#------------------------------------------------------------------------------
#$Date: 2019-11-17 10:16:30 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229300 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/73/7047346.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7047346
loop_
_publ_author_name
'Jin, Jun-Ling'
'Xie, Yun-Peng'
'Lu, Xing'
_publ_section_title
;
 High-nuclearity silver ethynide clusters containing polynucleating oxygen
 donor ligands.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              12972
_journal_page_last               12978
_journal_paper_doi               10.1039/c8dt02700e
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C159 H227 Ag30 Bi6 Cl2 F48 O51.5 P6'
_chemical_formula_weight         8621.09
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-08-16 deposited with the CCDC.
2018-08-22 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 95.212(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   26.438(2)
_cell_length_b                   19.3816(15)
_cell_length_c                   47.701(4)
_cell_measurement_reflns_used    9688
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      28.0627
_cell_measurement_theta_min      2.9472
_cell_volume                     24341(3)
_computing_cell_refinement       'SAINT (Bruker, 2014)'
_computing_data_collection       'Apex2 (Bruker, 2014)'
_computing_data_reduction        'SAINT (Bruker, 2014)'
_computing_molecular_graphics    'Bruker SHELXTL (Sheldrick, 2014)'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker D8 Quest'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0599
_diffrn_reflns_av_unetI/netI     0.0598
_diffrn_reflns_Laue_measured_fraction_full 0.993
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       52
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            60251
_diffrn_reflns_point_group_measured_fraction_full 0.993
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        23.013
_diffrn_reflns_theta_max         23.013
_diffrn_reflns_theta_min         2.947
_exptl_absorpt_coefficient_mu    6.828
_exptl_absorpt_correction_T_max  0.758
_exptl_absorpt_correction_T_min  0.591
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS-2014/2 (Bruker,2014)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.352
_exptl_crystal_description       block
_exptl_crystal_F_000             16228
_exptl_crystal_size_max          0.086
_exptl_crystal_size_mid          0.072
_exptl_crystal_size_min          0.043
_exptl_transmission_factor_max   0.0265
_exptl_transmission_factor_min   0.0069
_refine_diff_density_max         2.559
_refine_diff_density_min         -1.701
_refine_diff_density_rms         0.239
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.102
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1161
_refine_ls_number_reflns         16825
_refine_ls_number_restraints     1292
_refine_ls_restrained_S_all      1.086
_refine_ls_R_factor_all          0.1206
_refine_ls_R_factor_gt           0.0995
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+3055.1331P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2105
_refine_ls_wR_factor_ref         0.2231
_reflns_Friedel_coverage         0.000
_reflns_number_gt                13286
_reflns_number_total             16825
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8dt02700e2.cif
_cod_data_source_block           Complex4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7047343--7047346.cif.
;
_cod_original_cell_volume        24342(3)
_cod_original_formula_sum        'C159 H227 Ag30 Bi6 Cl2 F48 O51.50 P6'
_cod_database_code               7047346
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.591
_shelx_estimated_absorpt_t_max   0.758
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Bi1 Bi 0.67174(4) 0.20663(5) 0.03031(2) 0.0555(3) Uani 1 1 d . U . . .
Bi2 Bi 0.80124(4) 0.26532(5) 0.05401(2) 0.0559(3) Uani 1 1 d . U . . .
Bi3 Bi 0.78102(4) 0.11476(5) 0.00606(2) 0.0596(3) Uani 1 1 d . U . . .
Ag1 Ag 0.77469(9) 0.13793(12) 0.16744(5) 0.0770(6) Uani 1 1 d . U . . .
Ag2 Ag 0.75653(8) 0.06770(11) 0.10074(5) 0.0705(6) Uani 1 1 d . U . . .
Ag3 Ag 0.83157(9) 0.19990(13) 0.12389(5) 0.0767(6) Uani 1 1 d . U . . .
Ag4 Ag 0.84541(9) -0.06811(12) 0.10940(5) 0.0782(6) Uani 1 1 d . U . . .
Ag5 Ag 0.87015(9) 0.04835(12) 0.15157(6) 0.0823(7) Uani 1 1 d . U . . .
Ag6 Ag 0.66158(10) 0.08196(13) 0.15520(5) 0.0847(7) Uani 1 1 d . U . . .
Ag7 Ag 0.75224(11) -0.10993(13) 0.20848(5) 0.0888(7) Uani 1 1 d . U . . .
Ag8 Ag 0.73958(10) -0.11008(13) 0.09273(5) 0.0857(7) Uani 1 1 d . U . . .
Ag9 Ag 0.84190(10) -0.09576(13) 0.16993(5) 0.0867(7) Uani 1 1 d . U . . .
Ag10 Ag 0.6184(13) 0.1105(12) 0.0844(4) 0.091(4) Uani 0.32(3) 1 d . U P A 1
Ag1A Ag 0.6394(5) 0.0986(3) 0.0905(2) 0.0785(16) Uani 0.68(3) 1 d . U P A 2
Ag11 Ag 0.77057(11) 0.03736(15) 0.21511(6) 0.1017(8) Uani 1 1 d . U . . .
Ag12 Ag 0.80675(13) -0.04122(13) 0.04162(7) 0.1061(9) Uani 1 1 d . U . . .
Ag13 Ag 0.71928(12) -0.15160(14) 0.14961(6) 0.0991(8) Uani 1 1 d . U . . .
Ag14 Ag 0.6688(3) 0.0052(6) 0.2006(3) 0.099(2) Uani 0.444(19) 1 d . U P A 1
Ag4A Ag 0.6663(3) 0.0294(5) 0.2150(3) 0.097(2) Uani 0.556(19) 1 d . U P A 2
Ag15 Ag 0.64587(11) -0.04172(13) 0.11976(6) 0.0981(8) Uani 1 1 d . U . . .
Cl1 Cl 0.7589(3) -0.0060(4) 0.14821(15) 0.0723(16) Uani 1 1 d . U . . .
P1 P 0.6874(3) 0.0247(4) 0.04165(16) 0.0712(17) Uani 1 1 d . U . . .
P2 P 0.7111(3) 0.2261(3) 0.10311(15) 0.0593(15) Uani 1 1 d . U . . .
P3 P 0.8595(3) 0.1017(4) 0.07091(16) 0.0653(16) Uani 1 1 d . U . . .
F1 F 0.8862(10) -0.1598(13) 0.2238(5) 0.181(10) Uani 1 1 d D U . . .
F2 F 0.9337(8) -0.1315(10) 0.2611(4) 0.133(7) Uani 1 1 d D U . . .
F3 F 0.9501(10) -0.0913(17) 0.2206(5) 0.212(12) Uani 1 1 d D U . . .
F4 F 0.8190(11) 0.1117(17) 0.3079(6) 0.213(12) Uani 1 1 d D U . . .
F5 F 0.8986(10) 0.095(2) 0.3081(8) 0.273(17) Uani 1 1 d D U . . .
F6 F 0.8513(15) 0.0154(18) 0.3223(6) 0.254(14) Uani 1 1 d D U . . .
F7 F 0.9501(11) 0.336(2) 0.1281(8) 0.304(18) Uani 1 1 d D U . . .
F8 F 0.9141(15) 0.4291(16) 0.1465(7) 0.305(19) Uani 1 1 d D U . . .
F9 F 0.8862(16) 0.3229(18) 0.1563(6) 0.271(17) Uani 1 1 d D U . . .
F10 F 0.7521(15) 0.530(2) 0.1001(7) 0.298(18) Uani 1 1 d D U . . .
F11 F 0.8231(14) 0.5657(13) 0.0785(9) 0.285(17) Uani 1 1 d D U . . .
F12 F 0.7539(14) 0.517(2) 0.0514(7) 0.293(17) Uani 1 1 d D U . . .
F13 F 0.9112(15) -0.0871(16) -0.0307(9) 0.294(17) Uani 1 1 d D U . . .
F14 F 0.9517(15) 0.015(2) -0.0203(10) 0.320(19) Uani 1 1 d D U . . .
F15 F 0.9055(18) 0.001(2) -0.0628(7) 0.34(2) Uani 1 1 d D U . . .
O1 O 0.7626(6) 0.2496(8) 0.0936(3) 0.062(3) Uani 1 1 d . U . . .
O2 O 0.6711(6) 0.2121(9) 0.0781(4) 0.065(3) Uani 1 1 d . U . . .
O3 O 0.7181(7) 0.1620(9) 0.1222(4) 0.067(3) Uani 1 1 d . U . . .
O4 O 0.6586(7) 0.0940(9) 0.0418(4) 0.070(3) Uani 1 1 d . U . . .
O5 O 0.7350(8) 0.0301(8) 0.0249(4) 0.071(3) Uani 1 1 d . U . . .
O6 O 0.7015(7) -0.0008(9) 0.0715(4) 0.074(3) Uani 1 1 d . U . . .
O7 O 0.8304(13) -0.0272(13) -0.0059(5) 0.135(7) Uani 1 1 d . U . . .
O8 O 0.8635(10) 0.0737(13) -0.0187(5) 0.124(7) Uani 1 1 d . U . . .
O10 O 0.8490(6) 0.1793(9) 0.0757(4) 0.068(3) Uani 1 1 d . U . . .
O11 O 0.8427(7) 0.0592(9) 0.0951(4) 0.074(3) Uani 1 1 d . U . . .
O12 O 0.8345(7) 0.0768(9) 0.0427(4) 0.072(3) Uani 1 1 d . U . . .
O13 O 0.8329(5) 0.2108(8) 0.0131(3) 0.049(2) Uani 1 1 d . U . . .
O14 O 0.7503(6) 0.1808(7) 0.0371(3) 0.050(3) Uani 1 1 d . U . . .
O15 O 0.8027(5) 0.3476(7) 0.0096(3) 0.050(3) Uani 1 1 d . U . . .
O16 O 0.7806(5) 0.1915(7) -0.0383(3) 0.046(3) Uani 1 1 d . U . . .
O17 O 0.8215(11) 0.0783(14) 0.2539(6) 0.135(7) Uani 1 1 d . U . . .
O18 O 0.8513(9) -0.0287(12) 0.2159(5) 0.102(3) Uani 1 1 d . U . . .
O19 O 0.8587(10) 0.3098(11) 0.0998(5) 0.115(6) Uani 1 1 d D U . . .
O20 O 0.7908(12) 0.4015(10) 0.0677(5) 0.131(6) Uani 1 1 d D U . . .
C1 C 0.6426(12) -0.0376(15) 0.0225(6) 0.078(5) Uani 1 1 d . U . . .
C2 C 0.6309(15) -0.0111(17) -0.0068(7) 0.111(11) Uani 1 1 d . U . . .
H2A H 0.6617 -0.0083 -0.0160 0.167 Uiso 1 1 calc R U . . .
H2B H 0.6076 -0.0419 -0.0171 0.167 Uiso 1 1 calc R U . . .
H2C H 0.6159 0.0339 -0.0062 0.167 Uiso 1 1 calc R U . . .
C3 C 0.5998(14) -0.043(2) 0.0373(8) 0.119(11) Uani 1 1 d . U . . .
H3A H 0.6096 -0.0604 0.0559 0.179 Uiso 1 1 calc R U . . .
H3B H 0.5843 0.0013 0.0386 0.179 Uiso 1 1 calc R U . . .
H3C H 0.5760 -0.0745 0.0277 0.179 Uiso 1 1 calc R U . . .
C4 C 0.6711(14) -0.1062(14) 0.0210(7) 0.098(9) Uani 1 1 d . U . . .
H4A H 0.7002 -0.0997 0.0106 0.147 Uiso 1 1 calc R U . . .
H4B H 0.6819 -0.1217 0.0397 0.147 Uiso 1 1 calc R U . . .
H4C H 0.6490 -0.1400 0.0117 0.147 Uiso 1 1 calc R U . . .
C5 C 0.6891(10) 0.3007(14) 0.1230(6) 0.066(5) Uani 1 1 d . U . . .
C6 C 0.6735(11) 0.3581(13) 0.1038(6) 0.074(7) Uani 1 1 d . U . . .
H6A H 0.6471 0.3426 0.0900 0.111 Uiso 1 1 calc R U . . .
H6B H 0.6610 0.3956 0.1143 0.111 Uiso 1 1 calc R U . . .
H6C H 0.7021 0.3735 0.0944 0.111 Uiso 1 1 calc R U . . .
C7 C 0.6405(11) 0.2725(16) 0.1375(6) 0.082(8) Uani 1 1 d . U . . .
H7A H 0.6506 0.2352 0.1499 0.123 Uiso 1 1 calc R U . . .
H7B H 0.6265 0.3091 0.1479 0.123 Uiso 1 1 calc R U . . .
H7C H 0.6154 0.2565 0.1231 0.123 Uiso 1 1 calc R U . . .
C8 C 0.7300(11) 0.3198(15) 0.1451(6) 0.083(8) Uani 1 1 d . U . . .
H8A H 0.7384 0.2805 0.1569 0.124 Uiso 1 1 calc R U . . .
H8B H 0.7595 0.3345 0.1364 0.124 Uiso 1 1 calc R U . . .
H8C H 0.7184 0.3566 0.1564 0.124 Uiso 1 1 calc R U . . .
C9 C 0.9290(11) 0.0930(16) 0.0697(6) 0.078(5) Uani 1 1 d . U . . .
C10 C 0.9392(10) 0.0189(14) 0.0640(6) 0.075(7) Uani 1 1 d . U . . .
H10A H 0.9222 0.0060 0.0462 0.112 Uiso 1 1 calc R U . . .
H10B H 0.9751 0.0119 0.0637 0.112 Uiso 1 1 calc R U . . .
H10C H 0.9268 -0.0090 0.0786 0.112 Uiso 1 1 calc R U . . .
C11 C 0.9547(11) 0.1151(19) 0.0973(7) 0.099(9) Uani 1 1 d . U . . .
H11A H 0.9475 0.1629 0.1004 0.149 Uiso 1 1 calc R U . . .
H11B H 0.9424 0.0879 0.1121 0.149 Uiso 1 1 calc R U . . .
H11C H 0.9907 0.1088 0.0972 0.149 Uiso 1 1 calc R U . . .
C12 C 0.9451(11) 0.1389(16) 0.0467(7) 0.087(8) Uani 1 1 d . U . . .
H12A H 0.9284 0.1244 0.0289 0.130 Uiso 1 1 calc R U . . .
H12B H 0.9359 0.1858 0.0503 0.130 Uiso 1 1 calc R U . . .
H12C H 0.9812 0.1358 0.0461 0.130 Uiso 1 1 calc R U . . .
C13 C 0.8086(13) -0.1248(15) 0.0749(7) 0.085(3) Uani 1 1 d . U . . .
C14 C 0.8259(12) -0.1567(14) 0.0569(7) 0.082(5) Uani 1 1 d . U . . .
C15 C 0.850(2) -0.208(2) 0.0364(9) 0.135(10) Uani 1 1 d . U . . .
C16 C 0.824(2) -0.206(2) 0.0084(9) 0.170(17) Uani 1 1 d . U . . .
H16A H 0.8243 -0.1602 0.0013 0.255 Uiso 1 1 calc R U . . .
H16B H 0.8418 -0.2362 -0.0036 0.255 Uiso 1 1 calc R U . . .
H16C H 0.7899 -0.2221 0.0089 0.255 Uiso 1 1 calc R U . . .
C17 C 0.902(2) -0.178(3) 0.0302(13) 0.23(2) Uani 1 1 d . U . . .
H17A H 0.9238 -0.1755 0.0473 0.338 Uiso 1 1 calc R U . . .
H17B H 0.9169 -0.2071 0.0170 0.338 Uiso 1 1 calc R U . . .
H17C H 0.8972 -0.1324 0.0224 0.338 Uiso 1 1 calc R U . . .
C18 C 0.851(3) -0.277(2) 0.0489(10) 0.208(19) Uani 1 1 d . U . . .
H18A H 0.8685 -0.2753 0.0675 0.313 Uiso 1 1 calc R U . . .
H18B H 0.8172 -0.2938 0.0500 0.313 Uiso 1 1 calc R U . . .
H18C H 0.8691 -0.3080 0.0375 0.313 Uiso 1 1 calc R U . . .
C19 C 0.9019(11) -0.0530(16) 0.1453(7) 0.084(3) Uani 1 1 d . U . . .
C20 C 0.9435(12) -0.0786(18) 0.1451(7) 0.090(7) Uani 1 1 d . U . . .
C21 C 0.9957(14) -0.1032(18) 0.1432(7) 0.143(10) Uani 1 1 d D U . . .
C22 C 1.0345(14) -0.045(2) 0.1444(10) 0.185(11) Uani 1 1 d D U . . .
H22A H 1.0678 -0.0636 0.1431 0.277 Uiso 1 1 calc R U . . .
H22B H 1.0263 -0.0136 0.1291 0.277 Uiso 1 1 calc R U . . .
H22C H 1.0339 -0.0204 0.1619 0.277 Uiso 1 1 calc R U . . .
C23 C 0.9974(17) -0.142(3) 0.1155(8) 0.23(2) Uani 1 1 d D U . . .
H23A H 1.0313 -0.1584 0.1139 0.351 Uiso 1 1 calc R U . . .
H23B H 0.9745 -0.1804 0.1151 0.351 Uiso 1 1 calc R U . . .
H23C H 0.9875 -0.1115 0.1001 0.351 Uiso 1 1 calc R U . . .
C24 C 1.0088(14) -0.153(2) 0.1677(9) 0.185(11) Uani 1 1 d D U . . .
H24A H 1.0428 -0.1695 0.1669 0.277 Uiso 1 1 calc R U . . .
H24B H 1.0063 -0.1288 0.1851 0.277 Uiso 1 1 calc R U . . .
H24C H 0.9855 -0.1907 0.1663 0.277 Uiso 1 1 calc R U . . .
C25 C 0.7875(13) -0.1734(16) 0.1815(7) 0.094(3) Uani 1 1 d D U . . .
C26 C 0.8045(15) -0.2204(15) 0.1691(7) 0.100(4) Uani 1 1 d D U . . .
C27 C 0.8284(16) -0.2833(18) 0.1560(7) 0.103(7) Uani 1 1 d . U . . .
C28 C 0.8432(18) -0.266(2) 0.1265(8) 0.136(13) Uani 1 1 d . U . . .
H28A H 0.8664 -0.2275 0.1276 0.204 Uiso 1 1 calc R U . . .
H28B H 0.8591 -0.3050 0.1187 0.204 Uiso 1 1 calc R U . . .
H28C H 0.8132 -0.2535 0.1146 0.204 Uiso 1 1 calc R U . . .
C29 C 0.8779(16) -0.300(2) 0.1750(9) 0.145(13) Uani 1 1 d . U . . .
H29A H 0.9013 -0.2623 0.1744 0.217 Uiso 1 1 calc R U . . .
H29B H 0.8699 -0.3073 0.1940 0.217 Uiso 1 1 calc R U . . .
H29C H 0.8931 -0.3412 0.1682 0.217 Uiso 1 1 calc R U . . .
C30 C 0.7921(17) -0.342(2) 0.1569(8) 0.135(12) Uani 1 1 d . U . . .
H30A H 0.8063 -0.3825 0.1488 0.202 Uiso 1 1 calc R U . . .
H30B H 0.7862 -0.3518 0.1761 0.202 Uiso 1 1 calc R U . . .
H30C H 0.7606 -0.3307 0.1464 0.202 Uiso 1 1 calc R U . . .
C31 C 0.7196(14) -0.0508(18) 0.2381(7) 0.104(4) Uani 1 1 d D U . . .
C32 C 0.6978(15) -0.0385(18) 0.2585(7) 0.109(8) Uani 1 1 d D U . . .
C33 C 0.6689(17) -0.038(2) 0.2836(9) 0.135(10) Uani 1 1 d D U . . .
C34 C 0.639(3) -0.100(3) 0.2874(12) 0.23(2) Uani 1 1 d . U . . .
H34A H 0.6215 -0.0953 0.3042 0.351 Uiso 1 1 calc R U . . .
H34B H 0.6144 -0.1059 0.2714 0.351 Uiso 1 1 calc R U . . .
H34C H 0.6608 -0.1395 0.2892 0.351 Uiso 1 1 calc R U . . .
C35 C 0.6385(18) 0.029(2) 0.2834(10) 0.159(16) Uani 1 1 d . U . . .
H35A H 0.6605 0.0672 0.2808 0.238 Uiso 1 1 calc R U . . .
H35B H 0.6119 0.0277 0.2683 0.238 Uiso 1 1 calc R U . . .
H35C H 0.6238 0.0338 0.3010 0.238 Uiso 1 1 calc R U . . .
C36 C 0.711(2) -0.030(3) 0.3074(9) 0.213(19) Uani 1 1 d D U . . .
H36A H 0.7301 0.0109 0.3044 0.319 Uiso 1 1 calc R U . . .
H36B H 0.6962 -0.0264 0.3250 0.319 Uiso 1 1 calc R U . . .
H36C H 0.7330 -0.0695 0.3078 0.319 Uiso 1 1 calc R U . . .
C37 C 0.7040(12) 0.1188(16) 0.1914(7) 0.083(3) Uani 1 1 d . U . . .
C38 C 0.7205(14) 0.1623(17) 0.2069(7) 0.092(4) Uani 1 1 d . U . . .
C39 C 0.7271(16) 0.2238(19) 0.2287(7) 0.104(8) Uani 1 1 d . U . . .
C40 C 0.692(2) 0.282(2) 0.2214(9) 0.153(15) Uani 1 1 d . U . . .
H40A H 0.6576 0.2656 0.2191 0.230 Uiso 1 1 calc R U . . .
H40B H 0.6951 0.3158 0.2363 0.230 Uiso 1 1 calc R U . . .
H40C H 0.7003 0.3033 0.2042 0.230 Uiso 1 1 calc R U . . .
C41 C 0.7130(17) 0.189(2) 0.2572(7) 0.126(12) Uani 1 1 d . U . . .
H41A H 0.7357 0.1511 0.2619 0.189 Uiso 1 1 calc R U . . .
H41B H 0.7162 0.2223 0.2721 0.189 Uiso 1 1 calc R U . . .
H41C H 0.6787 0.1721 0.2548 0.189 Uiso 1 1 calc R U . . .
C42 C 0.7833(16) 0.244(2) 0.2330(7) 0.138(13) Uani 1 1 d . U . . .
H42A H 0.8033 0.2033 0.2375 0.207 Uiso 1 1 calc R U . . .
H42B H 0.7934 0.2640 0.2160 0.207 Uiso 1 1 calc R U . . .
H42C H 0.7883 0.2765 0.2481 0.207 Uiso 1 1 calc R U . . .
C43 C 0.8542(9) 0.1561(16) 0.1645(6) 0.078(3) Uani 1 1 d D U . . .
C44 C 0.8944(9) 0.1535(17) 0.1784(6) 0.085(6) Uani 1 1 d D U . . .
C45 C 0.9462(10) 0.1631(16) 0.1960(6) 0.121(9) Uani 1 1 d D U . . .
C46 C 0.9410(16) 0.2259(19) 0.2150(8) 0.175(17) Uani 1 1 d D U . . .
H46A H 0.9346 0.2663 0.2035 0.263 Uiso 1 1 calc R U . . .
H46B H 0.9134 0.2188 0.2264 0.263 Uiso 1 1 calc R U . . .
H46C H 0.9719 0.2321 0.2269 0.263 Uiso 1 1 calc R U . . .
C47 C 0.9892(13) 0.175(2) 0.1770(8) 0.176(16) Uani 1 1 d D U . . .
H47A H 0.9823 0.2165 0.1661 0.264 Uiso 1 1 calc R U . . .
H47B H 1.0208 0.1803 0.1884 0.264 Uiso 1 1 calc R U . . .
H47C H 0.9913 0.1367 0.1645 0.264 Uiso 1 1 calc R U . . .
C48 C 0.9564(17) 0.0979(18) 0.2134(8) 0.184(18) Uani 1 1 d D U . . .
H48A H 0.9595 0.0593 0.2011 0.276 Uiso 1 1 calc R U . . .
H48B H 0.9874 0.1033 0.2254 0.276 Uiso 1 1 calc R U . . .
H48C H 0.9289 0.0900 0.2248 0.276 Uiso 1 1 calc R U . . .
C49 C 0.6030(12) 0.0504(16) 0.1246(7) 0.084(3) Uani 1 1 d . U . . .
C50 C 0.5629(11) 0.0710(19) 0.1142(8) 0.098(6) Uani 1 1 d D U . . .
C51 C 0.5065(11) 0.085(2) 0.1060(7) 0.165(10) Uani 1 1 d D U . . .
C52 C 0.4773(14) 0.077(2) 0.1322(8) 0.165(10) Uani 1 1 d D U . . .
H52A H 0.4419 0.0854 0.1273 0.248 Uiso 1 1 calc R U . . .
H52B H 0.4818 0.0311 0.1396 0.248 Uiso 1 1 calc R U . . .
H52C H 0.4901 0.1097 0.1462 0.248 Uiso 1 1 calc R U . . .
C53 C 0.4826(18) 0.039(3) 0.0819(9) 0.25(2) Uani 1 1 d D U . . .
H53A H 0.4474 0.0510 0.0781 0.370 Uiso 1 1 calc R U . . .
H53B H 0.4999 0.0471 0.0654 0.370 Uiso 1 1 calc R U . . .
H53C H 0.4857 -0.0083 0.0873 0.370 Uiso 1 1 calc R U . . .
C54 C 0.508(2) 0.160(2) 0.0967(11) 0.26(2) Uani 1 1 d D U . . .
H54A H 0.4742 0.1759 0.0909 0.388 Uiso 1 1 calc R U . . .
H54B H 0.5221 0.1882 0.1122 0.388 Uiso 1 1 calc R U . . .
H54C H 0.5287 0.1647 0.0813 0.388 Uiso 1 1 calc R U . . .
C55 C 0.6686(13) -0.1412(14) 0.1116(7) 0.091(3) Uani 1 1 d D U . . .
C56 C 0.6488(15) -0.1943(16) 0.1039(8) 0.115(8) Uani 1 1 d D U . . .
C57 C 0.6044(14) -0.2439(19) 0.0961(8) 0.187(14) Uani 1 1 d D U . . .
C58 C 0.598(2) -0.257(2) 0.0643(8) 0.23(2) Uani 1 1 d D U . . .
H58A H 0.5874 -0.2152 0.0547 0.351 Uiso 1 1 calc R U . . .
H58B H 0.6297 -0.2720 0.0581 0.351 Uiso 1 1 calc R U . . .
H58C H 0.5727 -0.2920 0.0601 0.351 Uiso 1 1 calc R U . . .
C59 C 0.6212(19) -0.309(2) 0.1127(10) 0.24(2) Uani 1 1 d D U . . .
H59A H 0.6248 -0.2987 0.1325 0.358 Uiso 1 1 calc R U . . .
H59B H 0.5962 -0.3446 0.1090 0.358 Uiso 1 1 calc R U . . .
H59C H 0.6532 -0.3246 0.1070 0.358 Uiso 1 1 calc R U . . .
C60 C 0.5545(19) -0.215(3) 0.1063(13) 0.28(2) Uani 1 1 d D U . . .
H60A H 0.5592 -0.2066 0.1262 0.422 Uiso 1 1 calc R U . . .
H60B H 0.5461 -0.1718 0.0968 0.422 Uiso 1 1 calc R U . . .
H60C H 0.5274 -0.2470 0.1022 0.422 Uiso 1 1 calc R U . . .
C61 C 0.9054(13) 0.3635(14) 0.1359(7) 0.203(13) Uani 1 1 d D U . . .
C62 C 0.8669(15) 0.3665(13) 0.1104(8) 0.163(10) Uani 1 1 d D U . . .
C63 C 0.8445(19) 0.4387(18) 0.1069(10) 0.189(12) Uani 1 1 d D U . . .
H63 H 0.8545 0.4739 0.1195 0.227 Uiso 1 1 calc R U . . .
C64 C 0.8050(15) 0.4514(15) 0.0822(7) 0.177(10) Uani 1 1 d D U . . .
C65 C 0.7815(13) 0.5228(17) 0.0776(6) 0.206(12) Uani 1 1 d D U . . .
C66 C 0.9108(10) -0.1045(15) 0.2367(5) 0.132(8) Uani 1 1 d D U . . .
C67 C 0.8750(14) -0.0432(18) 0.2385(7) 0.111(7) Uani 1 1 d D U . . .
C68 C 0.8793(15) -0.015(2) 0.2684(7) 0.132(10) Uani 1 1 d D U . . .
H68 H 0.9002 -0.0326 0.2833 0.159 Uiso 1 1 calc R U . . .
C69 C 0.8439(16) 0.047(2) 0.2702(7) 0.136(9) Uani 1 1 d D U . . .
C70 C 0.8537(11) 0.0631(17) 0.3013(7) 0.170(11) Uani 1 1 d D U . . .
C71 C 0.9123(14) -0.0185(17) -0.0354(7) 0.202(13) Uani 1 1 d D U . . .
C72 C 0.8655(17) 0.008(2) -0.0221(10) 0.151(9) Uani 1 1 d D U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O14 Bi1 O4 84.6(6) . .
O14 Bi1 O2 87.5(6) . .
O4 Bi1 O2 77.8(6) . .
O14 Bi1 O15 70.5(5) . 7_655
O4 Bi1 O15 80.1(6) . 7_655
O2 Bi1 O15 150.0(5) . 7_655
O14 Bi1 O16 70.9(5) . 7_655
O4 Bi1 O16 148.5(6) . 7_655
O2 Bi1 O16 81.5(5) . 7_655
O15 Bi1 O16 108.7(5) 7_655 7_655
O14 Bi1 O13 103.8(5) . 7_655
O4 Bi1 O13 141.1(6) . 7_655
O2 Bi1 O13 139.4(5) . 7_655
O15 Bi1 O13 67.9(5) 7_655 7_655
O16 Bi1 O13 66.5(5) 7_655 7_655
O14 Bi1 Bi3 31.7(4) . .
O4 Bi1 Bi3 75.7(4) . .
O2 Bi1 Bi3 114.5(4) . .
O15 Bi1 Bi3 39.4(3) 7_655 .
O16 Bi1 Bi3 91.9(3) 7_655 .
O13 Bi1 Bi3 91.7(3) 7_655 .
O14 Bi1 Bi2 33.0(4) . .
O4 Bi1 Bi2 112.2(4) . .
O2 Bi1 Bi2 76.8(4) . .
O15 Bi1 Bi2 93.4(3) 7_655 .
O16 Bi1 Bi2 39.0(3) 7_655 .
O13 Bi1 Bi2 91.7(3) 7_655 .
Bi3 Bi1 Bi2 60.69(3) . .
O14 Bi2 O1 84.2(6) . .
O14 Bi2 O10 85.3(6) . .
O1 Bi2 O10 78.1(6) . .
O14 Bi2 O16 69.0(5) . 7_655
O1 Bi2 O16 80.9(5) . 7_655
O10 Bi2 O16 148.3(6) . 7_655
O14 Bi2 O13 68.3(5) . .
O1 Bi2 O13 146.1(5) . .
O10 Bi2 O13 80.2(5) . .
O16 Bi2 O13 105.7(5) 7_655 .
O14 Bi2 O15 101.8(5) . .
O1 Bi2 O15 142.4(5) . .
O10 Bi2 O15 138.9(5) . .
O16 Bi2 O15 67.4(5) 7_655 .
O13 Bi2 O15 65.8(4) . .
O14 Bi2 O19 144.1(6) . .
O1 Bi2 O19 68.1(7) . .
O10 Bi2 O19 67.5(7) . .
O16 Bi2 O19 125.0(7) 7_655 .
O13 Bi2 O19 125.5(7) . .
O15 Bi2 O19 114.1(6) . .
O14 Bi2 O20 136.5(7) . .
O1 Bi2 O20 82.4(7) . .
O10 Bi2 O20 131.2(8) . .
O16 Bi2 O20 68.1(7) 7_655 .
O13 Bi2 O20 131.2(7) . .
O15 Bi2 O20 67.7(6) . .
O19 Bi2 O20 63.8(8) . .
O14 Bi2 Bi1 31.5(4) . .
O1 Bi2 Bi1 74.7(4) . .
O10 Bi2 Bi1 112.0(5) . .
O16 Bi2 Bi1 38.6(3) 7_655 .
O13 Bi2 Bi1 89.9(3) . .
O15 Bi2 Bi1 91.2(3) . .
O19 Bi2 Bi1 142.1(5) . .
O20 Bi2 Bi1 105.1(6) . .
O14 Bi3 O12 84.9(6) . .
O14 Bi3 O5 84.8(6) . .
O12 Bi3 O5 77.3(7) . .
O14 Bi3 O13 71.4(5) . .
O12 Bi3 O13 80.1(6) . .
O5 Bi3 O13 148.4(6) . .
O14 Bi3 O15 68.9(5) . 7_655
O12 Bi3 O15 146.8(6) . 7_655
O5 Bi3 O15 80.2(6) . 7_655
O13 Bi3 O15 108.7(5) . 7_655
O14 Bi3 O16 104.2(5) . .
O12 Bi3 O16 140.6(6) . .
O5 Bi3 O16 140.8(6) . .
O13 Bi3 O16 67.4(5) . .
O15 Bi3 O16 68.4(5) 7_655 .
O14 Bi3 O8 147.3(8) . .
O12 Bi3 O8 76.6(7) . .
O5 Bi3 O8 116.3(7) . .
O13 Bi3 O8 79.0(7) . .
O15 Bi3 O8 135.9(7) 7_655 .
O16 Bi3 O8 75.8(6) . .
O14 Bi3 Ag12 104.3(4) . .
O12 Bi3 Ag12 42.9(5) . .
O5 Bi3 Ag12 43.4(5) . .
O13 Bi3 Ag12 122.4(3) . .
O15 Bi3 Ag12 123.4(4) 7_655 .
O16 Bi3 Ag12 151.5(3) . .
O8 Bi3 Ag12 80.1(5) . .
O14 Bi3 Bi1 31.2(4) . .
O12 Bi3 Bi1 111.6(5) . .
O5 Bi3 Bi1 76.1(5) . .
O13 Bi3 Bi1 92.1(4) . .
O15 Bi3 Bi1 38.3(4) 7_655 .
O16 Bi3 Bi1 91.9(3) . .
O8 Bi3 Bi1 166.9(5) . .
Ag12 Bi3 Bi1 112.96(6) . .
C43 Ag1 C37 154.2(11) . .
C43 Ag1 C38 130.3(11) . .
C37 Ag1 C38 27.9(10) . .
C43 Ag1 O3 114.5(8) . .
C37 Ag1 O3 90.5(9) . .
C38 Ag1 O3 105.6(9) . .
C43 Ag1 Ag3 47.0(7) . .
C37 Ag1 Ag3 155.2(8) . .
C38 Ag1 Ag3 145.0(8) . .
O3 Ag1 Ag3 68.0(4) . .
C43 Ag1 Ag11 105.0(8) . .
C37 Ag1 Ag11 55.6(8) . .
C38 Ag1 Ag11 59.5(8) . .
O3 Ag1 Ag11 134.3(4) . .
Ag3 Ag1 Ag11 149.17(11) . .
C43 Ag1 Ag6 162.1(8) . .
C37 Ag1 Ag6 41.1(8) . .
C38 Ag1 Ag6 67.1(8) . .
O3 Ag1 Ag6 55.9(4) . .
Ag3 Ag1 Ag6 122.92(10) . .
Ag11 Ag1 Ag6 79.62(9) . .
C43 Ag1 Ag5 43.8(8) . .
C37 Ag1 Ag5 136.0(8) . .
C38 Ag1 Ag5 142.4(8) . .
O3 Ag1 Ag5 108.2(4) . .
Ag3 Ag1 Ag5 65.75(8) . .
Ag11 Ag1 Ag5 84.90(9) . .
Ag6 Ag1 Ag5 121.18(10) . .
O11 Ag2 O6 117.0(7) . .
O11 Ag2 O3 124.7(6) . .
O6 Ag2 O3 115.3(6) . .
O11 Ag2 Cl1 96.4(5) . .
O6 Ag2 Cl1 99.7(5) . .
O3 Ag2 Cl1 91.4(5) . .
O11 Ag2 Ag1A 163.0(5) . .
O6 Ag2 Ag1A 57.6(5) . .
O3 Ag2 Ag1A 57.7(5) . .
Cl1 Ag2 Ag1A 100.4(2) . .
O11 Ag2 Ag3 62.4(5) . .
O6 Ag2 Ag3 161.0(5) . .
O3 Ag2 Ag3 62.2(4) . .
Cl1 Ag2 Ag3 99.25(18) . .
Ag1A Ag2 Ag3 116.66(14) . .
C43 Ag3 O10 136.9(9) . .
C43 Ag3 O1 145.9(8) . .
O10 Ag3 O1 72.3(5) . .
C43 Ag3 O19 132.0(9) . .
O10 Ag3 O19 67.9(7) . .
O1 Ag3 O19 68.0(7) . .
C43 Ag3 Ag1 47.0(7) . .
O10 Ag3 Ag1 139.5(4) . .
O1 Ag3 Ag1 100.3(4) . .
O19 Ag3 Ag1 147.6(6) . .
C43 Ag3 Ag5 41.1(8) . .
O10 Ag3 Ag5 98.8(4) . .
O1 Ag3 Ag5 140.5(4) . .
O19 Ag3 Ag5 145.4(6) . .
Ag1 Ag3 Ag5 61.15(8) . .
C43 Ag3 Ag2 95.9(8) . .
O10 Ag3 Ag2 73.7(4) . .
O1 Ag3 Ag2 73.6(4) . .
O19 Ag3 Ag2 132.0(5) . .
Ag1 Ag3 Ag2 66.13(8) . .
Ag5 Ag3 Ag2 67.05(7) . .
C13 Ag4 C19 154.4(11) . .
C13 Ag4 O11 106.9(9) . .
C19 Ag4 O11 94.6(9) . .
C13 Ag4 Ag9 127.5(9) . .
C19 Ag4 Ag9 48.5(8) . .
O11 Ag4 Ag9 115.7(4) . .
C13 Ag4 Ag8 45.4(9) . .
C19 Ag4 Ag8 144.2(8) . .
O11 Ag4 Ag8 101.0(4) . .
Ag9 Ag4 Ag8 95.76(10) . .
C13 Ag4 Ag5 160.4(8) . .
C19 Ag4 Ag5 45.2(8) . .
O11 Ag4 Ag5 57.5(4) . .
Ag9 Ag4 Ag5 60.86(8) . .
Ag8 Ag4 Ag5 121.46(10) . .
C13 Ag4 Ag12 42.0(8) . .
C19 Ag4 Ag12 149.7(8) . .
O11 Ag4 Ag12 66.0(4) . .
Ag9 Ag4 Ag12 160.44(12) . .
Ag8 Ag4 Ag12 65.38(9) . .
Ag5 Ag4 Ag12 123.38(10) . .
C19 Ag5 C43 166.7(10) . .
C19 Ag5 C44 137.5(10) . .
C43 Ag5 C44 29.2(4) . .
C19 Ag5 Ag9 46.8(8) . .
C43 Ag5 Ag9 136.4(8) . .
C44 Ag5 Ag9 132.1(8) . .
C19 Ag5 Ag4 45.7(9) . .
C43 Ag5 Ag4 147.1(6) . .
C44 Ag5 Ag4 170.0(8) . .
Ag9 Ag5 Ag4 57.82(8) . .
C19 Ag5 Ag1 147.7(8) . .
C43 Ag5 Ag1 41.8(7) . .
C44 Ag5 Ag1 66.6(6) . .
Ag9 Ag5 Ag1 102.12(10) . .
Ag4 Ag5 Ag1 115.41(10) . .
C19 Ag5 Ag3 148.2(9) . .
C43 Ag5 Ag3 39.3(7) . .
C44 Ag5 Ag3 62.2(6) . .
Ag9 Ag5 Ag3 147.90(10) . .
Ag4 Ag5 Ag3 110.49(9) . .
Ag1 Ag5 Ag3 53.09(7) . .
C37 Ag6 C49 165.5(12) . .
C37 Ag6 Ag14 61.3(9) . .
C49 Ag6 Ag14 113.5(9) . .
C37 Ag6 Ag15 142.0(8) . .
C49 Ag6 Ag15 46.6(9) . .
Ag14 Ag6 Ag15 90.5(4) . .
C37 Ag6 Ag4A 50.6(9) . .
C49 Ag6 Ag4A 121.2(8) . .
Ag15 Ag6 Ag4A 105.1(3) . .
C37 Ag6 Ag1A 145.2(9) . .
C49 Ag6 Ag1A 44.4(8) . .
Ag15 Ag6 Ag1A 60.59(14) . .
Ag4A Ag6 Ag1A 164.0(3) . .
C37 Ag6 Ag1 46.3(8) . .
C49 Ag6 Ag1 147.1(8) . .
Ag14 Ag6 Ag1 92.6(2) . .
Ag15 Ag6 Ag1 117.66(11) . .
Ag4A Ag6 Ag1 89.10(16) . .
Ag1A Ag6 Ag1 103.7(2) . .
C25 Ag7 C31 175.6(13) . .
C25 Ag7 Ag11 124.9(9) . .
C31 Ag7 Ag11 57.1(10) . .
C25 Ag7 Ag13 50.1(10) . .
C31 Ag7 Ag13 133.7(11) . .
Ag11 Ag7 Ag13 113.62(11) . .
C25 Ag7 Ag14 134.6(10) . .
C31 Ag7 Ag14 49.8(10) . .
Ag11 Ag7 Ag14 54.8(2) . .
Ag13 Ag7 Ag14 86.4(3) . .
C25 Ag7 Ag9 43.9(9) . .
C31 Ag7 Ag9 137.4(11) . .
Ag11 Ag7 Ag9 81.42(10) . .
Ag13 Ag7 Ag9 69.09(9) . .
Ag14 Ag7 Ag9 115.4(2) . .
C13 Ag8 C55 156.6(11) . .
C13 Ag8 O6 106.3(9) . .
C55 Ag8 O6 94.0(10) . .
C13 Ag8 Ag13 125.3(8) . .
C55 Ag8 Ag13 47.3(8) . .
O6 Ag8 Ag13 120.3(4) . .
C13 Ag8 Ag4 46.4(9) . .
C55 Ag8 Ag4 140.8(8) . .
O6 Ag8 Ag4 102.2(4) . .
Ag13 Ag8 Ag4 94.31(10) . .
C13 Ag8 Ag15 163.0(8) . .
C55 Ag8 Ag15 40.3(7) . .
O6 Ag8 Ag15 61.0(4) . .
Ag13 Ag8 Ag15 61.57(9) . .
Ag4 Ag8 Ag15 121.97(11) . .
C25 Ag9 C19 155.3(12) . .
C25 Ag9 O18 98.6(10) . .
C19 Ag9 O18 104.3(10) . .
C25 Ag9 C26 27.1(5) . .
C19 Ag9 C26 128.7(11) . .
O18 Ag9 C26 119.6(9) . .
C25 Ag9 Cl1 90.5(9) . .
C19 Ag9 Cl1 98.0(8) . .
O18 Ag9 Cl1 90.7(5) . .
C26 Ag9 Cl1 106.0(8) . .
C25 Ag9 Ag4 116.9(9) . .
C19 Ag9 Ag4 47.5(8) . .
O18 Ag9 Ag4 138.0(5) . .
C26 Ag9 Ag4 101.5(7) . .
Cl1 Ag9 Ag4 68.46(16) . .
C25 Ag9 Ag5 152.8(8) . .
C19 Ag9 Ag5 45.4(8) . .
O18 Ag9 Ag5 76.8(5) . .
C26 Ag9 Ag5 161.6(8) . .
Cl1 Ag9 Ag5 62.99(16) . .
Ag4 Ag9 Ag5 61.33(8) . .
C25 Ag9 Ag7 40.9(8) . .
C19 Ag9 Ag7 163.1(8) . .
O18 Ag9 Ag7 63.9(6) . .
C26 Ag9 Ag7 67.9(7) . .
Cl1 Ag9 Ag7 71.15(16) . .
Ag4 Ag9 Ag7 133.02(11) . .
Ag5 Ag9 Ag7 117.85(10) . .
C50 Ag10 C49 30.3(10) . .
C50 Ag10 O4 148.0(12) . .
C49 Ag10 O4 139.5(17) . .
C50 Ag10 O2 139.2(13) . .
C49 Ag10 O2 130.7(13) . .
O4 Ag10 O2 72.7(7) . .
C49 Ag1A O4 147.9(10) . .
C49 Ag1A O2 138.6(10) . .
O4 Ag1A O2 72.3(6) . .
C49 Ag1A C50 29.1(11) . .
O4 Ag1A C50 133.2(11) . .
O2 Ag1A C50 128.2(10) . .
C49 Ag1A Ag15 44.4(9) . .
O4 Ag1A Ag15 113.5(5) . .
O2 Ag1A Ag15 154.8(7) . .
C50 Ag1A Ag15 67.1(8) . .
C49 Ag1A Ag6 42.9(9) . .
O4 Ag1A Ag6 155.7(7) . .
O2 Ag1A Ag6 107.1(5) . .
C50 Ag1A Ag6 67.0(8) . .
Ag15 Ag1A Ag6 57.01(19) . .
C49 Ag1A Ag2 107.3(10) . .
O4 Ag1A Ag2 81.6(5) . .
O2 Ag1A Ag2 81.7(5) . .
C50 Ag1A Ag2 136.4(9) . .
Ag15 Ag1A Ag2 75.3(3) . .
Ag6 Ag1A Ag2 74.4(3) . .
O17 Ag11 O18 74.3(9) . .
O17 Ag11 C31 100.4(12) . .
O18 Ag11 C31 98.0(10) . .
O17 Ag11 C37 117.9(10) . .
O18 Ag11 C37 151.8(9) . .
C31 Ag11 C37 103.9(11) . .
O17 Ag11 Ag4A 121.7(8) . .
O18 Ag11 Ag4A 145.8(6) . .
C31 Ag11 Ag4A 51.8(8) . .
C37 Ag11 Ag4A 52.1(7) . .
O17 Ag11 Ag14 138.5(9) . .
O18 Ag11 Ag14 134.2(7) . .
C31 Ag11 Ag14 53.6(9) . .
C37 Ag11 Ag14 54.4(8) . .
O17 Ag11 Ag7 120.0(7) . .
O18 Ag11 Ag7 68.3(6) . .
C31 Ag11 Ag7 44.2(7) . .
C37 Ag11 Ag7 117.3(8) . .
Ag4A Ag11 Ag7 77.8(2) . .
Ag14 Ag11 Ag7 66.8(3) . .
O17 Ag11 Ag1 108.8(8) . .
O18 Ag11 Ag1 104.8(5) . .
C31 Ag11 Ag1 146.7(9) . .
C37 Ag11 Ag1 48.2(7) . .
Ag4A Ag11 Ag1 98.05(17) . .
Ag14 Ag11 Ag1 93.4(2) . .
Ag7 Ag11 Ag1 124.87(13) . .
C13 Ag12 C14 29.3(10) . .
C13 Ag12 O12 132.8(10) . .
C14 Ag12 O12 145.9(8) . .
C13 Ag12 O7 138.2(10) . .
C14 Ag12 O7 108.9(10) . .
O12 Ag12 O7 78.9(8) . .
C13 Ag12 O5 127.2(10) . .
C14 Ag12 O5 140.5(9) . .
O12 Ag12 O5 72.1(6) . .
O7 Ag12 O5 83.7(8) . .
C13 Ag12 Ag4 39.2(8) . .
C14 Ag12 Ag4 61.4(8) . .
O12 Ag12 Ag4 93.6(4) . .
O7 Ag12 Ag4 147.2(8) . .
O5 Ag12 Ag4 124.6(4) . .
C13 Ag12 Bi3 161.3(9) . .
C14 Ag12 Bi3 168.8(8) . .
O12 Ag12 Bi3 40.0(4) . .
O7 Ag12 Bi3 60.3(5) . .
O5 Ag12 Bi3 40.3(4) . .
Ag4 Ag12 Bi3 129.19(10) . .
C55 Ag13 C25 164.5(12) . .
C55 Ag13 C26 139.9(11) . .
C25 Ag13 C26 26.0(6) . .
C55 Ag13 Ag8 49.4(9) . .
C25 Ag13 Ag8 117.8(8) . .
C26 Ag13 Ag8 103.7(7) . .
C55 Ag13 Ag7 150.7(9) . .
C25 Ag13 Ag7 43.8(7) . .
C26 Ag13 Ag7 69.3(7) . .
Ag8 Ag13 Ag7 137.55(13) . .
C55 Ag13 Ag15 41.0(8) . .
C25 Ag13 Ag15 147.6(8) . .
C26 Ag13 Ag15 162.1(7) . .
Ag8 Ag13 Ag15 63.27(9) . .
Ag7 Ag13 Ag15 111.13(12) . .
C31 Ag14 C37 110.2(13) . .
C31 Ag14 Ag6 150.1(9) . .
C37 Ag14 Ag6 48.7(8) . .
C31 Ag14 Ag11 56.9(9) . .
C37 Ag14 Ag11 57.9(8) . .
Ag6 Ag14 Ag11 94.2(3) . .
C31 Ag14 Ag7 41.3(7) . .
C37 Ag14 Ag7 112.7(8) . .
Ag6 Ag14 Ag7 120.0(5) . .
Ag11 Ag14 Ag7 58.44(19) . .
C31 Ag4A C37 117.4(12) . .
C31 Ag4A C32 28.1(4) . .
C37 Ag4A C32 131.0(13) . .
C31 Ag4A Ag11 58.1(9) . .
C37 Ag4A Ag11 59.3(8) . .
C32 Ag4A Ag11 76.9(9) . .
C31 Ag4A Ag6 130.4(9) . .
C37 Ag4A Ag6 43.8(8) . .
C32 Ag4A Ag6 158.5(8) . .
Ag11 Ag4A Ag6 86.4(3) . .
C55 Ag15 C49 164.8(12) . .
C55 Ag15 Ag6 147.2(9) . .
C49 Ag15 Ag6 46.0(9) . .
C55 Ag15 Ag1A 138.5(9) . .
C49 Ag15 Ag1A 45.5(8) . .
Ag6 Ag15 Ag1A 62.40(19) . .
C55 Ag15 Ag13 43.4(9) . .
C49 Ag15 Ag13 146.1(9) . .
Ag6 Ag15 Ag13 104.08(11) . .
Ag1A Ag15 Ag13 145.0(3) . .
C55 Ag15 Ag8 44.4(9) . .
C49 Ag15 Ag8 146.2(8) . .
Ag6 Ag15 Ag8 119.84(11) . .
Ag1A Ag15 Ag8 101.44(18) . .
Ag13 Ag15 Ag8 55.16(8) . .
Ag2 Cl1 Ag9 125.4(3) . .
O6 P1 O4 110.9(11) . .
O6 P1 O5 111.2(11) . .
O4 P1 O5 111.5(10) . .
O6 P1 C1 109.7(13) . .
O4 P1 C1 105.8(12) . .
O5 P1 C1 107.4(12) . .
O3 P2 O1 110.6(10) . .
O3 P2 O2 110.5(10) . .
O1 P2 O2 112.8(10) . .
O3 P2 C5 110.7(11) . .
O1 P2 C5 104.3(11) . .
O2 P2 C5 107.8(11) . .
O11 P3 O12 111.6(11) . .
O11 P3 O10 110.2(10) . .
O12 P3 O10 111.7(10) . .
O11 P3 C9 109.5(12) . .
O12 P3 C9 107.2(12) . .
O10 P3 C9 106.5(12) . .
P2 O1 Bi2 140.1(10) . .
P2 O1 Ag3 110.1(9) . .
Bi2 O1 Ag3 100.4(6) . .
P2 O2 Bi1 135.3(10) . .
P2 O2 Ag1A 101.4(9) . .
Bi1 O2 Ag1A 103.4(7) . .
P2 O2 Ag10 113.9(12) . .
Bi1 O2 Ag10 98.1(7) . .
P2 O3 Ag2 113.6(9) . .
P2 O3 Ag1 132.4(10) . .
Ag2 O3 Ag1 89.0(5) . .
P1 O4 Bi1 138.0(11) . .
P1 O4 Ag10 112.1(13) . .
Bi1 O4 Ag10 99.5(8) . .
P1 O4 Ag1A 100.5(10) . .
Bi1 O4 Ag1A 104.2(7) . .
P1 O5 Bi3 137.6(10) . .
P1 O5 Ag12 116.1(9) . .
Bi3 O5 Ag12 96.3(7) . .
P1 O6 Ag2 117.4(10) . .
P1 O6 Ag8 134.8(10) . .
Ag2 O6 Ag8 91.9(6) . .
C72 O7 Ag12 143(3) . .
C72 O8 Bi3 113(2) . .
P3 O10 Bi2 137.8(11) . .
P3 O10 Ag3 110.7(9) . .
Bi2 O10 Ag3 99.5(6) . .
P3 O11 Ag2 114.0(10) . .
P3 O11 Ag4 136.3(10) . .
Ag2 O11 Ag4 92.4(6) . .
P3 O12 Bi3 140.2(10) . .
P3 O12 Ag12 115.3(9) . .
Bi3 O12 Ag12 97.1(7) . .
Bi3 O13 Bi2 102.9(5) . .
Bi3 O13 Bi1 113.1(6) . 7_655
Bi2 O13 Bi1 112.0(6) . 7_655
Bi1 O14 Bi3 117.1(7) . .
Bi1 O14 Bi2 115.5(6) . .
Bi3 O14 Bi2 115.5(6) . .
Bi1 O15 Bi3 102.2(6) 7_655 7_655
Bi1 O15 Bi2 114.1(5) 7_655 .
Bi3 O15 Bi2 110.7(5) 7_655 .
Bi1 O16 Bi2 102.4(5) 7_655 7_655
Bi1 O16 Bi3 112.8(5) 7_655 .
Bi2 O16 Bi3 113.4(6) 7_655 .
C69 O17 Ag11 127(3) . .
C67 O18 Ag11 120(2) . .
C67 O18 Ag9 130(2) . .
Ag11 O18 Ag9 103.5(8) . .
C62 O19 Ag3 128(2) . .
C62 O19 Bi2 134(3) . .
Ag3 O19 Bi2 86.4(6) . .
C64 O20 Bi2 149(3) . .
C3 C1 C2 113(3) . .
C3 C1 C4 113(3) . .
C2 C1 C4 108(3) . .
C3 C1 P1 108(2) . .
C2 C1 P1 108(2) . .
C4 C1 P1 107(2) . .
C1 C2 H2A 109.5 . .
C1 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
C1 C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
C1 C3 H3A 109.5 . .
C1 C3 H3B 109.5 . .
H3A C3 H3B 109.5 . .
C1 C3 H3C 109.5 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
C1 C4 H4A 109.5 . .
C1 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C1 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C6 C5 C8 113(3) . .
C6 C5 C7 109(2) . .
C8 C5 C7 110(2) . .
C6 C5 P2 110.7(18) . .
C8 C5 P2 108.4(18) . .
C7 C5 P2 104.8(19) . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C5 C7 H7A 109.5 . .
C5 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C5 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C5 C8 H8A 109.5 . .
C5 C8 H8B 109.5 . .
H8A C8 H8B 109.5 . .
C5 C8 H8C 109.5 . .
H8A C8 H8C 109.5 . .
H8B C8 H8C 109.5 . .
C11 C9 C10 111(3) . .
C11 C9 C12 110(3) . .
C10 C9 C12 112(2) . .
C11 C9 P3 109(2) . .
C10 C9 P3 107(2) . .
C12 C9 P3 108(2) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C9 C11 H11A 109.5 . .
C9 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C9 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C9 C12 H12A 109.5 . .
C9 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C9 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C14 C13 Ag8 141(3) . .
C14 C13 Ag4 130(3) . .
Ag8 C13 Ag4 88.2(13) . .
C14 C13 Ag12 81(2) . .
Ag8 C13 Ag12 102.9(12) . .
Ag4 C13 Ag12 98.7(12) . .
C13 C14 C15 171(3) . .
C13 C14 Ag12 69.3(19) . .
C15 C14 Ag12 119(2) . .
C16 C15 C18 113(4) . .
C16 C15 C17 99(5) . .
C18 C15 C17 115(5) . .
C16 C15 C14 113(4) . .
C18 C15 C14 109(4) . .
C17 C15 C14 107(4) . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C15 C17 H17A 109.5 . .
C15 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C15 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C15 C18 H18A 109.5 . .
C15 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C15 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C20 C19 Ag5 137(3) . .
C20 C19 Ag4 120(3) . .
Ag5 C19 Ag4 89.1(11) . .
C20 C19 Ag9 123(3) . .
Ag5 C19 Ag9 87.8(11) . .
Ag4 C19 Ag9 84.0(11) . .
C19 C20 C21 174(4) . .
C20 C21 C24 108(3) . .
C20 C21 C23 108(3) . .
C24 C21 C23 109(2) . .
C20 C21 C22 113(3) . .
C24 C21 C22 109(2) . .
C23 C21 C22 109(2) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C21 C23 H23A 109.5 . .
C21 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C21 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C21 C24 H24A 109.5 . .
C21 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C21 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C26 C25 Ag7 167(3) . .
C26 C25 Ag9 97(3) . .
Ag7 C25 Ag9 95.3(13) . .
C26 C25 Ag13 97(3) . .
Ag7 C25 Ag13 86.1(12) . .
Ag9 C25 Ag13 101.7(12) . .
C25 C26 C27 175(4) . .
C25 C26 Ag9 56(2) . .
C27 C26 Ag9 125(2) . .
C25 C26 Ag13 57(2) . .
C27 C26 Ag13 128(3) . .
Ag9 C26 Ag13 81.5(8) . .
C30 C27 C26 108(3) . .
C30 C27 C28 114(3) . .
C26 C27 C28 110(3) . .
C30 C27 C29 109(3) . .
C26 C27 C29 107(3) . .
C28 C27 C29 108(3) . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C27 C29 H29A 109.5 . .
C27 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C27 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C27 C30 H30A 109.5 . .
C27 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C27 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C32 C31 Ag7 158(3) . .
C32 C31 Ag4A 86(3) . .
Ag7 C31 Ag4A 108.8(14) . .
C32 C31 Ag14 104(3) . .
Ag7 C31 Ag14 89.0(13) . .
C32 C31 Ag11 123(3) . .
Ag7 C31 Ag11 78.6(10) . .
Ag4A C31 Ag11 70.1(9) . .
Ag14 C31 Ag11 69.6(9) . .
C31 C32 C33 169(4) . .
C31 C32 Ag4A 66(2) . .
C33 C32 Ag4A 120(3) . .
C34 C33 C32 115(4) . .
C34 C33 C36 111(5) . .
C32 C33 C36 102(4) . .
C34 C33 C35 114(4) . .
C32 C33 C35 108(3) . .
C36 C33 C35 105(4) . .
C33 C34 H34A 109.5 . .
C33 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
C33 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
C33 C35 H35A 109.5 . .
C33 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C33 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
C33 C36 H36A 109.5 . .
C33 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
C33 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
C38 C37 Ag6 154(3) . .
C38 C37 Ag1 86(2) . .
Ag6 C37 Ag1 92.6(11) . .
C38 C37 Ag4A 112(3) . .
Ag6 C37 Ag4A 85.7(12) . .
Ag1 C37 Ag4A 139.3(14) . .
C38 C37 Ag14 131(3) . .
Ag6 C37 Ag14 70.0(11) . .
Ag1 C37 Ag14 124.9(14) . .
C38 C37 Ag11 88(3) . .
Ag6 C37 Ag11 116.8(13) . .
Ag1 C37 Ag11 76.2(9) . .
Ag4A C37 Ag11 68.6(8) . .
Ag14 C37 Ag11 67.7(8) . .
C37 C38 C39 165(4) . .
C37 C38 Ag1 66(2) . .
C39 C38 Ag1 127(2) . .
C40 C39 C42 115(4) . .
C40 C39 C38 113(3) . .
C42 C39 C38 109(3) . .
C40 C39 C41 109(3) . .
C42 C39 C41 107(3) . .
C38 C39 C41 103(3) . .
C39 C40 H40A 109.5 . .
C39 C40 H40B 109.5 . .
H40A C40 H40B 109.5 . .
C39 C40 H40C 109.5 . .
H40A C40 H40C 109.5 . .
H40B C40 H40C 109.5 . .
C39 C41 H41A 109.5 . .
C39 C41 H41B 109.5 . .
H41A C41 H41B 109.5 . .
C39 C41 H41C 109.5 . .
H41A C41 H41C 109.5 . .
H41B C41 H41C 109.5 . .
C39 C42 H42A 109.5 . .
C39 C42 H42B 109.5 . .
H42A C42 H42B 109.5 . .
C39 C42 H42C 109.5 . .
H42A C42 H42C 109.5 . .
H42B C42 H42C 109.5 . .
C44 C43 Ag3 132(3) . .
C44 C43 Ag1 141(3) . .
Ag3 C43 Ag1 86.0(8) . .
C44 C43 Ag5 86(2) . .
Ag3 C43 Ag5 99.6(11) . .
Ag1 C43 Ag5 94.4(11) . .
C43 C44 C45 171(3) . .
C43 C44 Ag5 65(2) . .
C45 C44 Ag5 124(2) . .
C48 C45 C46 111.1(17) . .
C48 C45 C47 110.2(17) . .
C46 C45 C47 109.7(17) . .
C48 C45 C44 108(3) . .
C46 C45 C44 107(3) . .
C47 C45 C44 111(3) . .
C45 C46 H46A 109.5 . .
C45 C46 H46B 109.5 . .
H46A C46 H46B 109.5 . .
C45 C46 H46C 109.5 . .
H46A C46 H46C 109.5 . .
H46B C46 H46C 109.5 . .
C45 C47 H47A 109.5 . .
C45 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
C45 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
C45 C48 H48A 109.5 . .
C45 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C45 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C50 C49 Ag6 139(3) . .
C50 C49 Ag15 134(3) . .
Ag6 C49 Ag15 87.4(13) . .
C50 C49 Ag1A 89(2) . .
Ag6 C49 Ag1A 92.6(12) . .
Ag15 C49 Ag1A 90.1(12) . .
C50 C49 Ag10 73(2) . .
Ag6 C49 Ag10 104.7(14) . .
Ag15 C49 Ag10 101.3(15) . .
C49 C50 C51 166(4) . .
C49 C50 Ag10 77(2) . .
C51 C50 Ag10 117(2) . .
C49 C50 Ag1A 62(2) . .
C51 C50 Ag1A 132(2) . .
C50 C51 C53 115(3) . .
C50 C51 C52 109(3) . .
C53 C51 C52 110.7(19) . .
C50 C51 C54 101(3) . .
C53 C51 C54 111(2) . .
C52 C51 C54 110.7(19) . .
C51 C52 H52A 109.5 . .
C51 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
C51 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
C51 C53 H53A 109.5 . .
C51 C53 H53B 109.5 . .
H53A C53 H53B 109.5 . .
C51 C53 H53C 109.5 . .
H53A C53 H53C 109.5 . .
H53B C53 H53C 109.5 . .
C51 C54 H54A 109.5 . .
C51 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
C51 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
C56 C55 Ag15 137(3) . .
C56 C55 Ag13 113(3) . .
Ag15 C55 Ag13 95.6(11) . .
C56 C55 Ag8 118(3) . .
Ag15 C55 Ag8 95.3(10) . .
Ag13 C55 Ag8 83.3(12) . .
C55 C56 C57 156(4) . .
C58 C57 C59 112.1(19) . .
C58 C57 C56 111(3) . .
C59 C57 C56 102(3) . .
C58 C57 C60 110.5(19) . .
C59 C57 C60 110.7(19) . .
C56 C57 C60 110(4) . .
C57 C58 H58A 109.5 . .
C57 C58 H58B 109.5 . .
H58A C58 H58B 109.5 . .
C57 C58 H58C 109.5 . .
H58A C58 H58C 109.5 . .
H58B C58 H58C 109.5 . .
C57 C59 H59A 109.5 . .
C57 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
C57 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
C57 C60 H60A 109.5 . .
C57 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
C57 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
F7 C61 F8 110(2) . .
F7 C61 F9 110(2) . .
F8 C61 F9 109(2) . .
F7 C61 C62 109(2) . .
F8 C61 C62 110(2) . .
F9 C61 C62 109(2) . .
O19 C62 C61 112(3) . .
O19 C62 C63 137(4) . .
C61 C62 C63 110(2) . .
C62 C63 C64 118(3) . .
C62 C63 H63 121.2 . .
C64 C63 H63 121.2 . .
O20 C64 C63 118(4) . .
O20 C64 C65 122(3) . .
C63 C64 C65 120(2) . .
F11 C65 F10 114.7(18) . .
F11 C65 F12 115(2) . .
F10 C65 F12 115(2) . .
F11 C65 C64 103(2) . .
F10 C65 C64 103(2) . .
F12 C65 C64 103(2) . .
F2 C66 F1 103.6(19) . .
F2 C66 F3 104.4(19) . .
F1 C66 F3 104(2) . .
F2 C66 C67 119(2) . .
F1 C66 C67 111(2) . .
F3 C66 C67 113(3) . .
O18 C67 C68 137(3) . .
O18 C67 C66 113(3) . .
C68 C67 C66 110(3) . .
C67 C68 C69 110(3) . .
C67 C68 H68 124.9 . .
C69 C68 H68 124.9 . .
O17 C69 C70 128(3) . .
O17 C69 C68 132(3) . .
C70 C69 C68 99(3) . .
F5 C70 F6 103(2) . .
F5 C70 F4 103(2) . .
F6 C70 F4 103(2) . .
F5 C70 C69 113(3) . .
F6 C70 C69 125(3) . .
F4 C70 C69 108(3) . .
F13 C71 F15 115(2) . .
F13 C71 F14 114(2) . .
F15 C71 F14 113(2) . .
F13 C71 C72 103(3) . .
F15 C71 C72 106(3) . .
F14 C71 C72 103(4) . .
O8 C72 O7 112(3) . .
O8 C72 C71 115(4) . .
O7 C72 C71 131(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Bi1 O14 2.134(15) .
Bi1 O4 2.285(17) .
Bi1 O2 2.285(17) .
Bi1 O15 2.328(15) 7_655
Bi1 O16 2.355(15) 7_655
Bi1 O13 2.613(14) 7_655
Bi1 Bi3 3.6691(14) .
Bi1 Bi2 3.6865(14) .
Bi2 O14 2.225(15) .
Bi2 O1 2.248(16) .
Bi2 O10 2.282(17) .
Bi2 O16 2.377(13) 7_655
Bi2 O13 2.433(15) .
Bi2 O15 2.654(15) .
Bi2 O19 2.69(2) .
Bi2 O20 2.74(2) .
Bi3 O14 2.168(14) .
Bi3 O12 2.268(17) .
Bi3 O5 2.278(18) .
Bi3 O13 2.318(15) .
Bi3 O15 2.385(13) 7_655
Bi3 O16 2.586(14) .
Bi3 O8 2.69(2) .
Bi3 Ag12 3.503(3) .
Ag1 C43 2.15(3) .
Ag1 C37 2.31(3) .
Ag1 C38 2.51(3) .
Ag1 O3 2.557(18) .
Ag1 Ag3 2.930(3) .
Ag1 Ag11 3.004(4) .
Ag1 Ag6 3.185(3) .
Ag1 Ag5 3.210(3) .
Ag2 O11 2.324(18) .
Ag2 O6 2.335(18) .
Ag2 O3 2.368(16) .
Ag2 Cl1 2.673(8) .
Ag2 Ag1A 3.148(14) .
Ag2 Ag3 3.365(3) .
Ag3 C43 2.15(3) .
Ag3 O10 2.417(18) .
Ag3 O1 2.420(17) .
Ag3 O19 2.55(2) .
Ag3 Ag5 3.342(3) .
Ag4 C13 2.14(3) .
Ag4 C19 2.18(3) .
Ag4 O11 2.560(17) .
Ag4 Ag9 2.947(3) .
Ag4 Ag8 2.953(4) .
Ag4 Ag5 3.055(3) .
Ag4 Ag12 3.342(4) .
Ag5 C19 2.17(3) .
Ag5 C43 2.23(3) .
Ag5 C44 2.46(3) .
Ag5 Ag9 3.041(4) .
Ag6 C37 2.10(3) .
Ag6 C49 2.12(3) .
Ag6 Ag14 2.622(11) .
Ag6 Ag15 2.941(4) .
Ag6 Ag4A 3.022(10) .
Ag6 Ag1A 3.107(11) .
Ag7 C25 2.06(3) .
Ag7 C31 2.07(3) .
Ag7 Ag11 2.908(4) .
Ag7 Ag13 2.976(4) .
Ag7 Ag14 3.136(11) .
Ag7 Ag9 3.141(4) .
Ag8 C13 2.10(3) .
Ag8 C55 2.24(3) .
Ag8 O6 2.517(18) .
Ag8 Ag13 2.926(4) .
Ag8 Ag15 3.184(4) .
Ag9 C25 2.19(3) .
Ag9 C19 2.22(3) .
Ag9 O18 2.54(2) .
Ag9 C26 2.61(3) .
Ag9 Cl1 2.915(7) .
Ag10 C50 2.26(3) .
Ag10 C49 2.31(4) .
Ag10 O4 2.40(2) .
Ag10 O2 2.45(2) .
Ag1A C49 2.18(3) .
Ag1A O4 2.42(2) .
Ag1A O2 2.445(18) .
Ag1A C50 2.46(3) .
Ag1A Ag15 3.055(9) .
Ag11 O17 2.33(3) .
Ag11 O18 2.49(2) .
Ag11 C31 2.49(3) .
Ag11 C37 2.55(3) .
Ag11 Ag4A 2.761(8) .
Ag11 Ag14 2.788(10) .
Ag12 C13 2.26(3) .
Ag12 C14 2.39(3) .
Ag12 O12 2.402(18) .
Ag12 O7 2.42(3) .
Ag12 O5 2.423(18) .
Ag13 C55 2.16(3) .
Ag13 C25 2.29(4) .
Ag13 C26 2.71(4) .
Ag13 Ag15 3.135(4) .
Ag14 C31 2.39(4) .
Ag14 C37 2.45(3) .
Ag4A C31 2.31(3) .
Ag4A C37 2.34(3) .
Ag4A C32 2.53(4) .
Ag15 C55 2.07(3) .
Ag15 C49 2.14(3) .
P1 O6 1.522(19) .
P1 O4 1.545(18) .
P1 O5 1.55(2) .
P1 C1 1.87(3) .
P2 O3 1.540(18) .
P2 O1 1.543(18) .
P2 O2 1.545(19) .
P2 C5 1.85(3) .
P3 O11 1.516(19) .
P3 O12 1.52(2) .
P3 O10 1.551(19) .
P3 C9 1.85(3) .
F1 C66 1.370(19) .
F2 C66 1.366(18) .
F3 C66 1.370(19) .
F4 C70 1.370(19) .
F5 C70 1.351(19) .
F6 C70 1.368(19) .
F7 C61 1.38(2) .
F8 C61 1.379(19) .
F9 C61 1.38(2) .
F10 C65 1.39(2) .
F11 C65 1.38(2) .
F12 C65 1.39(2) .
F13 C71 1.35(2) .
F14 C71 1.38(2) .
F15 C71 1.36(2) .
O7 C72 1.43(5) .
O8 C72 1.29(5) .
O13 Bi1 2.613(14) 7_655
O15 Bi1 2.328(15) 7_655
O15 Bi3 2.385(13) 7_655
O16 Bi1 2.355(15) 7_655
O16 Bi2 2.377(13) 7_655
O17 C69 1.11(4) .
O18 C67 1.23(3) .
O19 C62 1.220(18) .
O20 C64 1.225(18) .
C1 C3 1.39(4) .
C1 C2 1.50(4) .
C1 C4 1.53(4) .
C2 H2A 0.9600 .
C2 H2B 0.9600 .
C2 H2C 0.9600 .
C3 H3A 0.9600 .
C3 H3B 0.9600 .
C3 H3C 0.9600 .
C4 H4A 0.9600 .
C4 H4B 0.9600 .
C4 H4C 0.9600 .
C5 C6 1.48(4) .
C5 C8 1.49(4) .
C5 C7 1.61(4) .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 H8A 0.9600 .
C8 H8B 0.9600 .
C8 H8C 0.9600 .
C9 C11 1.49(4) .
C9 C10 1.49(4) .
C9 C12 1.50(4) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 C14 1.18(4) .
C14 C15 1.56(5) .
C15 C16 1.44(5) .
C15 C18 1.47(5) .
C15 C17 1.55(7) .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 H17A 0.9600 .
C17 H17B 0.9600 .
C17 H17C 0.9600 .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 C20 1.21(4) .
C20 C21 1.47(4) .
C21 C24 1.52(2) .
C21 C23 1.53(2) .
C21 C22 1.53(2) .
C22 H22A 0.9600 .
C22 H22B 0.9600 .
C22 H22C 0.9600 .
C23 H23A 0.9600 .
C23 H23B 0.9600 .
C23 H23C 0.9600 .
C24 H24A 0.9600 .
C24 H24B 0.9600 .
C24 H24C 0.9600 .
C25 C26 1.196(10) .
C26 C27 1.53(4) .
C27 C30 1.50(5) .
C27 C28 1.53(4) .
C27 C29 1.56(5) .
C28 H28A 0.9600 .
C28 H28B 0.9600 .
C28 H28C 0.9600 .
C29 H29A 0.9600 .
C29 H29B 0.9600 .
C29 H29C 0.9600 .
C30 H30A 0.9600 .
C30 H30B 0.9600 .
C30 H30C 0.9600 .
C31 C32 1.196(10) .
C32 C33 1.48(5) .
C33 C34 1.46(6) .
C33 C36 1.52(2) .
C33 C35 1.53(5) .
C34 H34A 0.9600 .
C34 H34B 0.9600 .
C34 H34C 0.9600 .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
C36 H36A 0.9600 .
C36 H36B 0.9600 .
C36 H36C 0.9600 .
C37 C38 1.18(4) .
C38 C39 1.58(5) .
C39 C40 1.49(5) .
C39 C42 1.53(5) .
C39 C41 1.59(4) .
C40 H40A 0.9600 .
C40 H40B 0.9600 .
C40 H40C 0.9600 .
C41 H41A 0.9600 .
C41 H41B 0.9600 .
C41 H41C 0.9600 .
C42 H42A 0.9600 .
C42 H42B 0.9600 .
C42 H42C 0.9600 .
C43 C44 1.203(10) .
C44 C45 1.551(19) .
C45 C48 1.523(19) .
C45 C46 1.530(19) .
C45 C47 1.538(19) .
C46 H46A 0.9600 .
C46 H46B 0.9600 .
C46 H46C 0.9600 .
C47 H47A 0.9600 .
C47 H47B 0.9600 .
C47 H47C 0.9600 .
C48 H48A 0.9600 .
C48 H48B 0.9600 .
C48 H48C 0.9600 .
C49 C50 1.20(4) .
C50 C51 1.531(19) .
C51 C53 1.53(2) .
C51 C52 1.54(2) .
C51 C54 1.54(2) .
C52 H52A 0.9600 .
C52 H52B 0.9600 .
C52 H52C 0.9600 .
C53 H53A 0.9600 .
C53 H53B 0.9600 .
C53 H53C 0.9600 .
C54 H54A 0.9600 .
C54 H54B 0.9600 .
C54 H54C 0.9600 .
C55 C56 1.195(10) .
C56 C57 1.538(19) .
C57 C58 1.53(2) .
C57 C59 1.54(2) .
C57 C60 1.55(2) .
C58 H58A 0.9600 .
C58 H58B 0.9600 .
C58 H58C 0.9600 .
C59 H59A 0.9600 .
C59 H59B 0.9600 .
C59 H59C 0.9600 .
C60 H60A 0.9600 .
C60 H60B 0.9600 .
C60 H60C 0.9600 .
C61 C62 1.52(2) .
C62 C63 1.52(2) .
C63 C64 1.52(2) .
C63 H63 0.9300 .
C64 C65 1.53(2) .
C66 C67 1.526(19) .
C67 C68 1.523(19) .
C68 C69 1.533(19) .
C68 H68 0.9300 .
C69 C70 1.514(19) .
C71 C72 1.53(2) .
