#------------------------------------------------------------------------------
#$Date: 2019-11-17 09:51:35 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229197 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/68/7046816.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7046816
loop_
_publ_author_name
'de Bruin-Dickason, Caspar N'
'Boutland, Aaron J.'
'Dange, Deepak'
'Deacon, Glen B.'
'Jones, Cameron'
_publ_section_title
;
 Redox transmetallation approaches to the synthesis of extremely bulky
 amido-lanthanoid(ii) and -calcium(ii) complexes.
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9512
_journal_page_last               9520
_journal_paper_doi               10.1039/c8dt02138d
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C64 H64 Eu N O2 Si'
_chemical_formula_weight         1059.21
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2018-05-25 deposited with the CCDC.
2018-06-22 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 93.42(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.421(2)
_cell_length_b                   21.831(4)
_cell_length_c                   22.608(5)
_cell_measurement_reflns_used    12242
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      27.94
_cell_measurement_theta_min      2.03
_cell_volume                     5134.2(18)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker Apex X8'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0791
_diffrn_reflns_av_sigmaI/netI    0.0361
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            89878
_diffrn_reflns_theta_full        27.94
_diffrn_reflns_theta_max         27.94
_diffrn_reflns_theta_min         2.03
_exptl_absorpt_coefficient_mu    1.291
_exptl_absorpt_correction_T_max  0.881
_exptl_absorpt_correction_T_min  0.819
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sortav (Blessing)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.370
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2192
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.545
_refine_diff_density_min         -1.150
_refine_diff_density_rms         0.098
_refine_ls_extinction_coef       0.009(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.017
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     648
_refine_ls_number_reflns         12242
_refine_ls_number_restraints     29
_refine_ls_restrained_S_all      6.125
_refine_ls_R_factor_all          0.0726
_refine_ls_R_factor_gt           0.0532
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0680P)²+10.0076P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1317
_refine_ls_wR_factor_ref         0.1441
_reflns_number_gt                9403
_reflns_number_total             12242
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c8dt02138d2.cif
_cod_data_source_block           compound2
_cod_depositor_comments
'Adding full bibliography for 7046810--7046818.cif.'
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7046816
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.21459(13) 0.70216(7) 0.22916(5) 0.0475(6) Uani 1 1 d . A .
Si1 Si 0.0594(7) 0.6924(3) 0.3534(3) 0.0390(15) Uani 1 1 d . A .
O1 O 0.381(2) 0.6535(10) 0.1646(10) 0.070(6) Uani 1 1 d D . .
N1 N 0.0676(18) 0.7453(10) 0.3001(8) 0.038(4) Uani 1 1 d . . .
C1 C -0.002(2) 0.7973(12) 0.2808(11) 0.041(5) Uani 1 1 d . A .
O2 O 0.4022(18) 0.7624(11) 0.2747(9) 0.060(5) Uani 1 1 d . . .
C2 C -0.025(3) 0.8069(12) 0.2183(12) 0.046(6) Uani 1 1 d . . .
C3 C -0.093(3) 0.8582(14) 0.1971(13) 0.058(7) Uani 1 1 d . A .
H3 H -0.1064 0.8634 0.1555 0.070 Uiso 1 1 calc R . .
C4 C -0.142(3) 0.9014(14) 0.2337(15) 0.066(9) Uani 1 1 d . . .
C5 C -0.116(3) 0.8937(14) 0.2937(14) 0.057(7) Uani 1 1 d . A .
H5 H -0.1472 0.9236 0.3198 0.068 Uiso 1 1 calc R . .
C6 C -0.046(2) 0.8441(12) 0.3182(11) 0.042(5) Uani 1 1 d . . .
C7 C 0.030(3) 0.7652(13) 0.1732(11) 0.049(6) Uani 1 1 d . A .
C8 C -0.027(3) 0.7064(14) 0.1624(12) 0.052(6) Uani 1 1 d . . .
C9 C 0.031(3) 0.6578(15) 0.1306(12) 0.058(7) Uani 1 1 d . A .
H9 H 0.1099 0.6650 0.1132 0.070 Uiso 1 1 calc R . .
C10 C -0.027(4) 0.6008(15) 0.1247(13) 0.063(8) Uani 1 1 d . . .
H10 H 0.0143 0.5702 0.1026 0.076 Uiso 1 1 calc R A .
C11 C -0.139(4) 0.5866(17) 0.1491(16) 0.073(10) Uani 1 1 d . A .
H11 H -0.1769 0.5472 0.1442 0.088 Uiso 1 1 calc R . .
C12 C -0.198(4) 0.6326(16) 0.1821(16) 0.069(9) Uani 1 1 d . . .
H12 H -0.2757 0.6241 0.2002 0.082 Uiso 1 1 calc R A .
C13 C -0.142(3) 0.6904(14) 0.1881(14) 0.057(7) Uani 1 1 d . A .
H13 H -0.1839 0.7204 0.2106 0.068 Uiso 1 1 calc R . .
C14 C 0.130(3) 0.7924(13) 0.1390(12) 0.051(6) Uani 1 1 d . . .
C15 C 0.156(3) 0.7757(15) 0.0799(12) 0.057(7) Uani 1 1 d . A .
H15 H 0.1059 0.7443 0.0607 0.068 Uiso 1 1 calc R . .
C16 C 0.251(3) 0.8039(15) 0.0495(14) 0.061(8) Uani 1 1 d . . .
H16 H 0.2639 0.7923 0.0098 0.073 Uiso 1 1 calc R A .
C17 C 0.327(3) 0.8486(15) 0.0763(14) 0.062(8) Uani 1 1 d . A .
H17 H 0.3938 0.8671 0.0556 0.075 Uiso 1 1 calc R . .
C18 C 0.307(3) 0.8663(15) 0.1331(14) 0.061(7) Uani 1 1 d . . .
H18 H 0.3588 0.8973 0.1516 0.073 Uiso 1 1 calc R A .
C19 C 0.210(3) 0.8391(14) 0.1638(13) 0.055(7) Uani 1 1 d . A .
H19 H 0.1978 0.8524 0.2030 0.066 Uiso 1 1 calc R . .
C20 C -0.009(2) 0.8450(12) 0.3842(11) 0.041(5) Uani 1 1 d . A .
H20 H 0.0029 0.8014 0.3970 0.050 Uiso 1 1 calc R . .
C21 C 0.120(2) 0.8770(12) 0.3976(10) 0.041(5) Uani 1 1 d . . .
C22 C 0.196(2) 0.8614(13) 0.4483(11) 0.044(5) Uani 1 1 d . A .
H22 H 0.1687 0.8297 0.4734 0.053 Uiso 1 1 calc R . .
C23 C 0.311(3) 0.8911(13) 0.4627(12) 0.048(6) Uani 1 1 d . . .
H23 H 0.3618 0.8797 0.4973 0.058 Uiso 1 1 calc R A .
C24 C 0.352(3) 0.9368(14) 0.4270(13) 0.053(6) Uani 1 1 d . A .
H24 H 0.4315 0.9569 0.4367 0.063 Uiso 1 1 calc R . .
C25 C 0.279(3) 0.9537(14) 0.3771(13) 0.052(6) Uani 1 1 d . . .
H25 H 0.3063 0.9862 0.3530 0.063 Uiso 1 1 calc R A .
C26 C 0.164(2) 0.9233(13) 0.3618(11) 0.047(6) Uani 1 1 d . A .
H26 H 0.1156 0.9343 0.3265 0.057 Uiso 1 1 calc R . .
C27 C -0.114(2) 0.8723(13) 0.4207(12) 0.046(6) Uani 1 1 d . . .
C28 C -0.220(3) 0.8367(15) 0.4323(13) 0.053(6) Uani 1 1 d . A .
H28 H -0.2250 0.7955 0.4188 0.064 Uiso 1 1 calc R . .
C29 C -0.319(3) 0.8611(17) 0.4636(14) 0.062(8) Uani 1 1 d . . .
H29 H -0.3919 0.8366 0.4705 0.074 Uiso 1 1 calc R A .
C30 C -0.313(3) 0.9196(16) 0.4845(14) 0.059(7) Uani 1 1 d . A .
H30 H -0.3801 0.9356 0.5064 0.071 Uiso 1 1 calc R . .
C31 C -0.207(3) 0.9557(16) 0.4733(14) 0.063(8) Uani 1 1 d . . .
H31 H -0.2025 0.9968 0.4870 0.076 Uiso 1 1 calc R A .
C32 C -0.109(3) 0.9314(14) 0.4421(14) 0.057(7) Uani 1 1 d . A .
H32 H -0.0358 0.9561 0.4353 0.068 Uiso 1 1 calc R . .
C33 C -0.106(3) 0.6655(12) 0.3710(11) 0.045(5) Uani 1 1 d . . .
C34 C -0.120(3) 0.6146(14) 0.4075(12) 0.052(6) Uani 1 1 d . A .
H34 H -0.0456 0.5933 0.4225 0.062 Uiso 1 1 calc R . .
C35 C -0.241(3) 0.5943(15) 0.4223(14) 0.063(8) Uani 1 1 d . . .
H35 H -0.2479 0.5596 0.4472 0.075 Uiso 1 1 calc R A .
C36 C -0.349(3) 0.6247(16) 0.4006(15) 0.062(8) Uani 1 1 d . A .
H36 H -0.4312 0.6115 0.4113 0.074 Uiso 1 1 calc R . .
C37 C -0.339(3) 0.6738(17) 0.3636(16) 0.064(8) Uani 1 1 d . . .
H37 H -0.4139 0.6944 0.3483 0.076 Uiso 1 1 calc R A .
C38 C -0.218(3) 0.6933(14) 0.3487(14) 0.054(7) Uani 1 1 d . A .
H38 H -0.2124 0.7270 0.3223 0.064 Uiso 1 1 calc R . .
C39 C 0.139(3) 0.6205(12) 0.3234(10) 0.044(5) Uani 1 1 d . . .
C40 C 0.068(3) 0.5855(14) 0.2813(13) 0.052(6) Uani 1 1 d . A .
H40 H -0.0147 0.5997 0.2673 0.063 Uiso 1 1 calc R . .
C41 C 0.113(3) 0.5311(14) 0.2593(14) 0.059(7) Uani 1 1 d . . .
H41 H 0.0612 0.5084 0.2310 0.071 Uiso 1 1 calc R A .
C42 C 0.231(4) 0.5100(15) 0.2781(13) 0.064(8) Uani 1 1 d . A .
H42 H 0.2619 0.4722 0.2634 0.077 Uiso 1 1 calc R . .
C43 C 0.307(4) 0.5434(19) 0.3184(15) 0.081(12) Uani 1 1 d . . .
H43 H 0.3903 0.5293 0.3307 0.097 Uiso 1 1 calc R A .
C44 C 0.260(3) 0.5983(17) 0.3411(14) 0.069(9) Uani 1 1 d . A .
H44 H 0.3126 0.6208 0.3693 0.083 Uiso 1 1 calc R . .
C45 C 0.153(3) 0.7069(12) 0.4270(11) 0.044(5) Uani 1 1 d . . .
C46 C 0.097(3) 0.7040(13) 0.4815(12) 0.050(6) Uani 1 1 d . A .
H46 H 0.0071 0.6961 0.4828 0.060 Uiso 1 1 calc R . .
C47 C 0.172(3) 0.7127(14) 0.5345(12) 0.058(7) Uani 1 1 d . . .
H47 H 0.1332 0.7112 0.5714 0.069 Uiso 1 1 calc R A .
C48 C 0.302(3) 0.7233(16) 0.5337(13) 0.062(8) Uani 1 1 d . A .
H48 H 0.3521 0.7291 0.5697 0.075 Uiso 1 1 calc R . .
C49 C 0.358(3) 0.7254(16) 0.4801(14) 0.059(7) Uani 1 1 d . . .
H49 H 0.4485 0.7319 0.4793 0.071 Uiso 1 1 calc R A .
C50 C 0.284(3) 0.7181(13) 0.4275(12) 0.051(6) Uani 1 1 d . A .
H50 H 0.3245 0.7207 0.3909 0.061 Uiso 1 1 calc R . .
C51 C 0.520(3) 0.767(2) 0.2429(19) 0.075(10) Uani 1 1 d . A .
H51A H 0.4990 0.7760 0.2005 0.090 Uiso 1 1 calc R . .
H51B H 0.5693 0.7286 0.2463 0.090 Uiso 1 1 calc R . .
C52 C 0.393(4) 0.8163(18) 0.3110(17) 0.076(10) Uani 1 1 d . A .
H52A H 0.4084 0.8056 0.3534 0.091 Uiso 1 1 calc R . .
H52B H 0.3059 0.8345 0.3053 0.091 Uiso 1 1 calc R . .
C53 C 0.491(3) 0.8599(18) 0.2925(18) 0.073(9) Uani 1 1 d . . .
H53A H 0.5248 0.8854 0.3262 0.088 Uiso 1 1 calc R A .
H53B H 0.4565 0.8870 0.2602 0.088 Uiso 1 1 calc R . .
C54 C 0.593(4) 0.818(2) 0.271(3) 0.100(16) Uani 1 1 d . A .
H54A H 0.6458 0.8393 0.2426 0.120 Uiso 1 1 calc R . .
H54B H 0.6500 0.8033 0.3050 0.120 Uiso 1 1 calc R . .
C55 C 0.440(7) 0.598(3) 0.180(3) 0.052(17) Uani 0.52(12) 1 d PD A 1
H55A H 0.3765 0.5680 0.1926 0.062 Uiso 0.52(12) 1 calc PR A 1
H55B H 0.5067 0.6040 0.2125 0.062 Uiso 0.52(12) 1 calc PR A 1
C55A C 0.394(14) 0.591(4) 0.154(6) 0.09(3) Uani 0.48(12) 1 d PD A 2
H55C H 0.3094 0.5717 0.1443 0.105 Uiso 0.48(12) 1 calc PR A 2
H55D H 0.4348 0.5701 0.1893 0.105 Uiso 0.48(12) 1 calc PR A 2
C56 C 0.500(10) 0.576(5) 0.125(4) 0.05(2) Uani 0.52(12) 1 d PD A 1
H56A H 0.4431 0.5473 0.1020 0.066 Uiso 0.52(12) 1 calc PR A 1
H56B H 0.5842 0.5562 0.1342 0.066 Uiso 0.52(12) 1 calc PR A 1
C56A C 0.478(13) 0.585(7) 0.103(6) 0.08(4) Uani 0.48(12) 1 d PD A 2
H56C H 0.4371 0.5559 0.0734 0.097 Uiso 0.48(12) 1 calc PR A 2
H56D H 0.5618 0.5672 0.1168 0.097 Uiso 0.48(12) 1 calc PR A 2
C57 C 0.517(7) 0.636(3) 0.090(3) 0.056(19) Uani 0.52(12) 1 d PD A 1
H57A H 0.6089 0.6434 0.0845 0.067 Uiso 0.52(12) 1 calc PR A 1
H57B H 0.4705 0.6334 0.0508 0.067 Uiso 0.52(12) 1 calc PR A 1
C57A C 0.500(18) 0.645(8) 0.073(10) 0.19(10) Uani 0.48(12) 1 d PDU A 2
H57C H 0.5853 0.6633 0.0834 0.234 Uiso 0.48(12) 1 calc PR A 2
H57D H 0.4836 0.6438 0.0290 0.234 Uiso 0.48(12) 1 calc PR A 2
C58 C 0.463(10) 0.688(4) 0.125(4) 0.08(3) Uani 0.52(12) 1 d PD A 1
H58A H 0.5316 0.7111 0.1479 0.098 Uiso 0.52(12) 1 calc PR A 1
H58B H 0.4120 0.7170 0.0993 0.098 Uiso 0.52(12) 1 calc PR A 1
C58A C 0.398(7) 0.672(3) 0.103(3) 0.053(19) Uani 0.48(12) 1 d PD A 2
H58C H 0.3167 0.6627 0.0797 0.064 Uiso 0.48(12) 1 calc PR A 2
H58D H 0.4097 0.7167 0.1025 0.064 Uiso 0.48(12) 1 calc PR A 2
C59 C -0.223(5) 0.9551(18) 0.209(2) 0.099(14) Uani 1 1 d DU A .
H59 H -0.2793 0.9625 0.2431 0.118 Uiso 1 1 calc R B 1
C60 C -0.320(3) 0.9409(17) 0.1616(16) 0.072(9) Uani 1 1 d . . .
H60A H -0.3651 0.9785 0.1493 0.108 Uiso 1 1 calc R A .
H60B H -0.3811 0.9111 0.1757 0.108 Uiso 1 1 calc R . .
H60C H -0.2770 0.9237 0.1279 0.108 Uiso 1 1 calc R . .
C61 C -0.154(8) 1.010(3) 0.209(4) 0.07(2) Uiso 0.58(15) 1 d PD A 1
H61A H -0.2137 1.0441 0.1985 0.107 Uiso 0.58(15) 1 calc PR A 1
H61B H -0.0889 1.0079 0.1797 0.107 Uiso 0.58(15) 1 calc PR A 1
H61C H -0.1129 1.0179 0.2483 0.107 Uiso 0.58(15) 1 calc PR A 1
C61A C -0.204(11) 1.014(3) 0.234(5) 0.07(3) Uiso 0.42(15) 1 d PD A 2
H61D H -0.1117 1.0223 0.2409 0.102 Uiso 0.42(15) 1 calc PR A 2
H61E H -0.2454 1.0170 0.2719 0.102 Uiso 0.42(15) 1 calc PR A 2
H61F H -0.2418 1.0451 0.2066 0.102 Uiso 0.42(15) 1 calc PR A 2
C62 C -0.563(7) 0.554(4) 0.520(3) 0.15(2) Uiso 1 1 d D . .
H62 H -0.5970 0.5904 0.5353 0.183 Uiso 1 1 calc R . .
C63 C -0.439(5) 0.533(2) 0.537(2) 0.094(13) Uiso 1 1 d D . .
H63 H -0.3959 0.5585 0.5653 0.113 Uiso 1 1 calc R . .
C64 C -0.364(7) 0.485(3) 0.522(3) 0.14(2) Uiso 1 1 d D . .
H64 H -0.2787 0.4776 0.5373 0.167 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Eu1 O2 91.8(7) . .
N1 Eu1 O1 174.2(7) . .
O2 Eu1 O1 85.1(8) . .
N1 Eu1 C7 69.4(7) . .
O2 Eu1 C7 116.8(8) . .
O1 Eu1 C7 116.4(8) . .
N1 Eu1 C8 76.6(7) . .
O2 Eu1 C8 146.6(8) . .
O1 Eu1 C8 108.5(8) . .
C7 Eu1 C8 29.8(9) . .
N1 Eu1 C39 63.5(7) . .
O2 Eu1 C39 104.8(7) . .
O1 Eu1 C39 112.5(7) . .
C7 Eu1 C39 116.7(8) . .
C8 Eu1 C39 97.9(8) . .
N1 Eu1 C14 91.3(8) . .
O2 Eu1 C14 97.3(8) . .
O1 Eu1 C14 93.9(8) . .
C7 Eu1 C14 29.9(9) . .
C8 Eu1 C14 52.6(9) . .
C39 Eu1 C14 146.5(8) . .
N1 Eu1 C9 102.1(8) . .
O2 Eu1 C9 155.9(8) . .
O1 Eu1 C9 82.4(9) . .
C7 Eu1 C9 52.9(8) . .
C8 Eu1 C9 28.1(8) . .
C39 Eu1 C9 99.0(8) . .
C14 Eu1 C9 63.2(8) . .
N1 Eu1 C40 74.8(7) . .
O2 Eu1 C40 129.4(7) . .
O1 Eu1 C40 103.4(7) . .
C7 Eu1 C40 103.8(9) . .
C8 Eu1 C40 78.3(8) . .
C39 Eu1 C40 25.7(7) . .
C14 Eu1 C40 130.9(8) . .
C9 Eu1 C40 73.9(8) . .
N1 Eu1 Si1 29.0(5) . .
O2 Eu1 Si1 95.3(5) . .
O1 Eu1 Si1 146.4(5) . .
C7 Eu1 Si1 93.5(6) . .
C8 Eu1 Si1 89.4(6) . .
C39 Eu1 Si1 35.0(5) . .
C14 Eu1 Si1 119.3(6) . .
C9 Eu1 Si1 106.5(7) . .
C40 Eu1 Si1 51.5(5) . .
N1 Si1 C33 116.9(11) . .
N1 Si1 C45 118.0(11) . .
C33 Si1 C45 107.1(12) . .
N1 Si1 C39 105.5(10) . .
C33 Si1 C39 103.9(12) . .
C45 Si1 C39 103.6(11) . .
N1 Si1 Eu1 45.6(7) . .
C33 Si1 Eu1 133.9(8) . .
C45 Si1 Eu1 118.5(9) . .
C39 Si1 Eu1 60.7(8) . .
C55 O1 C55A 31(5) . .
C55 O1 C58A 113(4) . .
C55A O1 C58A 95(6) . .
C55 O1 C58 109(5) . .
C55A O1 C58 109(5) . .
C58A O1 C58 35(4) . .
C55 O1 Eu1 122(3) . .
C55A O1 Eu1 126(4) . .
C58A O1 Eu1 124(3) . .
C58 O1 Eu1 124(3) . .
C1 N1 Si1 137.3(17) . .
C1 N1 Eu1 115.8(15) . .
Si1 N1 Eu1 105.4(10) . .
N1 C1 C6 125(2) . .
N1 C1 C2 119(2) . .
C6 C1 C2 116(2) . .
C52 O2 C51 108(3) . .
C52 O2 Eu1 125(2) . .
C51 O2 Eu1 119(2) . .
C3 C2 C1 120(3) . .
C3 C2 C7 117(2) . .
C1 C2 C7 122(2) . .
C4 C3 C2 123(3) . .
C4 C3 H3 118.5 . .
C2 C3 H3 118.5 . .
C3 C4 C5 117(3) . .
C3 C4 C59 122(3) . .
C5 C4 C59 121(3) . .
C4 C5 C6 123(3) . .
C4 C5 H5 118.3 . .
C6 C5 H5 118.3 . .
C5 C6 C1 120(2) . .
C5 C6 C20 118(2) . .
C1 C6 C20 121(2) . .
C8 C7 C14 125(3) . .
C8 C7 C2 119(3) . .
C14 C7 C2 115(2) . .
C8 C7 Eu1 84.1(17) . .
C14 C7 Eu1 86.6(16) . .
C2 C7 Eu1 106.6(16) . .
C13 C8 C7 121(3) . .
C13 C8 C9 115(3) . .
C7 C8 C9 125(3) . .
C13 C8 Eu1 121.3(19) . .
C7 C8 Eu1 66.1(15) . .
C9 C8 Eu1 81.8(17) . .
C10 C9 C8 121(3) . .
C10 C9 Eu1 128(2) . .
C8 C9 Eu1 70.1(16) . .
C10 C9 H9 119.3 . .
C8 C9 H9 119.3 . .
Eu1 C9 H9 73.9 . .
C11 C10 C9 123(3) . .
C11 C10 H10 118.6 . .
C9 C10 H10 118.6 . .
C10 C11 C12 118(3) . .
C10 C11 H11 121.2 . .
C12 C11 H11 121.2 . .
C13 C12 C11 120(4) . .
C13 C12 H12 119.8 . .
C11 C12 H12 119.8 . .
C12 C13 C8 123(3) . .
C12 C13 H13 118.5 . .
C8 C13 H13 118.5 . .
C19 C14 C15 115(3) . .
C19 C14 C7 121(3) . .
C15 C14 C7 125(3) . .
C19 C14 Eu1 93.6(17) . .
C15 C14 Eu1 114.5(19) . .
C7 C14 Eu1 63.5(14) . .
C16 C15 C14 122(3) . .
C16 C15 H15 118.9 . .
C14 C15 H15 118.9 . .
C17 C16 C15 121(3) . .
C17 C16 H16 119.7 . .
C15 C16 H16 119.7 . .
C18 C17 C16 120(3) . .
C18 C17 H17 120.2 . .
C16 C17 H17 120.2 . .
C17 C18 C19 120(3) . .
C17 C18 H18 119.8 . .
C19 C18 H18 119.8 . .
C18 C19 C14 123(3) . .
C18 C19 H19 118.7 . .
C14 C19 H19 118.7 . .
C6 C20 C21 112(2) . .
C6 C20 C27 112(2) . .
C21 C20 C27 111(2) . .
C6 C20 H20 106.9 . .
C21 C20 H20 106.9 . .
C27 C20 H20 106.9 . .
C26 C21 C22 117(2) . .
C26 C21 C20 122(2) . .
C22 C21 C20 120(2) . .
C23 C22 C21 121(3) . .
C23 C22 H22 119.3 . .
C21 C22 H22 119.3 . .
C24 C23 C22 120(2) . .
C24 C23 H23 120.0 . .
C22 C23 H23 120.0 . .
C23 C24 C25 120(3) . .
C23 C24 H24 119.9 . .
C25 C24 H24 119.9 . .
C24 C25 C26 120(3) . .
C24 C25 H25 119.9 . .
C26 C25 H25 119.9 . .
C21 C26 C25 121(2) . .
C21 C26 H26 119.6 . .
C25 C26 H26 119.6 . .
C32 C27 C28 118(3) . .
C32 C27 C20 123(2) . .
C28 C27 C20 119(2) . .
C27 C28 C29 120(3) . .
C27 C28 H28 119.8 . .
C29 C28 H28 119.8 . .
C30 C29 C28 121(3) . .
C30 C29 H29 119.5 . .
C28 C29 H29 119.5 . .
C29 C30 C31 119(3) . .
C29 C30 H30 120.3 . .
C31 C30 H30 120.3 . .
C32 C31 C30 120(3) . .
C32 C31 H31 120.1 . .
C30 C31 H31 120.1 . .
C27 C32 C31 122(3) . .
C27 C32 H32 119.2 . .
C31 C32 H32 119.2 . .
C38 C33 C34 116(3) . .
C38 C33 Si1 123(2) . .
C34 C33 Si1 120(2) . .
C35 C34 C33 122(3) . .
C35 C34 H34 119.1 . .
C33 C34 H34 119.1 . .
C36 C35 C34 120(3) . .
C36 C35 H35 120.2 . .
C34 C35 H35 120.2 . .
C37 C36 C35 120(3) . .
C37 C36 H36 119.8 . .
C35 C36 H36 119.8 . .
C36 C37 C38 120(3) . .
C36 C37 H37 120.2 . .
C38 C37 H37 120.2 . .
C37 C38 C33 122(3) . .
C37 C38 H38 118.8 . .
C33 C38 H38 118.8 . .
C44 C39 C40 116(3) . .
C44 C39 Si1 126(2) . .
C40 C39 Si1 118(2) . .
C44 C39 Eu1 98(2) . .
C40 C39 Eu1 89.6(16) . .
Si1 C39 Eu1 84.3(9) . .
C41 C40 C39 123(3) . .
C41 C40 Eu1 112(2) . .
C39 C40 Eu1 64.8(15) . .
C41 C40 H40 118.7 . .
C39 C40 H40 118.7 . .
Eu1 C40 H40 93.5 . .
C42 C41 C40 120(3) . .
C42 C41 H41 120.0 . .
C40 C41 H41 120.0 . .
C41 C42 C43 120(3) . .
C41 C42 H42 120.0 . .
C43 C42 H42 120.0 . .
C42 C43 C44 120(3) . .
C42 C43 H43 120.0 . .
C44 C43 H43 120.0 . .
C39 C44 C43 121(3) . .
C39 C44 H44 119.3 . .
C43 C44 H44 119.3 . .
C50 C45 C46 118(2) . .
C50 C45 Si1 119(2) . .
C46 C45 Si1 123(2) . .
C45 C46 C47 120(3) . .
C45 C46 H46 120.0 . .
C47 C46 H46 120.0 . .
C48 C47 C46 121(3) . .
C48 C47 H47 119.5 . .
C46 C47 H47 119.5 . .
C47 C48 C49 119(3) . .
C47 C48 H48 120.3 . .
C49 C48 H48 120.3 . .
C48 C49 C50 120(3) . .
C48 C49 H49 119.9 . .
C50 C49 H49 119.9 . .
C49 C50 C45 121(3) . .
C49 C50 H50 119.3 . .
C45 C50 H50 119.3 . .
O2 C51 C54 106(3) . .
O2 C51 H51A 110.6 . .
C54 C51 H51A 110.6 . .
O2 C51 H51B 110.6 . .
C54 C51 H51B 110.6 . .
H51A C51 H51B 108.8 . .
O2 C52 C53 107(3) . .
O2 C52 H52A 110.3 . .
C53 C52 H52A 110.3 . .
O2 C52 H52B 110.3 . .
C53 C52 H52B 110.3 . .
H52A C52 H52B 108.6 . .
C52 C53 C54 102(3) . .
C52 C53 H53A 111.3 . .
C54 C53 H53A 111.3 . .
C52 C53 H53B 111.3 . .
C54 C53 H53B 111.3 . .
H53A C53 H53B 109.2 . .
C51 C54 C53 104(3) . .
C51 C54 H54A 111.0 . .
C53 C54 H54A 111.0 . .
C51 C54 H54B 111.0 . .
C53 C54 H54B 111.0 . .
H54A C54 H54B 109.0 . .
O1 C55 C56 106(5) . .
O1 C55 H55A 110.6 . .
C56 C55 H55A 110.6 . .
O1 C55 H55B 110.6 . .
C56 C55 H55B 110.6 . .
H55A C55 H55B 108.7 . .
O1 C55A C56A 107(8) . .
O1 C55A H55C 110.4 . .
C56A C55A H55C 110.4 . .
O1 C55A H55D 110.4 . .
C56A C55A H55D 110.4 . .
H55C C55A H55D 108.6 . .
C55 C56 C57 102(7) . .
C55 C56 H56A 111.3 . .
C57 C56 H56A 111.3 . .
C55 C56 H56B 111.3 . .
C57 C56 H56B 111.3 . .
H56A C56 H56B 109.2 . .
C55A C56A C57A 113(10) . .
C55A C56A H56C 109.1 . .
C57A C56A H56C 109.1 . .
C55A C56A H56D 109.1 . .
C57A C56A H56D 109.1 . .
H56C C56A H56D 107.8 . .
C58 C57 C56 109(5) . .
C58 C57 H57A 109.9 . .
C56 C57 H57A 109.9 . .
C58 C57 H57B 109.9 . .
C56 C57 H57B 109.9 . .
H57A C57 H57B 108.3 . .
C58A C57A C56A 90(10) . .
C58A C57A H57C 113.6 . .
C56A C57A H57C 113.6 . .
C58A C57A H57D 113.6 . .
C56A C57A H57D 113.6 . .
H57C C57A H57D 110.9 . .
O1 C58 C57 100(5) . .
O1 C58 H58A 111.8 . .
C57 C58 H58A 111.8 . .
O1 C58 H58B 111.8 . .
C57 C58 H58B 111.8 . .
H58A C58 H58B 109.5 . .
C57A C58A O1 119(9) . .
C57A C58A H58C 107.6 . .
O1 C58A H58C 107.6 . .
C57A C58A H58D 107.6 . .
O1 C58A H58D 107.6 . .
H58C C58A H58D 107.0 . .
C61 C59 C61A 33(4) . .
C61 C59 C60 120(4) . .
C61A C59 C60 124(5) . .
C61 C59 C4 113(4) . .
C61A C59 C4 120(5) . .
C60 C59 C4 116(3) . .
C61 C59 H59 100.8 . .
C61A C59 H59 68.2 . .
C60 C59 H59 100.8 . .
C4 C59 H59 100.8 . .
C59 C60 H60A 109.5 . .
C59 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
C59 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
C59 C61 H61A 109.5 . .
C59 C61 H61B 109.5 . .
C59 C61 H61C 109.5 . .
C59 C61A H61D 109.5 . .
C59 C61A H61E 109.5 . .
H61D C61A H61E 109.5 . .
C59 C61A H61F 109.5 . .
H61D C61A H61F 109.5 . .
H61E C61A H61F 109.5 . .
C63 C62 C64 115(6) . 3_466
C63 C62 H62 122.5 . .
C64 C62 H62 122.5 3_466 .
C64 C63 C62 136(6) . .
C64 C63 H63 111.9 . .
C62 C63 H63 111.9 . .
C63 C64 C62 109(6) . 3_466
C63 C64 H64 125.6 . .
C62 C64 H64 125.6 3_466 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 N1 2.469(19) .
Eu1 O2 2.53(2) .
Eu1 O1 2.56(2) .
Eu1 C7 2.63(3) .
Eu1 C8 2.86(3) .
Eu1 C39 2.92(2) .
Eu1 C14 2.93(3) .
Eu1 C9 3.01(3) .
Eu1 C40 3.23(3) .
Eu1 Si1 3.331(7) .
Si1 N1 1.68(2) .
Si1 C33 1.88(3) .
Si1 C45 1.90(3) .
Si1 C39 1.92(3) .
O1 C55 1.39(6) .
O1 C55A 1.40(8) .
O1 C58A 1.47(6) .
O1 C58 1.48(7) .
N1 C1 1.40(3) .
C1 C6 1.42(4) .
C1 C2 1.43(3) .
O2 C52 1.44(4) .
O2 C51 1.46(4) .
C2 C3 1.40(4) .
C2 C7 1.50(4) .
C3 C4 1.37(5) .
C3 H3 0.9500 .
C4 C5 1.38(4) .
C4 C59 1.53(4) .
C5 C6 1.40(4) .
C5 H5 0.9500 .
C6 C20 1.52(3) .
C7 C8 1.43(4) .
C7 C14 1.46(4) .
C8 C13 1.41(5) .
C8 C9 1.43(4) .
C9 C10 1.38(5) .
C9 H9 0.9500 .
C10 C11 1.36(5) .
C10 H10 0.9500 .
C11 C12 1.41(5) .
C11 H11 0.9500 .
C12 C13 1.39(5) .
C12 H12 0.9500 .
C13 H13 0.9500 .
C14 C19 1.41(4) .
C14 C15 1.43(4) .
C15 C16 1.38(5) .
C15 H15 0.9500 .
C16 C17 1.38(5) .
C16 H16 0.9500 .
C17 C18 1.37(4) .
C17 H17 0.9500 .
C18 C19 1.39(4) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C21 1.52(3) .
C20 C27 1.53(3) .
C20 H20 1.0000 .
C21 C26 1.39(4) .
C21 C22 1.40(3) .
C22 C23 1.38(4) .
C22 H22 0.9500 .
C23 C24 1.37(4) .
C23 H23 0.9500 .
C24 C25 1.38(4) .
C24 H24 0.9500 .
C25 C26 1.39(4) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C27 C32 1.38(4) .
C27 C28 1.39(4) .
C28 C29 1.39(4) .
C28 H28 0.9500 .
C29 C30 1.36(5) .
C29 H29 0.9500 .
C30 C31 1.39(5) .
C30 H30 0.9500 .
C31 C32 1.39(4) .
C31 H31 0.9500 .
C32 H32 0.9500 .
C33 C38 1.39(4) .
C33 C34 1.40(4) .
C34 C35 1.39(4) .
C34 H34 0.9500 .
C35 C36 1.38(5) .
C35 H35 0.9500 .
C36 C37 1.37(5) .
C36 H36 0.9500 .
C37 C38 1.39(4) .
C37 H37 0.9500 .
C38 H38 0.9500 .
C39 C44 1.39(4) .
C39 C40 1.40(4) .
C40 C41 1.38(4) .
C40 H40 0.9500 .
C41 C42 1.36(5) .
C41 H41 0.9500 .
C42 C43 1.38(5) .
C42 H42 0.9500 .
C43 C44 1.40(5) .
C43 H43 0.9500 .
C44 H44 0.9500 .
C45 C50 1.39(4) .
C45 C46 1.40(4) .
C46 C47 1.41(4) .
C46 H46 0.9500 .
C47 C48 1.37(5) .
C47 H47 0.9500 .
C48 C49 1.38(5) .
C48 H48 0.9500 .
C49 C50 1.39(4) .
C49 H49 0.9500 .
C50 H50 0.9500 .
C51 C54 1.48(6) .
C51 H51A 0.9900 .
C51 H51B 0.9900 .
C52 C53 1.48(5) .
C52 H52A 0.9900 .
C52 H52B 0.9900 .
C53 C54 1.50(6) .
C53 H53A 0.9900 .
C53 H53B 0.9900 .
C54 H54A 0.9900 .
C54 H54B 0.9900 .
C55 C56 1.51(8) .
C55 H55A 0.9900 .
C55 H55B 0.9900 .
C55A C56A 1.50(10) .
C55A H55C 0.9900 .
C55A H55D 0.9900 .
C56 C57 1.54(8) .
C56 H56A 0.9900 .
C56 H56B 0.9900 .
C56A C57A 1.51(11) .
C56A H56C 0.9900 .
C56A H56D 0.9900 .
C57 C58 1.51(8) .
C57 H57A 0.9900 .
C57 H57B 0.9900 .
C57A C58A 1.43(11) .
C57A H57C 0.9900 .
C57A H57D 0.9900 .
C58 H58A 0.9900 .
C58 H58B 0.9900 .
C58A H58C 0.9900 .
C58A H58D 0.9900 .
C59 C61 1.41(7) .
C59 C61A 1.42(8) .
C59 C60 1.46(5) .
C59 H59 1.0000 .
C60 H60A 0.9800 .
C60 H60B 0.9800 .
C60 H60C 0.9800 .
C61 H61A 0.9800 .
C61 H61B 0.9800 .
C61 H61C 0.9800 .
C61A H61D 0.9800 .
C61A H61E 0.9800 .
C61A H61F 0.9800 .
C62 C63 1.41(7) .
C62 C64 1.45(9) 3_466
C62 H62 0.9500 .
C63 C64 1.35(7) .
C63 H63 0.9500 .
C64 C62 1.45(9) 3_466
C64 H64 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 Eu1 Si1 N1 84.2(11) . .
O1 Eu1 Si1 N1 173.4(14) . .
C7 Eu1 Si1 N1 -33.1(11) . .
C8 Eu1 Si1 N1 -62.7(11) . .
C39 Eu1 Si1 N1 -167.4(13) . .
C14 Eu1 Si1 N1 -17.2(12) . .
C9 Eu1 Si1 N1 -85.4(12) . .
C40 Eu1 Si1 N1 -138.1(12) . .
N1 Eu1 Si1 C33 86.4(16) . .
O2 Eu1 Si1 C33 170.6(14) . .
O1 Eu1 Si1 C33 -100.2(17) . .
C7 Eu1 Si1 C33 53.3(14) . .
C8 Eu1 Si1 C33 23.8(14) . .
C39 Eu1 Si1 C33 -80.9(15) . .
C14 Eu1 Si1 C33 69.2(14) . .
C9 Eu1 Si1 C33 1.1(14) . .
C40 Eu1 Si1 C33 -51.6(14) . .
N1 Eu1 Si1 C45 -102.5(13) . .
O2 Eu1 Si1 C45 -18.3(11) . .
O1 Eu1 Si1 C45 70.9(15) . .
C7 Eu1 Si1 C45 -135.6(11) . .
C8 Eu1 Si1 C45 -165.1(11) . .
C39 Eu1 Si1 C45 90.2(13) . .
C14 Eu1 Si1 C45 -119.7(11) . .
C9 Eu1 Si1 C45 172.2(11) . .
C40 Eu1 Si1 C45 119.5(12) . .
N1 Eu1 Si1 C39 167.4(13) . .
O2 Eu1 Si1 C39 -108.4(10) . .
O1 Eu1 Si1 C39 -19.3(14) . .
C7 Eu1 Si1 C39 134.2(11) . .
C8 Eu1 Si1 C39 104.7(11) . .
C14 Eu1 Si1 C39 150.2(11) . .
C9 Eu1 Si1 C39 82.0(11) . .
C40 Eu1 Si1 C39 29.3(11) . .
N1 Eu1 O1 C55 37(10) . .
O2 Eu1 O1 C55 95(4) . .
C7 Eu1 O1 C55 -147(4) . .
C8 Eu1 O1 C55 -116(4) . .
C39 Eu1 O1 C55 -9(5) . .
C14 Eu1 O1 C55 -168(4) . .
C9 Eu1 O1 C55 -106(4) . .
C40 Eu1 O1 C55 -34(5) . .
Si1 Eu1 O1 C55 3(5) . .
N1 Eu1 O1 C55A 74(12) . .
O2 Eu1 O1 C55A 132(9) . .
C7 Eu1 O1 C55A -110(9) . .
C8 Eu1 O1 C55A -79(9) . .
C39 Eu1 O1 C55A 28(9) . .
C14 Eu1 O1 C55A -131(9) . .
C9 Eu1 O1 C55A -68(9) . .
C40 Eu1 O1 C55A 3(9) . .
Si1 Eu1 O1 C55A 40(9) . .
N1 Eu1 O1 C58A -159(7) . .
O2 Eu1 O1 C58A -101(4) . .
C7 Eu1 O1 C58A 17(4) . .
C8 Eu1 O1 C58A 48(4) . .
C39 Eu1 O1 C58A 155(4) . .
C14 Eu1 O1 C58A -4(4) . .
C9 Eu1 O1 C58A 58(4) . .
C40 Eu1 O1 C58A 130(4) . .
Si1 Eu1 O1 C58A 167(4) . .
N1 Eu1 O1 C58 -116(9) . .
O2 Eu1 O1 C58 -58(6) . .
C7 Eu1 O1 C58 59(6) . .
C8 Eu1 O1 C58 91(6) . .
C39 Eu1 O1 C58 -162(6) . .
C14 Eu1 O1 C58 39(6) . .
C9 Eu1 O1 C58 101(6) . .
C40 Eu1 O1 C58 173(6) . .
Si1 Eu1 O1 C58 -150(6) . .
C33 Si1 N1 C1 38(3) . .
C45 Si1 N1 C1 -92(3) . .
C39 Si1 N1 C1 153(2) . .
Eu1 Si1 N1 C1 164(3) . .
C33 Si1 N1 Eu1 -126.2(10) . .
C45 Si1 N1 Eu1 103.6(12) . .
C39 Si1 N1 Eu1 -11.4(12) . .
O2 Eu1 N1 C1 94.1(17) . .
O1 Eu1 N1 C1 152(7) . .
C7 Eu1 N1 C1 -23.9(16) . .
C8 Eu1 N1 C1 -54.2(17) . .
C39 Eu1 N1 C1 -160.2(18) . .
C14 Eu1 N1 C1 -3.2(17) . .
C9 Eu1 N1 C1 -66.1(17) . .
C40 Eu1 N1 C1 -135.4(17) . .
Si1 Eu1 N1 C1 -168(2) . .
O2 Eu1 N1 Si1 -97.6(10) . .
O1 Eu1 N1 Si1 -40(8) . .
C7 Eu1 N1 Si1 144.3(12) . .
C8 Eu1 N1 Si1 114.1(11) . .
C39 Eu1 N1 Si1 8.0(9) . .
C14 Eu1 N1 Si1 165.0(10) . .
C9 Eu1 N1 Si1 102.1(10) . .
C40 Eu1 N1 Si1 32.8(9) . .
Si1 N1 C1 C6 45(4) . .
Eu1 N1 C1 C6 -151(2) . .
Si1 N1 C1 C2 -139(2) . .
Eu1 N1 C1 C2 25(3) . .
N1 Eu1 O2 C52 -20(3) . .
O1 Eu1 O2 C52 165(3) . .
C7 Eu1 O2 C52 48(3) . .
C8 Eu1 O2 C52 48(3) . .
C39 Eu1 O2 C52 -83(3) . .
C14 Eu1 O2 C52 72(3) . .
C9 Eu1 O2 C52 106(3) . .
C40 Eu1 O2 C52 -92(3) . .
Si1 Eu1 O2 C52 -49(3) . .
N1 Eu1 O2 C51 -166(2) . .
O1 Eu1 O2 C51 18(2) . .
C7 Eu1 O2 C51 -99(2) . .
C8 Eu1 O2 C51 -98(3) . .
C39 Eu1 O2 C51 131(2) . .
C14 Eu1 O2 C51 -75(2) . .
C9 Eu1 O2 C51 -40(3) . .
C40 Eu1 O2 C51 122(2) . .
Si1 Eu1 O2 C51 165(2) . .
N1 C1 C2 C3 -180(3) . .
C6 C1 C2 C3 -3(4) . .
N1 C1 C2 C7 -4(4) . .
C6 C1 C2 C7 173(2) . .
C1 C2 C3 C4 0(5) . .
C7 C2 C3 C4 -177(3) . .
C2 C3 C4 C5 3(5) . .
C2 C3 C4 C59 -176(3) . .
C3 C4 C5 C6 -2(5) . .
C59 C4 C5 C6 178(3) . .
C4 C5 C6 C1 -2(5) . .
C4 C5 C6 C20 172(3) . .
N1 C1 C6 C5 -179(3) . .
C2 C1 C6 C5 4(4) . .
N1 C1 C6 C20 7(4) . .
C2 C1 C6 C20 -169(2) . .
C3 C2 C7 C8 -108(3) . .
C1 C2 C7 C8 76(3) . .
C3 C2 C7 C14 65(3) . .
C1 C2 C7 C14 -111(3) . .
C3 C2 C7 Eu1 159(2) . .
C1 C2 C7 Eu1 -17(3) . .
N1 Eu1 C7 C8 -99.2(17) . .
O2 Eu1 C7 C8 179.5(15) . .
O1 Eu1 C7 C8 81.2(18) . .
C39 Eu1 C7 C8 -55.4(18) . .
C14 Eu1 C7 C8 126(2) . .
C9 Eu1 C7 C8 25.3(16) . .
C40 Eu1 C7 C8 -31.6(18) . .
Si1 Eu1 C7 C8 -82.7(16) . .
N1 Eu1 C7 C14 134.8(17) . .
O2 Eu1 C7 C14 53.6(17) . .
O1 Eu1 C7 C14 -44.7(18) . .
C8 Eu1 C7 C14 -126(2) . .
C39 Eu1 C7 C14 178.6(15) . .
C9 Eu1 C7 C14 -100.6(18) . .
C40 Eu1 C7 C14 -157.6(15) . .
Si1 Eu1 C7 C14 151.3(15) . .
N1 Eu1 C7 C2 19.6(17) . .
O2 Eu1 C7 C2 -62(2) . .
O1 Eu1 C7 C2 -159.9(17) . .
C8 Eu1 C7 C2 119(3) . .
C39 Eu1 C7 C2 63(2) . .
C14 Eu1 C7 C2 -115(3) . .
C9 Eu1 C7 C2 144(2) . .
C40 Eu1 C7 C2 87.2(19) . .
Si1 Eu1 C7 C2 36.1(18) . .
C14 C7 C8 C13 -165(3) . .
C2 C7 C8 C13 8(4) . .
Eu1 C7 C8 C13 113(2) . .
C14 C7 C8 C9 21(4) . .
C2 C7 C8 C9 -166(2) . .
Eu1 C7 C8 C9 -60(3) . .
C14 C7 C8 Eu1 82(3) . .
C2 C7 C8 Eu1 -106(2) . .
N1 Eu1 C8 C13 -41(2) . .
O2 Eu1 C8 C13 -113(2) . .
O1 Eu1 C8 C13 137(2) . .
C7 Eu1 C8 C13 -112(3) . .
C39 Eu1 C8 C13 20(2) . .
C14 Eu1 C8 C13 -143(3) . .
C9 Eu1 C8 C13 114(3) . .
C40 Eu1 C8 C13 36(2) . .
Si1 Eu1 C8 C13 -14(2) . .
N1 Eu1 C8 C7 71.7(17) . .
O2 Eu1 C8 C7 -1(2) . .
O1 Eu1 C8 C7 -110.9(17) . .
C39 Eu1 C8 C7 132.0(17) . .
C14 Eu1 C8 C7 -30.5(16) . .
C9 Eu1 C8 C7 -134(3) . .
C40 Eu1 C8 C7 148.7(18) . .
Si1 Eu1 C8 C7 98.0(16) . .
N1 Eu1 C8 C9 -154.6(19) . .
O2 Eu1 C8 C9 132.9(18) . .
O1 Eu1 C8 C9 23(2) . .
C7 Eu1 C8 C9 134(3) . .
C39 Eu1 C8 C9 -94.3(18) . .
C14 Eu1 C8 C9 103(2) . .
C40 Eu1 C8 C9 -77.7(18) . .
Si1 Eu1 C8 C9 -128.3(18) . .
C13 C8 C9 C10 2(4) . .
C7 C8 C9 C10 176(3) . .
Eu1 C8 C9 C10 123(3) . .
C13 C8 C9 Eu1 -121(2) . .
C7 C8 C9 Eu1 53(2) . .
N1 Eu1 C9 C10 -90(3) . .
O2 Eu1 C9 C10 146(3) . .
O1 Eu1 C9 C10 87(3) . .
C7 Eu1 C9 C10 -142(3) . .
C8 Eu1 C9 C10 -115(4) . .
C39 Eu1 C9 C10 -25(3) . .
C14 Eu1 C9 C10 -175(3) . .
C40 Eu1 C9 C10 -20(3) . .
Si1 Eu1 C9 C10 -60(3) . .
N1 Eu1 C9 C8 25.3(19) . .
O2 Eu1 C9 C8 -99(3) . .
O1 Eu1 C9 C8 -158.3(19) . .
C7 Eu1 C9 C8 -26.8(17) . .
C39 Eu1 C9 C8 89.9(18) . .
C14 Eu1 C9 C8 -60.1(18) . .
C40 Eu1 C9 C8 95.3(19) . .
Si1 Eu1 C9 C8 54.9(18) . .
C8 C9 C10 C11 -1(5) . .
Eu1 C9 C10 C11 87(4) . .
C9 C10 C11 C12 0(5) . .
C10 C11 C12 C13 1(5) . .
C11 C12 C13 C8 0(5) . .
C7 C8 C13 C12 -176(3) . .
C9 C8 C13 C12 -2(4) . .
Eu1 C8 C13 C12 -97(3) . .
C8 C7 C14 C19 -158(3) . .
C2 C7 C14 C19 29(4) . .
Eu1 C7 C14 C19 -78(3) . .
C8 C7 C14 C15 22(4) . .
C2 C7 C14 C15 -151(3) . .
Eu1 C7 C14 C15 103(3) . .
C8 C7 C14 Eu1 -80(3) . .
C2 C7 C14 Eu1 107(2) . .
N1 Eu1 C14 C19 80.9(19) . .
O2 Eu1 C14 C19 -11.1(19) . .
O1 Eu1 C14 C19 -96.7(19) . .
C7 Eu1 C14 C19 122(3) . .
C8 Eu1 C14 C19 153(2) . .
C39 Eu1 C14 C19 120(2) . .
C9 Eu1 C14 C19 -176(2) . .
C40 Eu1 C14 C19 151.8(17) . .
Si1 Eu1 C14 C19 89.1(19) . .
N1 Eu1 C14 C15 -160(2) . .
O2 Eu1 C14 C15 108(2) . .
O1 Eu1 C14 C15 22(2) . .
C7 Eu1 C14 C15 -118(3) . .
C8 Eu1 C14 C15 -88(2) . .
C39 Eu1 C14 C15 -121(2) . .
C9 Eu1 C14 C15 -57(2) . .
C40 Eu1 C14 C15 -89(2) . .
Si1 Eu1 C14 C15 -152(2) . .
N1 Eu1 C14 C7 -41.6(16) . .
O2 Eu1 C14 C7 -133.6(16) . .
O1 Eu1 C14 C7 140.8(16) . .
C8 Eu1 C14 C7 30.4(15) . .
C39 Eu1 C14 C7 -2(2) . .
C9 Eu1 C14 C7 61.3(16) . .
C40 Eu1 C14 C7 29(2) . .
Si1 Eu1 C14 C7 -33.4(17) . .
C19 C14 C15 C16 -1(4) . .
C7 C14 C15 C16 179(3) . .
Eu1 C14 C15 C16 -107(3) . .
C14 C15 C16 C17 2(5) . .
C15 C16 C17 C18 -1(5) . .
C16 C17 C18 C19 0(5) . .
C17 C18 C19 C14 0(5) . .
C15 C14 C19 C18 0(4) . .
C7 C14 C19 C18 180(3) . .
Eu1 C14 C19 C18 119(3) . .
C5 C6 C20 C21 -88(3) . .
C1 C6 C20 C21 86(3) . .
C5 C6 C20 C27 38(3) . .
C1 C6 C20 C27 -148(2) . .
C6 C20 C21 C26 29(3) . .
C27 C20 C21 C26 -98(3) . .
C6 C20 C21 C22 -153(2) . .
C27 C20 C21 C22 80(3) . .
C26 C21 C22 C23 0(4) . .
C20 C21 C22 C23 -178(2) . .
C21 C22 C23 C24 0(4) . .
C22 C23 C24 C25 1(4) . .
C23 C24 C25 C26 -2(5) . .
C22 C21 C26 C25 -2(4) . .
C20 C21 C26 C25 177(2) . .
C24 C25 C26 C21 2(4) . .
C6 C20 C27 C32 -101(3) . .
C21 C20 C27 C32 25(4) . .
C6 C20 C27 C28 78(3) . .
C21 C20 C27 C28 -156(2) . .
C32 C27 C28 C29 1(4) . .
C20 C27 C28 C29 -178(3) . .
C27 C28 C29 C30 -1(5) . .
C28 C29 C30 C31 1(5) . .
C29 C30 C31 C32 -1(5) . .
C28 C27 C32 C31 -1(5) . .
C20 C27 C32 C31 178(3) . .
C30 C31 C32 C27 1(5) . .
N1 Si1 C33 C38 -10(3) . .
C45 Si1 C33 C38 125(2) . .
C39 Si1 C33 C38 -126(2) . .
Eu1 Si1 C33 C38 -63(3) . .
N1 Si1 C33 C34 169(2) . .
C45 Si1 C33 C34 -56(2) . .
C39 Si1 C33 C34 54(2) . .
Eu1 Si1 C33 C34 116(2) . .
C38 C33 C34 C35 -2(4) . .
Si1 C33 C34 C35 179(2) . .
C33 C34 C35 C36 0(4) . .
C34 C35 C36 C37 1(5) . .
C35 C36 C37 C38 -1(5) . .
C36 C37 C38 C33 -1(5) . .
C34 C33 C38 C37 3(4) . .
Si1 C33 C38 C37 -178(2) . .
N1 Si1 C39 C44 105(3) . .
C33 Si1 C39 C44 -131(3) . .
C45 Si1 C39 C44 -19(3) . .
Eu1 Si1 C39 C44 96(3) . .
N1 Si1 C39 C40 -77(2) . .
C33 Si1 C39 C40 46(2) . .
C45 Si1 C39 C40 158(2) . .
Eu1 Si1 C39 C40 -87(2) . .
N1 Si1 C39 Eu1 9.3(10) . .
C33 Si1 C39 Eu1 132.9(9) . .
C45 Si1 C39 Eu1 -115.3(10) . .
N1 Eu1 C39 C44 -132(2) . .
O2 Eu1 C39 C44 -47.9(19) . .
O1 Eu1 C39 C44 43(2) . .
C7 Eu1 C39 C44 -178.8(18) . .
C8 Eu1 C39 C44 156.8(18) . .
C14 Eu1 C39 C44 -177.6(17) . .
C9 Eu1 C39 C44 128.4(19) . .
C40 Eu1 C39 C44 116(3) . .
Si1 Eu1 C39 C44 -126(2) . .
N1 Eu1 C39 C40 111.1(18) . .
O2 Eu1 C39 C40 -164.4(16) . .
O1 Eu1 C39 C40 -73.5(18) . .
C7 Eu1 C39 C40 64.7(18) . .
C8 Eu1 C39 C40 40.3(18) . .
C14 Eu1 C39 C40 66(2) . .
C9 Eu1 C39 C40 11.9(18) . .
Si1 Eu1 C39 C40 118(2) . .
N1 Eu1 C39 Si1 -6.8(7) . .
O2 Eu1 C39 Si1 77.8(9) . .
O1 Eu1 C39 Si1 168.6(9) . .
C7 Eu1 C39 Si1 -53.2(11) . .
C8 Eu1 C39 Si1 -77.5(10) . .
C14 Eu1 C39 Si1 -51.9(17) . .
C9 Eu1 C39 Si1 -106.0(10) . .
C40 Eu1 C39 Si1 -118(2) . .
C44 C39 C40 C41 1(4) . .
Si1 C39 C40 C41 -176(2) . .
Eu1 C39 C40 C41 101(3) . .
C44 C39 C40 Eu1 -99(3) . .
Si1 C39 C40 Eu1 83.3(16) . .
N1 Eu1 C40 C41 -177(2) . .
O2 Eu1 C40 C41 -97(2) . .
O1 Eu1 C40 C41 -2(2) . .
C7 Eu1 C40 C41 119(2) . .
C8 Eu1 C40 C41 104(2) . .
C39 Eu1 C40 C41 -117(3) . .
C14 Eu1 C40 C41 105(2) . .
C9 Eu1 C40 C41 75(2) . .
Si1 Eu1 C40 C41 -157(3) . .
N1 Eu1 C40 C39 -59.9(16) . .
O2 Eu1 C40 C39 20(2) . .
O1 Eu1 C40 C39 114.4(17) . .
C7 Eu1 C40 C39 -123.7(17) . .
C8 Eu1 C40 C39 -139.1(18) . .
C14 Eu1 C40 C39 -138.2(16) . .
C9 Eu1 C40 C39 -167.7(18) . .
Si1 Eu1 C40 C39 -40.3(14) . .
C39 C40 C41 C42 -1(5) . .
Eu1 C40 C41 C42 72(3) . .
C40 C41 C42 C43 -1(5) . .
C41 C42 C43 C44 2(6) . .
C40 C39 C44 C43 -1(5) . .
Si1 C39 C44 C43 177(3) . .
Eu1 C39 C44 C43 -94(4) . .
C42 C43 C44 C39 -1(6) . .
N1 Si1 C45 C50 -55(3) . .
C33 Si1 C45 C50 170(2) . .
C39 Si1 C45 C50 61(2) . .
Eu1 Si1 C45 C50 -3(3) . .
N1 Si1 C45 C46 128(2) . .
C33 Si1 C45 C46 -7(3) . .
C39 Si1 C45 C46 -116(2) . .
Eu1 Si1 C45 C46 179.9(19) . .
C50 C45 C46 C47 0(4) . .
Si1 C45 C46 C47 177(2) . .
C45 C46 C47 C48 -1(5) . .
C46 C47 C48 C49 0(5) . .
C47 C48 C49 C50 1(5) . .
C48 C49 C50 C45 -2(5) . .
C46 C45 C50 C49 1(4) . .
Si1 C45 C50 C49 -176(2) . .
C52 O2 C51 C54 12(4) . .
Eu1 O2 C51 C54 164(3) . .
C51 O2 C52 C53 11(4) . .
Eu1 O2 C52 C53 -139(3) . .
O2 C52 C53 C54 -29(4) . .
O2 C51 C54 C53 -30(4) . .
C52 C53 C54 C51 36(5) . .
C55A O1 C55 C56 57(11) . .
C58A O1 C55 C56 -1(8) . .
C58 O1 C55 C56 -39(9) . .
Eu1 O1 C55 C56 165(5) . .
C55 O1 C55A C56A -101(15) . .
C58A O1 C55A C56A 28(10) . .
C58 O1 C55A C56A -5(13) . .
Eu1 O1 C55A C56A 166(6) . .
O1 C55 C56 C57 24(8) . .
O1 C55A C56A C57A -10(18) . .
C55 C56 C57 C58 -2(9) . .
C55A C56A C57A C58A -14(17) . .
C55 O1 C58 C57 36(9) . .
C55A O1 C58 C57 3(12) . .
C58A O1 C58 C57 -67(8) . .
Eu1 O1 C58 C57 -168(4) . .
C56 C57 C58 O1 -19(10) . .
C56A C57A C58A O1 37(16) . .
C55 O1 C58A C57A -20(14) . .
C55A O1 C58A C57A -46(14) . .
C58 O1 C58A C57A 71(12) . .
Eu1 O1 C58A C57A 175(11) . .
C3 C4 C59 C61 -103(6) . .
C5 C4 C59 C61 78(7) . .
C3 C4 C59 C61A -139(7) . .
C5 C4 C59 C61A 42(9) . .
C3 C4 C59 C60 43(6) . .
C5 C4 C59 C60 -137(4) . .
C64 C62 C63 C64 2(12) 3_466 .
C62 C63 C64 C62 -2(12) . 3_466
