#------------------------------------------------------------------------------
#$Date: 2019-11-07 23:06:04 +0200 (Thu, 07 Nov 2019) $
#$Revision: 223932 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/82/7048256.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7048256
loop_
_publ_author_name
'Hoshino, Norihisa'
'Fujita, Sena'
'Akutagawa, Tomoyuki'
_publ_section_title
;
 The trinuclear platinum(ii) complex in Vèzes' red salt as a building
 block of coordination polymers.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              176
_journal_page_last               181
_journal_paper_doi               10.1039/c8dt04121k
_journal_volume                  48
_journal_year                    2018
_chemical_formula_moiety
'(C12 H24 K N6 O19 Pt3), C14 H32 K O8, 2(H2 O)'
_chemical_formula_sum            'C26 H60 K2 N6 O29 Pt3'
_chemical_formula_weight         1584.27
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/1
_audit_update_record
;
2018-10-15 deposited with the CCDC.
2018-11-27 downloaded from the CCDC.
;
_cell_angle_alpha                95.484(7)
_cell_angle_beta                 100.669(7)
_cell_angle_gamma                90.825(6)
_cell_formula_units_Z            2
_cell_length_a                   8.2798(2)
_cell_length_b                   17.4801(5)
_cell_length_c                   18.1002(5)
_cell_measurement_reflns_used    19652
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      68.25
_cell_measurement_theta_min      3.38
_cell_volume                     2561.22(14)
_computing_cell_refinement       'RAPID AUTO (Rigaku, 2015)'
_computing_data_collection       'RAPID AUTO (Rigaku, 2015)'
_computing_data_reduction        'RAPID AUTO (Rigaku, 2015)'
_computing_molecular_graphics    'ORTEP-3 (Farrugia, 2012)'
_computing_publication_material  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_structure_refinement  'SHELXL-2018/1 (Sheldrick, 2018)'
_computing_structure_solution    'SIR2004 (Spagna, 2004)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54187
_diffrn_reflns_av_R_equivalents  0.1130
_diffrn_reflns_av_unetI/netI     0.1257
_diffrn_reflns_Laue_measured_fraction_full 0.982
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            28428
_diffrn_reflns_point_group_measured_fraction_full 0.982
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_theta_full        67.687
_diffrn_reflns_theta_max         68.226
_diffrn_reflns_theta_min         3.380
_diffrn_source                   'rotating-anode X-ray tube'
_exptl_absorpt_coefficient_mu    17.275
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.3373
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'abscor (Rigaku, 2010)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.054
_exptl_crystal_description       rod
_exptl_crystal_F_000             1524
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.090
_exptl_crystal_size_min          0.090
_refine_diff_density_max         3.136
_refine_diff_density_min         -2.054
_refine_diff_density_rms         0.267
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     578
_refine_ls_number_reflns         9169
_refine_ls_number_restraints     160
_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.1158
_refine_ls_R_factor_gt           0.0859
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0980P)²+36.2855P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2145
_refine_ls_wR_factor_ref         0.2337
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6432
_reflns_number_total             9169
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c8dt04121k2.cif
_cod_data_source_block           2
_cod_depositor_comments
'Adding full bibliography for 7048256--7048259.cif.'
_cod_database_code               7048256
_shelx_shelxl_version_number     2018/1
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.157
_shelx_estimated_absorpt_t_max   0.305
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Pt1 Pt 0.62152(9) 0.14913(4) 0.18752(4) 0.0477(2) Uani 1 1 d . .
Pt2 Pt 0.71442(9) 0.27360(4) 0.07719(4) 0.0485(2) Uani 1 1 d . .
Pt3 Pt 0.63485(10) 0.33080(4) 0.24261(4) 0.0559(3) Uani 1 1 d . .
K1 K 0.2587(5) 0.26334(19) 0.07268(19) 0.0481(8) Uani 1 1 d . .
K2 K 0.1096(7) 0.8036(3) 0.3827(2) 0.0878(16) Uani 1 1 d D .
O1 O 0.5713(13) 0.2536(6) 0.1544(7) 0.058(3) Uani 1 1 d . .
O2 O 0.6737(15) 0.1129(6) 0.0860(6) 0.055(3) Uani 1 1 d . .
O3 O 0.7226(17) 0.1363(8) -0.0220(7) 0.068(4) Uani 1 1 d . .
O4 O 0.7204(16) 0.3861(6) 0.1097(7) 0.057(3) Uani 1 1 d . .
O5 O 0.697(2) 0.4767(7) 0.1977(8) 0.080(4) Uani 1 1 d . .
O6 O 0.5652(16) 0.2536(8) 0.3069(7) 0.068(4) Uani 1 1 d . .
O7 O 0.5058(19) 0.1383(9) 0.3243(7) 0.079(4) Uani 1 1 d . .
O8 O 0.5583(18) -0.0053(8) 0.2121(9) 0.079(4) Uani 1 1 d . .
O9 O 0.8128(18) 0.0259(8) 0.2402(10) 0.095(5) Uani 1 1 d . .
O10 O 0.8103(18) 0.3592(8) -0.0312(9) 0.077(4) Uani 1 1 d . .
O11 O 0.9612(16) 0.2618(8) -0.0099(7) 0.069(4) Uani 1 1 d . .
O12 O 0.581(3) 0.4137(13) 0.3731(10) 0.130(8) Uani 1 1 d . .
O13 O 0.826(2) 0.4357(9) 0.3528(9) 0.095(5) Uani 1 1 d . .
O14 O 0.1665(18) 0.1108(9) 0.0774(8) 0.079(4) Uani 1 1 d . .
O15 O 0.3192(15) 0.1564(6) -0.0423(7) 0.056(3) Uani 1 1 d . .
O16 O 0.3133(14) 0.3119(6) -0.0653(6) 0.051(3) Uani 1 1 d . .
O17 O 0.2887(17) 0.4211(6) 0.0592(7) 0.062(3) Uani 1 1 d . .
O18 O 0.1531(18) 0.3700(8) 0.1795(7) 0.073(4) Uani 1 1 d . .
O19 O 0.1833(17) 0.2143(9) 0.2077(8) 0.076(4) Uani 1 1 d . .
O20 O 0.028(3) 0.6523(12) 0.3136(13) 0.182(11) Uani 1 1 d D U
O21 O 0.0871(16) 0.7695(8) 0.2284(7) 0.069(3) Uani 1 1 d . .
O22 O 0.2499(19) 0.9048(9) 0.3044(8) 0.083(4) Uani 1 1 d . .
O23 O 0.207(3) 0.9561(11) 0.4494(8) 0.118(7) Uani 1 1 d D .
O24 O 0.142(2) 0.8452(13) 0.5393(9) 0.111(5) Uani 1 1 d D .
O25 O -0.009(4) 0.7051(18) 0.4722(12) 0.194(12) Uani 1 1 d D U
O26 O 0.403(3) 0.7332(13) 0.4298(11) 0.133(7) Uani 1 1 d D .
O27 O -0.182(3) 0.8832(13) 0.3298(12) 0.152(9) Uani 1 1 d D .
N1 N 0.7033(18) 0.1684(11) 0.0438(8) 0.068(5) Uani 1 1 d . .
N2 N 0.697(2) 0.4085(9) 0.1791(9) 0.069(5) Uani 1 1 d . .
N3 N 0.562(2) 0.1817(9) 0.2827(10) 0.069(5) Uani 1 1 d . .
N4 N 0.672(2) 0.0453(9) 0.2169(8) 0.063(4) Uani 1 1 d . .
N5 N 0.8468(19) 0.3006(9) 0.0016(8) 0.058(4) Uani 1 1 d . .
N6 N 0.689(3) 0.4055(10) 0.3345(11) 0.077(5) Uani 1 1 d . .
C1 C 0.233(3) 0.0580(12) 0.0295(13) 0.080(7) Uani 1 1 d . .
H1 H 0.176415 0.007172 0.025767 0.096 Uiso 1 1 calc R U
H2 H 0.351348 0.052299 0.049713 0.096 Uiso 1 1 calc R U
C2 C 0.211(3) 0.0881(11) -0.0506(12) 0.080(7) Uani 1 1 d . .
H3 H 0.241265 0.048354 -0.087810 0.096 Uiso 1 1 calc R U
H4 H 0.094923 0.101390 -0.067921 0.096 Uiso 1 1 calc R U
C3 C 0.314(3) 0.1813(11) -0.1148(10) 0.071(6) Uani 1 1 d . .
H5 H 0.198858 0.184717 -0.140784 0.085 Uiso 1 1 calc R U
H6 H 0.369673 0.144046 -0.145731 0.085 Uiso 1 1 calc R U
C4 C 0.401(2) 0.2594(9) -0.1056(9) 0.049(4) Uani 1 1 d . .
H7 H 0.515167 0.256490 -0.077711 0.059 Uiso 1 1 calc R U
H8 H 0.405241 0.276562 -0.155826 0.059 Uiso 1 1 calc R U
C5 C 0.382(2) 0.3874(10) -0.0580(9) 0.056(4) Uani 1 1 d . .
H9 H 0.386380 0.404159 -0.108408 0.067 Uiso 1 1 calc R U
H10 H 0.495447 0.389567 -0.028073 0.067 Uiso 1 1 calc R U
C6 C 0.272(2) 0.4388(9) -0.0181(10) 0.060(5) Uani 1 1 d . .
H11 H 0.303433 0.493503 -0.019208 0.073 Uiso 1 1 calc R U
H12 H 0.156027 0.430321 -0.044156 0.073 Uiso 1 1 calc R U
C7 C 0.186(3) 0.4647(10) 0.0970(11) 0.074(6) Uani 1 1 d . .
H13 H 0.070550 0.454073 0.071584 0.089 Uiso 1 1 calc R U
H14 H 0.212249 0.520006 0.095940 0.089 Uiso 1 1 calc R U
C8 C 0.208(3) 0.4461(13) 0.1764(12) 0.083(7) Uani 1 1 d . .
H15 H 0.325433 0.452568 0.200359 0.100 Uiso 1 1 calc R U
H16 H 0.144841 0.482137 0.204817 0.100 Uiso 1 1 calc R U
C9 C 0.181(3) 0.3478(15) 0.2528(12) 0.090(7) Uani 1 1 d . U
H17 H 0.134767 0.385857 0.286501 0.108 Uiso 1 1 calc R U
H18 H 0.300992 0.346297 0.271882 0.108 Uiso 1 1 calc R U
C10 C 0.107(3) 0.2741(16) 0.2535(13) 0.090(7) Uani 1 1 d . U
H19 H -0.011903 0.275289 0.232858 0.108 Uiso 1 1 calc R U
H20 H 0.120905 0.260848 0.306214 0.108 Uiso 1 1 calc R U
C11 C 0.095(2) 0.1398(15) 0.1951(13) 0.088(8) Uani 1 1 d . .
H21 H -0.020062 0.145972 0.169363 0.105 Uiso 1 1 calc R U
H22 H 0.091773 0.119938 0.244313 0.105 Uiso 1 1 calc R U
C12 C 0.178(2) 0.0829(12) 0.1472(12) 0.070(6) Uani 1 1 d . .
H23 H 0.294734 0.078362 0.171018 0.084 Uiso 1 1 calc R U
H24 H 0.122681 0.031518 0.141664 0.084 Uiso 1 1 calc R U
C13 C -0.055(3) 0.6496(15) 0.2397(16) 0.113(8) Uani 1 1 d . .
H25 H -0.157704 0.678242 0.236226 0.135 Uiso 1 1 calc R U
H26 H -0.081219 0.595843 0.217593 0.135 Uiso 1 1 calc R U
C14 C 0.071(3) 0.6890(14) 0.1995(16) 0.103(6) Uani 1 1 d . .
H27 H 0.178748 0.664514 0.210083 0.123 Uiso 1 1 calc R U
H28 H 0.030947 0.683700 0.144159 0.123 Uiso 1 1 calc R U
C15 C 0.204(3) 0.8073(14) 0.2012(12) 0.083(6) Uani 1 1 d . .
H29 H 0.183193 0.798170 0.145370 0.099 Uiso 1 1 calc R U
H30 H 0.313482 0.787493 0.220792 0.099 Uiso 1 1 calc R U
C16 C 0.202(3) 0.8904(13) 0.2243(11) 0.079(5) Uani 1 1 d . .
H31 H 0.278908 0.918312 0.199608 0.095 Uiso 1 1 calc R U
H32 H 0.090396 0.909371 0.208127 0.095 Uiso 1 1 calc R U
C17 C 0.245(3) 0.9806(13) 0.3313(14) 0.091(6) Uani 1 1 d . .
H33 H 0.309031 1.012039 0.303600 0.110 Uiso 1 1 calc R U
H34 H 0.129433 0.996833 0.320837 0.110 Uiso 1 1 calc R U
C18 C 0.305(5) 0.9950(18) 0.4064(17) 0.134(10) Uani 1 1 d . .
H35 H 0.305707 1.051078 0.421086 0.161 Uiso 1 1 calc R U
H36 H 0.419157 0.977820 0.417631 0.161 Uiso 1 1 calc R U
C19 C 0.257(5) 0.965(2) 0.5295(11) 0.164(13) Uani 1 1 d D .
H37 H 0.262749 1.020067 0.548976 0.197 Uiso 1 1 calc R U
H38 H 0.367240 0.943435 0.544273 0.197 Uiso 1 1 calc R U
C20 C 0.128(5) 0.921(2) 0.561(2) 0.167(13) Uani 1 1 d D .
H39 H 0.147770 0.930818 0.616453 0.200 Uiso 1 1 calc R U
H40 H 0.016948 0.938298 0.540144 0.200 Uiso 1 1 calc R U
C21 C 0.049(4) 0.8053(19) 0.5806(18) 0.163(11) Uani 1 1 d D .
H41 H -0.066523 0.820787 0.571247 0.195 Uiso 1 1 calc R U
H42 H 0.094747 0.814578 0.635364 0.195 Uiso 1 1 calc R U
C22 C 0.063(4) 0.7198(18) 0.5516(11) 0.146(10) Uani 1 1 d D U
H43 H 0.180529 0.706353 0.559226 0.176 Uiso 1 1 calc R U
H44 H 0.006757 0.686788 0.581089 0.176 Uiso 1 1 calc R U
C23 C 0.048(5) 0.633(2) 0.443(2) 0.210(17) Uani 1 1 d D U
H45 H 0.031977 0.591940 0.475691 0.252 Uiso 1 1 calc R U
H46 H 0.166810 0.637247 0.441471 0.252 Uiso 1 1 calc R U
C24 C -0.052(7) 0.612(3) 0.362(2) 0.32(3) Uani 1 1 d D U
H47 H -0.052830 0.555601 0.348020 0.379 Uiso 1 1 calc R U
H48 H -0.167145 0.627877 0.359200 0.379 Uiso 1 1 calc R U
C25 C 0.518(4) 0.7678(17) 0.4952(16) 0.136(12) Uani 1 1 d D .
H49 H 0.577259 0.811266 0.481014 0.204 Uiso 1 1 calc R U
H50 H 0.596028 0.729554 0.514206 0.204 Uiso 1 1 calc R U
H51 H 0.456918 0.786045 0.534744 0.204 Uiso 1 1 calc R U
C26 C -0.327(4) 0.840(3) 0.3309(19) 0.30(4) Uani 1 1 d D U
H52 H -0.423184 0.870045 0.312311 0.452 Uiso 1 1 calc R U
H53 H -0.329761 0.791984 0.298343 0.452 Uiso 1 1 calc R U
H54 H -0.329623 0.829063 0.382690 0.452 Uiso 1 1 calc R U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
K K 0.3868 1.0657 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -4.5932 6.9264 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Pt1 N4 92.4(6) . .
N3 Pt1 O1 89.5(6) . .
N4 Pt1 O1 178.2(6) . .
N3 Pt1 O2 177.4(6) . .
N4 Pt1 O2 87.3(5) . .
O1 Pt1 O2 90.8(5) . .
N3 Pt1 Pt3 61.3(5) . .
N4 Pt1 Pt3 146.1(4) . .
O1 Pt1 Pt3 35.4(3) . .
O2 Pt1 Pt3 119.9(3) . .
N1 Pt2 N5 93.5(7) . .
N1 Pt2 O4 178.1(5) . .
N5 Pt2 O4 86.1(6) . .
N1 Pt2 O1 90.1(6) . .
N5 Pt2 O1 175.8(5) . .
O4 Pt2 O1 90.2(5) . .
O1 Pt3 N2 92.2(6) . .
O1 Pt3 N6 176.5(8) . .
N2 Pt3 N6 90.9(7) . .
O1 Pt3 O6 88.1(5) . .
N2 Pt3 O6 178.2(6) . .
N6 Pt3 O6 88.8(7) . .
O1 Pt3 Pt1 35.9(3) . .
N2 Pt3 Pt1 121.5(5) . .
N6 Pt3 Pt1 142.3(5) . .
O6 Pt3 Pt1 59.4(4) . .
O11 K1 O1 175.6(4) 1_455 .
O11 K1 O14 80.7(4) 1_455 .
O1 K1 O14 95.6(4) . .
O11 K1 O15 83.9(4) 1_455 .
O1 K1 O15 92.2(4) . .
O14 K1 O15 62.2(4) . .
O11 K1 O17 89.0(4) 1_455 .
O1 K1 O17 94.7(4) . .
O14 K1 O17 169.3(4) . .
O15 K1 O17 120.1(4) . .
O11 K1 O18 88.5(4) 1_455 .
O1 K1 O18 95.3(4) . .
O14 K1 O18 115.6(5) . .
O15 K1 O18 172.4(4) . .
O17 K1 O18 60.6(4) . .
O11 K1 O16 76.6(4) 1_455 .
O1 K1 O16 103.3(4) . .
O14 K1 O16 119.0(4) . .
O15 K1 O16 59.7(3) . .
O17 K1 O16 60.9(3) . .
O18 K1 O16 119.5(4) . .
O11 K1 O19 100.0(4) 1_455 .
O1 K1 O19 80.1(4) . .
O14 K1 O19 60.1(5) . .
O15 K1 O19 120.5(4) . .
O17 K1 O19 119.3(4) . .
O18 K1 O19 59.9(4) . .
O16 K1 O19 176.6(4) . .
O22 K2 O25 175.0(6) . .
O22 K2 O21 61.3(4) . .
O25 K2 O21 122.8(7) . .
O22 K2 O26 93.4(6) . .
O25 K2 O26 83.2(8) . .
O21 K2 O26 98.1(5) . .
O22 K2 O24 115.8(6) . .
O25 K2 O24 60.1(7) . .
O21 K2 O24 177.1(6) . .
O26 K2 O24 81.9(6) . .
O22 K2 O20 118.3(6) . .
O25 K2 O20 64.9(8) . .
O21 K2 O20 59.2(5) . .
O26 K2 O20 80.0(7) . .
O24 K2 O20 123.5(7) . .
O22 K2 O23 59.5(5) . .
O25 K2 O23 117.1(8) . .
O21 K2 O23 119.1(5) . .
O26 K2 O23 98.2(6) . .
O24 K2 O23 58.1(6) . .
O20 K2 O23 177.1(8) . .
O22 K2 O27 82.9(6) . .
O25 K2 O27 100.4(8) . .
O21 K2 O27 80.5(5) . .
O26 K2 O27 176.3(7) . .
O24 K2 O27 99.4(6) . .
O20 K2 O27 102.0(7) . .
O23 K2 O27 79.7(6) . .
Pt3 O1 Pt1 108.6(5) . .
Pt3 O1 Pt2 108.0(5) . .
Pt1 O1 Pt2 107.7(5) . .
Pt3 O1 K1 115.8(5) . .
Pt1 O1 K1 113.7(5) . .
Pt2 O1 K1 102.4(4) . .
N1 O2 Pt1 115.5(10) . .
N2 O4 Pt2 118.3(10) . .
N3 O6 Pt3 118.5(12) . .
N5 O11 K1 127.9(11) . 1_655
C12 O14 C1 109.1(16) . .
C12 O14 K1 118.5(13) . .
C1 O14 K1 114.9(12) . .
C3 O15 C2 108.1(14) . .
C3 O15 K1 118.1(10) . .
C2 O15 K1 111.3(11) . .
C4 O16 C5 111.7(13) . .
C4 O16 K1 113.7(8) . .
C5 O16 K1 113.5(9) . .
C7 O17 C6 111.1(13) . .
C7 O17 K1 113.2(11) . .
C6 O17 K1 113.3(9) . .
C9 O18 C8 113.0(18) . .
C9 O18 K1 113.8(13) . .
C8 O18 K1 113.3(12) . .
C11 O19 C10 113.7(17) . .
C11 O19 K1 112.5(12) . .
C10 O19 K1 114.1(11) . .
C13 O20 C24 115(3) . .
C13 O20 K2 113.6(15) . .
C24 O20 K2 108(2) . .
C15 O21 C14 111.8(19) . .
C15 O21 K2 112.6(12) . .
C14 O21 K2 117.1(14) . .
C17 O22 C16 114.0(17) . .
C17 O22 K2 114.6(15) . .
C16 O22 K2 113.9(11) . .
C19 O23 C18 117(3) . .
C19 O23 K2 116.0(18) . .
C18 O23 K2 112.1(15) . .
C20 O24 C21 107(3) . .
C20 O24 K2 116.0(17) . .
C21 O24 K2 119.4(18) . .
C22 O25 C23 109(3) . .
C22 O25 K2 113.4(16) . .
C23 O25 K2 100(2) . .
C25 O26 K2 119.4(18) . .
C26 O27 K2 113(2) . .
O3 N1 O2 108.4(16) . .
O3 N1 Pt2 127.7(12) . .
O2 N1 Pt2 123.9(12) . .
O5 N2 O4 117.8(16) . .
O5 N2 Pt3 122.3(14) . .
O4 N2 Pt3 119.4(11) . .
O7 N3 O6 113.7(18) . .
O7 N3 Pt1 125.3(13) . .
O6 N3 Pt1 120.8(13) . .
O9 N4 O8 116.7(15) . .
O9 N4 Pt1 122.8(14) . .
O8 N4 Pt1 120.6(12) . .
O11 N5 O10 122.1(16) . .
O11 N5 Pt2 120.1(12) . .
O10 N5 Pt2 117.8(13) . .
O13 N6 O12 124(2) . .
O13 N6 Pt3 120.2(17) . .
O12 N6 Pt3 116.0(17) . .
O14 C1 C2 108.6(17) . .
O14 C1 H1 110.0 . .
C2 C1 H1 110.0 . .
O14 C1 H2 110.0 . .
C2 C1 H2 110.0 . .
H1 C1 H2 108.3 . .
O15 C2 C1 106.3(16) . .
O15 C2 H3 110.5 . .
C1 C2 H3 110.5 . .
O15 C2 H4 110.5 . .
C1 C2 H4 110.5 . .
H3 C2 H4 108.7 . .
O15 C3 C4 108.6(14) . .
O15 C3 H5 110.0 . .
C4 C3 H5 110.0 . .
O15 C3 H6 110.0 . .
C4 C3 H6 110.0 . .
H5 C3 H6 108.4 . .
O16 C4 C3 108.4(15) . .
O16 C4 H7 110.0 . .
C3 C4 H7 110.0 . .
O16 C4 H8 110.0 . .
C3 C4 H8 110.0 . .
H7 C4 H8 108.4 . .
O16 C5 C6 106.5(14) . .
O16 C5 H9 110.4 . .
C6 C5 H9 110.4 . .
O16 C5 H10 110.4 . .
C6 C5 H10 110.4 . .
H9 C5 H10 108.6 . .
O17 C6 C5 109.1(13) . .
O17 C6 H11 109.9 . .
C5 C6 H11 109.9 . .
O17 C6 H12 109.9 . .
C5 C6 H12 109.9 . .
H11 C6 H12 108.3 . .
O17 C7 C8 109.9(16) . .
O17 C7 H13 109.7 . .
C8 C7 H13 109.7 . .
O17 C7 H14 109.7 . .
C8 C7 H14 109.7 . .
H13 C7 H14 108.2 . .
O18 C8 C7 110.7(17) . .
O18 C8 H15 109.5 . .
C7 C8 H15 109.5 . .
O18 C8 H16 109.5 . .
C7 C8 H16 109.5 . .
H15 C8 H16 108.1 . .
O18 C9 C10 110(2) . .
O18 C9 H17 109.6 . .
C10 C9 H17 109.6 . .
O18 C9 H18 109.6 . .
C10 C9 H18 109.6 . .
H17 C9 H18 108.1 . .
C9 C10 O19 111.0(18) . .
C9 C10 H19 109.4 . .
O19 C10 H19 109.4 . .
C9 C10 H20 109.4 . .
O19 C10 H20 109.4 . .
H19 C10 H20 108.0 . .
O19 C11 C12 110.3(16) . .
O19 C11 H21 109.6 . .
C12 C11 H21 109.6 . .
O19 C11 H22 109.6 . .
C12 C11 H22 109.6 . .
H21 C11 H22 108.1 . .
O14 C12 C11 106.8(16) . .
O14 C12 H23 110.4 . .
C11 C12 H23 110.4 . .
O14 C12 H24 110.4 . .
C11 C12 H24 110.4 . .
H23 C12 H24 108.6 . .
O20 C13 C14 103(2) . .
O20 C13 H25 111.2 . .
C14 C13 H25 111.2 . .
O20 C13 H26 111.2 . .
C14 C13 H26 111.2 . .
H25 C13 H26 109.1 . .
O21 C14 C13 108(2) . .
O21 C14 H27 110.2 . .
C13 C14 H27 110.2 . .
O21 C14 H28 110.2 . .
C13 C14 H28 110.2 . .
H27 C14 H28 108.5 . .
O21 C15 C16 110.0(19) . .
O21 C15 H29 109.7 . .
C16 C15 H29 109.7 . .
O21 C15 H30 109.7 . .
C16 C15 H30 109.7 . .
H29 C15 H30 108.2 . .
O22 C16 C15 110.0(17) . .
O22 C16 H31 109.7 . .
C15 C16 H31 109.7 . .
O22 C16 H32 109.7 . .
C15 C16 H32 109.7 . .
H31 C16 H32 108.2 . .
C18 C17 O22 114(2) . .
C18 C17 H33 108.8 . .
O22 C17 H33 108.8 . .
C18 C17 H34 108.8 . .
O22 C17 H34 108.8 . .
H33 C17 H34 107.7 . .
C17 C18 O23 111(3) . .
C17 C18 H35 109.4 . .
O23 C18 H35 109.4 . .
C17 C18 H36 109.4 . .
O23 C18 H36 109.4 . .
H35 C18 H36 108.0 . .
O23 C19 C20 106(2) . .
O23 C19 H37 110.6 . .
C20 C19 H37 110.6 . .
O23 C19 H38 110.6 . .
C20 C19 H38 110.6 . .
H37 C19 H38 108.7 . .
O24 C20 C19 107(3) . .
O24 C20 H39 110.2 . .
C19 C20 H39 110.2 . .
O24 C20 H40 110.2 . .
C19 C20 H40 110.2 . .
H39 C20 H40 108.5 . .
O24 C21 C22 104(3) . .
O24 C21 H41 110.9 . .
C22 C21 H41 110.9 . .
O24 C21 H42 110.9 . .
C22 C21 H42 110.9 . .
H41 C21 H42 108.9 . .
O25 C22 C21 111(3) . .
O25 C22 H43 109.4 . .
C21 C22 H43 109.4 . .
O25 C22 H44 109.4 . .
C21 C22 H44 109.4 . .
H43 C22 H44 108.0 . .
O25 C23 C24 108(4) . .
O25 C23 H45 110.2 . .
C24 C23 H45 110.2 . .
O25 C23 H46 110.2 . .
C24 C23 H46 110.2 . .
H45 C23 H46 108.5 . .
O20 C24 C23 106(3) . .
O20 C24 H47 110.6 . .
C23 C24 H47 110.6 . .
O20 C24 H48 110.6 . .
C23 C24 H48 110.6 . .
H47 C24 H48 108.7 . .
O26 C25 H49 109.5 . .
O26 C25 H50 109.5 . .
H49 C25 H50 109.5 . .
O26 C25 H51 109.5 . .
H49 C25 H51 109.5 . .
H50 C25 H51 109.5 . .
O27 C26 H52 109.5 . .
O27 C26 H53 109.5 . .
H52 C26 H53 109.5 . .
O27 C26 H54 109.5 . .
H52 C26 H54 109.5 . .
H53 C26 H54 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 N3 1.916(19) .
Pt1 N4 1.968(15) .
Pt1 O1 2.001(11) .
Pt1 O2 2.012(12) .
Pt2 N1 1.875(19) .
Pt2 N5 1.990(16) .
Pt2 O4 1.995(12) .
Pt2 O1 2.043(13) .
Pt3 O1 1.977(11) .
Pt3 N2 1.981(18) .
Pt3 N6 1.991(19) .
Pt3 O6 2.008(14) .
K1 O11 2.632(13) 1_455
K1 O1 2.750(10) .
K1 O14 2.777(14) .
K1 O15 2.783(12) .
K1 O17 2.803(11) .
K1 O18 2.823(13) .
K1 O16 2.825(11) .
K1 O19 2.836(13) .
K2 O22 2.742(16) .
K2 O25 2.76(2) .
K2 O21 2.770(14) .
K2 O26 2.77(2) .
K2 O24 2.821(18) .
K2 O20 2.83(2) .
K2 O23 2.86(2) .
K2 O27 2.862(15) .
O2 N1 1.338(19) .
O3 N1 1.305(19) .
O4 N2 1.329(19) .
O5 N2 1.208(18) .
O6 N3 1.290(19) .
O7 N3 1.26(2) .
O8 N4 1.27(2) .
O9 N4 1.225(19) .
O10 N5 1.246(18) .
O11 N5 1.211(18) .
O12 N6 1.23(2) .
O13 N6 1.22(2) .
O14 C12 1.39(2) .
O14 C1 1.39(3) .
O15 C3 1.42(2) .
O15 C2 1.46(2) .
O16 C4 1.411(19) .
O16 C5 1.41(2) .
O17 C7 1.38(2) .
O17 C6 1.44(2) .
O18 C9 1.40(2) .
O18 C8 1.41(3) .
O19 C11 1.46(3) .
O19 C10 1.49(3) .
O20 C13 1.38(3) .
O20 C24 1.429(19) .
O21 C15 1.36(2) .
O21 C14 1.45(3) .
O22 C17 1.37(2) .
O22 C16 1.43(2) .
O23 C19 1.426(17) .
O23 C18 1.43(4) .
O24 C20 1.36(4) .
O24 C21 1.386(18) .
O25 C22 1.448(18) .
O25 C23 1.448(19) .
O26 C25 1.447(18) .
O27 C26 1.410(19) .
C1 C2 1.57(3) .
C1 H1 0.9900 .
C1 H2 0.9900 .
C2 H3 0.9900 .
C2 H4 0.9900 .
C3 C4 1.51(2) .
C3 H5 0.9900 .
C3 H6 0.9900 .
C4 H7 0.9900 .
C4 H8 0.9900 .
C5 C6 1.52(2) .
C5 H9 0.9900 .
C5 H10 0.9900 .
C6 H11 0.9900 .
C6 H12 0.9900 .
C7 C8 1.48(3) .
C7 H13 0.9900 .
C7 H14 0.9900 .
C8 H15 0.9900 .
C8 H16 0.9900 .
C9 C10 1.42(3) .
C9 H17 0.9900 .
C9 H18 0.9900 .
C10 H19 0.9900 .
C10 H20 0.9900 .
C11 C12 1.51(3) .
C11 H21 0.9900 .
C11 H22 0.9900 .
C12 H23 0.9900 .
C12 H24 0.9900 .
C13 C14 1.56(4) .
C13 H25 0.9900 .
C13 H26 0.9900 .
C14 H27 0.9900 .
C14 H28 0.9900 .
C15 C16 1.47(3) .
C15 H29 0.9900 .
C15 H30 0.9900 .
C16 H31 0.9900 .
C16 H32 0.9900 .
C17 C18 1.35(3) .
C17 H33 0.9900 .
C17 H34 0.9900 .
C18 H35 0.9900 .
C18 H36 0.9900 .
C19 C20 1.525(19) .
C19 H37 0.9900 .
C19 H38 0.9900 .
C20 H39 0.9900 .
C20 H40 0.9900 .
C21 C22 1.550(19) .
C21 H41 0.9900 .
C21 H42 0.9900 .
C22 H43 0.9900 .
C22 H44 0.9900 .
C23 C24 1.548(19) .
C23 H45 0.9900 .
C23 H46 0.9900 .
C24 H47 0.9900 .
C24 H48 0.9900 .
C25 H49 0.9800 .
C25 H50 0.9800 .
C25 H51 0.9800 .
C26 H52 0.9800 .
C26 H53 0.9800 .
C26 H54 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
Pt1 O2 N1 O3 -175.3(9) .
Pt1 O2 N1 Pt2 5.0(15) .
N5 Pt2 N1 O3 -21.7(14) .
O1 Pt2 N1 O3 156.2(14) .
N5 Pt2 N1 O2 157.9(12) .
O1 Pt2 N1 O2 -24.2(12) .
Pt2 O4 N2 O5 -178.2(13) .
Pt2 O4 N2 Pt3 -6.2(17) .
Pt3 O6 N3 O7 -175.3(11) .
Pt3 O6 N3 Pt1 -0.2(17) .
K1 O11 N5 O10 99.5(18) 1_655
K1 O11 N5 Pt2 -78.6(16) 1_655
C12 O14 C1 C2 177.0(16) .
K1 O14 C1 C2 -47(2) .
C3 O15 C2 C1 174.6(17) .
K1 O15 C2 C1 -54.2(19) .
O14 C1 C2 O15 69(2) .
C2 O15 C3 C4 169.9(16) .
K1 O15 C3 C4 42.5(19) .
C5 O16 C4 C3 -176.8(13) .
K1 O16 C4 C3 53.2(14) .
O15 C3 C4 O16 -63.1(19) .
C4 O16 C5 C6 176.7(12) .
K1 O16 C5 C6 -53.1(14) .
C7 O17 C6 C5 -178.0(16) .
K1 O17 C6 C5 -49.2(17) .
O16 C5 C6 O17 69.1(17) .
C6 O17 C7 C8 -179.2(17) .
K1 O17 C7 C8 52(2) .
C9 O18 C8 C7 175.8(19) .
K1 O18 C8 C7 44(2) .
O17 C7 C8 O18 -66(2) .
C8 O18 C9 C10 173.5(19) .
K1 O18 C9 C10 -55(2) .
O18 C9 C10 O19 63(2) .
C11 O19 C10 C9 -169.9(17) .
K1 O19 C10 C9 -39(2) .
C10 O19 C11 C12 179.1(15) .
K1 O19 C11 C12 47.4(16) .
C1 O14 C12 C11 -176.5(17) .
K1 O14 C12 C11 49.4(18) .
O19 C11 C12 O14 -64(2) .
C24 O20 C13 C14 -173(4) .
K2 O20 C13 C14 61(3) .
C15 O21 C14 C13 175.0(18) .
K2 O21 C14 C13 43(2) .
O20 C13 C14 O21 -68(3) .
C14 O21 C15 C16 173.0(18) .
K2 O21 C15 C16 -53(2) .
C17 O22 C16 C15 -177(2) .
K2 O22 C16 C15 -43(2) .
O21 C15 C16 O22 66(2) .
C16 O22 C17 C18 -174(3) .
K2 O22 C17 C18 52(3) .
O22 C17 C18 O23 -64(4) .
K2 C17 C18 O23 -30(2) .
C19 O23 C18 C17 179(3) .
K2 O23 C18 C17 41(3) .
C18 O23 C19 C20 177(3) .
K2 O23 C19 C20 -47(3) .
C21 O24 C20 C19 168(2) .
K2 O24 C20 C19 -57(3) .
O23 C19 C20 O24 68(3) .
C20 O24 C21 C22 178(2) .
K2 O24 C21 C22 44(3) .
C23 O25 C22 C21 163(3) .
K2 O25 C22 C21 53(3) .
O24 C21 C22 O25 -63(3) .
C22 O25 C23 C24 171(2) .
K2 O25 C23 C24 -70(3) .
C13 O20 C24 C23 -172(3) .
K2 O20 C24 C23 -43(5) .
O25 C23 C24 O20 84(5) .
