13 C12 121.1(15) . .
C14 C13 H13 119.5 . .
C12 C13 H13 119.5 . .
C13 C14 N2 121.9(13) . .
C13 C14 H14 119.1 . .
N2 C14 H14 119.1 . .
N3 C15 C16 121.8(15) . .
N3 C15 H15 119.1 . .
C16 C15 H15 119.1 . .
C17 C16 C15 118.5(16) . .
C17 C16 H16 120.7 . .
C15 C16 H16 120.7 . .
C18 C17 C16 119.7(17) . .
C18 C17 H17 120.2 . .
C16 C17 H17 120.2 . .
C17 C18 C19 120.6(16) . .
C17 C18 H18 119.7 . .
C19 C18 H18 119.7 . .
C18 C19 N3 121.5(14) . .
C18 C19 C20 124.7(15) . .
N3 C19 C20 113.8(13) . .
N4 C20 C21 120.6(14) . .
N4 C20 C19 114.1(13) . .
C21 C20 C19 125.3(15) . .
C22 C21 C20 117.5(15) . .
C22 C21 H21 121.2 . .
C20 C21 H21 121.2 . .
C23 C22 C21 120.2(15) . .
C23 C22 H22 119.9 . .
C21 C22 H22 119.9 . .
C22 C23 C24 121.1(16) . .
C22 C23 H23 119.5 . .
C24 C23 H23 119.4 . .
N4 C24 C23 120.8(16) . .
N4 C24 H24 119.6 . .
C23 C24 H24 119.6 . .
C9 N1 C5 119.4(12) . .
C9 N1 Pt1 117.3(9) . .
C5 N1 Pt1 123.2(10) . .
C14 N2 C10 118.5(11) . .
C14 N2 Pt1 126.1(8) . .
C10 N2 Pt1 115.4(9) . .
C15 N3 C19 117.9(13) . .
C15 N3 Pt2 126.4(11) . .
C19 N3 Pt2 115.7(9) . .
C24 N4 C20 119.8(12) . .
C24 N4 Pt2 124.7(10) . .
C20 N4 Pt2 115.5(9) . .
C1 O1 Pt1 116.5(9) . .
C2 O3 Pt1 111.6(7) . .
C3 O4 Pt2 112.8(7) . .
C4 O5 Pt2 114.6(9) . .
H1SA O1S H1SB 109.5 . .
H2SA O2SA H2SB 109.5 . .
H2SC O2SB H2SD 79.0 . .
H3SA O3S H3SB 109.5 . .
H4SA O4S H4SB 109.5 . .
H5SA O5S H5SB 109.5 . .
H6SA O6S H6SB 109.5 . .
H7SA O7S H7SB 109.5 . .
H8SA O8S H8SB 109.5 . .
H9SA O9S H9SB 109.5 . .
H10A O10S H10B 109.5 . .
H12A O12S H12B 109.5 . .
H12A O12S H12A 111.6 . 2_655
H12B O12S H12A 96.8 . 2_655
H12A O12S H12B 96.8 . 2_655
H12B O12S H12B 132.7 . 2_655
H12A O12S H12B 109.5 2_655 2_655
H13A O13S H13B 109.5 . .
N1 Pt1 O1 94.4(4) . .
N1 Pt1 N2 80.2(5) . .
O1 Pt1 N2 174.5(4) . .
N1 Pt1 O3 174.6(4) . .
O1 Pt1 O3 82.0(3) . .
N2 Pt1 O3 103.4(4) . .
N3 Pt2 N4 80.9(5) . .
N3 Pt2 O5 177.4(4) . .
N4 Pt2 O5 96.7(4) . .
N3 Pt2 O4 99.9(4) . .
N4 Pt2 O4 178.0(4) . .
O5 Pt2 O4 82.5(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
O11S H11A 0.8657 .
O11S H11B 0.8583 .
C1 O2 1.225(17) .
C1 O1 1.291(16) .
C1 C2 1.52(2) .
C2 O3 1.440(14) .
C2 C3 1.539(17) .
C2 H2 1.0000 .
C3 O4 1.379(16) .
C3 C4 1.500(19) .
C3 H3 1.0000 .
C4 O6 1.249(17) .
C4 O5 1.305(17) .
C5 N1 1.366(18) .
C5 C6 1.38(2) .
C5 H5 0.9500 .
C6 C7 1.33(3) .
C6 H6 0.9500 .
C7 C8 1.37(3) .
C7 H7 0.9500 .
C8 C9 1.37(2) .
C8 H8 0.9500 .
C9 N1 1.362(18) .
C9 C10 1.49(2) .
C10 N2 1.357(16) .
C10 C11 1.38(2) .
C11 C12 1.34(2) .
C11 H11 0.9500 .
C12 C13 1.38(2) .
C12 H12 0.9500 .
C13 C14 1.329(18) .
C13 H13 0.9500 .
C14 N2 1.343(17) .
C14 H14 0.9500 .
C15 N3 1.345(18) .
C15 C16 1.39(2) .
C15 H15 0.9500 .
C16 C17 1.38(2) .
C16 H16 0.9500 .
C17 C18 1.35(2) .
C17 H17 0.9500 .
C18 C19 1.36(2) .
C18 H18 0.9500 .
C19 N3 1.374(19) .
C19 C20 1.46(2) .
C20 N4 1.359(19) .
C20 C21 1.417(19) .
C21 C22 1.38(2) .
C21 H21 0.9500 .
C22 C23 1.35(2) .
C22 H22 0.9500 .
C23 C24 1.36(2) .
C23 H23 0.9500 .
C24 N4 1.341(18) .
C24 H24 0.9500 .
N1 Pt1 1.966(10) .
N2 Pt1 2.009(11) .
N3 Pt2 1.969(12) .
N4 Pt2 1.986(11) .
O1 Pt1 1.993(9) .
O3 Pt1 2.041(8) .
O4 Pt2 2.005(9) .
O5 Pt2 1.991(9) .
O1S H1SA 0.8700 .
O1S H1SB 0.8699 .
O2SA H2SA 0.8703 .
O2SA H2SB 0.8698 .
O2SB H2SC 0.9620 .
O2SB H2SD 1.1217 .
O3S H3SA 0.8698 .
O3S H3SB 0.8698 .
O4S H4SA 0.8699 .
O4S H4SB 0.8701 .
O5S H5SA 0.8700 .
O5S H5SB 0.8699 .
O6S H6SA 0.8699 .
O6S H6SB 0.8700 .
O7S H7SA 0.8699 .
O7S H7SB 0.8702 .
O8S H8SA 0.8699 .
O8S H8SB 0.8700 .
O9S H9SA 0.8698 .
O9S H9SB 0.8699 .
O10S H10A 0.8700 .
O10S H10B 0.8699 .
O12S H12A 0.8702 .
O12S H12B 0.8700 .
O12S H12A 0.8701 2_655
O12S H12B 0.8700 2_655
O13S H13A 0.8699 .
O13S H13B 0.8703 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O13S H13B O8S 0.87 1.92 2.74(3) 155.4 4
O13S H13A O1S 0.87 1.84 2.71(4) 178.8 .
O12S H12A O9S 0.87 2.69 3.466(18) 149.0 .
O12S H12B O3S 0.87 1.85 2.69(2) 162.8 3_545
O11S H11B O2 0.86 2.64 3.12(2) 116.2 8_556
O11S H11B O1 0.86 2.29 3.13(2) 164.6 8_556
O11S H11A O9S 0.87 1.72 2.56(3) 165.0 .
O10S H10B O6S 0.87 2.15 3.01(3) 169.9 6_566
O10S H10A O11S 0.87 1.87 2.70(3) 158.8 3_455
O9S H9SA O7S 0.87 2.49 3.34(2) 167.4 .
O8S H8SB O7S 0.87 2.21 2.926(17) 139.6 4_545
O8S H8SA O6 0.87 2.10 2.898(19) 153.2 .
O8S H8SA O5 0.87 2.59 3.359(19) 147.5 .
O7S H7SA O5S 0.87 1.90 2.77(3) 172.4 .
O6S H6SB O8S 0.87 2.12 2.94(3) 156.8 4
O6S H6SA O5S 0.87 1.98 2.85(2) 178.7 .
O5S H5SB O6 0.87 2.29 2.98(2) 136.4 .
O5S H5SB O2 0.87 2.61 3.19(2) 125.3 .
O5S H5SA O4S 0.87 2.00 2.82(3) 156.7 .
O4S H4SA O3S 0.87 2.06 2.93(4) 178.0 4_545
O3S H3SB O10S 0.87 1.97 2.84(4) 175.5 .
O3S H3SA O13S 0.87 2.61 3.24(3) 129.6 .
O3S H3SA O2SB 0.87 2.18 2.88(5) 137.3 .
O3S H3SA O2SA 0.87 1.96 2.78(4) 156.6 .
O2SB H2SD O4 1.12 1.80 2.72(4) 135.2 .
O2SB H2SC O2SB 0.96 2.07 2.56(9) 110.0 2
O2SA H2SB O4 0.87 1.91 2.75(4) 161.3 .
O2SA H2SA O2SA 0.87 2.28 3.00(7) 139.4 2
O1S H1SB O2 0.87 2.04 2.809(19) 147.4 .
O1S H1SA O10S 0.87 1.96 2.80(2) 163.6 2
C24 H24 O5 0.95 2.57 3.108(17) 116.1 .
C21 H21 O7S 0.95 2.52 3.45(2) 165.4 7_556
C18 H18 O7S 0.95 2.41 3.33(2) 165.3 7_556
C15 H15 O2SB 0.95 2.53 3.48(4) 173.5 .
C14 H14 O3 0.95 2.34 3.275(15) 167.8 2
C6 H6 O9S 0.95 2.53 3.19(3) 127.6 8_455
C5 H5 O1 0.95 2.46 2.991(18) 115.5 .
C2 H2 O4 1.00 2.63 3.375(17) 131.7 2
