#------------------------------------------------------------------------------
#$Date: 2019-10-29 06:16:43 +0200 (Tue, 29 Oct 2019) $
#$Revision: 220352 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/05/89/7058951.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7058951
loop_
_publ_author_name
'Stierstorfer, Joerg'
'Wurzenberger, Maximilian Hans Horst'
'Lommel, Marcus'
'Gruhne, Michael S.'
'Szimhardt, Norbert'
'Bissinger, Benjamin'
_publ_section_title
;
 Synthesis and Comparison of Copper(II) Complexes with various
 N-Aminotetrazole Ligands Involving Trinitrophenol Anions
;
_journal_name_full               'New Journal of Chemistry'
_journal_paper_doi               10.1039/C9NJ03937F
_journal_year                    2019
_chemical_formula_moiety         'C16 H16 Cu N26 O18'
_chemical_formula_sum            'C16 H16 Cu N26 O18'
_chemical_formula_weight         924.09
_chemical_name_common
'tetrakis(2-aminotetrazolyl) bis(phloroglucinato) copper(II)'
_chemical_name_systematic
;
tetrakis(2-aminotetrazolyl) bis(phloroglucinato) copper(II)
;
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_date
;
'Wed Apr 12 16:27:45 2017'
;
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2019-08-26 deposited with the CCDC.    2019-10-28 downloaded from the CCDC.
;
_cell_angle_alpha                106.515(9)
_cell_angle_beta                 101.929(7)
_cell_angle_gamma                107.829(8)
_cell_formula_units_Z            1
_cell_length_a                   8.6130(7)
_cell_length_b                   9.2780(9)
_cell_length_c                   11.6430(12)
_cell_measurement_reflns_used    1984
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      30.6410
_cell_measurement_theta_min      4.5950
_cell_volume                     804.01(16)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_molecular_graphics    'Diamond 2.1c, Crystal Impact GbR'
_computing_publication_material  'enCIFer 1.5.1 (CCDC 2014)'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    SIR-92
_diffrn_ambient_temperature      173(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 15.9809
_diffrn_detector_type            Sapphire3
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -82.00   47.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -      -28.6994   19.0000 -150.0000 129

#__ type_ start__ end____ width___ exp.time_
  2 omega  -98.00  -47.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -      -28.6994 -179.0000 -180.0000 51

#__ type_ start__ end____ width___ exp.time_
  3 omega -101.00  -24.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -      -28.6994  -77.0000   60.0000 77

#__ type_ start__ end____ width___ exp.time_
  4 omega -109.00  -45.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -      -28.6994 -179.0000 -120.0000 64

#__ type_ start__ end____ width___ exp.time_
  5 omega -109.00  -69.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -      -28.6994 -179.0000   90.0000 40

#__ type_ start__ end____ width___ exp.time_
  6 omega   25.00   73.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       29.7932  -99.0000   90.0000 48

#__ type_ start__ end____ width___ exp.time_
  7 omega   40.00   65.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       29.7932  -99.0000  -90.0000 25

#__ type_ start__ end____ width___ exp.time_
  8 omega  -21.00   12.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       29.7932  -99.0000  -90.0000 33

;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0214060000
_diffrn_orient_matrix_UB_12      -0.0359298000
_diffrn_orient_matrix_UB_13      0.0438021000
_diffrn_orient_matrix_UB_21      -0.0885979000
_diffrn_orient_matrix_UB_22      -0.0312509000
_diffrn_orient_matrix_UB_23      -0.0354794000
_diffrn_orient_matrix_UB_31      0.0063789000
_diffrn_orient_matrix_UB_32      -0.0722802000
_diffrn_orient_matrix_UB_33      -0.0364219000
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0304
_diffrn_reflns_av_sigmaI/netI    0.0678
_diffrn_reflns_av_unetI/netI     0.0488
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       11
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            6244
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.240
_diffrn_reflns_theta_max         25.997
_diffrn_reflns_theta_min         4.261
_diffrn_source                   'Enhance (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    0.805
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.98572
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.909
_exptl_crystal_description       block
_exptl_crystal_F_000             467
_exptl_crystal_size_max          0.260
_exptl_crystal_size_mid          0.230
_exptl_crystal_size_min          0.130
_refine_diff_density_max         0.398
_refine_diff_density_min         -0.317
_refine_diff_density_rms         0.065
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.098
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     295
_refine_ls_number_reflns         3143
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.098
_refine_ls_R_factor_all          0.0489
_refine_ls_R_factor_gt           0.0363
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0332P)²+0.0636P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0797
_refine_ls_wR_factor_ref         0.0868
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2592
_reflns_number_total             3143
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c9nj03937f2.cif
_cod_data_source_block           mx174
_cod_original_cell_volume        804.01(14)
_cod_database_code               7058951
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.818
_shelx_estimated_absorpt_t_max   0.903
_shelxl_version_number           2013-4
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Cu1 Cu 0.5000 0.5000 0.0000 0.01863(13) Uani 1 2 d S . P
O1 O 0.4266(2) 0.4423(2) 0.17113(16) 0.0247(4) Uani 1 1 d . . .
O2 O 0.5504(3) 0.7386(2) 0.37294(19) 0.0368(5) Uani 1 1 d . . .
O3 O 0.8215(3) 0.7815(2) 0.43321(18) 0.0363(5) Uani 1 1 d . . .
O4 O 0.8182(3) 0.5977(2) 0.57449(18) 0.0364(5) Uani 1 1 d . . .
H4 H 0.8609 0.5570 0.6222 0.055 Uiso 1 1 calc R U .
O5 O 0.8481(3) 0.3687(2) 0.64325(18) 0.0392(5) Uani 1 1 d . . .
O6 O 0.6994(3) 0.1159(2) 0.52413(18) 0.0364(5) Uani 1 1 d . . .
O7 O 0.4863(2) 0.02895(19) 0.31046(17) 0.0259(4) Uani 1 1 d . . .
H7 H 0.5420 0.0155 0.3721 0.039 Uiso 1 1 calc R U .
O8 O 0.3785(2) 0.0047(2) 0.06755(16) 0.0272(4) Uani 1 1 d . . .
O9 O 0.1957(2) 0.1180(2) 0.08265(17) 0.0312(5) Uani 1 1 d . . .
N1 N 0.1780(3) 0.0143(2) -0.2222(2) 0.0259(5) Uani 1 1 d . . .
N2 N 0.0799(3) 0.0994(2) -0.23113(19) 0.0200(5) Uani 1 1 d . . .
N3 N 0.1574(3) 0.2558(2) -0.17113(19) 0.0212(5) Uani 1 1 d . . .
N4 N 0.3212(3) 0.2794(2) -0.11626(18) 0.0188(4) Uani 1 1 d . . .
N5 N -0.0943(3) 0.0232(3) -0.2957(3) 0.0318(6) Uani 1 1 d . . .
N6 N 0.8781(3) 0.3159(3) -0.0427(2) 0.0253(5) Uani 1 1 d . . .
N7 N 0.8704(2) 0.3280(2) 0.07229(19) 0.0193(5) Uani 1 1 d . . .
N8 N 0.7553(3) 0.3793(2) 0.10470(19) 0.0205(5) Uani 1 1 d . . .
N9 N 0.6799(2) 0.4038(2) 0.00408(18) 0.0186(4) Uani 1 1 d . . .
N10 N 0.9790(3) 0.2918(3) 0.1562(2) 0.0279(5) Uani 1 1 d . . .
N11 N 0.6680(3) 0.6914(3) 0.3956(2) 0.0266(5) Uani 1 1 d . . .
N12 N 0.7395(3) 0.2643(3) 0.5416(2) 0.0288(5) Uani 1 1 d . . .
N13 N 0.3351(3) 0.1115(2) 0.12493(19) 0.0204(5) Uani 1 1 d . . .
C1 C 0.3286(3) 0.1317(3) -0.1501(2) 0.0235(6) Uani 1 1 d . . .
H1 H 0.4310 0.1136 -0.1251 0.028 Uiso 1 1 calc R U .
C2 C 0.7564(3) 0.3659(3) -0.0827(2) 0.0227(6) Uani 1 1 d . . .
H2 H 0.7268 0.3740 -0.1632 0.027 Uiso 1 1 calc R U .
C3 C 0.4936(3) 0.4034(3) 0.2577(2) 0.0197(5) Uani 1 1 d . . .
C4 C 0.6219(3) 0.5194(3) 0.3754(2) 0.0214(5) Uani 1 1 d . . .
C5 C 0.7056(3) 0.4791(3) 0.4680(2) 0.0241(6) Uani 1 1 d . . .
C6 C 0.6616(3) 0.3096(3) 0.4477(2) 0.0237(6) Uani 1 1 d . . .
C7 C 0.5350(3) 0.1878(3) 0.3331(2) 0.0198(5) Uani 1 1 d . . .
C8 C 0.4557(3) 0.2361(3) 0.2443(2) 0.0183(5) Uani 1 1 d . . .
H5A H -0.128(4) 0.097(4) -0.307(3) 0.035(8) Uiso 1 1 d . . .
H5B H -0.106(4) -0.042(4) -0.370(3) 0.042(10) Uiso 1 1 d . . .
H10B H 1.053(4) 0.276(4) 0.126(3) 0.048(10) Uiso 1 1 d . . .
H10A H 0.909(5) 0.200(5) 0.166(4) 0.070(12) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N4 Cu1 N4 180.0 2_665 .
N4 Cu1 N9 90.83(7) 2_665 .
N4 Cu1 N9 89.17(7) . .
N4 Cu1 N9 89.17(7) 2_665 2_665
N4 Cu1 N9 90.83(7) . 2_665
N9 Cu1 N9 180.0 . 2_665
N4 Cu1 O1 88.37(7) 2_665 2_665
N4 Cu1 O1 91.62(7) . 2_665
N9 Cu1 O1 84.62(7) . 2_665
N9 Cu1 O1 95.38(7) 2_665 2_665
N4 Cu1 O1 91.62(7) 2_665 .
N4 Cu1 O1 88.38(7) . .
N9 Cu1 O1 95.38(7) . .
N9 Cu1 O1 84.62(7) 2_665 .
O1 Cu1 O1 180.0 2_665 .
C3 O1 Cu1 135.50(15) . .
C5 O4 H4 109.5 . .
C7 O7 H7 109.5 . .
C1 N1 N2 101.07(19) . .
N3 N2 N1 115.6(2) . .
N3 N2 N5 122.9(2) . .
N1 N2 N5 121.3(2) . .
N2 N3 N4 104.51(17) . .
C1 N4 N3 106.31(19) . .
C1 N4 Cu1 131.16(16) . .
N3 N4 Cu1 122.43(14) . .
N2 N5 H5A 106(2) . .
N2 N5 H5B 107(2) . .
H5A N5 H5B 107(3) . .
C2 N6 N7 100.95(19) . .
N8 N7 N6 115.86(18) . .
N8 N7 N10 120.7(2) . .
N6 N7 N10 123.4(2) . .
N7 N8 N9 103.96(19) . .
N8 N9 C2 107.38(17) . .
N8 N9 Cu1 123.27(15) . .
C2 N9 Cu1 129.14(16) . .
N7 N10 H10B 108(2) . .
N7 N10 H10A 106(2) . .
H10B N10 H10A 113(3) . .
O2 N11 O3 123.4(2) . .
O2 N11 C4 117.9(2) . .
O3 N11 C4 118.6(2) . .
O5 N12 O6 119.0(2) . .
O5 N12 C6 121.2(2) . .
O6 N12 C6 119.8(2) . .
O9 N13 O8 122.2(2) . .
O9 N13 C8 119.19(18) . .
O8 N13 C8 118.58(18) . .
N1 C1 N4 112.5(2) . .
N1 C1 H1 123.8 . .
N4 C1 H1 123.8 . .
N6 C2 N9 111.8(2) . .
N6 C2 H2 124.1 . .
N9 C2 H2 124.1 . .
O1 C3 C4 123.7(2) . .
O1 C3 C8 122.4(2) . .
C4 C3 C8 113.7(2) . .
C5 C4 C3 124.7(2) . .
C5 C4 N11 118.3(2) . .
C3 C4 N11 117.0(2) . .
O4 C5 C4 119.1(2) . .
O4 C5 C6 122.5(2) . .
C4 C5 C6 118.4(2) . .
N12 C6 C7 120.1(2) . .
N12 C6 C5 120.0(2) . .
C7 C6 C5 119.9(2) . .
O7 C7 C8 118.6(2) . .
O7 C7 C6 122.5(2) . .
C8 C7 C6 118.8(2) . .
C7 C8 C3 124.4(2) . .
C7 C8 N13 118.3(2) . .
C3 C8 N13 117.1(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cu1 N4 2.006(2) 2_665
Cu1 N4 2.006(2) .
Cu1 N9 2.0101(17) .
Cu1 N9 2.0101(17) 2_665
Cu1 O1 2.3614(17) 2_665
Cu1 O1 2.3614(17) .
O1 C3 1.254(3) .
O2 N11 1.230(3) .
O3 N11 1.231(3) .
O4 C5 1.328(3) .
O4 H4 0.8400 .
O5 N12 1.245(3) .
O6 N12 1.256(3) .
O7 C7 1.331(3) .
O7 H7 0.8400 .
O8 N13 1.234(2) .
O9 N13 1.227(2) .
N1 C1 1.318(3) .
N1 N2 1.330(3) .
N2 N3 1.295(3) .
N2 N5 1.378(3) .
N3 N4 1.343(3) .
N4 C1 1.340(3) .
N5 H5A 0.85(3) .
N5 H5B 0.86(3) .
N6 C2 1.323(3) .
N6 N7 1.329(3) .
N7 N8 1.302(3) .
N7 N10 1.394(3) .
N8 N9 1.331(3) .
N9 C2 1.339(3) .
N10 H10B 0.82(3) .
N10 H10A 0.93(4) .
N11 C4 1.456(3) .
N12 C6 1.397(3) .
N13 C8 1.449(3) .
C1 H1 0.9500 .
C2 H2 0.9500 .
C3 C4 1.437(3) .
C3 C8 1.439(3) .
C4 C5 1.376(3) .
C5 C6 1.435(3) .
C6 C7 1.426(3) .
C7 C8 1.378(3) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O4 H4 O5 0.84 1.81 2.537(3) 144.5 .
O4 H4 N12 0.84 2.40 2.847(3) 114.1 .
O4 H4 N10 0.84 2.41 2.957(3) 123.3 2_766
O7 H7 O6 0.84 1.77 2.505(2) 144.8 .
O7 H7 N12 0.84 2.39 2.843(3) 114.1 .
O7 H7 O2 0.84 2.60 3.154(2) 125.1 1_545
N5 H5A O6 0.85(3) 2.30(3) 2.952(3) 134(3) 1_454
N5 H5B O3 0.86(3) 2.23(3) 3.090(4) 171(3) 1_444
N10 H10B O9 0.82(3) 2.20(3) 2.921(3) 146(3) 1_655
N10 H10A N1 0.93(4) 2.23(4) 3.131(3) 162(3) 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C1 N1 N2 N3 -0.2(3)
C1 N1 N2 N5 -177.4(2)
N1 N2 N3 N4 -0.4(3)
N5 N2 N3 N4 176.8(2)
N2 N3 N4 C1 0.8(2)
N2 N3 N4 Cu1 -175.88(15)
C2 N6 N7 N8 0.4(3)
C2 N6 N7 N10 -178.5(2)
N6 N7 N8 N9 -0.1(3)
N10 N7 N8 N9 178.9(2)
N7 N8 N9 C2 -0.3(2)
N7 N8 N9 Cu1 -175.39(15)
N2 N1 C1 N4 0.7(3)
N3 N4 C1 N1 -1.0(3)
Cu1 N4 C1 N1 175.26(17)
N7 N6 C2 N9 -0.6(3)
N8 N9 C2 N6 0.6(3)
Cu1 N9 C2 N6 175.30(16)
Cu1 O1 C3 C4 84.9(3)
Cu1 O1 C3 C8 -91.2(3)
O1 C3 C4 C5 -175.4(2)
C8 C3 C4 C5 1.0(4)
O1 C3 C4 N11 3.3(4)
C8 C3 C4 N11 179.7(2)
O2 N11 C4 C5 -133.8(2)
O3 N11 C4 C5 46.8(3)
O2 N11 C4 C3 47.5(3)
O3 N11 C4 C3 -131.9(2)
C3 C4 C5 O4 -178.0(2)
N11 C4 C5 O4 3.3(4)
C3 C4 C5 C6 -0.7(4)
N11 C4 C5 C6 -179.4(2)
O5 N12 C6 C7 -178.7(2)
O6 N12 C6 C7 0.9(4)
O5 N12 C6 C5 -0.4(4)
O6 N12 C6 C5 179.2(2)
O4 C5 C6 N12 -0.6(4)
C4 C5 C6 N12 -177.7(2)
O4 C5 C6 C7 177.7(2)
C4 C5 C6 C7 0.6(4)
N12 C6 C7 O7 -0.1(4)
C5 C6 C7 O7 -178.4(2)
N12 C6 C7 C8 177.6(2)
C5 C6 C7 C8 -0.7(4)
O7 C7 C8 C3 178.8(2)
C6 C7 C8 C3 1.1(4)
O7 C7 C8 N13 -6.0(3)
C6 C7 C8 N13 176.2(2)
O1 C3 C8 C7 175.3(2)
C4 C3 C8 C7 -1.2(3)
O1 C3 C8 N13 0.1(3)
C4 C3 C8 N13 -176.40(19)
O9 N13 C8 C7 133.7(2)
O8 N13 C8 C7 -48.3(3)
O9 N13 C8 C3 -50.8(3)
O8 N13 C8 C3 127.2(2)
