#------------------------------------------------------------------------------
#$Date: 2019-11-17 11:39:28 +0200 (Sun, 17 Nov 2019) $
#$Revision: 229647 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/80/7048012.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7048012
loop_
_publ_author_name
'LaPierre, Etienne A.'
'Piers, Warren E.'
'Gendy, Chris'
_publ_section_title
;
 Redox-state dependent activation of silanes and ammonia with reverse
 polarity (PCcarbeneP)Ni complexes: electrophilic vs.
 nucleophilic carbenes.
;
_journal_issue                   46
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              16789
_journal_page_last               16797
_journal_paper_doi               10.1039/c8dt04409k
_journal_volume                  47
_journal_year                    2018
_chemical_formula_moiety         'C28 H45 N2 Ni P2, F6 Sb'
_chemical_formula_sum            'C28 H45 F6 N2 Ni P2 Sb'
_chemical_formula_weight         766.06
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2018-08-22 deposited with the CCDC.
2018-11-07 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 101.9790(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   10.9965(3)
_cell_length_b                   16.1517(4)
_cell_length_c                   18.8351(4)
_cell_measurement_reflns_used    9968
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.51
_cell_measurement_theta_min      2.55
_cell_volume                     3272.49(14)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'LinXTL v. 5.9.1 (Spasyuk, 2009)'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0488
_diffrn_reflns_av_unetI/netI     0.0340
_diffrn_reflns_Laue_measured_fraction_full 0.992
_diffrn_reflns_Laue_measured_fraction_max 0.992
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            33471
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.992
_diffrn_reflns_theta_full        25.000
_diffrn_reflns_theta_max         25.000
_diffrn_reflns_theta_min         3.154
_exptl_absorpt_coefficient_mu    1.553
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6064
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sadabs (Sheldrick, 1996)'
_exptl_crystal_colour            Purple
_exptl_crystal_density_diffrn    1.555
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1560
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.25
_refine_diff_density_max         1.322
_refine_diff_density_min         -0.962
_refine_diff_density_rms         0.081
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     372
_refine_ls_number_reflns         5713
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.016
_refine_ls_R_factor_all          0.0434
_refine_ls_R_factor_gt           0.0315
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0377P)²+4.4682P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0727
_refine_ls_wR_factor_ref         0.0812
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4715
_reflns_number_total             5713
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8dt04409k2.cif
_cod_data_source_block           CGEL180219020_0m
_cod_depositor_comments
'Adding full bibliography for 7048006--7048012.cif.'
_cod_database_code               7048012
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
C1 C 0.6621(3) 0.62005(19) 0.38344(16) 0.0204(7) Uani 1 1 d . .
C2 C 0.6709(3) 0.6271(2) 0.46381(17) 0.0224(7) Uani 1 1 d . .
C3 C 0.7123(3) 0.5588(2) 0.50818(17) 0.0235(7) Uani 1 1 d . .
C4 C 0.7428(3) 0.4778(2) 0.47378(18) 0.0252(7) Uani 1 1 d . .
C5 C 0.8038(3) 0.4974(2) 0.40988(17) 0.0237(7) Uani 1 1 d . .
C6 C 0.7624(3) 0.5662(2) 0.36582(16) 0.0207(7) Uani 1 1 d . .
C7 C 0.6425(3) 0.7018(2) 0.49222(17) 0.0235(7) Uani 1 1 d . .
C8 C 0.6537(3) 0.7096(2) 0.56734(18) 0.0297(8) Uani 1 1 d . .
H8 H 0.6353 0.7596 0.5872 0.036 Uiso 1 1 calc R U
C9 C 0.6922(3) 0.6428(2) 0.61155(18) 0.0310(8) Uani 1 1 d . .
H9 H 0.6985 0.6475 0.6614 0.037 Uiso 1 1 calc R U
C10 C 0.7216(3) 0.5686(2) 0.58248(18) 0.0283(8) Uani 1 1 d . .
H10 H 0.7483 0.5242 0.6133 0.034 Uiso 1 1 calc R U
C11 C 0.8156(3) 0.5865(2) 0.30702(17) 0.0243(7) Uani 1 1 d . .
C12 C 0.9082(3) 0.5369(2) 0.29006(19) 0.0290(8) Uani 1 1 d . .
H12 H 0.9424 0.5491 0.2501 0.035 Uiso 1 1 calc R U
C13 C 0.9494(3) 0.4692(2) 0.3330(2) 0.0302(8) Uani 1 1 d . .
H13 H 1.0121 0.4361 0.3219 0.036 Uiso 1 1 calc R U
C14 C 0.8987(3) 0.4497(2) 0.39242(19) 0.0281(8) Uani 1 1 d . .
H14 H 0.9285 0.4041 0.4210 0.034 Uiso 1 1 calc R U
C15 C 0.6190(3) 0.4307(2) 0.44542(19) 0.0297(8) Uani 1 1 d . .
H15A H 0.5676 0.4623 0.4076 0.044 Uiso 1 1 calc R U
H15B H 0.5764 0.4228 0.4845 0.044 Uiso 1 1 calc R U
H15C H 0.6366 0.3778 0.4266 0.044 Uiso 1 1 calc R U
C16 C 0.8258(4) 0.4207(2) 0.52884(19) 0.0314(8) Uani 1 1 d . .
H16A H 0.8372 0.3690 0.5059 0.047 Uiso 1 1 calc R U
H16B H 0.7869 0.4109 0.5692 0.047 Uiso 1 1 calc R U
H16C H 0.9051 0.4466 0.5457 0.047 Uiso 1 1 calc R U
C17 C 0.7057(4) 0.8704(2) 0.46370(19) 0.0345(9) Uani 1 1 d . .
H17 H 0.6875 0.8835 0.5112 0.041 Uiso 1 1 calc R U
C18 C 0.8420(4) 0.8461(3) 0.4755(2) 0.0488(11) Uani 1 1 d . .
H18A H 0.8637 0.8359 0.4295 0.073 Uiso 1 1 calc R U
H18B H 0.8561 0.7969 0.5046 0.073 Uiso 1 1 calc R U
H18C H 0.8925 0.8903 0.4999 0.073 Uiso 1 1 calc R U
C19 C 0.6760(5) 0.9464(2) 0.4162(2) 0.0474(11) Uani 1 1 d . .
H19A H 0.7303 0.9908 0.4364 0.071 Uiso 1 1 calc R U
H19B H 0.5913 0.9624 0.4140 0.071 Uiso 1 1 calc R U
H19C H 0.6877 0.9340 0.3682 0.071 Uiso 1 1 calc R U
C20 C 0.4470(3) 0.8217(2) 0.42910(18) 0.0287(8) Uani 1 1 d . .
H20 H 0.4273 0.8658 0.3928 0.034 Uiso 1 1 calc R U
C21 C 0.4313(4) 0.8590(3) 0.5011(2) 0.0447(11) Uani 1 1 d . .
H21A H 0.3484 0.8801 0.4962 0.067 Uiso 1 1 calc R U
H21B H 0.4899 0.9032 0.5145 0.067 Uiso 1 1 calc R U
H21C H 0.4459 0.8171 0.5381 0.067 Uiso 1 1 calc R U
C22 C 0.3517(4) 0.7534(3) 0.4055(2) 0.0415(10) Uani 1 1 d . .
H22A H 0.3671 0.7087 0.4399 0.062 Uiso 1 1 calc R U
H22B H 0.3584 0.7334 0.3585 0.062 Uiso 1 1 calc R U
H22C H 0.2697 0.7749 0.4034 0.062 Uiso 1 1 calc R U
C23 C 0.8967(3) 0.7471(2) 0.2615(2) 0.0362(9) Uani 1 1 d . .
H23 H 0.9301 0.7314 0.2190 0.043 Uiso 1 1 calc R U
C24 C 0.9974(4) 0.7350(3) 0.3271(3) 0.0599(13) Uani 1 1 d . .
H24A H 1.0612 0.7757 0.3276 0.090 Uiso 1 1 calc R U
H24B H 1.0321 0.6806 0.3261 0.090 Uiso 1 1 calc R U
H24C H 0.9636 0.7409 0.3699 0.090 Uiso 1 1 calc R U
C25 C 0.8575(4) 0.8385(2) 0.2523(2) 0.0447(10) Uani 1 1 d . .
H25A H 0.8289 0.8567 0.2945 0.067 Uiso 1 1 calc R U
H25B H 0.7918 0.8445 0.2102 0.067 Uiso 1 1 calc R U
H25C H 0.9274 0.8715 0.2465 0.067 Uiso 1 1 calc R U
C26 C 0.7145(4) 0.6456(2) 0.16533(18) 0.0304(8) Uani 1 1 d . .
H26 H 0.7877 0.6186 0.1536 0.036 Uiso 1 1 calc R U
C27 C 0.6762(4) 0.7160(3) 0.1115(2) 0.0456(11) Uani 1 1 d . .
H27A H 0.6537 0.6938 0.0633 0.068 Uiso 1 1 calc R U
H27B H 0.7444 0.7538 0.1143 0.068 Uiso 1 1 calc R U
H27C H 0.6064 0.7447 0.1231 0.068 Uiso 1 1 calc R U
C28 C 0.6116(4) 0.5820(3) 0.1574(2) 0.0373(9) Uani 1 1 d . .
H28A H 0.5392 0.6068 0.1695 0.056 Uiso 1 1 calc R U
H28B H 0.6385 0.5364 0.1894 0.056 Uiso 1 1 calc R U
H28C H 0.5919 0.5625 0.1082 0.056 Uiso 1 1 calc R U
F1 F 0.1532(2) 0.44777(14) 0.22510(11) 0.0456(6) Uani 1 1 d . .
F2 F 0.3888(2) 0.49000(14) 0.23384(12) 0.0427(5) Uani 1 1 d . .
F3 F 0.3167(2) 0.63718(13) 0.17671(12) 0.0406(5) Uani 1 1 d . .
F4 F 0.2442(2) 0.58458(15) 0.29331(11) 0.0441(6) Uani 1 1 d . .
F5 F 0.2285(3) 0.49930(17) 0.10782(11) 0.0600(8) Uani 1 1 d . .
F6 F 0.0826(2) 0.59488(18) 0.16813(14) 0.0615(8) Uani 1 1 d . .
N1 N 0.5398(3) 0.60332(17) 0.34104(14) 0.0234(6) Uani 1 1 d . .
H1A H 0.4771 0.6029 0.3643 0.028 Uiso 1 1 calc R U
H1B H 0.5336 0.5658 0.3058 0.028 Uiso 1 1 calc R U
N2 N 0.4889(3) 0.77960(18) 0.25052(15) 0.0322(7) Uani 1 1 d . .
H2A H 0.4347 0.7444 0.2248 0.048 Uiso 1 1 calc R U
H2B H 0.5281 0.8071 0.2209 0.048 Uiso 1 1 calc R U
H2C H 0.4488 0.8153 0.2734 0.048 Uiso 1 1 calc R U
Ni1 Ni 0.61383(4) 0.71624(3) 0.32382(2) 0.02129(11) Uani 1 1 d . .
P1 P 0.60400(8) 0.78353(5) 0.42479(4) 0.02252(19) Uani 1 1 d . .
P2 P 0.75677(8) 0.68213(6) 0.26133(4) 0.0232(2) Uani 1 1 d . .
Sb1 Sb 0.23584(2) 0.54189(2) 0.20007(2) 0.02885(9) Uani 1 1 d . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
N1 C1 C6 114.5(3)
N1 C1 C2 115.5(3)
C6 C1 C2 111.8(3)
N1 C1 Ni1 73.45(17)
C6 C1 Ni1 117.8(2)
C2 C1 Ni1 118.6(2)
C7 C2 C3 121.9(3)
C7 C2 C1 118.9(3)
C3 C2 C1 119.1(3)
C10 C3 C2 117.3(3)
C10 C3 C4 123.1(3)
C2 C3 C4 119.6(3)
C3 C4 C5 109.1(3)
C3 C4 C16 112.3(3)
C5 C4 C16 111.0(3)
C3 C4 C15 108.2(3)
C5 C4 C15 109.1(3)
C16 C4 C15 107.0(3)
C14 C5 C6 117.8(3)
C14 C5 C4 123.0(3)
C6 C5 C4 119.2(3)
C11 C6 C5 121.1(3)
C11 C6 C1 119.3(3)
C5 C6 C1 119.5(3)
C2 C7 C8 119.3(3)
C2 C7 P1 113.7(2)
C8 C7 P1 126.9(3)
C9 C8 C7 119.6(3)
C9 C8 H8 120.2
C7 C8 H8 120.2
C8 C9 C10 120.5(3)
C8 C9 H9 119.7
C10 C9 H9 119.7
C9 C10 C3 121.5(3)
C9 C10 H10 119.3
C3 C10 H10 119.3
C12 C11 C6 119.8(3)
C12 C11 P2 126.0(3)
C6 C11 P2 114.1(2)
C13 C12 C11 119.4(3)
C13 C12 H12 120.3
C11 C12 H12 120.3
C12 C13 C14 121.0(3)
C12 C13 H13 119.5
C14 C13 H13 119.5
C13 C14 C5 120.8(3)
C13 C14 H14 119.6
C5 C14 H14 119.6
C4 C15 H15A 109.5
C4 C15 H15B 109.5
H15A C15 H15B 109.5
C4 C15 H15C 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
C4 C16 H16A 109.5
C4 C16 H16B 109.5
H16A C16 H16B 109.5
C4 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
C19 C17 C18 112.3(4)
C19 C17 P1 110.1(3)
C18 C17 P1 111.1(3)
C19 C17 H17 107.7
C18 C17 H17 107.7
P1 C17 H17 107.7
C17 C18 H18A 109.5
C17 C18 H18B 109.5
H18A C18 H18B 109.5
C17 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
C17 C19 H19A 109.5
C17 C19 H19B 109.5
H19A C19 H19B 109.5
C17 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
C22 C20 C21 110.3(3)
C22 C20 P1 109.7(2)
C21 C20 P1 116.7(3)
C22 C20 H20 106.5
C21 C20 H20 106.5
P1 C20 H20 106.5
C20 C21 H21A 109.5
C20 C21 H21B 109.5
H21A C21 H21B 109.5
C20 C21 H21C 109.5
H21A C21 H21C 109.5
H21B C21 H21C 109.5
C20 C22 H22A 109.5
C20 C22 H22B 109.5
H22A C22 H22B 109.5
C20 C22 H22C 109.5
H22A C22 H22C 109.5
H22B C22 H22C 109.5
C24 C23 C25 111.2(4)
C24 C23 P2 113.5(3)
C25 C23 P2 109.2(3)
C24 C23 H23 107.6
C25 C23 H23 107.6
P2 C23 H23 107.6
C23 C24 H24A 109.5
C23 C24 H24B 109.5
H24A C24 H24B 109.5
C23 C24 H24C 109.5
H24A C24 H24C 109.5
H24B C24 H24C 109.5
C23 C25 H25A 109.5
C23 C25 H25B 109.5
H25A C25 H25B 109.5
C23 C25 H25C 109.5
H25A C25 H25C 109.5
H25B C25 H25C 109.5
C28 C26 C27 110.1(3)
C28 C26 P2 110.0(2)
C27 C26 P2 112.8(3)
C28 C26 H26 108.0
C27 C26 H26 108.0
P2 C26 H26 108.0
C26 C27 H27A 109.5
C26 C27 H27B 109.5
H27A C27 H27B 109.5
C26 C27 H27C 109.5
H27A C27 H27C 109.5
H27B C27 H27C 109.5
C26 C28 H28A 109.5
C26 C28 H28B 109.5
H28A C28 H28B 109.5
C26 C28 H28C 109.5
H28A C28 H28C 109.5
H28B C28 H28C 109.5
C1 N1 Ni1 64.21(16)
C1 N1 H1A 117.3
Ni1 N1 H1A 117.3
C1 N1 H1B 117.3
Ni1 N1 H1B 117.3
H1A N1 H1B 114.4
Ni1 N2 H2A 109.5
Ni1 N2 H2B 109.5
H2A N2 H2B 109.5
Ni1 N2 H2C 109.5
H2A N2 H2C 109.5
H2B N2 H2C 109.5
C1 Ni1 N2 151.20(13)
C1 Ni1 N1 42.33(12)
N2 Ni1 N1 108.89(12)
C1 Ni1 P1 87.24(10)
N2 Ni1 P1 101.05(9)
N1 Ni1 P1 102.07(8)
C1 Ni1 P2 88.22(10)
N2 Ni1 P2 102.70(9)
N1 Ni1 P2 102.20(8)
P1 Ni1 P2 138.08(4)
C7 P1 C17 103.85(16)
C7 P1 C20 107.17(16)
C17 P1 C20 102.88(17)
C7 P1 Ni1 101.42(11)
C17 P1 Ni1 125.47(12)
C20 P1 Ni1 114.45(12)
C11 P2 C23 105.38(17)
C11 P2 C26 100.53(16)
C23 P2 C26 102.65(17)
C11 P2 Ni1 100.43(11)
C23 P2 Ni1 122.34(13)
C26 P2 Ni1 122.06(12)
F5 Sb1 F2 90.79(12)
F5 Sb1 F4 179.67(13)
F2 Sb1 F4 88.88(10)
F5 Sb1 F6 90.41(13)
F2 Sb1 F6 178.81(11)
F4 Sb1 F6 89.93(12)
F5 Sb1 F3 90.87(10)
F2 Sb1 F3 90.61(10)
F4 Sb1 F3 89.11(10)
F6 Sb1 F3 89.34(11)
F5 Sb1 F1 90.32(10)
F2 Sb1 F1 90.00(10)
F4 Sb1 F1 89.71(10)
F6 Sb1 F1 90.03(11)
F3 Sb1 F1 178.66(10)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 N1 1.441(4)
C1 C6 1.495(4)
C1 C2 1.501(4)
C1 Ni1 1.926(3)
C2 C7 1.383(5)
C2 C3 1.401(5)
C3 C10 1.391(5)
C3 C4 1.528(5)
C4 C5 1.528(5)
C4 C16 1.538(5)
C4 C15 1.554(5)
C5 C14 1.390(5)
C5 C6 1.406(5)
C6 C11 1.394(5)
C7 C8 1.400(5)
C7 P1 1.819(3)
C8 C9 1.375(5)
C8 H8 0.9300
C9 C10 1.384(5)
C9 H9 0.9300
C10 H10 0.9300
C11 C12 1.385(5)
C11 P2 1.820(3)
C12 C13 1.379(5)
C12 H12 0.9300
C13 C14 1.387(5)
C13 H13 0.9300
C14 H14 0.9300
C15 H15A 0.9600
C15 H15B 0.9600
C15 H15C 0.9600
C16 H16A 0.9600
C16 H16B 0.9600
C16 H16C 0.9600
C17 C19 1.514(5)
C17 C18 1.521(6)
C17 P1 1.848(4)
C17 H17 0.9800
C18 H18A 0.9600
C18 H18B 0.9600
C18 H18C 0.9600
C19 H19A 0.9600
C19 H19B 0.9600
C19 H19C 0.9600
C20 C22 1.523(5)
C20 C21 1.526(5)
C20 P1 1.851(4)
C20 H20 0.9800
C21 H21A 0.9600
C21 H21B 0.9600
C21 H21C 0.9600
C22 H22A 0.9600
C22 H22B 0.9600
C22 H22C 0.9600
C23 C24 1.491(6)
C23 C25 1.537(6)
C23 P2 1.862(4)
C23 H23 0.9800
C24 H24A 0.9600
C24 H24B 0.9600
C24 H24C 0.9600
C25 H25A 0.9600
C25 H25B 0.9600
C25 H25C 0.9600
C26 C28 1.512(5)
C26 C27 1.522(5)
C26 P2 1.867(3)
C26 H26 0.9800
C27 H27A 0.9600
C27 H27B 0.9600
C27 H27C 0.9600
C28 H28A 0.9600
C28 H28B 0.9600
C28 H28C 0.9600
F1 Sb1 1.880(2)
F2 Sb1 1.869(2)
F3 Sb1 1.875(2)
F4 Sb1 1.871(2)
F5 Sb1 1.855(2)
F6 Sb1 1.874(2)
N1 Ni1 2.050(3)
N1 H1A 0.8900
N1 H1B 0.8900
N2 Ni1 2.013(3)
N2 H2A 0.8900
N2 H2B 0.8900
N2 H2C 0.8900
Ni1 P1 2.2124(9)
Ni1 P2 2.2199(10)
