#------------------------------------------------------------------------------
#$Date: 2016-03-26 02:13:44 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180129 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/27/7102731.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7102731
loop_
_publ_author_name
'Zhang, Jianyong'
'Nieuwenhuyzen, Mark'
'Charmant, Jonathan P H'
'James, Stuart L'
_publ_section_title
;
 A discrete dimer of coordination clusters connected through additional
 bridging ligands.
;
_journal_issue                   24
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              2808
_journal_page_last               2809
_journal_paper_doi               10.1039/b409502b
_journal_year                    2004
_chemical_formula_sum            'C266 H207 Ag8 Cl3 F48 N25 O8 P18 Sb8'
_chemical_formula_weight         7294.34
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 94.920(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   24.491(11)
_cell_length_b                   17.774(8)
_cell_length_c                   35.165(16)
_cell_measurement_temperature    153(2)
_cell_volume                     15251(12)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1851
_diffrn_reflns_av_sigmaI/netI    0.2125
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       41
_diffrn_reflns_limit_l_min       -41
_diffrn_reflns_number            144575
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         0.83
_exptl_absorpt_coefficient_mu    1.401
_exptl_absorpt_correction_T_max  0.7966
_exptl_absorpt_correction_T_min  0.6472
_exptl_absorpt_correction_type   none
_exptl_absorpt_process_details   empirical
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.588
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'irregular chunk'
_exptl_crystal_F_000             7158
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.17
_refine_diff_density_max         2.671
_refine_diff_density_min         -2.486
_refine_diff_density_rms         0.227
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.230
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1559
_refine_ls_number_reflns         26831
_refine_ls_number_restraints     373
_refine_ls_restrained_S_all      1.333
_refine_ls_R_factor_all          0.2502
_refine_ls_R_factor_gt           0.1019
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w==1/[σ²(Fo²)+(0.1016P)²+0.0000P] where P==(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2543
_refine_ls_wR_factor_ref         0.3042
_reflns_number_gt                9411
_reflns_number_total             26831
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b409502b.txt
_cod_data_source_block           jz002m
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not_measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               7102731
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.35331(6) -0.78094(9) 0.69037(4) 0.0469(4) Uani 1 1 d . . .
Ag2 Ag 0.15872(6) -0.95376(8) 0.59908(4) 0.0430(4) Uani 1 1 d . . .
Ag3 Ag 0.32041(6) -0.65193(9) 0.52343(4) 0.0491(4) Uani 1 1 d . . .
Ag4 Ag 0.17240(7) -0.56382(9) 0.68017(5) 0.0593(5) Uani 1 1 d . . .
P1 P 0.3884(2) -0.6507(3) 0.70033(15) 0.0490(14) Uani 1 1 d . . .
P2 P 0.2884(2) -0.8413(3) 0.73222(14) 0.0407(13) Uani 1 1 d . . .
P3 P 0.4077(2) -0.8581(3) 0.64672(14) 0.0404(13) Uani 1 1 d . . .
P4 P 0.2380(2) -1.0131(3) 0.57469(14) 0.0385(13) Uani 1 1 d . . .
P5 P 0.1056(2) -0.9464(3) 0.65365(15) 0.0435(13) Uani 1 1 d . . .
P6 P 0.3346(2) -0.7804(3) 0.50337(14) 0.0439(13) Uani 1 1 d . . .
P7 P 0.3709(2) -0.5452(3) 0.55300(15) 0.0447(14) Uani 1 1 d . . .
P8 P 0.1147(2) -0.6548(3) 0.70652(15) 0.0441(13) Uani 1 1 d . . .
P9 P 0.2271(2) -0.4645(3) 0.65685(16) 0.0446(14) Uani 1 1 d . . .
N1S N 0.1161(8) -0.8812(11) 0.5493(6) 0.074(6) Uani 1 1 d . . .
C2S C 0.0853(10) -0.8302(13) 0.5423(6) 0.064(7) Uani 1 1 d . . .
C3S C 0.0464(9) -0.7739(13) 0.5347(7) 0.060(6) Uani 1 1 d . . .
C4S C -0.0077(12) -0.7931(14) 0.5351(8) 0.101(10) Uani 1 1 d . . .
H4SA H -0.0175 -0.8439 0.5395 0.122 Uiso 1 1 calc R . .
C5S C -0.0498(10) -0.7371(14) 0.5290(8) 0.091(9) Uani 1 1 d . . .
H5SA H -0.0870 -0.7487 0.5319 0.110 Uiso 1 1 calc R . .
C6S C -0.0347(8) -0.6670(11) 0.5189(6) 0.048(5) Uani 1 1 d . . .
C7S C 0.0182(8) -0.6529(13) 0.5143(7) 0.070(7) Uani 1 1 d . . .
H7SA H 0.0279 -0.6044 0.5057 0.084 Uiso 1 1 calc R . .
C8S C 0.0589(10) -0.7057(14) 0.5214(8) 0.084(8) Uani 1 1 d . . .
H8SA H 0.0956 -0.6939 0.5170 0.101 Uiso 1 1 calc R . .
C9S C -0.0802(8) -0.6111(12) 0.5105(6) 0.056(6) Uani 1 1 d . . .
C10S C -0.1238(8) -0.6094(12) 0.5334(6) 0.055(6) Uani 1 1 d . . .
H10A H -0.1259 -0.6445 0.5536 0.066 Uiso 1 1 calc R . .
C11S C -0.1636(8) -0.5561(12) 0.5262(6) 0.056(6) Uani 1 1 d . . .
H11A H -0.1943 -0.5556 0.5410 0.067 Uiso 1 1 calc R . .
C12S C -0.1602(9) -0.5037(12) 0.4983(6) 0.054(6) Uani 1 1 d . . .
C13S C -0.1165(9) -0.5061(12) 0.4759(7) 0.063(6) Uani 1 1 d . . .
H13A H -0.1150 -0.4709 0.4557 0.076 Uiso 1 1 calc R . .
C14S C -0.0755(9) -0.5576(12) 0.4820(6) 0.061(6) Uani 1 1 d . . .
H14A H -0.0448 -0.5572 0.4673 0.073 Uiso 1 1 calc R . .
C15S C -0.2026(9) -0.4501(13) 0.4933(6) 0.059(6) Uani 1 1 d . . .
N16S N -0.2353(7) -0.4035(12) 0.4901(6) 0.073(6) Uani 1 1 d . . .
C1 C 0.3593(8) -0.5892(11) 0.6637(5) 0.043(5) Uani 1 1 d . . .
N2 N 0.3792(6) -0.5876(8) 0.6274(4) 0.039(4) Uani 1 1 d . . .
C3 C 0.3520(7) -0.5441(11) 0.6011(5) 0.036(5) Uani 1 1 d . . .
N4 N 0.3078(6) -0.5016(8) 0.6078(4) 0.038(4) Uani 1 1 d . . .
C5 C 0.2895(8) -0.5082(10) 0.6428(6) 0.047(5) Uani 1 1 d . . .
N6 N 0.3133(6) -0.5527(9) 0.6713(4) 0.043(4) Uani 1 1 d . . .
C7 C 0.3519(8) -0.4533(11) 0.5353(6) 0.044(5) Uani 1 1 d . . .
C8 C 0.3661(8) -0.3891(12) 0.5545(7) 0.058(6) Uani 1 1 d . . .
H8A H 0.3840 -0.3919 0.5795 0.069 Uiso 1 1 calc R . .
C9 C 0.3543(9) -0.3171(13) 0.5375(7) 0.063(6) Uani 1 1 d . . .
H9A H 0.3653 -0.2727 0.5511 0.075 Uiso 1 1 calc R . .
C10 C 0.3271(8) -0.3117(14) 0.5013(7) 0.060(6) Uani 1 1 d . . .
H10B H 0.3177 -0.2641 0.4904 0.072 Uiso 1 1 calc R . .
C11 C 0.3137(9) -0.3790(14) 0.4813(7) 0.069(7) Uani 1 1 d . . .
H11B H 0.2967 -0.3771 0.4560 0.083 Uiso 1 1 calc R . .
C12 C 0.3257(8) -0.4483(11) 0.4988(5) 0.046(5) Uani 1 1 d . . .
H12A H 0.3157 -0.4932 0.4853 0.055 Uiso 1 1 calc R . .
C13 C 0.4453(7) -0.5474(10) 0.5564(5) 0.039(5) Uani 1 1 d D . .
C14 C 0.4767(7) -0.5075(12) 0.5823(5) 0.058(6) Uani 1 1 d D . .
H14B H 0.4600 -0.4830 0.6023 0.069 Uiso 1 1 calc R . .
C15 C 0.5332(7) -0.5010(11) 0.5806(6) 0.056(6) Uani 1 1 d D . .
H15A H 0.5535 -0.4686 0.5981 0.068 Uiso 1 1 calc R . .
C16 C 0.5589(8) -0.5389(12) 0.5553(6) 0.067(7) Uani 1 1 d D . .
H16A H 0.5976 -0.5366 0.5551 0.080 Uiso 1 1 calc R . .
C17 C 0.5269(8) -0.5830(12) 0.5286(6) 0.068(7) Uani 1 1 d D . .
H17A H 0.5436 -0.6109 0.5098 0.082 Uiso 1 1 calc R . .
C18 C 0.4709(7) -0.5850(11) 0.5303(5) 0.056(6) Uani 1 1 d D . .
H18A H 0.4495 -0.6144 0.5120 0.067 Uiso 1 1 calc R . .
C19 C 0.1987(7) -0.4038(12) 0.6190(6) 0.048(5) Uani 1 1 d U . .
C20 C 0.1427(9) -0.3854(17) 0.6188(7) 0.094(8) Uani 1 1 d U . .
H20A H 0.1204 -0.4109 0.6354 0.113 Uiso 1 1 calc R . .
C21 C 0.1193(11) -0.3286(17) 0.5935(8) 0.100(8) Uani 1 1 d U . .
H21A H 0.0832 -0.3102 0.5955 0.120 Uiso 1 1 calc R . .
C22 C 0.1504(10) -0.3025(15) 0.5668(7) 0.080(7) Uani 1 1 d U . .
H22A H 0.1338 -0.2693 0.5481 0.097 Uiso 1 1 calc R . .
C23 C 0.2031(9) -0.3200(12) 0.5648(6) 0.056(6) Uani 1 1 d U . .
H23A H 0.2234 -0.2979 0.5459 0.067 Uiso 1 1 calc R . .
C24 C 0.2269(9) -0.3693(12) 0.5900(6) 0.057(6) Uani 1 1 d U . .
H24A H 0.2644 -0.3817 0.5883 0.069 Uiso 1 1 calc R . .
C25 C 0.2503(8) -0.4041(11) 0.6963(5) 0.048(5) Uani 1 1 d U . .
C26 C 0.2111(10) -0.3772(15) 0.7193(6) 0.083(7) Uani 1 1 d U . .
H26A H 0.1737 -0.3904 0.7140 0.100 Uiso 1 1 calc R . .
C27 C 0.2270(12) -0.3313(17) 0.7499(8) 0.108(9) Uani 1 1 d U . .
H27A H 0.2004 -0.3134 0.7658 0.130 Uiso 1 1 calc R . .
C28 C 0.2800(11) -0.3116(15) 0.7573(7) 0.080(7) Uani 1 1 d U . .
H28A H 0.2898 -0.2788 0.7781 0.096 Uiso 1 1 calc R . .
C29 C 0.3191(10) -0.3368(13) 0.7363(6) 0.075(7) Uani 1 1 d U . .
H29A H 0.3563 -0.3236 0.7426 0.090 Uiso 1 1 calc R . .
C30 C 0.3042(9) -0.3827(13) 0.7051(6) 0.067(6) Uani 1 1 d U . .
H30A H 0.3316 -0.3996 0.6895 0.080 Uiso 1 1 calc R . .
C31 C 0.2161(7) -0.8249(12) 0.7143(5) 0.042(5) Uani 1 1 d . . .
N32 N 0.1903(6) -0.8857(8) 0.6962(4) 0.038(4) Uani 1 1 d . . .
C33 C 0.1389(8) -0.8716(11) 0.6831(5) 0.039(5) Uani 1 1 d . . .
N34 N 0.1116(6) -0.8052(9) 0.6865(4) 0.043(4) Uani 1 1 d . . .
C35 C 0.1426(8) -0.7494(10) 0.7035(5) 0.039(5) Uani 1 1 d . . .
N36 N 0.1946(6) -0.7565(8) 0.7185(4) 0.037(4) Uani 1 1 d . . .
C37 C 0.0350(8) -0.9220(11) 0.6454(6) 0.047(5) Uani 1 1 d . . .
C38 C 0.0046(8) -0.8925(13) 0.6754(7) 0.066(7) Uani 1 1 d . . .
H38A H 0.0233 -0.8837 0.6998 0.079 Uiso 1 1 calc R . .
C39 C -0.0497(10) -0.8767(14) 0.6702(8) 0.080(8) Uani 1 1 d . . .
H39A H -0.0694 -0.8570 0.6902 0.096 Uiso 1 1 calc R . .
C40 C -0.0754(10) -0.8913(14) 0.6333(9) 0.079(8) Uani 1 1 d . . .
H40A H -0.1126 -0.8766 0.6281 0.095 Uiso 1 1 calc R . .
C41 C -0.0491(9) -0.9263(18) 0.6040(8) 0.100(10) Uani 1 1 d . . .
H41A H -0.0687 -0.9404 0.5806 0.120 Uiso 1 1 calc R . .
C42 C 0.0073(8) -0.9394(13) 0.6108(7) 0.068(7) Uani 1 1 d . . .
H42A H 0.0267 -0.9607 0.5912 0.082 Uiso 1 1 calc R . .
C43 C 0.1075(8) -1.0316(11) 0.6841(5) 0.043(5) Uani 1 1 d U . .
C44 C 0.0606(9) -1.0697(14) 0.6898(7) 0.073(7) Uani 1 1 d U . .
H44A H 0.0259 -1.0498 0.6806 0.088 Uiso 1 1 calc R . .
C45 C 0.0636(11) -1.1365(16) 0.7088(8) 0.102(9) Uani 1 1 d U . .
H45A H 0.0308 -1.1636 0.7118 0.122 Uiso 1 1 calc R . .
C46 C 0.1128(10) -1.1657(15) 0.7238(8) 0.102(9) Uani 1 1 d U . .
H46A H 0.1142 -1.2113 0.7380 0.123 Uiso 1 1 calc R . .
C47 C 0.1593(9) -1.1276(12) 0.7179(7) 0.072(7) Uani 1 1 d U . .
H47A H 0.1937 -1.1471 0.7278 0.087 Uiso 1 1 calc R . .
C48 C 0.1576(8) -1.0616(12) 0.6979(6) 0.053(5) Uani 1 1 d U . .
H48A H 0.1907 -1.0364 0.6935 0.063 Uiso 1 1 calc R . .
C49 C 0.0475(8) -0.6595(11) 0.6834(6) 0.051(5) Uani 1 1 d U . .
C50 C 0.0023(8) -0.6834(14) 0.6991(7) 0.069(6) Uani 1 1 d U . .
H50A H 0.0056 -0.7005 0.7248 0.083 Uiso 1 1 calc R . .
C51 C -0.0488(10) -0.6839(15) 0.6790(7) 0.078(7) Uani 1 1 d U . .
H51A H -0.0798 -0.7011 0.6909 0.094 Uiso 1 1 calc R . .
C52 C -0.0546(10) -0.6608(16) 0.6436(8) 0.089(8) Uani 1 1 d U . .
H52A H -0.0901 -0.6610 0.6304 0.106 Uiso 1 1 calc R . .
C53 C -0.0105(10) -0.6361(18) 0.6245(8) 0.107(9) Uani 1 1 d U . .
H53A H -0.0152 -0.6198 0.5987 0.129 Uiso 1 1 calc R . .
C54 C 0.0411(10) -0.6361(17) 0.6448(7) 0.099(8) Uani 1 1 d U . .
H54A H 0.0722 -0.6203 0.6326 0.119 Uiso 1 1 calc R . .
C55 C 0.1076(8) -0.6473(13) 0.7559(6) 0.052(6) Uani 1 1 d . . .
C56 C 0.1099(9) -0.5765(15) 0.7727(7) 0.080(8) Uani 1 1 d . . .
H56A H 0.1152 -0.5335 0.7573 0.096 Uiso 1 1 calc R . .
C57 C 0.1043(14) -0.567(2) 0.8124(9) 0.121(13) Uani 1 1 d . . .
H57A H 0.1077 -0.5188 0.8240 0.145 Uiso 1 1 calc R . .
C58 C 0.0939(10) -0.630(2) 0.8335(8) 0.094(11) Uani 1 1 d . . .
H58A H 0.0892 -0.6238 0.8599 0.113 Uiso 1 1 calc R . .
C59 C 0.0898(12) -0.704(2) 0.8178(8) 0.110(11) Uani 1 1 d . . .
H59A H 0.0824 -0.7467 0.8326 0.132 Uiso 1 1 calc R . .
C60 C 0.0975(9) -0.7078(15) 0.7789(7) 0.072(7) Uani 1 1 d . . .
H60A H 0.0957 -0.7562 0.7673 0.086 Uiso 1 1 calc R . .
C61 C 0.2945(7) -0.9452(10) 0.5728(5) 0.031(4) Uani 1 1 d . . .
N62 N 0.3269(6) -0.9363(8) 0.6046(4) 0.042(4) Uani 1 1 d . . .
C63 C 0.3639(7) -0.8816(10) 0.6042(5) 0.032(4) Uani 1 1 d . . .
N64 N 0.3673(6) -0.8349(8) 0.5739(4) 0.040(4) Uani 1 1 d . . .
C65 C 0.3317(7) -0.8477(10) 0.5423(5) 0.035(5) Uani 1 1 d . . .
N66 N 0.2939(6) -0.9027(8) 0.5407(4) 0.037(4) Uani 1 1 d . . .
C67 C 0.2665(8) -1.0915(11) 0.6026(5) 0.041(5) Uani 1 1 d . . .
C68 C 0.3194(9) -1.1147(11) 0.6004(5) 0.048(5) Uani 1 1 d . . .
H68A H 0.3431 -1.0860 0.5861 0.058 Uiso 1 1 calc R . .
C69 C 0.3390(9) -1.1793(12) 0.6188(6) 0.056(6) Uani 1 1 d . . .
H69A H 0.3755 -1.1957 0.6165 0.067 Uiso 1 1 calc R . .
C70 C 0.3039(10) -1.2208(12) 0.6409(7) 0.065(7) Uani 1 1 d . . .
H70A H 0.3174 -1.2646 0.6541 0.078 Uiso 1 1 calc R . .
C71 C 0.2495(10) -1.1983(12) 0.6437(6) 0.067(7) Uani 1 1 d . . .
H71A H 0.2259 -1.2259 0.6586 0.080 Uiso 1 1 calc R . .
C72 C 0.2313(9) -1.1333(10) 0.6236(5) 0.047(5) Uani 1 1 d . . .
H72A H 0.1943 -1.1176 0.6243 0.056 Uiso 1 1 calc R . .
C73 C 0.2218(8) -1.0472(10) 0.5272(5) 0.042(5) Uani 1 1 d . . .
C74 C 0.2300(8) -1.1275(11) 0.5184(6) 0.049(5) Uani 1 1 d . . .
H74A H 0.2482 -1.1594 0.5371 0.059 Uiso 1 1 calc R . .
C75 C 0.2117(8) -1.1564(13) 0.4834(6) 0.057(6) Uani 1 1 d . . .
H75A H 0.2145 -1.2088 0.4786 0.068 Uiso 1 1 calc R . .
C76 C 0.1890(9) -1.1086(15) 0.4551(6) 0.069(7) Uani 1 1 d . . .
H76A H 0.1775 -1.1281 0.4306 0.083 Uiso 1 1 calc R . .
C77 C 0.1831(9) -1.0327(12) 0.4623(6) 0.058(6) Uani 1 1 d . . .
H77A H 0.1672 -1.0008 0.4427 0.069 Uiso 1 1 calc R . .
C78 C 0.2000(8) -1.0026(11) 0.4976(6) 0.052(6) Uani 1 1 d . . .
H78A H 0.1966 -0.9500 0.5016 0.063 Uiso 1 1 calc R . .
C79 C 0.4257(8) -0.9429(10) 0.6666(5) 0.057(6) Uiso 1 1 d D . .
C80 C 0.4337(4) -1.0048(7) 0.6482(4) 0.081(8) Uiso 1 1 d D . .
H80 H 0.4272 -1.0034 0.6212 0.097 Uiso 1 1 calc R . .
C81 C 0.4510(4) -1.0732(7) 0.6647(4) 0.131(12) Uiso 1 1 d RD . .
H81 H 0.4563 -1.1160 0.6493 0.157 Uiso 1 1 calc R . .
C82 C 0.4596(4) -1.0768(7) 0.7023(4) 0.111(10) Uiso 1 1 d RD . .
H82 H 0.4717 -1.1221 0.7146 0.133 Uiso 1 1 calc R . .
C83 C 0.4503(4) -1.0109(7) 0.7235(4) 0.131(12) Uiso 1 1 d RD . .
H83 H 0.4547 -1.0111 0.7506 0.157 Uiso 1 1 calc R . .
C84 C 0.4349(4) -0.9480(7) 0.7039(4) 0.085(8) Uiso 1 1 d RD . .
H84 H 0.4303 -0.9036 0.7183 0.102 Uiso 1 1 calc R . .
C85 C 0.4675(8) -0.8197(10) 0.6305(5) 0.040(5) Uani 1 1 d . . .
C86 C 0.5175(8) -0.8604(13) 0.6324(6) 0.065(7) Uani 1 1 d . . .
H86A H 0.5180 -0.9114 0.6403 0.078 Uiso 1 1 calc R . .
C87 C 0.5659(9) -0.8268(15) 0.6227(7) 0.074(8) Uani 1 1 d . . .
H87A H 0.5997 -0.8531 0.6264 0.089 Uiso 1 1 calc R . .
C88 C 0.5642(9) -0.7547(15) 0.6077(7) 0.071(7) Uani 1 1 d . . .
H88A H 0.5966 -0.7329 0.5996 0.085 Uiso 1 1 calc R . .
C89 C 0.5159(10) -0.7142(13) 0.6045(6) 0.063(6) Uani 1 1 d . . .
H89A H 0.5147 -0.6650 0.5939 0.076 Uiso 1 1 calc R . .
C90 C 0.4688(8) -0.7468(12) 0.6172(5) 0.050(6) Uani 1 1 d . . .
H90A H 0.4363 -0.7175 0.6166 0.061 Uiso 1 1 calc R . .
C91 C 0.4611(9) -0.6498(12) 0.6971(6) 0.055(6) Uani 1 1 d . . .
C92 C 0.4895(9) -0.5884(13) 0.6820(6) 0.060(6) Uani 1 1 d . . .
H92A H 0.4706 -0.5442 0.6733 0.072 Uiso 1 1 calc R . .
C93 C 0.5493(10) -0.5954(18) 0.6804(6) 0.084(9) Uani 1 1 d . . .
H93A H 0.5680 -0.5550 0.6695 0.101 Uiso 1 1 calc R . .
C94 C 0.5783(13) -0.6540(17) 0.6930(8) 0.092(10) Uani 1 1 d . . .
H94A H 0.6166 -0.6577 0.6908 0.111 Uiso 1 1 calc R . .
C95 C 0.5494(11) -0.7089(17) 0.7093(8) 0.085(8) Uani 1 1 d . . .
H95A H 0.5699 -0.7498 0.7205 0.102 Uiso 1 1 calc R . .
C96 C 0.4918(10) -0.7112(14) 0.7111(6) 0.070(7) Uani 1 1 d . . .
H96A H 0.4747 -0.7535 0.7216 0.084 Uiso 1 1 calc R . .
C97 C 0.2883(8) -0.8199(13) 0.4656(6) 0.055(6) Uani 1 1 d U . .
C98 C 0.2374(9) -0.7901(14) 0.4567(7) 0.075(7) Uani 1 1 d U . .
H98A H 0.2263 -0.7495 0.4719 0.091 Uiso 1 1 calc R . .
C99 C 0.2015(12) -0.8145(17) 0.4277(8) 0.093(9) Uani 1 1 d U . .
H99A H 0.1674 -0.7898 0.4220 0.112 Uiso 1 1 calc R . .
C100 C 0.2151(12) -0.8725(17) 0.4081(8) 0.090(9) Uani 1 1 d U . .
H10C H 0.1905 -0.8910 0.3878 0.108 Uiso 1 1 calc R . .
C101 C 0.2654(12) -0.9077(16) 0.4163(7) 0.092(8) Uani 1 1 d U . .
H10D H 0.2739 -0.9517 0.4026 0.110 Uiso 1 1 calc R . .
C102 C 0.3034(11) -0.8796(13) 0.4443(6) 0.075(7) Uani 1 1 d U . .
H10E H 0.3388 -0.9011 0.4485 0.090 Uiso 1 1 calc R . .
C103 C 0.4017(9) -0.7883(14) 0.4860(6) 0.066(6) Uani 1 1 d U . .
C104 C 0.4104(10) -0.747(2) 0.4548(8) 0.134(10) Uani 1 1 d U . .
H10F H 0.3823 -0.7167 0.4425 0.161 Uiso 1 1 calc R . .
C105 C 0.4626(12) -0.751(2) 0.4414(9) 0.152(11) Uani 1 1 d U . .
H10G H 0.4680 -0.7314 0.4168 0.182 Uiso 1 1 calc R . .
C106 C 0.5056(10) -0.782(2) 0.4629(9) 0.117(10) Uani 1 1 d U . .
H10H H 0.5401 -0.7838 0.4525 0.140 Uiso 1 1 calc R . .
C107 C 0.5021(12) -0.808(2) 0.4961(10) 0.145(11) Uani 1 1 d U . .
H10I H 0.5335 -0.8235 0.5118 0.174 Uiso 1 1 calc R . .
C108 C 0.4483(11) -0.812(2) 0.5084(8) 0.128(10) Uani 1 1 d U . .
H10J H 0.4440 -0.8314 0.5331 0.154 Uiso 1 1 calc R . .
C109 C 0.3684(12) -0.5992(15) 0.7425(7) 0.094(8) Uiso 1 1 d DU . .
C110 C 0.3978(12) -0.5458(15) 0.7573(8) 0.107(9) Uiso 1 1 d DU . .
H110 H 0.4314 -0.5351 0.7468 0.128 Uiso 1 1 calc R . .
C111 C 0.3848(18) -0.506(2) 0.7853(9) 0.208(17) Uiso 1 1 d DU . .
H111 H 0.4084 -0.4674 0.7961 0.250 Uiso 1 1 calc R . .
C112 C 0.338(2) -0.520(3) 0.7982(16) 0.32(2) Uiso 1 1 d DU . .
H112 H 0.3255 -0.4940 0.8195 0.380 Uiso 1 1 calc R . .
C113 C 0.311(3) -0.571(3) 0.7798(15) 0.37(3) Uiso 1 1 d DU . .
H113 H 0.2757 -0.5787 0.7887 0.443 Uiso 1 1 calc R . .
C114 C 0.3202(13) -0.613(2) 0.7523(11) 0.167(14) Uiso 1 1 d DU . .
H114 H 0.2955 -0.6491 0.7407 0.200 Uiso 1 1 calc R . .
C115 C 0.2946(7) -0.9412(11) 0.7368(5) 0.044(5) Uani 1 1 d . . .
C116 C 0.3055(8) -0.9815(13) 0.7041(6) 0.057(6) Uani 1 1 d . . .
H11H H 0.3084 -0.9564 0.6805 0.068 Uiso 1 1 calc R . .
C117 C 0.3121(8) -1.0619(14) 0.7071(7) 0.060(6) Uani 1 1 d . . .
H11I H 0.3221 -1.0898 0.6857 0.072 Uiso 1 1 calc R . .
C118 C 0.3041(9) -1.0987(13) 0.7407(7) 0.065(7) Uani 1 1 d . . .
H11J H 0.3061 -1.1520 0.7414 0.078 Uiso 1 1 calc R . .
C119 C 0.2936(11) -1.0612(13) 0.7722(7) 0.077(8) Uani 1 1 d . . .
H11K H 0.2900 -1.0871 0.7955 0.093 Uiso 1 1 calc R . .
C120 C 0.2880(9) -0.9812(14) 0.7700(6) 0.067(7) Uani 1 1 d . . .
H12B H 0.2795 -0.9544 0.7921 0.080 Uiso 1 1 calc R . .
C121 C 0.2935(8) -0.8082(12) 0.7799(5) 0.053(5) Uani 1 1 d U . .
C122 C 0.3449(9) -0.8023(15) 0.7982(7) 0.086(8) Uani 1 1 d U . .
H12C H 0.3766 -0.8134 0.7855 0.103 Uiso 1 1 calc R . .
C123 C 0.3490(11) -0.7792(18) 0.8367(8) 0.109(9) Uani 1 1 d U . .
H12D H 0.3842 -0.7821 0.8503 0.131 Uiso 1 1 calc R . .
C124 C 0.3057(11) -0.7522(19) 0.8568(8) 0.110(9) Uani 1 1 d U . .
H12E H 0.3109 -0.7307 0.8816 0.131 Uiso 1 1 calc R . .
C125 C 0.2572(10) -0.7597(15) 0.8379(6) 0.083(7) Uani 1 1 d U . .
H12F H 0.2258 -0.7449 0.8502 0.099 Uiso 1 1 calc R . .
C126 C 0.2491(8) -0.7884(13) 0.8003(5) 0.064(6) Uani 1 1 d U . .
H12G H 0.2129 -0.7944 0.7887 0.077 Uiso 1 1 calc R . .
Sb1 Sb 0.21892(6) -0.71911(8) 0.60338(4) 0.0462(4) Uani 1 1 d D . .
F11 F 0.1945(5) -0.6208(7) 0.5970(4) 0.102(5) Uiso 1 1 d D . .
F12 F 0.2861(4) -0.6996(7) 0.5921(4) 0.084(4) Uiso 1 1 d D . .
F13 F 0.1516(5) -0.7428(8) 0.6143(4) 0.101(5) Uiso 1 1 d D . .
F14 F 0.2424(5) -0.8175(7) 0.6140(4) 0.092(4) Uiso 1 1 d D . .
F15 F 0.2413(5) -0.6939(7) 0.6518(3) 0.079(4) Uiso 1 1 d D . .
F16 F 0.2042(5) -0.7366(7) 0.5559(3) 0.089(4) Uiso 1 1 d D . .
Sb2 Sb 0.23647(7) 0.71929(10) 0.37133(5) 0.0724(5) Uani 1 1 d . . .
F21 F 0.2271(8) 0.8153(12) 0.3544(6) 0.170(8) Uiso 1 1 d . . .
F22 F 0.2389(11) 0.6239(15) 0.3912(8) 0.225(11) Uiso 1 1 d . . .
F23 F 0.2818(6) 0.7534(8) 0.4120(4) 0.097(5) Uiso 1 1 d . . .
F24 F 0.2919(7) 0.7074(10) 0.3412(5) 0.135(6) Uiso 1 1 d . . .
F25 F 0.1916(8) 0.6881(11) 0.3296(6) 0.161(7) Uiso 1 1 d . . .
F26 F 0.1775(10) 0.7392(14) 0.3994(7) 0.201(10) Uiso 1 1 d . . .
Sb3 Sb 0.47148(6) 0.66524(9) 0.67648(5) 0.0595(5) Uani 1 1 d . . .
F31 F 0.4163(5) 0.7276(7) 0.6908(3) 0.075(4) Uiso 1 1 d . . .
F32 F 0.4204(5) 0.5937(8) 0.6600(4) 0.090(4) Uiso 1 1 d . . .
F33 F 0.5218(7) 0.7377(10) 0.6924(5) 0.128(6) Uiso 1 1 d . . .
F34 F 0.5256(7) 0.6030(9) 0.6610(5) 0.120(6) Uiso 1 1 d . . .
F35 F 0.4632(7) 0.7104(10) 0.6290(5) 0.137(6) Uiso 1 1 d . . .
F36 F 0.4745(7) 0.6223(10) 0.7250(5) 0.129(6) Uiso 1 1 d . . .
Sb4 Sb -0.03189(13) 0.39580(17) 0.29032(8) 0.0553(8) Uani 0.50 1 d PD A 1
F41 F 0.0088(10) 0.3271(13) 0.2655(7) 0.119(11) Uiso 0.50 1 d PD A 1
F42 F -0.0535(9) 0.3283(11) 0.3206(6) 0.084(8) Uiso 0.50 1 d PD A 1
F43 F -0.0127(9) 0.4653(11) 0.2582(6) 0.083(8) Uiso 0.50 1 d PD A 1
F44 F -0.0718(7) 0.4651(9) 0.3152(5) 0.051(6) Uiso 0.50 1 d PD A 1
F45 F 0.0258(10) 0.3962(18) 0.3236(8) 0.193(18) Uiso 0.50 1 d PD A 1
F46 F -0.0817(8) 0.3691(13) 0.2564(6) 0.096(9) Uiso 0.50 1 d PD A 1
Sb5 Sb 0.07293(19) 0.3885(3) 0.40570(13) 0.1151(16) Uani 0.50 1 d PD B 2
F51 F 0.1401(7) 0.3693(12) 0.4290(7) 0.088(3) Uiso 0.50 1 d PD B 2
F52 F 0.0454(8) 0.4663(9) 0.4218(6) 0.088(3) Uiso 0.50 1 d PD B 2
F53 F 0.0470(9) 0.3008(8) 0.4113(6) 0.088(3) Uiso 0.50 1 d PD B 2
F54 F 0.0133(7) 0.4203(11) 0.3693(6) 0.088(3) Uiso 0.50 1 d PD B 2
F55 F 0.1165(7) 0.4627(11) 0.3972(6) 0.088(3) Uiso 0.50 1 d PD B 2
F56 F 0.0625(9) 0.3720(12) 0.4539(5) 0.088(3) Uiso 0.50 1 d PD B 2
C1SA C 0.0308(6) -1.137(3) 0.5684(7) 0.093(17) Uiso 0.50 1 d PD . .
H1SA H 0.0307 -1.1897 0.5584 0.111 Uiso 0.50 1 calc PRD . .
Cl1 Cl 0.0471(7) -1.1513(10) 0.6130(5) 0.141(7) Uiso 0.50 1 d PD . .
Cl2 Cl 0.0777(6) -1.0987(8) 0.5447(4) 0.099(5) Uiso 0.50 1 d PD . .
Cl3 Cl -0.0318(6) -1.1126(8) 0.5566(4) 0.098(4) Uiso 0.50 1 d PD . .
N1AS N 0.1388(13) -0.9380(17) 0.7901(10) 0.045(9) Uiso 0.50 1 d PD . .
O1S O 0.1540(15) -0.916(2) 0.8188(10) 0.108(13) Uiso 0.50 1 d PD . .
O2S O 0.1276(10) -0.9079(15) 0.7689(7) 0.046(7) Uiso 0.50 1 d PD . .
C1AS C 0.1224(16) -1.010(2) 0.7995(11) 0.055(11) Uiso 0.50 1 d PD . .
H1A1 H 0.0826 -1.0149 0.7945 0.082 Uiso 0.50 1 calc PR . .
H1A2 H 0.1328 -1.0199 0.8267 0.082 Uiso 0.50 1 calc PR . .
H1A3 H 0.1404 -1.0474 0.7841 0.082 Uiso 0.50 1 calc PR . .
N2AS N 0.3054(15) -0.928(2) 0.9115(10) 0.062(10) Uiso 0.50 1 d PD . .
O5S O 0.3743(14) -1.1242(18) 0.5167(10) 0.093(11) Uiso 0.50 1 d PD . .
O6S O 0.3891(12) -1.0233(16) 0.5145(9) 0.075(9) Uiso 0.50 1 d PD . .
C2AS C 0.2497(19) -0.930(3) 0.8997(16) 0.12(2) Uiso 0.50 1 d PD . .
H2A1 H 0.2290 -0.9430 0.9213 0.176 Uiso 0.50 1 calc PR . .
H2A2 H 0.2428 -0.9670 0.8793 0.176 Uiso 0.50 1 calc PR . .
H2A3 H 0.2382 -0.8799 0.8900 0.176 Uiso 0.50 1 calc PR . .
N3AS N 0.3683(12) -1.0703(18) 0.4964(9) 0.042(8) Uiso 0.50 1 d P . .
O7S O 0.3368(14) -0.8971(19) 0.9258(9) 0.084(10) Uiso 0.50 1 d P . .
O8S O 0.3170(16) -0.975(2) 0.8778(11) 0.119(13) Uiso 0.50 1 d P . .
C3AS C 0.3564(17) -1.078(2) 0.4595(12) 0.061(12) Uiso 0.50 1 d P . .
H3A1 H 0.3229 -1.0499 0.4518 0.092 Uiso 0.50 1 calc PR . .
H3A2 H 0.3508 -1.1313 0.4534 0.092 Uiso 0.50 1 calc PR . .
H3A3 H 0.3867 -1.0584 0.4459 0.092 Uiso 0.50 1 calc PR . .
O1W O 0.538(2) -1.062(3) 0.5964(13) 0.149(17) Uiso 0.50 1 d P C 1
O1W' O 0.5942(19) -1.025(3) 0.6063(13) 0.149(17) Uiso 0.50 1 d P D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Ag1 P2 123.17(18) . .
P1 Ag1 P3 113.49(18) . .
P2 Ag1 P3 121.35(18) . .
N1S Ag2 P5 109.2(5) . .
N1S Ag2 P4 107.1(5) . .
P5 Ag2 P4 143.70(18) . .
N16S Ag3 P6 119.3(5) 3_546 .
N16S Ag3 P7 99.8(5) 3_546 .
P6 Ag3 P7 140.75(18) . .
P8 Ag4 P9 175.25(19) . .
C91 P1 C1 106.6(10) . .
C91 P1 C109 112.3(12) . .
C1 P1 C109 99.1(10) . .
C91 P1 Ag1 109.4(7) . .
C1 P1 Ag1 110.9(7) . .
C109 P1 Ag1 117.6(9) . .
C121 P2 C115 104.3(10) . .
C121 P2 C31 104.9(9) . .
C115 P2 C31 104.9(9) . .
C121 P2 Ag1 114.7(7) . .
C115 P2 Ag1 115.2(6) . .
C31 P2 Ag1 111.8(6) . .
C79 P3 C85 106.5(10) . .
C79 P3 C63 104.5(9) . .
C85 P3 C63 105.8(9) . .
C79 P3 Ag1 111.3(7) . .
C85 P3 Ag1 119.0(7) . .
C63 P3 Ag1 108.7(6) . .
C73 P4 C67 106.8(9) . .
C73 P4 C61 107.2(8) . .
C67 P4 C61 105.6(9) . .
C73 P4 Ag2 110.8(6) . .
C67 P4 Ag2 115.2(7) . .
C61 P4 Ag2 110.7(5) . .
C37 P5 C33 107.0(9) . .
C37 P5 C43 105.6(9) . .
C33 P5 C43 106.2(9) . .
C37 P5 Ag2 117.8(7) . .
C33 P5 Ag2 104.2(6) . .
C43 P5 Ag2 115.3(6) . .
C103 P6 C97 104.6(10) . .
C103 P6 C65 107.3(9) . .
C97 P6 C65 103.5(9) . .
C103 P6 Ag3 109.2(8) . .
C97 P6 Ag3 118.8(8) . .
C65 P6 Ag3 112.6(6) . .
C3 P7 C7 103.7(9) . .
C3 P7 C13 106.0(8) . .
C7 P7 C13 105.7(9) . .
C3 P7 Ag3 104.4(6) . .
C7 P7 Ag3 116.9(7) . .
C13 P7 Ag3 118.6(6) . .
C55 P8 C49 106.7(10) . .
C55 P8 C35 101.3(10) . .
C49 P8 C35 105.5(10) . .
C55 P8 Ag4 116.3(8) . .
C49 P8 Ag4 114.3(7) . .
C35 P8 Ag4 111.5(6) . .
C19 P9 C25 106.6(9) . .
C19 P9 C5 109.6(10) . .
C25 P9 C5 104.2(9) . .
C19 P9 Ag4 120.0(7) . .
C25 P9 Ag4 108.8(7) . .
C5 P9 Ag4 106.6(6) . .
C2S N1S Ag2 143.8(19) . .
N1S C2S C3S 176(3) . .
C8S C3S C4S 118(2) . .
C8S C3S C2S 123(2) . .
C4S C3S C2S 118(2) . .
C3S C4S C5S 121(2) . .
C6S C5S C4S 118(2) . .
C7S C6S C5S 119(2) . .
C7S C6S C9S 124.1(19) . .
C5S C6S C9S 116(2) . .
C6S C7S C8S 123(2) . .
C3S C8S C7S 120(2) . .
C14S C9S C10S 121.0(19) . .
C14S C9S C6S 119.1(19) . .
C10S C9S C6S 120(2) . .
C11S C10S C9S 119(2) . .
C12S C11S C10S 121(2) . .
C11S C12S C13S 119(2) . .
C11S C12S C15S 117(2) . .
C13S C12S C15S 123(2) . .
C14S C13S C12S 122(2) . .
C13S C14S C9S 118(2) . .
N16S C15S C12S 176(3) . .
C15S N16S Ag3 158.8(19) . 3_546
N6 C1 N2 122.1(16) . .
N6 C1 P1 116.2(14) . .
N2 C1 P1 121.1(14) . .
C3 N2 C1 116.7(15) . .
N2 C3 N4 123.9(16) . .
N2 C3 P7 119.6(13) . .
N4 C3 P7 116.4(13) . .
C5 N4 C3 116.2(16) . .
N4 C5 N6 124.3(17) . .
N4 C5 P9 124.2(16) . .
N6 C5 P9 111.3(15) . .
C1 N6 C5 116.5(16) . .
C8 C7 C12 119.0(19) . .
C8 C7 P7 123.1(16) . .
C12 C7 P7 117.7(16) . .
C7 C8 C9 121(2) . .
C10 C9 C8 121(2) . .
C9 C10 C11 118(2) . .
C12 C11 C10 120(2) . .
C7 C12 C11 122(2) . .
C18 C13 C14 117.1(16) . .
C18 C13 P7 119.5(14) . .
C14 C13 P7 123.1(13) . .
C13 C14 C15 121.8(16) . .
C16 C15 C14 121.3(17) . .
C15 C16 C17 117.5(17) . .
C18 C17 C16 119.0(16) . .
C13 C18 C17 123.0(17) . .
C20 C19 C24 115(2) . .
C20 C19 P9 117.1(17) . .
C24 C19 P9 127.4(15) . .
C19 C20 C21 120(2) . .
C22 C21 C20 117(2) . .
C23 C22 C21 124(3) . .
C24 C23 C22 119(2) . .
C23 C24 C19 123(2) . .
C30 C25 C26 117.8(19) . .
C30 C25 P9 124.5(16) . .
C26 C25 P9 117.6(16) . .
C27 C26 C25 120(2) . .
C28 C27 C26 120(2) . .
C29 C28 C27 122(2) . .
C28 C29 C30 119(2) . .
C25 C30 C29 121(2) . .
N36 C31 N32 126.3(17) . .
N36 C31 P2 118.7(14) . .
N32 C31 P2 114.9(14) . .
C33 N32 C31 113.4(16) . .
N32 C33 N34 126.0(17) . .
N32 C33 P5 115.0(14) . .
N34 C33 P5 118.7(13) . .
C35 N34 C33 114.3(15) . .
N36 C35 N34 125.4(17) . .
N36 C35 P8 114.4(14) . .
N34 C35 P8 120.2(15) . .
C31 N36 C35 114.4(16) . .
C42 C37 C38 118.9(19) . .
C42 C37 P5 119.0(16) . .
C38 C37 P5 121.7(16) . .
C39 C38 C37 123(2) . .
C38 C39 C40 116(2) . .
C41 C40 C39 124(2) . .
C42 C41 C40 117(3) . .
C37 C42 C41 121(2) . .
C44 C43 C48 119(2) . .
C44 C43 P5 120.8(16) . .
C48 C43 P5 119.7(15) . .
C45 C44 C43 120(2) . .
C44 C45 C46 122(2) . .
C47 C46 C45 118(2) . .
C46 C47 C48 121(2) . .
C47 C48 C43 120(2) . .
C50 C49 C54 117(2) . .
C50 C49 P8 126.2(17) . .
C54 C49 P8 116.6(17) . .
C49 C50 C51 122(2) . .
C52 C51 C50 120(2) . .
C51 C52 C53 122(2) . .
C52 C53 C54 117(3) . .
C53 C54 C49 121(2) . .
C60 C55 C56 118(2) . .
C60 C55 P8 123.7(18) . .
C56 C55 P8 118.8(19) . .
C55 C56 C57 121(3) . .
C58 C57 C56 118(3) . .
C57 C58 C59 123(3) . .
C60 C59 C58 115(3) . .
C55 C60 C59 125(3) . .
N62 C61 N66 126.8(17) . .
N62 C61 P4 116.5(13) . .
N66 C61 P4 116.1(13) . .
C61 N62 C63 116.0(16) . .
N62 C63 N64 122.9(16) . .
N62 C63 P3 121.0(13) . .
N64 C63 P3 115.7(14) . .
C63 N64 C65 117.1(16) . .
N66 C65 N64 122.9(16) . .
N66 C65 P6 121.0(13) . .
N64 C65 P6 115.8(14) . .
C65 N66 C61 114.2(15) . .
C68 C67 C72 120.0(18) . .
C68 C67 P4 121.7(16) . .
C72 C67 P4 117.9(14) . .
C67 C68 C69 121(2) . .
C68 C69 C70 119(2) . .
C71 C70 C69 121(2) . .
C70 C71 C72 118(2) . .
C67 C72 C71 121(2) . .
C78 C73 C74 116.6(17) . .
C78 C73 P4 123.4(15) . .
C74 C73 P4 119.9(14) . .
C75 C74 C73 120.6(19) . .
C74 C75 C76 119(2) . .
C77 C76 C75 121(2) . .
C76 C77 C78 121(2) . .
C73 C78 C77 121.5(19) . .
C80 C79 C84 114.8(14) . .
C80 C79 P3 126.0(12) . .
C84 C79 P3 119.1(12) . .
C79 C80 C81 125.6(8) . .
C82 C81 C80 118.4 . .
C81 C82 C83 117.8 . .
C84 C83 C82 117.8 . .
C79 C84 C83 125.6(8) . .
C90 C85 C86 116.7(18) . .
C90 C85 P3 121.4(15) . .
C86 C85 P3 121.8(15) . .
C87 C86 C85 121(2) . .
C86 C87 C88 119(2) . .
C89 C88 C87 121(2) . .
C88 C89 C90 119(2) . .
C85 C90 C89 123(2) . .
C96 C91 C92 118(2) . .
C96 C91 P1 118.7(18) . .
C92 C91 P1 123.4(17) . .
C91 C92 C93 118(2) . .
C94 C93 C92 124(3) . .
C93 C94 C95 115(3) . .
C94 C95 C96 127(3) . .
C91 C96 C95 118(2) . .
C102 C97 C98 117(2) . .
C102 C97 P6 121.4(18) . .
C98 C97 P6 121.2(19) . .
C99 C98 C97 125(3) . .
C100 C99 C98 118(3) . .
C99 C100 C101 121(3) . .
C102 C101 C100 121(3) . .
C97 C102 C101 118(3) . .
C104 C103 C108 116(2) . .
C104 C103 P6 116.3(18) . .
C108 C103 P6 123.9(18) . .
C103 C104 C105 117(3) . .
C106 C105 C104 121(3) . .
C107 C106 C105 123(3) . .
C106 C107 C108 116(3) . .
C103 C108 C107 123(3) . .
C110 C109 C114 122(3) . .
C110 C109 P1 121(3) . .
C114 C109 P1 116(3) . .
C109 C110 C111 124(4) . .
C110 C111 C112 117(5) . .
C113 C112 C111 114(7) . .
C114 C113 C112 134(7) . .
C113 C114 C109 109(5) . .
C120 C115 C116 118(2) . .
C120 C115 P2 124.7(16) . .
C116 C115 P2 117.1(16) . .
C115 C116 C117 118(2) . .
C118 C117 C116 121(2) . .
C119 C118 C117 122(2) . .
C118 C119 C120 118(2) . .
C115 C120 C119 123(2) . .
C122 C121 C126 117.7(19) . .
C122 C121 P2 117.3(17) . .
C126 C121 P2 125.0(15) . .
C121 C122 C123 118(2) . .
C122 C123 C124 126(2) . .
C125 C124 C123 113(3) . .
C124 C125 C126 124(2) . .
C121 C126 C125 121.1(19) . .
F16 Sb1 F12 86.5(6) . .
F16 Sb1 F13 92.7(6) . .
F12 Sb1 F13 177.6(6) . .
F16 Sb1 F15 173.1(6) . .
F12 Sb1 F15 87.1(5) . .
F13 Sb1 F15 93.8(6) . .
F16 Sb1 F11 90.8(6) . .
F12 Sb1 F11 94.9(5) . .
F13 Sb1 F11 87.4(6) . .
F15 Sb1 F11 87.1(6) . .
F16 Sb1 F14 93.5(6) . .
F12 Sb1 F14 87.2(5) . .
F13 Sb1 F14 90.6(6) . .
F15 Sb1 F14 88.9(5) . .
F11 Sb1 F14 175.3(6) . .
F24 Sb2 F21 89.9(9) . .
F24 Sb2 F22 96.6(10) . .
F21 Sb2 F22 173.5(11) . .
F24 Sb2 F25 85.6(8) . .
F21 Sb2 F25 88.4(9) . .
F22 Sb2 F25 91.4(10) . .
F24 Sb2 F23 93.6(7) . .
F21 Sb2 F23 89.7(8) . .
F22 Sb2 F23 90.6(9) . .
F25 Sb2 F23 177.9(8) . .
F24 Sb2 F26 174.6(10) . .
F21 Sb2 F26 85.0(10) . .
F22 Sb2 F26 88.6(11) . .
F25 Sb2 F26 92.5(10) . .
F23 Sb2 F26 88.2(9) . .
F33 Sb3 F32 179.0(7) . .
F33 Sb3 F35 89.3(8) . .
F32 Sb3 F35 89.8(7) . .
F33 Sb3 F34 91.7(7) . .
F32 Sb3 F34 88.8(7) . .
F35 Sb3 F34 91.1(7) . .
F33 Sb3 F31 89.1(7) . .
F32 Sb3 F31 90.4(6) . .
F35 Sb3 F31 87.7(7) . .
F34 Sb3 F31 178.6(6) . .
F33 Sb3 F36 92.0(7) . .
F32 Sb3 F36 88.8(7) . .
F35 Sb3 F36 175.6(8) . .
F34 Sb3 F36 93.0(7) . .
F31 Sb3 F36 88.2(6) . .
F46 Sb4 F42 90.0(11) . .
F46 Sb4 F45 163.2(13) . .
F42 Sb4 F45 82.1(12) . .
F46 Sb4 F43 87.7(10) . .
F42 Sb4 F43 177.4(11) . .
F45 Sb4 F43 100.4(12) . .
F46 Sb4 F44 98.2(9) . .
F42 Sb4 F44 88.2(9) . .
F45 Sb4 F44 96.3(11) . .
F43 Sb4 F44 91.0(9) . .
F46 Sb4 F41 82.4(10) . .
F42 Sb4 F41 92.2(10) . .
F45 Sb4 F41 83.1(12) . .
F43 Sb4 F41 88.6(10) . .
F44 Sb4 F41 179.3(11) . .
F52 Sb5 F53 123.8(10) . .
F52 Sb5 F56 73.4(8) . .
F53 Sb5 F56 69.5(9) . .
F52 Sb5 F55 72.6(9) . .
F53 Sb5 F55 162.9(11) . .
F56 Sb5 F55 115.7(9) . .
F52 Sb5 F51 112.6(9) . .
F53 Sb5 F51 96.3(10) . .
F56 Sb5 F51 74.5(9) . .
F55 Sb5 F51 70.9(9) . .
F52 Sb5 F54 71.2(9) . .
F53 Sb5 F54 94.3(7) . .
F56 Sb5 F54 121.4(10) . .
F55 Sb5 F54 96.0(7) . .
F51 Sb5 F54 163.4(10) . .
F56 F52 Sb5 55.6(6) . .
F52 F56 Sb5 51.0(6) . .
Cl1 C1SA Cl3 116.4(15) . .
Cl1 C1SA Cl2 116.1(15) . .
Cl3 C1SA Cl2 117.0(15) . .
O2S N1AS O1S 125(4) . .
O2S N1AS C1AS 130(4) . .
O1S N1AS C1AS 101(4) . .
O7S N2AS C2AS 145(5) . .
O7S N2AS O8S 120(4) . .
C2AS N2AS O8S 90(4) . .
O6S N3AS O5S 103(3) . .
O6S N3AS C3AS 133(4) . .
O5S N3AS C3AS 121(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 P1 2.484(6) .
Ag1 P2 2.499(5) .
Ag1 P3 2.522(5) .
Ag2 N1S 2.345(19) .
Ag2 P5 2.413(6) .
Ag2 P4 2.430(5) .
Ag3 N16S 2.317(19) 3_546
Ag3 P6 2.424(6) .
Ag3 P7 2.446(6) .
Ag4 P8 2.386(6) .
Ag4 P9 2.403(6) .
P1 C91 1.79(2) .
P1 C1 1.790(19) .
P1 C109 1.85(3) .
P2 C121 1.77(2) .
P2 C115 1.79(2) .
P2 C31 1.850(19) .
P3 C79 1.704(18) .
P3 C85 1.756(18) .
P3 C63 1.812(18) .
P4 C73 1.789(19) .
P4 C67 1.809(19) .
P4 C61 1.841(18) .
P5 C37 1.783(19) .
P5 C33 1.832(19) .
P5 C43 1.852(19) .
P6 C103 1.81(2) .
P6 C97 1.81(2) .
P6 C65 1.824(18) .
P7 C3 1.790(18) .
P7 C7 1.795(19) .
P7 C13 1.817(17) .
P8 C55 1.77(2) .
P8 C49 1.77(2) .
P8 C35 1.820(19) .
P9 C19 1.81(2) .
P9 C25 1.806(19) .
P9 C5 1.818(19) .
N1S C2S 1.19(2) .
C2S C3S 1.39(3) .
C3S C8S 1.34(3) .
C3S C4S 1.37(3) .
C4S C5S 1.44(3) .
C5S C6S 1.36(3) .
C6S C7S 1.34(3) .
C6S C9S 1.50(3) .
C7S C8S 1.38(3) .
C9S C14S 1.39(3) .
C9S C10S 1.39(3) .
C10S C11S 1.37(2) .
C11S C12S 1.36(3) .
C12S C13S 1.38(3) .
C12S C15S 1.41(3) .
C13S C14S 1.36(3) .
C15S N16S 1.15(2) .
N16S Ag3 2.317(19) 3_546
C1 N6 1.34(2) .
C1 N2 1.41(2) .
N2 C3 1.34(2) .
C3 N4 1.36(2) .
N4 C5 1.35(2) .
C5 N6 1.37(2) .
C7 C8 1.36(3) .
C7 C12 1.39(2) .
C8 C9 1.43(3) .
C9 C10 1.39(3) .
C10 C11 1.41(3) .
C11 C12 1.40(3) .
C13 C18 1.334(19) .
C13 C14 1.343(19) .
C14 C15 1.394(16) .
C15 C16 1.319(16) .
C16 C17 1.408(17) .
C17 C18 1.379(16) .
C19 C20 1.41(3) .
C19 C24 1.42(3) .
C20 C21 1.43(3) .
C21 C22 1.34(3) .
C22 C23 1.34(3) .
C23 C24 1.34(3) .
C25 C30 1.38(3) .
C25 C26 1.39(3) .
C26 C27 1.38(3) .
C27 C28 1.35(3) .
C28 C29 1.33(3) .
C29 C30 1.39(3) .
C31 N36 1.34(2) .
C31 N32 1.38(2) .
N32 C33 1.33(2) .
C33 N34 1.37(2) .
N34 C35 1.36(2) .
C35 N36 1.34(2) .
C37 C42 1.38(3) .
C37 C38 1.44(3) .
C38 C39 1.36(3) .
C39 C40 1.42(3) .
C40 C41 1.41(3) .
C41 C42 1.40(3) .
C43 C44 1.36(3) .
C43 C48 1.39(2) .
C44 C45 1.36(3) .
C45 C46 1.38(3) .
C46 C47 1.36(3) .
C47 C48 1.36(3) .
C49 C50 1.35(3) .
C49 C54 1.42(3) .
C50 C51 1.38(3) .
C51 C52 1.31(3) .
C52 C53 1.39(3) .
C53 C54 1.40(3) .
C55 C60 1.38(3) .
C55 C56 1.39(3) .
C56 C57 1.43(3) .
C57 C58 1.38(4) .
C58 C59 1.42(4) .
C59 C60 1.40(3) .
C61 N62 1.32(2) .
C61 N66 1.36(2) .
N62 C63 1.33(2) .
C63 N64 1.36(2) .
N64 C65 1.37(2) .
C65 N66 1.34(2) .
C67 C68 1.37(2) .
C67 C72 1.40(3) .
C68 C69 1.38(3) .
C69 C70 1.42(3) .
C70 C71 1.40(3) .
C71 C72 1.41(3) .
C73 C78 1.38(2) .
C73 C74 1.48(2) .
C74 C75 1.37(2) .
C75 C76 1.39(3) .
C76 C77 1.38(3) .
C77 C78 1.38(2) .
C79 C80 1.299(18) .
C79 C84 1.311(18) .
C80 C81 1.3971 .
C81 C82 1.3208 .
C82 C83 1.4174 .
C83 C84 1.3508 .
C85 C90 1.38(2) .
C85 C86 1.42(2) .
C86 C87 1.39(3) .
C87 C88 1.38(3) .
C88 C89 1.38(3) .
C89 C90 1.40(3) .
C91 C96 1.39(3) .
C91 C92 1.42(3) .
C92 C93 1.48(3) .
C93 C94 1.32(3) .
C94 C95 1.36(3) .
C95 C96 1.42(3) .
C97 C102 1.37(3) .
C97 C98 1.37(3) .
C98 C99 1.36(3) .
C99 C100 1.30(4) .
C100 C101 1.39(3) .
C101 C102 1.39(3) .
C103 C104 1.35(3) .
C103 C108 1.39(3) .
C104 C105 1.40(3) .
C105 C106 1.36(4) .
C106 C107 1.26(4) .
C107 C108 1.42(3) .
C109 C110 1.275(14) .
C109 C114 1.281(15) .
C110 C111 1.279(15) .
C111 C112 1.29(2) .
C112 C113 1.273(16) .
C113 C114 1.262(13) .
C115 C120 1.39(3) .
C115 C116 1.40(3) .
C116 C117 1.44(3) .
C117 C118 1.38(3) .
C118 C119 1.34(3) .
C119 C120 1.43(3) .
C121 C122 1.37(3) .
C121 C126 1.40(3) .
C122 C123 1.41(3) .
C123 C124 1.41(3) .
C124 C125 1.32(3) .
C125 C126 1.41(3) .
Sb1 F16 1.706(12) .
Sb1 F12 1.760(11) .
Sb1 F13 1.776(12) .
Sb1 F15 1.800(11) .
Sb1 F11 1.854(12) .
Sb1 F14 1.869(12) .
Sb2 F24 1.805(18) .
Sb2 F21 1.82(2) .
Sb2 F22 1.83(3) .
Sb2 F25 1.84(2) .
Sb2 F23 1.836(14) .
Sb2 F26 1.85(2) .
Sb3 F33 1.837(17) .
Sb3 F32 1.842(14) .
Sb3 F35 1.847(18) .
Sb3 F34 1.845(16) .
Sb3 F31 1.850(12) .
Sb3 F36 1.865(17) .
Sb4 F46 1.699(16) .
Sb4 F42 1.717(15) .
Sb4 F45 1.757(17) .
Sb4 F43 1.765(15) .
Sb4 F44 1.839(14) .
Sb4 F41 1.842(17) .
Sb5 F52 1.659(14) .
Sb5 F53 1.701(15) .
Sb5 F56 1.760(15) .
Sb5 F55 1.738(15) .
Sb5 F51 1.806(15) .
Sb5 F54 1.942(14) .
F52 F56 2.04(2) .
C1SA Cl1 1.605(17) .
C1SA Cl3 1.613(17) .
C1SA Cl2 1.627(17) .
N1AS O2S 0.94(3) .
N1AS O1S 1.11(4) .
N1AS C1AS 1.40(4) .
N2AS O7S 1.04(4) .
N2AS C2AS 1.39(4) .
N2AS O8S 1.50(5) .
O5S N3AS 1.20(4) .
O6S N3AS 1.14(4) .
N3AS C3AS 1.31(4) .
