#------------------------------------------------------------------------------
#$Date: 2017-06-08 05:11:59 +0300 (Thu, 08 Jun 2017) $
#$Revision: 197637 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/32/7043265.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7043265
loop_
_publ_author_name
'Guo, Qianqian'
'Englert, Ulli'
_publ_section_title
;
 Neutral mixed-metal coordination polymers based on a ditopic
 acetylacetonate, Mg(II) and Ag(I): syntheses, characterization and
 solvent-dependent topologies
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT01283G
_journal_year                    2017
_chemical_formula_moiety         'C18 H18 Ag Mg N3 O6, 4(C H Cl3)'
_chemical_formula_sum            'C22 H22 Ag Cl12 Mg N3 O6'
_chemical_formula_weight         982.00
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2017-04-03 deposited with the CCDC.
2017-06-06 downloaded from the CCDC.
;
_cell_angle_alpha                93.407(4)
_cell_angle_beta                 115.185(3)
_cell_angle_gamma                118.122(3)
_cell_formula_units_Z            2
_cell_length_a                   13.165(3)
_cell_length_b                   13.170(3)
_cell_length_c                   14.234(3)
_cell_measurement_reflns_used    3006
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.11
_cell_measurement_theta_min      2.79
_cell_volume                     1862.2(7)
_computing_cell_refinement       'SAINT (Bruker, 2009)'
_computing_data_collection       'SMART (Bruker, 2002)'
_computing_data_reduction        'SAINT (Bruker, 2009)'
_computing_molecular_graphics    'PLATON (Spek, 2009)'
_computing_publication_material  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0736
_diffrn_reflns_av_unetI/netI     0.1027
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.986
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            17150
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.986
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.697
_diffrn_reflns_theta_min         1.858
_diffrn_source                   'Incoatec microsource'
_exptl_absorpt_coefficient_mu    1.459
_exptl_absorpt_correction_T_max  0.7454
_exptl_absorpt_correction_T_min  0.4258
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.751
_exptl_crystal_description       plate
_exptl_crystal_F_000             972
_exptl_crystal_size_max          0.310
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.170
_refine_diff_density_max         0.892
_refine_diff_density_min         -1.196
_refine_diff_density_rms         0.122
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     523
_refine_ls_number_reflns         7777
_refine_ls_number_restraints     313
_refine_ls_restrained_S_all      1.069
_refine_ls_R_factor_all          0.0773
_refine_ls_R_factor_gt           0.0544
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0521P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1308
_refine_ls_wR_factor_ref         0.1410
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5725
_reflns_number_total             7777
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7dt01283g2.cif
_cod_data_source_block           3a
_cod_database_code               7043265
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.661
_shelx_estimated_absorpt_t_max   0.790
_shelxl_version_number           2013-4
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Mg1 Mg 0.92761(14) 0.63365(13) 0.70441(11) 0.0205(3) Uani 1 1 d . . . . .
O1 O 0.7378(3) 0.5369(3) 0.6775(3) 0.0358(8) Uani 1 1 d . . . . .
O2 O 0.9712(3) 0.7467(3) 0.8399(2) 0.0252(7) Uani 1 1 d . . . . .
O3 O 0.9745(3) 0.5247(3) 0.7865(2) 0.0289(7) Uani 1 1 d . . . . .
O4 O 1.1285(3) 0.7384(3) 0.7587(2) 0.0229(7) Uani 1 1 d . . . . .
O5 O 0.8710(3) 0.5294(3) 0.5585(2) 0.0284(7) Uani 1 1 d . . . . .
O6 O 0.9015(3) 0.7492(3) 0.6212(2) 0.0325(8) Uani 1 1 d . . . . .
C1 C 0.5475(6) 0.4443(7) 0.6973(6) 0.081(3) Uani 1 1 d D U . . .
H1A H 0.4918 0.4767 0.6652 0.122 Uiso 1 1 calc R U . . .
H1B H 0.5393 0.4204 0.7589 0.122 Uiso 1 1 calc R U . . .
H1C H 0.5173 0.3731 0.6414 0.122 Uiso 1 1 calc R U . . .
C2 C 0.6925(5) 0.5410(5) 0.7379(4) 0.0386(12) Uani 1 1 d D U . . .
C3 C 0.7707(5) 0.6327(4) 0.8423(4) 0.0261(9) Uani 1 1 d . U . . .
C4 C 0.9063(5) 0.7342(4) 0.8875(4) 0.0252(10) Uani 1 1 d . . . . .
C5 C 0.9742(5) 0.8293(4) 0.9936(4) 0.0328(11) Uani 1 1 d . . . . .
H5A H 1.0658 0.8913 1.0129 0.049 Uiso 1 1 calc R U . . .
H5B H 0.9775 0.7918 1.0514 0.049 Uiso 1 1 calc R U . . .
H5C H 0.9239 0.8674 0.9864 0.049 Uiso 1 1 calc R U . . .
C6 C 0.7082(5) 0.6275(4) 0.9028(4) 0.0279(10) Uani 1 1 d . . . . .
C7 C 1.0859(5) 0.4484(5) 0.9091(6) 0.074(3) Uani 1 1 d . . . . .
H7A H 1.1331 0.4881 0.9884 0.111 Uiso 1 1 calc R U . . .
H7B H 1.1320 0.4154 0.8934 0.111 Uiso 1 1 calc R U . . .
H7C H 0.9933 0.3821 0.8832 0.111 Uiso 1 1 calc R U . . .
C8 C 1.0847(5) 0.5405(4) 0.8506(4) 0.0303(11) Uani 1 1 d . . . . .
C9 C 1.2108(4) 0.6421(4) 0.8740(4) 0.0240(10) Uani 1 1 d . . . . .
C10 C 1.2258(4) 0.7361(4) 0.8259(3) 0.0218(9) Uani 1 1 d . . . . .
C11 C 1.3652(5) 0.8389(4) 0.8569(4) 0.0331(11) Uani 1 1 d . . . . .
H11A H 1.4134 0.8050 0.8467 0.050 Uiso 1 1 calc R U . . .
H11B H 1.4143 0.8883 0.9340 0.050 Uiso 1 1 calc R U . . .
H11C H 1.3580 0.8898 0.8102 0.050 Uiso 1 1 calc R U . . .
C12 C 1.3295(4) 0.6484(4) 0.9488(4) 0.0277(10) Uani 1 1 d . . . . .
C13 C 0.8480(6) 0.8413(5) 0.4855(4) 0.0414(13) Uani 1 1 d . . . . .
H13A H 0.8878 0.9089 0.5499 0.062 Uiso 1 1 calc R U . . .
H13B H 0.7539 0.8127 0.4359 0.062 Uiso 1 1 calc R U . . .
H13C H 0.8977 0.8691 0.4472 0.062 Uiso 1 1 calc R U . . .
C14 C 0.8553(5) 0.7389(5) 0.5218(4) 0.0297(11) Uani 1 1 d . . . . .
C15 C 0.8101(4) 0.6346(4) 0.4403(3) 0.0257(10) Uani 1 1 d . . . . .
C16 C 0.8259(5) 0.5366(4) 0.4635(4) 0.0284(10) Uani 1 1 d . . . . .
C17 C 0.7892(7) 0.4393(6) 0.3727(4) 0.0588(18) Uani 1 1 d . . . . .
H17A H 0.8641 0.4290 0.3941 0.088 Uiso 1 1 calc R U . . .
H17B H 0.7701 0.4627 0.3062 0.088 Uiso 1 1 calc R U . . .
H17C H 0.7094 0.3625 0.3584 0.088 Uiso 1 1 calc R U . . .
C18 C 0.7547(4) 0.6328(4) 0.3296(3) 0.0274(10) Uani 1 1 d . . . . .
N1 N 0.6589(4) 0.6238(4) 0.9550(3) 0.0321(9) Uani 1 1 d . . . . .
N2 N 1.4254(4) 0.6541(4) 1.0098(3) 0.0335(10) Uani 1 1 d . . . . .
N3 N 0.7078(4) 0.6327(4) 0.2412(3) 0.0341(10) Uani 1 1 d . . . . .
Ag1 Ag 0.59999(3) 0.63706(3) 0.07706(3) 0.02405(12) Uani 1 1 d . . . . .
C19 C 1.1620(5) 1.0051(5) 0.8132(4) 0.0316(11) Uani 1 1 d D . . . .
H19 H 1.1019 0.9145 0.7901 0.038 Uiso 1 1 calc R U . . .
Cl1 Cl 1.06409(19) 1.0688(2) 0.78353(14) 0.0743(6) Uani 1 1 d D . . . .
Cl2 Cl 1.27715(14) 1.06282(14) 0.95515(11) 0.0520(4) Uani 1 1 d D . . . .
Cl3 Cl 1.24726(16) 1.04337(14) 0.74172(12) 0.0494(4) Uani 1 1 d D . . . .
C20A C 0.6148(10) 0.1903(8) 0.8182(7) 0.053(3) Uani 0.587(7) 1 d D U P A 1
H20A H 0.5698 0.2141 0.8479 0.063 Uiso 0.587(7) 1 calc R U P A 1
Cl4A Cl 0.7171(5) 0.3193(4) 0.7886(4) 0.0535(10) Uani 0.587(7) 1 d D U P A 1
Cl5A Cl 0.6747(4) 0.1144(3) 0.8993(4) 0.0606(12) Uani 0.587(7) 1 d D U P A 1
Cl6A Cl 0.4936(4) 0.0920(4) 0.6825(3) 0.0702(13) Uani 0.587(7) 1 d D U P A 1
C20B C 0.5787(10) 0.1962(9) 0.7729(10) 0.043(3) Uani 0.413(7) 1 d D U P A 2
H20B H 0.5432 0.2169 0.8155 0.052 Uiso 0.413(7) 1 calc R U P A 2
Cl4B Cl 0.7542(6) 0.3242(6) 0.8338(6) 0.0499(14) Uani 0.413(7) 1 d D U P A 2
Cl5B Cl 0.6185(6) 0.0914(5) 0.8240(8) 0.087(2) Uani 0.413(7) 1 d D U P A 2
Cl6B Cl 0.4425(5) 0.1177(4) 0.6336(4) 0.0515(14) Uani 0.413(7) 1 d D U P A 2
C21A C 0.8258(8) 0.2482(9) 0.5617(6) 0.038(2) Uani 0.568(3) 1 d D U P B 1
H21A H 0.8406 0.3308 0.5723 0.045 Uiso 0.568(3) 1 calc R U P B 1
Cl7A Cl 0.8273(3) 0.2060(2) 0.4433(2) 0.0426(6) Uani 0.568(3) 1 d D U P B 1
Cl8A Cl 0.9569(3) 0.2551(3) 0.6766(2) 0.0530(8) Uani 0.568(3) 1 d D U P B 1
Cl9A Cl 0.6700(3) 0.1444(3) 0.5482(3) 0.0647(9) Uani 0.568(3) 1 d D U P B 1
C21B C 0.8012(10) 0.2342(12) 0.6003(10) 0.043(3) Uani 0.432(3) 1 d D U P B 2
H21B H 0.8394 0.3130 0.6540 0.051 Uiso 0.432(3) 1 calc R U P B 2
Cl7B Cl 0.9042(5) 0.2588(5) 0.5468(5) 0.0871(18) Uani 0.432(3) 1 d D U P B 2
Cl8B Cl 0.8010(3) 0.1281(3) 0.6712(3) 0.0596(12) Uani 0.432(3) 1 d D U P B 2
Cl9B Cl 0.6380(3) 0.1824(3) 0.4993(3) 0.0547(10) Uani 0.432(3) 1 d D U P B 2
C22A C 0.4192(8) 0.1934(9) 0.3502(7) 0.048(3) Uani 0.470(3) 1 d D U P C 1
H22A H 0.4272 0.1240 0.3670 0.058 Uiso 0.470(3) 1 calc R U P C 1
Cl11 Cl 0.4244(5) 0.2083(4) 0.2292(3) 0.0664(13) Uani 0.470(3) 1 d D U P C 1
Cl12 Cl 0.5535(3) 0.3289(3) 0.4598(2) 0.0444(9) Uani 0.470(3) 1 d D U P C 1
Cl13 Cl 0.2670(4) 0.1663(4) 0.3315(4) 0.0626(12) Uani 0.470(3) 1 d D U P C 1
C22B C 0.3250(12) 0.1993(8) 0.3237(7) 0.057(3) Uani 0.530(3) 1 d D U P C 2
H22B H 0.2429 0.2013 0.3002 0.068 Uiso 0.530(3) 1 calc R U P C 2
Cl14 Cl 0.3389(5) 0.1757(4) 0.2082(3) 0.0675(12) Uani 0.530(3) 1 d D U P C 2
Cl15 Cl 0.4650(3) 0.3390(3) 0.4251(3) 0.0586(9) Uani 0.530(3) 1 d D U P C 2
Cl16 Cl 0.3050(3) 0.0779(3) 0.3742(3) 0.0636(10) Uani 0.530(3) 1 d D U P C 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mg Mg 0.0486 0.0363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Mg1 O1 92.43(14) . .
O5 Mg1 O2 172.93(13) . .
O1 Mg1 O2 85.16(13) . .
O5 Mg1 O4 96.31(14) . .
O1 Mg1 O4 170.43(14) . .
O2 Mg1 O4 86.60(13) . .
O5 Mg1 O6 85.18(13) . .
O1 Mg1 O6 95.66(15) . .
O2 Mg1 O6 88.43(13) . .
O4 Mg1 O6 88.96(13) . .
O5 Mg1 O3 92.57(13) . .
O1 Mg1 O3 91.13(14) . .
O2 Mg1 O3 94.12(13) . .
O4 Mg1 O3 84.61(12) . .
O6 Mg1 O3 172.93(14) . .
C2 O1 Mg1 131.4(3) . .
C4 O2 Mg1 131.6(3) . .
C8 O3 Mg1 131.3(3) . .
C10 O4 Mg1 132.2(3) . .
C16 O5 Mg1 132.3(3) . .
C14 O6 Mg1 131.6(3) . .
C2 C1 H1A 109.5 . .
C2 C1 H1B 109.5 . .
H1A C1 H1B 109.5 . .
C2 C1 H1C 109.5 . .
H1A C1 H1C 109.5 . .
H1B C1 H1C 109.5 . .
O1 C2 C3 123.2(4) . .
O1 C2 C1 117.9(5) . .
C3 C2 C1 118.9(5) . .
C6 C3 C2 117.9(4) . .
C6 C3 C4 117.3(4) . .
C2 C3 C4 124.7(4) . .
O2 C4 C3 122.1(4) . .
O2 C4 C5 118.0(4) . .
C3 C4 C5 119.9(4) . .
C4 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C4 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
N1 C6 C3 178.4(5) . .
C8 C7 H7A 109.5 . .
C8 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C8 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
O3 C8 C9 123.7(4) . .
O3 C8 C7 118.4(4) . .
C9 C8 C7 117.9(4) . .
C10 C9 C12 117.8(4) . .
C10 C9 C8 124.4(4) . .
C12 C9 C8 117.8(4) . .
O4 C10 C9 122.9(4) . .
O4 C10 C11 117.7(4) . .
C9 C10 C11 119.5(4) . .
C10 C11 H11A 109.5 . .
C10 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C10 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
N2 C12 C9 179.4(6) . .
C14 C13 H13A 109.5 . .
C14 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C14 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
O6 C14 C15 123.2(4) . .
O6 C14 C13 118.8(4) . .
C15 C14 C13 118.0(4) . .
C18 C15 C14 117.2(4) . .
C18 C15 C16 118.2(4) . .
C14 C15 C16 124.5(4) . .
O5 C16 C15 122.5(4) . .
O5 C16 C17 117.8(4) . .
C15 C16 C17 119.7(4) . .
C16 C17 H17A 109.5 . .
C16 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C16 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
N3 C18 C15 177.7(5) . .
C6 N1 Ag1 170.6(4) . 1_556
C12 N2 Ag1 161.5(4) . 1_656
C18 N3 Ag1 172.1(4) . .
N3 Ag1 N2 126.91(15) . 1_454
N3 Ag1 N1 121.46(14) . 1_554
N2 Ag1 N1 111.63(15) 1_454 1_554
N3 Ag1 Ag1 105.81(12) . 2_665
N2 Ag1 Ag1 87.42(11) 1_454 2_665
N1 Ag1 Ag1 74.33(11) 1_554 2_665
Cl3 C19 Cl2 110.2(3) . .
Cl3 C19 Cl1 109.3(2) . .
Cl2 C19 Cl1 108.9(3) . .
Cl3 C19 H19 109.5 . .
Cl2 C19 H19 109.5 . .
Cl1 C19 H19 109.5 . .
Cl5A C20A Cl6A 110.1(6) . .
Cl5A C20A Cl4A 124.2(7) . .
Cl6A C20A Cl4A 98.2(5) . .
Cl5A C20A H20A 107.7 . .
Cl6A C20A H20A 107.7 . .
Cl4A C20A H20A 107.7 . .
Cl5B C20B Cl6B 108.0(7) . .
Cl5B C20B Cl4B 95.4(5) . .
Cl6B C20B Cl4B 131.8(9) . .
Cl5B C20B H20B 106.4 . .
Cl6B C20B H20B 106.4 . .
Cl4B C20B H20B 106.4 . .
Cl7A C21A Cl8A 109.6(4) . .
Cl7A C21A Cl9A 110.7(5) . .
Cl8A C21A Cl9A 110.3(5) . .
Cl7A C21A H21A 108.7 . .
Cl8A C21A H21A 108.7 . .
Cl9A C21A H21A 108.7 . .
Cl7B C21B Cl9B 112.3(7) . .
Cl7B C21B Cl8B 108.9(6) . .
Cl9B C21B Cl8B 110.3(6) . .
Cl7B C21B H21B 108.4 . .
Cl9B C21B H21B 108.4 . .
Cl8B C21B H21B 108.4 . .
C21B Cl8B Cl16 136.6(5) . 2_656
Cl13 C22A Cl12 109.3(5) . .
Cl13 C22A Cl11 109.7(5) . .
Cl12 C22A Cl11 109.2(5) . .
Cl13 C22A H22A 109.6 . .
Cl12 C22A H22A 109.6 . .
Cl11 C22A H22A 109.6 . .
Cl16 C22B Cl14 109.3(6) . .
Cl16 C22B Cl15 111.3(6) . .
Cl14 C22B Cl15 111.1(6) . .
Cl16 C22B H22B 108.3 . .
Cl14 C22B H22B 108.3 . .
Cl15 C22B H22B 108.3 . .
C22B Cl16 Cl8B 145.3(4) . 2_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Mg1 O5 2.033(3) .
Mg1 O1 2.034(4) .
Mg1 O2 2.043(3) .
Mg1 O4 2.047(3) .
Mg1 O6 2.049(3) .
Mg1 O3 2.056(3) .
O1 C2 1.249(6) .
O2 C4 1.261(5) .
O3 C8 1.244(5) .
O4 C10 1.247(5) .
O5 C16 1.255(5) .
O6 C14 1.248(5) .
C1 C2 1.511(7) .
C1 H1A 0.9800 .
C1 H1B 0.9800 .
C1 H1C 0.9800 .
C2 C3 1.428(7) .
C3 C6 1.407(6) .
C3 C4 1.435(6) .
C4 C5 1.490(6) .
C5 H5A 0.9800 .
C5 H5B 0.9800 .
C5 H5C 0.9800 .
C6 N1 1.166(6) .
C7 C8 1.513(6) .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 C9 1.428(6) .
C9 C10 1.423(5) .
C9 C12 1.426(6) .
C10 C11 1.514(6) .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 N2 1.151(5) .
C13 C14 1.502(6) .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 C15 1.429(7) .
C15 C18 1.420(5) .
C15 C16 1.436(6) .
C16 C17 1.495(7) .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 N3 1.140(5) .
N1 Ag1 2.211(4) 1_556
N2 Ag1 2.211(3) 1_656
N3 Ag1 2.179(3) .
Ag1 N2 2.211(3) 1_454
Ag1 N1 2.211(4) 1_554
Ag1 Ag1 3.1558(9) 2_665
C19 Cl3 1.746(5) .
C19 Cl2 1.755(5) .
C19 Cl1 1.772(4) .
C19 H19 1.0000 .
C20A Cl5A 1.749(8) .
C20A Cl6A 1.757(9) .
C20A Cl4A 1.812(8) .
C20A H20A 1.0000 .
C20B Cl5B 1.784(10) .
C20B Cl6B 1.789(9) .
C20B Cl4B 1.839(10) .
C20B H20B 1.0000 .
C21A Cl7A 1.753(8) .
C21A Cl8A 1.759(7) .
C21A Cl9A 1.762(8) .
C21A H21A 1.0000 .
C21B Cl7B 1.738(9) .
C21B Cl9B 1.738(10) .
C21B Cl8B 1.772(9) .
C21B H21B 1.0000 .
C22A Cl13 1.754(8) .
C22A Cl12 1.759(9) .
C22A Cl11 1.771(9) .
C22A H22A 1.0000 .
C22B Cl16 1.744(9) .
C22B Cl14 1.757(9) .
C22B Cl15 1.757(9) .
C22B H22B 1.0000 .
